Water put into a freezer compartment in the same refrigerator goes into a state of less molecular disorder when it freezes. Is this an exception to the entropy principle
Answer:
No it is not an exception to this principle
Explanation:
Work was carried out by this compressor to reduce the entropy of ice. What this means is that the ice gave out heat which is as a result of the work that the compressor was putting in. there are violations of this principle
the entropy principle has that the entropy of the universe is always going to be more than 0 (system + surrounding). in this question, the that of the system is negative while that of the surrounding is positive. As the refrigerator was cooling the water, the air outside was getting heated. Outside this refrigerator, the gain in entropy is more than the entropy that was lost in the water.
the entropy of the universe once again is more than 0.
What is the pH of a solution prepared by mixing 100.00 mL of 0.020 M Ca(OH)2 with 50.00 mL of 0.100 M NaOH? Assume that the volumes are additive?a. 12.78.b. 13.25.c. 12.67.d. 12.95.
Answer:
The pH of the solution is 12.78.
Explanation:
The pOH (or potential OH) is a measure of the basicity or alkalinity of a solution. The pOH is defined as the negative logarithm of the activity of the hydroxide ions. That is, the concentration of OH- ions:
pOH= - log [OH-]
On the other side, Molarity or Molar Concentration is the number of moles of solute that are dissolved in a certain volume. Molarity is calculated as:
[tex]Molarity= \frac{number of moles}{volume}[/tex]
Molarity is expressed in units: [tex]\frac{moles}{liter}[/tex]
In this case, the solution is prepared by mixing 100 ml (equal to 0.1 L, where 1000 mL = 1 L) of Ca(OH)₂ 0.020 M with 50 ml (equal to 0.05 L) of 0.100 M NaOH. Then, Ca(OH)₂ and NaOH are strong bases, so they dissociate completely. In the case of the first hydroxide, for each mole of Ca(OH)₂,
form two moles of OH-. In the case of sodium hydroxide, for each mole of hydroxide, one mole of OH- is formed. So, taking into account the definition of molarity, the number of moles of OH- that each hydroxide contributes to the solution is calculated as:
From Ca(OH)₂: 0.1 L* 0.02 M*2 = 0.004 moles
From NaOH: 0.05 L* 0.1 M= 0.005 moles
So, the amount of total moles of OH- is the sum that each hydroxide contributes to the solution: 0.004 moles + 0.005 moles= 0.009 moles
On the other hand, volumes are additive. Then: 0.1 L + 0.05 L= 0.15 L
Replacing in the definition of molarity the number of moles and the volume:
[tex][OH-]=\frac{0.009 moles}{0.15 L}[/tex]
Solving:
[OH-]= 0.06 [tex]\frac{moles}{liter}[/tex]
Replacing in the definition of pOH:
pOH= - log 0.06
pOH= 1.22
The following relationship can be established between pH and pOH:
pH + pOH= 14
Being pOH= 1.22 and replacing:
pH + 1.22= 14
pH= 14 - 1.22
pH= 12.78
The pH of the solution is 12.78.
When CH3NO2 burns in excess oxygen, it forms carbon dioxide, nitrogen dioxide and water. How many moles of oxygen are required to burn 17.10 mole(s) of CH3NO2
Explanation:
The given reaction is the combustion of CH3NO2.
The balanced chemical equation of the reaction is:
[tex]4CH_3NO_2+ 7O_2 ->4 CO_2+4NO_2+6H_2O[/tex]
So, from the balanced chemical equation, it is clear that:
4 moles of CH3NO2 --- 7 moles of oxygen gas is required.
then,
for 17.10 moles of CH3NO2 the following number of moles of oxygen is required.
[tex]The number of moles of O_2 required=17.10 mol. x \frac{7 mol}{4 mol} \\=29.925 mol[/tex]
Answer is :
29.9 mol of oxygen gas is required.
what are the angles a and b in the actual molecule of which this is a lewis structure note for advanced students give the ideal angles and don t worry about small differences from the ideal that might be caused by the fact that different electron groups may have slightly different sizes
Answer:
The answer is "120 C and 109.5 C".
