Answer:
c) will never be spontaneous at any pressure.
Explanation:
Hello,
In this case, we need to remember that the second law of thermodynamics states that heat flow is transferred from a hot object to a cold object only, never the other way around, therefore, the answer is c) will never be spontaneous at any pressure. This is supported by driving force that in this case is the temperature difference which must be negative for the hot object (it gets eventually cold) and positive for the cold object (it gets eventually hot) until they reach the equilibrium temperature.
Best regards.
2NH3 → N2 + 3H2 If 2.22 moles of ammonia (NH3) decomposes according to the reaction shown, how many moles of hydrogen (H2) are formed? A) 2.22 moles of H2 B) 1.11 moles of H2 C) 3.33 moles of H2 D) 6.66 moles of H2
Answer:
C
Explanation:
According to the mole ratio, using 2NH3 will give you 3H2. Which means in order to find the moles of H2 you would only need to divide 2 and multiply 3 to get the amount of moles of H2 produced.
Answer:
I think it's C
Explanation:
Please, tell me if I'm incorrect.
Which of the following substances (along with its corresponding salt) would be best suited for generating a buffer solution with a pH below 7?
a. CH3CO2H
b. C5H5N
c. HCl
d. None of the above
Answer:
d. None of the above
Explanation:
A buffer works when pH of the buffer is ± 1. Out of this range, the buffering capacity is very low.
Acetic acid, CH₃CO₂H, has a pKa of 4.74. That means its buffering capacity is between 3.74 and 5.74 of pH. Is not a good buffer to pH 7
Pyridine is a weak base with pKa of 5.52. Its buffering capacity is between 6.52 and 4.52. Is not a good buffer to pH 7
HCl is a strong acid. Just weak acids and bases can produce a buffer with its conjugate base. HCl can't produce a buffer.
Thus, right answer is:
d. None of the aboveAnswer:
CH3CO2H
Explanation:
A weak acid, such as acetic acid, paired with its conjugate base (here, the acetate ion) will be an ideal system for creating an acidic buffer solution with a pH below 7.
What's the mass in grams of 0.442 moles of calcium bromide, CaBr2? The atomic
weight of Ca is 40.1 and the atomic weight of Br is 79.9.
A) 452.3 g
B) 53.04 g
C) 44.2 g
D) 88.4 g
Answer:
Below
Explanation:
Let n be the quantity of matter in the Calcium Bromide
● n = m/ M
M is the atomic weight and m is the mass
M of CaBr2 is the sum of the atomic wieght of its components (2 Bromes atoms and 1 calcium atom)
M = 40.1 + 2×79.9
● 0.422 = m/ (40.1+2×79.9)
●0.422 = m/ 199.9
● m = 0.422 × 199.9
● m = 84.35 g wich is 88.4 g approximatively
88.4 g approximatively is the mass in grams of 0.442 moles of calcium bromide, CaBr2 ,therefore option (d) is correct.
What do you mean by mass ?Mass is the amount of matter that a body possesses. Mass is usually measured in grams (g) or kilograms (kg) .
To calculate mass in grams of 0.442 moles of calcium bromide, CaBr2,
Let n be the quantity of matter in the Calcium Bromide
M is the atomic weight and m is the mass
n = m/ MM of CaBr2 is the sum of the atomic weight of its components
Mass of Ca = 40.1 , Mass of Br = 79.9
M = 40.1 + 2×79.9
0.422 = m/ (40.1+2×79.9)
0.422 = m/ 199.9
m = 0.422 × 199.9
m = 84.35 g which is 88.4 g approximatively .
Thus ,88.4 g approximatively is the mass in grams of 0.442 moles of calcium bromide, CaBr2 , hence option (d) is correct .
Learn more about mass ,here:
https://brainly.com/question/6240825
#SPJ2
If the heat released during condensation goes only to warming the iron block, what is the final temperature (in ∘C) of the iron block? (Assume a constant enthalpy of vaporization for water of 44.0 kJ/mol and a heat capacity for iron of 0.449 J⋅g−1⋅∘C−1.)
