Cis-4-tertButylcyclohexyl bromide (compound 1) and Trans-4 tert Butylcyclohexylbromide (compound 2) are reacted with Potassium Tertiary butoxide in Tertiary butanol to produce 4-tertbutylcyclohexene. The following statement is completely true?A. In compound 1 the Tert butyl group occupies the equatorial position and the Bromine occupies the axial position and in compound 2 both the Tert butyl and the bromine occupy equatorial positions. Compound 1 reacts faster than compound 2.
B. In compound 1 the Tert butyl group occupies the axial position and the Bromine occupies the axial position and in compound 2 both the Tert butyl and the bromine occupy equatorial positions. Compound 1 reacts faster than compound 2.
C. In compound 1 the Tert butyl group occupies the equatorial position and the Bromine occupies the equatorial position and in compound 2 both the Tert butyl and the bromine occupy equatorial positions. Compound 1 reacts faster than compound 2.
D. In compound 1 the Tert butyl group occupies the equatorial position and the Bromine occupies the axial position and in compound 2 the Tert butyl occupies the axial and the bromine occupies equatorial positions. Compound 1 reacts faster than compound 2.
E. In compound 1 the Tert butyl group occupies the equatorial position and the Bromine occupies the axial position and in compound 2 both the Tert butyl occupies the equatorial and the bromine occupies axial position. Compound 1 reacts faster than compound 2.
F. In compound 1 the Tert butyl group occupies the equatorial position and the Bromine occupies the axial position and in compound 2 both the Tert butyl and the bromine occupy equatorial positions. Compond 2 reacts faster than compound 1.

Answers

Answer 1

Answer:

In compound 1 the Tert butyl group occupies the equatorial position and the Bromine occupies the axial position and in compound 2 the Tert butyl occupies the axial and the bromine occupies equatorial positions. Compound 1 reacts faster than compound 2.

Explanation:

In cyclic organic compounds, substituents may occupy the axial or equatorial positions. The axial positions are aligned parallel to the symmetry axis of the ring while the equatorial positions are around the plane of the ring.

Bulky substituents have more room in the equatorial than in the axial position. This means that compound 1 is more stable than compound 2.

This is clear on the basis of stability of the molecules because compound 1 will react faster than compound 2 since the bulky tertiary butyl group in compound 1 occupy equatorial and not axial positions.


Related Questions

Identify the change in state that does NOT have an increase in entropy. Identify the change in state that does NOT have an increase in entropy. water evaporating dry ice subliming steam condensing water boiling popsicle melting

Answers

Answer:

condensing water

Explanation:

Entropy refers to the level of disorderliness in a system. The entropy of liquids is greater than that of solids. The entropy of gases is greater than that of liquids.

A process of physical change involving a change of state from solid to liquid or liquid to gas is accompanied by increase in entropy.

However, a change of state involving a change from liquid to solid or gas to liquid is accompanied by decrease in entropy.

Hence, steam condensing to water leads to decrease and not increase in entropy of the system.

Which of the following was NOT explained by Dalton's atomic theory?
ANSWER:
A. the Law of Multiple Proportions
B. the difference between elements and compounds
C.?the difference between isotopes of an element
D. the Law of Conservation of Mass

Answers

Answer:

i think 1. law of muliple proportion

Explanation:

please like

liquid junction potential arise due to?

Answers

Answer:

liquid junction potentials

when a cell contains a boundary between two electrolytic solutions of different composition or concentration, a liquid junction potential is developed due to the "diffusion of the various components at characteristic rates in the boundary zone."

#carryonlearning

which of the following is not an instance of benefit in from gases ?

1) filling thermometers
2) inflating tyres
3) in LP gas cylinders
4) in pressure cookers​

Answers

Answer:

1) filling thermometers

Explanation:

thermometers are filled with liquid mercury

An unidentified gas is determined to be 24.0% carbon and 76% fluorine by mass. What is the empirical formula of this gas

Answers

Answer:

CF₂

Explanation:

Let's assume we have 100 g of the gas. If that were the case we'd have

24 g of C76 g of F

Now we convert both masses into moles, using their respective molar mass:

24 g C ÷ 12 g/mol = 2 mol C76 g F ÷ 19 g/mol = 4 mol F

We can express those results as C₂F₄.

To determine the empirical formula we reduce those coefficients to the lowest possible integers, leaving us with CF₂.