Explanation:
The carbon atom is hybridized by sp2. This angle of connection thus is 120 degrees. Alkene, specifically both carbons which are in the C=C, are an instance of carbon with sp2 hybridized atom's nucleus. Those three hybridized orbits were linked to certain other atoms forming sigma connections. Its remaining 2p orbital makes a pi link with 2p orbit by the side-overlap of all the other carbon. O is hybridized inside the [-OH] Group. The optimal bond angle therefore is [tex]109.5^{\circ}[/tex].
[tex]a= 120 \ C\\\\b= 109.5 \ C[/tex]
Approximately how much energy (in kJ) would be released during the formation of the bonds in 2.00 mol of acetone molecules
Answer:
7822 kJ
Explanation:
The formula for acetone is: CH3COCH3
From the standard bond energy(enthalpy):
C - H bond = 412
C - C bond = 348
C = O bond = 743
From the structure of an acetone
C is bonded to H in six places;
so, for C- H bond = 6 × 412 = 2472
C is only bonded to two other carbon atoms
For C - C bond = 2 × 348 = 696
Carbon is only doubly bonded to an oxygen atom
For C = O bond = 1 × 743 = 743
∴
The total net energy bond in a mole = (2472 + 696 + 743) kJ/mol
= 3911 kJ/mol
Finally, in 2 moles of acetone, the required amount of energy will be:
= 3911 kJ/moles × 2 moles
= 7822 kJ
Caffeine is a bitter stimulant drug and is found in varying quantities in seeds, leaves, and so on.
a. True
b. False
Answer:
The answer Is B.....False
Please help me order these bonds urgent
Answer:
From least polar covalent to most polar covalent;
S-I< Br-Cl < N-H< Te-O
From most ionic to least ionic
Cs-F> Sr-Cl> Li- N> Al-O
Explanation:
Electro negativity refers to the ability of an atom in a bond to attract the shared electrons of the bond towards itself.
Electro negativity difference between two atoms is a key player in the nature of bond that exists between any two atoms. A large difference in electron negativity leads to an ionic bond while an intermediate difference in electro negativity leads to a polar covalent bond.
Based on electro negativity differences, the bonds in the answer have been arranged in order of increasing polar covalent nature or decreasing ionic nature.
Hazmat products warnings or labels allowed in fc
Answer:
The Hazmat products warnings or labels allowed in fc include:
1. Fully Regulated Aerosol Placard
2. Fully Regulated Flammable Solid Placard
3. Fully Regulated Flammable
4. Lithium-Ion/Metal Battery label
Explanation:
Hazmat products (including explosives, flammable liquids and solids, and gases, etc.) are classified as dangerous substances and materials that pose a risk to people during their storage, handling, or transportation. The requirement for this Hazmat classification is to show that the identified products require diligence, carefulness, and alertness in handling, transporting, and storing them. The reason for this is that mishaps can occur. Some of them can also cause fire outbreaks.
What is the fourth quantum number of the 3p electron in aluminum,
1s^2 2s^2 2p^6 3s^2 3p^1?
A. ms = -1
B. ms = +1/2
C. ms=0
D. ms = +1
Explanation:
here's the answer to your question
The quantum numbers are defined as the set of four numbers with the help of which we can get complete information about the electrons in an atom. The fourth quantum number is the spin quantum number. Here ms for 3p electron in 'Al' is ms = + 1/2. The correct option is B.
The quantum number which describes the spin orientation of the electron is defined as the spin quantum number. Since the electron can spin only in two ways, clockwise and anti-clockwise, the spin quantum number can have either the value +1/2 or -1/2 depending upon the direction of spin.
Thus for 3p electron in 'Al' ,ms is option B.
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In a first order reaction 40% of reactant gets converted into product in 30 minutes. What time would it require to convert 75% into product?
