Consider the following reaction at 298K.
I2 (s) + Pb (s) = 2 I- (aq) + Pb2+ (aq)
Which of the following statements are correct?
Choose all that apply.
ΔGo > 0
The reaction is product-favored.
K < 1
Eocell > 0
n = 2 mol electrons
B-

Answers

Answer 1

Answer:

Eªcell > 0; n = 2

Explanation:

The reaction:

I2 (s) + Pb (s) → 2 I- (aq) + Pb2+ (aq)

Is product favored.

A reaction that is product favored has ΔG < 0 (Spontaneous)

K > 1 (Because concentration of products is >>>> concentration reactants).

Eªcell > 0 Because reaction is spontaneous.

And n = 2 electrons because Pb(s) is oxidizing to Pb2+ and I₂ is reducing to I⁻ (2 electrons). Statements that are true are:

Eªcell > 0; n = 2

Related Questions

What is the rate constant of a reaction if rate = 1 x 10-2 (mol/L)/s, [A] is 2 M,
[B] is 3 M, m = 2, and n = 1?

Answers

Answer:

[tex]0.10 \text{ L$^2$mol$^{-2}$s$^{-1}$}[/tex]

Explanation:

The general formula for a rate law is

[tex]\text{rate} = k\text{[A]}^m \text{[B]}^{n}[/tex]

With your numbers, the rate law becomes

1.2 mol·L⁻¹s⁻¹ = k(2 mol·L⁻¹)²(3 mol·L⁻¹)¹ = k × 4 mol²L⁻² × 3 mol·L⁻¹

= 12k mol³L⁻³

[tex]\\ k = \dfrac{\text{1.2 mol $\cdot$ L$^{-1}$s$^{-1}$} }{12\text{ mol$^{3}$L}^{-3}} = \mathbf{0.10} \textbf{ L$\mathbf{^2}$mol$^{\mathbf{-2}}$s$^{\mathbf{-1}}$}[/tex]

Determine whether the following statement about equilibrium is true or false.
(a) When a reaction system reaches a state of equilibrium, the concentration of the products is equal to the concentration of the reactants.
(b) When a system is at equilibrium, Keq = 1.
(c) At equilibrium, the rates of the forward reaction and the reverse reaction are equal.
(d) Adding a catalyst to a reaction system will shift the position of equilibrium to the right so there are more products at equilibrium than if there was no catalyst present.

Answers

Answer:

(a) when a reaction system reaches a state of equilibrium, the concentration of the products is equal to the concentration of the reactants

Determining whether the statements about equilibrium is True or False

A) The concentration of the products is equal to the concentration of the reactants at equilibrium : TRUE

B) When a system is at equilibrium, Keq = 1 : TRUE

C) The rates of the forward reaction and the reverse reaction are equal at equilibrium :  TRUE

D) Adding a catalyst to a reaction system will shift the position of equilibrium to the right : FALSE

Reaction at equilibrium

In a chemical reaction at equilibrium the value of Keq will be equal to 1 because the concentration of the products is equal to the concentration of the reactants in the chemica reaction. Also at equilibrium the rate of forward reaction is same as the rate of reverse reaction.

A catalyst can only affect the rate of reaction and not the amount of product ( yield of reaction).

Hence we can conclude that the answers to your questions are as listed above.

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A solution is known to contain only one type of cation. Addition of Cl1- ion to the solution had no apparent effect, but addition of (SO4)2- ion resulted in a precipitate. Which cation is present

Answers

Answer:

We can have: Calcium, strontium, or barium

Explanation:

In this case, we have to remember the solubility rules for sulfate [tex]SO_4~^-^2[/tex] and the chloride [tex]Cl^-[/tex]:

Sulfate

All sulfate salts are SOLUBLE-EXCEPT those also containing: Calcium, silver, mercury (I), strontium, barium or lead.([tex]Ca^+^2~,Ag^+~,Hg_2^+^2~,Sr^+2~,Ba^+^2~,Pb^+^2[/tex]), which are NOT soluble.

Chloride

All chloride salts as SOLUBLE-EXCEPT those also containing: lead, silver, or mercury (I). ([tex]Pb^+^2~,Ag^+~,Hg_2~^+^2[/tex]), which are NOT soluble.

If we the salt formed a precipitated with the sulfate anion, we will have as possibilities "Calcium, silver, mercury (I), strontium, barium or lead". If We dont have any precipitated with the Chloride anion we can discard "Silver, mercury (I),  lead" and our possibilities are:

"Calcium, strontium, or barium".

I hope it helps!