Answer:
[tex]91°C[/tex]
Explanation:
CHECK THE COMPLETE QUESTION BELOW;
Suppose that 0.95 g of water condenses on a 75.0 g block of iron that is initially at 22 °c. if the heat released during condensation is used only to warm the iron block, what is the final temperature (in °c) of the iron block? (assume a constant enthalpy of vaporization for water of 44.0 kj/mol.)
Heat capacity which is the amount of heat required to raise the temperature of an object or a substance by one degree
From the question, it was said that that 0.95 g of water condenses on the block thenwe know that Heat evolved during condensation is equal to the heat absorbed by iron block.
Then number of moles =given mass/ molecular mass
Molecular mass of water= 18 g/mol
Given mass= 0.95 g
( 0.95 g/18 g/mol)
= 0.053 moles
Then Heat evolved during condensation = moles of water x Latent heat of vaporization
Q= heat absorbed or released
H=enthalpy of vaporization for water
n= number of moles
Q=nΔH
Q = 0.053 moles x 44.0 kJ/mol
= 2.322 Kj
=2322J
We can now calculate Heat gained by Iron block
Q = mCΔT
m = mass of substance
c = specific heat capacity
=change in temperature
m = 75 g
c = 0.450 J/g/°C
If we substitute into the above formula we have
Q= 75 x 0.450 x ΔT
2322 = 75 x 0.450 x ΔT
ΔT = 68.8°C
Since we know the difference in temperature, we can calculate the final temperature
ΔT = T2 - T1
T1= Initial temperature = 22°C
T2= final temperature
ΔT= change in temperature
T2 = T1+ ΔT
= 68.8 + 22
= 90.8 °C
=91°C
Therefore, final temperature is [tex]91°C[/tex]
The final temperature of the iron block is 91∘C.
Given that;
Heat lost during condensation of the water = Heat gained by iron block
Mass of water(mw) = 0.95 g
Latent heat of vaporization = Latent heat of condensation(L) = 44.0 kJ/mol
Mass of iron(mi) = 75.0 g
Initial temperature of iron(T1) = 22∘C
Final temperature of iron(T2) = ?
Heat capacity of iron(ci) = 0.449 J⋅g−1⋅∘C−1
So;
mwL = mici(T2 - T1)
Substituting values;
(0.95g/18g/mol) × 44.0 × 10^3(J/mol) = 75.0(g) × 0.449 J⋅g−1⋅∘C−1 (T2 - 22∘C)
2322.2 = 33.7T2 - 741.4
2322.2 + 741.4 = 37.4T2
T2 = (2322.2 + 741.4)/ 33.7
T2 =91∘C
Missing parts;
Suppose that 0.95 g of water condenses on a 75.0 g block of iron that is initially at 22 °c. if the heat released during condensation is used only to warm the iron block, what is the final temperature (in °c) of the iron block? (assume a constant enthalpy of vaporization for water of 44.0 kj/mol.)
Learn more: https://brainly.com/question/9352088
If for a particular process, ΔH=308 kJmol and ΔS=439 Jmol K, in what temperature range will the process be spontaneous?
Answer:
The process will be spontaneous above 702 K.
Explanation:
Step 1: Given data
Standard enthalpy of the reaction (ΔH°): 308 kJ/molStandard entropy of the reaction (ΔS°): 439 J/mol.KStep 2: Calculate the temperature range in which the process will be spontaneous
The reaction will be spontaneous when the standard Gibbs free energy (ΔG°) is negative. We can calculate ΔG° using the following expression.
ΔG° = ΔH° - T × ΔS°
When ΔG° < 0,
ΔH° - T × ΔS° < 0
ΔH° < T × ΔS°
T > ΔH°/ΔS°
T > (308,000 J/mol)/(439 J/mol.K)
T > 702 K
The process will be spontaneous above 702 K.
Q 13.3: Which of the following is the least stable radical choice? Tertiary radical. B : Allyl radical. C : Secondary radical. D : Methyl radical. E : Primary radical.