In a first order reaction 40% of reactant gets converted into product in 30 minutes. The time would it require to convert 75% into product is 81.57 minutes.
What is first order reaction?First order reaction is defined as a chemical reaction in which the concentration of just one ingredient directly affects the pace of the reaction. If the first-order reactant concentration is doubled in these reactions, the reaction rate will likewise double. Chemical reactions classified as first order kinetics have rates of reaction that depend on the molar concentration of one component.
First order reaction = 2.303 / t log a / (a-x)
k = 2.303 / 30 log 100 (100 - 40)
k = 0.0767 log 1.66
k = 0.017 min⁻¹
The time required to convert 75 % product
t = 2.303 / 0.017 log 100 (100 - 75)
t = 135.5 log 4
t = 135.5 x 0.602
t = 81.57 minutes
Thus, in a first order reaction 40% of reactant gets converted into product in 30 minutes. The time would it require to convert 75% into product is 81.57 minutes.
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Name the functional group in the
following molecule:
Answer:
B. Aromatic
Explanation:
Functional groups are groups that differentiate a specific organic compound from others. A functional group determines the chemical property of the compound that possesses it.
For example, just like alkene and alcohol functional groups have characteristics double bond (=) and hydroxyl (OH) group respectively, the image in the attachment of this question has a BENZENE RING at the core of its structure, hence, the organic compound can be regarded to have an AROMATIC FUNCTIONAL GROUP.
Answer:
(B) aromatic
Explanation:
A step by step explanation
Explain how the existence of isotopes relates to the number of neutrons within the nuclei of an element.
Answer:
because of it less attraction and its neutral position
Answer:
The existence of isotopes relates to the number of neutrons within the nuclei of an element because isotopes contain the same amount of protons (based on what element they are) but different number of neutrons in their nuclei. Because they have a different amount of neutrons, than the original element
,they also have a different atomic mass.
Explanation:
hope it helps!
Determine the molecular formula of a compound if it is composed of 40.92% carbon, 4.58% hydrogen, and 54.50% oxygen. The molar mass is 176.12 g/mol.
A) C3H8O3.
B) CH2O.
C) C2H3O2.
D) C3H4O3.
Answer:
No correct answer listed. See explanation for defense.
Explanation:
Given
C: 40.92% => 40.92g/100wt => (40.92/12)moles C = 3.41 moles O
H: 4.58% => 4.58g/100wt => (4.58/1)moles H = 4.58 moles H
O: 54.50% => 54.5g/100wt => (54.5/16)moles O = 3.41 moles O
Empirical ratio => C : H: O => (3.41/3.41) : (4.58/3.41) : (3.41/3.41) => 1 : 1.34 : 1
=> C : H : O => 3(1 : 1.34 : 1) => 3 : 4 : 3 => Empirical Formula C₃H₄O₃
Molecular Weight = Empirical Formula Wt x N
176.12 = 88 x N
N = whole number multiple of empirical formula = 176.12/88 = 2
∴ Molecular Formula => (C₃H₄O₃)₂ => C₆H₈O₆
Note => Only ionic compounds (salts) have subscripts reduced to lowest whole number ratios. Molecular compounds as C₆H₈O₆ are not reduced to lowest whole number ratios. Therefore, there is no correct answer in the answer choice list for the 'Molecular Formula'. Doc :-)
the -OH group cannot exhibit inductive effect? true/false, and reason for ur choice
Answer:
false
Explanation:
The inductive effects are know as the ability of the atom or a group to create polarization and electronic density long the covalent bond and it needs a higher density. The -OH group cannot exhibit the indictive effects as it becomes --O.Consider the reaction: CaCO3(s)CaO(s) CO2(g) Using standard absolute entropies at 298K, calculate the entropy change for the system when 1.58 moles of CaCO3(s) react at standard conditions.