To calculate changes in concentration for a system not at equilibrium, the first step is to determine the direction the reaction will proceed. To do so, we calculate Q and compare it to the equilibrium concentration, K. We can then determine that a reaction will shift to the right if:__________

Answers

Answer:

We can then determine that a reaction will shift to the right if Q<K

Explanation:

Comparing Q with K allows to find out the status and evolution of the system:

If the reaction quotient is equal to the equilibrium constant, Qc = Kc, the system has reached chemical equilibrium. If the reaction quotient is greater than the equilibrium constant, Qc> Kc, the system is not in equilibrium and will evolve spontaneously, decreasing the value of Qc until it equals the equilibrium constant. In this way, the concentrations of the products will decrease and the concentrations of the reagents will increase. In other words, the reverse reaction is favored to achieve equilibrium. Then the system will evolve to the left (ie products will be consumed and more reagents will be formed).If the reaction quotient is less than the equilibrium constant, Qc <Kc, the system is not in equilibrium and will evolve spontaneously increasing the value of Qc until it equals the equilibrium constant. This implies that the concentrations of the products will increase and those of the reagents will decrease. In other words, to achieve balance, direct reaction is favored. Then the reaction will shift to the right, that is, reagents will be consumed and more products will be formed.

In this case, we can then determine that a reaction will shift to the right if Q<K

Given the following equivalents, make the following conversion: 1.00 knop = ? knips

4 clips = 5 blips
1 knop = 6 bippy
3 blip = 18 pringle
1 clip = 10 knip
10 bippy = 8 pringle

Answers

Answer:

[tex]6.4knips[/tex]

Explanation:

Hello,

In this case, given the stated equivalences, we can use the following proportional factor in order to compute the required knips:

[tex]knips=1.00knop*\frac{6bippy}{1knop} *\frac{8pringle}{10bippy}* \frac{3blip}{18pringle} *\frac{4clips}{5blips} *\frac{10knip}{1clip} \\\\=6.4knips[/tex]

Regards.

1 knop=6.4 knips

First convert knop to bippy:-

[tex]1\ knop\times\frac{6\ bippy}{1\ knop} =6\ bippy[/tex]

Now, Convert 6 bippy to pringle:-

[tex]6\ bippy\times\frac{8\ pringle}{10\ bippy} =4.8\ pringle[/tex]

Now, convert 4.8 pringle to blip:-

[tex]4.8\ pringle\times\frac{3\ blip}{18\ priangle} =0.8\ blip[/tex]

Now, convert 0.8 blip to clips as follows:-

[tex]0.8\ blip\times\frac{4\ clips}{5\ blip} =0.64\ clip[/tex]

Now, convert 0.64 clip to knips:-

[tex]0.64\ clip\times\frac{10\ knip}{1\ clip} =6.4\ knip[/tex]

Hence, the following conversion is as follows:-

1.00 knop=6.4 knips

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What can you learn about the pH of a substance with the conductivity test? hint: gives you no info on concentration.

Answers

Answer:

See explanation

Explanation:

So, I'm gonna take a shot at this one and say this:

With a strongly acidic/basic solution, you'll get a high conductivity when preforming a conductivity test.

The more acidic or basic a substance is, the higher the electrical conductivity.

Based on how high or low the conductivity is, it will give you an idea of the substance's pH.

Hope that made since or gave you an idea of what you're looking for. Good luck :)

Of the following two gases, which would you predict to diffuse more rapidly? PLZZ HELPP PLZ PLZ PLZ

Answers

Answer:

CO2 will diffuse more rapidly.

Explanation:

From Graham's law of diffusion, we understood that the rate of diffusion of a gas is inversely proportional to the square root of its density as shown below:

Rate (R) & 1/√Density (d)

R & 1/√d

But, the density of a gas is directly proportional to the relative molecular mass (M) of the gas.

Thus, we can say that the rate of diffusion of a gas is inversely proportional to the square root of the molar mass of the gas. This can be represented mathematically as:

Rate (R) & 1/√Molar mass (M)

R & 1/√M

From the above illustration, we can say that the lighter the gas, the faster the rate of diffusion and the heavier the gas, the slower the rate of diffusion.

Now, to answer the question given above,let us determine the molar mass of Cl2 and CO2.

This is illustrated below:

Molar mass of Cl2 = 2 x 35.5 = 71 g/mol

Molar mass of CO2 = 12 + (2x16) = 12 + 32 = 44 g/mol

Summary

Gas >>>>>> Molar mass

Cl2 >>>>>> 71 g/mol

CO2 >>>>> 44 g/mol

From the illustration above, we can see that CO2 is lighter than Cl2.

Therefore, CO2 will diffuse more rapidly.

