Answer:
Lies predominantly to the left.
Explanation:
In the reaction:
NH4⁺(aq) + Br-(aq) ⇄ NH3(aq) + HBr(aq)
Conjugate acid + Ion ⇄ weak base + strong acid
HBr is a strong acid whereas NH3/NH4⁺ are the weak base and its conjugate base. A strong acid as HBr dissociates completely in solution as H⁺ and Br⁻. That means in solution you will never have HBr without dissociation doing the reaction:
lies predominantly to the left.The tosylate of (2R,3S)-3-phenylbutan-2-ol undergoes an E2 elimination on treatment with sodium ethoxide. Draw the structure of the alkene that is produced.
Answer:
(R)-but-3-en-2-ylbenzene
Explanation:
In this reaction, we have a very strong base (sodium ethoxide). This base, will remove a hydrogen producing a double bond. We know that the reaction occurs through an E2 mechanism, therefore, the hydrogen that is removed must have an angle of 180º with respect to the leaving group (the "OH"). This is known as the anti-periplanar configuration.
The hydrogen that has this configuration is the one that placed with the dashed bond (red hydrogen). In such a way, that the base will remove this hydrogen, the "OH" will leave the molecule and a double bond will be formed between the methyl and the carbon that was previously attached to the "OH", producing the molecule (R) -but-3- en-2-ylbenzene.
See figure 1
I hope it helps!
An HCl solution has a concentration of 0.09714 M. Then 10.00 mL of this solution was then diluted to 250.00 mL in a volumetric flask. The diluted solution was then used to titrate 250.0 mL of a saturated AgOH solution using methyl orange indicator to reach the endpoint.
Required:
a. What is the concentration of the diluted HCI solution?
b. If 7.93 mL of the diluted HCI solution was required to reach the endpoint, what is the concentration of OH- in solution?
c. What is the concentration of Ag+ in solution?
d. What is the Ksp expression for the dissolution of AgOH?
Answer:
a. 3.8856x10⁻³M HCl
b. 1.23x10⁻⁴M OH⁻
c. 1.23x10⁻⁴M Ag⁺
d. Ksp = [Ag⁺] [OH⁻]
Explanation:
a. The reaction that you are studying is:
HCl(aq) + AgOH(aq) → H₂O(l) + AgCl(s)
The HCl solution is diluted from 10.00mL to 250.00mL, that is:
250.00mL / 10.00mL = 25 -The solution is diluted 25 times-
As original concentration of HCl is 0.09714M, the concentration of the diluted solution is:
0.09714M / 25 =
3.8856x10⁻³M HClb. 1 mole of HCl reacts per mole of AgOH, moles of HCl that reacts are:
7.93mL = 7.93x10⁻³L × (3.8856x10⁻³mol HCl / L) = 3.0813x10⁻⁵ moles of HCl.
Based on the reaction, you have in solution
3.0813x10⁻⁵ moles of AgOH = Ag⁺ = OH⁻
The AgOH solution was 250.0mL = 0.2500L, its concentration is:
3.0813x10⁻⁵ moles OH⁻ / 0.2500L =
1.23x10⁻⁴M OH⁻c. In solution, AgOH produce Ag⁺ and OH⁻ in equals proportions, that means:
1.23x10⁻⁴M OH⁻ =
1.23x10⁻⁴M Ag⁺d. The solubility product reaction of AgOH(s) is:
AgOH(s) ⇄ Ag⁺(aq) + OH⁻(aq)
Where Ksp for this reaction is defined as:
Ksp = [Ag⁺] [OH⁻]3,3-dibromo-4-methylhex-1-yne
Explanation:
see the attachment. hope it will help you...what is ammonium nitrate
Answer:
Ammonium nitrate is a chemical compound with the chemical formula NH₄NO₃. It is a white crystalline solid consisting of ions of ammonium and nitrate.
The direction of the functional group is called?
Explanation:
they are called hydrocarbyls
pls mark me brainliest
Answer:
The first carbon atom that attaches to the functional group is referred to as the alpha carbon.
