The reaction can be solved as reaction 1 :-HPO²¯ + H+ − H₂ + PO²¯ reaction 2: -HPO²¯ +OH¯ ⇒ H₂O + PO²¯
What is Brønsted–Lowry reactions. ?
Brønsted–Lowry reactions are a type of acid-base reaction in which an acid donates a proton (H+) to a base, which then accepts the proton. The Brønsted–Lowry theory defines an acid as a species that donates a proton, while a base is a species that accepts a proton.
In a Brønsted–Lowry acid-base reaction, the acid and base always exist in a conjugate acid-base pair, which are related to each other by the transfer of a proton. For example, in the reaction:
HA + B- → A- + HB
HA is the acid and donates a proton to B-, which is the base. The product A- is the conjugate base of the acid HA, and the product HB is the conjugate acid of the base B-.
Brønsted–Lowry reactions are an important concept in chemistry and are used to explain many types of reactions, including acid-base titrations, buffer solutions, and chemical equilibria.
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Thermochemistry Modified Portfolio Questions
Please help with these questions
1. Describe each part of the equation. (Look at the pdf/picture for the equation)
Heat gained or lost = Specific Heat x Mass x Change in Temperature
- Specific Heat:
- Mass:
- Change in Temperature:
2. Identify the following statements as either Heat, Thermal Energy, or Temperature
- __________ is the total heat found on the inside of a sample of matter.
- __________ is the flow of thermal energy from one loaction to another.
- __________ is the measure of average kinetic energy of the particles in a sample of matter, it is also a measure of the hotness or coldness of an object in simpler terms.
Thermal Energy is the total heat found on the inside of a sample of matter.
Heat is the flow of thermal energy from one location to another.
Temperature is the measure of average kinetic energy of the particles in a sample of matter.
What are the parts of the equation?The equation Heat gained or lost = Specific Heat x Mass x Change in Temperature is used to calculate the amount of heat gained or lost by a substance when its temperature changes.
Heat gained or lost: This is the energy that is either absorbed or released by a substance as it undergoes a temperature change. The unit of heat is joule (J) in SI units or calorie (cal) in other systems.
Specific Heat: This is a measure of the amount of heat energy required to raise the temperature of a given amount of a substance by one degree Celsius (or Kelvin). The unit of specific heat is J/g °C (or J/g K).
Mass: This refers to the amount of substance being heated or cooled, measured in grams (g).
Change in Temperature: This is the difference between the final and initial temperatures of the substance, measured in Celsius or Kelvin (°C or K).
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how is the atomic number of an atom determined? view available hint(s)for part a how is the atomic number of an atom determined? counting the number of atoms of an element in a mineral counting the number of protons circling the nucleus counting the number of protons in the nucleus counting the number of neutrons in the nucleus counting the number of protons and neutrons in the nucleus
The atomic number of an atom is determined by counting the number of protons in the nucleus. This is because the atomic number is defined as the number of protons in an atom's nucleus.
What is atomic number?
The atomic number is the number of protons in an atom. The periodic table is arranged according to atomic number, which determines the chemical properties of an element. All neutral atoms of a given element have the same number of protons and electrons.
A neutral atom has an equal number of positively charged protons and negatively charged electrons, which results in no overall charge.The electron arrangement in an atom determines how it will interact with other atoms. The element's chemical properties are determined by the electron configuration of its atoms.
The number of protons in the nucleus determines the element's atomic number, which is a fundamental property of the element. The atomic number identifies the element and its position on the periodic table.
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true/ false: the main form of ketones present in the blood is called acetoacetate (select one word answer only please)
The sentence "The main form of ketones present in the blood is called acetoacetate" is True.
Acetoacetate is one of the three ketone bodies produced in the human liver. The other two ketones are beta-hydroxybutyrate and acetone.
What are ketones? Ketones are substances that are formed when the body breaks down fat for energy when glucose, which is the body's main source of energy, is scarce.
The liver synthesizes ketones from fats as a backup source of fuel when the body runs out of glucose.
A high concentration of ketones in the bloodstream is known as ketosis, and it can occur when a person is fasting, dieting, or has uncontrolled diabetes.
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A chemist dissolves 551. mg of pure barium hydroxide in enough water to make up 180. mL of solution. Calculate the pH of the solution. (The temperature of the solution is 25 °C.) Be sure your answer has the correct number of significant digits.______.
The pH of the solution of 551 mg of Barium Hydroxide and 180 mL water is 12.6.
What is a solution?A solution in chemistry is a specific kind of homogenous mixture made up of two or more components.
A solute is a material that has been dissolved in the solvent in such a combination.
