If 194.7 g of KClO3 is fully decomposed, approximately 76.5 g of O2 gas will be produced. To determine the amount of oxygen gas produced from the decomposition of potassium chlorate (KClO3), we first need to balance the equation: 2KClO3 (s) → 2KCl (s) + 3O2 (g).
The molar mass of KClO3 is 122.55 g/mol, so 194.7 g of KClO3 is equal to 1.59 mol. From the balanced equation, we can see that for every 2 mol of KClO3, 3 mol of O2 are produced. Using this ratio, we can calculate the amount of O2 produced: 1.59 mol KClO3 * (3 mol O2 / 2 mol KClO3) = 2.39 mol O2.
Finally, to convert from moles to grams, we multiply by the molar mass of O2, which is 32.00 g/mol: 2.39 mol O2 * 32.00 g/mol = 76.5 g O2. Therefore, if 194.7 g of KClO3 is fully decomposed, approximately 76.5 g of O2 gas will be produced.
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A graduated cylinder contains 26 cm3 of water. an object with a mass of 21 grams and a volume of 15 cm3 is lowered into the water. what will the new water level be
When the object with a volume of 15 cm3 is lowered into the water in the graduated cylinder, the new water level will be 11 cm3.
The new water level in the graduated cylinder can be determined by considering the principle of displacement. When the object is lowered into the water, it will displace an amount of water equal to its own volume.
Given that the object has a volume of 15 cm3, it will displace 15 cm3 of water. Since the initial volume of water in the graduated cylinder is 26 cm3, the new water level can be calculated by subtracting the volume of water displaced by the object from the initial volume of water.
Therefore, the new water level in the graduated cylinder will be 26 cm3 - 15 cm3 = 11 cm3.
To summarize, when the object with a volume of 15 cm3 is lowered into the water in the graduated cylinder, the new water level will be 11 cm3.
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at constant temperature, a 144.0 ml sample of gas in a piston chamber has a pressure of 2.25 atm. calculate the pressure of the gas if this piston is pushed down hard so that the gas now has a volume of 36.0 ml.
The pressure of the gas would be 9.0 atm if the piston is pushed down hard to a volume of 36.0 ml.
To solve this problem, we can use Boyle's Law, which states that the pressure of a gas is inversely proportional to its volume at constant temperature.
First, we need to set up the equation: P1V1 = P2V2, where P1 and V1 are the initial pressure and volume, and P2 and V2 are the final pressure and volume.
Given that the initial volume (V1) is 144.0 ml and the initial pressure (P1) is 2.25 atm, and the final volume (V2) is 36.0 ml, we can plug in the values into the equation:
2.25 atm * 144.0 ml = P2 * 36.0 ml
Next, we can solve for P2 by dividing both sides of the equation by 36.0 ml:
2.25 atm * 144.0 ml / 36.0 ml = P2
P2 = 9.0 atm
Therefore, the pressure of the gas would be 9.0 atm if the piston is pushed down hard to a volume of 36.0 ml.
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30 ml of 0. 00138 m cl- solution is titrated with 0. 00057 m ag+. calculate the pag half-way to the equivalence point when the added titrant volume is 30ml. (hint!: use the ksp value for agcl)
The pAg halfway to the equivalence point when the added titrant volume is 30 ml is 7.45.
The pAg halfway to the equivalence point can be calculated using the concept of stoichiometry and the equilibrium constant expression for the formation of silver chloride (AgCl).
First, we need to determine the number of moles of Cl- present in the initial solution. The initial concentration of Cl- is 0.00138 M, and the volume of the solution is 30 ml. Therefore, the moles of Cl- can be calculated as follows:
Moles of Cl- = Concentration of Cl- × Volume of Solution
= 0.00138 M × 0.030 L
= 0.0000414 moles
Since the stoichiometry between Ag+ and Cl- is 1:1, the moles of Ag+ required to react with the moles of Cl- can be assumed to be the same.
