energy difference between t2g and EG level in octahedral complex is denoted by ​

Answers

Answer 1

Answer:

∆o

Explanation:

Usually, the d level consists of a set of five degenerate d orbitals. These orbitals rema degenerate until the approach of ligands.

When ligands approach, the d orbitals are split into higher energy eg and lower energy t2g orbitals.

There exists an energy difference between this t2g and eg levels. This energy difference is called the octahedral crystal field splitting denoted as ∆o.


Related Questions

Suppose we have two rock samples, A and B. Rock A was subject to both physical and chemical weathering while rock B was subject to chemical weathering only. Which rock would experience more chemical weathering? Why? (2pts) (Hint: consider the effect of surface area on the rate of chemical weathering)

Answers

Answer:

Rock A will have far more chemical weathering than Rock B due to the rise in area effect

Explanation:

Rock A undergoes both Physical and Chemical weathering. So, thanks to physical weathering there'll appear cracks within the rock, which can, in turn, increase the area of rock on which weathering is occurring. So, Chemical weathering will happen much faster now as there's a rise in the area. within the case of Rock B, there's only chemical weathering therefore the increase in the area won't be that very much like compared to Rock A.

Why does increasing the temperature of two reactants in solution make a
reaction proceed more quickly?

Answers

The two molecules will only react if they have enough energy. By heating the mixture, you are raising the energy levels of the molecules involved in the reaction. Increasing temperature also means the molecules are moving around faster and will therefore "bump" into each other more often.

Answer:

-The particles of the two reactants will gain kinetic energy and collide with one another more frequently and forcefully, which makes the reaction take place more quickly


please help!

What is the definition of thermal chemistry?

a.The study of change that involves warm objects

b.The study of change that involves heat

c.The study of change that involves cool objects

d.The study of change that involves temperature

Answers

D. That is the correct answer

The absorption spectrum of neon has a line at 633 nm. What is the energy of this line? (The speed of light in a vacuum is 3.00 x 108 m/s, and Planck's constant is 6.626 x 10-34 J·s.)

Answers

Answer:

B

Explanation:

E = hc/[tex]\lambda[/tex]. Remember, it is in meters not nanometers so you have to convert. You end up with B.

If the temperature of a volume of dieal gas ncreases for 100 to 200, what happens to the average kinetic energy of the molecules?

Answers

Answer:

It increases but less than double

Explanation:

As the temperature of a gas increase, the average kinetic energy of the gas increases. The kinetic energy of a gas is the thermal energy that the gas contains.

We know, the kinetic energy of an ideal gas is given by :

[tex]$V_{avg} = \sqrt{\frac{8R}{\pi M}}$[/tex]

where, R = gas constant

            T = absolute temperature

            M = molecular mass of the gas

From the above law, we get

[tex]$V_{avg} \propto \sqrt{T}$[/tex]

Thus, if we increase the temperature then the average kinetic energy of the ideal gas increases.

In the context, if the temperature of the ideal gas increases from 100°C to 200°C, then

[tex]$\frac{(V_{avg)_2}}{(V_{avg)_1}} =\sqrt{\frac{T_2}{T_1}}$[/tex]

[tex]$\frac{(V_{avg)_2}}{(V_{avg)_1}} =\sqrt{\frac{473.15}{373.15}}$[/tex]

[tex]$\frac{(V_{avg)_2}}{(V_{avg)_1}} =\sqrt{1.26}$[/tex]

[tex]$\frac{(V_{avg)_2}}{(V_{avg)_1}} =1.12$[/tex]

[tex]$(V_{avg})_2 = 1.12\ (V_{avg})_1$[/tex]

Therefore, [tex]$(V_{avg})_2 > (V_{avg})_1$[/tex]

Thus the average kinetic energy of the molecule increases but it increases 1.12 times which is less than the double.

Thus, the answer is " It increases but less that double".

