15. You are interested in separating 4-methylbenzoic acid from 1,4-dimethoxybenzene using a procedure similar to the extraction procedure we used in lab. You plan to use sodium bicarbonate instead of sodium hydroxide. a) Show the reaction between salicylic acid and sodium bicarbonate. Label the acid, base, conjugate acid, conjugate base. b) Give the pKa values of the acid and conjugate acid. c) Which base will work better, sodium hydroxide or sodium bicarbonate

Answers

Answer 1

Solution :

a). The separation of 4-methylbenzoic acid from 1,4-dimethoxybenzene will work but it will result in lower recovery.

In the reaction of acid-base to form a sodium 4 - methoxy benzoate, that is soluble in the water, 4-methoxy benzoic acid reacts with the sodium bicarbonate to give sodium 4-methoxybenzoate as well as carbonic acid.

b). The pKa for the 4-methoxybenzoic acid is [tex]4.46[/tex], and that of carbonic acid is [tex]6.37[/tex]

c). The Keq for the reaction is [tex]10(6.37 - 4.46) = 101.91[/tex]

Therefore, the equilibrium lies to the right  and also the reaction favors the products and the separation works.

But the recovery will be low when compared to the extraction with Sodium hydroxide as the strong base will drive the equilibrium further to the right position, thus neutralizing all the acids virtually. And the weak base will partially neutralize the acid.


Related Questions

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Answers

Answer:

Danger

Explanation:

Cal is titrating 57.7 mL of 0.311 M HBr with 0.304 M Ba(OH)2. How many mL of Ba(OH)2 does Cal need to add to reach the equivalence point?

Answers

Answer:

118.06 mL

Explanation:

The neutralization reaction between HBr (acid) and Ba(OH)₂ (base) is the following:

2HBr + Ba(OH)₂ → BaBr₂ + 2H₂O

According to the equation, 2 moles of HBr react with 1 mol Ba(OH)₂. Thus, at the equivalence point the moles of acid and base react completely:

2 moles HBr = 1 mol Ba(OH)₂

We can replace the moles by the product of the molar concentration (M) and volume (V):

2 x (M HBr) x (V HBr) = M Ba(OH)₂ x V Ba(OH)₂

Now, we introduce the data in the equation to calculate the volume in mL of Ba(OH)₂:

V Ba(OH)₂ = (2 x (M HBr) x (V HBr))/M Ba(OH)₂

                 = (2 x 0.311 M x 57.7 mL)/(0.304 M)

                 = 118.06 mL

Therefore, 118 mL of Ba(OH)₂ are needed.

Which procedure could a student use to examine an intensive property of a rectangular block of wood
Find the mass.
Record the length. Measure the volume. Determine the density.

Answers

Answer:

density

Explanation:

The procedure that the student could use to examine an intensive property of a rectangular block of wood is to determine its density. Density is intensive because it is the ration between the mass and the volume.

Answer: find the mass option A

Explanation:

How do forces between particles in gases compare to forces in the other states of matter?​

Answers

The forces in gases are weaker than forces in solids and liquids.

Because they have more kinetic energy that overcomes the force of attraction.

By how many times would you expect Al2(SO4)3 to depress the F.P of water compared to sucrose C12H22011 ?​

Answers

Answer:

By how many times would you expect Al2(SO4)3 to depress the F.P of water compared to sucrose C12H22011 ?.

Explanation:

The freezing point of a pure solvent decreases further by adding a nonvolatile solute.

This is called depression in freezing point.

When an ionic solute is dissolved then the depression in the freezing point is proportional to the number of ions present in the solution.

In aluminum sulfate, there are five ions formed as shown below:

[tex]Al_2(SO_4)_3(aq)->2Al^3^+(aq)+3SO_4^2^-(aq)[/tex]

But sucrose is a covalent compound and it does not undergo dissociation.

Hence, aluminum sulfate decreases the freezing point of water by five times compared to sucrose.