The first step is to calculate the molarity of the barium hydroxide solution. We can use the formula:
Molarity (M) = moles of solute / volume of solution (in liters)
The molar mass of barium hydroxide [Ba(OH)²] is 171.34 g/mol. Therefore, the number of moles of Ba(OH)² in 551 mg (0.551 g) can be calculated as:
moles of Ba(OH)² = mass / molar mass = 0.551 g / 171.34 g/mol = 0.003214 mol
The volume of the solution is 180 mL, which is equivalent to 0.180 L. Therefore, the molarity of the barium hydroxide solution is:
Molarity = 0.003214 mol / 0.180 L = 0.01786 M
Barium hydroxide is a strong base that completely dissociates in water to give barium ions (Ba²) and hydroxide ions (OH⁻):
Ba(OH)²⁺ (s) → Ba²⁺ (aq) + 2OH⁻ (aq)
In an aqueous solution, the hydroxide ions can react with water to produce hydroxide ions and hydronium ions (H₃O⁺):
OH⁻ (aq) + H₂O (l) → H₃O⁺ (aq) + OH⁻- (aq)
Since the concentration of OH- ions in the solution is twice the concentration of Ba(OH)₂, we can use the following equation to calculate the hydroxide ion concentration:
[OH-] = 2 x Molarity of Ba(OH)₂ = 2 x 0.01786 M = 0.0357 M
Now, we can use the equation for the ion product constant of water to calculate the hydronium ion concentration:
Kw = [H₃3O⁺][OH⁻] = 1.0 x 10⁻¹⁴
[H₃O⁺] = Kw / [OH⁻] = 1.0 x 10⁻¹⁴ / 0.0357 = 2.801 x 10⁻¹³ M
Finally, we can calculate the pH of the solution using the equation:
pH = -log[H₃O⁺] = -log(2.801 x 10⁻¹³) = 12.552
Therefore, the pH of the solution is 12.6 (rounded to one decimal place).
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what is the correct order of the five para substituents on the carbocation intermediate, if arranged from most stabilizing to least stabilizing?
The correct order of the five para substituents on the carbocation intermediate, if arranged from most stabilizing to least stabilizing is as follows:1) Methoxy group (-OCH3): Methoxy group is an electron-donating group that has a stabilizing effect on carbocation.2) Alkyl groups (-CH3, -C2H5).
These groups also have an electron-donating effect, but their effect is less than that of methoxy.3) Halogens (-F, -Cl, -Br, -I): These are electron-withdrawing groups, but their inductive effect is much weaker than their mesomeric effect. The mesomeric effect of halogens is electron-donating, which compensates for their inductive electron-withdrawing effect.4) Nitro group (-NO2): Nitro is a strongly electron-withdrawing group that destabilizes carbocation.5) Carbonyl group (-COCH3): Carbonyl is also an electron-withdrawing group that destabilizes carbocation.
They are formed by the loss of a leaving group from a substrate, leaving behind a positively charged carbon atom. The stability of the carbocation intermediate is influenced by the nature of the substituents attached to the carbon atom. Substituents can be electron-donating or electron-withdrawing, depending on their effect on the carbocation.The most stabilizing substituents are electron-donating groups, such as methoxy (-OCH3) and alkyl groups (-CH3, -C2H5). These groups donate electrons to the carbocation, which increases its stability. Halogens (-F, -Cl, -Br, -I) are also electron-donating, but their mesomeric effect is stronger than their inductive effect. This means that their overall effect is electron-donating, but weaker than that of methoxy and alkyl groups.
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why do reversible reactions always result in chemical equilibria
Reversible reactions always result in chemical equilibria because the rate of the forward reaction is equal to the rate of the reverse reaction at equilibrium.
The chemical equilibrium is the state where there is no net change in the concentrations of the reactants and products. Example: Consider the reversible reaction, N2(g) + 3H2(g) ⇋ 2NH3(g)This is the Haber process, which is an important industrial reaction for producing ammonia from nitrogen and hydrogen gases. In this reaction, nitrogen and hydrogen gases react to form ammonia gas, and ammonia gas can also break down into nitrogen and hydrogen gases. Hence, it is a reversible reaction. When the reaction begins, both the forward and reverse reactions occur at different rates. Initially, the rate of the forward reaction is high, and the rate of the reverse reaction is low, resulting in the accumulation of ammonia gas. As the concentration of ammonia gas increases, the rate of the forward reaction decreases, and the rate of the reverse reaction increases. Eventually, the rates of the forward and reverse reactions become equal, resulting in the formation of a chemical equilibrium. The Haber process reaches equilibrium when the rate of the forward reaction (formation of ammonia) is equal to the rate of the reverse reaction (breakdown of ammonia). At equilibrium, there is no net change in the concentrations of nitrogen, hydrogen, and ammonia gases, and the reaction quotient (Qc) is equal to the equilibrium constant (Kc). Hence, reversible reactions always result in chemical equilibria.
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Did the control experiment verify or refute the results from exercise 1? use your results from exercises 1 and 2 to validate your answer.
Experiment 1 E Data Table 1 B Data Table 2 Data Table 1: Antacid Neutralization Data Mass of 0. 59 Crushed Antacid (9) Concentration 1. 0 of HCI (M) Volume HCI 5. 0 (mL) Concentration 1. 0 of NaOH (M) Initial NaOH 9. 4 mL Volume (mL) Final NaOH 8. 2 mL Volume (mL) Total Volume 1. 2 mL of NaOH Used (mL) Experiment 1 Data Table 1 Data Table 2 Data Table 2: Experimental Results I 0. 1825 g 0. 0012 HCl available for neutralization (g): Moles of NaOH required to reach stoichiometric point (mol): HCI neutralized by antacid (g): НСІ neutralized per gram of antacid (9) 0. 1387 0. 2774 Experiment 2 El Data Table 3 B Data Table 4 Data Table 3: Control Experiment Data Concentration 1. 0 of HCI (M) Volume HCI 5. 0 (mL) Concentration 1. 0 of NaOH (M) Initial NaOH 9. 2 mL Volume (mL) Final NaOH 3. 6 mL Volume (mL) Total Volume 5. 6 mL of NaOH Used (mL) Data Table 4: Control Experiment Results 0. 2049 Moles of 0. 0056mol NaOH needed to neutralize 5. 0 mL of 1. OM HCI (mol): Grams of HCI neutralized (g): NaOH 4. 4mL volume difference between back titration and control (ml): Grams of 0. 160g HCI neutralized by NaOH volume difference (9)
Volume difference between back titration and controlHCI neutralized by NaOH volume difference is 0.0056 moles.