Enzyme catalyzing breakdown of atp to adp

Answers

Answer:

ATP hydrolase

Explanation:

Enzymes are biological catalysts which perform diverse functions in the body. Enzymes are specific in their mode of action because an enzyme fits into its substrate as a key fits into a lock.

The particular enzyme that catalyzes the breakdown of ATP to ADP is ATP hydrolase. The phosphate released by the action of this enzyme is used in the phosphorylation of other compounds thereby making them more reactive.

A researcher is attempting to produce ethanol using an enzyme catalyzed batch reactor. The ethanol is produced from corn starch by first-order kinetics with a rate constant of 0.05 hr-1. Assuming the concentration of ethanol initially is 1 mg/L, what will be the concentration of ethanol (in mg/L) after 24 hours

Answers

Answer:

The correct solution is "3.32 gm/L".

Explanation:

Given:

Rate constant,

[tex]K = 0.05 \ hr^{-1}[/tex]

Time,

[tex]t = 24 \ hours[/tex]

Concentration of ethanol,

[tex]C_o= 1 \ mg/L[/tex]

Now,

The concentration of ethanol after 24 hours will be:

⇒ [tex]C_o=C\times e^{-K\times t}[/tex]

By putting the values, we get

    [tex]1=C\times e^{-0.05\times 24}[/tex]

    [tex]1=C\times 0.30119[/tex]

    [tex]C= 3.32 \ gm/L[/tex]

10g of a non-volatile and non-dissociating solute is dissolved in 200g of benzene.
The resulting solution boils At temperature of 81.20oC. Find the molar mass of solute.
Given that the BP of pure benzene is 80.10oC and Its elevation boiling point constant = 2.53 oC/m.

Answers

Answer: The molar mass of solute is 115 g/mol.

Explanation:

Elevation in the boiling point is defined as the difference between the boiling point of the solution and the boiling point of the pure solvent.

The expression for the calculation of elevation in boiling point is:

[tex]\text{Boiling point of solution}-\text{boiling point of pure solvent}=i\times K_b\times m[/tex]

OR

[tex]\text{Boiling point of solution}-\text{Boiling point of pure solvent}=i\times K_f\times \frac{m_{solute}\times 1000}{M_{solute}\times w_{solvent}\text{(in g)}}[/tex] ......(1)

where,

Boiling point of pure solvent (benzene) = [tex]80.10^oC[/tex]

Boiling point of solution = [tex]81.20^oC[/tex]

i = Vant Hoff factor = 1 (for non-electrolytes)

[tex]K_b[/tex] = Boiling point elevation constant = [tex]2.53^oC/m[/tex]

[tex]m_{solute}[/tex] = Given mass of solute = 10 g

[tex]M_{solute}[/tex] = Molar mass of solute = ? g/mol

[tex]w_{solvent}[/tex] = Mass of solvent = 200 g

Putting values in equation 1, we get:

[tex]81.20-80.10=1\times 2.53\times \frac{10\times 1000}{M_{solute}\times 200}\\\\M_{solute}=\frac{1\times 2.53\times 10\times 1000}{1.1\times 200}\\\\M_{solute}=115g/mol[/tex]

Hence, the molar mass of solute is 115 g/mol.

A sample of hellium has a volume of 500 mL at STP. What will be its new volume be in mL if the temperature is increased to 325 K and its pressure is increased to 125 kPa?

Answers

Answer:

[tex]V_2=482.5mL[/tex]

Explanation:

Hello there!

In this case, according to the given information, it turns out possible for us to solve this problem by using the combined gas law due to the fact that we are dealing with variable volume, temperature and pressure:

[tex]\frac{P_2V_2}{T_2}=\frac{P_1V_1}{T_1}[/tex]

In such a way, we solve for the final volume, V2, considering that the initial volume, V1, is 500 mL, the initial temperature, T1, is 273 K (STP), the initial pressure, P1, is 1 atm (STP) and the final temperature, T2, is 325 K and the final pressure, P2, is 125 kPa (1.23 atm):

[tex]V_2=\frac{P_1V_1T_2}{T_1P_2} \\\\V_2=\frac{(1atm)(500mL)(325K)}{(273K)(1.23atm)} \\\\V_2=482.5mL[/tex]

Regards!

