Determine the reducing agent in the following reaction. Explain your answer. 2 Li(s) + Fe(C2H3O2)2(aq) → 2 LiC2H3O2(aq) + Fe(s)

Answers

Answer 1

The reducing agent in the reaction 2Li(s) + Fe(CH₃COO)₂(aq) → 2LiCH₃COO(aq) + Fe(s) is lithium (Li).

The general reaction is:

2Li(s) + Fe(CH₃COO)₂(aq) → 2LiCH₃COO(aq) + Fe(s)   (1)

We can write the above reaction in two reactions, one for oxidation and the other for reduction:

Oxidation reaction

Li⁰(s) → Li⁺(aq) + e⁻   (2)

Reduction reaction

Fe²⁺(aq) + 2e⁻ → Fe⁰(s)    (3)

We can see that Li⁰ is oxidizing to Li⁺ (by losing one electron) in the lithium acetate (reaction 2) and that Fe²⁺ in iron(II) acetate is reducing to Fe⁰ (by gaining two electrons) (reaction 3).  

We must remember that the reducing agent is the one that will be oxidized by reducing another element and that the oxidizing agent is the one that will be reduced by oxidizing another species.

In reaction (1), the reducing agent is Li (it is oxidizing to Li⁺), and the oxidizing agent is Fe(CH₃COO)₂ (it is reducing to Fe⁰).  

Therefore, the reducing agent in reaction (1) is lithium (Li).  

 

Learn more here:

https://brainly.com/question/10547418?referrer=searchResultshttps://brainly.com/question/14096111?referrer=searchResults

I hope it helps you!

Determine The Reducing Agent In The Following Reaction. Explain Your Answer. 2 Li(s) + Fe(C2H3O2)2(aq)

Related Questions

What are the dependent and independent variables in this experiment? How are outside factors being controlled in this experiment to make sure that the results test only the dependent variable?

Answers

Answer:

1. An independent variable is manipulated, or changed. The dependent, or responding variable, changes based on the independent variable. The dependent variable is examined.

2. It is a controlled experiment.

Explanation:

In a controlled experiment all variables are kept the same, except for the one being tested, which is called the experimental variable , or independent variable . This group is the experimental group . The group that is not affected by the experimental variable is the control group .

Very often a graph will be used to analyze the results of the experiment. The independent/experimental variable is placed on the x-axis and the dependent variable is placed on the y-axis. The dependent variable is what is measured as a result of the application of the experimental variable.

A variable that is independent is altered. Based on the independent variable, the responding variable, or dependent variable, alters. Examining the dependent variable. The experiment is carefully controlled.

What is an independent variable ?

In mathematical modeling, statistical modeling, and experimental sciences, there are dependent and independent variables. Dependent variables get their name because, during an experiment, their values are investigated under the presumption or requirement that they are dependent on the values of other variables due to some law or rule.

A variable that is independent is precisely what it sounds like. It is a stand-alone variable that is unaffected by the other variables you are attempting to assess. Age, for instance, could be an independent variable.

When doing an experiment, the independent variable is what you alter, and the dependent variable is what changes as a result of that change. This is an easy way to conceive of independent and dependent variables.

Thus, based on the independent variable, the responding variable, or dependent variable, alters.

To learn more about independent variable, follow the link;

https://brainly.com/question/967776

#SPJ2

Grace wanted to find out the best conditions for growing lettuce plants.
She took 4 trays and planted 8 lettuce plants in each.
The results of her investigation are shown below.

How many days did the investigation last?
Use the table to help you.

Answers

Explanation:

the investigation lasts for 7 days.

hope this helps you.

4.What volume of hydrogen gas at STP is produced when 2.5 grams of zinc react with an
excess of hydrochloric acid?

Answers

Answer:

0.86

Explanation:

1mol of Zn has mass of 65.39g.The amount of Zn is 2.5g65.39g/mol=0.038mol.

The amount of H2 produced is the same as the amount of Zn consumed (0.038mol).

1mol of ideal gas will occupy 22.4L at STP.

The H2 will occupy 0.038mol×22.4L/mol=0.86L

.

Because electron delocalization stabilizes a compound, if the only way electrons can be moved is away from the most electroneagtive atom, that is better than no electron delocalization at all.

a. True
b. False

Answers

It’s is false because it is

As electron delocalization stabilizes the compound it is necessary that it takes place for compound to exist , hence the given statement is false.

