2.Which of the alcohols listed below would you expect to react most rapidly with PBr3?A)CH3CH2CH2CH2CH2CH2OHB)(CH3CH2)2CH(OH)CH2CH3C)(CH3CH2)2CHOHCH3D)(CH3CH2)3COHE)(CH3CH2)2C(CH3)OH

Answers

Answer 1

Answer:

A) CH3CH2CH2CH2CH2CH2OH

Explanation:

For this question, we have the following answer options:

A) CH3CH2CH2CH2CH2CH2OH

B) (CH3CH2)2CH(OH)CH2CH3

C) (CH3CH2)2CHOHCH3

D) (CH3CH2)3COH

E) (CH3CH2)2C(CH3)OH

We have to remember the reaction mechanism of the substitution reaction with [tex]PBr_3[/tex]. The idea is to generate a better leaving group in order to add a "Br" atom.

The [tex]PBr_3[/tex] attacks the "OH" generation new a bond to P (O-P bonds are very strong), due to this new bond we will have a better leaving group that can remove the oxygen an allow the attack of the Br atom to generating a new C-Br bond. This is made by an Sn2 reaction. Therefore we will have a faster reaction with primary substrates. In this case, the only primary substrate is molecule A. So, "CH3CH2CH2CH2CH2CH2OH" will react faster.

See figure 1

I hope it helps!

2.Which Of The Alcohols Listed Below Would You Expect To React Most Rapidly With PBr3?A)CH3CH2CH2CH2CH2CH2OHB)(CH3CH2)2CH(OH)CH2CH3C)(CH3CH2)2CHOHCH3D)(CH3CH2)3COHE)(CH3CH2)2C(CH3)OH

Related Questions

A sample of ammonia gas was allowed to come to equilibrium at 400 K. 2NH3(g) <----> N2(g) 3H2(g) At equilibrium, it was found that the concentration of H2 was 0.0484 M, the concentration of N2 was 0.0161 M, and the concentration of NH3 was 0.295 M. What was the initial concentration of ammonia

Answers

Answer:

0.327 M

Explanation:

Step 1: Write the balanced equation

2 NH₃(g) ⇄ N₂(g) + 3H₂(g)

Step 2: Make an ICE chart

        2 NH₃(g) ⇄ N₂(g) + 3 H₂(g)

I              x             0            0

C          -2y            +y         +3y

E         x-2y             y           3y

Step 3: Find the value of y

The concentration of N₂ at equilibrium is 0.0161 M. Then,

y = 0.0161

Step 4: Find the value of x

The concentration of NH₃ at equilibrium is 0.295 M. Then,

x-2y = 0.295

x-2(0.0161) = 0.295

x = 0.327

Which of the following goes through the largest volumetric change? Question 4 options: A) Water when it's heated from 1oC to 99oC B) Water when it freezes into ice C) Ice when it melts into water D) Water when it boils into steam

Answers

Answer:

Water when it freezes into ice

Explanation:

Most liquids expand when heated and contract when cooled, water behaves in an anomalous fashion. Water rather expands when cooled and contracts when heated.

Water usually contracts on cooling from any temperature until 4°C, after 4°C, the water begins to expand rapidly. Hence water has its least volume at 4°C and increases rapidly afterwards.

Thus the largest volume change for water occurs during freezing since it expands when cooled.

A variation of the acetamidomalonate synthesis can be used to synthesize threonine. The process involves the following steps: Ethoxide ion deprotonates diethyl acetamidomalonate, forming enolate anion 1; Enolate anion 1 makes a nucleophilic attack on acetaldehyde, forming tetrahedral intermediate 2; Protonation of the oxyanion forms alcohol 3; Acid hydrolysis yields dicarboxyamino alcohol 4; Decarboxylation leads to the final amino acid. Write out the mechanism on a separate sheet of paper, and then draw the structure of tetrahedral intermediate 2.

Answers

Answer:

See figure 1

Explanation:

For this reaction, we have the production of a carbanion as the first step. The base "ethoxide" can remove a hydrogen-producing a negative charge in the carbon (enolate anion 1). Then this negative charge can attack the carbon of the carbonyl group in the molecule acetaldehyde and the tetrahedral intermediate 2 is form. In the next step, we have the protonation of the oxygen to produce alcohol 3. A continuation we have the hydrolysis of the ester groups to produce the Dicarboxyamino alcohol and finally, we have a decarboxylation reaction we will produce the amino acid Threonine.

