Potassium chlorate, a common oxidizing agent in fireworks and matchheads, undergoes a solid-state disproportionation reaction when heated:

4KClO3 (s) ⟶ Δ3KClO4 (s) + KCl (s).

Use ΔHf ° and S° values to calculate ΔG_sys ° (which is ΔGrxn °) in kJ at 25°C for this reaction.

Answers

Answer 1

Answer:

Explanation:

[tex]\text{From the information given:}[/tex]

[tex]\text{The chemical reaction is : } 4 KClO_{3(s)} \to 3 KClO_{4(s)} + KCl_{(s)}[/tex]

[tex]\text{To find} \ \Delta G^0_{rxn}\ \text{using the formula}: \\ \\ \Delta G^0_{rxn} = \sum n_p \times \Delta _f G^0 (Products) - \sum n_R \times \Delta _fG^0 ( Reactants) \\ \\ where; n_p = \text{no of moles of products } \ and; \\ \\ n_R = \text{no of moles of reactants }[/tex]

[tex]\implies G^0_{rxn} = 3 \times \Delta _fG^0 [KClO_4{(s)}] + \Delta_fG^0[KCl_{(s)}] - 4 \times \Delta _f G^0 [ KClO_3 (s) ][/tex]

[tex]\Delta _fG^0 \ values \ at \ 25^0 \ C (298 \ K) are\ given \ as:\\\\ \Delta _fG^0 [KClO_4(s)] = -303.09 \ kJ \\ \\ \Delta _fG^0 [KCl(s) ] = - 409.14 \ kJ \\ \\ \Delta_f G^0 [KClO_3_{(s)}] = -296.25 \ kJ \\ \\ replacing \ the \ above \ values \ into \ equation (1) ; then:\\ \\ \\\Delta G^0_{rxn} = 3 *(-303.09) + (-409.14) - 4*(-296.25) \ kJ \\ \\ = (-909.27 - 409.14 + 1185) \ kJ \\ \\ = -133.41 \ kJ \\ \\ \mathbf{\Delta G^0_{rxn} = -133.4 \ kJ }[/tex]

Answer 2

The standard free energy change of the reaction is -133 kJ.

From the reaction equation, we have; 4KClO3 ⇄ 3KClO4 (s) + KCl (s). The standard free energy of formation of each specie is given below;

ΔG°f KClO3 = -296.35 kJ

ΔG°f KClO4 = -303.09 kJ

ΔG°f KCl = -409.14 kJ

Hence;

ΔG°rxn = [3(-303.09)] + ( -409.14)] - [(4( -296.35))]

ΔG°rxn = (-909.27) + (-409.14) - (-1185.4)

ΔG°rxn = -133 kJ

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Related Questions

Ca3(PO4)2 + 3H2SO4  3CaSO4 + 2H3PO4.
What mass of concentrated H2SO4 (98% by mass) must be used to react completely
with 100.00 g of calcium phosphate?

Answers

If anything isn’t obvious, don’t hesitate to ask me
Check the attached photo out...

100g  

H2SO4 = 3x98x100/310 = 94.84g

used mass of h2so4x100/all mass of H2so4 = 98%

yx100/98=94.84x100/98 = 96.81.

Check the attached photo for clear answer.

What is the use of calcium phosphate?

It may be used to treat conditions caused by low calcium levels such as bone loss (osteoporosis), weak bones (osteomalacia/rickets), decreased activity of the parathyroid gland (hypoparathyroidism), and certain muscle diseases (latent tetany).

Is calcium phosphate good for health?

About Calcium Phosphate Supplements

It aids in healthy bone development and is crucial from infancy to adulthood. But, calcium does more than build strong bones. It's also very important for healthy digestion. Calcium aids in bile acid metabolism, excretion of fatty acids, and healthy gut microbiota.

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Balance C3H8 + O2 + CO2 + H2O

Answers

Assuming the second plus sign is a typo and was meant to be a reaction arrow, this would be the balanced equation:

C3H8 + 5O2 —> 3CO2 + 4H2O

Which of the following statements is correct?

A. 2 moles of O2 is equal to 64 g of O2.

B. 2 moles of O2 is equal to 32 g of O2.

C. 2 moles of O2 is equal to 2 g of O2.

D. 1 moles of O2 is equal to 2 g of O2.

Answers

Answer:

pretty sure its B but if not I'm sorry

2 moles of O₂ is equal to 64 g of O₂ is the only correct statement among the given statements. Hence, Option (A) is correct. It can be solved by mole concept

What is Mole concept ?

The mole, symbol mol, is the SI base unit of amount of substance.