The Lewis structure of N2H2 shows ________. Group of answer choices a nitrogen-nitrogen single bond each hydrogen has one nonbonding electron pair each nitrogen has one nonbonding electron pair each nitrogen has two nonbonding electron pairs a nitrogen-nitrogen triple bond
Answer:
one bond between nitrogen and hydrogen and a double bond between the nitrogen atoms.
Explanation:
H-N=N-H
Oxygen condenses into a liquid at approximately 90 K. What temperature, in degrees Fahrenheit, does this correspond to?
Answer:
-297.67 °F
Explanation:
Oxygen condenses into a liquid at approximately 90 K. We can convert any temperature in the Kelvin scale (absolute scale) to the Fahrenheit scale using the following expression.
°F = (K − 273.15) × 9/5 + 32
°F = (90 − 273.15) × 9/5 + 32
°F = (-183.15) × 9/5 + 32
°F = -329.67 + 32
°F = -297.67 °F
Two elements represents by the letter Q and R atomic number 9 and 12 respectively. Write the electronic configuration of R
Answer:
Atomic no = 12 = Mg
Explanation:
It is given that,
The atomic number of two elements that are represented by letter Q and R are 9 and 12.
We need to write the electronic configuration of R. Atomic number shows the number of protons in atom.
For R, atomic number = 12
Its electronic configuration is : 2,8,2
It has two valance electrons in its outermost shell. The element is Magnesium (Mg).
For the reaction CO2(g) + H2(g)CO(g) + H20(g)
∆H°=41.2 kJ and ∆S°=42.1 J/K
The standard free energy change for the reaction of 1.96 moles of Co2(g) at 289 K, 1 atm would be_________KJ.
This reaction is (reactant, product)___________ favored under standard conditions at 289 K.
Assume that ∆H° and ∆S° are independent of temperature.
Answer:
The ΔG° is 29 kJ and the reaction is favored towards reactant.
Explanation:
Based on the given information, the ΔH°rxn or enthalpy change is 41.2 kJ, the ΔS°rxn or change in entropy is 42.1 J/K or 42.1 * 10⁻³ kJ/K. The temperature given is 289 K. Now the Gibbs Free energy change can be calculated by using the formula,
ΔG° = ΔH°rxn - TΔS°rxn
= 41.2 kJ - 289 K × 42.1 × 10⁻³ kJ/K
= 41.2 kJ - 12.2 kJ
= 29 kJ
As ΔG° of the reaction is positive, therefore, the reaction is favored towards reactant.
Which of the following elements is in the same group as Sulfur (S)?
Answer:
PLEASE SHOW ME THE ELEMENTS OR I WOULD ENLIST ALL THE ELEMENTS.
Explanation:
Group 6A (or VIA) of the periodic table are the chalcogens: the nonmetals oxygen (O), sulfur (S), and selenium (Se), the metalloid tellurium (Te), and the metal polonium (Po)
When the following molecular equation is balanced using the smallest possible integer coefficients, the values of these coefficients are:
________hydrochloric acid (aq) + ___________oxygen (g) → _________water (l) + ________chlorine (g)
Answer:
The coefficients are; 4, 0, 2, 2
Explanation:
The equation is given as;
HCl + O2 --> H2O + Cl2
Upon balancing the equation, we have;
4HCl + O2 --> 2H2O + 2Cl2
Will a precipitate of magnesium fluoride form when 300. mL of 1.1 × 10 –3 M MgCl 2 are added to 500. mL of 1.2 × 10 –3 M NaF? [K sp (MgF 2) = 6.9 × 10 –9]
Answer:
No precipitate is formed.
