Melanie has completed the analysis of her data for the reaction of KMnO4 with malonic acid and data for a reaction of KMnO4 with tartaric acid. She compared the activation energies, Ea, she calculated for the two reactions and found the Ea for the malonic acid reaction to be greater than the Ea for the tartaric acid reaction.
Required:
What does this mean about the magnitude of the rate constant, k, and the rate of the reaction?
Answer:
See explanation
Explanation:
The relationship between the activation energy and rate of reaction is best captured by the Arrhenius equation;
k= Ae^-Ea/RT
Where;
k= rate constant
A= pre-exponential factor
Ea=activation energy
R= gas constant
T= temperature
We can see from the foregoing that, as the activation energy increases, the rate of reaction decreases and vice versa. reactions that have a very high activation energy are markedly slow.
Since the activation energy for the malonic acid reaction is found to be greater than the activation energy for the tartaric acid reaction, then the rate of the malonic acid reaction(k) will be slower than that of the tartaric acid reaction.
The study of chemistry and bonds is called chemistry. There are two types of elements metal and nonmetals.
The correct answer is mentioned below.
What is the Arrhenius equation?The relationship between the activation energy and rate of reaction is best captured by the Arrhenius equationThe equation is as follows:-
[tex]k= Ae^{-Ea/RT[/tex] Where;
k= rate constantA= pre-exponential factorEa=activation energyR= gas constantT= temperatureWe can see from the foregoing that, as the activation energy increases, the rate of reaction decreases and vice versa. reactions that have very high activation energy are markedly slow. Since the activation energy for the malonic acid reaction is found to be greater than the activation energy for the tartaric acid reaction, then the rate of the malonic acid reaction(k) will be slower than that of the tartaric acid reaction.
Hence, the correct answer is mentioned above.
For more information about the equation, refer to the link:-
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Tick (√) the statements that are correct.
a) By eating rice alone, we can fulfil nutritional requirement of our body. ( )
b) Deficiency Diseases can be prevented by eating a balanced diet. ( )
c) Balanced diet for the body should contain a variety of food items. ( )
d) Meat alone. is sufficient to provide all nutrients to the body. ( )
b) (√)
c)(✓)
hsjdhfjdkskkshd
Ethylene glycol (C2H6O2) is mixed with water to make auto engine coolants. How many grams of C2H6O2 are in 5.00 L of a 6.00 M aqueous solution
Answer:
1860g.
Explanation:
It is known that the molar mass of C2H6O2 is 62.08 g/mol.,
Now to solve for the number of moles of solute, one must multiply both
sides by the volume:
moles of solute = (6.00 M)(5.00 L) = 30.0 mol
Notice since the definition of molarity is mol/L, the
product M × L gives mol, a unit of amount.
Use the molar mass of C3H8O3, one can convert mol to g:
Mass m =30 mol × 62.08 g/mol
m = 1860g.
Hence, there are 1,860 g of C2H6O2 in the specified amount of
engine coolant.
0.28 M Ca(NO3)2
Express your answer using two significant figures.
Answer:
Mass=Moles × RFM
Mass= 0.28M× 164
Mass= 45.92 grammes
Carbonic anhydrase is strongly inhibited by the drug acetazolamide, which is used as a diuretic (i.e., to increase the production of urine) and to lower excessively high pressure in the eye (due to accumulation of intraocular fluid) in glaucoma.
a. True
b. False
Answer:
a. True
Explanation:
There is strong inhibition of Carbon Anhydrase by Aceta-zolamide Carbonic Anhydrase. The drug acetazolamide is used as diuretic which increase the urine production in human body. It lowers pressure in eye in glaucoma.
What is the molecular geometry of CIO3F as predicted by the VSEPR model?
Multiple Choice
trigonal pyramidal
square planar
square pyramidal
tetrahedral
octahedral
Explanation:
since there are no lone pairs on the central atom, the shape will be tetrahedral
Plastic is a polymer
-True
-False
TRUE
Explanation:
*not sure about this answer
What is the direct function of the energy released from the nuclear chain reaction in a nuclear power plant? turning the blades of the turbine heating water to produce steam powering the condenser carrying electricity from the plant to consumers
Answer:
the energy released is to make steam to create electricity. yes you are right i just didnt feel like being super technical
In a nuclear reaction, the direct function of the energy released from the nuclear chain reaction in a nuclear power plant is turning the blades of the turbine heating water to produce steam .
