The following 1H NMR absorptions were obtained on a spectrometer operating at 200 MHz and are given in Hz downfield from TMS. Convert the absorptions to δ units. a) 416 Hz = δ b) 1.97×103 Hz = δ c) 1.50×103 Hz = δ

Answers

Answer 1

Answer:

For (a): The chemical shift is [tex]2.08\delta[/tex]

For (b): The chemical shift is [tex]9.85\delta[/tex]

For (c): The chemical shift is [tex]7.5\delta[/tex]

Explanation:

To calculate the chemical shift, we use the equation:

[tex]\text{Chemical shift in ppm}=\frac{\text{Peak position (in Hz)}}{\text{Spectrometer frequency (in MHz)}}[/tex]

Given value of spectrometer frequency = 200 MHz

For (a):

Given peak position = 416 Hz

Putting values in above equation, we get:

[tex]\text{Chemical shift in ppm}=\frac{416Hz}{200MHz}\\\\\text{Chemical shift in ppm}=2.08\delta[/tex]

For (b):

Given peak position = [tex]1.97\times 10^3 Hz[/tex]

Putting values in above equation, we get:

[tex]\text{Chemical shift in ppm}=\frac{1.97\times 10^3Hz}{200MHz}\\\\\text{Chemical shift in ppm}=9.85\delta[/tex]

For (c):

Given peak position = [tex]1.50\times 10^3 Hz[/tex]

Putting values in above equation, we get:

[tex]\text{Chemical shift in ppm}=\frac{1.50\times 10^3Hz}{200MHz}\\\\\text{Chemical shift in ppm}=7.5\delta[/tex]


Related Questions

A 3.25-gram bullet traveling at 345 ms-1 strikes and enters a 2.50-kg crate. The crate slides 0.75 m along a wood floor until it comes to rest.

Required:
a. What is the coefficient of dynamic friction between crate and the floor?
b. What is the average force applied by the crate on the bullet during collision if the bullet penetrates the 1.10cm into the crate?

Answers

Answer:

a)   μ = 0.0136, b)   F = 22.8 N

Explanation:

This exercise must be solved in parts. Let's start by using conservation of moment.

a) We define a system formed by the downward and the box, therefore the forces during the collision are internal and the momentum is conserved

initial instant. Before the crash

        p₀ = m v₀

final instant. After inelastic shock

        p_f = (m + M) v

the moment is preserved

        p₀ = p_f

        m v₀ = (m + M) v

        v = [tex]\frac{m}{m + M} \ v_o[/tex]

We look for the speed of the block with the bullet inside

        v = [tex]\frac{0.00325}{0.00325 + 2.50 } \ 345[/tex]

        v = 0.448 m / s

Now we use the relationship between work and kinetic energy for the block with the bullet

in this journey the force that acts is the friction

         W = ΔK

          W = ½ (m + M) [tex]v_f^2[/tex]  - ½ (m + M) v₀²

the final speed of the block is zero

the work between the friction force and the displacement is negative, because the friction always opposes the displacement

         W = - fr x

we substitute

           - fr x = 0 - ½ (m + M) vo²

           fr = ½ (m + M) v₀² / x

         

the friction force is

          fr = μ N

          μ = fr / N

equilibrium condition

          N - W = 0

          N = W

          N = (m + M) g

we substitute

         μ = ½ v₀² / x g

we calculate

          μ = ½ 0.448 ^ 2 / 0.75 9.8

          μ = 0.0136

b) Let's use the relationship between work and the variation of the kinetic energy of the block

          W = ΔK

initial block velocity is zero vo = 0

         F x₁ = ½ M v² - 0

         F = [tex]\frac{1}{2} M \frac{x}{y} \frac{v^2}{x1}[/tex]

         F = ½ 2.50 0.448² / 0.0110

         F = 22.8 N

PLEASE HELP ME WITH THIS ONE QUESTION
The half-life of Barium-139 is 4.96 x 10^3 seconds. A sample contains 3.21 x 10^17 nuclei. How much of the sample is left after 1.98 x 10^4 seconds?

A) 8.03 x 10^16 nuclei

B) 4.01 x 10^16 nuclei

C) 2.02 x 10^16 nuclei

D) 1.61 x 10^17 nuclei

Answers

OPTION C is the correct answer.

