How many moles of Al are necessary to form 45.0 g of AlBr, from this
reaction:
2 Al(s) + 3 Br_(1) ► 2 AlBr_(s)?

Answers

Answer 1

Answer:

0.169 mole of Al

Explanation:

We'll begin by by calculating the number of mole in 45 gof AlBr₃. This can be obtained as follow:

Mass of AlBr₃ = 45 g

Molar mass of AlBr₃ = 27 + (3×80)

= 27 + 240

= 267 g/mol

Mole of AlBr₃ =?

Mole = mass /molar mass

Mole of AlBr₃ = 45 / 267

Mole of AlBr₃ = 0.169 mole

Finally, we shall determine the number of mole of Al needed to produce 45 g (i.e 0.169 mole) of AlBr₃. This can be obtained as illustrated below:

2Al + 3Br₂ —> 2AlBr₃

From the balanced equation above,

2 moles of Al reacted to produce 2 moles of AlBr₃.

Therefore, 0.169 mole of Al will also react to produce 0.169 mole of AlBr₃.

Thus, 0.169 mole of Al is needed for the reaction.


Related Questions

Write a complete, balanced equation for the following reactions:

e) The heating of sodium carbonate (teachers note: produces sodium oxide and carbon dioxide).
f) chromium (III) hydroxide plus sulfuric acid (teachers note: You figure out products).
g) aluminum metal plus chlorine gas (teachers note: produces aluminum chloride).

Please explain as well, thanks!

Answers

Answer:

Solution given:

e) The heating of sodium carbonate to produces sodium oxide and carbon dioxide

Solution given:

Balanced chemical equation:

[tex]\boxed{\bold{\green{Na_{2}CO_{2} +heat \rightarrow Na_{2}O +CO_{2}}}}[/tex]

when sodium carbonate is heated it decomposed and form sodium oxide and carbon dioxide

f) chromium (III) hydroxide plus sulfuric acid

Balanced chemical equation:

[tex]\boxed{\bold{\green{2Cr(OH)_{3}+ 3H_{2}SO_{4} → Cr_{2}(SO_{4})_{3} + 6H_{2}O}}}[/tex]

When chromium (III) hydroxide react with sulfuric acid double displacement takes place and forms produce chromium(III) sulfate and water.

g) aluminum metal plus chlorine gas

[tex]\boxed{\bold{\green{2Al(s) + 3Cl_2(g) \rightarrow 2AlCl_2 }}}[/tex]

When aluminum metal is added to chlorine gas Combination reaction takes place and forms aluminum chloride.

e) The heating of sodium carbonate to produces sodium oxide and carbon dioxide

Solution given:

Balanced chemical equation:

[tex]\boxed{\bold{\green{Na_{2}CO_{2} +heat \rightarrow Na_{2}O +CO_{2}}}}[/tex]

when sodium carbonate is heated it decomposed and form sodium oxide and carbon dioxide

f) chromium (III) hydroxide plus sulfuric acid

Balanced chemical equation:

[tex]\boxed{\bold{\green{2Cr(OH)_{3}+ 3H_{2}SO_{4} → Cr_{2}(SO_{4})_{3} + 6H_{2}O}}}[/tex]

When chromium (III) hydroxide react with sulfuric acid double displacement takes place and forms produce chromium(III) sulfate and water.

g) aluminum metal plus chlorine gas

[tex]\boxed{\bold{\green{2Al(s) + 3Cl_2(g) \rightarrow 2AlCl_2 }}}[/tex]

When aluminum metal is added to chlorine gas Combination reaction takes place and forms aluminum chloride.

5) When heated in a flame, the element Indium emits electromagnetic radiation with a distinctive indigo blue
color (the name indium is derived from the word indigo). The emitted photons that give rise to this
color
have energies of 4.405 x 10^-19J. Calculate the wavelength of this radiation in nanometers.

Answers

Answer:

[tex]\lambda=451nm[/tex]

Explanation:

Hello there!

In this case, according to the given information, it turns out possible for us to solve this problem by using the following equation, defined in terms of energy, Planck's constant, wavelength and speed of light:

[tex]E=\frac{hC}{\lambda }[/tex]

Thus, we solve for the wavelength as shown below:

[tex]\lambda=\frac{hC}{ E}[/tex]

And finally plug in the energy, Planck's constant and speed of light to obtain:

[tex]\lambda=\frac{6.6261 x 10^{-34} m^2 kg / s*3x10^8m/s}{4.405x10^{-19}m^2kg/s^2}\\\\\lambda=4.513x10^{-7}m*\frac{1nm}{10^{-9}m} \\\\\lambda=451nm[/tex]

Regards!