Given,
* Mass of Antacid = 0.5g
* [HCl] = 1M
* [tex]V_{HCl}[/tex] = 5 ml (pipetted out)
* [NaOH] = 1M
* [tex]V_{NaOH}[/tex] - 1.2 ml (consumed)
* Amt. of HCl avaliable for neutralisation = 0.1825 g
* No. of moles of NaOH req. to reach eq. point = 0.0012
* Amt. of HCl neutralised by antalid = 0.1387 g
* Amt. of HCl neutralised by antalid = 0.1387 g
* Amt. of HCl neutralised per gram of antalid = 0.1387 g
Solution: [tex]([/tex][tex]N[/tex] × [tex]V[/tex][tex])_{HCl}[/tex] = [tex]([/tex][tex]N[/tex] × [tex]V[/tex][tex])_{NaOH}[/tex]
(1 x 5 ) = [tex]([/tex][tex]1[/tex] × [tex]V[/tex][tex])_{NaOH}[/tex]
= [tex]V(NaOH)[/tex] = ( 1 x 5) / 1 = 5ml
In control expt. data [tex]V(NaOH)[/tex] = 5.6ml
But in given data, [tex]V(NaOH)[/tex] = 1.2ml
So, Volume diff. of NaOH between back titration and control = 5.6 - 1.2 = 4.4ml
So, given follows
So, 4.4 ml of HCl means,
its Conc. will be equal to, 4.4 x 36.5 / 1000 = 0.1606 g
This is correct in control expt. results
In control expt. data, [tex]V(NaOH)[/tex] = 5.6ml
This corresponds to 5.6 x 40 / 1000 = 0.224g
This correspond to 0.224 / 40 = 0.0056 moles
This is correct in control expt. results.
Titration is a laboratory technique used to determine the concentration of an unknown solution by reacting it with a known solution. It is a quantitative method used to determine the amount of a substance in a sample. Titration is often used in chemistry to determine the concentration of acids, bases, and salts.
In a titration, a measured amount of the unknown solution is slowly added to a known solution of a substance with a known concentration called the titrant. The titrant is added until the reaction is complete, and a color change or other observable change occurs. The point at which the reaction is complete is known as the endpoint, and it is usually determined using an indicator, which changes color when the reaction is complete.
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silver nitrate can inhibit the amylase reaction by?
By severing disfluid connections, silver nitrate can prevent the amylase reaction from happening. Wheat flour's -amylase can be prevented from working by adding silver nitrate (AgNO₃).
As silver nitrate is a non-competitive inhibitor that disrupts the folding of the enzyme, it should be the most efficient in inhibiting amylase at 37°C if different inhibitors are tried with amylase to quantify the quantities of free-reducing sugars.
Accurate evaluation of the pasting qualities of wheat flour is hampered by endogenous -amylase. When rice flour with a medium to high amylose content is gelatinized, the capacity of silver nitrate (AgNO₃) solutions at seven various concentrations (0.001-0.1 m) to inhibit -amylase activity is compared with a deionized water (dH₂O) control (AC). Using a Quick Visco Analyzer, pasting characteristics are evaluated (RVA).
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how many total valence electrons are present in a molecule of PCl3 ?
The total number of valence electrons that are present in a molecule of PCl3 is 26.
PCl3 stands for Phosphorus Trichloride. The molecular structure of PCl3 is trigonal pyramidal. It has three chlorine atoms and one phosphorus atom, which are bonded by three covalent bonds.
In order to determine the total number of valence electrons in PCl3, first we have to Count the valence electrons present in each atom. Phosphorus has 5 valence electrons. Chlorine has 7 valence electrons then Add the valence electrons from each atom.
P = 5 e- (phosphorus has 5 valence electrons)
Cl = 7 e- (chlorine has 7 valence electrons)
Total valence electrons in PCl3 = 5 + 7 × 3 = 5 + 21 = 26.
Therefore, there are 26 valence electrons in a molecule of PCl3.
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Atomic weight of Boron is 10.81 and it has 2 isotopes 5B10 and 5B11, then the ratio of 5B10:5B11 in nature would be 1. 15:16 2. 10:11 3. 19:81 4. 81:19
The atomic weight of Boron is 10.81 and it has two isotopes 5B10 and 5B11. The ratio of 5B10:5B11 in nature would be 10:11. Correct answer is option 2
The isotopes of an element have the same atomic number, indicating that they have the same number of protons in their nucleus, but a different atomic mass, indicating that they have a different number of neutrons in their nucleus. Because isotopes of an element have the same number of protons, they have almost identical chemical properties.
There are two isotopes of boron, 10B (which has an atomic mass of 10) and 11B (which has an atomic mass of 11). Boron has an atomic weight of 10.81. Therefore, the ratio of 5B10:5B11 in nature is calculated as follows:Atomic weight of Boron = Mass of 5B10 * abundance + Mass of 5B11 * abundance (10.81) = (10 * x) + (11 * y) [where x = abundance of 5B10 and y = abundance of 5B11]
Therefore, x + y = 1On solving the above two equations we get the abundance 5B10 as 0.199 and abundance of 5B11 as 0.801. The ratio of 5B10:5B11 in nature would be 10:11. Therefore, option 2. 10:11 is the correct answer.