Explanation:

Which of the following was NOT explained by Dalton's atomic theory?
ANSWER:
A. the Law of Multiple Proportions
B. the difference between elements and compounds
C.?the difference between isotopes of an element
D. the Law of Conservation of Mass

Answers

Answer:

i think 1. law of muliple proportion

Explanation:

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Answers

Answer:

hey friend

how can I help you

I need help with the practice question at the bottom. Thank you.

Answers

As the gas expands on the surrounding, work is done by the system.

Therefore, W= -279J

Absorbtion of heat,q= +216J

∆U=q+W = (216-279)J= -63J

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Which statement describes an electron?
EEEE
It has a positive charge and is located in the nucleus.
O It has a positive charge and is located in orbitals around the nucleus.
It has a negative charge and is located in the nucleus.
O It has a negative charge and is located in orbitals around the nucleus.

Answers

Answer:

It has a negative charge and is located in orbitals around the nucleus

Explanation:

The statement describes an electron is " It has a negative charge and is located in orbitals around the nucleus."

What is electron?

The electron would be a subatomic particle with a negatively one elementary charge electric charge.

What is nucleus?

Protons, that have a positive charge, as well as neutrons, which have no electrical charge, make up the nucleus. Quarks were subatomic particles that make up protons but also neutrons.

Electrons were present surrounding the atom's nucleus, in contrast to protons as well as neutrons, that are contained within the nucleus at its core. Negative electrons were drawn to the positive nucleus since the electric charges of opposite polarity attract one another.

To know more about electrons and nucleus.

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The length of a covalent bond depends upon the size of the atoms and the bond order.

a. True
b. False

Answers

Answer:

True

Explanation:

The length of covalent bond depends upon the size of atoms and the bond order.

What is the cell potential of an electrochemical cell that has the half-reactions shown below?
Ag⁺ + e⁻ → Ag
Fe → Fe³⁺ + 3e⁻

Answers

Answer:

E°(Ag⁺/Fe°) = 0.836 volt

Explanation:

3Ag⁺ + 3e⁻ => Ag°;            E° = +0.800 volt

Fe° => Fe⁺³ + 3e⁻ ;             E° = -0.036 volt

_________________________________

Fe°(s) + 3Ag⁺(aq) => Fe⁺³(aq) + 3Ag°(s) ...    

E°(Ag⁺/Fe°) = E°(Ag⁺) - E°(Fe°) = 0.800v - ( -0.036v) = 0.836 volt

What is unit? Write down the units of mass, temperature and power​

Answers

Explanation:

a single thing, person, or group forming part of a whole There are 36 units in my apartment building. the least whole number : one. a fixed quantity (as of length, time, or value) used as a standard of measurement An inch is a unit of length.

mass=kilogram (kg)

temperature=kelvin

power=watt

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A unit of measurement is a definite magnitude of a quantity, defined and adopted by convention or by law, that is used as a standard for measurement of the same kind of quantity. Any other quantity of that kind can be expressed as a multiple of the unit of measurement
Mass - kilogram ( kg )
Temperature - Kelvin
Power - watt

Which of the five type of equilibrium problems best applies to this question: Consider the following reaction at equilibrium. What effect will reducing the volume of the reaction mixture have on the system

Answers

Answer:

d

Explanation:

g in the following three compounds(1,2,3) arrange their relative reactivity towards the reagent CH3Cl / AlCl3. Justify your order

Answers

Answer:

3 > 2> 1

Explanation:

Aromatic compounds undergo electrophilic substitution reaction with several electrophiles.

Some substituted benzenes are more reactive towards electrophilic aromatic substitution than unsubstituted benzene.

Certain groups of substituents increase the ease with which an aromatic compound undergoes aromatic substitution.

If we look at the compounds closely, we will notice that only toluene leads to easy reaction with CH3Cl / AlCl3. Thus is due to the +I inductive effect of -CH3 which stabilizes the negatively charged intermediate produced in the reaction.