What is a compound?

Compound is defined as a chemical substance made up of identical molecules containing atoms from more than one type of chemical element.

Molecule consisting atoms of only one element is not called compound.It is transformed into new substances during chemical reactions. There are four major types of compounds depending on chemical bonding present in them.They are:

1)Molecular compounds where in atoms are joined by covalent bonds.

2) ionic compounds where atoms are joined by ionic bond.

3)Inter-metallic compounds where atoms are held by metallic bonds

4) co-ordination complexes where atoms are held by co-ordinate bonds.

They have a unique chemical structure held together by chemical bonds .Compounds have different properties as those of elements because when a compound is formed the properties of the substance are totally altered.

Learn more about compounds,here:

https://brainly.com/question/13516179

#SPJ2

Please help asap chemistry worksheet doesn’t make sense

Answers

Answer:

dog dog im not gon hold u we kinda screwed

Which of the following best describes the scientific exploration of the atom?

Answers

where do we pick or where is it

Escriba un poema usando 4 de las siguientes palabras: lluvia, nieve, lluvia, granizo, tornado, huracanes, frente cálido, frente frío, alta presión, baja presión, termómetro, barómetro, anemómetro, pluviómetro, veleta o higrómetro.
plis ayúdenme porfa

Answers

Answer:

i dont speak mexican

Explanation:

an alloy composed of tin, lead, and cadmium is analyzed. the mole ratio of sn:pb is 2.73:1.00, and the mass ratio of pb:cd is 1.78:1.00. what is the mass percent composition of pb in the alloy

Answers

This problem is describe the mole-ratio composition of an allow composed by tin, lead and cadmium. Ratios are given as Sn:Pb 2.73:1.00 and Pb:Cd is 1.78:1.00, and we are asked to calculate the mass percent compositon of Pb in the allow.

In this case, according to the given information, it turns out possible realize that the following number of moles are present in the alloy, according to the aforementioned ratios:

[tex]2.73mol Sn\\\\1.00molPb\\\\\frac{1.00molPb*1.00molCd}{1.78molPb}= 0.562molCd[/tex]

Next, we calculate the masses by using each metal's atomic mass:

[tex]m_{Sn}=2.73mol*\frac{118.7g}{1mol}=324.05g\\\\ m_{Pb}=1.00mol*\frac{207.2g}{1mol}=207.2g\\\\m_{Cd}=0.562mol*\frac{112.4g}{1mol}=63.2g[/tex]

Thus, the mass percent composition of each metal is shown below:

[tex]\%Sn=\frac{324.05g}{324.05g+207.2g+63.2g} *100\%=54.5\%\\\\\%Pb=\frac{207.2g}{324.05g+207.2g+63.2g} *100\%=34.9\%\\\\\%Cd=\frac{63.2}{324.05g+207.2g+63.2g} *100\%=10.6\%[/tex]

So that of lead is 34.9 %.

https://brainly.com/question/19168996https://brainly.com/question/2578569

Learn more:

Magnesium metal burns in air with an intense bright light according to the equation
2 Mg(s) + O2(g) → 2 MgO(s) + 1200 kJ

A.) What is the amount of energy in kJ produced when 4.5 mol of Mg is burned in the presence of excess oxygen?

Answers

The heat produced by 4.5 moles of magnesium when burnt is 2700 kJ.

A thermochemical reaction is a reaction in which the amount of heat lost or gained is included in the reaction equation. The thermochemical reaction equation for the combustion of magnesium is shown as follows;

2 Mg(s) + O2(g) → 2 MgO(s) + 1200 kJ

From the reaction equation;

2 moles of magnesium produced 1200 kJ of heat

4.5 moles of magnesium will produce 4.5 moles × 1200 kJ/2 moles

= 2700 kJ

Learn more: https://brainly.com/question/14281129

Can KI+Cl2 occur or not

Answers

Yes according to reliable sources.

1 ton of methanol are accidentally discharged into a lake. By how much is the biological oxygen demand of this water increased

Answers

The biological Oxygen demand of the lake is increased by 1.5 ton.

Discussion:

The reaction of methanol with Oxygen is as follows;

2CH3OH + 3O2 ==> 2CO2 + 4H2O.