Write the cell notation for an electrochemical cell consisting of an anode where Mn (s) is oxidized to Mn2 (aq) and a cathode where Co2 (aq) is reduced to Co (s) . Assume all aqueous solutions have a concentration of 1 mol/L.

Answers

Answer:

Mn(s)/Mn^2+(aq)//Co^2+(aq)/Co(s)

Explanation:

In writing the cell notation for an electrochemical cell, the anode is written on the left hand side while the cathode is written on the right hand side. The two half cells are separated by two thick lines which represents the salt bridge.

For the cell discussed in the question; the Mn(s)/Mn^2+(aq) is the anode while the Co^2+(aq)/Co(s) half cell is the cathode.

Hence I can write; Mn(s)/Mn^2+(aq)//Co^2+(aq)/Co(s)

how does lead resemble chromium?​

Answers

Lead resembles chromium as they both are what you call heavy metals this refers to any metallic chemical element that has a relatively high density examples of heavy metals will include lead,chromium

Write the separation scheme for the isolation of triphenylmethanol from the reaction mixture once the reaction is complete. The separation begins after the addition of HCl and water to the reaction and includes the column chromatography procedure to further purify crude triphenylmethanol isolated in the day 1 procedure.

Answers

````````````````````

1. Why is it necessary to equalize the pressure(i.e, have the water level the same in each tube) before taking a volume reading?

2. Why is it important to use water that has been pre-saturated with CO2 in the gas burettes?

3.If your antacid sample had been contaminated by moisture, what effect(if any )would you expect this to have on your result

4.Explain why an'antacid is called as such,what is the role of the NAHCO3 or CACO3 in reactions?

Answers

Answer:

If you contact water with a gas at a certain temperature and (partial) pressure, the concentration of the gas in the water will reach an equilibrium ('saturation') according to Henry's law.

Explanation:

This means: if you increase the pressure (e.g. by keeping the vial closed), the CO2 concentration will increase. So it simply depends what concentration you need for your assay: 'CO2-saturated' water at low pressure or 'CO2-saturated' water at high pressure.

5. How many grams of tin metal can be produced from smelting (heating) of a 4.5 kilograms of tin (IV) oxide? (Note: Elemental tin and oxygen gas are the only products of this reaction).

Answers

Answer:

About 3500 grams of tin.

Explanation:

We want to determine amount of tin metal (in grams) that can be produced from smelting 4.5 kilograms of tin(IV) oxide.

First, write the chemical compound. Since our cation is tin(IV), it forms a 3+ charge. Oxygen has a 2- charge, so we will have two oxygen atoms. Hence, tin(IV) oxide is given by SnO₂.

By smelting it, we acquire elemental tin and oxygen gas. Hence:

[tex]\text{SnO$_2$}\rightarrow \text{Sn} + \text{O$_2$}[/tex]

(Note: oxygen is a diatomic element.)

The equation is balanced as well.

To convert from SnO₂ to only Sn, we can first convert from grams of SnO₂ to moles, use mole ratios to convert to moles of Sn, and then from there convert to grams.

Since Sn has a molar mass of 118.71 g/mol and oxygen has a molar mass of 15.999 g/mol, the molar mass of SnO₂ is:

[tex](118.71)+2(15.999) = 150.708\text{ g/mol}[/tex]

Therefore, given 4.5 kilograms of SnO₂, we can first convert this into grams using 1000 g / kg and then using the ratio:

[tex]\displaystyle \frac{1\text{ mol SnO$_2$}}{150.708\text{ g SnO$_2$}}[/tex]

