At 298 K, ∆H = -314 kJ/mol and ∆S = -0.372 kJ/(K•mol). What is the Gibbs free energy of the reaction?

Answer:

An indicator added to the solution turns green-blue.

Explanation:

An indicator is a substance which shows the degree of acidity or alkalinity of a solution by change in colour of the solution.

The universal indicator changes colour as the pH of the solution changes. Looking at the colour ranges for the universal indicator, the green-blue colour indicates a weak base.

Answer:

0.0063 mol

Explanation:

Step 1: Write the balanced combustion equation

C₈H₁₈(l) + 12.5 O₂(g) ⇒ 8 CO₂(g) + 9 H₂O(g)

Step 2: Establish the appropriate molar ratio

According to the balanced equation, the molar ratio of C₈H₁₈ to CO₂ is 1:8.

Step 3: Calculate the number of moles of C₈H₁₈ needed to produce 0.050 moles of CO₂

0.050 mol CO₂ × 1 mol C₈H₁₈/8 mol CO₂ = 0.0063 mol C₈H₁₈

Answer:

[tex]\boxed {\boxed {\sf 8.10 \ L}}[/tex]

Explanation:

This question asks us find the volume of a gas sample given a change in temperature. Since the pressure remains constant, we only are concerned with the variables of temperature and volume.

We will use Charles's Law. This states the volume of a gas is directly proportional to the temperature of a gas. The formula is:

[tex]\frac{V_1}{T_1}=\frac{V_2}{T_2}[/tex]

The gas starts at a volume of 2.70 liters and a temperature of 25.0 degrees Celsius.

[tex]\frac {2.70 \ L}{25.0 \textdegree C}=\frac{V_2}{T_2}[/tex]

The temperature is increased to 75.0 degrees Celsius, but the volume is unknown.

[tex]\frac {2.70 \ L}{25.0 \textdegree C}=\frac{V_2}{75.0 \textdegree C}[/tex]

We are solving for the volume at 75 degrees Celsius, so we must isolate the variable V₂.

It is being divided by 75.0 °C. The inverse operation of division is multiplication, so we multiply both sides of the equation by 75.0 °C.

[tex]75.0 \textdegree C *\frac {2.70 \ L}{25.0 \textdegree C}=\frac{V_2}{75.0 \textdegree C} * 75.0 \textdegree C[/tex]

[tex]75.0 \textdegree C *\frac {2.70 \ L}{25.0 \textdegree C}= V_2[/tex]

The units of degrees Celsius (° C) cancel.

[tex]75.0 *\frac {2.70 \ L}{25.0}= V_2[/tex]

[tex]75.0 *0.108 \ L = V_2[/tex]

[tex]8.1 \ L = V_2[/tex]

The original measurements have 3 significant figures, so our answer must have the same. Currently, the answer has 2. If we add another 0, the value of the answer does not change, but the number of sig figs does.

[tex]8.10 \ L = V_2[/tex]

The volume of this gas sample at 75.0 degrees Celsius is 8.10 Liters.

Answer:  inference because she drew a conclusion based on evidence.

why?:

Because the evidence was that she heard the crashing sound, and then when she came into her room saw the broken window and baseball.

It was not an observation because she did not directly see the baseball going through the window

Answer:

[tex]K=1.7x10^{-3}[/tex]

Explanation:

Hello there!

In this case, according to the given information, it turns out possible for us to solve this problem by firstly setting up the equilibrium expression for the given reaction, in agreement to the law of mass action:

[tex]K=\frac{[NO]^2}{[N_2][O_2]}[/tex]

Next, we plug in the given concentrations on the data table to obtain:

[tex]K=\frac{(0.034)^2}{(0.69)(0.98)}\\\\K=1.7x10^{-3}[/tex]

Regards!

Solution :

Spontaneous Process

A spontaneous process is defined as the process that occurs without the help of any external aid or inputs. A spontaneous process is a natural process which occurs naturally in the environment.

Non Spontaneous process

A non spontaneous process is a process which does not occur naturally. Some inputs are provided for the process to occur. Energy from external source is applied into the process to start the process.

