Answer:
I. dipole-dipole
III. dispersion
IV. hydrogen bonding
Explanation:
Intermolecular forces are weak attraction force joining nonpolar and polar molecules together.
London Dispersion Forces are weak attraction force joining non-polar and polar molecules together. e.g O₂, H₂,N₂,Cl₂ and noble gases. The attractions here can be attributed to the fact that a non -polar molecule sometimes becomes polar because the constant motion of its electrons may lead to an uneven charge distribution at an instant.
Dispersion forces are the weakest of all electrical forces that act between atoms and molecules. The force is responsible for liquefaction or solidification of non-polar substances such as noble gas an halogen at low temperatures.
Dipole-Dipole Attractions are forces of attraction existing between polar molecules ( unsymmetrical molecules) i.e molecules that have permanent dipoles such as HCl, CH3NH2 . Such molecules line up such that the positive pole of one molecule attracts the negative pole of another.
Dipole - Dipole attractions are more stronger than the London dispersion forces but weaker than the attraction between full charges carried by ions in ionic crystal lattice.
Hydrogen Bonding is a dipole-dipole intermolecular attraction which occurs when hydrogen is covalently bonded to highly electronegative elements such as nitrogen, oxygen or fluorine. The highly electronegative elements have very strong affinity for electrons. Hence, they attracts the shared pair of electrons in the covalent bonds towards themselves, leaving a partial positive charge on the hydrogen atom and a partial negative charge on the electronegative atom ( nitrogen in the case of CH3NH2 ) . This attractive force is know as hydrogen bonding.
Answer:
The intermolecular forces present in CH_3NH_2 includes
II. (ion-dipole) and IV. (hydrogen bonding)Explanation:
The intermolecular forces present in CH_3NH_2 includes II. (ion-dipole) and IV. (hydrogen bonding)
It is a polar molecule due to NH polar bond and it can form Hydrogen bond also due to NH bond.
Interaction will be dipole- dipole and Hydrogen dispersion forces can always be taken into account.
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Determine whether the following statement about reaction rates is true or false. If the statement is false, select the reason why.
Increasing the temperature of a reaction system decreases the activation energy of the reaction.
A. True
B. False
Answer:
False
Explanation:
The reaction rate increases if the temperature also increases, as does the concentration of ractives or the presence of catalysts.
The reaction rate talks about how reagents are converted into products as a function of time, this process can take less or more depending on the factors to which the reaction is exposed.
The increasing temperature generates an increase in the kinetic energy of the particles, promoting their proximity and their reaction between them to be able to give the final product, so a faster reaction occurs, which is why it has promoted when the particles collide.
volume of percentage =
formula??
Answer:
Volume percent is defined as: v/v % = [(volume of solute)/(volume of solution)] x 100%
Explanation:
Draw the major condensation product obtained by treatment of ethyl 3-methylbutanoate with sodium ethoxide in ethanol.
Answer:
ethyl 3-ethoxy-3-hydroxy-2-isopropyl-5-methyl hexanoate
Explanation:
In this case, we have a very strong base (sodium ethoxide). Therefore, this compound will remove a hydrogen from ethyl 3-methyl butanoate generating a carbanion.
This carbanion, can attack another ethyl 3-methyl butanoate molecule on the carbonyl group generating a new C-C bond and producing a negative charge in the oxygen.
Then the ethanol can protonate the molecule generating an "OH" group and the ethoxide.
See figure 1
I hope it helps!
For the following set of pressure/volume data, calculate the new volume of the gas sample after the pressure change is made. Assume that the temperature and the amount of gas remain constant.
a. 125 mL at 755 mm Hg; V =2mL at 780 mm Hg
b. 223 mL at 1.08 atm; V =2mL at 0.951 atm
c. 3.02 L at 103 kPa; V= 2Lat 121 kPa
Answer:
a. 121 ml, b. 253 ml and c. 2.57 L.