Which does not result in deviations from linearity in a Beer's law plot of absorbance versus concentration?a. light losses at the cell interface b. all are sources of nonlinearity c. stray radiation d. equilibrium between different forms of the analyte e. a wide bandwidth relative to the width of the absorption band

Answers

Answer:

a

Explanation:

Beer-Lambert Law shows the relationship between the factors affecting the absorbance of a sample in relation to the concentration. These factors are:

the concentration c, path length (l), and the molar absorptivity (ε).

As a result, more radiation is assimilated as the concentration rises, and the absorbance rises as well. However, the longer the path length, the increase in the number of molecules and the higher the absorbance.

Thus, the straight-line equation for Beer-Lambert's law is:

A = εcl

From the above explanation, the option that doesn't relate to the deviations from linearity of Beer's law plot is in Option (a).

An experimental drug, D, is known to decompose in the blood stream. Tripling the concentration of the drug increases the decomposition rate by a factor of nine. Write the rate law for decomposition of D.

Answers

Answer:

R=k[D]^2

Explanation:

Given that it is a decomposition reaction;

D--->product

Hence;

The rate law is;

R= k[D]^x ----(1)

When we triple the concentration of D we have;

[D]' = [3D]^x

Therefore;

R'= 3R

R'= k[D]'----(2)

Hence dividing (1) by (2);

R/R' = k[D]^x/k[D]'

R/9R = k[D]^x/k[3D]^x

1/9 = 1/3^x (take inverse of both sides)

9 = 3^x

3^2 = 3^x

x= 2

Hence the rate law;

R=k[D]^2

which of these statements is true about planets? Planets
A. revolve around the sun
B. are spherical in shape
C. rotate in its axis
D. all of the above​

Answers

Answer:

D. all of the above

Explanation:

A and C are verified by Keplar's laws of planetary motion.

B is verified by the equatorial and polar aces of the Planet.

Answer:

c

Explanation:

they dont have to orbit the sun specifically and are commonly more ovoid than spherical

How many atom in protons

Answers

Answer:

Its atomic number is 14 and its atomic mass is 28. The most common isotope of uranium has 92 protons and 146 neutrons. Its atomic number is 92 and its atomic mass is 238 (92 + 146).

X = atomic number - number of core electrons

Which of the following explains the identity of X and its trends down a group?

A. X is the effective nuclear charge, and it remains constant down a group.

B. X is the screening constant, and it remains constant down a group.

C. X is the effective nuclear charge, and it increases down a group.

D. X is the screening constant, and it increases down a group.

Answers

Based on the expression given in the question, X is the effective nuclear charge, and it increases down a group.

What is an effective nuclear charge?

Effective nuclear charge is the net nuclear charge that an electron in an atom experiences, after subtracting the nuclear charge shielded by other electrons.

The effective nuclear charge is denoted by Zeff and can be calculated by subtracting the number of shielding electrons from the atomic number.

Therefore, based on the expression given in the question, X is the effective nuclear charge, and it increases down a group.

Learn more about effective nuclear charge at: https://brainly.com/question/13664060

#SPJ1

You will observe a weak acid-strong base titration in this experiment. Select all statements that are true about weak acid-strong base titrations.
A. Weak acid-strong base titrations always start at a higher pH than strong acid-strong base titrations, no matter the initial concentration.
B. The pH is less than 7 at the equivalence point.
C. The pH is greater than 7 at the equivalence point.
D. Half way to the equivalence point, a buffer region is observed.

Answers

Answer:

The pH is greater than 7 at the equivalence point.

Explanation:

Equivalence point is the point where the acid reacts with the base as stipulated in the equation of the reaction.

When a weak acid and a strong base are titrated, the pH of the solution at equivalence point is actually found to be around about pH ~ 9.

Hence, for a weak acid and strong base titration, The pH is greater than 7 at the equivalence point.

A titration between a weak acid and a strong base yields a solution whose pH is greater than 7 at the equivalence point.

