Answer:
dont buy cheap and off we went
Predict the missing component in the nuclear equation.
238 92U → 234 90Th + X
A. 4 2He
B. 0 -1e
C. 0 0v
Answer:
A
Explanation:
helium (alpha particle)
how many mols of nh4cl are present in 279.0ml of a 0.975 M nh4cl soution?
Answer:
how many mols of nh4cl are present in 279.0ml of a 0.975 M nh4cl soution?
At a constant temperature, a sample of gas occupies 1.5 L at a pressure of 2.8 ATM. What will be the pressure of this sample, in atmospheres, if the new volume is 0.92 L?
Using boyles law
[tex]\boxed{\sf v\propto \dfrac{1}{p}}[/tex]
[tex]\\ \sf\longmapsto P_1V_1=P_2V_2[/tex]
[tex]\\ \sf\longmapsto P_2=\dfrac{P_1V_1}{V_2}[/tex]
[tex]\\ \sf\longmapsto P_2=\dfrac{2.8\times 1.5}{0.92}[/tex]
[tex]\\ \sf\longmapsto P_2=\dfrac{4.2}{0.92}[/tex]
[tex]\\ \sf\longmapsto P_2=4.56atm[/tex]
[tex]\\ \sf\longmapsto P_2\approx 4.6atm[/tex]
Answer:
[tex]\boxed {\boxed {\sf 4.6 \ atm}}[/tex]
Explanation:
We are asked to find the new pressure given a change in volume. We will use Boyle's Law, which states the volume of a gas is inversely proportional to the pressure. The formula for this law is:
[tex]P_1V_1= P_2V_2[/tex]
Initially, the gas occupies 1.5 liters at a pressure of 2.8 atmospheres.
[tex]1.5 \ L * 2.8 \ atm = P_2V_2[/tex]
The volume is changed to 0.92 liters, but the pressure is unknown.
[tex]1.5 \ L * 2.8 \ atm = P_2* 0.92 \ L[/tex]
We are solving for the final pressure, so we must isolate the variable P₂. It is being multiplied by 0.92 liters. The inverse operation of multiplication is division, so we divide both sides by 0.92 L.
[tex]\frac {1.5 \ L * 2.8 \ atm}{0.92 \ L} = \frac{P_2* 0.92 \ L}{0.92 \ L}[/tex]
[tex]\frac {1.5 \ L * 2.8 \ atm}{0.92 \ L}= P_2[/tex]
The units of liters cancel each other out.
[tex]\frac {1.5 * 2.8 \ atm}{0.92 }=P_2[/tex]
[tex]\frac {4.2}{0.92} \ atm= P_2[/tex]
[tex]4.565217391 \ atm = P_2[/tex]
The original measurements of pressure and volume have 2 significant figures, so our answer must have the same. For the number we calculated, that is the tenths place. The 6 in the hundredth place tells us to round the 5 up to a 6.
[tex]4.6 \ atm \approx P_2[/tex]
The pressure is approximately 4.6 atmospheres.
calculate the volume of 20.5g of oxygen occupied at standard temperature and pressure.what the volume
Answer :
volume of a gas = weight * 22.4 l / gram molecular weight
volume of o2 = ?
weight given = 20.5 g
gram molecular weight of oxygen = 32 (because of 2 oxygen atoms )
volume of oxygen = 20.5 * 22.4 / 32
volume of oxygen = 14.35 liters
Explanation:
hope this helps you
if wrong just correct me
Cho biết độ tan của NH4Cl trong nước ở 20oC và 70oC lần lượt là 37,2 g/100 gam nước và 60,2 gam/100 g nước. Hòa tan 166,8 gam NH4Cl vào 400 gam nước ở 70oC thu được dung dịch X. Sau đó, hạ nhiệt độ dung dịch X xuống 20oC. Tính khối lượng (gam) NH4Cl kết tinh lại trong X?
Answer: Hợp chất CTHH 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 70 °C
Actini(III) hydroxide Ac(OH)3 0,0022
Amonia NH3 1176 900 702 565 428 333 188
Amoni azua NH4N3 16 25,3 37,1
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hehe
calcium is added to water,the liberated gas is
Answer:
In both cases, the gas evolved is H2. When calcium reacts with water the heat evolved is not suffcient for hydrogen to catch fire. On the other hand, sodium metal reacts with water violently and in this case a lot of heat is evolved which is sufficient for hydrogen to catch fire.