Answer:
Methyl radical
Explanation:
A radical is any specie that contains an odd number of electrons. We must note that the greater the number of alkyl groups which are attached to a carbon atom that bears the odd electrons, the more the degree of delocalization of the odd electrons and consequently the more stable we expect the free radical to be.
Hence the order of free radical stability is; Methyl < Primary < Secondary < Tertiary. Hence, we can easily see that the methyl radical is the least stable free radical.
Answer: Methyl radical
Explanation:
A microwave oven heats by radiating food with microwave radiation, which is absorbed by the food and converted to heat. If the radiation wavelength is 12.5 cm, how many photons of this radiation would be required to heat a container with 0.250 L of water from a temperature of 20.0oC to a temperature of 99oC
Answer:
The total photons required for this radiation = 5.1938 × 10²⁸ photons
Explanation:
Given that:
A microwave oven heats by radiating food with microwave radiation, which is absorbed by the food and converted to heat.
If the radiation wavelength is 12.5 cm,
density of water = 1g/cm³
volume of the container = 0.250 L = 250 cm³
density = mass/volume
mass of the water = density × volume
mass of the water = 1g/cm³ × 250 cm³
mass of the water = 250 g
specific heat capacity of water = 4.182 J/g°C
The change in temperature was from 20.0° C to 99° C
ΔT =( 99 -20.0)° C
ΔT = 79.0° C
The heat absorbed in the process is calculated by using the formula,
q = mcΔT
q = 250 g × 4.182 J/g°C × 79.0° C
q = 82594.5 Joules
Recall that the radiation wavelength λ = 12.5 cm = 0.125 m
The amount of energy of one photon of the radiation wavelength is determined by using the formula:
E = hv
since v = c/λ
E = hc/λ
where;
h = Planck's constant = 6.626 × 10⁻³⁴ J.s
c = velocity of light = 3.0 × 10⁸ m/s
∴
E = (6.626 × 10⁻³⁴ J.s × 3.0 × 10⁸ m/s)/ 0.125 m
E = 1.59024⁻²⁴ Joules
The total photons required for this radiation = total heat energy/energy of radiation
The total photons required for this radiation = 82594.5 Joules/1.59024⁻²⁴ Joules
The total photons required for this radiation = 5.1938 × 10²⁸ photons
what is the colour before and after when bromine reacts with chlorine ??
ANSWER
I need great answers
EXPLANATION
please rate my answer as great
A particular reaction at constant pressure is spontaneous at 390K. The enthalpy change for this reaction is +23.7kJ. What can you conclude about the sign and magnitude of ΔS for this reaction?a. smallb. largec. + smalld. + largee. 0.0
Answer:
+ small
Explanation:
The entropy is obtained from;
∆S= ∆H/T
Where;
∆S= entropy of the system
∆H= enthalpy if the system = +23.7 KJ
T= absolute temperature of the system = 390 K
∆S= 23.7 ×10^3/390 = 60.8 JK^-
There is a small positive change in entropy.
In a fixed cylinder are 3moles of oxygen gas at 300Kelvin and 1.25atm. What is the volume of the container?