Explanation:
Hello,
In this case, given the dissociation reaction of magnesium fluoride:
[tex]MgF_2(s)\rightleftharpoons Mg^{2+}+2F^-[/tex]
And the undergoing chemical reaction:
[tex]MgCl_2+2NaF\rightarrow MgF_2+2NaCl[/tex]
We need to compute the yielded moles of magnesium fluoride, but first we need to identify the limiting reactant for which we compute the available moles of magnesium chloride:
[tex]n_{MgCl_2}=0.3L*1.1x10^{-3}mol/L=3.3x10^{-4}molMgCl_2[/tex]
Next, the moles of magnesium chloride consumed by the sodium fluoride:
[tex]n_{MgCl_2}^{consumed}=0.5L*1.2x10^{-3}molNaF/L*\frac{1molCaCl_2}{2molNaF} =3x10^{-4}molMgCl_2[/tex]
Thus, less moles are consumed by the NaF, for which the moles of formed magnesium fluoride are:
[tex]n_{MgF_2}=3x10^{-4}molMgCl_2*\frac{1molMgF_2}{1molMgCl_2}=3x10^{-4}molMgF_2[/tex]
Next, since the magnesium fluoride to magnesium and fluoride ions is in a 1:1 and 1:2 molar ratio, the concentrations of such ions are:
[tex][Mg^{2+}]=\frac{3x10^{-4}molMg^{+2}}{(0.3+0.5)L} =3.75x10^{-4}M[/tex]
[tex][F^-]=\frac{2*3x10^{-4}molMg^{+2}}{(0.3+0.5)L} =7.5x10^{-4}M[/tex]
Thereby, the reaction quotient is:
[tex]Q=(3.75x10^{-4})(7.5x10^{-4})^2=2.11x10^{-10}[/tex]
In such a way, since Q<Ksp we say that the ions tend to be formed, so no precipitate is formed.
Regards.
Nitric oxide (NO) can be formed from nitrogen, hydrogen and oxygen in two steps. In the first step, nitrogen and hydrogen react to form ammonia: (g) (g) (g) In the second step, ammonia and oxygen react to form nitric oxide and water: (g) (g) (g) (g) Calculate the net change in enthalpy for the formation of one mole of nitric oxide from nitrogen, hydrogen and oxygen from these reactions. Round your answer to the nearest .
Answer: [tex]\Delta H = -272.25kJ[/tex] for 1 mole of NO.
Explanation: Hess' Law of Constant Summation or Hess' Law states that the total enthalpy change of a reaction with multiple stages is the sum of the enthalpies of all the changes.
For this question:
1) [tex]N_{2}_{(g)} + 3H_{2}_{(g)}[/tex] => [tex]2NH_{3}_{(g)}[/tex] [tex]\Delta H=-92kJ[/tex]
2) [tex]4NH_{3}_{(g)}+5O_{2}_{(g)}[/tex] => [tex]4NO_{(g)}+6H_{2}O_{(g)}[/tex] [tex]\Delta H=-905kJ[/tex]
Amonia ([tex]NH_{3}_{(g)}[/tex]) appeares as product in the first equation and as reagent in the 2 reaction, so when adding both, there is no need to inverse reactions. However, in the 2nd, there are 4 moles of that molecule, so to cancel it, you have to multiply by 2 the first chemical equation and enthalpy:
[tex]2N_{2}_{(g)} + 6H_{2}_{(g)}[/tex] => [tex]4NH_{3}_{(g)}[/tex] [tex]\Delta H=-184kJ[/tex]
Now, adding them:
[tex]2N_{2}_{(g)} + 6H_{2}_{(g)}[/tex] => [tex]4NH_{3}_{(g)}[/tex] [tex]\Delta H=-184kJ[/tex]
[tex]4NH_{3}_{(g)}+5O_{2}_{(g)}[/tex] => [tex]4NO_{(g)}+6H_{2}O_{(g)}[/tex] [tex]\Delta H=-905kJ[/tex]
[tex]2N_{2}_{(g)}+6H_{2}_{(g)}+5O_{2}_{(g)}=>4NO_{(g)}+6H_{2}O_{(g)}[/tex] [tex]\Delta H = -185-905[/tex]
[tex]2N_{2}_{(g)}+6H_{2}_{(g)}+5O_{2}_{(g)}=>4NO_{(g)}+6H_{2}O_{(g)}[/tex] [tex]\Delta H = -1089kJ[/tex]
Note net enthalpy is for the formation of 4 moles of nitric oxide.
For 1 mole:
[tex]\Delta H = \frac{-1089}{4}[/tex]
[tex]\Delta H=-272.25kJ[/tex]
To form 1 mol of nitric oxide from nitrogen, oxygen and hydrogen, net change in enthalpy is [tex]\Delta H=-272.25kJ[/tex].
You wish to construct a galvanic cell with the anode consisting of a Ni electrode in a 1.0 M Ni(NO3)2 solution. What would be the highest standard cell potential if used as the cathode in this galvanic cell?