What are nuclear reactions?There are two types of nuclear reactions which are nuclear fusion and nuclear fission .They involve the combination and disintegration of the element's nucleus respectively.
In nuclear fission, the nucleus of the atom is bombarded with electrons of low energy which splits the nucleus in to two parts .Large amount of energy is released in the process.It is used in nuclear power reactors as it produces large amount of energy.
In nuclear fusion,on the other hand, is a reaction which occurs when two or more atoms combine to form a heavy nucleus.Large amount of energy is released in the process which is greater than that of the energy which is released in nuclear fission process.
Learn more about nuclear reactions,here:
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Help naming this plzzzzzzzzzzzzz
Answer:
A. 3-chloro-1-methylcyclobutane.
Explanation:
Hello there!
In this case, according to the given information, it turns out possible for us to infer that the name of this compound is A. 3-chloro-1-methylcyclobutane because of the fact that the parent chain is a cyclobutane which starts by the methyl radical as it has the priority over the chlorine radical which is actually named first at the third carbon (clockwise).
Therefore the name is given in A, accordingly to the IUPAC rules of nomenclature.
Regards!
repining of fruits is which type of change
Answer:
irreversible.
I hope this will help you
Choose the correct answer to make the statement true.
a. An exothermic reaction has a positive ΔH and absorbs heat from the surroundings.
b. An exothermic reaction feels warm to the touch. a positive ΔH and gives off heat to the surroundings.
c. An exothermic reaction feels warm to the touch. a negative ΔH and absorbs heat from the surroundings.
d. An exothermic reaction feels warm to the touch. a negative ΔH and gives off heat to the surroundings.
e. An exothermic reaction feels warm to the touch.
A student attempts to separate 4.656 g of a sand/salt mixture just like you did in this lab. After carrying out the experiment, she recovers 2.775 g of sand and 0.852 g of salt.a. What was the percent composition of sand in the mixture according to the student's data? b. What was the percent recovery?
Answer:
Explanation:
a ) Total mixture = 4.656 g
Sand recovered = 2.775 g
percent composition of sand in the mixture
= (2.775 g / 4.656 g ) x 100
= 59.6 % .
b )
Total of sand and salt recovered = 2.775 g + .852 g = 3.627 g .
Total mixture = 4.656 g
percent recovery = (3.627 / 4.656 ) x 100
= 77.9 % .
How many colors are there in a rainbow?
[tex]\boxed{\large{\bold{\blue{ANSWER~:) }}}}[/tex]
There are 7 colours in a rainbow The colours of the rainbow are Red, Orange, Yellow, Green, Blue, Indigo and Violet.Explanation:
there r seven colors in a rainbow.red, orange, yellow, green, blue, indigo and violet.hope it helps.stay safe healthy and happy..sự sắp xếp nguyên tử trong vật chất
Answer:
sosksjsjjs
Explanation:
even i know how to type şïllily
what is the hybridisation of the central carbon in CH3C triple bonded to N
Explanation:
the carbon would be sp3 hybridized, and it doesn't matter which carbon, since either of them have a full octet
2. For each of the ionic compounds in the table below, name the compound and explain the rule that you
used in formulating your name for the compound.
Name:
Rule for naming compound:
-PbF4
-NH4NO3
-Li2S
Answer:
2
Explanation:
Lead(|V) fluoride
Ammonium Nitrate
Lithium sulfide
For the rules, I don't know what you were taught. I just do it intuitively since I have done so much chemistry.
The first one the roman numerals represents the charge of the lead which much match the 4- charge from the 4 fluorides.
The second one is just two polyatomic ions which you just have to remember.
The last one is the typical ionic compound naming technique i guess.
2. 27.8 mL of an unknown were added to a 50.0-mL flask that weighs 464.7 g. The total mass of the flask and the liquid is 552.4 g. Calculate the density of the liquid in Lbs/ in3.
Answer:
[tex]d=4.24x10^{-4}\frac{lb}{in^3}[/tex]
Explanation:
Hello there!