Answer:
The volume of the container is 59.112 L
Explanation:
Given that,
Number of moles of Oxygen, n = 3
Temperature of the gas, T = 300 K
Pressure of the gas, P = 1.25 atm
We need to find the volume of the container. For a gas, we know that,
PV = nRT
V is volume
R is gas constant, R = 0.0821 atm-L/mol-K
So,
[tex]V=\dfrac{nRT}{P}\\\\V=\dfrac{3\ mol\times 0.0821\ L-atm/mol-K \times 300\ K}{1.25\ atm}\\\\V=59.112\ L[/tex]
So, the volume of the container is 59.112 L
A sample of pure lithium chloride contains 16% lithium by mass. What is the % lithium by mass in a sample of pure lithium carbonate that has twice the mass of the first sample
Answer:
Percentage lithium by mass in Lithium carbonate sample = 19.0%
Explanation:
Atomic mass of lithium = 7.0 g; atomic mass of Chlorine = 35.5 g; atomic mass of carbon = 12.0 g; atomic mass of oxygen = 16.0 g
Molar mass of lithium chloride, LiCl = 7 + 35.5 = 42.5 g
Percentage by mass of lithium in LiCl = (7/42.5) * 100% = 16.4 % aproximately 16%
Molar mass of lithium carbonate, Li₂CO₃ = 7 * 2 + 12 + 16 * 3 =74.0 g
Percentage by mass of lithium in Li₂CO₃ = (14/74) * 100% = 18.9 % approximately 19%
Mass of Lithium carbonate sample = 2 * 42.5 = 85.0 g
mass of lithium in 85.0 g Li₂CO₃ = 19% * 85.0 g = 16.15 g
Percentage by mass of lithium in 85.0 g Li₂CO₃ = (16.15/85.0) * 100 % = 19.0%
Percentage lithium by mass in Lithium carbonate sample = 19.0%
What is the concentration of MgSO4 in a solution prepared by dissolving 30g MgSO4 in 500ml distilled water. Express concentration in
(i)ppm
(ii) %w/v
(iii) %w/w
Assume the solution density is 1.15g/ml.
Answer:
Concentration of MgSO4 = 0.0521 × 10⁶ ppmConcentration of MgSO4 = 6% w/vConcentration of MgSO4 = 5.21% w/wExplanation:
Given:
Mass of solute = 30 gram
Volume of water = 500 ml
Density = 1.15g/ml
Find:
(i)ppm
(ii) %w/v
(iii) %w/w
Computation:
Water in gram = 500 ml × 1.15 g/ml
Water in gram = 575 gram
In ppm
Concentration of MgSO4 = [30 / 575] × 10⁶
Concentration of MgSO4 = 0.0521 × 10⁶ ppm
in % w/v
Concentration of MgSO4 = [30 / 500] × 100
Concentration of MgSO4 = 6% w/v
in % w/w
Concentration of MgSO4 = [30 / 575] × 100
Concentration of MgSO4 = 5.21% w/w
By December 31, 2003, concerns over arsenic contamination had prompted the manufacturers of pressure-treated lumber to voluntarily cease producing lumber treated with CCA (chromated copper arsenate) for residential use. CCA-treated lumber has a light greenish color and was widely used to build decks, sand boxes, and playground structures.
Required:
Draw the Lewis structure of the arsenate ion (ASO4^3-) that yields the most favorable formal charges.
Answer:
Explanation:
lewis structure can be defined as a process of how the valence shell electrons of a molecule is being arranged, the pattern of it arrangement and the relationship between the bonding atoms and the lone pairs present in the molecule.
In order to draw the Lewis structure for Arsenate ion [tex]\mathsf{AsO \ _4^{3-}}[/tex], first thing is to count the valence electrons in the molecule. Once we determine the valence electrons, then we distribute them around the central atom. The Arsenate ion structure is tetrahedral in nature with a bond angle of 109.5° and it is sp³ hybridized.
If I make a solution by adding 83 grams of sodium hydroxide to 750 mL of water. a. What is the molality of sodium hydroxide in this solution
Answer:
2.77 mol/kg
Explanation:
Molality is a sort of concentration that indicates the moles of solute in 1kg of solvent. In this case our solvent is water and, if we consider water's density as 1g/mL, we determine that the mass of solvent is 750 g.
We convert the mass to kg → 750 g . 1kg /1000g = 0.750 kg
Our solute is the NaOH → 83 g.
We convert the mass to moles → 83 g . 1mol /40g = 2.075 mol
Molality (mol/kg) = 2.075 mol / 0.75kg = 2.77 m
If sulfur gained another electron, would its charge be positive or negative?
Explain your thinking. *
Answer:
AS WE KNOW THAT , when non-metallic elements gain electrons to form anions, SO sulphur is non metal and have the capacity to gain two electrons as lies in 6th group so it can gain electron and become sulphide ion(S-).