The following processes are :

1. Melling of ice   ---- Spontaneous

2 Rusting of iron  --- Spontaneous

3. Marble going down the spiral.   --- spontaneous

4. Going up the hill  ---- Non spontaneous

5. Keeping the food fresh from spoilage​  --- Non spontaneous

Answer:

77%

Explanation:

First we convert 3.0 g of cyclohexanol (C₆H₁₂O) to moles, using its molar mass:

Then we convert 1.9 g of cyclohexene (C₆H₁₀) to moles, using its molar mass:

Finally we calculate the theoretical yield:

Answer:

Explanation:

When Tollen's test is done by aldehyde , silver ion is converted into silver which forms a layer which looks like a mirror.

Ag⁺ + e = Ag

It is a reduction process where silver(1) ion is reduced to metallic silver.

Aldehyde is oxidized to carboxylate ion.

CH₃CHO + 2 OH⁻ = CH₃COO⁻ + H₂O + H⁺ + 2e

Visual indicator is silver metal which forms silver mirror at the bottom of test tube .

Answer:

C

Explanation:

The specific heat capacity=quantity of heat in joule/mass×change in temperature

from this question the quantity of heat is 75250,the mass is 2000 and the change in temperature is 50-30

which is 20

therefore

c=75250/2000×20

c=75250/40000

c=1.88

I hope this helps

Answer:

See explanation

Explanation:

Truly, the second law of thermodynamics requires that spontaneous processes generate entropy, either in the system or in the surroundings.

When a solid is dissolved in a liquid, the solid dissociates into ions. These ions increases the number of particles and hence the entropy of the system thereby making the process spontaneous.

Hence, the dissolution of a substance via an endothermic process is spontaneous because of increase in the number of particles which in turn increases the entropy of the system.

Answer:

0.21 g

Explanation:

The equation of the reaction is;

NaCl(aq) + AgNO3(aq) -----> NaNO3(aq) + AgCl(s)

Number of moles of NaCl= 0.0860 g /58.5 g/mol = 0.00147 moles

Number of moles of AgNO3 = 30/1000 L × 0.050 M = 0.0015 moles

Since the reaction is 1:1, NaCl is the limiting reactant.

1 mole of NaCl yields 1 mole of AgCl

0.00147 moles of NaCl yields 0.00147 moles of AgCl

Mass of precipitate formed = 0.00147 moles of AgCl × 143.32 g/mol

= 0.21 g

Answer:

heat; temperature; surrounding; insulated.

Explanation:

A calorimeter can be defined as a scientific instrument (device) that is designed and developed for measurement of the heat involved in chemical reactions or other processes, especially by taking the measurement of the temperature of the materials surrounding the process.

Basically, a calorimeter is insulated using materials with a very high level of resistivity, so as to prevent heat transfer to the outside of the device (calorimeter).

Some of the components that make up a simple calorimeter are; thermometer, an interior styrofoam cup, an exterior styrofoam cup, cover, etc.

Additionally, a calorie refers to the amount of heat required to raise the temperature of a gram of water by one degree Celsius (°C)

A calorimeter measures the heat involved in reactions or other processes by measuring the temperature of the materials surrounding the process. The calorimeter is insulated to prevent transfer of heat to outside the device.

Calorimeter is an instrument used in chemical reactions for measuring the heat, physical changes as well as heat capacity of the chemical reaction.

From the definition of calorimeter it is clear that it checks the temperature of the reaction and calculates the heat of the chemical reaction. It is insulated by those materials which are bad conductors of heat so that no heat will loss from this apparatus.

Hence, correct options are heat, temperature, surroundings and insulated.

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Answer:

2.5 × 10² L

Explanation:

Step 1: Given and required data

Step 2: Convert 25 °C to Kelvin

We will use the following expression.

K = °C + 273.15 = 25 + 273.15 = 298 K

Step 3: Calculate the volume (V) of the balloon

We will use the ideal gas equation.

P × V = n × R × T

V = n × R × T / P

V = 9.7 mol × (0.0821 atm.L/mol.K) × 298 K / 0.955 atm = 2.5 × 10² L

Ribose is a reducing sugar. A reducing sugar is a carbohydrate that can undergo a redox reaction, in which it donates electrons to another chemical species.

