During electrophilic aromatic substitution, a resonance-stabilized cation intermediate is formed. Groups, already present on the benzene ring, that direct ortho/para further stabilize this intermediate by participating in the resonance delocalization of the positive charge. Assume that the following group is present on a benzene ring at position 1 and that you are brominating the ring at positon 4. Draw the structure of the resonance contributor that shows this group actively participating in the charge delocalization.

-----OCH3

Answers

Answer 1

Answer:

See explanation and image attached

Explanation:

Aromatic compounds undergo electrophilic aromatic substitution reactions in which the aromatic ring is maintained.

Substituted benzenes may be more or less reactive towards electrophilic aromatic substitution than benzene depending on the nature of the substituent present in the ring.

Substituents that activate the ring towards electrophilic substitution such as -OCH3 are ortho-para directing.

The major products of the bromination of anisole are p-bromoanisole and o-bromoanisole. The resonance structures leading to these products are shown in the image attached.


Related Questions

The element Co exists in two oxidation states, Co(II) and Co(III), and the ions form many complexes. The rate at which one of the complexes of Co(III) was reduced by Fe(II) in water was measured. Determine the activation energy of the reaction from the following data:

T(K) K(s^-1)
293 0.054
298 0.100

Answers

We measured the Fe(II) reduction of one of the Co(III) complexes by water at a rate of about 0.545 kJ/mol (to three significant figures).

How is activation energy determined?

Calculating a Reaction's Activation Energy A reaction's rate is influenced by the temperature at which it is carried out. The molecules travel more quickly and clash more frequently as the temperature rises. Moreover, the molecules contain greater kinetic energy.

We can use the Arrhenius equation to calculate the reaction's activation energy:

k = A × exp(-Ea/RT)

When the activation energy Ea, the rate constant k, the gas constant R, and the temperature T in Kelvin are all present.

Finding the natural logarithm of the equation's two sides results in:

ln(k) = ln(A) - (Ea/RT)

This equation can be rearranged to take a linear form:

ln(k) = (-Ea/R) × (1/T) + ln(A)

y = mx + b, where (1/T) is x, (-Ea/R) is the slope, and ln(A) is the y-intercept, has the form of a linear equation.

We can get the slope of the line using the given data:

slope = (-Ea/R) = (ln(k2/k1)) / (1/T2 - 1/T1)

where the rate constants for temperatures T1 and T2, respectively, are k1 and k2.

substituting the specified values:

k1 = 0.054s⁻¹ at 293 K

k2 = 0.100s⁻¹ at 298 K

T1 = 293 K

T2 = 298 K

slope = (-Ea/R)

= (ln(0.100/0.054)) / (1/298 - 1/293)

= 65.5 kJ/mol

Therefore, the activation energy of the reaction is:

Ea = slope * R = 65.5 kJ/mol × 8.314 J/mol-K = 545 J/mol

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Hello, I am a bit stuck on this. Could someone help?

Answers

There is no picture or question. What am I supposed to answer to?

313.9 liters of a gas has a pressure of 390.89 kPa at 76.6°C. If the pressure increases to 718.3 kPa and the temperature to 154.2°C, what would be the new volume of the gas?

A.) 210
B.) 353
C.) 470
D.) 209.92

Answers

Explanation:

P1V1/T1 = P2V2/T2

=((390.89×313.9)/76.6)×((718.3×V2)/154.2)

= (122700.371/76.7) × ((718.3×V2)/154.2)

make V2 the subject of the formula...

V2 =(122700.371×154.2)/(76.6×718.3)

V2 =18920397.21/55021.78

V2 = 343.87

Which one of these statements is/are true: I. All redox reactions with positive emfs are spontaneous. II. If a redox reaction is spontaneous, it must be fast. III. A spontaneous redox reaction will have a cathode reaction that has a more negative reduction potential than the anode. III only. I and III are true. I only. II only. All of I, II, and III are true.

Answers

Answer:

yea all the answers are true

Redox reaction is the transfer of the electron from one species to another. All of the three statements are true about the redox reaction.