Thanks for asking questionExplanation:
g If the titration of a 10.0-mL sample of sulfuric acid requires 28.15 mL of 0.100 M sodium hydroxide, what is the molarity of the acid
Answer:
[tex]M_{acid}=0.141M[/tex]
Explanation:
Hello,
In this case, the reaction between sulfuric acid and hydroxide is:
[tex]H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O[/tex]
We can notice a 1:2 molar ratio between the acid and the base respectively, therefore, at the equivalence point we have:
[tex]2*n_{acid}=n_{base}[/tex]
And in terms of volumes and concentrations:
[tex]2*M_{acid}V_{acid}=M_{base}V_{base}[/tex]
So we compute the molarity of sulfuric acid as shown below:
[tex]M_{acid}=\frac{M_{base}V_{base}}{2*V_{acid}} =\frac{0.100M*28.15mL}{2*10.0mL}\\ \\M_{acid}=0.141M[/tex]
Best regards.
For an ideal gas condition, what is the mass (g) of N2 if the pressure is 2.0 atm, the volume is 25 mL and the temperature is 290 Kelvin.
Answer:
THE MASS OF NITROGEN GAS IN THIS CONDITIONS IS 0.0589 g
Explanation:
In an ideal condition
PV = nRT or PV = MRT/ MM where:
M = mass = unknown
MM =molar mass = 28 g/mol
P = pressure = 2 atm
V = volume = 25 mL = 0.025 L
R = gas constant = 0.082 L atm/mol K
T = temperature = 290 K
n = number of moles
The gas in the question is nitrogen gas
Molar mass of nitrogen gas = 14 * 2 = 28 g/mol
Then equating the variables and solving for M, we have
M = PV MM/ RT
M = 2 * 0.025 * 28 / 0.082 * 290
M = 1.4 / 23.78
M = 0.0589 g
The mass of the nitrogen gas at ideal conditions of 2 atm, 25 mL volume and 290 K temperature is 0.0589 g
Chelsi has talked to her artist friends about how much money they earn each year from working in the arts. She gathers these values from seven people: [$1,500; $6,700; $2,200; $8,100; $50,500; $12,000; $2,200].
What is the median of this data set?
Answer:
The median would be 6700
Explanation:
Arrange data values from lowest to highest value
The median is the data value in the middle of the set
.
Ordering a data set x1 ≤ x2 ≤ x3 ≤ ... ≤ xn from lowest to highest value, the median x˜ is the data point separating the upper half of the data values from the lower half.
If the size of the data set n is odd the median is the value at position p where
Formula for the median
p=n+12
x˜=xp
If n is even the median is the average of the values at positions p and p + 1 where
p=n2
x˜=xp+xp+12
If there are 2 data values in the middle the median is the mean of those 2 values.
A 1.2 L weather balloon on the ground has a temperature of 25°C and is at atmospheric pressure (1.0 atm). When it rises to an elevation where the pressure is 0.73 atm, then the new volume is 1.8 L. What is the temperature (in °C) of the air at this elevation?
Answer:
The temperature of the air at this given elevation will be 53.32425°C
Explanation:
We can calculate the final temperature through the combined gas law. Therefore we will need to know 1 ) The initial volume, 2 ) The initial temperature, 3 ) Initial Pressure, 4 ) Final Volume, 5 ) Final Pressure.