The quantity amount of substance is a measure of how many elementary entities of a given substance are in an object or sample.

formula ;

n = given weight / molecular weight

  = 64 / 32

  = 2 moles

Therefore, 2 moles of O₂ is equal to 64 g of O₂ is the only correct statement among the given statements. Hence, Option (A) is correct.

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PLEASE PLEAS HELP I REALLY NEED IT

Answers

Answer:  

A i took the quiz

Explanation:

How many grams of nitrogen dioxide are required to produce 260 grams of nitrogen monoxide? 3NO2 + H20 → 2HNO3 + NO

Answers

Answer:

1196 g

Explanation:

N= 14 O= 16

every 3 moles of NO2 gives one mole of NO

So, 3[14 + (2×16)] = 138 grams of NO2

gives : 14+16 = 30 grams of NO

NO2 NO

138 30

? 260

Therefore, 260 × 138 ÷ 30 = 1196 g of NO2 are required

How many moles of silver atoms are in the piece of jewelry?

Answers

moles contains 6.02 x 10^23 silver atoms

so moles = (5.29 X 10^22)/ (6.02 x 10^23)
= 5.29/6.02 x 1/10

The number of moles of silver atoms in the piece of jewelry is 0.08784 moles

Here is the complete question:

Suppose a piece of jewelry contains 5.29 × 10²² atoms of silver  . How many moles of silver atoms are in the piece of jewelry?

From the question,

A piece of jewelry contains 5.29 × 10²² atoms of silver.

To determine number of moles of silver atoms in the piece of jewelry,

We will use the formula

[tex]Number \ of \ moles = \frac{Number \ of \ atoms }{Avogadro's \ number}[/tex]

From the question

Number of atoms of silver = 5.29 × 10²² atoms

and

Avogadro's number = 6.022 × 10²³ atoms/mole

∴ [tex]Number \ of \ moles \ of \ silver \ atoms= \frac{5.29 \times 10^{22} }{ 6.022 \times 10^{23} }[/tex]

Number of moles of silver atoms = 0.08784 moles

Hence, the number of moles of silver atoms in the piece of jewelry is 0.08784 moles

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A 20.0 L container at 303 K holds a mixture of two gases with a total pressure of 5.00 atm. If there are 2.00 mol of Gas A in the mixture, how many moles of Gas B are present?

Answers

PV = nRT —> n = PV/RT
P = 5.00 atm
V = 20.0 L
R = 0.08206 L atm / mol K
T = 303 K

n = (5.00 • 20.0)/(0.08206 • 303)
= 4.02 mol = A + B
A = 2.00 mol
B = 2.02 mol

The number of moles of Gas B in the gas mixture is equal to 2.00 mol.

What is the ideal gas equation?

The ideal gas equation can be explained as an equation that describes the state of an ideal gas. This equation gives the product of the volume and pressure of ideal gas equal to the multiplication of the universal gas constant, absolute temperature, and moles of gas.

The mathematical form of the ideal gas equation mentioned below:

PV = nRT

Where P is the pressure, V is the volume, n is the moles, and R is the gas constant.

Given, the volume of the gas mixture, V = 500 ml = 0.5 L

The temperature of the gas mixture, T = 303 K

The pressure of the gas mixture = 5 atm

The value of gas constant, R =0.082 atmL/K mol

Substituting the values R, V, P, and T in the ideal gas law, we get:

The number of moles of the gas mixture, n = PV/RT

n = 5 ×20/(0.082 × 303)

n = 4.00 mol

The total number of moles of gas mixture = 4.00 mol

The moles of Gas A = 2.00 mol

The moles of Gas B = 4 - 2 = 2.00 mol

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Which of the following phase changes is exothermic?

gas to solid
solid to liquid
solid to gas
liquid to gas

Answers

Answer:

gas to solid

Explanation:

Exothermic means the release of heat. Any transformation from a less ordered to a more ordered state releases energy. This is represented by the change of a liquid to solid, gas to liquid, or gas to solid. Vise versa endothermic is the transformation from a more ordered state to a less ordered state represented by solid to liquid, liquid to gas, and solid to gas.


How many moles of chlorine atoms are there in 0.5 mol of titanium (III) chloride?​

Answers

Answer:

it is your answer..... if it is helpful plzz like and comment.....