What are weak acids?

Weak acids are acids which only ionize partially in aqueous solutions.

When weak acids are dissolved in water, they produce only few hydrogen ions.

A strong base on the other hand ionizes completely to produce hydroxide ions in aqueous solutions.

The titration of a weak acid and a strong base gives a solution whose pH is greater than 7 at equivalence point.

Learn more about equivalence point at: https://brainly.com/question/18933025

2. 27.8 mL of an unknown were added to a 50.0-mL flask that weighs 464.7 g. The total mass of the flask and the liquid is 552.4 g. Calculate the density of the liquid in Lbs/ in3.

Answers

Answer:

[tex]d=4.24x10^{-4}\frac{lb}{in^3}[/tex]

Explanation:

Hello there!

In this case, according to the given information, it turns out firstly necessary for us to set the equation for the calculation of density and mass divided by volume:

[tex]d=\frac{m}{V}[/tex]

Thus, we can find the mass of the unknown by subtracting the total mass of the liquid to the mass of the flask and the liquid:

[tex]m=552.4g-464.7g=87.7g[/tex]

So that we are now able to calculate the density in g/mL first:

[tex]d=\frac{87.7g}{27.8mL}=3.15g/mL[/tex]

Now, we proceed to the conversion to lb/in³ by using the following setup:

[tex]d=3.15\frac{g}{mL}*\frac{1lb}{453.6g}*\frac{1in^3}{16.3871mL}\\\\d=4.24x10^{-4}\frac{lb}{in^3}[/tex]

Regards!

Identify effective techniques for accurate pipet use. Select all that apply. Select one or more: Measure liquid by aligning the meniscus with the volume line. Leave any air bubbles in a pipet that occur after drawing up liquid. Do not let liquid enter the pipet bulb or pump. Use the pipet bulb to force the last drop out of the tip.

Answers

Answer:

Measure liquid by aligning the meniscus with the volume line.

Explanation:

A pipette is an instrument specially made for measuring a small volume of liquid.

The pipette comes in various sizes to be used in measuring various volumes of liquid. Generally, the pipette has a volume line which helps us to measure a liquid.

A liquid is measured by aligning the meniscus with the volume line.

A student pours a few drops of vinegar onto limestone and it starts bubbling. What kind of reaction is this? How does it relate to chemical weathering, monuments and statues?

Answers

Answer:

The correct answer is - acid-base reaction or chemical weathering.

Explanation:

Vinegar is an acid that dissolves a material that is commonly found and known as calcium carbonate present in the limestone. When these two, vinegar mix with calcium carbonate of the limestone, the atoms in the acetic acid and the calcium carbonate come apart and rearrange in different ways to make new chemicals.

This rearrangement results in the release of carbon dioxide as a stream of bubbles. It is a form of weathering called chemical weathering and many monuments are based on rocks that have limestones in their composition and acid rain work similar to vinegar.

Consider the reaction of 2-chloro-2-methylpentane with sodium iodide.
Assuming no other changes, how would it affect the rate if one simultaneously doubled the concentration of 2-chloro-2-methylpentane and sodium iodide?
A) No effect.
B) It would double the rate.
C) It would triple the rate.
D) It would quadruple the rate.
E) It would increase the rate five times.

Answers

Answer:

Explanation:

The reaction between 2 chloro- 2 methyl pentane and sodium iodide takes place through SN2 mechanism . iodide ion is the nucleophile which attacks the substrate . The rate of such reaction depends upon concentration of both the nucleophile and the substrate .

Hence rate of reaction will be increased by 2 x 2 = 4 times.

option D ) is correct.

Explanation:

The given reaction represents the reaction between a tertiary alkyl halide that is 2-chloro-2-methylpentane and a nucleophile that is NaI.

This reaction favors SN1 mechanism which has order one.

So, the given reaction follows first-order kinetics.

For a first-order reaction, the rate law is:

rate =k [A]

That means the rate of the reaction is dependent on the concentration of reactants.

So, when the concentration of the reactant is doubled then, the rate of the reaction is also doubled.

Among the given options the correct answer is option B) It would double the rate.