Initial Volume = 1.2 L ; Initial Temperature = 25°C = 298.15 K ; Initial pressure = 1.0 atm ; Final Volume = 1.8 L ; Final pressure = 0.73 atm
We have all the information we need. Now let us substitute into the following formula, and solve for the final temperature ( T[tex]_2[/tex] ),
P[tex]_1[/tex]V[tex]_1[/tex] / T[tex]_1[/tex] = P[tex]_2[/tex]V[tex]_2[/tex] / T[tex]_2[/tex],
T[tex]_2[/tex] = P[tex]_2[/tex]V[tex]_2[/tex]T[tex]_1[/tex] / P[tex]_1[/tex]V[tex]_1[/tex],
T[tex]_2[/tex] = 0.73 atm [tex]*[/tex] 1.8 L [tex]*[/tex] 298.15 K / 1 atm [tex]*[/tex] 1.2 L = ( 0.73 [tex]*[/tex] 1.8 [tex]*[/tex] 298.15 / 1 [tex]*[/tex] 1.2 ) K = 326.47425 K,
T[tex]_2[/tex] = 326.47425 K = 53.32425 C
Automotive air bags inflate when sodium azide decomposes explosively to its constituent elements: 2NaN3 (s) → 2Na (s) + 3N2 (g) How many grams of sodium azide are required to produce 30.5 g of nitroge
Answer:
NaN3 = 47.2 g
Explanation:
Given:
2 NaN3 ⇒ 2 Na + 3 N2
Find:
Amount of NaN3
Computation:
N2 moles = Product of N2 / molar mass of N2
N2 moles =30.5/28
N2 moles = 1.0893
2NaN3 makes 3(N2 )
So,
NaN3 moles = (2/3) moles of N2
NaN3 moles = ( 2/3) × 1.0893
NaN3 moles = = 0.7262
NaN3 mass = 0.7262 x 65
NaN3 = 47.2 g
Answer:
NaN3 = 47.2 g
Explanation:
Given:
2 NaN3 ⇒ 2 Na + 3 N2
Find:
Amount of NaN3
Computation:
N2 moles = Product of N2 / molar mass of N2
N2 moles =30.5/28
N2 moles = 1.0893
2NaN3 makes 3(N2 )
So,
NaN3 moles = (2/3) moles of N2
NaN3 moles = ( 2/3) × 1.0893
NaN3 moles = = 0.7262
NaN3 mass = 0.7262 x 65
NaN3 = 47.2 g
Explanation:
clacium hydroxide is slightly soluable in water about 1 gram will dissolve in 1 liter what are the spectator ions in the reaction ions in the reaction of such a dilute solution of calcium hydroxide with hydrochloric acid
Answer:
Ca²⁺ and Cl⁻
Explanation:
In a chemical reaction, spectator ions are ions that are not involved in the reaction, that means are the same before and after the reaction.
In water, calcium hydroxide, Ca(OH)₂ is dissociated in Ca²⁺ and OH⁻. Also, hydrochloric acid, HCl, dissociates in H⁺ and Cl⁻. The reaction is:
Ca²⁺ + 2OH⁻ + 2H⁺ + 2Cl⁻ → 2H₂O + Ca²⁺ + 2Cl⁻
The ions that react are H⁺ and OH⁻ (Acid and base producing water)
And the ions that are not reacting, spectator ions, are:
Ca²⁺ and Cl⁻A chemist prepares a solution of sodium chloride by measuring out 25.4 grams of sodium chloride into a 100. mL volumetric flask and filling the flask to the mark with water. Calculate the concentration in mol/L of the chemist's sodium chloride solution. Be sure your answer has the correct number of significant digits.
Answer:
The concentration in mol/L = 4.342 mol/L
Explanation:
Given that :
mass of sodium chloride = 25.4 grams
Volume of the volumetric flask = 100 mL
We all know that the molar mass of sodium chloride NaCl = 58.5 g/mol
and number of moles = mass/molar mass
The number of moles of sodium chloride = 25.4 g/58.5 g/mol
The number of moles of sodium chloride = 0.434188 mol
The concentration in mol/L = number of mol/ volume of the solution
The concentration in mol/L = 0.434188 mol/ 100 × 10⁻³ L
The concentration in mol/L = 4.34188 mol/L
The concentration in mol/L = 4.342 mol/L
A 50.0 L cylinder of oxygen gas is stored at 150. atm. What volume would the oxygen gas occupy if the cylinder were opened into a hot air balloon (completely deflated) until the final pressure is 735 torr
Answer:
THE VOLUME OF THE OXYGEN GAS AFTER DEFLATION TILL A PRESSURE OF 735 TORR IS ATTAINED IS 7836.99 L
Explanation:
Using Boyle's law,
P1V1 = P2V2
P1 = 150 atm
V1 = 50 L
P2 = 735 Torr
V2 = unknown
We must first convert the pressures into the same SI unit for easy calculation
1torr = 1/760 atm
So converting 735 torr to atm; we have:
1 torr = 1/ 760 atm
735 torr = 735 * 1 / 760 atm
= 0.967 atm
In other words, P2 = 0.957 atm
So rearranging the formula by making V2 the subject of the equation, we have:
V2 = P1 V1 / P2
V2 = 150 * 50 / 0.957
V2 = 7836.99 L
The volume of the oxygen cylinder after deflation to a final pressure of 735 torr or 0.967 atm pressure is 7836.99 L.