Answer: CO2

Explanation:

Consider the following reaction: 2Fe2+(aq) + Cu2+ --> 2Fe3+(aq) + Cu. When the ion concentrations change to the point where the reaction comes to equilibrium, what would be the cell voltage?

Answers

Answer:

At equilibrium, the cell voltage is zero volts.

Explanation:

During an electrochemical reaction, electrical energy is produced. The reaction continues to produce electrical energy until a point is reached in which the reaction attains equilibrium.

Before the reaction attains equilibrium, the cell voltage continues to decrease progressively as the reaction progresses. At equilibrium, the cell voltage becomes zero and the read out voltmeter records 0 V.

Hence, at equilibrium, the cell voltage is zero volts.

. You have two solutions, both with a concentration of 0.1M. Solution A contains a weak acid with a pKa of 5. ThepH of solution A is 3. Solution B contains a weak acid with a pKa of 9. The pH of solution B is:

Answers

Answer:

pH of solution B is 5

Explanation:

A weak acid, HA, is in equilibrium with water as follows:

HA(aq) + H₂O(l) ⇄ A⁻(aq) + H₃O⁺(aq)

Where Ka (10^-pKa = 1x10⁻⁹) is:

Ka = 1x10⁻⁹ = [A⁻] [H₃O⁺] / [HA]

Where concentrations of this species are equilibrium concentrations

As initial concentration of HA is 0.1M, the equilibrium concentrations of the species are:

[HA] = 0.1M - X

[A⁻] = X

[H₃O⁺] = X

Where X is the amount of HA that reacts until reach the equilibrium, X is reaction coordinate.

Replacing in Ka expression:

1x10⁻⁹ = [A⁻] [H₃O⁺] / [HA]

1x10⁻⁹ = [X] [X] / [0.1 - X]

1x10⁻¹⁰ - 1x10⁻⁹X = X²

1x10⁻¹⁰ - 1x10⁻⁹X - X² = 0

Solving for X:

X = -0.00001 → False solution, there is no negative concentrations.

X = 1x10⁻⁵ → Right solution.

As [H₃O⁺] = X

[H₃O⁺] = 1x10⁻⁵M

And pH = -log[H₃O⁺]

pH = 5

pH of solution B is 5

Consider the reaction: C(s) + O2(g)CO2(g) Write the equilibrium constant for this reaction in terms of the equilibrium constants, Ka and Kb, for reactions a and b below: a.) C(s) + 1/2 O2(g) CO(g) Ka b.) CO(g) + 1/2 O2(g) CO2(g) Kb

Answers

Answer:

A. Ka = [CO2] / [C] [O2]^1/2

B. Kb = [CO2] / [CO] [O2]^1/2

Explanation:

Equilibrium constant is simply defined as the ratio of the concentration of the products raised to their coefficient to the concentration of the reactants raised to their coefficient.

Now, we shall obtain the expression for the equilibrium constant for the reaction as follow:

A. Determination of the expression for equilibrium constant Ka.

This is illustrated below:

C(s) + 1/2 O2(g) <==> CO(g)

Ka = [CO2] / [C] [O2]^1/2

B. Determination of the expression for equilibrium constant Kb.

This is illustrated below:

CO(g) + 1/2 O2(g) <==> CO2(g)

Kb = [CO2] / [CO] [O2]^1/2

A sample of argon gas (molar mass 40 g) is at four times the absolute temperature of a sample of hydrogen gas (molar mass 2 g). Find the ratio of the rms speed of the argon molecules to that of the hydrogen. Assume hydrogen molecule has only translational degree of freedom.

Answers

Answer:

Ratio of Vrms of argon to Vrms of hydrogen = 0.316 : 1

Explanation:

The root-mean-square speed measures the average speed of particles in a gas, and is given by the following formula:  

Vrms = [tex]\sqrt{3RT/M}[/tex]

where R is molar gas constant = 8.3145 J/K.mol, T is temperature in kelvin, M is molar mass of gas in Kg/mol

For argon, M = 40/1000 Kg/mol = 0.04 Kg/mol, T = 4T , R = R

Vrms = √(3 * R *4T)/0.04 = √300RT

For hydrogen; M = 1/1000 Kg/mol = 0.001 Kg/mol, T = T, R = R

Vrms = √(3 * R *T)/0.001 = √3000RT

Ratio of Vrms of argon to that of hydrogen = √300RT / √3000RT = 0.316

Ratio of Vrms of argon to that of hydrogen = 0.316 : 1

Which of the following forms a molecular solid? Which of the following forms a molecular solid? C10H22 CaO gold C, graphite

Answers

Answer:

C10H22

Explanation:

Graphite is known as an allotrope of carbon. Its characteristics include being black and slippery and as used as lubricants.