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How does the number of dissolved ions in solution affect the boiling point of that solution?
A solution's boiling point rises as the amount of dissolved ions increases because more energy is needed to overcome greater intermolecular interactions that occur between the ions and solvent molecules.
The intermolecular interactions between the molecules of the solute and solvent are impacted when a solute is dissolved in a solvent. When it comes to ionic solutes, the ions separate and create ion-dipole interactions with the solvent molecules. In non-ionic solutions, these interactions are more potent than the dipole-dipole and London dispersion forces. Because the intermolecular interactions in a solution with more dissolved ions are stronger, more energy is needed to overcome them and reach the boiling point. The van 't Hoff factor, which measures the amount of ions created by each solute molecule, and the molality of the solution are used to quantify the boiling point elevation impact.
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Calculate the acid ionization constant (Ka) for the acid. Express your answer using two significant figures. IVO AO ? K. = Submit Request Answer A 0.120 M solution of a weak acid (HA) has a pH of 3.28. You may want to reference (Pages 737 - 745) section 16.6 while completing this problem.
Answer : The acid ionization constant (Ka) for the given acid HA is 1.1 x 10^(-5), rounded to two significant figures.
To calculate the acid ionization constant (Ka) for the given acid HA, we must first find its pH using the given concentration of the solution. Then, we can use the pH to find the concentration of H+ ions in the solution. Finally, we can plug these values into the expression for Ka to solve for the acid ionization constant.
The pH of the 0.120 M solution of HA is given to be 3.28. This means that [H+] = 10^(-pH) = 10^(-3.28) = 5.01 x 10^(-4) M.
Now, we can use the expression for Ka: Ka = [H+][A-]/[HA], Since HA is a weak acid, we can assume that it dissociates as follows: HA + H2O ⇌ H3O+ + A- This means that [A-] = [H3O+], and [HA] = initial concentration of the acid (0.120 M) - [H3O+].
Substituting these values, we get: Ka = (5.01 x 10^(-4) M)^2 / (0.120 M - 5.01 x 10^(-4) M) = 1.1 x 10^(-5). Therefore, the acid ionization constant (Ka) for the given acid HA is 1.1 x 10^(-5), rounded to two significant figures.
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What volume will 3.50 mol of ammonia gas occupy at conditions of standard temperature pressure?
A 5.41L
B 10.5 L
C 78.4L
D 7,940L
Answer:
C - 78.4L
Explanation:
Took the test.
which of the compounds of h2c2o4 , ca(oh)2 , koh , and hi , behave as acids when they are dissolved in water?
The compounds of H2C2O4 (oxalic acid), Ca(OH)2 (calcium hydroxide), and KOH (potassium hydroxide) all behave as acids when they are dissolved in water. HI (hydrogen iodide) is an inorganic compound and will not behave as an acid when dissolved in water.
Out of the compounds of H2C2O4, Ca(OH)2, KOH, and HI, the only acid is HI (Hydroiodic acid).Explanation:The strength of an acid is determined by its ability to donate a proton (H+). When an acid is dissolved in water, it dissociates and releases hydrogen ions (H+), which contribute to the acidic nature of the solution. HI (Hydroiodic acid) is the only acid among H2C2O4, Ca(OH)2, KOH, and HI.Calcium hydroxide (Ca(OH)2) and potassium hydroxide (KOH) are strong bases that are completely ionized in water. As a result, they dissociate and release hydroxide ions (OH-) into the solution, making it alkaline. Oxalic acid, which is H2C2O4, is a dicarboxylic acid with a chemical structure of HOOC-COOH. It is a weak organic acid that is used to clean equipment in laboratories.HI (Hydroiodic acid) is a hydrogen halide compound that is soluble in water. It is a strong acid that dissociates completely in water, releasing hydrogen ions (H+). When HI is dissolved in water, it acts as an acid and increases the acidity of the solution. Therefore, the correct answer is that HI (Hydroiodic acid) behaves as an acid when dissolved in water.
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H2C2O4, also known as oxalic acid, is a weak organic acid that behaves as an acid when dissolved in water. In aqueous solution, it donates H+ ions to the water, resulting in an acidic solution.
Ca(OH)2 and KOH are both strong bases and do not behave as acids when dissolved in water. They accept H+ ions from water to form OH- ions, resulting in a basic solution.HI, also known as hydroiodic acid, is a strong acid that behaves as an acid when dissolved in water. It dissociates completely in water, producing H+ ions and I- ions.In summary, H2C2O4 and HI behave as acids when dissolved in water, while Ca(OH)2 and KOH behave as bases. The behavior of a compound in water is determined by its chemical properties, such as the strength of its acid or base character, and its ability to donate or accept H+ ions.For such more question on oxalic acid
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a molecular cloud fragments as it collapses because density variations from place to place grow larger as the cloud collapses.truefalse
The given statement a molecular cloud fragments as it collapses because density variations from place to place grow larger as the cloud collapses is true because as the cloud collapses, denser regions attract more matter from the surrounding regions, causing density variations to grow larger and eventually become unstable, leading to the fragmentation of the cloud into smaller clumps.
As a molecular cloud collapses, it can fragment into smaller clumps due to density variations. The collapse of a molecular cloud is primarily driven by gravity, but there are other factors such as turbulence, magnetic fields, and thermal pressure that can affect the process. As the cloud collapses, the denser regions can attract more matter from the surrounding regions, causing density variations to grow larger. These density variations can eventually become unstable and lead to the fragmentation of the cloud into smaller clumps, which can further collapse to form stars or star systems. This process is known as hierarchical fragmentation and is an important part of the formation of stars and galaxies in the universe.