We can convert this into moles.

Next, from the chemical equation, we can see that one mole of SnO₂ produces exactly one mole of Sn (and also one mole of O₂). So, our mole ratio is:

[tex]\displaystyle \frac{1\text{ mol Sn}}{1\text{ mol SnO$_2$}}[/tex]

With SnO₂ in the denominator to simplify units.

Finally, we can convert from moles Sn to grams Sn using its molar mass:

[tex]\displaystyle \frac{118.71\text{ g Sn}}{1\text{ mol Sn}}[/tex]

With the initial value and above ratios, we acquire:

[tex]\displaystyle 4.5\text{ kg SnO$_2$}\cdot \frac{1000 \text{ g SnO$_2$}}{1\text{ kg SnO$_2$}}\cdot \displaystyle \frac{1\text{ mol SnO$_2$}}{150.708\text{ g SnO$_2$}}\cdot \displaystyle \frac{1\text{ mol Sn}}{1 \text{ mol SnO$_2$}} \cdot\displaystyle \frac{118.71\text{ g Sn}}{1\text{ mol Sn}}[/tex]

Cancel like units:

[tex]=\displaystyle 4.5\cdot \frac{1000}{1}\cdot \displaystyle \frac{1}{150.708}\cdot \displaystyle \frac{1}{1} \cdot\displaystyle \frac{118.71\text{ g Sn}}{1}[/tex]

Multiply. Hence:

[tex]\displaystyle = 3544.5696...\text{ g Sn}[/tex]

Since we should have two significant figures:

[tex]=3500 \text{ g Sn}[/tex]

So, about 3500 grams of tin is produced from smelting 4.5 kg of tin(IV) oxide.

Answer:

3546g

Explanation:

start w/ tin (IV) oxide n elemental tin and oxygen gas are the only products of this reaction

SnO2 -> Sn + O2

Sn molecular wt: 119

O2 molecular wt: 32

SnO2 molecular wt:  119+32 = 151

so Sn / SnO2 wt ratio = 119 / 151

4.5 kilograms of tin (IV) oxide will produce:

= 4.5 * 119 / 151

= 3.546 kg

or 3546 grams of tin metal

no need to involve moles ;)

7. There are 7. 0 ml of 0.175 M H2C2O4 , 1 ml of water , 4 ml of 3.5M KMnO4 what is the molar concentration ofH2C2O4 ?
8. Using the data from question 7 what is the molar concentration of KMnO4 ?
10. From question number 7, what effect increasing the volume of water has on the reaction rate?

Answers

Answer:

7. 0.1021 M

8. 1.167 M

10. Increase in volume of water would lower the rate of reaction

Explanation:

7. What is the molar concentration of H₂C₂O₄ ?

Since we have 7.0 ml of 0.175 M H₂C₂O₄, the number of moles of H₂C₂O₄ present n = molarity of H₂C₂O₄ × volume of H₂C₂O₄ = 0.175 mol/L × 7.0 ml = 0.175 mol/L × 7 × 10⁻³ L = 1.225 × 10⁻³ mol.

Also, the total volume present V = volume of H2C2O4 + volume of water + volume of KMnO4 = 7.0 ml + 1 ml + 4 ml = 12 ml = 12 × 10⁻³ L

So, the molar concentration of H₂C₂O₄, M = number of moles of H₂C₂O₄/volume = n/V

= 1.225 × 10⁻³ mol/12 × 10⁻³ L

= 0.1021 mol/L

= 0.1021 M

8. Using the data from question 7 what is the molar concentration of KMnO₄ ?

Since we have 4.0 ml of 3.5 M KMnO₄, the number of moles of KMnO4 present n' = molarity of KMnO₄ × volume of KMnO₄ = 3.5 mol/L × 4.0 ml = 3.5 mol/L × 4 × 10⁻³ L = 14 × 10⁻³ mol.

Also, the total volume present V = volume of KMnO₄ + volume of water + volume of KMnO₄ = 7.0 ml + 1 ml + 4 ml = 12 ml = 12 × 10⁻³ L

So, the molar concentration of KMnO₄, M' = number of moles of KMnO₄/volume = n'/V

= 14 × 10⁻³ mol/12 × 10⁻³ L

= 1.167 mol/L

= 1.167 M

10. From question number 7, what effect increasing the volume of water has on the reaction rate?

Increase in volume of water would lower the rate of reaction because, the particles of both substances would have to travel farther distances to collide with each other, since there are less particles present in the solution and thus, the concentration of the particles would decrease thereby decreasing the rate of reaction.