What is the percent composition of hydrogen in glucose

Answers

Answer:

67%

Explanation:

Thus the % composition of glucose by mass is carbon 40.0 % oxygen 53.3 % hydrogen 6.7 % in this way, the % composition by mass of any compound can be calculated provided that is formed is known.

pleaaaaase helppppppppppppp ASAP

Answers

Answer:

Explanation:

a) The forward reaction is exothermic, hence when temperature is increased the equilibrium shift towards the reactants side to get rid of the excess energy. This will mean that more reactants are produced decreasing yield

b) There are a fewer number of moles of gas on the right side compared to the left side (Just count the coefficients before each compound) so a higher pressure will mean that the equilibrium will shift towards the products side in order to decrease the pressure. This will mean that more products are formed increasing yield

c) When something is powdered it's surface area to volume ratio increases. A higher surface area means that the particles around it have more area to work on so the frequency of collisions will increase increasing the rate of reaction. This is why iron is powdered.

Using the periodic table, choose the more reactive nonmetal.
Te or O

Answers

Answer:

answer is TE

Explanation:

Answer:

Tellurium is more reactive than Oxygen

How does size affect weight?
(20 points, write at least 5 sentences answer pls thx!)

Answers

Many weight charts have 10 pound increments in each frame size; small, medium, and large. ... Being big-boned or small boned doesn't justify a 20-25 pounds differential from a normal size person. If you are truly convinced you are not overweight just big boned.

Chlorine and hydrogen gas react to form hydrogen chloride as shown in the following reaction Cl 2 ( g)+H 2 (g)--->2HCl (g) Given a 7.10 g sample of chlorine (MM =71.0 g/mol) , how many grams of hydrogen chloride (MM =36.5 g/mol) is produced, assuming the reaction goes to completion? a. 7.10 g 6.3.65 9 c. 5,68 g d 7.300​

Answers

Answer:

it should be 7.300 sorry if I am wrong

Answer:

The answer is 115

Explanation:

Teacher walked me through it.

Which of the following would be defined as an exact number?
A. bronze is 12.5% by mass tin
B. 25 ml
C. 50.00 cm
D. 1.000 liters

Answers

a because that is the only anwser that would make sense

A chemist has a sample of 1.88 M HCl. What volume of the sample does he require to prepare 200 mL of 0.45 M HCl?

Answers

Answer: v = 200 ml · 0.45 M/ 1.88 M

Explanation: when solution is diluted, amount of substance

is same and n= c · V v1 = v2 · c2 / c1

The appropriate answer is "47.87 mL".

Given values are:

Concentration of undiluted HCl, [tex]C_1=1.88 \ M[/tex]Concentration of diluted HCl, [tex]C_2=0.45 \ M[/tex]Volume of diluted HCl, [tex]V_2=200 \ mL[/tex]

By using the dilution equation, we get

→ [tex]C_1V_1=C_2V_2[/tex]

or,

→     [tex]V_1=\frac{C_2V_2}{C_1}[/tex]

By substituting the given values, we get

→          [tex]=\frac{0.45\times 200}{1.88}[/tex]

→          [tex]=\frac{90}{1.88}[/tex]

→          [tex]= 47.87 \ mL[/tex]

Thus the above answer is correct.

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How can the speed of solvent molecules be slowed down?

A.by increasing the temperature

B. by increasing the surface area of the solute

C. by increasing the pressure

D. by decreasing the temperature

E. by decreasing the surface area of the solute

Answers

Answer:

D

Explanation:

When molecules absorb energy they speed up and have a more forceful collision with solute molecules.

You heat water and olive oil in two separate pans for a delicious new pasta recipe. The pans are the same temperature, but only the water is boiling! Why?

A
Olive oil has weaker intermolecular forces than water. This makes the intermolecular forces in oil easier to break, and keeps the molecules stuck together in a liquid state.

B
Water has weaker intermolecular forces than olive oil. This makes the intermolecular forces easier to break, allowing the individual water molecules to separate and change to a gas.

C
Water is losing electrons more quickly than olive oil is. The electrons float to the surface of the water, and their movement allows the phase change to happen.

Answers

Answer:

I think A is the correct answer

Answer: the answer is B 100%

Describe how chemical reactions are affected by reaction conditions
of monction?

Answers

Answer:

hope his helps

Explanation:

Mention the factors affecting the rate of reaction

There are four main factors that can affect the reaction rate of a chemical reaction:

Reactant concentration. Increasing the concentration of one or more reactants will often increase the rate of reaction. ...

Physical state of the reactants and surface area. ...

Temperature. ...

Presence of a catalyst.

What is the molality of a solution containing 18.2 g HCl and 250. g of water?

Answers

Answer:

m=2.0mol/kg

Explanation:

Hello there!

In this case, according to the formula to compute molality, which requires moles of solute (HCl) and kilograms of solvent (water), we first compute the moles of the former with its molar mass as shown below:

[tex]n=\frac{18.2g}{36.46g/mol}= 0.50mol[/tex]

And then the kilograms of water:

[tex]\frac{250.g}{1000g/kg} =0.250kg[/tex]

Finally, the molality turns out to be:

[tex]m=\frac{0.50mol}{0.250kg}\\\\m=2.0mol/kg[/tex]

Best regards!