Answer:
Au^3+(aq) +3e ------> Au(s). 1.50 V
Explanation:
When we construct the galvanic cell, our intention is to produce energy by spontaneous electrochemical reactions. In order to have a spontaneous electrochemical reaction, E°cell must be positive. The more positive the value of E°cell, the more spontaneous the reaction is.
E°cell= E°cathode - E°anode
If E°cathode= 1.50 V
E°anode= -0.25 V
E°cell= 1.50 -(-0.25)
E°cell= 1.75 V
Hence the process; Au^3+(aq) +3e ------> Au(s) yields the highest standard cell potential
3. Identify the reagents you would use to convert 1-bromopentane into each of the following compounds: (a) Pentanoic acid (b) Hexanoic acid (c) Pentanoyl chloride (d) Hexanamide (e) Pentanamide (f) Ethyl hexanoate
Answer:
Explanation:
a )
CH₃CH₂CH₂CH₂CH₂Br + KOH ⇒ CH₃CH₂CH₂CH₂CH₂OH
CH₃CH₂CH₂CH₂CH₂OH + acidic potassium dichromate ⇒ CH₃CH₂CH₂CH₂COOH
b )
CH₃CH₂CH₂CH₂CH₂Br + KCN ⇒ CH₃CH₂CH₂CH₂CH₂CN Hydrolysis ⇒ CH₃CH₂CH₂CH₂CH₂COOH .
c )
CH₃CH₂CH₂CH₂CH₂Br + KOH ⇒ CH₃CH₂CH₂CH₂CH₂OH
CH₃CH₂CH₂CH₂CH₂OH + acidic potassium dichromate ⇒ CH₃CH₂CH₂CH₂COOH + SOCl₂ ( thionyl chloride ) ⇒ CH₃CH₂CH₂CH₂COCl
d )
CH₃CH₂CH₂CH₂CH₂Br + KCN ⇒ CH₃CH₂CH₂CH₂CH₂CN Hydrolysis ⇒ CH₃CH₂CH₂CH₂CH₂COOH + PCC ( NH₃ ) ⇒ CH₃CH₂CH₂CH₂CH₂CONH₂
e )
CH₃CH₂CH₂CH₂CH₂Br + KCN ⇒ CH₃CH₂CH₂CH₂CH₂CN Hydrolysis ⇒ CH₃CH₂CH₂CH₂CH₂COOH + C₂H₅OH ( Ethyl alcohol + H⁺ )⇒
CH₃CH₂CH₂CH₂CH₂COOC₂H₅ ( ethyl hexanoate )
Calculate the pH of a 0.20 M NH3/0.20 M NH4Cl buffer after the addition of 25.0 mL of 0.10 M HCl to 65.0 mL of the buffer.
Answer:
Explanation:
For pH of a buffer solution , the formula is
pH = pKa + log [ Base ] / [ conjugate acid ]
= pKa + log [ NH₃ ] / [ NH₄⁺ ]
Ka = Kw / Kb
Kb for NH₄OH = 1.8 x 10⁻⁵
Ka = 10⁻¹⁴ / 1.8 x 10⁻⁵
= 5.6 x 10⁻¹⁰
pH = - log ( 5.6 x 10⁻¹⁰ ) + log 0.2 / 0.2
= 10 - log 5.6
= 9.25
Effect of addition of HCl
H⁺ of HCl will react with NH₃ to produce NH₄⁺
25 mL of .1 HCl = 2.5 mM of HCl
25 mL of .1 NH₄⁺ = 2.5 mM of NH₄⁺
65 mL of .2 M NH₃ = 13 mM of NH₃
65 mL of .2 M NH₄⁺ = 13 mM of NH₄⁺
NH₃ + H⁺ = NH₄⁺
NH₄⁺ formed = 2.5 + 13 mM
15.5 mM of NH₄⁺
NH₃ = 13 mM
Concentration of NH₃ = 13 / 90
Concentration of NH₄⁺ = 15.5 / 90
pH of final buffer mixture
= 9.6 + log 13 / 15.5
= 9.25 - .076
= 9.174
The pH value is mathematically given as
pH= -6.332.