The radioactive decay follows the first order kinetics. The number of atoms decaying at any time is proportional to the number of atoms present at that instant. The amount of sample left is 2.02 x 10¹⁶nuclei. The correct option is C.

What is half-life?

The time required for the decay of one half of the amount of the species is defined as the half-life period of a radionuclide. The half-life period is a characteristic of a radionuclide. The half lives can vary from seconds to billions of years.

The isotope decay of an atom is given by the equation:

ln [A] = -kt + ln [A]₀

The rate constant, k is:

k = ln 2 / Half life

k = ln 2 / 4.96 x 10³

k = 1.40 × 10⁻⁴ s⁻¹

t = 1.98 x 10⁴

[A]₀ = 3.21 x 10¹⁷

ln [A] = -1.40 × 10⁻⁴  ×  1.98 x 10⁴ + ln [3.21 x 10¹⁷] = 37.538

[A] = 2.02 x 10¹⁶ nuclei

Thus the correct option is C.

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According to Newton’s law of universal gravitation, which statements are true?

Answers

1,3,5 it should be right because i have took that thing before

FROM THE _____ WHOLE WATER CYCLE STARTS ALL OVER AGAIN

Answers

Clouds? I am not sure of your options!

From the water whole water cycle starts again.

Most possibly water should be the answer.

reviews the general principles in this problem. A projectile is launched from ground level at an angle of 13.0 ° above the horizontal. It returns to ground level. To what value should the launch angle be adjusted, without changing the launch speed, so that the range doubles?

Answers

Answer: θ would equal approximately 28.7°

This is a kinematics problem, where one is only given the theta value 13.0° in regards to the range; thus, the problem is testing one's understanding of the relationships between the variables.

Range (aka x) = (v₀ sin (2θ₀))/g, where θ₀ = 13.0°

Now if we multiply the range by 2, we get:

2x = 2((v₀ sin (2θ₀))/g) → to verbalize, if range equates to (v₀ sin (2θ₀))/g, and doubling the range equals twice the product value, then:

2θ = sin⁻¹(2sin(2(13.0° )) = sin⁻¹(2(0.76255845048)) = sin⁻¹ (1.52511690096) = 57.35560850015109°/2 = θ

Thus, θ = 28.67780425

It's been awhile since I did this; though I hope it helped!

Trong máy phát điện xoay chiều ba pha khi tổng điện áp tức thời của cuộn 1,2 là e1+e2=120V thì điện áp tức thời của cuộn 3 là

Answers

Answer:

I just noticd i dont speak this launguage

Explanation:

From the top of the leaning tower of Pisa, a steel ball is thrown vertically downwards with a speed of 3.00 m/s. if the height of the tower is 200 m, how long will it take for the ball to hit the ground? Ignore air resistance.

Answers

Answer:

66,7 seconds

Explanation:

the formula for height/distance is : S=v.t

2. The given graph shows that the object is
(a) in non-uniform motion
(b) in uniform motion
(c) at rest
(d) in an oscillatory motion.
distance
time​

Answers

Answer:

(c) at rest

Explanation:

Given

See attachment for the distance time graph

Required

What does the graph illustrate?

From the graph, we can see that the line of distance is a horizontal line.

This suggests that a time increases, the distance remains unchanged

When distance remains unchanged over time, then it means the object is at rest.

Hence, (c) is correct

What is the energy equivalent of an object with a mass of 1.05g?​

Answers

Answer:

The equivalent energy of an object given its mass is calculated through the equation,

                             E = mc²

where c is the speed of light (3 x 10^8 m/s)

Substituting the known values,

                            E = (1.05 g/ 1000) (3 x 10^8 m/s)²

                               E = 9.45x10^13 J

Explanation:

An astronaut throws a wrench in interstellar space. How much force is required to keep the wrench moving continuously with constant velocity?
A.
a force equal to its weight on Earth
B.
a force equal to zero
C.
a force equal to half of its weight on Earth
D.
a force equal to double its weight on Earth

Answers

Answer:

0 N

Explanation:

This is a trick question, the mass of the wrench would be 0 due to it being in space and has no gravitational pull to weight it down. And since acceleration is defined as the rate and change of velocity with no respect of time and the wrench is moving at a constant velocity, that means the velocity is 0. and since F = m*a it would be F = 0 * 0 = 0 N

What happens in the gray zone between solid and liquid?-,-​

Answers

The gray zone transition is very crucial which includes the inter molecular forces acting on the molecules and each atoms which makes the change in state from hot to cold and cold to hot. and for it to be liquid to solid or solid to liquid the transition needs to cross the gray zone.