To further explanations see figure 1

I hope it helps!

Which of the following happens to a molecule of an object when the object is heated? (1 point)

Answers

Answer:

They get more energy, so they vibrate!

Explanation:

How are Math, Physics, Chemistry, and Biology all related?

Answers

Answer:

- you have to do maths in all 3

- atoms make up everything even parts of a cel and theyre studied in chem and physics

- chemistry is used in biology by finding out what different substances are eg cytoplasm in a cell

The direction of the functional group is called?

Answers

Explanation:

they are called hydrocarbyls

pls mark me brainliest

Answer:

The first carbon atom that attaches to the functional group is referred to as the alpha carbon.

Calculate the amount of heat needed to melt of ice () and bring it to a temperature of . Round your answer to significant digits. Also, be sure your answer contains a unit symbol.

Answers

Answer:

your answer is given below

Explanation:

Take it stepwise, and you are going to have to look up the various heat values.

You have 36.5grams of ice, presumably at 0C.  You will need to add heat to take the ice at 0 C to water at 0 C. (Latent heat of melting)  Then you add in a different heat value to take the water at 0 C to water at 82.3 C. (Specific heat of water)

Add the two heat amounts together.

According to specific heat capacity, to calculate the amount of heat needed to melt ice given mass of ices is multiplied by specific heat of ice and the temperature change which it undergoes.

What is specific heat capacity?

Specific heat capacity is defined as the amount of energy required to raise the temperature of one gram of substance by one degree Celsius. It has units of calories or joules per gram per degree Celsius.

It varies with temperature and is different for each state of matter. Water in the liquid form has the highest specific heat capacity among all common substances .Specific heat capacity of a substance is infinite as it undergoes phase transition ,it is highest for gases and can rise if the gas is allowed to expand.

It is given by the formula ,

Q=mcΔT

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11mg of cyanide per kilogram of body weight is lethal for 50% of domestic chickens. How many grams per kilogram of body weight is a lethal dose for 50% of domestic chickens?

Answers

Answer:

[tex]0.033g[/tex]

Explanation:

Hello,

In this case, since 11 mg per kilogram of body weight has the given lethality, the mg that turn out lethal for a chicken weighting 3 kg is computed by using a rule of three:

[tex]11mg\longrightarrow 1kg\\\\x\ \ \ \ \ \ \longrightarrow 3kg[/tex]

Thus, we obtain:

[tex]x=\frac{3kg*11mg}{1kg}\\ \\x=33mg[/tex]

That in grams is:

[tex]=33mg*\frac{1g}{1000mg} \\\\=0.033g[/tex]

Regards.

Nitric oxide (NO) can be formed from nitrogen, hydrogen and oxygen in two steps. In the first step, nitrogen and hydrogen react to form ammonia: (g) (g) (g) In the second step, ammonia and oxygen react to form nitric oxide and water: (g) (g) (g) (g) Calculate the net change in enthalpy for the formation of one mole of nitric oxide from nitrogen, hydrogen and oxygen from these reactions. Round your answer to the nearest .

Answers

Answer: [tex]\Delta H = -272.25kJ[/tex] for 1 mole of NO.

Explanation: Hess' Law of Constant Summation or Hess' Law states that the total enthalpy change of a reaction with multiple stages is the sum of the enthalpies of all the changes.

For this question:

1) [tex]N_{2}_{(g)} + 3H_{2}_{(g)}[/tex] => [tex]2NH_{3}_{(g)}[/tex]       [tex]\Delta H=-92kJ[/tex]

2) [tex]4NH_{3}_{(g)}+5O_{2}_{(g)}[/tex] => [tex]4NO_{(g)}+6H_{2}O_{(g)}[/tex]       [tex]\Delta H=-905kJ[/tex]

Amonia ([tex]NH_{3}_{(g)}[/tex]) appeares as product in the first equation and as reagent in the 2 reaction, so when adding both, there is no need to inverse reactions. However, in the 2nd, there are 4 moles of that molecule, so to cancel it, you have to multiply by 2 the first chemical equation and enthalpy:

[tex]2N_{2}_{(g)} + 6H_{2}_{(g)}[/tex] => [tex]4NH_{3}_{(g)}[/tex]     [tex]\Delta H=-184kJ[/tex]

Now, adding them:

[tex]2N_{2}_{(g)} + 6H_{2}_{(g)}[/tex] => [tex]4NH_{3}_{(g)}[/tex]     [tex]\Delta H=-184kJ[/tex]  

[tex]4NH_{3}_{(g)}+5O_{2}_{(g)}[/tex] => [tex]4NO_{(g)}+6H_{2}O_{(g)}[/tex]       [tex]\Delta H=-905kJ[/tex]

[tex]2N_{2}_{(g)}+6H_{2}_{(g)}+5O_{2}_{(g)}=>4NO_{(g)}+6H_{2}O_{(g)}[/tex]  [tex]\Delta H = -185-905[/tex]

[tex]2N_{2}_{(g)}+6H_{2}_{(g)}+5O_{2}_{(g)}=>4NO_{(g)}+6H_{2}O_{(g)}[/tex]  [tex]\Delta H = -1089kJ[/tex]

Note net enthalpy is for the formation of 4 moles of nitric oxide.

For 1 mole:

[tex]\Delta H = \frac{-1089}{4}[/tex]

[tex]\Delta H=-272.25kJ[/tex]

To form 1 mol of nitric oxide from nitrogen, oxygen and hydrogen, net change in enthalpy is [tex]\Delta H=-272.25kJ[/tex].

105/22 • (1.251 - 0.620)=

Answers

Answer:

105/22*(1.251-0.620)

105/22*0.631

4.772*0.631

3.011132

Hope it helps

Answer:

3.0

Explanation:

First, complete the operations inside the parenthesis according to the normal rules for significant figures. Because there are subsequent calculations, keep at least one extra significant figure when possible: (4.7727) × (0.631).

The final product will be rounded to two significant figures because it can’t be more precise than the least precise number in the problem, 22. The final product is 3.0.

PLEASE HELP WILL GIVE BRAINLIEST!!!
Refining aluminum takes place in steel vats lined with graphite. What function does the graphite lining serve?
A. It is the cathode.
B. It is the anode.
C. It soaks up the waste oxygen released from bauxite (Al2O3)
D. It serves as a grounding layer to prevent electrical surges.

Answers

Answer: It's the anode broski (B)

Explanation: I'm taking the Chem summer course too broski, this was the correct answer. Cheers broski

From the graph of Density vs. Concentration, created in Graph 1, what was the relationship between the concentration of the sugar solution and the density of the sugar solution?

Answers

The graph is not given in the question, so, the required graph is attached below:

Answer:

According to the graph, the relationship between the density of the sugar solution and the concentration of the sugar solution is directly proportional to each other as they both are increasing exponentially.

The graph shows that, the density of sugar solution will increase with the increase in concentration of sugar in the solution.

I add a 50. g piece of Al (c = 0.88 J/g-deg) that is at 225°C to 100. mL of water at 20°C. What is the final temperature of the water in °C? The density of water is approximately 1g/mL.

Answers

Answer:

THE FINAL TEMPERATURE OF WATER IS -4.117 °C

Explanation:

Mass of the aluminium = 50 g

c = 0.88 J/g C

Initial temperature of aluminium = 225 °C

Volume of water = 100 ml

Density of water = 1 g/ml

Mass of water = density * volume of water

Mass of water = 1 * 100 = 100 g of water

Initial temperature of water = 20 C

It is worthy to note that the heat of a system is constant and conserved as no heat is lost or gained by a closed system,

So therefore,

heat lost by aluminium = heat gained by water

H = mass * specific heat capacity * temeprature change

So:

m c ( T2- T1) = m c (T2-T1)

50 * 0.88 * ( T2 - 225) = 100 * 4.18 *( T2 - 20)

44 ( T2 - 225 ) = 418 ( T2 - 20)

44 T2 - 9900 = 418 T2 - 8360

-9900 + 8360 = 418 T2 - 44 T2

-1540 = 374 T2

T2 = - 4.117

So therefore the final temperature of water is -4.117 °C

g All of the molecules below have polar bonds but only one of the molecules is a polar molecule. Which one is a polar molecule? A) C2F2 B) C2Cl4 C) CO2 D) NF3 E) CF4

Answers

Answer: [tex]NF_3[/tex]

Explanation:

Geometrical symmetry of the molecule and the polarity of the bonds determine the polarity of the molecule.