Explanation:
The new volume can be calculated by using the Boyle's law equation:
P1V1 = P2V2
In the equation, P1 and P2 are the initial and final pressures and V1 and V2 are the initial and final volumes for a real gas at constant temperature.
a) Based on the given information, P1 = 755 mmHg, V1 = 125 ml, P2 = 780 mm Hg and V2 will be,
V2 = P1V1/P2
V2 = 755 mmHg × 125 ml/780 mmHg
V2 = 121 ml
b) Based on the given information, P1 = 1.08 atm, V1 = 223 ml, P2 = 0.951 atm and V2 will be,
V2 = P1V1/P2
V2 = 1.08 atm × 223 ml/0.951 atm
V2 = 253 ml
c) Based on the given information, P1 = 103 kPa, V1 = 3.02 L, P2 = 121 kPa and V2 will be,
V2 = P1V1/P2
V2 = 103 kPa × 3.02 L/121kPa
V2 = 2.57 L
The formula of complex ion formed when aluminum hydroxide dissolves in sodium hydroxide will be: Select the correct answer below: [AlOH]2+
Answer:
Al(OH)₃ + OH⁻ → Al(OH)₄⁻
The compound is called hydroxoaluminate.
Explanation:
Aluminiun Hydroxide → Al(OH)₃
NaOH → Sodium hydroxide.
The Al(OH)₃ is an amphoteric compound, while the NaOH is a strong base. When they react, we may think that, fist of all, the base can dissociate: NaOH → Na⁺ + OH⁻
So the Al(OH)₃ will be a Lewis acid, as it can donate a pair of e⁻
Al(OH)₃ + OH⁻ → Al(OH)₄⁻
Lead ions are toxic when absorbed into the body and can interfere with the neurological development of children. Based on what you learned in this lab activity, what substance might be added to an IV solution to remove Pb2 ions from the blood of a contaminated person
Answer:
The interpretation of the particular subject is covered in the subsection below in detail.
Explanation:
Large quantities of heavy substances like Lead ions become extremely poisonous when provided by a human. The administration of the medications recognized as "chelators" will eliminate these harmful chemicals from an infected individual's blood.However, here law enforcers calcium sodium polyacrylate seems to be the safest chelator in radiation sickness. It could be administered intravenously and attaches throughout the blood system with either the lead ions and afterward, removes the metal-chelator complicated from urine.A certain reaction has an activation energy of 39.5 kJ/mol. As the temperature is increased from 25.0°C to a higher temperature, the rate constant increases by a factor of 5.90. Calculate the higher temperature (in °C).
Answer:
Explanation:
We shall apply Arrhenius equation which is given below .
[tex]ln\frac{k_2}{k_1} = \frac{E_a}{R} [\frac{1}{T_1} -\frac{1}{T_2} ][/tex]
K₂ and K₁ are rate constant at temperature T₂ and T₁ , Ea is activation energy .
Putting the given values
[tex]ln\frac{5.9}{1} = \frac{39500}{8.3} [\frac{1}{298} -\frac{1}{T_2} ][/tex]
[tex].000373= [\frac{1}{298} -\frac{1}{T_2} ][/tex]
T₂ = 335.27 K
= 62.27 °C
The higher temperature is 62.27°C.
Calculating the higher temperature:Given that the activation energy of the reaction is:
Eₐ = 39.5 kJ/mol
initial temperature T₁ = 25°C = 298K
Let the final temperature be T₂
The rate constant at temperature T₁ be K₁, and at a temperature T₂ be K₂.
According to the question: K₂/K₁ = 5.9
Now, applying the Arrhenius equation we get:
[tex]\ln\frac{K_2}{K1}=\frac{E_a}{R}[\frac{1}{T_1} -\frac{1}{T_2}]\\\\\ln(5.9)= \frac{39.5}{8.3}[\frac{1}{298} -\frac{1}{T_2}]\\\\0.000373=\frac{1}{298} -\frac{1}{T_2}[/tex]
T₂ = 335.27K
T₂ = 335.27 -273
T₂ = 62.27°C
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To calculate changes in concentration for a system not at equilibrium, the first step is to determine the direction the reaction will proceed. To do so, we calculate Q and compare it to the equilibrium concentration, K. We can then determine that a reaction will shift to the right if:__________
Answer:
We can then determine that a reaction will shift to the right if Q<K
Explanation:
Comparing Q with K allows to find out the status and evolution of the system:
If the reaction quotient is equal to the equilibrium constant, Qc = Kc, the system has reached chemical equilibrium. If the reaction quotient is greater than the equilibrium constant, Qc> Kc, the system is not in equilibrium and will evolve spontaneously, decreasing the value of Qc until it equals the equilibrium constant. In this way, the concentrations of the products will decrease and the concentrations of the reagents will increase. In other words, the reverse reaction is favored to achieve equilibrium. Then the system will evolve to the left (ie products will be consumed and more reagents will be formed).If the reaction quotient is less than the equilibrium constant, Qc <Kc, the system is not in equilibrium and will evolve spontaneously increasing the value of Qc until it equals the equilibrium constant. This implies that the concentrations of the products will increase and those of the reagents will decrease. In other words, to achieve balance, direct reaction is favored. Then the reaction will shift to the right, that is, reagents will be consumed and more products will be formed.In this case, we can then determine that a reaction will shift to the right if Q<K
A laboratory assistant needs to prepare 217 mL of 0.246 M solution. How many grams of calcium chloride will she need
Answer:
5.92 g
Explanation:
Convert milliliters to liters.