Gold (Au) is an element on the periodic table with atomic number 79 and a mass number 197 which exists as a metal due to its hydrogen bonds.

C10H22 which is also known as decane belongs to the Alkane family.The General forces of attraction between the alkane family are weak but in the case of decade there is Van der waal force which makes Decane C10H22 a Molecular Solid.

Aqueous potassium nitrate (KNO3) and solid silver bromide are formed by the reaction of aqueous potassium bromide and aqueous silver nitrate (AgNO3). Write a balanced chemical equation for this reaction

Answers

Answer:

For the mentioned reaction, the balanced chemical equation is:  

KBr (aq) + AgNO3 (s) ⇒ KNO3 (aq) + AgBr (s)

The number written in front of the ion, atoms, and molecules in a chemical reaction so that each of the elements on both the sides of reactants and products of the equation gets balanced is known as the stoichiometric coefficient.  

From the mentioned balanced equation, the stoichiometric coefficient before KBr is 1, AgNO3 is 1, KNO3 is 1, as well as before AgBr is also 1. Thus, it is clear that 1 mole of potassium bromide reacts with 1 mole of silver nitrate to produce 1 mole of potassium nitrate and 1 mole of silver bromide.  

2. Which one is the odd one
out and why?
o Water
• Hydrogen
Chlorine
o Aluminum

Answers

Answer:

Reaction of Chlorine with Hydrogen Chlorine and Hydrogen mixed together explodes when exposed to sunlight, which produces Hydrogen Chloride. In the dark away from sunlight, no reaction occurs, so light energy is required for a reaction. Cl2 + H2 = 2 HCl Reaction of Chlorine with Non-Metals Chlorine directly combines with most non-metals.

Explanation:

I hope this helps bro

When the nuclide bismuth-210 undergoes alpha decay:
The name of the product nuclide is_____.
The symbol for the product nuclide is_____
Fill in the nuclide symbol for the missing particle in the following nuclear equation.
_____ rightarrow 4He+ 234Th
2 90
Write a balanced nuclear equation for the following:
The nuclide radium-226 undergoes alpha emission.

Answers

Explanation:

An atom undergoes alpha decay by losing a helium atom.

So when bismuth undergoes alpha decay, we have;

²¹⁰₈₃Bi --> ⁴₂He + X

Mass number;

210 = 4 + x

x = 206

Atomic number;

83 = 2 + x

x = 81

The element is Thallium. The symbol is Ti.

For the second part;

X --> ⁴₂He + ²³⁴₉₀Th

Mass number;

x = 4 + 234 = 238

Atomic Number;

x = 2 + 90 = 92

The balanced nuclear equation is;

²³⁸₉₂U --> ⁴₂He + ²³⁴₉₀Th

An ice cube at 0.00C with a mass of 8.32g is placed Into 55g of water, initially at 25C. If no heat is lost to the surroundings, what is the final temperature of the entire water sample after all the ice is melted (answer must be in 3 sig figs)

Answers

Answer:

The final temperature of the entire water sample after all the ice is melted, is 12,9°C. We should realize that if there is no loss of heat in our system, the sum of lost or gained heat is 0.  It is logical to say that the temperature has decreased because the ice gave the water "heat" and cooled it

Thats all i know

Which of the following pieces of information is given in a half-reaction?
O A. The number of electrons transferred in the reaction
B. The compounds that the atoms in the reaction came from
C. The state symbol of each compound in the reaction
D. The spectator ions that are involved in the reaction

Answers

Answer:

The number of electrons transferred in the reaction

Explanation:

Answer:

A

Explanation:

Each energy sublevel contains __________ number of electrons. For example, sublevel D can hold up to _______ electrons. A. the same, 10 B. the same, 14 C. a different, 6 D. a different, 10

Answers

Answer:

Each energy sublevel contains a different number of electrons. For example, sublevel D can contain up to 10 electrons

Explanation:

The atoms are surrounded by propellers that within each propeller there is a certain number of electrons, these electrons jump from orbit to orbit according to the amount of energy they have. The four levels that make up the electronic cloud that surrounds an atom are: s p d f.

When these electrons change orbit or level they release energy in the form of light, which is known as a photon.

The substance formed on addition of water to an aldehyde or ketone is called a hydrate or a/an:_______
A) vicinal diol
B) geminal diol
C) acetal
D) ketal

Answers

Answer:

B) geminal diol

Explanation:

Hello,

In this case, considering the attached picture, you can see that the substance resulting from the hydrolysis of an aldehyde or a ketone is a geminal diol since the two hydroxyl groups are in the same carbon. Such hydrolysis could be carried out in either acidic or basic conditions depending upon the equilibrium constant.