What is the volume of a flask containing 0.199mol of Cl2at a temperature of 313K and a pressure of 1.19atm

Answers

Answer:

43.0 L

Explanation:

Step 1: Given and required data

Moles of chlorine gas (n): 0.199 molTemperature (T): 313 KPressure (P): 1.19 atmIdeal gas constant (R): 0.0821 atm.L/mol.K

Step 2: Calculate the volume of the flask (V)

We will use the ideal gas equation.

P × V = n × R × T

V = n × R × T / P

V = 1.99 mol × (0.0821 atm.L/mol.K) × 313 K / 1.19 atm = 43.0 L

The answer is 4.30 L

A major component of gasoline is octane when octane is burned in air it chemically reacts with oxygen to produce carbon dioxide and water what mass of carbon dioxide is produced by the reaction of oxygen

Answers

gasoline is the chemical that is coming out of the air

A beaker is filled to the 500 mL mark with alcohol. What increase in volume (in mL) does the beaker contain when the temperature changes from 5° C to 30° C? (Neglect the expansion of the beaker, evaporation of alcohol and absorption of water vapor by alcohol.) The volume coefficient of expansion γγ for alcohol = 1.12 x 10-4 K-1

Answers

Answer:

"1.4 mL" is the appropriate solution.

Explanation:

According to the question,

[tex]v_0=500[/tex][tex]\alpha =1.12\times 10^{-4}[/tex][tex]\Delta \epsilon = 25[/tex]

Now,

Increase in volume will be:

⇒ [tex]\Delta V = \alpha\times v_0\times \Delta \epsilon[/tex]

By putting the given values, we get

           [tex]=1.12\times 10^{-4}\times 500\times 25[/tex]

           [tex]=1.12\times 10^{-4}\times 12500[/tex]

           [tex]=1.4 \ mL[/tex]


Methanol has the formula CH3OH. What is the predominant intermolecular force between methanol molecules?
ANSWER:
dispersion forces
dipole forces
ionic bonds
hydrogen bonds

Answers

Answer:

hydrogen bonds

Explanation:

similarly CH3OH also has a OH group and H hydrogen thus it will also form h-bonding.

An unknown weak acid with a concentration of 0.530 M has a pH of 5.600. What is the Ka of the weak acid

Answers

Answer:

Ka = 3.45x10⁻⁶

Explanation:

First we calculate [H⁺], using the given pH:

pH = -log[H⁺][H⁺] = [tex]10^{-pH}=10^{-5.6}[/tex] [H⁺] = 2.51x10⁻⁶ M

To solve this problem we can use the following formula describing a monoprotic weak acid:

[H⁺] = [tex]\sqrt{C*Ka}[/tex]

We input the data that we already know:

2.51x10⁻⁶ = [tex]\sqrt{0.530*Ka}[/tex]

And solve for Ka:

Ka = 3.45x10⁻⁶

A product of homolytic fission can never be

a - charged

b - nucleophile

c- both

d-none of these

Answers

Answer:

both

Explanation:

A homolytic fission is said to have occurred when the breakage of a bond between two atoms leaves each of the bonding atoms with equal number of electrons. Homolytic fission often results in the creation of radicals.

Since homolytic fission yields two species with equal number of electrons(usually odd number of electrons), the products of such process can not be charged. They can not be nucleophiles because nucleophiles need to possess two electrons which can be shared with another chemical specie.

define saturated and unsaturated fats​

Answers

Saturated fatty acids lack double bonds between the individual carbon atoms, while in unsaturated fatty acids there is at least one double bond in the fatty acid chain. Saturated fats tend to be solid at room temperature and from animal sources, while unsaturated fats are usually liquid and from plant sources.

Answer:

hope it is helpful to you

Predict the products of below reaction, and whether the solution at equilibrium will be acidic, basic, or neutral.