1.0 g of a compound A is prepared in 100 mL of water, and then extracted with 50 mL of ether. After the extraction, 0.25 g of the compound was recovered from the ether layer. What is the partitioning coefficient([A]ether/[A]water) for this compound in the system used?a. 4.0b. 3.0c. 1.5d. 0.75e. 0.25f. 0.67

Answers

Answer:

uh 2

Explanation:

Its 2 cause uh 2 sounds about right

To solve this we must know the concept behind partition coefficient. The partitioning coefficient for this compound in the system used is 0.67. Therefore, the correct option is option F.

What is partition coefficient?

The ratio of a solute's concentrations in two solids, immiscible liquids, or barely miscible liquids when they are in equilibrium throughout the interface connecting them is called partition coefficient.

In fundamental chemistry, partitioning is utilized to separate components in procedures like chromatography. Partitioning is a crucial factor in the distribution of chemicals and medications between the blood and bodily tissues in the field of pharmacology.

Mathematically,

partition coefficient= concentration of the solute in  stationary phase/concentration of the solute in mobile phase

partition coefficient={(0.25 /M)÷50}÷{(1.0/M)÷100 }

                                =0.005÷0.01

                                =0.67

Therefore, the correct option is option F.

To learn more about partition coefficient, here:

https://brainly.com/question/29845640

#SPJ5


How did the work of Dmitri Mendeleev differ from that of John Newlands in the development of the periodic table?

Answers

Answer: Mendeleev predicted elements that would later be discovered.

2. For each of the ionic compounds in the table below, name the compound and explain the rule that you
used in formulating your name for the compound.
Name:
Rule for naming compound:
-PbF4
-NH4NO3
-Li2S

Answers

Answer:

2

Explanation:

Lead(|V) fluoride

Ammonium Nitrate

Lithium sulfide

For the rules, I don't know what you were taught. I just do it intuitively since I have done so much chemistry.

The first one the roman numerals represents the charge of the lead which much match the 4- charge from the 4 fluorides.

The second one is just two polyatomic ions which you just have to remember.

The last one is the typical ionic compound naming technique i guess.

Based on the electron configuration of the two atoms, predict the ratio of metal cationic (+) atom to nonmetal anionic (-) atom in the compound.
Lithium 1s^22s^1
Chlorine 1s^22s^22p^6 3s^23p^5

Answers

Answer:

Option A. 1:1

Explanation:

From the question given above, the following data were obtained:

Li => 1s² 2s¹

Cl => 1s² 2s²2p⁶ 3s²2p⁵

Lithium (Li) will form compound with Cl by losing 1 electron as shown below:

Li —> Li⁺ + e¯ ..... (1)

Cl on the other hand will accept 1 electron from Li to form the chloride ion, Cl¯ as shown below:

Cl + e¯ —> Cl¯ ...... (2)

Combining equation 1 and 2, we have:

Li + Cl + e¯ —> Li⁺ + Cl¯ +

Cancel e¯ from both side

Li + Cl —> Li⁺Cl¯

Thus, the ratio of metallic cation (+) to non-metallic anion (-) in the compound is 1:1

Identify the compound in the following group that is most soluble in water. Match the words in the left column to the appropriate blanks in the sentences on the right. ResetHelp Of the three compounds butanoic acid, butane, and butanone, the one that is most soluble in water is . This is because its functional group can form the intermolecular forces with polar water.
butanoic acid strongest hydrocarbon butanone butane alcohol carboxylic acid What carboxylic acid is found in each of the following substances? Drag the appropriate descriptions to their respective bins. Reset rancid butter stinging red ants Methanoic acid Butanoic acid Propanoic acid Ethanoic acid Review Co Draw the structure of methyl butanoate, Draw the molecule on the canvas by choosing buttons from the Tools (for bonds and charges), Atoms toolbars. H: 129 uxo com H o с + N 1 0 S a CH Br р

Answers

Answer:

Following are the responses to the given points:

Explanation:

For question 1:

Butanoic acid, butane, and butanone are also the three chemicals most dissolve in water. Its intermolecular force forces are produced by carboxylic acid functional groups with water.

For question 2:

Butanoic acid is a rancid buffer.

Methanoic acid is responsible for the stinging red ants

For question 3:

Methyl butanoate's chemical structure.

Fill in the left side of this equilibrium constant equation for the reaction of acetic acid HCH3CO2 with water.