Regards.

Provide the name(s) for the tertiary alcohol(s) with the chemical formula C6H14O that have a 4-carbon chain. Although stereochemistry may be implied in the question, DO NOT consider stereochemistry in your name. Alcohol #1______ Alcohol #2: ______Alcohol #3______

Answers

Answer:

Explanation:

A tertiary alcohol is a compound (an alcohol) in which the carbon atom that has the hydroxyl group (-OH) is also bonded (saturated) to three different carbon atoms.

Based on the question, the only tertiary alcohol that can result from C₆H₁₄O that have a 4-carbon chain is

2-hydroxy-2,3-dimethylbutane

     H  OH   H    H

      |     |       |      |

H - C - C -   C  - C - H

      |     |       |      |

     H  CH₃  CH₃ H

From the above, we can see that the carbon atom having the hydroxyl group is also bonded to three other carbon atoms. And since we aren't considering stereochemistry, this is the only tertiary alcohol we can have with a 4-carbon chain

3. Identify the reagents you would use to convert 1-bromopentane into each of the following compounds: (a) Pentanoic acid (b) Hexanoic acid (c) Pentanoyl chloride (d) Hexanamide (e) Pentanamide (f) Ethyl hexanoate

Answers

Answer:

Explanation:

a )

CH₃CH₂CH₂CH₂CH₂Br + KOH   ⇒ CH₃CH₂CH₂CH₂CH₂OH

CH₃CH₂CH₂CH₂CH₂OH  + acidic potassium dichromate ⇒  CH₃CH₂CH₂CH₂COOH

b )

CH₃CH₂CH₂CH₂CH₂Br + KCN ⇒ CH₃CH₂CH₂CH₂CH₂CN  Hydrolysis ⇒ CH₃CH₂CH₂CH₂CH₂COOH .

c )

CH₃CH₂CH₂CH₂CH₂Br + KOH   ⇒ CH₃CH₂CH₂CH₂CH₂OH

CH₃CH₂CH₂CH₂CH₂OH  + acidic potassium dichromate ⇒  CH₃CH₂CH₂CH₂COOH + SOCl₂ ( thionyl  chloride ) ⇒ CH₃CH₂CH₂CH₂COCl

d )

CH₃CH₂CH₂CH₂CH₂Br + KCN ⇒ CH₃CH₂CH₂CH₂CH₂CN  Hydrolysis ⇒ CH₃CH₂CH₂CH₂CH₂COOH + PCC ( NH₃ ) ⇒ CH₃CH₂CH₂CH₂CH₂CONH₂

e )

CH₃CH₂CH₂CH₂CH₂Br + KCN ⇒ CH₃CH₂CH₂CH₂CH₂CN  Hydrolysis ⇒ CH₃CH₂CH₂CH₂CH₂COOH + C₂H₅OH ( Ethyl alcohol + H⁺ )⇒  

CH₃CH₂CH₂CH₂CH₂COOC₂H₅ ( ethyl hexanoate )

Arrange the compounds in order of decreasing magnitude of lattice energy:


a. LiBr

b. KI

c. CaO.


Rank from largest to smallest.

Answers

Answer:

The correct answer is CaO > LiBr > KI.

Explanation:

Lattice energy is directly proportional to the charge and is inversely proportional to the size. The compound LiBr comprises Li+ and Br- ions, KI comprises K+ and I- ions, and CaO comprise Ca²⁺ and O²⁻ ions.  

With the increase in the charge, there will be an increase in lattice energy. In the given case, the lattice energy of CaO will be the highest due to the presence of +2 and -2 ions. K⁺ ions are larger than Li⁺ ion, and I⁻ ions are larger than Br⁻ ion.  

The distance between Li⁺ and Br⁻ ions in LiBr is less in comparison to the distance between K⁺ and I⁻ ions in KI. As a consequence, the lattice energy of LiBr is greater than KI. Therefore, CaO exhibits the largest lattice energy, while KI the smallest.  

Arranging the chemical compounds in order of decreasing magnitude of lattice energy, we have:

c. CaO.

a. LiBr

b. KI

Lattice energy can be defined as a measure of the energy required to dissociate one (1) mole of an ionic compound into its constituent anions and cations, in the gaseous state.

Hence, it is typically used to measure the bond strength of ionic compounds.

Generally, lattice energy is inversely proportional to the size of the ions and directly proportional to their electric charges.

