A binary system of species 1 and 2 consists of vapor and liquid phases in equilibrium
at temperature T. The overall mole fraction of species 1 in the system is z1 = 0.65. At
temperature T, lnγ1 = 0.67 x2
2; lnγ2 = 0.67 x1
2; P1
sat = 32.27 kPa; and P2
sat = 73.14 kPa.
Assuming the validity of Eq. (13.19),
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13.10. Problems 511
smi96529_ch13_450-523.indd 511 01/06/17 03:27 PM
(a) Over what range of pressures can this system exist as two phases at the given T and z1?
(b) For a liquid-phase mole fraction x1 = 0.75, what is the pressure P and what molar
fraction of the system is vapor?
(c) Show whether or not the system exhibits an azeotrope

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