In the reaction above; Since Methanol, CH3OH and Oxygen, O2 have the same molar mass; 32.

Therefore we can say since;

2 moles of CH3OH requires 3 moles of O2.

Therefore, 1 ton of methanol will require 1.5 ton of oxygen.

The biological Oxygen demand of the water is therefore increased by 1.5 ton as this is the amount of Oxygen consumed by the ethanol.

Read more:

https://brainly.com/question/13386150

How is hot spot and ring of fire similar

Answers

Answer:The plates are not fixed but are constantly moving atop a layer of solid and molten rock called the mantle. The Ring of Fire is a string of volcanoes and sites of seismic activity, or earthquakes, around the edges of the Pacific Ocean. ... A hotspot is a place in the middle of a tectonic plate where hot magma rises.

Explanation:

Which of the following is NOT a type of evidence indicating that a chemical change has occurred? *

- fizzing/bubbling
- heat is released
- solubility
- sound is given off

Answers

Answer:

sound is given off

Explanation:

due to a number of scientific research sound that is given off of an object is not due to a chemical reaction.

classify each of the statements about gases as true or false. oxygen molecules at 25 celsius are moving faster than oxygen

Answers

Since gas molecules average velocity depends on temperature, oxygen molecules at 25°C are moving faster than oxygen molecules at 0 °C.

According to the kinetic theory of gases, the molecules of a gas are in constant random motion and collide frequently with each other and the walls of the container.

The average speed of gas molecules depends on temperature and molar mass as shown by the relation;

vrms = √3RT/M

The following statement are true among the options provided;

Oxygen molecules at 25°C are moving faster than oxygen molecules at 0 °C Gases exert pressure by colliding with container walls

The following are false among the options provided;

All hydrogen molecules are moving with the same velocityNitrogen gas exerts more pressure than hydrogen gas because nitrogen molecules are heavier than hydrogen molecules. Nitrogen molecules remain suspended in the atmosphere because they are not attracted to Earth by gravitational forces.

Learn more: https://brainly.com/question/6505878

A car is traveling 70km in 45 minutes. How many miles an hour is the car traveling?

Answers

52

Explanation:

70x45÷60= 52

I hope this is helpful

Dissolution of KOH, ΔHsoln:

KOH(s) → KOH(aq) (10.1)
Neutralization of solid KOH, ΔHneut:

KOH(s) + HCl(aq) → H2O(l) + KCl(aq) (10.2)

1) Using Hess's law, show how to combine Reaction 10.1 and Reaction 10.2 to give
KOH(aq) + HCl(aq) → H2O(l) + KCl(aq) (10.3)

2)How should ΔHsoln and ΔHneut be combined (mathematically) to give the change in enthalpy for Reaction 10.3, ΔH?

Answers

Using Hess's law we found:

1) By adding reaction 10.2 with the reverse of reaction 10.1 we get reaction 10.3:

KOH(aq) + HCl(aq)  → H₂O(l) + KCl(aq)   ΔH  (10.3)

2) The ΔHsoln must be subtracted from ΔHneut to get the total change in enthalpy (ΔH).    

The reactions of dissolution (10.1) and neutralization (10.2) are:

KOH(s) → KOH(aq)   ΔHsoln    (10.1)

KOH(s) + HCl(aq) → H₂O(l) + KCl(aq)     ΔHneut     (10.2)

1) According to Hess's law, the total change in enthalpy of a reaction resulting from differents changes in various reactions can be calculated as the sum of all the enthalpies of all those reactions.      

Hence, to get reaction 10.3:

KOH(aq) + HCl(aq) → H₂O(l) + KCl(aq)    (10.3)

We need to add reaction 10.2 to the reverse of reaction 10.1

KOH(s) + HCl(aq) + KOH(aq) → H₂O(l) + KCl(aq) + KOH(s)

Canceling the KOH(s) from both sides, we get reaction 10.3:

KOH(aq) + HCl(aq)  → H₂O(l) + KCl(aq)    (10.3)

2) The change in enthalpy for reaction 10.3 can be calculated as the sum of the enthalpies ΔHsoln and ΔHneut:

[tex] \Delta H = \Delta H_{soln} + \Delta H_{neut} [/tex]

The enthalpy of reaction 10.1 (ΔHsoln) changed its sign when we reversed reaction 10.1, so:

[tex] \Delta H = \Delta H_{neut} - \Delta H_{soln} [/tex]

Therefore, the ΔHsoln must be subtracted from ΔHneut to get the total change in enthalpy ΔH.