:]

Calculating Acceleration
Initial
velocity
Time to travel
0.25 m
Final
velocity
Acceleration
Time to travel
0.50 m
# of
washers
11
(m/s)
V2
(m/s)
ti
(s)
t₂
(s)
a = (v2 - v4)/(t2-tı)
(m/s)
1
0.11
0.28
2.23
3.13
0.19
2
0.13
0.36
1.92
2.61
The acceleration of the car with two washers added to the string would be

Answers

I can not even read this question.

What are you trying to even say?

The acceleration of the car with two (2) washers added is equal to 0.33 [tex]m/s^2[/tex].

Given the following data:

Initial velocity = 0.13 m/s.Final velocity = 0.36 m/s.Initial time = 1.92 seconds.Final time = 2.61 seconds.

What is an acceleration?

An acceleration can be defined as the rate of change of velocity of an object with respect to time and it is measured in meter per seconds square.

How to calculate average acceleration.

In Science, the average acceleration of an object is calculated by subtracting its initial velocity from the final velocity and dividing by the change in time for the given interval.

Mathematically, average acceleration is given by this formula:

[tex]a = \frac{V\;-\;U}{t_f-t_i}[/tex]

Where:  

V is the final velocity.U is the initial velocity.[tex]t_i[/tex]initial time measured in seconds.[tex]t_f[/tex] final time measured in seconds.

Substituting the given parameters into the formula, we have;

[tex]a = \frac{0.36\;-\;0.13}{2.61\;-\;1.92}\\\\a=\frac{0.23}{0.69}[/tex]

a = 0.33 [tex]m/s^2[/tex]

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how do you use the coefficient to calculate the number of atoms in each molecule?​

Answers

wait is there supposed to be a picture here?

Answer:

To find out the number of atoms: MULTIPLY all the SUBSCRIPTS in the molecule by the COEFFICIENT. (This will give you the number of atoms of each element.)

Explanation:

A magnetic field of 0.276 T exists in the region enclosed by a solenoid that has 517 turns and a diameter of 10.5 cm. Within what period of time must the field be reduced to zero if the average magnitude of the induced emf within the coil during this time interval is to be 12.6 kV

Answers

Answer:

The period the field must be reduced to zero is 9.81 x 10⁻⁵ s

Explanation:

Given;

initial value of the magnetic field, B₁ = 0.276 T

number of turns of the solenoid, N = 517 turns

diameter of the solenoid, d = 10.5 cm = 0.105 m

induced emf, = 12.6 kV = 12,600 V

when the field becomes zero, then the final magnetic field value, B₂ = 0

The induced emf is given by Faraday's law;

[tex]emf = -\frac{NA\Delta B}{t} \\\\emf = -\frac{NA (B_2 -B_1)}{t} \\\\t = -\frac{NA (B_2 -B_1)}{emf}\\\\t = \frac{NA (B_1 -B_2)}{emf}\\\\where;\\\\t \ is \ the \ time \ when \ B = 0 \ \ (i.e\ B_2 = 0)\\\\A \ is \ the \ area \ of \ the \ coil\\\\A = \frac{\pi d^2}{4} = \frac{\pi (0.105)^2}{4} = 0.00866 \ m^2\\\\t= \frac{(517) \times (0.00866)\times (0.276 -0)}{12,600}\\\\t = 9.81 \times 10^{-5} \ s[/tex]

Therefore, the period the field must be reduced to zero is 9.81 x 10⁻⁵ s

The viscid silk produced by the European garden spider (Araneus diadematus) has a resilience of 0.35. If 10.0 J of work are done on the silk to stretch it out, how many Joules of work are released as thermal energy as it relaxes?