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Which of the following complexes will absorb a photon with the lowest energy?
Group of answer choices
A. [Co(OH)6]3-
B. [Co(SCN)6]3-
C. [Co(NO2)6]3-
The complex that will absorb a photon with the lowest energy is [Co(OH)6]3-. The correct answer is option A
Co(OH)6]3- is the complex that absorbs a photon with the lowest energy. It is because of the crystal field effect. The complex [Co(OH)6]3- has the lowest energy for the d-electrons of the cobalt ion. A photon is an elementary particle that forms a light beam. It has a small mass and no charge. A photon has wave-particle duality, which means it exhibits properties of both a wave and a particle. Photons are electromagnetic radiation particles, which means they have both electric and magnetic components.
The lowest energy is defined as the minimum energy that a system can have. It is the energy state that is energetically stable. Photons have energy, and the energy of the photon is directly proportional to its frequency. The energy of a photon can be used to determine the energy of the electron that absorbs it.
A weak field ligand environment means that there is a small energy gap between the t2g and eg orbitals. As a result, it absorbs photons with the lowest energy, according to the spectrochemical series. In comparison to the other complexes, [Co(OH)6]3- has a low-energy gap, which makes it the most stable.
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volatile organic compoundsa. are tiny particles of liquid or solid matter. b. are produced by chemical interactions between sulfur and oxygen.c. are an odorless, colorless poisonous gas.d. are organic chemicals that form toxic fumes. 19
Volatile organic compounds are organic chemicals that form toxic fumes.
What are Volatile Organic Compounds?Volatile organic compounds, or VOCs, are organic chemicals that readily vaporize at room temperature. They are emitted from a wide range of products and processes. Benzene, toluene, and xylene are examples of volatile organic compounds (VOCs). VOCs have been linked to a variety of health problems, including asthma and headaches. They can also cause irritation of the eyes, nose, and throat.
VOCs are released by a variety of sources, including paint, building materials, and household cleaning products. Gasoline, diesel fuel, and other fuels are also sources of VOCs. Many VOCs are also produced by natural sources like trees and vegetation, which is why they are present in outdoor air in addition to indoor air.
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Journal articles can be helpful resources when writing a laboratory report, but it is important to ensure that these references are cited properly. Which components are typically included when citing a journal artide? Select one or more:a. volume or issue number b. author(s)c.name of journal d. commentse. page number(s) f. abstract g. year of publicationh. conclusions
Components that are typically included when citing a journal article are, volume or issue number, author(s), name of journal, page number(s), year of publication are typically included when citing a journal article. The correct choices are a, b, c, d, e.
The abstract, comments, and conclusions may or may not be included depending on the citation style and the specific requirements of the report. When citing a journal article in a laboratory report, it is important to include certain components to provide enough information for the reader to locate the article.
The name of the journal in which the article was published should be included, as well as the volume and issue number (if applicable) and the page numbers of the article within the journal. This information helps to identify the specific article within the publication. The author or authors of the article should also be included, typically in the format of last name followed by initials. The year of publication is also important information to include.
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When preparing to light a gas burner, which of the following do you do first?
Answer: clear the area of anything flammable such as hair, chemicals, Ect.
If you wanted to shift the potential of the lead-zinc cell upward,toward 0.70 V, which of the following actions would give thedesired result? Check all that apply. *Ignore the currentchecks.
Anyaction that makes [Zn2+] smaller than[Pb2+].
Any action that makes [Zn2+]larger than [Pb2+].
Adding some concentratedZn(C2H3O2)2 solution tothe Zn2+/Zn couple.
Anyaction that makes Q > 1.0.
Addingsome concentratedPb(C2H3O2)2 solution tothe Pb2+/Pb couple.
Anyaction that makes log Q positive.
Any action that makes log Qnegative.
Any action that makes Q <1.0.
To shift the potential of the lead-zinc cell upward, toward 0.70 V, the following actions would give the desired result:
Add some concentrated Pb(C2H3O2)2 solution to the Pb2+/Pb couple
Adding some concentrated Zn(C2H3O2)2 solution to the Zn2+/Zn couple
Any action that makes [Zn2+] larger than [Pb2+]
A lead-zinc cell is a galvanic cell consisting of lead and zinc electrodes immersed in a suitable electrolyte. The potential of the lead-zinc cell is the difference in electrode potential between the lead and zinc electrodes, as determined by their concentration gradient.
Therefore, to shift the potential of the lead-zinc cell upward, toward 0.70 V, one should add some concentrated Pb(C2H3O2)2 solution to the Pb2+/Pb couple, add some concentrated Zn(C2H3O2)2 solution to the Zn2+/Zn couple, and any action that makes [Zn2+] larger than [Pb2+].
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An electric current of 1.00 ampere is passed through an aqueous solution of Ni(NO3)2. How long will it take to plate out exactly 1.00 mol of nickel metal, assuming 100 percent current efficiency? (1 Faraday = 96,500 coulombs = 6.02 x 1023 electrons). multiple choice: 386,000 sec
193,000 sec
96,500 sec
48,200 sec
24,100 sec
Answer:
An electric current of 1.00 ampere is passed through an aqueous solution of Ni(NO3)2. The time required to plate out 1.00 mol of nickel metal assuming 100% current efficiency is 193,000 sec.