Lithium bromide (LiBr) comprises the following ions:

[tex]Li^+[/tex] and [tex]Br^-[/tex]

Potassium iodide (KI) comprises the following ions:

[tex]K^+[/tex] and [tex]I^-[/tex]

Calcium oxide (CaO) comprises the following ions:

[tex]Ca^{2+}[/tex] and [tex]O^{2-}[/tex]

From the above, we can deduce that there is an increase in the charge possessed by the ionic chemical compounds and as such this would result in an increase in the lattice energy.

In order of decreasing magnitude of lattice energy, the chemical compounds are arranged as:

I. CaO.

II. KI.

III. LiBr.

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Find the density if the volume is 15 mL and the mass is 8.6 g. (5 pts)
Find the volume if the density is 2.6 g/mL and the mass is 9.7 g.(5 pts)
Find the mass if the density is 1.6 g/cm3 and the volume is 4.1 cm3 (5 pts)
Find the density if the initial volume of water is 12.8 mL, the final volume is 24.6 mL and the mass of the object is 4.3 g. Make a drawing to show the water displacement using a graduated cylinder. (gdoc, gdraw)

Answers

Answer:

[tex]\large \boxed{\text{0.57 g/mL; 3.7 mL; 6.6 g; 0.366 g/mL}}[/tex]

Explanation:

1. Density from mass and volume

[tex]\text{Density} = \dfrac{\text{mass}}{\text{volume}}\\\\\rho = \dfrac{m}{V}\\\\\rho = \dfrac{\text{8.6 g}}{\text{15 mL}} = \text{0.57 g/mL}\\\text{The density is $\large \boxed{\textbf{0.57 g/mL}}$}[/tex]

2. Volume from density and mass

[tex]V = \text{9.7 g}\times\dfrac{\text{1 mL}}{\text{2.6 g}} = \text{3.7 mL}\\\\\text{The volume is $\large \boxed{\textbf{3.7 mL}}$}[/tex]

3. Mass from density and volume

[tex]\text{Mass} = \text{4.1 cm}^{3} \times \dfrac{\text{1.6 g}}{\text{1 cm}^{3}} = \textbf{6.6 g}\\\\\text{The mass is $\large \boxed{\textbf{6.6 g}}$}[/tex]

4. Density by displacement

Volume of water + object = 24.6 mL

Volume of water                = 12.8 mL

Volume of object               = 11.8 mL

[tex]\rho = \dfrac{\text{4.3 g}}{\text{11.8 mL}} = \text{0.36 g/mL}\\\text{The density is $\large \boxed{\textbf{0.36 g/mL}}$}[/tex]

Your drawing showing water displacement using a graduated cylinder should resemble the figure below.

 

1. What volume in milliliters of 0.100 M HClO₃ is required to neutralize 40.0 mL of 0.140 M KOH? 2. A 25.0 mL solution of HNO₃ is neutralized with 15.7 mL of 0.250 M Ba(OH)₂. What is the concentration of the original HNO₃ solution?

Answers

Answer:

The correct answer is 1) 56 ml and 2) 0.314 M

Explanation:

1. The reaction taking place in the given case is,  

HClO₃ + KOH ⇒ KClO₃ + H2O, the molarity of HClO₃ given is 0.100 M, the molarity of KOH given is 0.140 M and the volume of KOH given is 40 ml, there is a need to find the volume of HClO₃.  

Therefore, the mole of HClO₃ = mole of KOH

= MHClO₃ × VHClO₃ = MKOH × VKOH

= 0.100 M × VHClO₃ = 0.140 M × 40 ml

VHClO₃ = 0.140 M × 40 ml/0.100 M

VHClO₃ = 56 ml.  

2. The reaction taking place is,  

2HNO₃ + Ba(OH)₂ ⇒ Ba(NO₃)₂ + 2H₂O

The volume of HNO₃ given is 25 ml, the molarity of Ba(OH)2 is 0.250 M, the volume of Ba(OH)2 is 15.7 ml, the n or the number of moles of HNO₃ is 2, and the n of Ba(OH)2 is 1, the concentration or M of HNO₃ is,  

M₁V₁/n₁ = M₂V₂/n₂

M₁ × 25/ 2 = 0.25 × 15.7/1

M₁ or molarity of HNO₃ = 0.314 M

1. The volume of HClO₃ required to neutralize the KOH is 56.0 mL

2. The concentration of the original HNO₃ solution is 0.314 M

1.