What is the pH of a 0.20 M NH3/0.20 M NH4Cl buffer?Question Parameters:
the pH of a 0.20 M NH3/0.20 M NH4Cl buffer
the addition of 25.0 mL of 0.10 M HCl to 65.0 mL of the buffer.
Generally, the equation for the Chemical Reaction is mathematically given as
HCl + NH3 --> NH4^+ + Cl^-
Therefore
pH= pka + log(13/14).
pH= -6.3 + log 0.93.
pH= -6.3+ (-0.032).
pH= -6.332.
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If 2.9g of water is heated from 23.9C to 98.9C, how much heat (in calories) was added to the water?
Answer:
Explanation:
we know that
ΔH=m C ΔT
where ΔH is the change in enthalpy (j)
m is the mass of the given substance which is water in this case
ΔT IS the change in temperature and c is the specific heat constant
we know that given mass=2.9 g
ΔT=T2-T1 =98.9 °C-23.9°C=75°C
specific heat constant for water is 4.18 j/g°C
therefore ΔH=2.9 g*4.18 j/g°C*75°C
ΔH=909.15 j
candium forms the ion Sc3+. How many bromite ions could bond with Sc3+, and what would be the chemical formula?
a.3 bromite ions, Sc(Broa)2
b.2 bromite ions, Sc(BrO4)3
c.3 bromite ions, Sc(Broz)
d.2 bromite ions, Sc (BrO2)2
Answer: 3 bromite ions and [tex]Sc(BrO_2)_3[/tex]
Explanation:
For formation of a neutral ionic compound, the charges on cation and anion must be balanced. The cation is formed by loss of electrons by metals and anions are formed by gain of electrons by non metals.
Here scandium is having an oxidation state of +3 called as [tex]Sc^{3+}[/tex] cation and bromite is an anion with oxidation state of -1 called as [tex]BrO_2^-[/tex]. Thus 1 Scandium ion combines with three bromite ions and their oxidation states are exchanged and written in simplest whole number ratios to give neutral [tex]Sc(BrO_2)_3[/tex]
Answer:
3 bromite ions and
Explanation:
Suppose that a 100 mL sample of ideal gas is held in a piston-cylinder apparatus. Its volume could be increased to 200 mL by
Answer:
e. reducing the pressure from 608 torr to 0.40 atm at constant temperature.
Explanation:
According to Boyle's law when a gas is at the same temperature and there is a mass in a closed container so the pressure and the volume changes in the opposite direction
So here the equation is
[tex]P_1V_1=P_2V_2[/tex]
Now we choose the options
where,
[tex]V_1 = 100\ mL = 0.1\ L\\\\V_2 = 200\ mL = 0.2\ L[/tex]
[tex]P_1 = 608\ torr = 0.8\ atm \\\\P_2= 0.4\ atm[/tex]
Now applying these values to the above equation
So,
P1V1=P2V2
[tex]P_1V_1=P_2V_2[/tex]
[tex]0.8\times0.1 = 0.4\times0.2[/tex]
0.8 = 0.8
Hence, it is proved
1.40 m3 is how many mL
[tex] \LARGE{ \boxed{ \rm{ \pink{Solution:}}}}[/tex]
We know, 1 m³ of space can hold 1000 l of the substance.
⇛ 1 m³ = 1000 l----(1)
And, 1 l is 1000 times more than 1 ml
⇛ 1 l = 1000 ml------(2)
So, From (1) and (2),
⇛ 1 m³ = 1000 × 1000 ml
⇛ 1m³ = 1000000 ml
We had to find,
⇛ 1.40 m³ = 1.40 × 1000000 ml
⇛ 1.40 m³ = 140/100 × 1000000 ml
⇛ 1.40 m³ = 1400000 ml
⇛ 1.40 m³ = 14,00,000 ml / 14 × 10⁵ ml / 1.4 × 10⁶ ml
☃️ So, 1.40 m³ = 14 × 10⁵ ml / 1.4 × 10⁶ ml.
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Advantages of using a resource person in handling the first aid lesson
The advantage of a resource person would be that it will provide a hands-on activity that will allow the students to experience spacing between organs and on the body of the person.