Explanation:
How to calculate the time required to plate out 1.00 mol of nickel metal in an aqueous solution of Ni(NO3)2?
The current efficiency is 100%, which means that all the current passing through the electrolytic cell is used in the reaction. The following steps are used to determine the time required to plate out 1.00 mol of nickel metal in an aqueous solution of Ni(NO3)2
Step 1: Write the reaction and calculate the charge required to produce 1.00 mol of nickel metal
Ni²⁺(aq) + 2e⁻ → Ni(s). The number of electrons involved in the reaction is 2; thus the charge required to produce 1.00 mol of nickel metal can be calculated by multiplying Faraday's constant by the number of moles of electrons.
Faraday's constant is 96,500 coulombs/1 mol of electrons; thus the charge required to produce 1.00 mol of nickel metal is2 mol of electrons x 1 Faraday/ 1 mol of electrons x 96,500 coulombs/Faraday = 193,000 coulombs
Step 2: Calculate the time required to produce 193,000 coulombs of charge at a current of 1.00 ampere
Time = charge/current = 193,000 coulombs/1.00 ampere = 193,000 sec = 53.6 hr
Thus, the time required to plate out 1.00 mol of nickel metal assuming 100% current efficiency is 193,000 sec. Answer: 193,000 sec.
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3.00 moles of neon in a flask has a pressure of l.50 atm. the pressure rises to 4.50 atm. when 1.00 mole of hydrogen and some oxygen gas are added to the flask. how many moles of oxygen are added?
0.99 moles of oxygen are added in a flask .
To calculate the number of moles of oxygen added to the flask, we need to use the ideal gas law equation. The ideal gas law is defined by PV = nRT.
Where P is the pressure, V is the volume, n is the number of moles, R is the gas constant and T is the temperature of the gas.
Considering the first scenario where only neon is present in the flask
Pressure [tex]P_1[/tex] = 1.50 atm
Number of moles [tex]n_1[/tex] = 3.00 mol
The temperature and volume remain constant during the process. Therefore, we can equate the first scenario with the second scenario to get the number of moles of oxygen added in the flask. So, the equation becomes:
[tex]P_1[/tex]V = [tex]n_1[/tex] R [tex]T_1[/tex] [tex]V_2[/tex]
V = (n1 + n2)RT2
Where P2 = 4.50 atm, n1 = 3.00 mol, n2 = Number of moles of oxygen, T1 = T2 (the temperature is constant), R is the gas constant.
[tex]P_1[/tex] V / T = ( [tex]n_1[/tex] + [tex]n_2[/tex] )R... (1)
[tex]P_2[/tex] V / T = ( [tex]n_1[/tex] + [tex]P_2[/tex] )R... (2)
Dividing equation 1 by equation 2, we get:
( [tex]P_1[/tex] V / T) / ( [tex]P_2[/tex] V / T) = [tex]n_1[/tex] + [tex]n_2[/tex] / [tex]n_1[/tex] + [tex]n_2[/tex]
[tex]n_2[/tex] = ( [tex]P_2[/tex] V / T - [tex]P_1[/tex] V / T) / R = (4.50 x V - 1.50 x V) / R = 3.00V / R
For neon, the molecular weight is 20.18 g/mol. Therefore, the mass of neon in the flask is 3.00 x 20.18 g = 60.54 g.
For hydrogen, the molecular weight is 2.02 g/mol. Therefore, the mass of hydrogen added to the flask is 1.00 x 2.02 g = 2.02 g.
The mass of oxygen added to the flask can be calculated by mass balance.
Mass of neon + Mass of hydrogen + Mass of oxygen = Total mass of gas in the flask
60.54 g + 2.02 g + Mass of oxygen = (3.00 + 1.00 + n2) x (2.02 + 32.00 + 20.18) g
Using the above equation, we can calculate the mass of oxygen as follows:
Mass of oxygen = 94.24 - 62.56 g = 31.68 g
Moles of oxygen = 31.68 g / 32.00 g/mol = 0.99 mol
Therefore, 0.99 moles of oxygen are added.
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Chlorate is an oxyanion. It contains a single covalent bond between oxygen and chlorine atoms. The ion also have an ovaral negative charge. Show by calculation that the percentage by mass of chlorate 1 in calcium chlorate 1 is greater than the percentage by mass of chlorate 1 ions in Sodium chlorate
Percentage by mass of chlorate 1 in calcium chlorate 1 is greater than the percentage by mass of chlorate 1 ions in Sodium chlorate.
What is an oxyanion? Give an example of an oxyanion.An oxyanion is a polyatomic ion that contains at least one oxygen atom and one or more other elements, typically nonmetals. Examples of oxyanions include nitrate (NO3-), sulfate (SO42-), and phosphate (PO43-).
The molecular formula for calcium chlorate is Ca(ClO3)2, and the molecular formula for sodium chlorate is NaClO3.
To calculate the percentage by mass of chlorate 1 in calcium chlorate 1, we need to calculate the molar mass of Ca(ClO3)2 and the molar mass of chlorate 1.