What is a redox reaction?

A redox reaction is a type of chemical reaction in which the electrons are gained and lost by a species. The positive EMF of the cell results in spontaneous and will move the reaction in the forward direction.  

In a redox reaction, the cathode reaction is comparatively more negative than the reduction potential present at the anode.

Therefore, option E. All I, II, and III are true.

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Which of the following is an example of an optional deduction ? " a ) Medicare Ob ) Social Security c ) Retirement plan d ) State tax

Answers

Medicare  

United states program for people who are older than 60

A person uses 400.8 kcal of energy to run a race. Convert the energy used for the race to the following energy units:

(provide an answer in 4 significant figures)

Calories

calories

Food Calories

Joules

Kilojoules

Hint: 1kcal=4.184kJ

Answers

Calories, we know that fat burn is calories.

What does the third quantum number (m) describe?
A. Which energy level the electron is in
B. What type of orbital the electron is in
C. What direction the electron is spinning
D. The specific orbital within a sublevel

Answers

I think c the best answer

The third quantum number (m) describes the specific orbital within a sublevel. The correct answer is option D.

Quantum numbers are a set of four numbers that describe the properties of an electron in an atom. They specify the energy, position, and orientation of an electron in an atom.

The third quantum number (m) is also called the magnetic quantum number. It describes the orientation of the orbital in space. Each orbital within a sublevel has a different orientation in space, and the magnetic quantum number tells us which orbital we are talking about.

The value of m can range from -l to +l, where l is the second quantum number (the angular momentum quantum number). The value of l determines the number of orbitals in a sublevel, and the value of m determines the specific orbital within that sublevel.

In conclusion, the third quantum number (m) describes the specific orbital within a sublevel. It tells us how the orbital is oriented in space, and it can have values ranging from[tex]\rm -l \ to +l[/tex], where l is the second quantum number.

Option D is the correct answer.

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The surface of silver metal, Ag(s), became tarnished when it was exposed to oxygen, producing Ag2O. In Ag2O, the oxidation state of silver is 1. According to this information, silver metal was _____. Please choose the correct answer from the following choices, and then select the submit answer button. Answer choices reduced

Answers

Answer: The silver metal was OXIDIZED.

Explanation:

OXIDATION is defined as loss of electrons and increase in oxidation number of an atom.

Oxidation number is the charge on an ion in an ionic compound or the charge that an atom in a covalent compound would have it it were ionic. There are basic rules governing oxidation number, they include:

--> the oxidation number of elements in their free states is ZERO. Example O2, Cl2,Na, Al, Ag.

-->The oxidation number for an ion is the same as the size and sign of the charge on the ion. For example the oxidation number of Zn2+ is +2.

--> the sum of all the oxidation numbers of the elements in a compound is zero.

--> oxidation numbers are always written with either a positive or a negative sign.

On the other hand, reduction is the opposite of oxidation. As oxidation is taking place, reduction is also taking place. Reduction involves:

--> Gain of electron and

--> decrease in oxidation number

From the question, the silver metal had ZERO as it's oxidation number because it's in free state. After being exposed to oxygen to form silver oxide, the oxidation number became +1.

Since there is an increase in the oxidation number, the silver metal was OXIDIZED

Consider a hypothetical metal that has a density of 10.6 g/cm3, an atomic weight of 176.8 g/mol, and an atomic radius of 0.130 nm. Compute the atomic packing factor if the unit cell has tetragonal symmetry, values for the a and c lattice parameters are 0.570 and 0.341, respectively.

Answers

Answer:

0.3323

Explanation:

GIven that:

Density of the metal = 10.6 g/cm^3

atomic weight = 176.8 g/mol

atmic radius = 0.130 nm

values of a and c = 0.570 nm and 0.341 nm respectively

For us to determine the atomic packing factor, we need to first determine the volume of all spheres (Vs) and the volume of unit cell (Vc).