N2O5 + 3H2O → __________

Answers

Answer: The product of the given reaction is [tex]HNO_{3}[/tex] and the solution at equilibrium will be acidic.

Explanation:

When two or more chemical substances react together then it forms new substances and these new substances are called products.

For example, [tex]3N_{2}O_{5} + 3H_{2}O \rightarrow 6HNO_{3}[/tex]

This shows that nitric acid [tex](HNO_{3})[/tex] is the product formed and it is an acidic substance.

Hence, the solution at equilibrium will be acidic in nature.

Thus, we can conclude that the product of the given reaction is [tex]HNO_{3}[/tex] and the solution at equilibrium will be acidic.

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For the reaction C + 2H2 → CH4, how many moles of hydrogen are needed to make 146.6 grams of methane, CH4 ?

Round your answer to the nearest tenth. If you answer is a whole number like 4, report the answer as 4.0

Use the following molar masses. If you do not use these masses, the computer will mark your answer incorrect.:

Element

Molar Mass

Hydrogen

1

Carbon

12

Answers

Answer: Moles of hydrogen required are 4.57 moles to make 146.6 grams of methane, [tex]CH_{4}[/tex].

Explanation:

Given: Mass of methane = 146.6 g

As moles is the mass of a substance divided by its molar mass. So, moles of methane (molar mass = 16.04 g/mol) are calculated as follows.

[tex]Moles = \frac{mass}{molar mass}\\= \frac{146.6 g}{16.04 g/mol}\\= 9.14 mol[/tex]

The given reaction equation is as follows.

[tex]C + 2H_{2} \rightarrow CH_{4}[/tex]

This shows that 2 moles of hydrogen gives 1 mole of methane. Hence, moles of hydrogen required to form 9.14 moles of methane is as follows.

[tex]Moles of H_{2} = \frac{9.14}{2}\\= 4.57 mol[/tex]

Thus, we can conclude that moles of hydrogen required are 4.57 moles to make 146.6 grams of methane, [tex]CH_{4}[/tex].

Predict the product when 2-methylbutanol is oxidised with pyridium chlorochromate in dichloromethane (PCC/CH2C12) a. CH3CH2CH(CH3)COOH b. CH3CH2CH2CH(CH3)CHO C. CH3CH2CH(CH3)CHO d. CH3CH2CH(CH3)OH 8:40 PM Type a message​

Answers

Answer:

c. CH3CH2CH(CH3)CHO

Explanation:

Hello there!

In this case, according to the process for the one-step oxidation of a primary alcohol with a moderately strong oxidizing agent like pyridinium chlorochromate (PCC), whereby an aldehyde is produced, we infer that the corresponding product will be 2-methylbutanal, which matches with the choice c. CH3CH2CH(CH3)CHO according to the following reaction:

[tex]CH_3CH_2CH(CH_3)CH_2OH\rightarrow CH_3CH_2CH(CH_3)COH[/tex]

Regards!

Classify each of the following as a strong acid or a weak acid and indicate how each should be written in aqueous solution. Classify ... In solution this acid should be written as: weak 1. hydrocyanic acid H3O CN- _______ 2. hydrobromic acid

Answers

Answer:

HCN, weak acid

H⁺, Br⁻, strong acid

Explanation:

Hydrocyanic acid is a weak acid, according to the following equation.

HCN(aq) ⇄ H⁺(aq) + CN⁻(aq)

Thus, it should be written in the undissociated form (HCN).

Hydrobromic acid is a strong acid, according to the following equation.

HBr(aq) ⇒ H⁺(aq) + Br⁻(aq)

Thus, it should be written in the ionic form (H⁺, Br⁻).

what type of properties change ina physical change? Give an example to support your answer?



pls quick who will give the answer first will get the brainliest​

Answers

Explanation:

We can observe some physical properties, such as density and color, without changing the physical state of the matter observed. Other physical properties, such as the melting temperature of iron or the freezing temperature of water, can only be observed as matter undergoes. A physical change physical change involves a change in physical properties. Examples of physical properties include melting, transition to a gas, change of strength, change of durability, changes to crystal form, textural change, shape, size, color, volume and density.