What is the oxidation state of nitrogen in N ?

Answers

Answer:

+5

Explanation:

Name the following molecule

Answers

Answer:

It is a Biological Molecule

Classify each of the reactions listed below as a single-displacement, double-displacement, synthesis,
decomposition, oxidation reduction or combustion reaction.
Reaction Type
: 2Na + Cl2 → 2NaCl
: C2H4 + 3O2 → 2CO2 + 2H2O
: 2Ag2O-> 4Ag + O2
: BaCl2 + Na2SO4->BaSO4 +2NaCl
: 2AI + Fe2O3-> 2Fe + Al2O3

Answers

1. Synthesis
2. Combustion
3. Decomposition
4. Double Replacement
5. Single replacement

The SALT I agreement in 1972 brought about
O the creation of documents that officially ended the Cold War.
O the US recognition of China for the first time since 1949.
• the regulation of Chinese production or missiles that carried nuclear weapons.
• the regulation of Soviet production of missiles that carried nuclear weapons.

Answers

Answer:

the regulation of Soviet production of missiles that carried nuclear weapons

Explanation:

The aim of the SALT I agreement in 1972 was to stop or greatly reduce the arms race where world powers were stockpiling ballistic missiles and other nuclear arsenal.

Therefore, this agreement brought about the regulation of Soviet production of missiles that carried nuclear weapons

Answer:

D. the regulation of Soviet production of missiles that carried nuclear weapons.

Explanation:

how does iron I differ from iron II

Answers

Answer:

Metals tend to form positive oxidation states. Here, Iron (I) has an oxidation state of +1 while Iron (II) has an oxidation state of +2. Similarly, Lead (I) has an oxidation state of +1 while Lead(II) has an oxidation state of +2. A change in oxidation state can rather cause significant changes in the compound.


The diagram above shows the hydrides of groups 14, 15, 16, and 17 elements. Why does H20, HF, and NH3 have much higher boiling points than the rest of the molecules in their groups?

Answers

Answer:

Hydrogen Bonding

Explanation:

Hydrogen Bonding occurs when a hydrogen atom is bonded to N, O, and F atoms.

The molecules H₂O, HF, and NH₃ all experience hydrogen bonding, which is a relatively strong IMF, causing the molecules to have stronger attraction to each other. Having a stronger attraction between molecules results in more energy required to separate them, thus these molecules will have a higher boiling point than the rest of the molecules in their group.

Choose all the answers that apply. Silicon (Si) has 14 protons and an atomic mass of 28. Silicon has _____. three electron shells 14 electrons 14 neutrons two electron shells 28 electrons

Answers

Answer:

three electron shells

14 electrons

14 neutrons

Explanation:

Silicon has three electron shells arranged as follows; 2, 8, 4. This corresponds to the fact that silicon is a member of group 14 of the periodic table.

Note that, the number of protons in an atom is the same as the number of electrons in the neutral atom. Since Silicon has 14 protons, it also has 14 electrons likewise.

The mass number of silicon is 28 but number of neutrons= mass number - number of protons. Since mass number = 28, then there are 14 neutrons in silicon.

Predict the Normality of H2SO4 if 75 ml of 96.6 % pure H2SO4 added to 425 ml water. The density of H2SO4 is 1.83 g/cm3?

Answers

Explanation:

Normality is one of the concentration terms.

It is expressed as:

[tex]N=\frac{mass of the substance}{equivalent mass}* \frac{1}{volume of solution in L.}[/tex]

The volume of the solution is 425 mL.