However, the number of atoms  in the unit cell (n) can be computed as:

[tex]n = \dfrac{\rho * V_c *N_A}{A} \\ \\ n = \dfrac{(10.6) * (5.7)^2 (3.41)*(10^{-24}) *(6.022*10^{23})}{176.8}[/tex]

n = 4.0

Thus, the number of atoms in the unit cell is 4

The atomic paking factor (APF) is calculated by using the formula:

[tex]\dfrac{Vs}{Vc} = \dfrac{4 * \dfrac{4}{3}\pi *R^3 }{a^2 *c} \\ \\ \\ \dfrac{Vs}{Vc} = \dfrac{4 * \dfrac{4}{3}\pi *(1.30*10^{-8})^3 }{(5.70*10^{-8})^2 *(3.41*10^{-8})}[/tex]

= 0.3323

10. At 573K, NO2(g) decomposes forming NO and O2. The decomposition reaction is second order in NO2 with a rate constant of 1.1 M-1s-1. If the initial concentration of NO2 is 0.056 M, how long will it take for 75% of the NO2 to decompose

Answers

Answer:

48.67 seconds

Explanation:

From;

1/[A] = kt + 1/[A]o

[A] = concentration at time t

t= time taken

k= rate constant

[A]o = initial concentration

Since [A] =[A]o - 0.75[A]o

[A] = 0.056 M - 0.042 M

[A] = 0.014 M

1/0.014 = (1.1t) + 1/0.056

71.4 - 17.86 = 1.1t

53.54 = 1.1t

t= 53.54/1.1

t= 48.67 seconds

Hence,it takes 48.67 seconds to decompose.

A piece of metal has a volume of 30.0cm3 and a mass of 252g. What is its density? what metal do you think this is?

Answers

Answer:

Explanation:

get density = D = m / V = 0.252 / 0.00003 = 8400 metal will be Cu => bronze

HELP! How is the mass number of an atom calculated?
A - total number of electrons

B - total number of protons

C - protons plus neutrons

D - electrons plus neutrons

Answers

The answer is C. Mass number = protons + neutrons

Hypercalcemia sign and symptoms severe symptoms

Answers

Answer:

Hypercalcemia can cause stomach upset, nausea, vomiting and constipation. Bones and muscles. In most cases, the excess calcium in your blood was leached from your bones, which weakens them. This can cause bone pain and muscle weakness.

Some symptoms are:

Fatigue, bone pain, headaches.

Nausea, vomiting, constipation, decrease in appetite.

Forgetfulness.

Lethargy, depression, memory loss or irritability.

Muscle aches, weakness, cramping and/or twitches.

How many milliliters of 0.204 Mol KMnO4 are needed to react with 3.24 g of iron(II) sulfate, FeSO4? The reation is as folows. 10FeSO4(aq) + 2 KMnO4(aq) = 5Fe2(SO4)3(aq) + 2MnSO4(aq) + K2SO4(aq) + 8H2O(l)​

Answers

Answer:

Explanation:

nFeSo4=3.36/152

nkmno4=1/5nFeSO4

V=17.68 ml

cuales son las caracteristicas de el livermorio

Answers

Answer:

Livermorium is a radioactive, artificially produced element about which little is known. It is expected to be a solid and classified as a metal. It is a member of the chalcogen group. Livermorium has four isotopes with known half-lives, all of which decay through alpha decay

A fusion reaction releases energy because the binding energy of the resulting nucleus:______.
a. is released in the process.
b. is equal to the binding energy of the original nuclei.
c. is absorbed in the process.
d. is less than the binding energy of the original nuclei.
e. is greater than the binding energy of the original nuclei.

Answers

Answer:

a. is released in the process

Explanation:

In fusion reaction the nucleus is unstable so it releases its binding energy resulting in decreasing its mass so it becomes more stable.

Two methods by which we can conserve water and water the plants.

Answers

Answer:

Two methods which help us to conserve water are:

Sprinkler irrigation system: this irrigation has an arrangement of vertical pipes with rotating nozzles on the top. It is more useful in the uneven and sandy land where sufficient water is not available.