First, we will write a balanced chemical equation for the reaction

The balanced chemical equation for the reaction is

HClO₃ + KOH → KClO₃ + H₂O

This means,

1 mole of HClO₃ is required to neutralize 1 mole of KOH

From the titration formula

[tex]\frac{C_{A}V_{A} }{C_{B}V_{B}} = \frac{n_{A}}{n_{B}}[/tex]

Where

[tex]C_{A}[/tex] is the concentration of acid

[tex]C_{B}[/tex] is the concentration of base

[tex]V_{A}[/tex] is the volume of acid

[tex]V_{B}[/tex] is the volume of base

[tex]n_{A}[/tex] is the mole ratio of acid

[tex]n_{B}[/tex] is the mole ratio of base

From the given information,

[tex]C_{A} = 0.100 \ M[/tex]

[tex]C_{B} = 0.140 \ M[/tex]

[tex]V_{B} = 40.0 \ mL[/tex]

From the balanced chemical equation

[tex]n_{A} = 1[/tex]

[tex]n_{B} =1[/tex]

Putting the values into the formula, we get

[tex]\frac{0.100 \times V_{A} }{0.140 \times 40.0} = \frac{1}{1}[/tex]

∴ [tex]0.100 \times V_{A} = 0.140 \times 40.0[/tex]

[tex]V_{A}=\frac{0.140\times 40.0}{0.100}[/tex]

[tex]V_{A}=\frac{5.60}{0.100}[/tex]

[tex]V_{A}=56.0 \ mL[/tex]

Hence, the volume of HClO₃ required to neutralize the KOH is 56.0 mL

2.

First, we will write the balanced chemical equation for the reaction

The balanced chemical equation for the reaction is

2HNO₃ + Ba(OH)₂ → Ba(NO₃)₂ + 2H₂O

This means, 2 mole of HNO₃ is required to neutralize 1 mole Ba(OH)₂  

From the given information,

[tex]V_{A} = 25.0\ mL[/tex]

[tex]C_{B} = 0.250 \ M[/tex]

[tex]V_{B} = 15.7 \ mL[/tex]

From the balanced chemical equation

[tex]n_{A} = 2[/tex]

[tex]n_{B} =1[/tex]

Also, Using the titration formula

[tex]\frac{C_{A}V_{A} }{C_{B}V_{B}} = \frac{n_{A}}{n_{B}}[/tex]

We get

[tex]\frac{C_{A} \times 25.0 }{0.250 \times 15.7} = \frac{2}{1}[/tex]

Then,

[tex]C_{A} = \frac{2\times 0.250 \times 15.7} {1 \times 25.0}[/tex]

[tex]C_{A} =\frac{7.85}{25.0}[/tex]

[tex]C_{A} =0.314 \ M[/tex]

Hence, the concentration of the original HNO₃ solution is 0.314 M

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A 1.0 L buffer solution is 0.250 M HC2H3O2 and 0.050 M LiC2H3O2. Which of the following actions will destroy the buffer?

A. adding 0.050 moles of NaOH
B. adding 0.050 moles of LiC2H3O2
C. adding 0.050 moles of HC2H3O2
D. adding 0.050 moles of HCl
E. None of the above will destroy the buffer.

Answers

Answer:

D

Explanation:

Addition of 0.05 M HCl, will react with all of the C2H3O2- from LiAc which will give 0.05 M more HAc. So there will be no Acetate ion left to make the solution buffer. Hence, the correct option for the this question is d, which is adding 0.050 moles of HCl.

The action that destroys the buffer is option c. adding 0.050 moles of HCl.

What is acid buffer?

It is a solution of a weak acid and salt.

Here, The buffer will destroy at the time when either HC2H3O2 or NaC2H3O2 should not be present in the solution.

The addition of equal moles of HCl finishly reacts with equal moles of NaC2H3O2. Due to this,  there will be only acid in the solution.

Since

moles of HC2H3O2 = 1*0.250 = 0.250

moles of NaC2H3O2 = 1*0.050 = 0.050.

moles of HCl is added = 0.050

Now

The reaction between HCl and NaC2H3O2

[tex]HCl + NaC_2H_3O_2 \rightarrow HC_2H_3O_2 + NaCl[/tex]

Now

BCA table is

            NaC2H3O2  HCl       HC2H3O2

Before 0.050 0.050 0.250

Change -0.050 -0.050 +0.050

After 0 0 0.300

Now, the solution contains the acid (HC2H3O2 ) only.

Therefore addition of 0.050 moles of HCl will destroy the buffer.

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At what temperature in K will 0.750 moles of oxygen gas occupy 10.0 L and exert 2.50 atm of pressure

Answers

Answer:

406 K.

Explanation:

The following data were obtained from the question:

Number of mole (n) = 0.750 mole

Volume (V) = 10.0 L

Pressure (P) = 2.50 atm

Temperature (T) =.?