Mass of sulfuric acid given is:

[tex]mass=volume * purity* density\\ = 75 mL * 0.966 * 1.83 g/mL\\\\=132.5 grams\\[/tex]

The equivalent mass of sulfuric acid is 49.0g/equivalents

Hence, the normality of the given solution is:

[tex]N=\frac{132.5g}{49.0g/equi.} *\frac{1000}{425mL} \\Normality=6.36N[/tex]

Answer is: 6.36N.

Why does the dehydration of an alcohol more often use concentrated sulfuric acid, H 2 S O 4 HX2SOX4, as the acid catalyst rather than dilute hydrochloric acid, H C l HCl

Answers

KAnswer:

See explanation

Explanation:

It is more common to use H2SO4 for dehydration reaction rather than HCl because HCl contains a good nucleophile,the chloride ion.

Owing to the presence of the chloride ion, a substitution reaction involving the chloride ion may also proceed also thereby affecting the elimination reaction.

Also, concentrated H2SO4 is a very good drying agent thus, as long as it is used, the alcohol substrate is completely dehydrated to yield the alkene.

Note that HCl is not a dehydrating agent.

Name of this product

Answers

Answer:

Explanation:

ethyl 3-methylbenzoate

A rigid, sealed container that can hold 26 L of gas is filled to a pressure of
5.97 atm at 374 °C. The pressure suddenly decreases to 3.64 atm. What is
the new temperature inside the container, in units of °C?

Answers

Answer:

121 °C

Explanation:

From the question given above, the following data were obtained:

Initial pressure (P₁) = 5.97 atm

Initial temperature (T₁) = 374 °C

Final pressure (P₂) = 3.64 atm

Final temperature (T₂) =?

NOTE: Volume = constant

Next, we shall convert 374 °C to Kelvin temperature. This can be obtained as follow:

T(K) = T(°C) + 273

Initial temperature (T₁) = 374 °C

Initial temperature (T₁) = 374 °C + 273

Initial temperature (T₁) = 647 K

Next, we shall determine the final temperature. This can be obtained as follow:

Initial pressure (P₁) = 5.97 atm

Initial temperature (T₁) = 647 K

Final pressure (P₂) = 3.64 atm

Final temperature (T₂) =?

P₁ / T₁ = P₂ / T₂

5.97 / 647 = 3.64 / T₂

Cross multiply

5.97 × T₂ = 647 × 3.64

5.97 × T₂ = 2355.08

Divide both side by 5.97

T₂ = 2355.08 / 5.97

T₂ = 394 K

Finally, we shall convert 394 K to celsius temperature. This can be obtained as follow:

T(°C) = T(K) – 273

Final temperature (T₂) = 394 K

Final temperature (T₂) = 394 – 273

Final temperature (T₂) = 121 °C

Thus, the new temperature is 121 °C

How many molecules (or formula units) are in 138.56 g C4H10 Express your answer using four significant figures.

Answers

Answer:

dont buy cheap and off we went

Based on the "Reactivity in Substitution Reactions" experiment, which molecule would be expected to react the fastest using AgNO3 in water-ethanol ?

Answers

Answer:

C) EtOH 1% AgNO3

What is a system called when neither energy nor matter is exchanged between the system and the surroundings?

Closed system
Free energy
Isolated system
Open system

Answers

Answer:

open system

Explanation:

Answer:

Isolated system

Explanation:

An isolated system is one that cannot exchange either matter or energy with its surroundings.

  A solution is made by dissolving 20 ml of acetic acid in 180ml of water. Calculate its volume concentration​

Answers

Answer:

water is 9/10

chemical would be 1/10

Explanation:

180/200 would be water concentration in solution

and 20/200 would be chemical solution concentration in solution (if the chemical were to be polar and mix)

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