Answers

Answer: The energy released as thermal energy is 6.5 J

Explanation:

Energy stored by the spider when it relaxes is given by:

[tex]E_o=\text{Resilience}\times \text{Work}[/tex]

We are given:

Resilience = 0.35

Work done = 10.0 J

Putting values in above equation, we get:

[tex]E_o=0.35\times 10\\\\E_o=3.5J[/tex]

Energy released at thermal energy is the difference between the work done and the energy it takes to relaxes, which is given by the equation:

[tex]E_T=\text{Work done}-E_o[/tex]

Putting values in above equation, we get:

[tex]E_T=(10-3.5)=6.5J[/tex]

Hence, the energy released as thermal energy is 6.5 J

The energy released as thermal energy when 10 J of work is done to stretch silk will be 6.5 J

What is thermal energy?

Thermal energy refers to the energy contained within a system that is responsible for its temperature. Heat is the flow of thermal energy.

Energy stored by the spider when it relaxes is given by:

[tex]\rm E_o=Resilience \ \times Work[/tex]

We are given:

Resilience = 0.35

Work done = 10.0 J

Putting values in above equation, we get:

[tex]\rm E_o=0.35\times 10[/tex]

[tex]E_o=3.5\ J[/tex]

Energy released at thermal energy is the difference between the work done and the energy it takes to relaxes, which is given by the equation:

[tex]E_T=\rm Work done -E_o[/tex]

Putting values in above equation, we get:

[tex]E_T=(10-3.5)=6.5\ J[/tex]

Hence, the energy released as thermal energy is 6.5 J

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What recommendations would you give to the global government to help Decrease the global effects of human impact on the environment mystery recommendations and how they will positively impact our planet

Answers

Answer:

We can help to keep it magnificent for ourselves, our children and grandchildren, and other living things besides us.

Explanation:

5 ways our governments can confront climate change

PROTECT AND RESTORE KEY ECOSYSTEMS

SUPPORT SMALL AGRICULTURAL PRODUCERS

PROMOTE GREEN ENERGY

COMBAT SHORT-LIVED CLIMATE POLLUTANTS

BET ON ADAPTATION, NOT JUST MITIGATION

A positively charged plastic ruler is brought close to a piece paper resting on the desk. The piece of paper was initially neutral. When the ruler was brought closer, the paper is attracted to the ruler. The surface of the paper became charged through:_________

Answers

Answer: static electricity

Explanation:

When the plastic ruler is rubbed, friction opposes the motion and causes the transfer of electron from one surface to another such that plastic becomes negatively charged. When ruler is brought nearer to the paper, it induces the   positive charge in the piece of paper.

An electric device, which heats water by immersing a resistance wire in the water, generates 20 cal of heat

per second when an electric potential difference of 6 V is placed across its leads. What is the resistance in Ω

of the heater wire? (Note: 1 cal = 4.186 J)

Select one:
a. 0.86
b. 0.17
c. 0.29
d. 0.43

Answers

Answer:

1 cal/s =4.184w

p=50 cal/s =2093w

v=12v

P = V*I

I =P/V

I = 17.43 A

P =1²*R

R = P/I²

R = 0.68

please help very easy 5th grade work giving brainliest

Answers

Answer:

the answer is option B because opposit sides of the magnets attract each other

Which type of energy is stored in a battery?
A. Nuclear energy
B. Electromagnetic energy
C. Chemical energy
D. Electrical energy
SUBMI

Answers

Answer:

c

Explanation:

in food and batteries chemical energy is stored :) hope this helped

Radiation exerts pressure on surfaces on which it lalls (radintion pressure). Will this pressure be greater on a shiny surface or a dark surface

Answers

Answer:

Shiny surface.

Explanation:

We know that radiation pressure is the pressure over a surface exposed to electromagnetic radiation.

Where if the radiation is absorbed by the material (like in the case of a dark surface), the pressure is the energy density flux divided by the speed of light, while if the radiation is totally reflected (idealized case, but we can suppose that this happens for a shiny surface) the pressure is twice pressure for the absorbed case.

This is a simplification for the radiation pressure but is enough to conclude that the radiation pressure is always greater on reflective surfaces, then for this case, the pressure will be greater on a shiny surface than in a dark surface,

Calculate the Combined resistance of the Circuit voltage across each resistor Current Passing through each resistor of 6,8,12ohms​

Answers

Answer:

Sorry I don't know the answer

PLEASE HELP ME WITH THIS ONE QUESTION
The half-life of Barium-139 is 4.96 x 10^3 seconds. A sample contains 3.21 x 10^17 nuclei. What is the decay constant for this decay?