217 mL = 0.217 L
Since molarity (M) is moles per liter(mol/L), multiply the molarity by the volume to find out how many moles you will need.
0.217 L × 0.246 M = 0.05338 mol
Now, convert the moles to grams using the molar mass. The molar mass of calcium chloride is 110.98 g/mol.
0.05338 mol × 110.98 g/mol = 5.924 g ≈ 5.92 g
You will need 5.92 g of calcium chloride.
At standard temperature and pressure conditions, the volume of an ideal gas contained in a jar is 55.3 L. How many molecules are in the jar. This question is to be answered in scientific notation.(eg. 1.5 e5)
Answer:
1.49e24
Explanation:
Standars temperature and pressure are 273.15K and 1atm, respectively.
Using ideal gas law, we can find moles of an ideal gas if we know its pressure, temperature and volume as follows:
PV = nRT
PV / RT = n
Where P is pressure (1atm), V is volume (55.3L), R is gas constant (0.082atmL/molK), T is temperature (273.15K) and n moles of the ideal gas.
Replacing:
PV / RT = n
1atm*55.3L / 0.082atmL/molK*273.15K = n
2.47 moles = n
Now, the question is about the number of molecules in the jar. By definition, 1 mole = 6.022x10²³ molecules.
As we have 2.47 moles:
2.47 mol × (6.022x10²³ molecules / 1 mole) =
1.49x10²⁴ molecules that are in the jar
In scientific notation:
1.49e24Write a balanced chemical equation for the base hydrolysis of methyl butanoate with NaOH. (Use either molecular formulas or condensed structural formulas, but be consistent in your equation.)
Explanation:
C5H10O2 + NaOH = C2H5COONa + C2H5OH
your result are : sodium propanoate and ethanol
A balanced chemical equation represents atoms and their numbers with their charge. The balanced equation for base hydrolysis is C₅H₁₀O₂ + NaOH → C₂H₅COONa + C₂H₅OH.
What is hydrolysis?Base hydrolysis is the splitting of the ester linkage by the basic molecule. As the result the acidic ester portion makes the salt, and also alcohol is produced as the by-product.
The base hydrolysis of methyl butanoate is shown as,
C₅H₁₀O₂ + NaOH → C₂H₅COONa + C₂H₅OH
Here, sodium propanoate and ethanol are produced by the splitting of methyl butanoate in the presence of the base (NaOH).
Therefore, C₅H₁₀O₂ + NaOH → C₂H₅COONa + C₂H₅OH is balanced reaction.
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Atoms are indivisible spheres. 1.plum pudding model 2.Dalton model 3.Bohr model
Answer: 2. Dalton Model
Explanation:
John Dalton proposed that atoms are indivisible spheres. Although his model of an atom was not entirely new to the scientific world since the ancient Greeks has made a similar statement in the past ( all matter are made up of small indivisible particle called atom).
As of when Dalton proposed his model of an atom, electrons and nucleus where yet to be discovered.
Please help, Which type of molecule is shown below?
Answer:
Carbohydrate
Explanation:
A.pex
Which of the following happens to a molecule of an object when the object is heated? (1 point)
Answer:
They get more energy, so they vibrate!
Explanation:
A certain covalent compound is named sulfur hexafluoride. What's the chemical formula for this compound? A. F6S2 B. F6S C. S2F6 D. SF6
Answer: The sulphur hexafluoride will have a chemical formula of [tex]SF_6[/tex]
Explanation:
A covalent compound is a compound where the sharing of electrons takes place between two elements which are non-metals.