Give an example of an electrolyte ​

Answers

Answer: sodium chloride water solution

Explanation: Eelctrolyte contains cations and anions which can

Transfer charge

Answer:

some energy drinks like powerade or Gatorade, and some juice drinks to.

Who ever has the best answer to this question gets brainliest

Answers

Answer:

"Conduction from the sun heating the metal slide" is the answer

Explanation:

I don’t understand please help

Answers

It’s C)H2SO4
Good luck
I agree the answer is C according to my research about it

g You are given a 1.25 gram mixture of calcium nitrate and calcium chloride. You dissolve this mixture in 200.0 mL of water and add an excess of 0.300 M silver nitrate. You collect and dry the white precipitate which forms and find it has a mass of 0.535 grams. Calculate the percent calcium chloride by mass in the original mixture.

Answers

Answer:

16.51%

Explanation:

The reaction that takes place is

CaCl₂(aq) + 2AgNO₃(aq) → 2AgCl(s) + Ca(NO₃)₂(aq)

Meaning that the white precipitate that formed is AgCl. Now we convert 0.535 g of AgCl into moles, using its molar mass:

0.535 g ÷ 143.43 g/mol = 0.00373 mol AgCl

Then we convert 0.00373 moles of AgCl into moles of CaCl₂, using the stoichiometric coefficients:

0.00373 mol AgCl * [tex]\frac{1molCaCl_2}{2molAgCl}[/tex] = 0.00186 mol CaCl₂

We convert moles of CaCl₂ into grams, using its molar mass:

0.00186 mol CaCl₂ * 110.98 g/mol = 0.206 g

Finally we calculate the percent of CaCl₂ by mass in the original mixture:

0.206 g / 1.25 g * 100% = 16.51%

The percent calcium chloride by mass in the original mixture is 16.4%

The equation of the reaction between calcium nitrate and silver chloride is:

[tex]\mathbf{CaCl_2 + 2AgNO_3 \to 2 AgCl+Ca(NO_3)_2}[/tex]

Given that;

the weight mass of the white precipitate formed is = 0.535 grams

the number of moles of the precipitated AgCl is:

= 0.535 g / 143.32 g/mol

= 0.0037 moles

From the above reaction, If 2 moles of AgCl are formed  by 1 mole of CaCl2

Then, 0.0037 moles of AgCl will form (0.0037 × 1)/2 moles of CaCl2.

0.0037 moles of AgCl will form 0.00185 moles of CaCl2.

Now, we can say that the number of moles of CaCl2 present in the mixture is =  0.00185 moles

Mass amount of CaCl2 present = 0.00185 moles × 110.98 g/mol

Mass amount of CaCl2 present = 0.205 grams

Finally, the mass percentage   [tex]\mathbf{=\dfrac{0.205}{1.25}\times 100\%}[/tex]

= 16.4%

Therefore, we can conclude that the percent calcium chloride by mass in the original mixture is 16.4%

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need help asap, In this reaction how many units of B are required to form 40 units of C? A+2B--->C​

Answers

Answer:

80 units B

Explanation:

Equation for the reaction is given below:

A + 2B —> C

From the equation above,

2 units of B reacted to produce 1 unit to C.

Finally, we shall determine the unit of B needed to produce 40 units of C. This can be obtained as follow:

From the equation above,

2 units of B reacted to produce 1 unit to C.

Therefore, x unit of B will react to produce 40 units of C i.e

x unit of B = 2 × 40

x unit of B = 80 units

Thus, 80 units B is needed for the reaction.

Which superpower would you have for the rest of your life?
The ability to fly
Teleportation
Super speed
Super strength
Invisibility
Time travel
Or be normal and have nothing special

Answers

time travel is the best option

Identify the type of reaction.

Al + MgSO4 = Al2(SO4)3 + Mg

Answers

Answer: its combustion

Explanation:

120 L of C3H8 is how many grams?

Answers

Answer:

44.09562 grams

Explanation:

what are the twa parts of central nervous system ?​

Answers

the brain and the spinal cord

Answer:

The nervous system has two main parts: The central nervous system is made up of the brain and spinal cord.

Explanation:

Which environment can occur for a short while and usually found in low level areas along rivers, lakes, and streams?

Desert
Mountain
Rainforest
Wetland

Answers

the answer is wetland

Answer:The answer is wetland or rainforest

Explanation:

It’s wetland or rainforest because its with the tropical zone and there will be no such thing as desert and mountain have those but the rainforest is with the tropic to so Goodluck with any of your test and hope this did not make sense xdd

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