Learn more here:

https://brainly.com/question/2082986?referrer=searchResultshttps://brainly.com/question/1657608?referrer=searchResults  

I hope it helps you!

Three test tubes contain aqueous hydrogen sulfide, aqueous sulfur-dioxide and Lugol reagent. By mixing any two of the three test tubes, identify their contents. Explain, stating reasons, how you arrive at your conclusions. Write equations whenever applicable.

Answers

Answer:

Initial rate experiments

The simplest initial rate experiments involve measuring the time taken for some recognizable event to happen early in a reaction. This could be the time required for 5 cm3 of gas to be produced, for a small, measurable amount of precipitate to form, or for a dramatic color change to occur. Examples of these three indicators are discussed below.

The concentration of one of the components of the reaction could be changed, holding everything else constant: the concentrations of other reactants, the total volume of the solution and the temperature. The time required for the event to occur is then measured. This process is repeated for a range of concentrations of the substance of interest. A reasonably wide range of concentrations must be measured.This process could be repeated by altering a different property.

Explanation:

I don't think so if this is the answer. if not ok sorry

What is the [H+] if pOH =9.50
will it be acid or basic?

Answers

Taking into account the definition of pH and pOH, the [H⁺] is 3.16×10⁻⁵ M and the solution will be acid.

First of all, pH is a measure of acidity or alkalinity that indicates the amount of hydrogen ions present in a solution or substance.

The pH is defined as the negative base 10 logarithm of the activity of hydrogen ions, that is, the concentration of hydrogen ions or H₃O⁺:

pH= - log [H⁺]= - log [H₃O⁺]

Similarly, pOH is a measure of hydroxyl ions in a solution and is expressed as the logarithm of the concentration of OH⁻ ions, with the sign changed:

pOH= - log [OH⁻]

The following relationship can be established between pH and pOH:

pH + pOH= 14

In this case, being pOH= 9.50, pH is calculated as:

pH + 9.40= 14

pH= 14 - 9.50

pH= 4.50

Replacing in the definition of pH the concentration of H⁺ ions is obtained:

- log [H⁺]= 4.50

Solving :

[H⁺]= 10⁻⁴ ⁵

[H⁺]= 3.16×10⁻⁵ M

The numerical scale that measures the pH of the substances includes the numbers from 0 to 14, being acidic solutions with a pH lower than 7, and basic those with a pH greater than 7. The pH = 7 indicates the neutrality of the solution.

In this case, the pH has a value of 4.50. So, the solution is acidic.

In summary, the [H⁺] is 3.16×10⁻⁵ M and the solution will be acid.  

Learn more:

brainly.com/question/16032912?referrer=searchResults brainly.com/question/13557815?referrer=searchResults

how is waste removed from the body

Answers

Waste is removed from the body in various ways. Kidneys filter out metabolic waste, excess fluid and eliminate it in the form of urine. Lungs exhale CO2 from the deoxygenated blood. The undigested solid waste is egested out from the large intestine. Excretion is the process of removing wastes and excess water from the body. It is one of the major ways the body maintains homeostasis. Organs of excretion make up the excretory system. They include the kidneys, large intestine, liver, skin, and lungs.

Maybe drinks such as kombucha or alcohol to get rid of bacteria replacing with good bacteria

please i need this now ill give you brainlest ​

Answers

Answer: The following information should be included;

What is the difference between the greenhouse effect, climate change and global warming?

What proof do we have that climate change is happening?

Why is it happening?