______ = Ka

Answers

Answer:

The left side equation is:

[tex]Ka = \frac{[CH_{3}COO^{-}] [H_{3}O^{+}]}{[HCH_{3}COO] [H_{2}O]}[/tex]

Explanation:

For the reaction of acetic acid HCH3CO2 with the water, The equilibrium constant equation is

[tex]HCH_{3}COO + H_{2}O \rightleftharpoons CH_{3}COO^{-} + H_{3}O[/tex]

The left side of this equilibrium constant equation will be written as shown below:

[tex]Ka = \frac{[CH_{3}COO^{-}] [H_{3}O^{+}]}{[HCH_{3}COO] [H_{2}O]}[/tex]

The following compound can be identified as

Answers

Answer:

3: Lactone

Explanation:

Lactones are defined as carboxylic esters that contain the structure (−C(=O)−O−) which is essentially showing that an ester has now become part of the chemical structure of the ring.

Thus, looking at the question, it has the structure as defined in Lactones.

Thus, we can say that the compound is a Lactone.

Hydrogen gas and fluorine gas will react to form hydrogen fluoride gas. What is the standard free energy change for this reaction

Answers

Answer:

[tex]\Delta G=-541.4kJ/mol[/tex]

Explanation:

Hello there!

In this case, according to the given information, it turns out firstly necessary to write out the described chemical reaction as shown below:

[tex]H_2+F_2\rightarrow 2HF[/tex]

Now, we set up the expression for the calculation of the standard free energy change, considering the free energy of formation of each species, specially those of H2 and F2 which are both 0 because they are pure elements:

[tex]\Delta G=2\Delta G_f^{HF}-(\Delta G_f^{H_2}+\Delta G_f^{F_2})\\\\\Delta G=2*-270.70kJ/mol-(0kJ/mol+0kJ/mol)\\\\\Delta G=-541.4kJ/mol[/tex]

Regards!

1: When salt is mixed into water it becomes a. element​

Answers

Water molecules pull the sodium and chloride ions apart, breaking the ionic bond that held them together. After the salt compounds are pulled apart, the sodium and chloride atoms are surrounded by water molecules, as this diagram shows. Once this happens, the salt is dissolved, resulting in a homogeneous solution.

hope this helps you

have a nice day:)

Oleic acid and elaidic acid are isomeric alkenes.

a. True
b. False

Answers

Answer:

False

Explanation:

Because Elaidic acid is an isomer of oleic acid. I really hope this helps you.

what is the hybridisation of the central carbon in CH3C triple bonded to N​

Answers

Explanation:

the carbon would be sp3 hybridized, and it doesn't matter which carbon, since either of them have a full octet

A second-order reaction has a half-life of 12 s when the initial concentration of reactant is 0.98 M. The rate constant for this reaction is ________ M-1s-1. A) 12

Answers

Answer: 0.085 (Ms)⁻¹

Explanation: Half life = 12 s

is the initial concentration = 0.98 M

Half life expression for second order kinetic is:

k = 0.085 (Ms)⁻¹

The rate constant for this reaction is 0.085 (Ms)⁻¹ .

Which type of element is almost always found as a single atom in nature?
O A. Alkaline earth metal
O B. Halogen
c. Noble gas
D. Oxygen family element

Answers

Noble gas elements are almost always found as a single atom in nature.

What is inert gas?

An inert gas is a gas that does not undergo chemical reactions under a set of given conditions. The noble gases often do not react with many substances and were historically referred to as inert gases.

All noble gases have the maximum number of electrons in their outer shell; i.e. 2 electrons for helium and 8 for the other five.

Noble gases are monoatomic, which means they exist as single atoms. This is because of their electronic stability.

Thus, noble gas elements are almost always found as a single atom in nature. Hence, option C is correct.

Learn more about the inert gas here:

https://brainly.ph/question/4502738

#SPJ1

what are the products in a chemical equation located?

Answers

Answer:

they are the end results so they are after the yields symbol

Explanation:

Suppose that a certain atom possesses only four distinct energy levels. Assuming that all transitions between levels are possible, how many spectral lines will this atom exhibit

Answers

Answer:

Following are the response to the given question:

Explanation:

The number of shells

n = 4

Calculating the spectral line:

[tex]= \frac{n(n-1)}{2}\\\\ = \frac{4(4-1)}{2} \\\\= \frac{4\times 3}{2}\\\\ = \frac{12}{2}\\\\ = 6[/tex]

You have 10 pounds of egg whites. You need 6oz to make one serving of cosomme. How many servings can you make?