This is usually observed when the sugar opens its ring structure to form an aldehyde or ketone functional group.

Ribose, a five-carbon sugar, can form an open-chain structure with an aldehyde functional group. In this form, it can donate electrons and act as a reducing agent in certain chemical reactions, such as the reduction of other compounds like Benedict's reagent during laboratory tests for reducing sugars.

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Answer:

See explanation

Explanation:

The relationship between the activation energy and rate of reaction is best captured by the Arrhenius equation;

k= Ae^-Ea/RT

Where;

k= rate constant

A= pre-exponential factor

Ea=activation energy

R= gas constant

T= temperature

We can see from the foregoing that, as the activation energy increases, the rate of reaction decreases and vice versa. reactions that have a very high activation energy are markedly slow.

Since the activation energy for the malonic acid reaction is found to be greater than the activation energy for the tartaric acid reaction, then the rate of the malonic acid reaction(k) will be slower than that of the tartaric acid reaction.

The study of chemistry and bonds is called chemistry. There are two types of elements metal and nonmetals.

The correct answer is mentioned below.

The equation is as follows:-

[tex]k= Ae^{-Ea/RT[/tex] Where;

We can see from the foregoing that, as the activation energy increases, the rate of reaction decreases and vice versa. reactions that have very high activation energy are markedly slow. Since the activation energy for the malonic acid reaction is found to be greater than the activation energy for the tartaric acid reaction, then the rate of the malonic acid reaction(k) will be slower than that of the tartaric acid reaction.

Hence, the correct answer is mentioned above.

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If Gold's natural state has a definite shape and a definite volume, then its natural state is solid.

Answer:

0.696 m

Explanation:

We'll begin by calculating the number of mole in 16.7 g of C₆H₁₂O₆. This can be obtained as follow:

Mass of C₆H₁₂O₆ = 16.7 g

Molar mass of C₆H₁₂O₆ = (6×12) + (12×1) + (6×16)

= 72 + 12 + 96

= 180 g/mol

Mole of C₆H₁₂O₆ =?

Mole = mass / molar mass

Mole of C₆H₁₂O₆ = 16.7 / 180

Mole of C₆H₁₂O₆ = 0.093 mole

Next, we shall convert 133.6 g of water to Kg. This can be obtained as follow:

1000 g = 1 Kg

Therefore,

133.6 g = 133.6 g × 1 Kg / 1000 g

133.6 g = 0.1336 Kg

Thus, 133.6 g is equivalent to 0.1336 Kg.

Finally, we shall determine the molality of the solution. This can be obtained as illustrated below:

Mole of C₆H₁₂O₆ = 0.093 mole

Mass of water = 0.1336 Kg

Molality =?

Molality = mole / mass of water (in Kg)

Molality = 0.093 / 0.1336

Molality = 0.696 m

Therefore, the molality of the solution is 0.696 m

Answer:

i. HCIO2 - 2.9

ii. CH3COOH - 2.64

iii. HF - 3.27

iv. HNO2 - 2.67

Explanation:

The Ph value differ for base and acid. A neutral solution will have Ph value of 7. For acid the Ph value is less than 7 and for base Ph value is greater than 7. The highest Ph value for the given acids is 3.27 for hydroflouric acids.

The pH of the resulting solution is 3.16. Acetic acid having the formula [tex]CH_3COOH[/tex] would produce the highest pH at the equivalence point in a weak acid-strong base titration.

Kingsley adds 49.28 mL of NaOH to 250.00 mL of the HCOOH solution.

The neutralization reaction resulted in 0.098 moles of HCOOH and 0.025 moles of HCOO⁻ left in the solution.

We have to determine the pH of the resulting solution and identify the acid that would produce the highest pH at the equivalence point in a weak acid-strong base titration.

pH, a quantitative measure of the acidity or basicity of aqueous or other liquid solutions.

Kingsley adds 49.28 mL of NaOH to 250.00 mL of the HCOOH solution.