In this case, according to the given information, it turns out firstly necessary for us to set the equation for the calculation of density and mass divided by volume:
[tex]d=\frac{m}{V}[/tex]
Thus, we can find the mass of the unknown by subtracting the total mass of the liquid to the mass of the flask and the liquid:
[tex]m=552.4g-464.7g=87.7g[/tex]
So that we are now able to calculate the density in g/mL first:
[tex]d=\frac{87.7g}{27.8mL}=3.15g/mL[/tex]
Now, we proceed to the conversion to lb/in³ by using the following setup:
[tex]d=3.15\frac{g}{mL}*\frac{1lb}{453.6g}*\frac{1in^3}{16.3871mL}\\\\d=4.24x10^{-4}\frac{lb}{in^3}[/tex]
Regards!
why beta carbon hydrogen is easily replaceable but not alpha carbon hydrogen
Answer:
Four common types of reactions involving carbonyl reactions: 1) nucleophilic addition; 2) nucleophilic acyl substitution; 3) alpha substitution; 4) carbonyl condensations. The first two were previously discussed and the second two involve the properties of the carbon directly adjacent to the carbonyls, α carbons.
Alpha-substitution reactions results in the replacement of an H attached to the alpha carbon with an electrophile.
The nucleophile in these reactions are new and called enols and enolates.
Explanation:
The carbon in the carbonyl is the reference point and the alpha carbon is adjacent to the carbonyl carbon.
Hydrogen atoms attached the these carbons denoted with Greek letters will have the same designation, so an alpha hydrogen is attached to an alpha carbon.
Aldehyde hydrogens not given Greek leters.
α hydrogens display unusual acidity, due to the resonance stabilization of the carbanion conjugate base, called an enolate.
Tautomers are readily interconverted constitutional isomers, usually distinguished by a different location for an atom or a group, which is different than resonance.
The tautomerization in this chapter focuses on the carbonyl group with alpha hydrogen, which undergo keto-enol tautomerism.
Keto refers to the tautomer containing the carbonyl while enol implies a double bond and a hydroxyl group present in the tautomer.
The keto-enol tautomerization equilibrium is dependent on stabilization factors of both the keto tautomer and the enol tautomer, though the keto form is typically favored for simple carbonyl compounds.
The 1,3 arrangement of two carbonyl groups can work synergistically to stabilize the enol tautomer, increasing the amount present at equilibrium.
The positioning of the carbonyl groups in the 1,3 arrangement allows for the formation of a stabilizing intramolecular hydrogen bond between the hydroxyl group of the enol and the carbonyl oxygen as well as the alkene group of the enol tautomer is also conjugated with the carbonyl double bond which provides additional stabilization.
Aromaticity can also stabilize the enol tautomer over the keto tautomer.
Under neutral conditions, the tautomerization is slow, but both acid and base catalysts can be utilized to speed the reaction up.
Biological enol forming reactions use isomerase enzymes to catalyze the shifting of a carbonyl group in sugar molecules, often converting between a ketose and an aldose in a process called carbonyl isomerization.
Identify each of the following half-reactions as either an oxidation half-reaction or a reduction half-reaction.
half-reaction identification
Cu+(aq)--->Cu2+(aq) + e- _________
I2(s) + 2e--->2I-(aq) _________
Answer:
Cu+(aq)--->Cu2+(aq) + e- : oxidation
reason: there is loss of electrons.
I2(s) + 2e--->2I-(aq) : reduction
reason: There is reduction of electrons.
g A high altitude balloon is filled with 1.41 x 104 L of hydrogen gas (H2) at a temperature of 21oC and a pressure of 745 torr. What is the volume of the balloon at a height of 20 km, where the temperature is -48oC and the pressure is 63.1 torr
Answer:
1.27 × 10⁵ L
Explanation:
Step 1: Given data
Initial pressure (P₁): 745 TorrInitial volume (V₁): 1.41 × 10⁴ LInital temperature (T₁): 21 °CFinal pressure (P₂): 63.1 TorrFinal volume (V₂): ?Final temperature (T₂): -48 °CStep 2: Convert the temperatures to the Kelvin scale
We will use the following expression.
K = °C + 273.15
K = 21 °C + 273.15 = 294 K
K = -48 °C + 273.15 = 225 K
Step 3: Calculate the final volume of the balloon
We will use the combined gas law.
P₁ × V₁ / T₁ = P₂ × V₂ / T₂
V₂ = P₁ × V₁ × T₂/ T₁ × P₂
V₂ = 745 Torr × 1.41 × 10⁴ L × 225 K/ 294 K × 63.1 Torr
V₂ = 1.27 × 10⁵ L
CAN HF USED TO CLEAVE ETHERS EXPLAIN
Answer:
no
Explanation:
Fluoride is not nucleophilic (having the tendency to donate electrons) enough to allow for the use of HF to cleave ethers in protic media(protic solvents are polar liquid compounds that have dissociable hydrogen atoms). The rate of reaction is comparably low, so that heating of the reaction mixture is required.