A) 1.67 x 10^-4 s^-1

B) 5.43 x 10^-4 s^-1

C) 1.40 x 10^-4 s^-1

D) 2.22 x 10^-4 s^-1

Answers

OPTION C is the correct answer.

Consider a swimmer that swims a complete round-trip lap of a 50 m long pool in 100 seconds. What is the swimmers average speed and average velocity?

Answers

Answer:

The average speed is 1 m/s

The average velocity is 0

Explanation:

Given;

length of the pool, L = 50 m

time taken for the motion, t = 100 s

The total distance = 50 m + 50 m

The total distance = 100 m

The average speed = total distance / total time

                                  = 100 / 100

                                  = 1 m/s

The average velocity = change in displacement / change in time

change in displacement = 50 m - 50 m = 0

The average velocity = 0 / 100

The average velocity = 0

A 5 kg box drops a distance of 10 m to the ground. If 70% of the initial potential energy goes into increasing the internal energy of the box, determine the magnitude of the increase.

Answers

Answer:

Explanation:

From the given information:

The initial PE [tex](PE)_i[/tex] = m×g×h

= 5 kg × 9.81 m/s² × 10 m

= 490.5 J

The change in Potential energy P.E of the box is:

ΔP.E = [tex]P.E_f -P.E_i[/tex]

ΔP.E = 0 - [tex](PE)_i[/tex]

ΔP.E = [tex]-P.E_i[/tex]

If we take a look at conservation of total energy for determining the change in the internal energy of the box;

[tex]\Delta P.E + \Delta K.E + \Delta U = 0[/tex]

[tex]\Delta U = -\Delta P.E - \Delta K.E[/tex]

this can be re-written as:

[tex]\Delta U =- (-\Delta P.E_i) - \Delta K.E[/tex]

Here, K.E = 0

Also, 70% goes into raising the internal energy for the box;

Thus,

[tex]\Delta U =(70\%) \Delta P.E_i-0[/tex]

[tex]\Delta U =(0.70) (490.5)[/tex]

ΔU = 343.35  J

Thus, the magnitude of the increase is = 343.35 J

g Is a nucleus that absorbs at 4.13 δ more shielded or less shielded than a nucleus that absorbs at 11.45 δ? _________ Does the nucleus that absorbs at 4.13 δ require a stronger applied field or a weaker applied field to come into resonance than the nucleus that absorbs at 11.45 δ?

Answers

Answer: A nucleus that absorbs at [tex]11.45\delta[/tex] is less shielded and a nucleus that absorbs at [tex]4.13\delta[/tex] will require a stronger applied field

Explanation:

While interpreting the data in NMR, the positions of signals are studied.

The nucleus/ protons having a higher value of [tex]\delta[/tex] are said to be less shielded. They are said to be upfield.

The nucleus/protons having a lower value of [tex]\delta[/tex] are said to be more shielded. They are said to be downfield.

So, a nucleus that absorbs at [tex]11.45\delta[/tex] is less shielded by the nucleus that absorbs at [tex]4.13\delta[/tex]

Also, the less shielded nucleus/protons will require a weak applied field to come into resonance than the more shielded nucleus/protons

So, a nucleus that absorbs at [tex]4.13\delta[/tex] will require a stronger applied field to come into resonance than the nucleus that absorbs at [tex]11.45\delta[/tex]

Assume that the energy lost was entirely due to friction and that the total length of the PVC pipe is 1 meter. Use this length to compute the average force of friction (for this calculation, you may neglect uncertainties).

Answers

The question is incomplete. The complete question is :

Assume that the energy lost was entirely due to friction and that the total length of the PVC pipe is 1 meter. Use this length to compute the average force of friction (for this calculation, you may neglect uncertainties).