A student dropped a piece of silver metal into a solution of HCl(aq). He observed the formation of gas bubbles and collected the gas into another test tube. The student performed a splint test and observed that the splint produced a popping sound when he placed the splint into the test tube of the gas. What can be said about the results of this students experiment?

a. The student performed the splint test incorrectly. He should of observed the splint flare up when the splint was placed in the test tube.
b. The student completed the experiment correctly and there were no errors in the experiment.
c. The experiment was performed incorrectly. Silver doesn't react with HCl. Therefore, the student picked up the wrong metal when conducting the experiment.
d. The student performed the splint test incorrectly. He should of observed the flame being extinguished when the splint was placed in the test tube.

Answers

Answer:

The student completed the experiment correctly and there were no errors in the experiment.

Explanation:

When a pea size amount of Ag is dropped into a solution of HCl, the following reaction occurs;

Ag(s) + 2HCl(aq) ----> AgCl(aq) + H2(g)

The gas H2 burns with a pop sound. The gas obtained does not react to litmus. The products of the reaction are expected.

Hence, the experiment was properly conducted and the student completed the experiment correctly and there were no errors in the experiment.

When taking a measurement with a pH meter, keep the instrument in the _______storage solution or water until it is needed. Rinse the pH meter with
_______deionized water or acetone and gently pat dry. Place the meter in the sample solution, and record the measurement when the pH _______stabilizes or reaches the maximum value

Answers

Answer:

storage solution , deionized water, stabilizes

Explanation:

A pH meter is a scientific device or instrument that is used to measure the pH of a given aqueous solution thereby determining the nature of the solution whether it is acidic or basic or neutral.

While using the pH meter or taking the measurement using the pH meter --

it should be kept in a storage solution for effective working.Before using the device, it is rinsed with a deionized water and pat dry.Record the measurements when the pH meter stabilizes.

How many g of Al are required to produce 2.8 mol of Al2O3

Answers

Answer:

290 g Al₂O₃

General Formulas and Concepts:

Atomic Structure

Reading a Periodic TableMoles

Stoichiometry

Using Dimensional Analysis

Explanation:

Step 1: Define

[Given] 2.8 mol Al₂O₃

[Solve] g Al₂O₃

Step 2: Identify Conversions

[PT] Molar Mass of Al: 26.98 g/mol

[PT] Molar Mass of O: 16.00 g/mol

Molar Mass of Al₂O₃: 2(26.98) + 3(16.00) = 101.96 g/mol

Step 3: Convert

[DA] Set up:                                                                                                       [tex]\displaystyle 2.8 \ mol \ Al_2O_3(\frac{101.96 \ g \ Al_2O_3}{1 \ mol \ Al_2O_3})[/tex][DA] Multiply [Cancel out units]:                                                                      [tex]\displaystyle 285.488 \ g \ Al_2O_3[/tex]

Step 4: Check

Follow sig fig rules and round. We are given 2 sig figs.

285.488 g Al₂O₃ ≈ 290 g Al₂O₃

Topic: AP Chemistry

Unit: Atomic Structure

290 g is the answer yeaaaa

Which equation expresses the solubility product of Zn3(PO4)2?

a. Ksp = [Zn2+][PO43]

b. Ksp = [Zn2+]3 [PO43]2

c. Ksp = 6[Zn2+][PO43]2

d. Ksp = 108[Zn2+][PO43]2​

Answers

AnSweR : -

b. Ksp = [Zn2+]3 [PO43]2

Hope It Helps You ✌️

Design an experiment to demonstrate phototropism.

Answers

Answer:

Object: To demonstrate phototropism

equipments: A black box, window with light source, a well watered potted plant.

Experiment: A wellwatered potted plant is placed inside a darkened black  box that is having a small window on one side. This is called as phototropic chamber. Window is remain closed for a day the plant shows normal growth.

Whereas if window is opened atwo days it will be found that shoot tip bends and grows towards light proving that it is positively phototropic.

when (S)-3-bromo-2,3-dimethylpentane is treated with sodium chloride with water as the solvent, the products formed are ___________. *Select all that apply

Answers

Answer:

(S)-3-chloro-2,3-dimethylpentane

Explanation:

When sodium chloride is treated with bromo dimethylpentane in presence of water, then chloro dimethylpentane is formed. This chemical reaction is stable reaction in water because of its solvency.