Total volume of the solution = 49.28 mL + 250.0 mL = 299.28 mL = 0.29928 L

At neutralization point, HCOOH = 0.098 mol = [tex]\frac{0.098\ mol}{0.29928\ L} = 0.32745\ M[/tex]

So, Concentration of HCOOH at neutralization point = 0.32745 M

And [tex]HCOO^-[/tex] at neutralization point = 0.025 mol = [tex]\frac{0.025\ mol}{0.29928\ L} = 0.08353\ M[/tex]

So, Concentration of HCOO⁻ at neutralization point = 0.08353 M

Now, [tex]K_a[/tex] value of HCOOH = [tex]1.77\times10^{-4}[/tex] (reference value}

We know that [tex]pK_a = -logK_a[/tex]

[tex]pK_a = -log(1.77\times10^{-4}) = 3.75[/tex]

Now, HCOOH  is acid and HCOO⁻ is the conjugate base.

According to Henderson Hasselblach equation:

[tex]pH = pK_a + log\frac{[conjugate\ base]}{[acid]}\\ \therefore pH = 3.75 + log\frac{[HCOO^-]}{[HCOOH]}\\pH = 3.75 + log(\frac{0.08353}{0.32745})\\pH = 3.75 +(-0.59)\\pH = 3.16[/tex]

Therefore, the pH of the resulting solution is 3.16.

When weak acid is titrated with a strong base, the pH at the neutralization point is always greater than 7. It is because the conjugate base produced by weak acid in neutralization reaction is comparatively stronger in nature which produces [tex]OH^-[/tex] at neutralization point after reacting with water. so the solution is basic. As a result, pH is more than 7.

Now, the weaker is the acid, the stronger is the conjugate base, and vice-versa. Therefore, the concentration of [tex]OH^-[/tex] ions is more at the neutralization point. So more will be the pH value.

Given acids with the corresponding [tex]K_a[/tex] value are shown below:

[tex]K_a(HF) =6.8\times10^{-4}\\K_a(HNO_2) =4.5\times10^{-4}\\K_a(HClO_2) =1.1\times10^{-2}\\K_a(CH_3COOH) =1.8\times10^{-5}[/tex]

We know that lower the value of [tex]K_a[/tex] of  acid, the weaker is the acid and vice-versa. Hence, [tex]CH_3COOH[/tex] has lowest [tex]K_a[/tex] value compared to other acids. Therefore, [tex]CH_3COOH[/tex]  would  produce the highest pH at the equivalence point in a weak acid-strong base titration.

Hence, The pH of the resulting solution is 3.16. Acetic acid having the formula [tex]CH_3COOH[/tex] would produce the highest pH at the equivalence point in a weak acid-strong base titration.

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Answer:

35g/l

Explanation:

Salinity is practically the saltiness of the water, in basic terms. It's basically the amount of salt dissolved in water. Ocean water has a salinity of around 35g/l (that's about 3.5% of which is dissolved salt in water!). However, Atlantic Ocean (the ocean with the saltiest water), can range up to 37g/l.

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b) (√)

c)(✓)

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Stalactites and stalagmites form as ________ precipitates out of the water evaporating in underground caves.

Group of answer choices

hydrochloric acid

sodium bicarbonate

calcium carbonate

sodium chloride

sodium hydroxide

Answer:

calcium carbonate

Explanation:

A stalactite is an icicle-looking mould that is formed by the precipitation of natural minerals as a result of water dripping from the ceiling, hanging from a cave.

A stalagmites in the other hand, grows upwards and is also a mound that is formed by the deposits of minerals gotten by the water dripping on the floor of a cave.

Therefore, stalactites and stalagmites form as calcium carbonate precipitates out of the water evaporating in underground caves.

Answer:

Explanation:

Assume we have 100g of this substance. That means we would have 20.24g of Cl and 79.76g of Al. Now we can find how many moles of each we have:

[tex]\frac{79.76 \:g}{35.45 \: g/mol}[/tex] = 2.25 mol of chlorine

[tex]\frac{20.24 \: g}{26.98 \: g/mol}[/tex] = 0.750 mol of Al.

To form a integer ratio, do 2.25/0.75 = 2.99999 ~= 3.