The molecule that has zero dipole moment that means it is a geometrically symmetric molecule and the molecule which has some net dipole moment means it is a geometrically asymmetric molecule.

As the molecule is symmetric, the dipole moment will be zero as dipole moments cancel each other and the molecule will be non-polar.

As the molecule is asymmetric, the dipole moment will not be zero and the molecule will be polar.

Example: [tex]NF_3[/tex]

Thus, we can say that [tex]NF_3[/tex] is a polar molecule.

i) Briefly discuss the strengths and weaknesses of the four spectroscopy techniques listed below. Include in your answer the specific structural information you get from each method.
 IR
 UV-VIS
 NMR
 Mass Spec

Answers

delete please .....................................

A 135 g sample of H20 at 85°C is cooled. The water loses a total of 15 kJ of energy in the cooling

process. What is the final temperature of the water? The specific heat of water is 4.184 J/g.°C.

A. 112°C

B. 58°C

C. 70°C

D. 84°C

E. 27°C

Answers

Answer:

B. 58°C

Explanation:

Hello,

In this case, the relationship among heat, mass, specific heat and temperature for water is mathematically by:

[tex]Q=mCp\Delta T=mCp(T_2-T_1)[/tex]

In such a way, solving for the final temperature [tex]T_2[/tex] we obtain:

[tex]T_2=T_1+\frac{Q}{mCp}[/tex]

Therefore, we final temperature is computed as follows, considering that the involved heat is negative as it is lost for water:

[tex]T_2=85\°C+\frac{-15kJ*\frac{1000J}{1kJ} }{135g*4.184\frac{J}{g\°C} }\\\\T_2=58\°C[/tex]

Thereby, answer is B. 58°C .

Regards.

The complex ion Fe(CN)63- is paramagnetic with one unpaired electron. The complex ion Fe(SCN)63- has five unpaired electrons. Where does SCN- lie in the spectrochemical series with respect to CN-?

Answers

Answer:

SCN- is a weak field ligand while CN- is a strong field ligand

Explanation:

The spectrochemical series is an arrangement of ligands according to their magnitude of crystal field splitting. Ligands that cause only a small degree of crystal field splitting are called weak field ligands while ligands that cause large crystal field splitting are called strong field ligands.

Strong field ligands often lead to the formation of low spin complexes with the least number of unpaired electrons while high spin complexes are formed by weak field ligands.

CN- is a strong field ligand as it lies towards the right hand side of the spectrochemical series.

SCN- is a weak field ligand hence it forms a high spin complex having the maximum number of unpaired electrons for Fe^3+, hence the answer.

SCN⁻ lies in the lower (weak field) region of the spectrochemical series while CN⁻ lies in the higher (stronger field) region.

CN⁻ is a strong field ligand with a large splitting constant, and it is high up in the spectrochemical series.

Conversely, SCN⁻ is a weak field ligand with a low splitting constant, and it is lower in the spectrochemical series.

Hence, SCN⁻ lies in the lower (weak field) region of the spectrochemical series while CN⁻ lies in the higher (stronger field) region.

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The entropy of a substance above absolute zero will always be:

a. Negative
b. Positive
c. Neither Negative nor positive

Answers

i will be positive. just because it’s positive

What is advertising used for? Check all that apply. influencing consumer tastes tracking product popularity increasing product awareness promoting company branding gathering data about potential consumers

Answers

Answer:

influencing consumer tastes

increasing product awareness

promoting company branding

Explanation:

Advertising is basically a form of communication using creative ideas and communicating benefits of the products. Advertising plays a very crucial role in product business and some of the important uses of advertising are as follows:

Creative advertisements, influence customers or consumers to buy the product.Advertisings involve information regarding the product and so increases product awareness.Advertising on social media platforms, TVs, radio and newspapers, promotes company branding.

Hence, the correct options are:

influencing consumer tastesincreasing product awarenesspromoting company branding

Answer:

1,3,4

Explanation:

I took the test

What is the pOH of a solution at 25.0∘C with [H3O+]=4.8×10−6 M?

Answers

Answer:

8.68

Explanation:

pOH = 8.68

all you need is contained in the sheet

Answer:

Approximately [tex]8.68[/tex].