2. What pressure is required to compress 196.0 L of air at 1.00 atmosphere into a cylinder
whose volume is 26 0 L? (2 points)

Answers

Answer:

7.54 atm

Explanation:

The required pressure can be found by using the formula for Boyle's law which is

[tex]P_2 = \frac{P_1V_1}{V_2} \\[/tex]

where

P1 is the initial pressure

P2 is the final pressure

V1 is the initial volume

V2 is the final volume

From the question we have

[tex]P_2 = \frac{1 \times 196}{26} = \frac{196}{26} \\ = 7.538461...[/tex]

We have the final answer as

7.54 atm

Hope this helps you

A 5.35 M sugar solution is diluted from 240.0 mL to 862.5 mL. What is the concentration of the dilute solution

Answers

Answer:

1.345.0

Explanation:

Hope this helpssss


Identify the strongest intermolecular force that is likely to affect each of the samples described below.
A mixture of chlorine gas (Cl) and fluorine gas (F): V London dispersion forces
COMPLETE
Tweaks
Menu
A mixture of hydrogen sulfide (H2S) and hydrogen chloride (HCI): V dipole-dipole interactions
Search
Selection
COMPLETE
Guess
this
hydrogen bonding
A mixture of water (H2O) and ammonia (NH3):

Answers

Answer:

A mixture of chlorine gas (Cl2) and fluorine gas (F2):

✔ London dispersion forces

Explanation:

A chemical reaction involves the reactants A and B, and the product C.
A+B→C
Trial 1 2 3
[A](mol/L) 0.10 0.10 0.20
[B](mol/L) 0.10 0.20 0.10
−Δ[A]Δt(molL s) 3.08×10−9 2.464×10−8 1.232×10−8

Answers

Explanation:

a+b =ab

answer

ab added all

is give answer

A metal (FW 241.5 g/mol) crystallizes into a face-centered cubic unit cell and has a radius of 1.92 Angstrom. What is the density of this metal in g/cm3

Answers

This  problem provides the molar mass and radius of a metal that has an FCC unit cell and the density is required.

Firstly, we begin with the formula that relates the aforementioned variables and also includes the Avogadro's number and the volume of the unit cell:

[tex]\rho=\frac{Z*M}{V*N_A}[/tex]

Whereas Z stands for the number of atoms in the unit cell, M the molar mass, V the volume and NA the Avogadro's number. Next, since FFC is able to hold 4 atoms and M and NA are given. Next, we calculate the volume of the atom in the unit given the radius in meters:

[tex]V=a^3=(2*1.92x10^-10m*\sqrt{2} )^3=1.60x10^{-28}m^3/atom[/tex]

And finally the required density in g/cm³:

[tex]\rho=\frac{4*241.5g/mol}{1.60x10^{-28}m^3/atom*6.022x10^{23}atom/mol} \\\\\rho=10025739g/m^3=10.03 g/cm^3[/tex]

Learn more:

https://brainly.com/question/12977980https://brainly.com/question/13110055

Construct a conclusion using the claim, evidence and reasoning format to explain the typical properties observed by ionic and covalent compounds.

Answers

Answer:

The key to understanding why ionic and covalent compounds have different properties from each other is understanding what's going on with the electrons in a compound. Ionic bonds form when atoms have different electronegativity values from each other. When the electronegativity values are comparable, covalent bonds form.

But, what does this mean? Electronegativity is a measure of how easily an atom attracts bonding electrons. If two atoms attract electrons more or less equally, they share the electrons. Sharing electrons results in less polarity or inequality of charge distribution. In contrast, if one atom attracts bonding electrons more strongly than the other, the bond is polar.

Ionic compounds dissolve in polar solvents (like water), stack neatly on each other to form crystals, and require a lot of energy for their chemical bonds to break. Covalent compounds can be either polar or nonpolar, but they contain weaker bonds than ionic compounds because they are sharing electrons. So, their melting and boiling points are lower and they are softer.

I hope this helps have a great day :)

Plaseee ASAP

In an experiment hydrochloric acid is added drop by drop to solid sodium sulfite (Na2SO3). A gas is evolved and collected. Half of the collected gas is added to Lugol solution (I2 dissolved in KI solution), the other half of the gas is added to hydrogen sulfide solution. Write the equation of the reactions, discuss the observations that can be seen during the reactions and explain the changes. In your answer, also discuss the followings:


a) What gas is liberated during the reaction between HCl and Na2SO3? Why can it be liberated this way? Write an equation for the reaction.


b) What ability of the gas is
demonstrated in the reactions with Lugol solution and with H2S? Write equations and use oxidation numbers to prove it. What makes it possible for the substance to act differently in the two reactions?


c) What other properties of the gas evolved can you recall?


d) What are the environmental implications of the gas evolved? Write the appropriate equation for the reaction.

Answers

SO2 acts both as an oxidizing and a reducing agent depending on the conditions of the reaction. It also leads to acid rain.