The naming of covalent compound is given by:
1. The less electronegative element is written first.
2. The more electronegative element is written second. Then a suffix is added with it. The suffix added is '-ide'.
3. If atoms of an element is greater than 1, then prefixes are added which are 'mono' for 1 atom, 'di' for 2 atoms, 'tri' for 3 atoms and so on.
Thus sulphur hexafluoride will have a chemical formula of [tex]SF_6[/tex]
Answer:
D. sf6
Explanation:
Consider the following reaction at 298K.
I2 (s) + Pb (s) = 2 I- (aq) + Pb2+ (aq)
Which of the following statements are correct?
Choose all that apply.
ΔGo > 0
The reaction is product-favored.
K < 1
Eocell > 0
n = 2 mol electrons
B-
Answer:
Eªcell > 0; n = 2
Explanation:
The reaction:
I2 (s) + Pb (s) → 2 I- (aq) + Pb2+ (aq)
Is product favored.
A reaction that is product favored has ΔG < 0 (Spontaneous)
K > 1 (Because concentration of products is >>>> concentration reactants).
Eªcell > 0 Because reaction is spontaneous.
And n = 2 electrons because Pb(s) is oxidizing to Pb2+ and I₂ is reducing to I⁻ (2 electrons). Statements that are true are:
Eªcell > 0; n = 2There are 2.4g of calcium hydroxide reacted with nitric acid. Calculate the number of moles of calcium hydroxide used. Write your answer using proper significant digits and units. Show all your work.
Answer:
0.032 moles
Explanation:
no of moles =
[tex] \frac{mass \: in \: grams}{relative \: molecular \: mass} [/tex]
=
[tex] \frac{2.4}{40 + 32 + 2} [/tex]
= 0.032
Calcium hydroxide reacted with nitric acid the total number of moles will be 0.032 moles.
What is a mole?
A mole is Avogadro's number of particles, which is exactly 6.02214076×1023.
The mole is widely used in chemistry as a convenient way to express amounts of reactants and products of chemical reactions. For example, the chemical equation 2H2 + O2 → 2H2O can be interpreted to mean that for each 2 mol dihydrogen (H2) and 1 mol dioxygen (O2) that react 2 mol of water (H2O) form.
Number of moles = Mass of substance / Mass of one mole Number of moles
mass of substance = 2.4g
molar mass of calcium hydroxide is (1 ×40.078g/mol Ca) +(2 × 15.999g/mol O) + (2 × 1.008g/mol H) = 74.092 g/mol Ca (OH)2
substituting the value,
number of moles = 2.4 / 74.029
= 0.032 moles
Therefore, moles of calcium hydroxide will be 0.032 moles
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3. Write the following isotope in hyphenated form (e.g., "carbon-14”): Kr
a. Krypton-109
b. Krypton -37
c. Krypton -36
d. Krypton -73
Answer:
Krypton -73
Explanation:
There are 33 known isotopes of krypton (36Kr) with atomic mass numbers from 69 through 101.
Good luck!
Answer:
D. Krypton-73
Explanation:
An isotope of an element has the same atomic number and the same number of protons but a different number of neutrons and a different atomic weight. Krypton is the 36th element on the periodic table. It has 36 protons and 48 neutrons. Krypton-73 is one of 33 known isotopes of Krypton and is the only one that actually exists from the list of choices.
Hope that helps.
Which one of the following compound does not undergo an aldol addition reaction in presence of aqueous sodium hydroxide?
a. butanal
b. 2-methylbutanal
c. 3-methylpentanal
d. 2, 2-dimethylbutanal
The compound does not undergo an aldol addition reaction in presence of aqueous sodium hydroxide is 2, 2-dimethylbutanal.
What is aldol reaction?The Aldol Reaction occurs when the enolate of an aldehyde or ketone combines with the carbonyl of another molecule at the aplha-carbon under basic or acidic circumstances to produce beta-hydroxy aldehyde or ketone.
For the formation of enolate ion, compound should contain alpha hydrogen in it and among the given compound only 2, 2-dimethylbutanal will not have alpha hydrogens.
Butanal, 2-methylbutanal and 3-methylpentanal will have aplha hydrogens in it so that it takes part in the aldol reaction.Hence 2, 2-dimethylbutanal does not undergo an aldol addition reaction.