Explanation:

The [tex]\rm pOH[/tex] of a solution can be found from the hydroxide ion concentration [tex]\rm \left[OH^{-}\right][/tex] with the following equation:

[tex]\displaystyle \rm pOH = -\log_{10} \rm \left[OH^{-}\right][/tex].

On the other hand, the ion-product constant of water, [tex]K_{\text{w}}[/tex], relates the hydroxide ion concentration [tex]\rm \left[OH^{-}\right][/tex] of a solution to its hydronium ion concentration [tex]\rm \left[{H_3O}^{+}\right][/tex]:

[tex]K_\text{w} = \rm \left[{H_3O}^{+}\right] \cdot \rm \left[OH^{-}\right][/tex].

At [tex]25 \; ^\circ \rm C[/tex], [tex]K_{\text{w}} \approx 1.0 \times 10^{-14}[/tex]. For this particular [tex]25 \; ^\circ \rm C[/tex] solution, [tex]\rm \left[{H_3O}^{+}\right] = 4.8 \times 10^{-6}\; \rm mol \cdot L^{-1}[/tex].

Hence the [tex]\rm \left[OH^{-}\right][/tex] of this solution:

[tex]\begin{aligned}\left[\mathrm{OH}^{-}\right] &= \frac{K_\text{w}}{\rm \left[{H_3O}^{+}\right]} \\ &= \frac{1.0 \times 10^{-14}}{4.8 \times 10^{-6}}\; \rm mol\cdot L^{-1} \approx 2.08333 \times 10^{-9}\; \rm mol\cdot L^{-1}\end{aligned}[/tex].

Therefore, the [tex]\rm pOH[/tex] of this solution would be:

[tex]\begin{aligned}\rm pOH &= -\log_{10} \rm \left[OH^{-}\right] \\ &\approx -\log_{10} \left(4.8 \times 10^{-6}\right) \approx 8.68\end{aligned}[/tex].

Note that by convention, the number of decimal places in [tex]\rm pOH[/tex] should be the same as the number of significant figures in [tex]\rm \left[OH^{-}\right][/tex].

For example, because the [tex]\rm \left[{H_3O}^{+}\right][/tex] from the question has two significant figures, the [tex]\rm \left[OH^{-}\right][/tex] here also has two significant figures. As a result, the [tex]\rm pOH[/tex] in the result should have two decimal places.

During a titration, a known concentration of _____ is added to a _____ of an unknown concentration g

Answers

Explanation:

The whole process of titration involves finding the concentration of a solution (usually an acid or base) by adding (titrating) it to a solution(acid or base) with a known concentration.

The solution of unknown concentration (the analyte) is usually placed in an flask, while the solution of known concentration (titrant) is placed in a burette and slowly added to the flask.

what is ammonium nitrate

Answers

Answer:

Ammonium nitrate is a chemical compound with the chemical formula NH₄NO₃. It is a white crystalline solid consisting of ions of ammonium and nitrate.

We discussed the different types of intermolecular forces in this lesson, which can affect the boiling point of a substance.
1. Which of these has the highest boiling point?
A) Ar
B) Kr
C) Xe
D) Ne
2. Which substance has the highest boiling point?
A) CH4
B) He
C) HF
D) Cl2

Answers

Answer:

1, C, Xe 2, B,He

Explanation:

1, cause as u go down a group the boiling point increases.

2, boiling point of single element is greater than a compound

According to  periodic trends in periodic table boiling point increases down the  group and hence Xe has highest boiling point and more amount of heat is required to boil an element hence He has highest boiling point.

What is periodic table?

Periodic table is a tabular arrangement of elements in the form of a table. In the periodic table, elements are arranged according to the modern periodic law which states that the properties of elements are a periodic function of their atomic numbers.

It is called as periodic because properties repeat after regular intervals of atomic numbers . It is a tabular arrangement consisting of seven horizontal rows called periods and eighteen vertical columns called groups.

Elements present in the same group have same number of valence electrons and hence have similar properties while elements present in the same period show gradual variation in properties due to addition of one electron for each successive element in a period.

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If the heat of combustion for a specific compound is −1320.0 kJ/mol and its molar mass is 30.55 g/mol, how many grams of this compound must you burn to release 617.30 kJ of heat?