Si enfriamos mercurio de 100C. Calcular la cantidad de calor que se debe restar sabiendo que la masa de mercurio es de 1800gr
Answer:
I do not speak Spanish.
Explanation:
Balance the following chemical equation.
CCl4 -> ___ C+ ___ Cl2
Answer:
Explanation:
CCl4 => C + 2Cl2
A molecule of acetone and a molecule of propyl aldehyde are both made from 3 carbon atoms, 6 hydrogen atoms, and 1 oxygen atom. The molecules differ in their arrangement of atoms. How do formulas for the two compounds compare? Both compounds have the same molecular formula, but have unique structural formulas. Both compounds have unique molecular formulas and structural formulas. Both compounds have the same structural formula, but have unique molecular formulas.
Explanation:
The structures of both acetone and propanal are shown below:
In the formula of propanal there is -CHO functional group at the end.
In acetone -CO- group is present in the middle that is on the second carbon.
The molecular formula is C3H6O.
Both have same molecular formula but different structural formulas.
A hypothetical A-B alloy of composition 53 wt% B-47 wt% A at some temperature is found to consist of mass fractions of 0.5 for both and phases. If the composition of the phase is 92 wt% B-8 wt% A, what is the composition of the phase
Answer:
the composition of the ∝ phase C∝ = 14 or [ 14 wt% B-86 wt% A ]
Explanation:
Given the data in the question;
Co = 53 or [ 53 wt% B-47 wt% A ]
W∝ = 0.5 = Wβ
Cβ = 92 or [ 92 wt% B-8 wt% A ]
Now, lets set up the Lever rule for W∝ as follows;
W∝ = [ Cβ - Co ] / [ Cβ - C∝ ]
so we substitute our given values into the expression;
0.5 = [ 92 - 53 ] / [ 92 - C∝ ]
0.5 = 39 / [ 92 - C∝ ]
0.5[ 92 - C∝ ] = 39
46 - 0.5C∝ = 39
0.5C∝ = 46 - 39
0.5C∝ = 7
C∝ = 7 / 0.5
C∝ = 14 or [ 14 wt% B-86 wt% A ]
Therefore, the composition of the ∝ phase C∝ = 14 or [ 14 wt% B-86 wt% A ]
In the given range,at what temperature does oxy gen have the highest solubility?
How can a Bose-Einstein condensate be formed? A. B super-heating a gas. B. By super-cooling certain types of solid. C. By super-cooling certain types of plasma. D. By super-heating a plasma
Answer:
C. By super-cooling certain types of plasma.
Explanation:
Bose-Einstein condensate is a state of matter whereby atoms or particles become cooled to a very low energy state leading to their condensation to give a single quantum state.
Note that plasma refers to atoms that have had some or even all of its electrons stripped away leaving only positively charged ions. Simply put, plasma is ionized matter.
When certain types of plasma are super cooled, Bose-Einstein condensate are formed.
A uniform plastic block floats in water with 50.0 % of its volume above the surface of the water. The block is placed in a second liquid and floats with 23.0 % of its volume above the surface of the liquid.
What is the density of the second liquid?
Express your answer with the appropriate units.
Answer:
density of second liquid = 650 kg/m³
Explanation:
Given that:
The volume of the plastic block submerged inside the water = 0.5 V
The force on the plastic block = [tex]\rho_1V_1g[/tex]
[tex]= 0.5p_1 V_g[/tex]
when the block is floating, the weight supporting the force (buoyancy force) is:
W [tex]= 0.5p_1 V_g[/tex]
[tex]\rho Vg = 0.5p_1 V_g[/tex]
[tex]\rho = 0.5 \rho _1[/tex]
where;
water density [tex]\rho _1[/tex] = 1000
[tex]\rho = 0.5 (1000)[/tex]
[tex]\rho = 500 kg/m^3[/tex]
In the second liquid, the volume of plastic block in the water = (100-23)%
= 77% = 0.7 V
The force on the plastic block is:
[tex]= 0.77p_2 V_g[/tex]
when the block is floating, the weight supporting the force (buoyancy force) is:
[tex]W = 0.77p_2 V_g[/tex]
[tex]\rho Vg = 0.77 \rho_2 V_g \\ \\ \rho = 0.77 \rho_2 \\ \\ 500 = 0.77 \rho_2 \\ \\ \rho_2 = 500/0.77[/tex]
[tex]\mathbf{ \rho_2 \simeq 650 \ kg/m^3}[/tex]
For each of the following compounds, indicate the pH at which 50% of the compound will be in a form that possesses a charge and at which pH more than 99% of the compound will be in a form that possesses a charge.