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The heat of vaporization of water is 40.66 kJ/mol. How much heat is absorbed when 3.11 g of water boils at atmospheric pressure?
Answer:
The amount of heat that is absorbed when 3.11 g of water boils at atmospheric pressure is 7.026 kJ.
Explanation:
A molar heat of vaporization of 40.66 kJ / mol means that 40.66 kJ of heat needs to be supplied to boil 1 mol of water at its normal boiling point.
To know the amount of heat that is absorbed when 3.11 g of water boils at atmospheric pressure, the number of moles represented by 3.11 g of water is necessary. Being:
H: 1 g/moleO: 16 g/molethe molar mass of water is:
H₂O= 2* 1 g/mole + 16 g/mole= 18 g/mole
So: if 18 grams of water are contained in 1 mole, 3.11 grams of water in how many moles are present?
[tex]moles of water=\frac{3.11 grams*1 mole}{18 gramos}[/tex]
moles of water= 0.1728
Finally, the following rule of three can be applied: if to boil 1 mole of water at its boiling point it is necessary to supply 40.66 kJ of heat, to boil 0.1728 moles of water, how much heat is necessary to supply?
[tex]heat=\frac{0.1728 moles*40.66 kJ}{1 mole}[/tex]
heat= 7.026 kJ
The amount of heat that is absorbed when 3.11 g of water boils at atmospheric pressure is 7.026 kJ.
I need to name an ionic compound containing a transition metal cation and a halogen anion. Below are the rules I should follow to write the correct name for such compound, but one of the options is incorrect: identify and select it.
a. Identify the metal and write its name first
b. Use the periodic table to work out the charge (oxidation number) on the transition metal according to the group in the periodic table
c. From the charge of the anion work out the charge of cation as Roman number in parenthesis: specify this charge in the name as a Roman number in parenthesis.
d. Write the number of the anion after the name of the metal
Answer:
b. Use the periodic table to work out the charge (oxidation number) on the transition metal according to the group in the periodic table
Explanation:
The keyword in this problem us "transition metal". Transition metals are found between the group 2 and group 3 elements. They have the d sub shells and also exhibit variable oxidation numbers (valency).
Among the options, the incorrect option is option B.
This is because transition metals d not have a fixed oxidation number and they cannot be obtained by looking up the group in the periodic table.
The iconic compounds obtain a transition of metal caution and a halon anon. As per the rules the correct name of the compounds should be written as to identify the incorrect one.
Option B use the ability to check and to work out the charges (oxidation number) of the transition metal as per the group given in the table. The problem with the keyword is transition metal.Learn more about the ionic compound containing a transition metal.
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(a) Identify the name of the method used below for the separation.
(b) Give one more application of this method of separation.
(c) What is the name for the line at position B ?
(d) what conclusions can you draw about the colours present in sweets C and D ?
Answer:
(a) Chromatography
(b) DNA fingerprinting
(c) Origin
(d) Sweet C consists of more colours than sweet D.
ii. The speed of colours in sweet C are proportional to one another, while that of colours in D is not.
Explanation:
Chromatography is one of the physical method of separating mixtures. This process composed of the ability of the constituents in a mixture to separate by virtue of rate of movement through a medium, thus separates into constituents.
It can be used to determine the soluble constituents of a given mixture. And for purification purpose.
When 2 moles of NH3(g) react with N2O(g) to form N2(g) and H2O(g) according to the following equation, 880 kJ of energy are evolved. 2NH3(g) 3N2O(g)4N2(g) 3H2O(g) Is this reaction endothermic or exothermic
Answer:
Explanation:
This is a bit of a trick question.
Usually an exothermic reaction is written as
A + B - heat = C + D
The meaning of this equation is that when the bonds of the reactants break, heat has to be given away to the environment. On the left, exothermic means that heat has to be given.
The wording on this question means that heat is a product
A + B = C + D + heat.
In other words heat is given up to the environment. So this reaction is exothermic.
Please help, Which molecule is shown below
Answer:
Option B. 3–methylheptane.
Explanation:
To obtain the name of the compound given in the question above, we must
1. Determine the functional group of the compound.
2. Locate the longest continuous carbon chain. This gives the parent name of the compound.
3. Identify the substituent groups attached.
4. Locate the position of the substituent group attached by giving it the lowest possible count.
5. Combine the above to obtain the name.
Now let us name the compound given in the question above.