Answers

Answer:

14.297 g

Explanation:

From the question;

1 mo of the compound requires 1320.0 kJ

From the molar mass;

1 ml of the compound weighs 30.55g

How many grams requires 617.30kJ?

1 ml = 1320

x mol = 617.30

x = 617.30 / 1320

x = 0.468 mol

But 1 mol = 30.55

0.468 mol = x

x = 14.297 g

A 100.0 mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3. Determine the pH of the solution before the addition of any HNO3. The Kb of NH3 is 1.8 × 10-5.

Answers

Answer:

[tex]pH=11.12[/tex]

Explanation:

Hello,

In this case, ammonia dissociation is:

[tex]NH_3(aq)+H_2O(l)\rightleftharpoons NH_4^+(aq)+OH^-(aq)[/tex]

So the equilibrium expression:

[tex]Kb=\frac{[NH_4^+][OH^-]}{[NH_3]}[/tex]

That in terms of the reaction extent and the initial concentration of ammonia is written as:

[tex]1.8x10^{-5}=\frac{x*x}{0.10M-x}[/tex]

Thus, solving by using solver or quadratic equation we find:

[tex]x=0.00133M[/tex]

Which actually equals the concentration of hydroxyl ion, therefore the pOH is computed:

[tex]pOH=-log([OH^-])=-log(0.00133)=2.88[/tex]

And the pH from the pOH is:

[tex]pH=14-pOH=14-2.88\\\\pH=11.12[/tex]

Best regards.

A strand of messenger RNA coding the synthesis of a protein with 146 amino acids must have a string of___________ bases along its backbone. a. 146 b. 292 c. 438 d. 20 e. 3

Answers

Answer:

Since the relationship between amino acid and codon bases would be the values of 3 nitrogenous bases per 1 amino acid.

knowing this relationship what you would do is simply multiply 146 x 3 to find the number of codon bases which would be C. 438.

A strand of messenger RNA coding the synthesis of a protein with 146 amino acids must have a string of 438 bases along its backbone and the correct option is option C.

What is messenger RNA?

mRNA or messenger RNA is a single stranded RNA molecule. It is complementary to the DNA and carries genetic information present in the DNA. It is translated to form proteins. The genetic codes (triplet) present on mRNA get translated to amino acids, giving rise to the functional product of a gene.

So mRNA really is a form of nucleic acid, which helps the human genome which is coded in DNA to be read by the cellular machinery. mRNA is actually the translated form of DNA that the machinery can recognize and use to assemble amino acids into proteins.

Each strand has 3 bases, so 146 × 3 = 438 bases

Therefore, A strand of messenger RNA coding the synthesis of a protein with 146 amino acids must have a string of 438 bases along its backbone and the correct option is option C.

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If you had a cup full of methanol and a pool full of methanol, would the mass change?

Answers

Answer:

the mass does not change

Explanation:

The solubility of lead(II) iodide is 0.064 g/100 mL at 20ºC. What is the solubility product for lead(II) iodide?

Answers

Answer:

[tex]Ksp=1.07x10^{-8}[/tex]

Explanation:

Hello,

In this case, the dissociation reaction is:

[tex]PbI_2(s)\rightleftharpoons Pb^{2+}(aq)+2I^-(aq)[/tex]

For which the equilibrium expression is:

[tex]Ksp=[Pb^{2+}][I^-]^2[/tex]

Thus, since the saturated solution is 0.064g/100 mL at 20 °C we need to compute the molar solubility by using its molar mass (461.2 g/mol)

[tex]Molar solubility=\frac{0.064g}{100mL}*\frac{1000mL}{1L}*\frac{1mol}{461.2g}=1.39x10^{-3}M[/tex]

In such a way, since the mole ratio between lead (II) iodide to lead (II) and iodide ions is 1:1 and 1:2 respectively, the concentration of each ion turns out:

[tex][Pb^{2+}]=1.39x10^{-3}M[/tex]

[tex][I^-]=1.39x10^{-3}M*2=2.78x10^{-3}M[/tex]

Thereby, the solubility product results:

[tex]Ksp=(1.39x10^{-3}M)(2.78x10^{-3}M)^2\\\\Ksp=1.07x10^{-8}[/tex]

Regards.