Answers

Answer:

I think you can make 26, hope this helped.

Explanation:

which of the following kb values represents the weakest base?

Answers

Answer:

the weakest base will have a higher Kb value since it will be closer to an acid than a base

7 kb values represents the weakest base.

What is kb value?

Kb is the base dissociation constant which is a measure of how completely a base dissociates into its component ions in water. pKb is define as the negative base-10 logarithm of the base dissociation constant (Kb) of a solution.

Ka is define as the acid dissociation constant while pKa is the -log of this constant. Kb is define as the base dissociation constant, while pKb is the -log of the constant.

The acid and base dissociation constants are usually expressed in terms of moles per liter (mol/L).

Thus, 7 kb values represents the weakest base.

Learn more about Kb value, here:

https://brainly.com/question/29427601

#SPJ2

The product of the following reaction is

Answers

``````````````````````````````````

Other Questions
I need help solving this problem Match each lab incident to the item of PPE that will protect you from it. Each item of PPE will only be used once. While picking up a buret, an unknown solution left by a previous solution drips onto your hand._______________While pulling an empty beaker off the shelf at the beginning of lab, it slips out of your hand onto the floor _______ While checking on a stirring solution, the solution splashes up towards your face. _______While transferring a solution from a flask to a beaker, the solution accidentally spills down the front of the lab bench, __________ A. Gloves B. Lab coat C. Goggles D. Closed-toe shoes Given the circle with equation x+ y =17a). Determine if the points D(-4, -1) and E(1, 4) are on the circle. Show all workb). Find the equation of the perpendicular bisector of the chord DEc). Verify that the perpendicular bisector from part b) passes through the center of the circle which ordered pair is the best estimate for the solution to the system? What process occurs during transcription? (2 points)Synthesis of proteins that are coded for by mRNACopying of DNA to form an mRNA strandReplication of DNA to produce a complementary DNA strandmRNA folding up by forming complementary bonds with itself Azure, a C corporation, reports the following: Pretax book income is $543,000. Depreciation on the tax return is $20,000 greater than depreciation on the financial statements. Rent income reportable on the tax return is $36,000 greater than rent income per the financial statements. Fines for pollution appear as a $10,000 expense in the financial statements. Interest earned on municipal bonds is $25,000. What is Azure's taxable income the family member you like most When readers establish a goal for reading a text, they are 2),ABCWhich of the molecules above is a tRNA molecule?none of the above.A CB Some of the principles of ethical violations discussed in class are the following: stress and psychological harm, deception, invasion of privacy, breach of confidentiality, involuntary recruitment, use of special populations, withholding beneficial treatment, and fraud. The following research situations illustrate one or more possible ethical violations. For each situation: (1) Identify what you believe are the violations of ethical principles which are most apparent. (2) Explain your answers. (3) State how the violations can be remedied. (4) After all 12 situations are analyzed, rank the violations according to minor, moderate, and major ethical violations choose the correct answer 1. a) William is a factory's workerb) William is a factory worker 2.a) I enjoy visiting my friend home.b) I'm driving looking my friends home c) I enjoy visiting friends' home When dragons on planet Pern lay eggs, the eggs are either green or yellow. The biologists have observed over the years that 21% of the eggs are yellow, and the rest green. Next spring the lead scientist has permission to randomly select 58 of the dragon eggs to incubate. Consider all the possible samples of 58 dragon eggs.What is the usual number of yellow eggs in samples of 58 eggs? (Give answers as SENSIBLE whole numbers.)minimum usual number of yellow eggs =maximum usual number of yellow eggs Please Help!find the value of x round to the nearest tenth as needed purchased heavy equipment by giving the seller a $30,000 cash down payment and a 5-year interest-bearing note for the $170,000 balance of the price. Compute Pettit's book basis and tax basis in the equipment please help solve this (geometry) Help me plz I need help The shiny silver mouse has a population mean size of 8.3 cm and and a population standard deviation of 1.2 cm. If one individual is sampled from the population what is the probability that it will be greater than 9 cm A is 2 times older than B. Identify the appropriate expression. What is the name of for a different froms of gene Almost all people have at one time or another experienced (select all that apply): Schizophrenia Anxiety Depression Bipolar