Explanation:
may this answer is helpful for you
Hydrogen
The reaction is given by
[tex]\boxed{\sf {Ca\atop Calcium}+{H_2O\atop Water}\longrightarrow {Ca(OH)_2\atop Calcium\:Hydroxide}+{H_2\atop Hydrogen}}[/tex]
Balanced equation:-
[tex]\boxed{\sf {Ca\atop Calcium}+{2H_2O\atop Water}\longrightarrow {Ca(OH)_2\atop Calcium\:Hydroxide}+{H_2\atop Hydrogen}}[/tex]
Which substance has the highest boiling point?
Select the correct answer below:
A) ethyl ether
B) ethyl alcohol
C) water
D) these all have the same boiling point
Answer:
D) these all have the same boiling point
Which redox reaction would most likely occur if silver and copper metal were added to a solution that contained silver and copper ions?
A. Cu + Agt Cu2+ + 2Ag
B. Cu2+ + 2Ag* → Cu + 2Ag
C. Cu2+ + 2Ag → Cu + 2Ag+
D. Cu + 2Ag Cu²+ + 2Ag+
give the wrong answer and I'm reporting
Answer:
B
Explanation:
b/c copper is readuction agent
The most likely redox reaction that would occur if silver and copper metal were added to a solution that contained silver and copper ions is [tex]\rm Cu^{2+} + 2Ag \rightarrow Cu + 2Ag^+[/tex]. The correct answer is option C.
Redox reaction is a reaction in which reduction and oxidation takes place simultaneously.
In this reaction:
[tex]\rm Cu^{2+} + 2Ag \rightarrow Cu + 2Ag^+[/tex]
Copper metal has a higher reduction potential than silver metal, which means that it will be oxidized to [tex]\rm Cu^{2+}[/tex] ions before silver metal is oxidized to [tex]\rm Ag^+[/tex] ions.
The [tex]\rm Cu^{2+}[/tex] ions in the solution will then react with the silver metal to form [tex]\rm Ag^+[/tex] ions and Copper metal. This reaction is an example of a displacement reaction, where a more reactive metal removes a less reactive metal from its compound.
Therefore, option C. [tex]\rm Cu^{2+} + 2Ag \rightarrow Cu + 2Ag^+[/tex] is the correct answer.
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g An aqueous solution of nitric acid is standardized by titration with a 0.137 M solution of calcium hydroxide. If 19.0 mL of base are required to neutralize 21.8 mL of the acid, what is the molarity of the nitric acid solution
Answer:
M of HNO₃ is 0.119M
Explanation:
A basic concept of titration is that in equivalence point:
mmoles of acid = mmoles of base
We have data from base and we only have data from volume of acid.
In a case our titration is a strong acid against a strong base.
We apply formula:
M of acid . Vol of acid = M of base . Vol of base
M of acid . 21.8 mL = 0.137M . 19 mL
M of acid = (0.137M . 19 mL) / 21.8 mL
M of acid = 0.119 M
When we neutralize all the titrant we reach the equivalence point.
At this point, pH = 7
2HNO₃ + Ca(OH)₂ → Ca(NO₃)₂ + 2H₂O
Starting from (R)-3-methylhex-1-yne as the substrate at the center of your page, draw a reaction map showing the regiochemical and stereochemical outcome or outcomes for each of the following series of reagents. Name each of your products, including stereochemical designations for any chirality centers that are generated.
a. HgSO4, H2SO4, H2O
b. 1. 9-BBN; 2. H2O2, NaOH
c. Br2, CCl4
d. HBr
Solution :
A substrate is defined as the chemical species that are being observed in the chemical reaction where the substrate reacts with a reagent and forms a product. It can also be referred to the surface where some other chemical reactions are performed.
Stereochemistry is defined as the study of relative spatial arrangement of the atoms which forms the structure of the molecules and their respective manipulations.
In the context, the products including the stereochemical designations for any chirality centers starting from the (R)-3-methylhex-1-yne as the substrate are attached below.
what is valency of an atom?
The number of replaceable electrons in an atom is called its valency.
Examples
Monovalent - HydrogenDivalent - OxygenValency = 8 - Number of electron in last shell [When number of electrons in last shell > 4]Valency = Number of electron in last shell [When number of electrons in last shell < 4]Thanks !