1. The compound is an alkane since it contains only single bond.
2. The longest continuous carbon chain is 7. Hence the parent name I the compound is heptane.
3. The substituent group attached is
—CH3 i.e methyl.
4. The substituent group attached is at carbon 3.
5. Therefore, the name of the compound is:
3–methylheptane.
What is the final volume V2 in milliliters when 0.551 L of a 50.0 % (m/v) solution is diluted to 23.5 % (m/v)?
Answer:
[tex]V_2=1.17L[/tex]
Explanation:
Hello,
In this case, for dilution processes, we must remember that the amount of solute remains the same, therefore, we can write:
[tex]V_1C_1=V_2C_2[/tex]
Whereas V accounts for volume and C for concentration that in this case is %(m/v). In such a way, the final volume V2 turns out:
[tex]V_2=\frac{V_1C_1}{C_2}= \frac{0.551L*50.0\%}{23.5\%}\\ \\V_2=1.17L[/tex]
Best regards.
In a reversible reaction, the endothermic reaction absorbs ____________ the exothermic reaction releases. A. less energy than B. None of these, endothermic reactions release energy C. the same amount of energy as D. more energy than
Answer: C. the same amount of energy as
Explanation:
A reversible reaction is a chemical reaction where the reactants form products that, in turn, react together to give the reactants back.
Reversible reactions will reach an equilibrium point where the concentrations of the reactants and products will no longer change.
[tex]A+B\rightleftharpoons C+D[/tex]
Thus if forward reaction is exothermic i.e. the heat is released , the backward reaction will be endothermic i.e. the heat is absorbed and in same amount.
The amount of energy released will be equal and opposite in sign to the energy absorbed in that reaction.
Answer:
C.) the same amount of energy as
Explanation:
I got it correct on founders edtell
Indicate the peptides that would result from cleavage by the indicated reagent: a. Gly-Lys-Leu-Ala-Cys-Arg-Ala-Phe by trypsin b. Glu-Ala-Phe-Gly-Ala-Tyr by chymotrypsin
Answer:
a. Gly-Lys + Leu-Ala-Cys-Arg + Ala-Phe
b. Glu-Ala-Phe + Gly-Ala-Tyr
Explanation:
In this case, we have to remember which peptidic bonds can break each protease:
-) Trypsin
It breaks selectively the peptidic bond in the carbonyl group of lysine or arginine.
-) Chymotrypsin
It breaks selectively the peptidic bond in the carbonyl group of phenylalanine, tryptophan, or tyrosine.
With this in mind in "peptide a", the peptidic bonds that would be broken are the ones in the "Lis" and "Arg" (See figure 1).
In "peptide b", the peptidic bond that would be broken is the one in the "Phe" (See figure 2). The second amino acid that can be broken is tyrosine, but this amino acid is placed in the C terminal spot, therefore will not be involved in the hydrolysis.
Calculate the enthalpy change (∆H) for the reaction- N2(g) + 3 F2(g) –––> 2 NF3(g) given the following bond enthalpies: N≡N 945 kJ/mol F–F 155 kJ/mol N–F 283 kJ/mol
Answer:
– 844 kJ/mol.
Explanation:
The following data were obtained from the question:
N2(g) + 3 F2(g) –––> 2 NF3(g)
Enthalpy of N≡N (N2) = 945 kJ/mol
Enthalpy of F–F (F2) = 155 kJ/mol
Enthalpy of N–F3 (NF3) = 283 kJ/mol
Enthalpy change (∆H) =?
Next, we shall determine the enthalpy of reactant.
This is illustrated below:
Enthalpy of reactant (Hr) = 945 + 3(155)
Enthalpy of reactant (Hr) = 945 + 465
Enthalpy of reactant (Hr) = 1410 kJ/mol
Next, we shall determine the enthalpy of the product.
This is illustrated below:
Enthalpy of product (Hp) = 2 x 283
Enthalpy of product (Hp) = 566 kJ/mol
Finally, we shall determine the enthalpy change (∆H) for the reaction as follow:
Enthalpy of reactant (Hr) = 1410 kJ/mol
Enthalpy of product (Hp) = 566 kJ/mol
Enthalpy change (∆H) =?