The balanced equation for the reaction between aqueous ammonium sulfate and aqueous barium acetate is:________.
A. (NH4)2SO4 (aq) + Ba(C2H302)2 (aq) - Baso, (aq) + 2 NH.C2H2O2 (s).
B. (NH4)2SO3 (aq) + Ba(C2H302)2 (aq) - BaSO3(aq) + NH.C2H3O2 (aq).
C. (NH4)2SO4 (aq) + Ba(C2H302)2 (aq) - BaSO4(s) + 2 NH C2H2O2 (aq).
D. (NH4)2SO4 (aq) + Ba(C2H202)2 (aq) - BaSO4(s) + NHC2H2O2 (aq).
E. NH,SO4 (aq) + BaC2H302 (aq) -- BaSO4(s) + NH4C2H2O2 (aq).

Answers

Answer:

(NH4)2SO4 (aq) + Ba(C2H302)2 (aq) - BaSO4(s) + 2 NH4C2H3O2 (aq).

Explanation:

In balancing redox reaction equations, the rule of thumb is that the number of atoms on the left hand side of the reaction equation must be equal to the number of atoms of the same element on the left hand side of the reaction equation.

To ensure this, the correct coefficients are written in front of each of the reactants/products and the number of atoms of each element is counted to ensure that the equation is balanced.

If all these procedures are meticulously carried out, the balanced equation for the reaction between aqueous ammonium sulfate and aqueous barium acetate is:

(NH4)2SO4 (aq) + Ba(C2H302)2 (aq) - BaSO4(s) + 2 NH4C2H3O2 (aq).

In an exothermic chemical reaction:____.
A. The mass of the products is greater than the mass of the reactants.
B. The mass of the products is less then the mass of the reactants.
C. Heat is released as the reaction proceeds.
D. Heat is absorbed as the reaction proceeds.

Answers

Answer:

C

Explanation:

Think of 'exo' as exit and 'thermic' as relating to thermal energy/ heat. Thus, an exothermic release thermal energy as the reaction proceeds.

In an exothermic reaction, the total energy of the products is lesser than that of the reactants and ΔH (change in energy) is less than zero.

When heat is absorbed as the reaction proceeds, the chemical reaction is an endothermic reaction.

Ammonia and oxygen react to form nitrogen monoxide and water. Construct your own balanced equation to determine the amount of NO and H2O that would form when 2.78 mol NH3 and 5.19 mol O2 react.

Answers

Answer:

The amount of NO formed s 2.78 moles or 83.4 grams

The amount of H2O formed is 4.17 moles or 75.1 grams

Explanation:

Step 1: Data given

Ammonia = NH3

Oxygen = O2

nitrogen monoxide = NO

water = H2O

Number of moles NH3 = 2.78 moles

Number of O2 = 5.19 moles

Step 2: The balanced reaction

4NH3 + 5O2 → 4NO + 6H2O

Step 3: Calculate moles of products

For 4 moles NH3 we need 5 moles O2 to produce 4 moles NO and 6 moles H2O

NH3 is the limiting reactant

All the NH3 will react. There will be 0 moles of NH3 left

For 4 moles NH3 we need 5 moles O2

For 2.78 moles NH3 we need 5/4 * 2.78 = 3.475 moles

There will be left 5.19 - 3.475 = 1.715 moles O2

For 4 moles NH3 we need 5 moles O2 to produce 4 moles NO and 6 moles H2O

For 2.78 moles NH3 we'll have 2.78 moles NO and 6/4 * 2.78 = 4.17 moles H2O

Step 4: Calculate mass of NO and H2O

Mass = moles * molar mass

Mass NO = 2.78 moles * 30.01 g/mol

Mass NO = 83.43 grams

Mass H2O = 4.17 moles * 18.02 g/mol

Mass H2O = 75.14 grams

The amount of NO formed s 2.78 moles or 83.4 grams

The amount of H2O formed is 4.17 moles or 75.1 grams

Identify a process that is NOT reversible. Identify a process that is NOT reversible. melting of snow baking of bread deposition of carbon dioxide freezing water melting of aluminum

Answers

Answer:

Identify a process that is NOT reversible.

Melting of snow

baking of bread

deposition of carbon dioxide

freezing water

melting of aluminum

Explanation:

A physical change is the one in which there is a change only in its physical state, color, the appearance of the substance. But the chemical composition of the substance remains unchanged.