Answer:
the entropy change for the system when 1.58 moles of CaCO3(s) react at standard conditions is 253.748 J/K
Explanation:
Given the data in the question;
CaCO₃(s) → CaO(s) + CO₂(g)
1.58 moles 1.58 moles 1.58 moles
Since 1 mole of CaCO₃ gives 1 mole of CaO and 1 mole of CO₂
Thus, 1.58 mole of CaCO₃ gives 1.58 moles of CaO and 1.58 moles of CO₂.
Now,
At 298 K, standard entropy values are;
ΔS° ( CaCO₃ ) = 92.9 J/mol.K
ΔS° ( CaO ) = 39.8 J/mol.K
ΔS° ( CO₂ ) = 213.7 J/mol.K
So,
ΔS°[tex]_{system[/tex] = ∑ΔS°( product ) - ∑ΔS°( reactant )
ΔS°[tex]_{system[/tex] = [ ΔS°(CaO) + ΔS°( CO₂ ) ] - ΔS°( CaCO₃ )
we substitute
ΔS°[tex]_{system[/tex] = [ 39.8 J/mol.K + 213.7 J/mol.K ] - 92.9 J/mol.K
ΔS°[tex]_{system[/tex] = 160.6 J/mol.K
i.e, for 1 mol CaCO₃, ΔS°[tex]_{system[/tex] = 160.6 J/mol.K
Now, for 1.58 mol CaCO₃,
ΔS°[tex]_{system[/tex] = 1.58 mol × 160.6 J/mol.K
ΔS°[tex]_{system[/tex] = 253.748 J/K
Therefore, the entropy change for the system when 1.58 moles of CaCO3(s) react at standard conditions is 253.748 J/K
Flag A solution of the weak acid, HF, and a solution of the strong acid, HCl, have the same pH. Which solution will require the most sodium hydroxide, NaOH, to neutralize
Answer:
C) Both will require the same amount because the concentrations are equal.
Explanation:
The pH of a solution is defined as:
pH = -log [H+]
This H+ is the ion that reacts with OH- (From NaOH) as follows:
H+ + OH- → H2O
When all H+ reacts, we can say the solution was neutralized.
Now, as both, the solution with the weak acid and the solution with strong acid have the same pH, we can say that their [H+] is the same. Assuming the volume of both solutions is the same:
Both will require the same amount because the concentrations are equal.
Categorize the following reaction as an acid-base neutralization, precipitation, combination, decomposition, combustion, displacement, or disproportionation reaction.
Ba(C2H3O2)2(aq) + Na2CO3(aq) → BaCO3(s) + 2 NaC2H3O2(aq)
Answer:
Precipitation
Explanation:
Let's consider the balanced chemical equation between barium acetate and sodium carbonate to form barium carbonate and sodium acetate.
Ba(C₂H₃O₂)₂(aq) + Na₂CO₃(aq) → BaCO₃(s) + 2 NaC₂H₃O₂(aq)
Both products and reactants are salts. But, among the products, barium carbonate is solid. This allows us to classify it as a precipitation reaction.
For the reaction of oxygen and nitrogen to form nitric oxide, consider the following thermodynamic data :
ΔH∘rxn 180.5kJ/mol
ΔS∘rxn 24.80J/(mol⋅K)
Required:
a. Calculate the temperature in kelvins above which this reaction is spontaneous
b. Calculate the equilibrium constant for the following reaction at room temperature, 25°C
Answer:
a. 7278 K
b. Kc = 4.542 × 10⁻³¹
Explanation:
a.
The reaction is spontaneous when ΔG° < 0. We can calculate ΔG° using the following expression.
ΔG° = ΔH° - T × ΔS°
Then, the reaction will be spontaneous when,
ΔH° - T × ΔS° < 0
T > ΔH°/ΔS
T > (180.5 × 10³ J/mol)/(24.80J/mol⋅K)
T > 7278 K
b.