Solubility product constant for the product of lead(II) iodide is [tex]\bold { 1.07x 10^-^8}[/tex].

The dissociation reaction for lead (II) iodide

[tex]\bold {Pb I^2 (s) \leftrightharpoons Pb^2^+ + 2I^- }[/tex]

Solubility product constant at equilibrium.

[tex]\bold {Ksp = [Pb^2^++[I^-]^2}[/tex]

The molar solubility of the substance can be calculated by using the molar mass,

[tex]\bold {s = \dfrac {0.064}{100 mL} \times 461.2 g/mol = 1.39x10^-^3}[/tex]

Molar ratio between between PbI to lead and iodide ions is 1:1 and 1:2 respectively.

Thus Ksp will be,

[tex]\bold {Ksp =(1.39x10^-^3)(2.78x10^-^3 )^2}\\\\\bold {Ksp = 1.07x 10^-^8}[/tex]

Therefore, solubility product constant for the product of lead(II) iodide is [tex]\bold { 1.07x 10^-^8}[/tex].

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In the laboratory, a general chemistry student measured the pH of a 0.425 M aqueous solution of benzoic acid, C6H5COOH to be 2.270.

Use the information she obtained to determine the Ka for this acid.

Ka(experiment) = _____

Answers

Answer:

Ka = 6.87x10⁻⁵

Explanation:

The equilibrium of benzoic acid in water is:

C₆H₅COOH(aq) + H₂O(l) ⇄ C₆H₅COO⁻(aq) + H₃O⁺(aq)

The equilibrium constant, Ka, is:

Ka = [C₆H₅COO⁻] [H₃O⁺] / [C₆H₅COOH]

The initial concentration of benzoic acid is 0.425M. In equilibrium its concentration is 0.425M - X and [C₆H₅COO⁻] [H₃O⁺] = X.

X is the reaction coordinate. How many acid produce C₆H₅COO⁻ and H₃O⁺ until reach equilibrium.

Concentrations in equilibrium are:

[C₆H₅COOH] = 0.425M - X[C₆H₅COO⁻] = X [H₃O⁺] = X

pH is defined as -log [H₃O⁺]. As pH = 2.270

2.270 = -log [H₃O⁺]

10^-2.270 = [H₃O⁺]

5.37x10⁻³M = [H₃O⁺] = X.

Replacing, concentrations in equilibrium are:

[C₆H₅COOH] = 0.425M - 5.37x10⁻³M = 0.4196M

[C₆H₅COO⁻] = 5.37x10⁻³M

[H₃O⁺] = 5.37x10⁻³M

Ka = [5.37x10⁻³M] [5.37x10⁻³M] / [0.4196M]

Ka = 6.87x10⁻⁵

Calculate the equilibrium constant K c for the following overall reaction: AgCl(s) + 2CN –(aq) Ag(CN) 2 –(aq) + Cl –(aq) For AgCl, K sp = 1.6 × 10 –10; for Ag(CN) 2 –, K f = 1.0 × 10 21.

Answers

Answer:

1.6x10¹¹ = Kc

Explanation:

For the reaction:

AgCl(s) + 2CN⁻(aq) ⇄ Ag(CN)₂⁻(aq) + Cl⁻(aq)

Kc is defined as:

Kc = [Ag(CN)₂⁻] [Cl⁻] / [CN⁻]²

Ksp of AgCl is:

AgCl(s) ⇄ Ag⁺(aq) + Cl⁻(aq)

Where Ksp is:

Ksp = [Ag⁺] [Cl⁻] = 1.6x10⁻¹⁰

In the same way, Kf of Ag(CN)₂⁻ is:

Ag⁺(aq) + 2CN⁻ ⇄ Ag(CN)₂⁻

Kf = [Ag(CN)₂⁻] / [CN⁻]² [Ag⁺] = 1.0x10²¹

The multiplication of Kf with Ksp gives:

[Ag⁺] [Cl⁻] *  [Ag(CN)₂⁻] / [CN⁻]² [Ag⁺] = Ksp*Kf

[Ag(CN)₂⁻] [Cl⁻] / [CN⁻]² = Ksp*Kf

Obtaining the same expression of the first reaction

That means Ksp*Kf = Kc

1.6x10⁻¹⁰*1.0x10²¹ = Kc

1.6x10¹¹ = Kc
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