Enthalpy change (∆H) = Enthalpy of product (Hp) – Enthalpy of reactant (Hr)
Enthalpy change (∆H) = 566 – 1410
Enthalpy change (∆H) = – 844 kJ/mol
Answer:
– 844 kJ/mol.
Explanation:
The following data were obtained from the question:
N2(g) + 3 F2(g) –––> 2 NF3(g)
Enthalpy of N≡N (N2) = 945 kJ/mol
Enthalpy of F–F (F2) = 155 kJ/mol
Enthalpy of N–F3 (NF3) = 283 kJ/mol
Enthalpy change (∆H) =?
Next, we shall determine the enthalpy of reactant.
This is illustrated below:
Enthalpy of reactant (Hr) = 945 + 3(155)
Enthalpy of reactant (Hr) = 945 + 465
Enthalpy of reactant (Hr) = 1410 kJ/mol
Next, we shall determine the enthalpy of the product.
This is illustrated below:
Enthalpy of product (Hp) = 2 x 283
Enthalpy of product (Hp) = 566 kJ/mol
Finally, we shall determine the enthalpy change (∆H) for the reaction as follow:
Enthalpy of reactant (Hr) = 1410 kJ/mol
Enthalpy of product (Hp) = 566 kJ/mol
Enthalpy change (∆H) =?
Enthalpy change (∆H) = Enthalpy of product (Hp) – Enthalpy of reactant (Hr)
Enthalpy change (∆H) = 566 – 1410
Enthalpy change (∆H) = – 844 kJ/mol
Explanation:
How many moles of NaF must be dissolved in 1.00 liter of a saturated solution of PbF 2 at 25°C to reduce the [Pb 2+] to 1.0 × 10 –6 M? The K sp for PbF 2 at 25 °C is 4.0 × 10 –8.
Answer:
0.1957 moles of NaF
Explanation:
The Pb²⁺ and F⁻ are in equilibrium with PbF₂ as follows:
PbF₂(s) ⇄ Pb²⁺(aq) + 2F⁻(aq)
Where Ksp expression is:
Ksp = 4.0x10⁻⁸ = [Pb²⁺] [F⁻]²
A saturated solution contains the maximum possible amount of Pb²⁺ and F⁻. That is:
PbF₂(s) ⇄ Pb²⁺(aq) + 2F⁻(aq)
PbF₂(s) ⇄ X + 2X
Where X is amount of ions presents in solution
4.0x10⁻⁸ = [Pb²⁺] [F⁻]²
4.0x10⁻⁸ = [X] [2X]²
4.0x10⁻⁸ = 4X³
4.0x10⁻⁸/4 = X³
1.0x10⁻⁸ = X³
2.15x10⁻³M = X
That means initial concentration of Pb²⁺ is = X = 2.15x10⁻³M and [F⁻] = 2X = 4.30x10⁻³M
Now, using again Ksp, if you want a [Pb²⁺] = 1.0x10⁻⁶M, the [F⁻] you need is:
4.0x10⁻⁸ = [Pb²⁺] [F⁻]²
4.0x10⁻⁸ = [1.0x10⁻⁶M] [F⁻]²
0.04M = [F⁻]²
0.2M = [F⁻]
You need a final concentration of 0.2M of F⁻. As initial concentration was 4.30x10⁻³M and volume of the buffer is 1.00L, the moles of F⁻ = moles of NaF you must add are:
0.2M - 4.30x10⁻³M =
0.1957 moles of NaFThe change in entropy for the surroundings in a situation where heat flows from a hotter system to a cooler surrounding is: ________
a. Greater than zero
b. Less than zero
c. Equal to zero
d. Impossible to predict
Answer:
A
Explanation:
The change in entropy for the surroundings in a situation where heat flows from a hotter system to a cooler surrounding is Greater than Zero.
Here the randomness of the molecules increase as the temperature of the surrounding increases.( it absorbs heat from the system).
Answer:
Option a (Greater than zero) is the correct answer.
Explanation:
The entropy transition can sometimes be due to something like the reconfiguration of atom or molecule through one sequence to the next. In the substances, there would be a corresponding increase throughout entropy mostly during response unless the compounds are still very much abnormal compared with the reaction mixture.Some other three choices don't apply to either the situations in question. And the correct approach will be Options A.