First, we will calculate ΔG° at 25 °C (298 K)
ΔG° = ΔH° - T × ΔS°
ΔG° = (180.5 × 10³ J/mol) - 298 K × (24.80J/mol⋅K) = 1.731 × 10⁵ J/mol
Then, we will calculate the equilibrium constant (Kc) using the following expression.
ΔG° = - R × T × ln Kc
-ΔG°/R × T = ln Kc
-(1.731 × 10⁵ J/mol)/(8.314 J/mol.K) × 298 K = ln Kc
Kc = 4.542 × 10⁻³¹
What is the concentration (M) of Ch3OH a solution prepared by dissolving of CH3OH sufficient water to give exactly 230 of solution?
Answer:
1.59 M
Explanation:
What is the concentration (M) of CH₃OH a solution prepared by dissolving 11.7 g of CH₃OH sufficient water to give exactly 230 mL of solution?
Step 1: Given data
Mass of CH₃OH: 11.7 gVolume of solution: 230 mL (0.230 L)Step 2: Calculate the moles corresponding to 11.7 g of CH₃OH
The molar mass of CH₃OH is 32.04 g/mol.
11.7 g × 1 mol/32.04 g = 0.365 mol
Step 3: Calculate the molarity of the solution
M = moles of solute / liters of solution
M = 0.365 mol / 0.230 L = 1.59 M
Enzyme catalyzing breakdown of atp to adp
Answer:
ATP hydrolase
Explanation:
Enzymes are biological catalysts which perform diverse functions in the body. Enzymes are specific in their mode of action because an enzyme fits into its substrate as a key fits into a lock.
The particular enzyme that catalyzes the breakdown of ATP to ADP is ATP hydrolase. The phosphate released by the action of this enzyme is used in the phosphorylation of other compounds thereby making them more reactive.
1. Why is it necessary to equalize the pressure(i.e, have the water level the same in each tube) before taking a volume reading?
2. Why is it important to use water that has been pre-saturated with CO2 in the gas burettes?
3.If your antacid sample had been contaminated by moisture, what effect(if any )would you expect this to have on your result
4.Explain why an'antacid is called as such,what is the role of the NAHCO3 or CACO3 in reactions?
Answer:
If you contact water with a gas at a certain temperature and (partial) pressure, the concentration of the gas in the water will reach an equilibrium ('saturation') according to Henry's law.
Explanation:
This means: if you increase the pressure (e.g. by keeping the vial closed), the CO2 concentration will increase. So it simply depends what concentration you need for your assay: 'CO2-saturated' water at low pressure or 'CO2-saturated' water at high pressure.
Predict the Normality of H2SO4 if 75 ml of 96.6 % pure H2SO4 added to 425 ml water. The density of H2SO4 is 1.83 g/cm3?
Explanation:
Normality is one of the concentration terms.
It is expressed as:
[tex]N=\frac{mass of the substance}{equivalent mass}* \frac{1}{volume of solution in L.}[/tex]
The volume of the solution is 425 mL.
Mass of sulfuric acid given is:
[tex]mass=volume * purity* density\\ = 75 mL * 0.966 * 1.83 g/mL\\\\=132.5 grams\\[/tex]
The equivalent mass of sulfuric acid is 49.0g/equivalents
Hence, the normality of the given solution is:
[tex]N=\frac{132.5g}{49.0g/equi.} *\frac{1000}{425mL} \\Normality=6.36N[/tex]
Answer is: 6.36N.
Write the separation scheme for the isolation of triphenylmethanol from the reaction mixture once the reaction is complete. The separation begins after the addition of HCl and water to the reaction and includes the column chromatography procedure to further purify crude triphenylmethanol isolated in the day 1 procedure.
````````````````````
What is the oxidation state of nitrogen in N ?
Answer:
+5
Explanation:
The diagram above shows the hydrides of groups 14, 15, 16, and 17 elements. Why does H20, HF, and NH3 have much higher boiling points than the rest of the molecules in their groups?
Answer:
Hydrogen Bonding
Explanation:
Hydrogen Bonding occurs when a hydrogen atom is bonded to N, O, and F atoms.