So the ratio is essentially Al : Cl => 1 : 3. To the compound is possibly [tex]AlCl_3[/tex].

However, it says it has a molar mass of 266.64 g/mol, and since AlCl3 has a molar mass of 133.32, it must be [tex]Al_2Cl_6[/tex].

Actually this molecule isn't exactly AlCl3 (which is ionic). Al2Cl6 forms a banana bond where Cl acts as a hapto-2 ligand. But that's a bit advanced. All you need to know is X = Al2Cl6

The molecular formula of the compound is Al₂Cl₆

To solve the question given above, we'll begin by obtaining the empirical formula of the compound. This can be obtained as follow:

Aluminum (Al) = 20.24%

Chlorine (Cl) = 79.76%

Al = 20.24%

Cl = 79.76%

Divide by their molar mass

Al = 20.24 / 27 = 0.75

Cl = 79.76 / 35.5 = 2.25

Divide by the smallest

Al = 0.75 / 0.75 = 1

Cl = 2.25 / 0.75 = 3

Thus, the empirical formula of the compound is AlCl₃

Finally, we shall determine the the molecular formula of the compound.

Molar mass of compound = 266.64 g/mol

Empirical formula = AlCl₃

[AlCl₃]ₙ = 266.64

[27 + (3×35.5)]n = 266.64

[27 + 106.5]n = 266.64

133.5n = 266.64

Divide both side by 133.5

n = 266.64 / 133.5

Molecular formula = [AlCl₃]ₙ

Molecular formula = [AlCl₃]₂

Therefore, the molecular formula of the compound is Al₂Cl₆

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Answer:

Every atom of a given element has the same number of protons

The protons in the nucleus of the helium atom are held together by a force called the strong nuclear force.

Explanation:

Atoms are composed of electrons, protons and neutrons. The electron is negatively charged, protons are positively charged and the neutrons have no charge.

Electrons are found in shells while protons are found inside the atomic nucleus. Similar to electrostatic forces between electron and proton, protons of helium are held together by a strong nuclear blinding force.

Note that, all isotopes must have the same atomic number. This shows that they are all the same atom changed by differences in number of neutrons.

Answer:

The correct equation is "[tex]\frac{[Ni(H_2O)_3 (NH_3)]^{2+}}{[Ni(H_2O)_4]^{2+} [NH_3]}[/tex]".

Explanation:

According to the question,

Throughout an aqueous solution, [tex]Ni^{2+}[/tex] exist as [tex][Ni(H_2O)_4]^{2+}[/tex]

So,

⇒ [tex][Ni(H_2O)_4]^{2+} + 4NH_3 \rightleftharpoons [Ni(NH_3)_4]^{2+} + H_2O[/tex]

⇒ [tex]K_f = \frac{[Ni(NH_3)_4]^{2+}}{[Ni(H_2O)_4^{2+}] [NH_3]^4}[/tex]

Here, we have excluded [tex][H_2O][/tex] as concentration of water will be const.

Now,

This formation of [tex][Ni(NH_3)_4]^{2+}[/tex] proceeds via several steps,

Step 1:

⇒ [tex][Ni(H_2O)_4]^{2+}+NH_3 \rightleftharpoons [Ni(H_2O)_3 (NH_3)]^{2+} + H_2O[/tex]

⇒ [tex]K_1 = \frac{[Ni(H_2O)_3 (NH_3)]^{2+}}{[Ni(H_2O)_4]^{2+} [NH_3]}[/tex]

Answer:

62.5 ml of 0.032 M  KMnO₄ are required to react with 50.0 ml of 0.100 molar H₂C₂O₄ in the presence of excess H₂SO₄

Explanation:

The balanced reaction is:

2 KMnO₄ + 5 H₂C₂O₄ + 3 H₂SO₄ → K₂SO₄ + 2 MnSO₄ + 8 H₂O + 10 CO₂

By stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

Molarity or Molar Concentration is the number of moles of solute that are dissolved in a certain volume.