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Answer:
the combining capacity if an atom is know as valency.
the property of an element that determines the number of other atimd with an aton if the element can combine.
How many grams of magnesium chloride can be produced from 2.30 moles of chlorine gas reacting w excess magnesium Mg(s)+Cl2(g)->MgCl2(s)
The mass of magnesium chloride produced from 2.30 moles of chlorine gas is 218.99 grams.
How to calculate moles in stoichiometry?Stoichiometry refers to the study and calculation of quantitative (measurable) relationships of the reactants and products in chemical reactions.
According to this question, magnesium reacts with chlorine gas to form magnesium chloride as follows:
Mg + Cl₂ → MgCl₂
Based on the above chemical equation, 1 mole of chlorine gas forms 1 mole of magnesium chloride.
This means that 2.30 moles of chlorine gas will 2.30 moles of magnesium chloride.
Next, we convert moles of magnesium chloride to mass as follows:
molar mass of magnesium chloride = 95.211g/mol
mass of magnesium chloride = 95.211 × 2.30 = 218.99 grams.
Therefore, 218.99 grams of magnesium chloride will be formed.
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PLEASE HELP ASAP
A total of 132.33g C3H8 is burned in 384.00 g O2. Use the following questions to determine the amounts of products formed.
• How many grams of CO2 and H2O will be produced? (2 points)
b. If the furnace is not properly adjusted, the products of combustion can include other gases, such as CO and unburned hydrocarbons. If only 269.34 g of CO2 were formed in the above reaction, what would the percent yield be? (2 points)
1. Draw the condensed structural formula of sodium benzoate showing all charges, atoms including any lone pairs in the side chain functional group, and all sigma and pi bonds.
2. Draw the condensed structural formula of benzoic acid showing all atoms including any lone pairs in the side chain functional group, and all sigma and pi bonds. Indicate the acidic hydrogen.
3. Draw the condensed structural formula of tetrahydrofuran (THF) showing all heteroatoms plus their lone pairs and all sigma and pi bonds.
The structures are shown in the image attached.
A structural formula is the representation of the molecule in which all atoms and bonds in the molecule are shown.
Since the question requires that all the lone pairs, formal charges and sigma and pi bonds should be shown, then the simple condensed structural formula becomes insufficient in this case.
I have attached images of the structural formula of sodium benzoate (image 1), benzoic acid (image 2) and tetrahydrofuran (image 3).
All the formal charges, lone pairs as well as sigma and pi bonds are fully shown.
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Which phenomenon explained below is an example of deposition?
Select the correct answer below:
A) Hail is formed from water droplets lifted by air currents to an altitude where they turn into pellets of ice.
B) Frost forms when cold evening temperatures convert the humidity in the air to thin layers of ice on the ground.
C) In the winter, the top few inches of a pond turn to ice.
D) The visible cloud arising from a boiling tea kettle is not actually steam, but droplets of liquid water that form as the
steam cools in the air.
Answer:
b
Explanation:
deposition is when water turns from gas to solid. b is the only one that fits
Deposition is frost forms when cold evening temperatures convert the humidity in the air to thin layers of ice on the ground.
What is deposition?Deposition is a process that involves collection of large mass or when mean distance between molecules are reduced. It can also be explained as gathering of substances together to form a larger mass.
Therefore, the phenomenon explained in the given example about deposition is frost forms when cold evening temperatures convert the humidity in the air to thin layers of ice on the ground.
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cesium-131 has a half life of 9.7 days. what percent of a cesium-131 sample remains after 60 days?
Explanation:
From the question given above, the following data were obtained:
Half-life (t½) = 9.7 days
Time (t) = 60 days
Percentage remaining after 60 days =?Next, we shall determine the number of half-lives that has elapsed. This can be obtained as follow:
Half-life (t½) = 9.7 days
Time (t) = 60 days
Number of half-lives (n) =?
n = t / t½
n = 60 / 9.7Finally, we shall determine the percentage remaining. This can be obtained as follow:
Let the original amount be N₀
Let the amount remaining be N
Number of half-lives (n) = 60 / 9.7
N = N₀ / 2ⁿ
Divide both side by N₀
N/N₀ = 1/2ⁿ
N/N₀ = 1 / 2⁽⁶⁰÷⁹•⁷⁾
N/N₀ = 0.0137
Multiply by 100 to express in percentage
N/N₀ = 0.0137 × 100
N/N₀ = 1.37%Therefore, the percentage remaining after 60 days is 1.37%
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11 Explain how you would obtain solid lead carbonate from a mixture of lead carbonate and sodium chloride
Explanation:
Add water, Na2CO3 dissolves, filter, PbCO3 stays in the paper and dissolved Na2CO3 goes through as the solution. Dry the PbCO3 and you have the dry solid.