The molecules H₂O, HF, and NH₃ all experience hydrogen bonding, which is a relatively strong IMF, causing the molecules to have stronger attraction to each other. Having a stronger attraction between molecules results in more energy required to separate them, thus these molecules will have a higher boiling point than the rest of the molecules in their group.
Name the following molecule
Answer:
It is a Biological Molecule
how does iron I differ from iron II
Answer:
Metals tend to form positive oxidation states. Here, Iron (I) has an oxidation state of +1 while Iron (II) has an oxidation state of +2. Similarly, Lead (I) has an oxidation state of +1 while Lead(II) has an oxidation state of +2. A change in oxidation state can rather cause significant changes in the compound.
A researcher is attempting to produce ethanol using an enzyme catalyzed batch reactor. The ethanol is produced from corn starch by first-order kinetics with a rate constant of 0.05 hr-1. Assuming the concentration of ethanol initially is 1 mg/L, what will be the concentration of ethanol (in mg/L) after 24 hours
Answer:
The correct solution is "3.32 gm/L".
Explanation:
Given:
Rate constant,
[tex]K = 0.05 \ hr^{-1}[/tex]
Time,
[tex]t = 24 \ hours[/tex]
Concentration of ethanol,
[tex]C_o= 1 \ mg/L[/tex]
Now,
The concentration of ethanol after 24 hours will be:
⇒ [tex]C_o=C\times e^{-K\times t}[/tex]
By putting the values, we get
[tex]1=C\times e^{-0.05\times 24}[/tex]
[tex]1=C\times 0.30119[/tex]
[tex]C= 3.32 \ gm/L[/tex]
A rigid, sealed container that can hold 26 L of gas is filled to a pressure of
5.97 atm at 374 °C. The pressure suddenly decreases to 3.64 atm. What is
the new temperature inside the container, in units of °C?
Answer:
121 °C
Explanation:
From the question given above, the following data were obtained:
Initial pressure (P₁) = 5.97 atm
Initial temperature (T₁) = 374 °C
Final pressure (P₂) = 3.64 atm
Final temperature (T₂) =?
NOTE: Volume = constant
Next, we shall convert 374 °C to Kelvin temperature. This can be obtained as follow:
T(K) = T(°C) + 273
Initial temperature (T₁) = 374 °C
Initial temperature (T₁) = 374 °C + 273
Initial temperature (T₁) = 647 K
Next, we shall determine the final temperature. This can be obtained as follow:
Initial pressure (P₁) = 5.97 atm
Initial temperature (T₁) = 647 K
Final pressure (P₂) = 3.64 atm
Final temperature (T₂) =?
P₁ / T₁ = P₂ / T₂
5.97 / 647 = 3.64 / T₂
Cross multiply
5.97 × T₂ = 647 × 3.64
5.97 × T₂ = 2355.08
Divide both side by 5.97
T₂ = 2355.08 / 5.97
T₂ = 394 K
Finally, we shall convert 394 K to celsius temperature. This can be obtained as follow:
T(°C) = T(K) – 273
Final temperature (T₂) = 394 K
Final temperature (T₂) = 394 – 273
Final temperature (T₂) = 121 °C
Thus, the new temperature is 121 °C
Suppose we have two rock samples, A and B. Rock A was subject to both physical and chemical weathering while rock B was subject to chemical weathering only. Which rock would experience more chemical weathering? Why? (2pts) (Hint: consider the effect of surface area on the rate of chemical weathering)
Answer:
Rock A will have far more chemical weathering than Rock B due to the rise in area effect
Explanation:
Rock A undergoes both Physical and Chemical weathering. So, thanks to physical weathering there'll appear cracks within the rock, which can, in turn, increase the area of rock on which weathering is occurring. So, Chemical weathering will happen much faster now as there's a rise in the area. within the case of Rock B, there's only chemical weathering therefore the increase in the area won't be that very much like compared to Rock A.