It will also allow them to identify challenges when doing this and will engage them more in the activity and lesson.
Answer:A resource person add knowledge to the course
Explanation:
what is a chemical that is safe to use in food but in small amounts?
Answer:
Toxins
Explanation:
f the Ksp for HgBr2 is 2.8×10−14, and the mercury ion concentration in solution is 0.085 M, what does the bromide concentration need to be for a precipitate to occur?
Answer:
0.057 M
Explanation:
Step 1: Given data
Solubility product constant (Ksp) for HgBr₂: 2.8 × 10⁻⁴
Concentration of mercury (II) ion: 0.085 M
Step 2: Write the reaction for the solution of HgBr₂
HgBr₂(s) ⇄ Hg²⁺(aq) + 2 Br⁻
Step 3: Calculate the bromide concentration needed for a precipitate to occur
The Ksp is:
Ksp = 2.8 × 10⁻⁴ = [Hg²⁺] × [Br⁻]²
[Br⁻] = √(2.8 × 10⁻⁴/0.085) = 0.057 M
The enthalpy change for a chemical reaction is: a. the temperature change b. the amount of heat given off or absorbed c. related to molar volume d. none of the above
Answer:
b. the amount of heat given off or absorbed
Explanation:
Hello,
In this case, we should take into account a formal definition of enthalpy change such as an energetic change that occurs in a system when matter is transformed by a given chemical reaction from reactants to products. Thus, such energetic change is macroscopically exhibited and it is related with either a temperature increase or decrease; it means that if a reaction exhibits a temperature increase, we say that heat was given off and if the temperature exhibits a decrease, we say that heat is absorbed. For that reason, answer is b. the amount of heat given off or absorbed.
Regards.
While balancing a chemical equation, we change the _____ to balance the number of atoms on each side of the equation.
Answer:
While balancing a chemical equation, we change the coefficient to balance the number of atoms on each side of the equation
Explanation:
While balancing a chemical equation, we change the coefficient to balance the number of atoms on each side of the equation.
What is chemical equation?To summarize in chemistry terms, a chemical equation depicts the initial chemicals, or reactants, on the left-hand side and the final compounds, or products, just on right-hand side, divided by an arrow. In the chemical equation, the number of atoms in each element as well as the total charge are the same on opposite of the equation's sides.
Chemical equations are used in chemistry to depict chemical processes by writing the reactants and products in terms of their corresponding chemical formulas. While balancing a chemical equation, we change the coefficient to balance the number of atoms on each side of the equation.
Therefore, while balancing a chemical equation, we change the coefficient to balance the number of atoms on each side of the equation.
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Use the following equation to determine the charge on bromine when it dissociates from sodium and determine whether it is being oxidized or reduced: Cl2 + NaBr -> NaCl + Br2A. It starts with a charge of 0 and is oxidized. B. It starts with a charge of -1 and is reduced. C. It starts with a charge of 0 and is reduced. D. It starts with a charge of -1 and is oxidized.
It starts with a charge of 0 and is oxidized. Hence, option A is correct.
What is a chemical equation?A chemical reaction is a representation of symbols of the elements to indicate the number of substances and moles of reactant and product.
[tex]Cl_2 + NaBr[/tex] ->[tex]NaCl + Br_2[/tex]
The oxidation number of bromine changes from -1 (in NaBr) to 0 (in Br
2). Thus, NaBr is oxidized.
The oxidation number of chlorine changes from 0 to -1. Thus, chlorine is reduced.
Hence, option A is correct.
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Using these metal ion/metal standard reduction potentials Cd2+(aq)|Cd(s) Zn2+(aq)|Zn(s) Ni2+(aq)|Ni(s) Cu2+(aq)/Cu(s) -0.40 V -0.76 V ‑0.25 V +0.34 V Calculate the standard cell potential for the cell whose reaction is Ni2+(aq) + Zn(s) →Zn2+(aq)+ Ni(s)
Answer: The standard cell potential for the cell is +0.51 V
Explanation:
Given : [tex]E^0_{Ni^{2+}/Ni}=-0.25V[/tex]
[tex]E^0_{Zn^{2+}/Zn}=-0.76V[/tex]
The given reaction is:
[tex]Ni^{2+}(aq)+Zn(s)\rightarrow Zn^{2+}(aq)+Ni(s)[/tex]
As nickel is undergoing reduction, it acts as cathode and Zinc is undergoing oxidation, so it acts as anode.