Next, we calculate the concentration of Ag+ required to react with the moles of Cl-. The moles of Ag+ can be determined as follows:
Moles of Ag+ = Concentration of Ag+ × Volume of Titrant Added
= 0.00057 M × 0.030 L
= 0.0000171 moles
At the halfway point, the moles of Ag+ reacted with the moles of Cl- are equal. Therefore, the moles of Ag+ remaining in solution are:
Moles of Ag+ remaining = Moles of Ag+ initial - Moles of Ag+ reacted
= 0.0000171 moles - 0.0000414 moles
= -0.0000243 moles
Since the moles of Ag+ cannot be negative, we assume that all the Cl- ions have reacted, and the excess Ag+ ions have formed a precipitate of AgCl.
Using the equilibrium constant expression for AgCl, Ksp = [Ag+][Cl-], we can calculate the concentration of Ag+ at the halfway point.
Ksp = [Ag+][Cl-]
[Ag+] = Ksp / [Cl-]
= (1.77 × 10^-10) / (0.00138 M)
≈ 1.285 × 10^-7 M
Finally, we can calculate the pAg halfway to the equivalence point using the formula:
pAg = -log10([Ag+])
= -log10(1.285 × 10^-7)
≈ 7.45
Step 3: At the halfway point, all the Cl- ions have reacted with Ag+ ions to form AgCl. The remaining Ag+ ions in solution will be in equilibrium with the AgCl precipitate. The concentration of Ag+ at this point can be calculated using the equilibrium constant expression for AgCl.
The pAg halfway to the equivalence point is 7.45. This means that the concentration of Ag+ ions in the solution is approximately 1.285 × 10^-7 M. At this concentration, the solution is close to the solubility product constant (Ksp) for AgCl, which is 1.77 × 10^-10.
The pAg value represents the negative logarithm of the Ag+ concentration in the solution. By calculating the concentration of Ag+ at the halfway point, we can determine the pAg value.
The result indicates that halfway to the equivalence point, the concentration of Ag+ ions in the solution is relatively high, indicating that a significant portion of the AgCl precipitate has formed. This corresponds to the formation of a visible white precip
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You prepare a stock solution that has a concentration of 2. 5 m. An aliquot with a volume of 10. 0 ml is removed from the solution. What is the concentration of the aliquot?.
The concentration of the aliquot is 2.5 M.
The concentration of a solution is defined as the amount of solute present per unit volume of the solution.
In this case, the stock solution has a concentration of 2.5 M (moles per liter).
An aliquot is a small portion or sample taken from a larger solution. In this scenario, an aliquot with a volume of 10.0 ml is removed from the stock solution.
Since the concentration of the stock solution is given in terms of moles per liter (M), the concentration of the aliquot will be the same as the concentration of the stock solution.
The concentration does not change when a specific volume is removed from the solution.
Therefore, the concentration of the aliquot is 2.5 M. It is important to note that the concentration remains the same regardless of the volume of the aliquot, as long as the proportion of solute to solvent remains constant.
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High-energy molecules contain one or more high-energy bonds, when hydrolyzed, is accompanied by a ______________ in free energy.
High-energy molecules contain one or more high-energy bonds, which store energy that can be released through hydrolysis. Hydrolysis is a chemical reaction that involves the breaking of a molecule with the addition of water. When high-energy bonds are hydrolyzed, the reaction is accompanied by a decrease in free energy.
During hydrolysis, the high-energy bond in the molecule is broken, releasing energy. This energy is used to form new bonds with the water molecules, resulting in the formation of new compounds. The breaking of the high-energy bond and the formation of new bonds with water molecules require energy, which leads to a decrease in free energy.
To illustrate this concept, let's consider the hydrolysis of ATP (adenosine triphosphate), which is a high-energy molecule commonly used as a source of energy in cells. When ATP is hydrolyzed, one of its phosphate groups is cleaved off, forming ADP and inorganic phosphate (Pi). This hydrolysis reaction releases energy that can be used by cells to perform various cellular processes.
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