Organic compounds undergo a variety of different reactions, including substitution, addition, elimination, and rearrangement. An atom or a group of atoms in a molecule is replaced by another atom or a group of atoms in a substitution reaction. In an addition reaction, two molecules combine to yield a single molecule. Addition reactions occur at double or triple bonds. An elimination reaction can be thought of as the reverse of an addition reaction. It involves the removal of two atoms or groups from a molecule. A rearrangement reaction occurs when bonds in the molecule are broken and new bonds are formed, converting it to its isomer. Classify the following characteristics of the organic reactions according to the type of organic reaction.
a. Reactions involving the replacement of one atom or group of atoms.
b. Reactions involving removal of two atoms or groups from a molecule.
c. Products show increased bond order between two adjacent atoms.
d. Reactant requires presence of a π bond.
e. Product is the structural isomer of the reactant.
1. Substitution reaction
2. Addition reaction
3. Elimination reaction
4. Rearrangement reaction
Answer:
Reactions involving the replacement of one atom or group of atoms. - Substitution reaction
Reactions involving removal of two atoms or groups from a molecule - Elimination reaction
Products show increased bond order between two adjacent atoms - Elimination reaction
Reactant requires presence of a π bond - Addition reaction
Product is the structural isomer of the reactant - Rearrangement reaction
Explanation:
When an atom or a group of atoms is replaced by another in a reaction, then such is a substitution reaction. A typical example is the halogenation of alkanes.
A reaction involving the removal of two atoms or groups from a molecule resulting in increased bond order of products is called an elimination reaction. A typical example of such is dehydrohalogenation of alkyl halides.
Any reaction that involves a pi bond is an addition reaction because a molecule is added across the pi bond. A typical example is hydrogenation of alkenes.
Rearrangement reactions yield isomers of a molecule. Rearrangement may involve alkyl or hydride shifts in molecules.
Reactions involving the replacement of one atom or group of atoms is substitution reaction, reactions involving removal of two atoms or groups from a molecule and products show increased bond order between two adjacent atoms is elimination reaction, reactant requires presence of a π bond in addition reaction and product is the structural isomer of the reactant is rearrangement reaction.
What is chemical reaction?Chemical reactions are those reactions in which reactants undergoes through a variety of changes for the formation of new product.
Substitution reaction: In this reaction any atom or molecule of reactant is replaced by any outside atom or molecule.Addition reaction: In this reaction addition of any reagent takes place across the double or triple bond of any reactant for the formation of product.Elimination reaction: In this reaction any molecule or two atoms will eliminate from the reactant as a result of which we get a bond order increased product.Rearrangement reaction: In this reaction atoms or bonds of a reactant get rearranged for the formation of new product.Hence, classification of above points are done according to their characteristics.
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Trộn 100ml dung dịch H2SO4 0,03M với 200ml dung dịch HCl 0,03M và 0,001mol Ba(OH)2 0,05M . Hãy tính pH của dung dịch này?
Answer:
pH = 1.92Explanation:
[H+] = 0.1x0.03x2 + 0.2x0.03 = 0.012 mol
[OH-] = 0.001x0.05x2 = 0.0001 mol
=> [H+] dư = 0.012 - 0.0001 =0.0119 mol
pH = -log[H+] = 1.92
A 14.570 g sample of CaCl2 was added to 12.285 g of K2CO3 and mixed in water. A 3.494 g yield of CaCO3 was obtained.
What is the limiting reagent?
-CaCO3
-K2CO3
-CaCl2
Calculate the percent yield of CaCO3.
yield of CaCO3= %
Answer:
Limiting reagent is the potassium carbonate.
Percent yield of calcium carbonate is: 39.3 %
Explanation:
The reaction is:
CaCl₂ + K₂CO₃ → CaCO₃ + 2KCl
Formula for percent yield is:
(Produced yield / Thoeretical yield) . 100
Firstly we determine the moles of each reactant, in order to say what is the limiting reagent: ratio is 1:1.
1 mol of chloride need 1 mol of carbonate.
14.570 g . 1 mol /110.98 g = 0.131 moles of CaCl₂
12.285 g . 1 mol / 138.2g = 0.0889 moles of carbonate.
Limiting reagent is carbonate. For 0.131 moles of CaCl₂ we need the same amount of carbonate and we have less moles.
Ratio is also 1:1, with calcium carbonate.
1 mol of potassium carbonate produces 1 mol of calcium carbonate
then, 0.0889 moles will produce the same amount of CaCO₃
We convert moles to mass: 0.0889 mol . 100.08g /mol = 8.89 g
That's the theoretical yield; to find the percent yield:
(3.494 g / 8.89g) . 100 = 39.3%
What is the observation of heating of iodine crystals
Answer:
On heating, the van der Waals dispersion forces existing then will easily break as it has a low boiling point and sublimates into gas. On heating iodine in the test tube, iodine evolves as violet fuming gas.
Explanation:
A student named a particular compound 2-ethyl-3-methyl-2-butene. Assuming that the student's choice actually corresponded to the correct distribution of the double bond and the substituents, what is the correct IUPAC name for this compound
Answer:
2-ethyl-3-methylbut-2-ene
Explanation:
The whole idea of IUPAC nomenclature is to devise a universally accepted system of writing the name of a compound from its structure.
According to IUPAC nomenclature, the root of the compound is the longest carbon chain. The substituents are named in alphabetical order and in such a way as to give each one the lowest number. The position of the functional group is indicated accordingly.
For the compound in question, its correct IUPAC name is 2-ethyl-3-methylbut-2-ene.
Predict the products from theses reaction, and balance the equations. Include phase symbols.
Reaction : K(s)+Cl2(g)⟶
Reaction :Cu(s)+O2(g)⟶
Answer:
2 K(s) + Cl₂(g) ⟶ 2 KCl(s)
2 Cu(s) + O₂(g) ⟶ 2 CuO(s)
Explanation:
Both reactions are synthesis reactions (two substances combine to form another).
Reaction: K(s) + Cl₂(g) ⟶
The product is the binary salt KCl. The balanced chemical equation is:
2 K(s) + Cl₂(g) ⟶ 2 KCl(s)
Reaction: Cu(s) + O₂(g) ⟶
The most likely product is the metal oxide CuO. The balanced chemical equation is:
2 Cu(s) + O₂(g) ⟶ 2 CuO(s)
Which best expresses the uncertainty of the measurement 32.23 cm?
A.) ±0.05 cm
B.) 0.1 cm
C.) 1%
D.) ±0.01 cm?
Answer:
D.) ±0.01 cm?
Explanation:
Since 32.23 cm has two decimal places, the uncertainty is taken as one-half the last decimal pace.
The last decimal place is 0.03. Half of this is 0.03 cm/2 = 0.015 cm.
Since we cannot go below two decimal places, we ignore the 5 in 0.015 cm.
So, we have our uncertainty as 0.01 cm.
So, the best expression of the uncertainty in the measurement 32.23 cm is ± 0.01 cm.
So, the answer is D. which is ± 0.01 cm.
How many milliliters of a 0.40%(w/v) solution of nalorphine must be injected to obtain a dose of 1.5 mg?
Answer:
0.375mL of solution of nalorphine must be injected
Explanation:
A solution of 0.40% (w/v) contains 0.40g of solute (In this case, nalorphine), in 100mL of solution. To obtain 1.5mg of nalorphine = 1.5x10⁻³g of nalorphine are needed:
1.5x10⁻³g * (100mL / 0.40g) =
0.375mL of solution of nalorphine must be injected