OR
Add water to dissolve then filter to obtain PbCo3 as you're residue and Na2Co3 as the filtrate. Dry the insoluble PbCo3 between filter papers and you obtain solid PbCo3
Which subshells are found in each of the following shells
electron subshell - M shell
Answer:
3
Explanation:
The electron shells are labelled as K,L,M,N,O,P, and Q or 1,2,3,4,5,6, and 7.
As we go from innermost shell outwards, this number denotes the number of subshell in the shell. Electrons in outer shells have higher average energy and travel farther from the nucleus than those in inner shells.
Hence, M shell contains s,p and d subshells.
The decrease in the water table due to overuse of water.
Answer: Groundwater and surface water are connected. When groundwater is overused, the lakes, streams, and rivers connected to groundwater can also have their supply diminished. Land subsidence occurs when there is a loss of support below ground. This is most often caused by human activities, mainly from the overuse of groundwater, when the soil collapses, compacts, and drops.
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Van der Waals forces hold molecules together by: A. moving electrons from one molecule to another. B. attracting a lone pair of electrons to the positive charge of a hydrogen. C. inducing temporary dipoles that attract each other. D. sharing electrons between atoms.
Van der Waals forces hold molecules together by inducing temporary dipoles that attract each other. That is option C
Van Der Waals forces are example of those intermolecular forces which are weaker than ionic and covalent bonds that exists between molecules.
Van Der Waals forces was postulated by a Dutch physicist known as Van Der Waals. He postulated the existence of weak, short-range forces of attraction, which are independent of normal bonding forces, between non-polar molecules. He came to this conclusion after studying the of real gases at low temperatures and high pressures that:
electrons in a non-polar molecule such as hydrogen are close to one nucleus as to the other, although momentary concentration at one end of the molecule may occur, this momentary concentration of electron cloud on one side create a temporary dipole in the hydrogen molecule, that is, one side of the molecule acquires a partial negative charge while the other side acquires a partial positive charge of equal magnitude, the temporary dipole induces a similar dipole in an adjacent behavior molecule, this results in a temporary dipole-induced dipole attraction between the positive and negative ends of the adjacent molecules.This is how weak Van Der Waals forces are set up. Therefore, option C is CORRECT
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A skydiver slows down from 65 m/s to 5 m/s by opening the parachute. If this
takes 0.75 seconds, what is the skydiver's acceleration?
A. 45 m/s2 up
B. 80 m/s2 up
C. 45 m/s2 down
D. 80 m/s2 down
Answer:
D. -80m/s^2
Explanation:
V = u + at
5 = 65 + a (0.75)
0.75a = -60
a = -60/0.75
a = -80m/s^2
Therefore, is decelerating at 80m/s^2
Answer:
[tex]\boxed {\boxed {\sf D. \ 80 \ m/s^2 \ down}}[/tex]
Explanation:
We are asked to find the acceleration of a skydiver. Acceleration is the change in velocity over the change in time, so the formula for calculating acceleration is:
[tex]a= \frac{v_f-v_i}{t}[/tex]
The skydiver was initially traveling 65 meters per second, then he slowed down to a final velocity of 5 meters per second. He slowed down in 0.75 seconds.
[tex]\bullet \ v_f = 5 \ m/s \\\bullet \ v_i= 65 \ m/s \\\bullet \ t= 0.75 \ s[/tex]
Substitute the values into the formula.
[tex]a= \frac{ 5 \ m/s - 65 \ m/s}{0.75 \ s}[/tex]
Solve the numerator.
[tex]a= \frac{-60 \ m/s}{0.75 \ s}[/tex]
Divide.