Note: Gas constant (R) = 0.0821 atm.L/Kmol

The temperature, T can be obtained by using the ideal gas equation as follow:

PV = nRT

2.5 x 10 = 0.75 x 0.0821 x T

Divide both side by 0.75 x 0.0821

T = (2.5 x 10) /(0.75 x 0.0821 )

T = 406 K.

Therefore, the temperature is 406 K.

Answer: 406 K

Explanation:

We can rewrite the ideal gas law to solve for T:

PV = nRT

T=PV / nR

We are given the following from the problem:

n=0.750 mol P=2.50 atm V=10.0 L

Plugging in our values and using R=0.08206 L⋅atm / K⋅mol we get:

T=(2.50 atm)(10.0 L) / (0.750 mole)(0.08206L ⋅ atm ⋅ mole K) = 406 K

What is the molarity of 4 g of NaCl dissolved in 100mL of water?

Answers

Answer:

[tex]M=0.684M[/tex]

Explanation:

Hello,

In this case, considering that the solution is formed by NaCl as the solute and water as the solvent, we can compute the molarity as shown below:

[tex]M=\frac{mol_{solute}}{V_{solution}}[/tex]

Whereas the volume of the solution must be in liters. In such a way, since the addition of sodium chloride does not significantly changes the volume of the solution we can say it remains in 100 mL (0.100 L) and the moles of sodium chloride are computed by using its molar mass (58.45 g/mol):

[tex]mol_{solute}=4g*\frac{1mol}{58.45g} =0.0684mol[/tex]

Therefore, the molarity is:

[tex]M=\frac{0.0684mol}{0.100L} \\\\M=0.684\frac{mol}{L}=0.684M[/tex]

Regards.

What are the correct half reactions for the following reaction: Cu2+ + Mg -> Cu + Mg2+

Answers

Answer:

Cu2 + 2Mg-> 2Cu+ Mg2

Explanation:

Balance the equation and make sure both the reactant and the products are the same

Hope it will be helpful

[tex]Cu^{+2} + 2Mg[/tex]  -> [tex]2Cu + Mg^+2[/tex]  is the correct half-reactions.

What is a balanced equation?

A balanced equation is an equation for a chemical reaction in which the number of atoms for each element in the reaction and the total oxidation numbers is the same for both the reactants and the products.

[tex]Cu^{+2} + 2Mg[/tex]  -> [tex]2Cu + Mg^+2[/tex] is the correct half-reactions.

Magnesium is oxidized because its oxidation state increased from 0 to +2 while Cu is reduced because its oxidation state decreased from +2 to 0.

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While balancing a chemical equation, we change the _____ to balance the number of atoms on each side of the equation.

Answers

Answer:

While balancing a chemical equation, we change the coefficient  to balance the number of atoms on each side of the equation

Explanation:

While balancing a chemical equation, we change the coefficient to balance the number of atoms on each side of the equation.

What is chemical equation?

To summarize in chemistry terms, a chemical equation depicts the initial chemicals, or reactants, on the left-hand side and the final compounds, or products, just on right-hand side, divided by an arrow. In the chemical equation, the number of atoms in each element as well as the total charge are the same on opposite of the equation's sides.

Chemical equations are used in chemistry to depict chemical processes by writing the reactants and products in terms of their corresponding chemical formulas. While balancing a chemical equation, we change the coefficient to balance the number of atoms on each side of the equation.

Therefore, while balancing a chemical equation, we change the coefficient to balance the number of atoms on each side of the equation.

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For an ideal gas condition, what is the mass (g) of N2 if the pressure is 2.0 atm, the volume is 25 mL and the temperature is 290 Kelvin.

Answers

Answer:

THE MASS OF NITROGEN GAS IN THIS CONDITIONS IS 0.0589 g

Explanation:

In an ideal condition

PV = nRT or PV = MRT/ MM where:

M = mass = unknown

MM =molar mass = 28 g/mol

P = pressure = 2 atm

V = volume = 25 mL = 0.025 L

R = gas constant = 0.082 L atm/mol K

T = temperature = 290 K

n = number of moles

The gas in the question is nitrogen gas

Molar mass of nitrogen gas = 14 * 2 = 28 g/mol

Then equating the variables and solving for M, we have

M = PV MM/ RT

M = 2 * 0.025 * 28 / 0.082 * 290

M = 1.4 / 23.78

M = 0.0589 g

The mass of the nitrogen gas at ideal conditions of 2 atm, 25 mL volume and 290 K temperature is 0.0589 g

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