The reaction of HCl with Na2SO3 occurs as follows;

Na2SO3 + 2HCl ------> 2NaCl + SO2 + H2O

The gas evolved in the reaction is SO2. It is liberated because sulfites react with acids to liberate sulfur IV oxide.

The ionic equation of the reaction is; [tex]SO3^2-(aq) + 2H^+(aq) ----> SO2(g) + H2O(l)[/tex]

The reaction of SO2 with Lugol solution occurs as follows;

SO2 +I2 + 2H20→ H2SO4 + 2HI. This demonstrates oxidation because sulfur is oxidized from +4 to +6 state from left to right. This shows SO2 as a reducing agent.

With H2S, the gas reacts as follows;

2H2S + SO2 → 3S (s) + 2H2O

The oxidation number of sulfur decreases from +4 to zero. This demonstrates the gas as an oxidizing agent. SO2 can act as oxidizing or reducing agent because it can change its oxidation state to +6(oxidation) by electron loss or gain electrons to decrease its oxidation state as low as -2.

The gas SO2 is an acid gas. It dissolves in water to yield an acid solution. Also SO2 is a bleaching agent. The major environmental impact of SO2 is that it leads to acid rain as follows; 2SO2 + O2 + 2H2O⇌2H2SO4.

Learn more:  https://brainly.com/question/2510654

How to find distance from motion graph velocity - time?

Answers

Answer:

by finding the slope of tangent (y2 - y1)/(x2 - x1)

In a constant-pressure calorimeter, 55.0 mL of 0.340 M Ba(OH), was added to 55.0 mL of 0.680 M HCI. The reaction caused the temperature of the solution to rise from 22.21 °C to 26.84 °C. If the solution has the same density and specific heat as water (1.00 g/mL and 4.184J/g • °C.) respectively), what is A4 for this reaction (per mole H,O produced)? Assume that the total volume is the sum of the individual volumes.​

Answers

Answer:

Ba(OH)2 + 2 HCl → BaCl2 + 2 H2O

The reactants are present in equimolar amounts, so there is no excess or limiting reactants.

(0.0500 L) x (0.600 mol/L HCl) x (2 mol H2O / 2 mol HCl) = 0.0300 mol H2O

(4.184 J/g·°C) x (50.0 g + 50.0 g) x (25.82 - 21.73)°C = 1711.256 J

(1711.256 J) / (0.0300 mol H2O) = 57042 J/mol = 57.0 kJ/mol H2O

Explanation:

pls help 8th grade k12

Answers

Look it up online you will find it
Other Questions
9. Which substance is cut byrestriction enzymes?A. DNAB. proteinsC. amino acidsD. chromosomes Please help, need this ASAP!In what ways does the Constitution limit the powers of the federal government? the decimal equivalent of 14/26 Two sides of a triangle measure 10 feet and 14 feet. Whichinequality shows the possible lengths for the third side, x?Answers options:10 x 144 x 2410 < x < 144 < x < 24 write a summary of the brave little toaster by cory doctorow PLS HELPPPPP WILL GIVE BRAILIEST!!!!! HELPPPPPPPPPPPPPp Which aspect of validity involves conscious, critical self-awareness by individuals and teams about their own pre-conceptions, biases, and assumptions both before the research begins and as it unfolds At State College last term, 63 of the students in a Physics course earned As, 85earned Bs, 123 got Cs, 84 were issued Ds, and 64 failed the course. If this gradedistribution was graphed on a pie chart, how many degrees would be used to indicatethe B region? what is 78x85x99x1 i need helppp Complete combustion of 6.4g of compound K produced 8.8 g of carbon dioxide and 7.2 g of water. Calculate the empirical formula of K. What major public construction project does this photo show? What does the average young child need in order to develop oral language skills?. Help, Is the following triangle acute, obtuse, or a right triangle The first step in pursuing your fianancial goals is________. a Thesis sentence of how music impacts me The magnitude of vector A is 2.5 m and is directed towards east. The magnitude and direction of A /2 will be How does Dickens present Scrooges character in Stave 1 ? Bright yellow urine usually is indicative that someone is supplementing with ________. nutrition the sun faces the equator twice in a year. how is the length of the day and night during the time and why what is the intercepts of the line? x-intercept and y-intercept 4x-1=3y+5 help need it done for tomorrow