The molarity of a solution is calculated by dividing the moles of the solute by the volume of the solution:

[tex]Molarity=\frac{number of moles of solute}{volume}[/tex]

Molarity is expressed in units [tex]\frac{moles}{liter}[/tex]

In this case, 50 mL (0.05 L) of 0.1 M H₂C₂O₄ react. So, replacing the data in the definition of molarity:

[tex]0.1 M=\frac{number of moles of solute}{0.05 L}[/tex]

Solving:

number of moles of solute= 0.1 M*0.05 L

number of moles of solute= 0.005 moles

So, 0.005 moles of H₂C₂O₄ react.  Then you can apply the following rule of three: if by stoichiometry 5 moles of H₂C₂O₄ react with 2 moles of KMnO₄, 0.005 moles of H₂C₂O₄ react with how many moles of KMnO₄?

[tex]moles of KMnO_{4} =\frac{0.005moles of H_{2} C_{2} O_{4}* 2moles of KMnO_{4} }{5moles of H_{2} C_{2} O_{4} }[/tex]

moles of KMnO₄= 0.002 moles

Knowing that the molarity of KMnO₄ is 0.032 M, replacing in its definition and solving:

[tex]0.032 M=\frac{0.002 moles}{volume}[/tex]

[tex]volume=\frac{0.002 moles}{0.032 M}[/tex]

volume= 0.0625 L= 62.5 mL

62.5 ml of 0.032 M  KMnO₄ are required to react with 50.0 ml of 0.100 molar H₂C₂O₄ in the presence of excess H₂SO₄

Answer:

c. C3H9N2O2

Explanation:

The empirical formula of a compound is defined as the simplest whole number ratio of atoms present in a molecule. To solve this question we need to convert the mass of each atom to moles. With the moles we can find the ratio as follows:

Moles N -Molar mass: 14.01g/mol-

0.420g N * (1mol/14.01g) = 0.0300 moles N

Moles O -Molar mass: 16g/mol-

0.480g O * (1mol/16g) = 0.0300 moles O

Moles C -Molar mass: 12.01g/mol-

0.540g C * (1mol/12.01g) = 0.0450 moles C

Moles H -Molar mass: 1.0g/mol-

0.135g H * (1mol/1g) = 0.135moles H

Dividing in the moles of N (Lower number of moles) the ratio of atoms is:

N = 0.0300 moles N / 0.0300 moles N = 1

O = 0.0300 moles O / 0.0300 moles N = 1

C = 0.0450 moles C / 0.0300 moles N = 1.5

H = 0.135 moles H / 0.0300 moles N = 4.5

As the empirical formula requires whole numbers, multiplying each ratio twice:

N = 2, O = 2, C = 3 and H = 9

And the empirical formula is:

Answer:

4.858 g

Explanation:

Start with the formula

density = [tex]\frac{mass}{volume}[/tex]

density = 1.98 g/mL

volume = 2.45 mL

mass = ??

rearrange the formula to solve for mass

(density) x (volume) = mass

Add in the substitutes and solve for mass

1.98 g/mL x 2.45 mL = 4.858 g

Answer:.......

Explanation:

Answer:

0.030 M

Explanation:

Step 1: Make an ICE chart

        2 SO₂(g) + O₂(g) ⇄ 2 SO₃(g)

I        0.060      0.050          0

C         -2x            -x            +2x

E     0.060-2x  0.050-x       2x

Step 2: Find the value of x

The concentration of SO₃ at equilibrium is 0.040 mol/L. Then,

2x = 0.040

x = 0.020

Step 3: Calculate the concentration at equilibrium of O₂

[O₂] = 0.050 - x = 0.050 - 0.020 = 0.030 M

The equilibrium concentration of oxygen is 0.030 M.

A reversible reaction is a reaction that can move either in the forward or in the reverse direction. We have the reaction; 2SO2(g) + O2(g) ⇄ 2SO3(g). We can now set up the ICE table as shown below;

  2 SO₂(g) + O₂(g) ⇄ 2 SO₃(g)

I        0.060      0.050          0

C         -2x            -x            +2x

E     0.060-2x  0.050-x       2x

At equilibrium;

2x = 0.040 M

x = 0.040 M/2 =  0.020 M

For oxygen;

0.050-x  

0.050 M - 0.020 M = 0.030 M

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