ClCH2COOH (pKa = 2.86)
CH3CH2NH+3 (pKa = 10.7)
Express your answer using two decimal places
a. Determine a pH at which 50% of ClCH2COOH will be in a form that possesses a charge.
b. Determine a pH at which pH more than 99% of ClCH2COOH will be in a form that possesses a charge.
c. Determine a pH at which 50% of CH3CH2NH+3 will be in a form that possesses a charge.
d. Determine a pH at which pH more than 99% of CH3CH2NH+3 will be in a form that possesses a charge.
Answer:
a. 2..86 b. 4.86 c. 10.7 d. 8.7
Explanation:
a. Determine a pH at which 50% of ClCH2COOH will be in a form that possesses a charge.
Using the Henderson-Hasselbalch equation,
pH = pKa + log[A⁻]/[HA]
where [A⁻] = concentration of conjugate base (or charged form) and [HA] = concentration of acid.
At 50% concentration, [A⁻] = [HA] ⇒ [A⁻]/[HA] = 1
So, pH = pKa + log[A⁻]/[HA]
pH = pKa + log1
pH = pKa = 2.86
b. Determine a pH at which pH more than 99% of ClCH2COOH will be in a form that possesses a charge.
Let x be the concentration of the acid. Since 99% of it should possess a charge, the basic concentration is 0.99x while the acidic concentration is remaining 1 % (1 - 0.99)x = 0.01x
Using the Henderson-Hasselbalch equation,
pH = pKa + log[A⁻]/[HA] where [A⁻] = concentration of conjugate base (or charged form) = 0.99x and [HA] = concentration of acid = 0.01x.
pH = pKa + log0.99x/0.01x
pH = pKa + log0.99/0.01
pH = 2.86 + log99
pH = 2.86 + 1.996
pH = 4.856
pH ≅ 4.86
c. Determine a pH at which 50% of CH3CH2NH+3 will be in a form that possesses a charge.
Using the Henderson-Hasselbalch equation,
pH = pKa + log[A⁻]/[HA]
where [A⁻] = concentration of conjugate base and [HA] = concentration of acid.
At 50% concentration, [A⁻] = [HA] ⇒ [A⁻]/[HA] = 1
So, pH = pKa + log[A⁻]/[HA]
pH = pKa + log1
pH = pKa = 10.7
d. Determine a pH at which pH more than 99% of CH3CH2NH+3 will be in a form that possesses a charge.
Let x be the concentration of the acid. Since 99% of it should possess a charge, the basic concentration is 0.01x while the acidic concentration is remaining 99 % (1 - 0.01)x = 0.99x (which possesses the charge).
Using the Henderson-Hasselbalch equation,
pH = pKa + log[A⁻]/[HA] where [A⁻] = concentration of conjugate base = 0.01x and [HA] = concentration of acid = 0.99x.
pH = pKa + log0.01x/0.99x
pH = pKa + log1/99
pH = 10.7 - log99
pH = 10.7 - 1.996
pH = 8.704
pH ≅ 8.7
Calculate the mass of sodium phosphate in aqueous solution to fully react with 37 g of chromium nitrate(III) an aqueous solution?(report answer in grams and only three Sigg figs do not put the unit)
Answer:
41 g
Explanation:
The equation of the reaction is;
Cr(NO3)3(aq)+Na3PO4(aq)=3NaNO3(s)+CrPO4(aq)
Number of moles of chromium nitrate = 37g/ 146.97 g/mol = 0.25 moles
1 mole of sodium phosphate reacts with 1 mole of chromium nitrate
x moles of sodium phosphate react as with 0.25 moles of chromium nitrate
x= 1 × 0.25/1
x= 0.25 moles
Mass of sodium phosphate = 0.25 moles × 163.94 g/mol
Mass of sodium phosphate = 41 g