Molar mass of Ca(ClO3)2 = 1 mol Ca + 2 mol ClO3
= 40.08 g/mol Ca + 2(35.45 g/mol Cl + 3(16.00 g/mol O))
= 238.06 g/mol
Molar mass of chlorate 1 = 35.45 g/mol Cl + 3(16.00 g/mol O)
= 99.45 g/mol
Now, we can calculate the percentage by mass of chlorate 1 in calcium chlorate 1:
% by mass of chlorate 1 in calcium chlorate 1 = (2 mol ClO3 x 99.45 g/mol) / (1 mol Ca(ClO3)2 x 238.06 g/mol) x 100%
= 83.3%
To calculate the percentage by mass of chlorate 1 in sodium chlorate, we only need to calculate the molar mass of NaClO3 and the molar mass of chlorate 1.
Molar mass of NaClO3 = 22.99 g/mol Na + 35.45 g/mol Cl + 3(16.00 g/mol O)
= 106.99 g/mol
Molar mass of chlorate 1 = 35.45 g/mol Cl + 3(16.00 g/mol O)
= 99.45 g/mol
Now, we can calculate the percentage by mass of chlorate 1 in sodium chlorate:
% by mass of chlorate 1 in sodium chlorate = (1 mol ClO3 x 99.45 g/mol) / (1 mol NaClO3 x 106.99 g/mol) x 100%
= 92.9%
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Find an expression for the oscillation frequency of an electric dipole of dipole moment P and rotational inertia I for small amplitudes of oscillation about its equilibrium position in a uniform electric field of magnitude E.
The oscillation frequency of an electric dipole in a uniform electric field can be expressed as:
f = (1/2π) x (1/√(I/2P x E))
What is oscillation?Oscillation can be defined simply as a variation that is repetitive (in time) of measures about a value which is central, or a value between two or more accounts of different states. The oscillation occurs not only in the mechanical system but it also occurs in dynamic systems areas of every scientific founding.
The oscillation frequency is given by
f = (1/2π) x (1/√(I/2P x E))
where:
f is the oscillation frequency in Hertz (Hz) I is the rotational inertia of the dipole in kg*m² P is the dipole moment in Coulomb-meter (C*m) E is the magnitude of the uniform electric field in Volts/meter (V/m)This expression assumes small amplitude oscillations and is derived from the equation of motion of a simple harmonic oscillator. In this case, the torque on the dipole due to the electric field is proportional to the displacement of the dipole from its equilibrium position, and the restoring torque due to the rotational inertia of the dipole is proportional to the angular displacement. By equating these torques, we get the equation of motion of the dipole in terms of the oscillation frequency, rotational inertia, dipole moment, and electric field.
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What is/are the spectator ion(s) for the reaction of perchloric acid with sodium hydroxide? Select ALL of the spectator ions from the list below.a. Na+b. CO2c. O2d. Cl-
The spectator ions for the reaction of perchloric acid with sodium hydroxide are Na+ and Cl-.The spectator ions are those ions that are present on both sides of the chemical equation but do not participate in the reaction.
These ions do not change their oxidation state or form new compounds. Therefore, they are considered to be spectators and are excluded from the overall ionic equation. The equation for the reaction of perchloric acid with sodium hydroxide is:HClO4 + NaOH → NaClO4 + H2O. Sodium ions and chloride ions are the spectator ions in this reaction. Sodium ions (Na+) are present on both sides of the equation, and they do not participate in any chemical reaction.
They remain in the same oxidation state and do not form any new compound. Hence, Na+ ions are spectator ions in this reaction. Similarly, the chloride ions (Cl-) are also present on both sides of the equation and are not involved in any reaction. Therefore, they are also spectator ions.
In summary, the spectator ions for the reaction of perchloric acid with sodium hydroxide are Na+ and Cl-. These ions are present on both sides of the equation but do not participate in any chemical reaction. They are considered spectators and are excluded from the overall ionic equation.
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The results of the gold foil experiment led to the conclusion that an atom is
1.
mostly empty space and has a small, negatively charged nucleus
2.
mostly empty space and has a small, positively charged nucleus
3.
a hard sphere and has a large, negatively charged nucleus
4.
a hard sphere and has large a large, positively charged nucbus
The results of the gold foil experiment led to the conclusion that an atom is mostly empty space and has a small, positively charged nucleus.
This was concluded by Ernest Rutherford, Hans Geiger, and Ernest Marsden through their gold foil experiment.
The Gold Foil Experiment was an experimental test conducted by Ernest Rutherford, Hans Geiger, and Ernest Marsden in which they bombarded alpha particles onto thin gold foils, expecting them to pass right through the gold foil. The team was astonished when the alpha particles were deflected back in all directions.
The results of the gold foil experiment led to the conclusion that an atom is mostly empty space and has a small, positively charged nucleus. Most of the alpha particles passed straight through the gold foil, indicating that the atom's mass was not evenly distributed but instead concentrated in a small, positively charged nucleus in the atom's center.
The Rutherford model, often known as the planetary model of the atom, was developed by Ernest Rutherford following the gold foil experiment. The model depicted the atom as a tiny, dense, and positively charged nucleus, with electrons orbiting the nucleus in the way that planets orbit a star.
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an unknown gas effuses at a rate 0.667 times the rate of co₂. what is the molar mass of the unknown gas?
An unknown gas effuses at a rate 0.667 times the rate of co₂. The molar mass of the unknown gas is 120 g/mol.
The rate of effusion for an ideal gas is proportional to the inverse square root of the gas' molar mass. It's known as Graham's law. Graham's Law explains the rate of effusion of a gas through a small hole into a vacuum. The rate of effusion for an ideal gas is proportional to the inverse square root of the gas' molar mass (relative molecular mass). According to the question, the effusion rate of the unknown gas is 0.667 times that of CO₂.
Let the molar mass of the unknown gas be "x".