Drip irrigation system: this irrigation system has an arrangement of pipes or tubes with very small holes in them to water plants drop by drop just at the base of the root. It is very efficient as water is not wasted at all.

When a marble is dropped into a beamer of water

Answers

Answer:

The water will rise.

Explanation:

hope this helps you

-Sweety<3

The mass of the marble is greater than that of the water. The marble weighs more than an equivalent volume of the water. The force from dropping the marble breaks the surface tension of the water. The marble has greater mass and volume than the water.

A chemist is preparing to carry out a reaction that requires 5.75 moles of hydrogen gas. The chemist pumps the hydrogen into a 10.5 L rigid steel container at 20.0 °C. To what pressure, in kPa, must the hydrogen be compressed? (Show all work for full credit and circle your final answer) *

Answers

Answer:

The hydrogen must be compressed to 1333.13302 kPa.

Explanation:

An ideal gas is characterized by three state variables: absolute pressure (P), volume (V), and absolute temperature (T). The relationship between them constitutes the ideal gas law, an equation that relates the three variables if the amount of substance, number of moles n, remains constant and where R is the molar constant of the gases:

P * V = n * R * T

In this case:

P= ?V= 10.5 Ln= 5.75 molesR= 0.082 [tex]\frac{atm*L}{mol*K}[/tex]T= 20 C= 293 K (being 0 C= 273 K)

Replacing:

P* 10.5 L= 5.75 moles* 0.082 [tex]\frac{atm*L}{mol*K}[/tex] * 293 K

Solving:

[tex]P=\frac{5.75 moles* 0.082 \frac{atm*L}{mol*K} * 293 K}{10.5 L}[/tex]

P= 13.157 atm

If 1 atm is equal to 101.325 kPa, then 13.157 atm is equal to 1333.13302 kPa.

The hydrogen must be compressed to 1333.13302 kPa.

J00
Sugar
(C2H2011)
260
KNO
220
180
Solubility (g solute per 100 g H,0)
140
NaNO,
NaBr
100
KBr
60
КСІ
Naci
20
0
0
20
Ce (50)
40 60
Temperature (°C)
80
100
Which compound would make a saturated solution if 98 grams were
dissolved in 100 grams of solution at 80 degrees Celsius?
O KBr
O Sugar
OKCI
O NaCl
alish

Answers

the compound would be CO2 which is glass so 80 degrees celsius would work

Three important nutritional additions to training for a long distance race are
O Protein
O Water
O Increase calories
O All of the answer choices

Answers

All of the answer choices would likely be correct. This is just due to the fact that you need to stay hydrated and have protein in your system. The increase of calories would also be nice on account of the burning of them that occurs in a long distance race- therefore, ALL OF THE ANSWER CHOICES, is the correct choice.

The Lewis dot model of a molecule is shown.

Based on the model, which of the following is true?


Each carbon has three lone pairs of electrons on it.

The octet of carbon atom remains incomplete in the molecule.

The two carbon atoms share a total of six electrons with each other.

The difference between the electronegativity of carbon and hydrogen is greater than 1.7.

Answers

Answer:

The two carbon atoms share a total of six electrons with each other.

Explanation:

Looking at the structure of the molecule H-C≡C-H as shown in the question, we will notice that there exists a triple bond between the two carbon atoms.

Each bond between the two carbon atoms represents two electrons shared. Since there are three bonds between the two carbon atoms, then a total of six electrons were shared between the two carbon atoms hence the answer chosen above.

Complete the following nuclear equations. I recommend filling in the atomic number below each symbol. Instead of using superscripts in our answers, put each answer in the corresponding box. A). 54Fe 4He --> 2 1n _____

Answers

Answer:

gamma ray

Explanation:

Gu
Magnesium metal is reacted with hydrochloric acid to produce
hydrogen gas. A sample of hydrogen gas is collected over water
in a eudiometer at 28.0°C. The atmospheric pressure is 636
mmHg. Determine the pressure (in atm) of the hydrogen gas
produced
Pressure =
atm

Answers

The pressure of hydrogen gas is 607.7 mmHg

According of Dalton's law of Partial pressure, the total pressure of a mixture of gases is the sum of the partial pressures of the individual gases in the mixture.