[tex]E^0_{cell}=E^0_{cathode}-E^0_{anode}[/tex]
where both [tex]E^0[/tex] are standard reduction potentials.
Thus putting the values we get:
[tex]E^0_{cell}=-0.25-(-0.76)[/tex]
[tex]E^0_{cell}=0.51V[/tex]
Thus the standard cell potential for the cell is +0.51 V
Q 11.20: What is the product of the reaction between t-BuCl and MeOH? A : t-BuOH B : MeOCl C : t-BuOMe D : (CH3)2CCH2
Answer:
C : t-BuOMe
Explanation:
The tert -butanol is a tertiary alcohol and when chloride ion attacks the carbocation, it forms t-BuCl.
The reaction of tert-butyl chloride or t-BuCl ((CH3)3C−Cl) with methanol and MeOH (CH3−OH) gives the product tert-Butyl methyl ether or t-BuOMe (CH3)3C−OCH3:
(CH3)3C−Cl + CH3−OH => (CH3)3C−OCH3 + HCl
Hence, the correct asnwer is C : t-BuOMe
A balloon is filled to a volume of 1.50 L with 3.00 moles of gas at 25 °C. With pressure and temperature held constant, what will be the volume (in L) of the balloon if 0.50 moles of gas are released?
Answer:
Volume : 1.25 L
Explanation:
We are given here that the volume ( V[tex]_1[/tex] ) = 1.50 Liters, the initial moles ( held at 25 °C ) = 3.00 mol, and the final moles ( n[tex]_2[/tex] ) = 3.00 - 0.5 = 2.5 mol. The final mol is calculated given that 0.50 mol of gas are released from the prior 3.00 moles of gas.
Volume ( V[tex]_1[/tex] ) = 1.50 L,
Initial moles ( n[tex]_1[/tex] ) = 3.00 mol,
Final Volume ( n[tex]_2[/tex] ) = 3.00 - 0.5 = 2.5 mol
Applying the combined gas law, we can calculate the final volume ( V[tex]_2[/tex] ).
P[tex]_1[/tex]V[tex]_1[/tex] / n[tex]_1[/tex]T[tex]_1[/tex] = P[tex]_2[/tex]V[tex]_2[/tex] / n[tex]_2[/tex]T[tex]_2[/tex] - we know that the pressure and temperature are constant, and therefore we can apply the following formula,
V[tex]_1[/tex] / n[tex]_1[/tex] = V[tex]_2[/tex] / n[tex]_2[/tex] - isolate V[tex]_2[/tex],
V[tex]_2[/tex] = V[tex]_1[/tex] n[tex]_2[/tex] / n[tex]_1[/tex] = 1.50 L [tex]*[/tex] 2.5 mol / 3.00 mol = ( 1.5 [tex]*[/tex] 2.5 / 3 ) L = 1.25 L
The volume of the balloon will be 1.25 L.
An 80L capacity steel cylinder contains H2 at a pressure of 110 atm and 30 ° C, after extracting a certain amount of gas, the pressure is 80 atm at the same temperature. How many liters of hydrogen (measured under normal conditions) have been extracted?
Answer:
2200 L
Explanation:
Ideal gas law:
PV = nRT,
where P is absolute pressure,
V is volume,
n is number of moles,
R is universal gas constant,
and T is absolute temperature.
The initial number of moles is:
(110 atm) (80 L) = n (0.0821 L atm / K / mol) (30 + 273.15) K
n = 353.58 mol
After some gas is removed, the number of moles remaining is:
(80 atm) (80 L) = n (0.0821 L atm / K / mol) (30 + 273.15) K
n = 257.15 mol
The amount of gas removed is therefore:
n = 353.58 mol − 257.15 mol
n = 92.43 mol
At normal conditions, the volume of this gas is:
PV = nRT
(1 atm) V = (92.43 mol) (0.0821 L atm / K / mol) (273.15 K)
V = 2162.5 L
Rounded, the volume is approximately 2200 liters.