It is a temporary change and can be reversed easily.

For example:

melting, freezing, deposition etc.

Baking is a permanent change and the chemical composition of the substance changes.

Hence, among the given options, baking of bread is not a reversible change.

Out of the following all are physical changes except baking of bread and physical changes are reversible so the process  which is not reversible is baking of bread.

What are physical changes?

Physical changes are defined as changes which affect only the form of a substance but not it's chemical composition. They are used to separate mixtures in to chemical components but cannot be used to separate compounds to simpler compounds.

Physical changes are always reversible using physical means and involve a change in the physical properties.Examples of physical changes include melting,boiling , change in texture, size,color,volume and density.Magnetism, crystallization, formation of alloys are all reversible and hence physical changes.

They involve only rearrangement of atoms and are often characterized to be changes which are reversible.

Learn more about physical changes,here:

https://brainly.com/question/17931044

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Methanol has the formula CH3OH. What is the predominant intermolecular force between methanol molecules?
ANSWER:
dispersion forces
dipole forces
ionic bonds
hydrogen bonds

Answers

Answer:

hydrogen bonds

Explanation:

similarly CH3OH also has a OH group and H hydrogen thus it will also form h-bonding.


A scientific hypothesis is
ANSWER:
predictive.
testable.
explanatory.
all of the above.

Answers

Answer:

All of the above.

Explanation:

For a scientific hypothesis to be considered a hypothesis, it has to be testable. When conducting a lab experiment, it also allows the tester to predict what might occur during and after the experimentation. They are also explanatory. For example, theories are hypotheses that have been verified and can explain why something in nature takes place.

Plz!!!!Plz!!!!!help help

Answers

Answer:

false

Explanation:

category 1 is the worst

22 Agas that is collected by upward delivery is likely to be A heavier than air B insoluble in water C lighter than air D Soluble in water

Answers

Answer:

joib

Explanation:

A frozen TV dinner contains 21 g of protein, 59 g of carbohydrate, and 18 g of fat. What is the total number of kilojoules (kJ) of potential energy within this TV
dinner? The accepted values for potential energy are 17 kJ per gram of protein, 17 kJ per gramof carbohydrate, and 38 kJ per gram of fat.
Round your answer to the nearest tens place and with the appropriate units.

Answers

Answer:

2040 kJ

Explanation:

Step 1: Calculate the energy provided by 21 g of protein

17 kJ are provided per gram of protein.

21 g × 17 kJ/g = 357 kJ

Step 2: Calculate the energy provided by 59 g of carbohydrate

17 kJ are provided per gram of carbohydrate.

59 g × 17 kJ/g = 1003 kJ

Step 3: Calculate the energy provided by 18 g of fat

38 kJ are provided per gram of fat.

18 g × 38 kJ/g = 684 kJ

Step 4: Calculate the total energy provided by the dinner

357 kJ + 1003 kJ + 684 kJ = 2044 kJ ≈ 2040 kJ

from the following equation in which decomposition of CaCO3 takes place, give your justification. CaCO3 gives Ca +CO2 ​

Answers

Answer:

CaCO₃(s) => CaO(s) + CO₂(g) ... GpIIA Decomp

Explanation:

Metallic Carbonates decompose into a metallic oxide and carbon dioxide.

Examples:

Na₂CO₃(s) => Na₂O(s) + CO₂(g) ... GpIA Decomp

MgCO₃(s) => MgO(s) + CO₂(g) ... GpIIA Decomp

if salt and sand is mixed with distilled water, what will be the residue? and, what will be the filtrate?

Answers

Answer:

Filtration is a technique used as a remedy to separate mixes

Explanation:

If you have a sodium, then you will explore that salt dissolves but the sand is still the same.

If the salt in the resin water solution scanners, the sand remains the residue and passes through the filter paper.

All you have to do now is pleasant the salty water so that the water can evaporate, leaving the salt behind.

aromatic compounds aliphatic compounds

Answers

Answer:

I hoped it helps you fod blessed:)

Suppose of sodium iodide is dissolved in of a aqueous solution of potassium carbonate. Calculate the final molarity of sodium cation in the solution. You can assume the volume of the solution doesn't change when the sodium iodide is dissolved in it. Round your answer to significant digits.

Answers

Answer:

0.2762M Na+ in the solution

Explanation:

2.07g of sodium iodide Is Dissolved In 50.ML Of A 0.30M...