We can now write;

The for hydrogen collected over water, we have a mixture of hydrogen gas and water vapour.

Total pressure = pressure of hydrogen gas + vapour pressure of water

Pressure of hydrogen gas = Total pressure - vapour pressure of water

Pressure of hydrogen gas =  636 mmHg - 28.3 mmHg

Pressure of hydrogen gas = 607.7 mmHg

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The number of organic compounds that have been reported in 2019 is more than 10 million. This is due to carbon's ability to bond to other carbon molecules, called





electron affinity.




ionic bonding.




catenation.




electronegativity.

Answers

Answer:

catenation

Explanation:

Carbon atoms have four electrons to share in bonding environments to get to the ideal octet. To do this, it bonds with other carbon molecules, called catenation. Catenation is the ability of an atom to bond and share electrons with other atoms of its kind.

PLEASE HELP ASAP!!!

Answers

Answer:

I don't know What can I do.

2. An ion is a charged particle that is formed when
a. An atom gains electrons
b. An atom loses electrons
c. Both A and B
d. None of the above

Answers

The correct answer is option c. Both A and B: An ion is a charged particle that is formed when an atom gains electrons or an atom loses electrons.

First you need to know the definition of ion. An ion is a molecule or atom that has a positive or negative electrical charge.

That is, an ion is an atom whose electric charge is not neutral. This charged particle can be positive or negative.  

Ionization is the chemical or physical process by which ions are produced. In this process, negatively charged ions are produced by gaining electrons and are known as anions.

The positively charged are produced by the loss of electrons and are known as cations.

In summary, an ion is a charged particle that is formed when  an atom gains electrons or an atom loses electrons, and they are known as cations and anions respectively.

The correct answer is both A and B.

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Consider an equilibrium (K1) that is established after 10 mL of compound A and 10 mL of compound B are mixed. Now, imagine the equilibrium (K2) where 1 mL of compound A is added to 100 mL of compound B. How are K1 and K2 related algebraically (read this question VERY carefully, at least one more time)

Answers

The equilibrium constant K₁ = Equilbrium constant K₂.

The equilibrium constant, K, of a reaction, is defined as:

"The ratio between concentration of products powered to their reaction quotient and concentration of reactants powered to thier reaction quotient".

For the reaction:

aA + bB ⇄ cC + dD

The equilibrium constant, K, is:

[tex]K = \frac{[C]^c[D]^d}{[A]^a[B]^b}[/tex]

Now, assuming the reaction of the problem is 1:1:

A + B ⇄ C + D

[tex]K = \frac{[C][D]}{[A][B]}[/tex]

The concentrations of the reactants are directly proportional to the volume added. Thus, we can assume that concentration = Volume. Replacing for K₁ and K₂:

[tex]K_1 = \frac{[C][D]}{[10mL][10mL]} = K_1 = \frac{[C][D]}{100mL^2}[/tex]

In the same way:

[tex]K_2 = \frac{[C][D]}{[1mL][100mL]} = K_2 = \frac{[C][D]}{100mL^2}[/tex]

Thus, we can say:

K₁ = K₂

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In the graphic, 195 represents the _______.

195 Pt
78

A. Atomic Mass
B. Atomic Number
C. Neutron Number​

Answers

Answer:

ITS ANSWER IS

OPTION B. ATOMIC NUMBER

HI HAVE A NICE DAY

When hydrogen gas reacts with oxygen gas, water vapour is formed according to the
reaction 2H2 + O2 2H2O. If 3.00 mol of hydrogen gas react with 3.00 mol
of oxygen gas, which reactant will be the reactant in excess?

Answers

Explanation:

here's the answer to the question

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