Im really confused and select all that apply questions scare me.
Answer:
The 3rd one
Explanation:
The standard free energy change for a reaction can be calculated using the equation ΔG∘′=−nFΔE∘′ ΔG∘′=−nFΔE∘′ where nn is the number of electrons transferred, FF is Faraday's constant, 96.5 kJ·mol−1·V−1, and ΔE∘′ΔE∘′ is the difference in reduction potential. For each of the given reactions, determine the number of electrons transferred (n)(n) and calculate standard free energy (ΔG∘′)(ΔG∘′) . Consider the half-reactions and overall reaction for reaction 1. half-reactions:fumarate 2−+2H+CoQH2↽−−⇀succinate−↽−−⇀CoQ+2H+ half-reactions:fumarate−+2H+↽−−⇀succinate2−CoQH2↽−−⇀CoQ+2H+ overall reaction:fumarate2−+CoQH2↽−−⇀succinate2−+CoQΔE∘′=−0.009 V
Answer:
ΔG°′ = 1.737 KJ/mol
Explanation:
The reaction involves the transfer of two electrons in the form of hydride ions from reduced coenzyme Q, CoQH₂ to fumarae to form succinate and oxidized coenzyme Q, CoQ.
The overall equation of reaction is as follows:
fumarate²⁻ + CoQH₂ ↽⇀ succinate²⁻ + CoQ ; ΔE∘′=−0.009 V
Using the equation for standard free energy change; ΔG°′ = −nFΔE°′
where n = 2; F = 96.5 KJ.V⁻¹.mol⁻¹; ΔE°′ = 0.009 V
ΔG°′ = - 2 * 96.5 KJ.V⁻¹.mol⁻¹ * 0.009 V
ΔG°′ = 1.737 KJ/mol
What is the concentration in ppm of 4 g of NaCl dissolved in 100 mL of water?
A chemist fills a reaction vessel with 0.978 g aluminum hydroxide AlOH3 solid, 0.607 M aluminum Al+3 aqueous solution, and 0.396 M hydroxide OH− aqueous solution at a temperature of 25.0°C.
Under these conditions, calculate the reaction free energy ΔG for the following chemical reaction:
Al(OH)3(s) = A1+ (aq) +30H (aq)
Use the thermodynamic information in the ALEKS Data tab. Round your answer to the nearest kilojoule.
KJ
Answer: [tex]\Delta G^{0}[/tex] = 168.12 kJ
Explanation: Gibbs Free Energy, at any time, is defined as the enthalpy of the system minus product of temperature and entropy of the reaction, i.e.:
[tex]\Delta G^{0} = \Delta H^{0} - T.\Delta S^{0}[/tex]
Enthalpy is defined as internal heat existent in the system. It is calculated as:
[tex]\Delta H^{0} = \Sigma H^{0}_{product} - \Sigma H^{0}_{reagent}[/tex]
Using Enthalpy Formation Table:
[tex]\Delta H^{0} = [3*(-299.9)+(-524.7)] - (-1277)[/tex]
[tex]\Delta H^{0} = 62,6 kJ[/tex]
Entropy is the degree of disorder in the system. It is found by:
[tex]\Delta S^{0} = \Sigma S^{0}_{products} - \Sigma S^{0}_{reagents}[/tex]
Calculating:
[tex]\Delta S^{0} = (-321.7) + 3(-10.8) - 0[/tex]
[tex]\Delta S^{0} = -354.1J[/tex]
And so, Gibbs Free energy will be:
[tex]\Delta G^{0} = \Delta H^{0} - T.\Delta S^{0}[/tex]
[tex]\Delta G^{0} = 62600 - [298.(-354.1)][/tex]
[tex]\Delta G^{0} = 168121.8 J[/tex]
Rounding to the nearest kJ:
[tex]\Delta G^{0}[/tex] = 168.12 kJ
A flask contains 6g hydrogen gas and 64 g oxygen at rtp the partial pressure of hydrogen gas in the flask of the total pressure (p)will be
A.2/3p
B.3/5p
C.2/5p
D.1/3p
Answer this with reason
Answer:
B.3/5p
Explanation:
For this question, we have to remember "Dalton's Law of Partial Pressures". This law says that the pressure of the mixture would be equal to the sum of the partial pressure of each gas.