[tex]a= -80 \ m/s^2[/tex]
The acceleration of the skydiver is -80 meters per second squared or 80 meters per second squared down. The skydiver is slowing down or decelerating, so the acceleration is negative or down.
which of the following is indicated by the ph value of a solution?
a- it's hydrogen ion concentration
b- its ammonium ion concentration
c- ability to undergo chemical reaction
d- its ratio of solute amount to solvent volume
Answer:
c- ability to undergo chemical reaction
Determine the effect each given mutation would have on the rate of glycolysis in muscle cells.
a. loss of binding site for fructose 1 ,6-bisphophate in pyruvate kinase.
b. loss of allosteric binding site for ATP in pyruvate kinase.
c. loss of allosteric binding site for AMP in phosphofructokinase.
d. loss of regulatory binding site for ATP in phosphofructokinase.
1. Increase
2. decrease
3. No effect
Answer:
a. Decrease
b. Increase
c. Increase
d. No effect
Explanation:
Glycolysis is present in muscle cells which converts glucose to pyruvate, water and NADH. It produces two molecules of ATP. Cellular respiration produces more molecules of ATP from pyruvate in mitochondria. Glycolysis increases in pyruvate kinase.
a. Loss of binding site for fructose 1,6-bisphosphate in pyruvate kinase: Decrease
b. Loss of allosteric binding site for ATP in pyruvate kinase: No effect
c. Loss of allosteric binding site for AMP in phosphofructokinase: Increase
d. Loss of regulatory binding site for ATP in phosphofructokinase: Increase
A. An important substrate in the glycolysis pathway is fructose 1,6-bisphosphate. It stimulates pyruvate kinase, an essential enzyme in glycolysis. The amount of pyruvate kinase that is activated will decrease if the fructose 1,6-bisphosphate binding site in pyruvate kinase is eliminated. As a result the rate of glycolysis in the muscle cells will probably decrease.
B. The allosteric ATP binding site of pyruvate kinase controls how active the enzyme is. However, pyruvate kinase is not significantly regulated by ATP in muscle cells. Therefore, it is unlikely that deletion of the ATP-binding allosteric site in pyruvate kinase would have no effect on the rate of glycolysis in muscle cells.
C. The rate-limiting enzyme in glycolysis, phosphofructokinase, is activated from all forms by AMP. It increases the rate of glycolysis by stimulating the activity of phosphofructokinase. If the allosteric binding site for AMP is eliminated, phosphofructokinase activation will be reduced. As a result, the rate of glycolysis in muscle cells will decrease.
D. Phosphofructokinase is inhibited allosterically by ATP. It regulates the rate of glycolysis by a feedback mechanism. High ATP concentrations cause phosphofructokinase to bind to its regulatory site, limiting its activity and delaying glycolysis. If the regulatory binding site for ATP is eliminated, the inhibitory action of ATP on phosphofructokinase would be lost. As a result, muscle cells will glycolysis at a faster rate.
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Determine whether each of the examples represents a colligative property or a non-colligative property. boiling point elevation Choose... color Choose... freezing point depression Choose... vapor pressure lowering Choose... density Choose...
Answer:
boiling point elevation - colligative property
color - non-colligative property
freezing point depression - colligative property
vapor pressure lowering - colligative property
density - non-colligative property
Explanation:
A colligative property is a property that depends on the number of particles present in the system.
Freezing point depression, boiling point elevation and vapour pressure lowering are all colligative properties of solutions.
Colour and density do not depend on the number of particles present hence they are not colligative properties.
The boiling point elevation, freezing point depression, and vapor pressure lowering are colligative properties. And color and density are non-colligative properties.
Explanation:
The colligative properties are the properties depending upon the number of particles of solute not on the nature of the solute.Example of colligative properties:Vapor pressure loweringElevation boiling pointDepression in freezing pointOsmotic pressureThe non-colligative properties are the properties depending upon the nature of solute and solvent.Example of non-colligative properties :ViscositySurface tensionDensitySolubilitySo, from this, we can conclude that boiling point elevation, freezing point depression, and vapor pressure lowering are colligative properties. And color and density are non-colligative properties.