To solve this question we need to find the moles of sodium iodide, NaI, that are the same than the moles of sodium cation, Na+. The volume in liters of the solution is 0.050L. The molarity is:

Moles NaI = Moles Na+ -Molar mass NaI: 149.89g/mol-

2.07g NaI * (1mol / 149.89g) = 0.01381 moles NaI = Moles Na+

Molarity:

0.01381 moles Na+ / 0.0500L =

0.2762M Na+ in the solution

A compound, C7H13Cl, is reacted with sodium ethoxide and gives a single elimination product, C7H12. Treatment with ozone followed by zinc and water gives the compound below. Identify the original compound.
A. 2-chloro-1,1-dimethylcyclopentane.
B. 1-chloro-1,2-dimethylcyclopentane.
C. 4-chloro-1,2-dimethylcyclopentane.
D. 2-chloro-1,3-dimethylcyclopentane.

Answers

Answer:2-chloro-1,3-dimethylcyclopentane

Explanation

Suppose 20.8 g of sodium iodide is dissolved in 250. mL of a 0.70 M aqueous solution of silver nitrate. Calculate the final molarity of ALL IONS in the solution. You can assume the volume of the solution doesn't change when the sodium iodide is dissolved in it. Round your answer to 3 significant digits.

Answers

Answer:

[Ag+] = [NO3-] = 0.700M

0.555M = [Na+] = [I-]

Explanation:

To solve this question we need to find the moles of sodium iodide, NaI, using its molar mass -. With the moles and the volume we can find the molarity of Na+ and I-. The molarity of the ions of silver nitrate, AgNO3 doesn't change because we are assuming the volume doesn't change:

Molarity Ag⁺ = Molarity NO₃⁻ = 0.700M

Moles NaI -Molar mass: 149.89g/mol-

20.8g NaI * (1mol/149.89g) = 0.0139 moles NaI

Molarity:

0.0139 moles NaI / 0.250L = 0.555M = [Na+] = [I-]

The radius of a platinum atom is 139 pm. How many platinum atoms would have to be laid side by side to span a distance of 1.39 mm?

Answers

Answer:

5x10⁶ atoms of platium have to be laid side by side

Explanation:

1 atom of platium has a radius of 139pm = 139x10⁻¹²m. The distance that occupies 1 atom of platinum is 2 times its ratio:

139x10⁻¹²m*2 = 2.78x10⁻¹⁰m

Assuming there is no distance between to atoms of platinum, just its ratio. The amount of atoms necessary to occupy  1.39mm = 1.39x10⁻³m is:

1.39x10⁻³m / 2.78x10⁻¹⁰m =

5x10⁶ atoms of platium have to be laid side by side

I have an unknown volume of gas at a pressure of 0.50 atm and a temperature of 325 K. If I raise the pressure to 1.2 atm, decrease the temperature to 320 K, and measure the final volume to be 48 liters, what was the initial volume of the gas?
SHOW YOUR WORK

Answers

Answer:

the answer is 2.1 atm

Explanation:

the way people normally do it is by simply deciding the 325k with the 1.2

Why do gases act more ideal at
lower pressures?

Answers

Answer:

Gases act more ideal at lower pressure beacuse the attractive forces between molecules will decrease or become less significant compared to the empty space between them.

Explanation:

Generally, a gas behaves more like an ideal gas at higher temperature and lower pressure as the potential energy due to intermolecular forces becomes less significant compared with the particles "kinetic energy" and the size of the molecules become less significant compared to the empty space between them.

Attractive forces between molecules, decrease the pressure of a reak gas, slowing the molecules and reducing collisions with the walls.The higher the value of a gas, the greater the attraction between molecules and the more easily the gas will compress.

HOPE IT HELPS MUCH

answered by: John Glenly Pillazo Mahusay

What volume is occupied by 0.104 mol of helium gas at a pressure of 0.91 atm and a temperature of 314 K ?

Answers

Answer:

The volume will be "2.95 L".

Explanation:

Given:

n = 0.104

p = 0.91 atm

T = 314 K

Now,

The Volume (V) will be:

= [tex]\frac{nRT}{P}[/tex]

By putting the values, we get

= [tex]\frac{0.104\times 0.0821\times 314}{0.91}[/tex]

= [tex]\frac{2.6810}{0.91}[/tex]

= [tex]2.95 \ L[/tex]

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