Mass of the ball :  16.3 g

Predicted range :  0.3503 m

Actual range : 1.09 m

Solution :

Given that :

The predicted range is 0.3503 m

Time of the fall is :

[tex]$t=\sqrt{\frac{2H}{g}}$[/tex]

[tex]v_1t= 0.35[/tex]  ...........(i)

[tex]v_0t= 1.09[/tex]  ...........(ii)

Dividing the equation (ii) by (i)

[tex]$\frac{v_0t}{v_1t}=\frac{1.09}{035} = 3.11$[/tex]

∴ [tex]v_0=3.11 \ v_1[/tex]

Now loss of energy  = change in the kinetic energy

[tex]$W=\frac{1}{2} m [v_0^2-v_1^2]$[/tex]

[tex]$W=\frac{1}{2} \times (16.3 \times 10^{-3}) \times [v_0^2-\left(\frac{v_0}{3.11}\right)^2]$[/tex]

[tex]$W=7.307\times 10^{-3} \ v_0^2$[/tex]

If f is average friction force, then

(f)(L) = W

(f) (1) = [tex]$7.307\times 10^{-3} \ v_0^2$[/tex]

(f)  = [tex]$7.307\times 10^{-3} \ v_0^2$[/tex]

The Average force of friction is ( F )  = 7.307 * 10⁻³ v₀²

Given data:

Predicted range ( v₁t ) = 0.3503 m

Actual range ( v₀t ) = 1.09 m

mass = 16.3 g

First step : Determine the value of  V₀

[tex]t = \sqrt{\frac{2H}{g} }[/tex]    ,    v₁t  =  0.3503 ,    ( v₀t ) = 1.09 m

To obtain the value of  V₀  

Divide ( v₀t ) by ( v₁t )  =  1.09 / 0.3503 = 3.11 v₁

V₀ = 3.11 v₁

Next step : Determine the average force of friction ( f )

given that loss of energy results in a change in kinetic energy

W = [tex]\frac{1}{2} m ( vo^{2} - v1^{2} )[/tex]

    = 1/2 * 16.3 * 10⁻³ * [ v₀² - [tex](\frac{v_{0} }{3.11} )^{2}[/tex] ]

W = 7.307 * 10⁻³ v₀²

Average force of friction = W / Actual length

                                         = 7.307 * 10⁻³ v₀² / 1  

∴ Average force of friction ( F )  = 7.307 * 10⁻³ v₀²

Hence we can conclude that the average force of friction is 7.307 * 10⁻³ v₀²

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Your question has some missing data below are the missing data related to your question

Mass of the ball :  16.3 g

Predicted range :  0.3503 m

Actual range : 1.09 m

The power in an electrical circuit is given by the equation P= RR, where /is the current flowing through the circuit and Ris the resistance of the circuit. What is the current in a circuit that has a resistance of 100 ohms and a power of 15 watts?

[pleas ee helpppp)​

Answers

I= 0.39 A

OPTION B is the correct answer.

A laser emits a single 3.0-ms pulse of light that has a frequency of 2.83E11 Hz and a total power of 65000 W. How many photons are in the pulse? Please provide all equations and work.

6.0E23
1.0E24
2.4E25
3.6E25
4.8E26

Answers

Answer:

The number of photons in the pulse is 1.04 x 10²⁴

Explanation:

Given;

frequency of the emitted photons, f = 2.83 x 10¹¹ Hz

duration of the incident light, t = 3 ms = 3 x 10⁻³ s

power of the incident light, P = 65,000 W

The energy of each photon emitted is calculated as;

E = hf

where;

h is Planck's constant, = 6.626 x 10⁻³⁴ Js

E =  6.626 x 10⁻³⁴ x  2.83 x 10¹¹

E = 1.875 x 10⁻²² J

let the number of photons in the pulse = n

n(E)= Power x time

[tex]n = \frac{Pt}{E} \\\\n = \frac{65,000 \times 3\times 10^{-3}}{1.875 \times 10^{-22}} \\\\n = 1.04 \times 10^{24} \ photons[/tex]

At 20 ◦C a copper wire has a resistance of 4×10−3 Ω and a temperature coefficient of resistivity of 3.9×10−3 (C◦)−1, its resistance at 100 ◦C is

A.
52.5 × 10-3 Ω
B.
5.25 × 10-3 Ω
C.
5.25 × 10-4 Ω
D.
5.25 × 10-2 Ω


E.
25.5 × 10-3 Ω

Answers

Answer:

[tex]R _{t} = R _{0}( \alpha t + 1) \\ = 4 \times {10}^{ - 3} (3.9 \times {10}^{ - 3} \times 20 + 1) \\ = 4 \times {10}^{ - 3} (1.078) \\ = 4.312 \times {10}^{ - 3} \: Ω[/tex]

Other Questions
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