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What is the formula of the compound Pentasilicon trioxide ?

Answers

Answer: the molecular formula of  trioxide is ClOClO3 or Cl2O4

hope its helps you.

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I need help with the practice question at the bottom. Thank you.

Answers

Explanation:

For this question, we apply the equation: Q = mCp AT Where m is the mass of the substance, Cp

is its specific heat capacity and AT is the

temperature change. Q = 896 x 0.45 x (5-94)

Q = -35884.8 Joules

So about -36 kilojoules of heat is released.

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How many liters of hydrogen can be produced at a pressure of 2 atm and a temperature of 298 K

Answers

Answer:

1.17 L of H₂

Explanation:

We'll begin by calculating the number of mole in 2.3 g of Mg. This can be obtained as follow:

Mass of Mg = 2.3 g

Molar mass of Mg = 24 g/mol

Mole of Mg =?

Mole = mass /molar mass

Mole of Mg = 2.3 / 24

Mole of Mg = 0.096 mole

Next, we shall determine the number of mole of H₂ produced by the reaction of 2.3 g (i.e 0.096 mole) of Mg. This can be obtained as follow:

Mg + 2HCl —> MgCl₂ + H₂

From the balanced equation above,

1 mole of Mg reacted to 1 mole of H₂.

Therefore, 0.096 mole of Mg will also react to produce 0.096 mole of H₂.

Finally, we shall determine volume of H₂ produced from the reaction. This can be obtained as follow:

Number of mole (n) of H₂ = 0.096 mole

Pressure (P) = 2 atm

Temperature (T) = 298 K

Gas constant (R) = 0.0821 atm.L/Kmol

Volume (V) of H₂ =?

PV = nRT

2 × V = 0.096 × 0.0821 × 298

Divide both side by 2

V = (0.096 × 0.0821 × 298) /2

V = 1.17 L

Therefore, 1.17 L of H₂ were obtained from the reaction.

If a hydrogen atom and a helium atom have the same kinetic energy:________
a. the wavelength of the hydrogen atom will be about 4 times longer than the wavelength of the helium atom.
b. the wavelength of the hydrogen atom will be about 2 times longer than the wavelength of the helium.
c. the wavelength of the hydrogen atom will be roughly equal to the wavelength of the helium atom.
d. the wavelength of the helium atom will be about 2 times longer than the wavelength of the hydrogen atom.
e. the wavelength of the helium atom will be about 4 times longer than the wavelength of the hydrogen atom.

Answers

Answer: If a hydrogen atom and a helium atom have the same kinetic energy then the wavelength of the hydrogen atom will be roughly equal to the wavelength of the helium atom.

Explanation:

The relation between energy and wavelength is as follows.

[tex]E = \frac{hc}{\lambda}\\[/tex]

This means that energy is inversely proportional to wavelength.

As it is given that energy of a hydrogen atom and a helium atom is same.

Let us assume that [tex]E_{hydrogen} = E_{helium} = E'[/tex]. Hence, relation between their wavelengths will be calculated as follows.

[tex]E_{hydrogen} = \frac{hc}{\lambda_{hydrogen}}[/tex]    ... (1)

[tex]E_{helium} = \frac{hc}{\lambda_{helium}}[/tex]         ... (2)

Equating the equations (1) and (2) as follows.

[tex]E_{hydrogen} = E_{helium} = E'\\\frac{hc}{\lambda_{hydrogen}} = \frac{hc}{\lambda_{helium}} = E'\\\lambda_{helium} = \lambda_{hydrogen} = E'[/tex]

Thus, we can conclude that if a hydrogen atom and a helium atom have the same kinetic energy then the wavelength of the hydrogen atom will be roughly equal to the wavelength of the helium atom.

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