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Another method for creating a buffer, in situ, is to add an appropriate amount of a strong base, e.g., NaOH, to a weak acid OR add an appropriate amount of a strong acid, e.g., HNO3, to a weak base. As an example, mixing 1.0 mol of acetic acid with 0.5 mol of NaOH will result in a buffer solution with 0.5 mol of acetic acid and 0.5 mol of acetate. The acetate is created by the reaction of acetic acid and the strong base, hydroxide. Given this information, which of the following, when mixed with the appropriate amount of HCl, would create a buffer solution?
a. HNO3
b. HClO2
c. LiCl
d. NH3
Answer:
As an example, mixing 1.0 mol of acetic acid with 0.5 mol of NaOH will result in a buffer solution with 0.5 mol of acetic acid and 0.5 mol of acetate. The acetate is created by the reaction of acetic acid and the strong base, hydroxide.
When HClO2 is mixed with the appropriate amount of HCl it would create a buffer solution. That is option B.
Methods used to form buffer solutionA buffer solution is the solution that resists a change in pH of a solution when acid or base is added because it is made up of weak acid and the conjugate base or weak base and the conjugate acid.
The methods that can be used to form a buffer solution include:
Adding a strong base to a weak acid: For example, mixing 1.0 mol of acetic acid with 0.5 mol of NaOH will result in a buffer solution with 0.5 mol of acetic acid and 0.5 mol of acetate.Adding a weak acid to a conjugate base: For example HCl is a strong acid which will react with a conjugate base such as HClO2.Although HCl is a strong acid, it can be converted to a weak acid through dilution with water. It is in this context that it can be used to form a buffer solution.
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A filament for a light bulb needs to conduct electricity. Which of the elements listed below might be useful as a light bulb filament? Explain your thinking.
A. Tungsten, W
B. Sulfur, S
C. Bromine, Br
Answer:
A. tungsten
Explanation:
Tungsten is a material which high melting point ie. does not melt easily incase of high temperature
Answer:
option(A):Tungsten
Explanation:
tungsten has highest melting point.
What information does the first quantum number of an electron give?
A. The sublevel that the electron is in
B. The specific orbital the electron is in
C. The energy level the electron is in
D. The spin that the specific electron has
Answer:
с
Explanation:
the first quantum number of an electron gives the information about the energy level the electron is in
The information first quantum number of an electron give is the energy level the electron is in.
What are quantum numbers?Quantum numbers is a set of symbols which gives idea about the position of electron present inside an atom.
First quantum number is denoted by symbol 'n' which gives idea about the number of shell or energy level in which electron is present.The sublevel that the electron is in is the second quantum number denoted by symbol 'l'.The specific orbital in which electron is present is denoted by symbol 'm' and it is the third quantum number.The spin that the specific electron has is the forth quantum number and denoted by symbol 's'.Hence first quantum number of electron gives ideal about the energy level.
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Sally has constructed a concentration cell to measure Ksp for MCln. She constructs the cell by adding 2 mL of 0.05 M M(NO3)n to one compartment of the microwell plate. She then makes a solution of MCln by adding KCl to M(NO3)n. She adds 7.903 mL of the resulting mixture to a second compartment of the microwell plate. Sally knows n = +2. She has already calculated [Mn+] in the prepared MCln solution using the Nernst equation. [Mn+] = 8.279 M
Required:
How many moles of [Cl-] must be dissolved in that compartment?
Answer:
0.1309 mol
Explanation:
From the given information:
The metal ion, two ions of [tex]M^{+}[/tex] reacted with Cl⁻ to form [tex]MCl_n[/tex] i.e. the compound formed is [tex]MCl_2[/tex].
The concentration of the metal ion formed [tex][M^+][/tex] = 8.279 M
The concentration of the chlorine ion formed [tex][Cl^-][/tex] = 2 × 8.279 M
= 16.558 M
∴
We know that:
[tex]\mathsf{Molarity = \dfrac{no \ of \ moles }{volume (mL)}}[/tex]
The number of moles of [tex][Cl^-][/tex] = [tex]16.558 \ mol.L^{-1} \times 7.903 \ mL \times \dfrac{1 \ L}{1000 \ mL}[/tex]
= 0.1309 mol
state function and non state function
Answer:
State functions represent quantities or properties of a thermodynamic system, while non-state functions represent a process during which the state functions change. For example, the state function PV is proportional to the internal energy of an ideal gas, but the work W is the amount of energy transferred as the system performs work.
Explanation:
Assuming a mixture of equal volumes of o xylene and cyclohexane,which of these will distill off first?