Therefore, the effusion rate for the unknown gas is proportional to
.[tex]\[\frac{1}{\sqrt{x}}\].[/tex]
The effusion rate of CO₂ is proportional to \[\frac{1}{\sqrt{44}}\].
Now,
[tex]\[\frac{\text{Effusion rate of the unknown gas}}{\text{Effusion rate of CO}_2}=\frac{0.667}{1}\][/tex]
or,
\[tex]\[\frac{1}{\sqrt{x}}=\frac{0.667}{\sqrt{44}}\][/tex]]
or,
[tex]\[\sqrt{x}=\frac{\sqrt{44}}{0.667}\][/tex]
or,
[tex]\[x=\left ( \frac{\sqrt{44}}{0.667} \right )^{2}\][/tex]
Therefore, the molar mass of the unknown gas is 120 g/mol.
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In the Insoluble and Soluble Saltlab, the dropper bottles containing the anions to be studied were all _____The dropper bottles containing the cations to be studied were all ______salt solutions
The dropper bottles containing the anions to be studied were all sodium hydroxide (NaOH) solutions. The dropper bottles containing the cations to be studied were all potassium chloride (KCl) salt solutions.
Salt- A salt is a chemical compound that is produced by the reaction of an acid with a base, which results in a substance that is made up of positively charged ions and negatively charged ions, known as cations and anions, respectively.
Soluble salt- It is formed by reacting an alkali and an acid in a solution. In this case, NaOH and KCl are reacted to form the soluble salt solution, i.e., NaCl solution.
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20.0 ml of a strong acid ha has a ph of 5.00 what would happen to the ph if 1980.0 ml of distilled water was added?
The pH of a strong acid solution with 20.0 mL of ha that has a pH of 5.00 will decrease if 1980.0 mL of distilled water is added to it.
The negative logarithm of the concentration of H+ ion in the solution is called pH. The pH is calculated using the following formula: pH = -log [H+]
If the concentration of hydrogen ions is known, the pH of the solution can be calculated. Acids, bases, and neutral solutions all have a pH value.
A pH of 7 is used to describe a neutral solution. A pH of less than 7 is used to describe an acidic solutionA pH of more than 7 is used to describe a basic solution.In this case, Let's use the formula, pH = -log [H+], to find the hydrogen ion concentration of the given solution.
5 = -log [H+]
Convert the pH to the concentration of hydrogen ions on both sides.
10^-5 = [H+]
Calculate the concentration of hydrogen ions.
[H+] = 1.0 x 10^-5 moles/L
The pH of the solution is determined to be 5.00. When 1980.0 mL of distilled water is added to it, the volume of the solution is increased, but the concentration of the hydrogen ion remains constant as it is an acid and it is strong. Since pH is the negative logarithm of hydrogen ion concentration, it will decrease as the concentration of hydrogen ion decreases.
The pH of the solution after adding the distilled water will be calculated as follows:
pH = -log [H+]pH = -log [1.0 x 10^-7]pH = 7.0
Hence, the pH of the solution would be 7.0 if 1980.0 ml of distilled water is added to it.
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When 1980.0 mL of distilled water is added to 20.0 mL of a strong acid HA having pH 5.00, the new pH would be 7.01.
Adding distilled water to a strong acid lowers the concentration of the acid. It raises the pH of the solution since the concentration of H+ ions decreases.
To calculate the new pH, we can use the Henderson-Hasselbalch equation, which is given by:
pH = pKa + log([A-]/[HA])
Where A- is the conjugate base of the acid and HA is the acid.
When water is added, the concentration of A- decreases, and the concentration of HA increases.
Since the acid is strong, it dissociates almost completely, and we can assume that [HA] = the original concentration of the acid.
In this case, since the acid is strong, it dissociates completely, and [HA] = the original concentration of the acid = 10^-{5} M.
The pH of the solution is given as 5.00, so we can find the pKa:
pH = -log[H+]5.00 = -log[H+][H+] = 10^{-5.00}
= 1.00 x 10^{-5}
pKa = -log(Ka)
Ka = 10^{-pKa}
Ka = [H+][A-]/[HA][A-]/[HA]
= Ka/[H+]A- = 10^{-9.00}
= 1.00 x 10^{-9} M
We can now use the Henderson-Hasselbalch equation to find the new pH:
pH = pKa + log([A-]/[HA])
pH = 9.00 + log(1.00 x 10^{-9}/10^{-5})
pH = 7.01
The new pH of the solution is 7.01.
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mpirical formula for a compound which contains 0.0134 g of iron, 0.00769 g of sulfur and 0.0115 g of oxygen
The empirical formula for a compound which contains 0.0134 g of iron, 0.00769 g of sulfur and 0.0115 g of oxygen is FeS2O3.
First determine the ratio of each element. Divide the mass of each element by its atomic weight and then divide the results by the smallest value obtained.
The atomic weights are: Fe=55.845, S=32.065 and O=16.00. Dividing the mass of each element by its atomic weight gives the following ratios: Fe=0.0240, S=0.0024 and O=0.0072.
Dividing the ratios by the smallest value (0.0024) gives us 10, 1 and 3 respectively. This means that the empirical formula is Fe10S1O3.
We must divide all values by the highest common factor, which in this case is 2. This gives us Fe5S1/2O3/2 or FeS2O3.
Therefore, the empirical formula for a compound which contains 0.0134 g of iron, 0.00769 g of sulfur and 0.0115 g of oxygen is FeS2O3.
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