Additionally, we have a proportional relationship between moles and pressure. In other words, more moles indicate more pressure and vice-versa.
[tex]P_i=P_t_o_t_a_l*X_i[/tex]
Where:
[tex]P_i[/tex]=Partial pressure
[tex]P_t_o_t_a_l[/tex]=Total pressure
[tex]X_i[/tex]=mole fraction
With this in mind, we can work with the moles of each compound if we want to analyze the pressure. With the molar mass of each compound we can calculate the moles:
moles of hydrogen gas
The molar mass of hydrogen gas ([tex]H_2[/tex]) is 2 g/mol, so:
[tex]6g~H_2\frac{1~mol~H_2}{2~g~H_2}=~3~mol~H_2[/tex]
moles of oxygen gas
The molar mass of oxygen gas ([tex]O_2[/tex]) is 32 g/mol, so:
[tex]64g~H_2\frac{1~mol~H_2}{32~g~H_2}=~2~mol~O_2[/tex]
Now, total moles are:
Total moles = 2 + 3 = 5
With this value, we can write the partial pressure expression for each gas:
[tex]P_H_2=\frac{3}{5}*P_t_o_t_a_l[/tex]
[tex]P_O_2=\frac{2}{5}*P_t_o_t_a_l[/tex]
So, the answer would be 3/5P.
I hope it helps!
For a sample of stomach acid that is 2.02×10−2 M in HCl, how many moles of HCl are in 14.6 mL of the stomach acid?
Answer:
0.0002949 moles
Explanation:
Concentration = 2.02×10−2 M
Volume = 14.6 mL = 0.0146 L (Upon converting to litres)
Number of moles = ?
These variables are related by the fllowing equation;
Concentration = Number of moles / Volume
Number of moles = Concentration * Volume
Number of moles = 2.02×10−2 * 0.0146 = 0.0002949 moles
Please Help! Use Hess’s Law to determine the ΔHrxn for: Ca (s) + ½ O2 (g) → CaO (s) Given: Ca (s) + 2 H+ (aq) → Ca2+ (aq) + H2 (g) ΔH = 1925.9 kJ/mol 2 H2 (g) + O2 (g) → 2 H2O (l) ΔH = −571.68 kJ/mole CaO (s) + 2 H+ (aq) → Ca2+ (aq) + H2O (l) ΔH = 2275.2 kJ/mole ΔHrxn =
Answer:
ΔHrxn = -635.14kJ/mol
Explanation:
We can make algebraic operations of reactions until obtain the desire reaction and, ΔH of the reaction must be operated in the same way to obtain the ΔH of the desire reaction (Hess's law). Using the reactions:
(1)Ca(s) + 2 H+(aq) → Ca2+(aq) + H2(g) ΔH = 1925.9 kJ/mol
(2) 2H2(g) + O2 g) → 2 H2O(l) ΔH = −571.68 kJ/mole
(3) CaO(s) + 2 H+(aq) → Ca2+(aq) + H2O(l) ΔH = 2275.2 kJ/mole
Reaction (1) - (3) produce:
Ca(s) + H2O(l) → H2(g) + CaO(s)
ΔH = 1925.9kJ/mol - 2275.2kJ/mol = -349.3kJ/mol
Now this reaction + 1/2(2):
Ca(s) + ½ O2(g) → CaO(s)
ΔH = -349.3kJ/mol + 1/2 (-571.68kJ/mol)
ΔHrxn = -635.14kJ/mol