The substitution reaction of toluene with Br2 can, in principle, lead to the formation of three isomeric bromotoluene products. In practice, however, only o- and p-bromotoluene are formed in substantial amounts. The meta isomer is not formed. Draw the structures of the three possible carbocation intermediates, and explain why ortho and para products predominate over meta products.

Answers

Answer 1

Answer:

See explanation and image attached

Explanation:

Aromatic hydrocarbons undergo electrophillic substitution. Usually, substituted benzene is more or less reactive to electrophillic substitution compared to unsubstituted benzene.

Substituents on the benzene ring tend to direct the incoming electrophile during electrophillic substititution. The presence of the -CH3 group on toluene directs the incoming Br electrophile to the ortho/para position.

Where the incoming electrphile E is Bromine, we can see that in the ortho/ para product, the electron pushing -CH3 stabilizes the resonance structure formed and increases electron density at the ortho/para position via resonance compared to the meta product as we can see from the image attached. Hence, the ortho and para products predominate over meta products.

Image credit: Chemistry steps

The Substitution Reaction Of Toluene With Br2 Can, In Principle, Lead To The Formation Of Three Isomeric

Related Questions

tom pays 5 cents per minute to use his cell phone. Write an expression for the cost in cents of using his cell phone for minutes.

Answers

Answer:5m

Explanation:Because in the question it say per minute so it would be 5 times m

4. A sample of ammonia, NH3, contains 3.3 x 1021 hydrogen atoms. How many NH; molecules are in this sample?​

Answers

Answer:

1.1 × 10²¹ NH₃ molecules

Explanation:

From the given information:

We were being told that the number of the hydrogen (H) atoms present in the sample of NH3 = 3.3 × 10²¹ hydrogen.

However, it signifies that each molecule of ammonia harbors 3hydrogen (H) atoms.

Hence,  the number of  molecules of NH₃ present;

[tex]\mathsf{=\dfrac{3.3\times 10^{21}}{3} \ molecules \ of \ {NH_3}}[/tex]

= 1.1 × 10²¹ NH₃ molecules

How many oxygen atoms are there in 0.25 mole of CO2?

Answers

Answer:

It is known that 1 mol of a molecule contains 6.023×1023 6.023 × 10 23 number of molecules. So, 0.25 moles of CO2 C O 2.

The correct option for the given question about Mole Concept is Na / 2 atom of oxygen.

What is mole?In chemistry, a mole is a unit. A mole of a substance is the mass of the substance containing precisely 12 gram of the same number of atoms as 12C.The mole is the SI unit used to measure a substance's quantity. It has the symbol mol.

How to solve this question?

In 1 mole number of molecules of CO₂ = Na (Avagadro Number)

In 0.25 mole number of molecules of CO₂ = 0.25 × Na molecules

In 1 molecule number of oxygen atom = 2 atom

In 0.25 × Na molecules number of oxygen atom = 2 × 0.25 × Na atom

In 0.25 × Na molecules number of oxygen atom = 0.5 × Na atom

So in 0.25 mole of CO₂ number of oxygen atom = Na / 2 atom

Thus we can conclude that in 0.25 mole of CO₂ number of oxygen atom will be Na / 2, where Na is Avagadro Number.

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According to the ideal gas law, a 9.998 mol sample of argon gas in a 0.8311 L container at 502.7 K should exert a pressure of 496.2
atm. What is the percent difference between the pressure calculated using the van der Waals' equation and the ideal pressure? For Ar
gas, a = 1.345 L’atm/mol? and b = 3.219x10-2 L/mol.
Pideal – Puan der Waals |
Percent difference
x 100

Answers

Answer:

[tex]\%diff=24.0\%[/tex]

Explanation:

Hello there!

In this case, according to the given information, it turns out firstly necessary for us to set up the van der Waals' equation as shown below:

[tex]p=\frac{RT}{v-b}-\frac{a}{v^2}[/tex]

Thus, we secondly calculate the molar volume as:

[tex]v=\frac{0.8311L}{9.998mol} =0.083L/mol[/tex]

Then, we plug in the entire variables in the vdW equation to get such pressure:

[tex]p=\frac{0.08206\frac{atm*L}{mol*K}*502.7K}{0.08313L/mol-0.03219L/mol}-\frac{1.345L*atm/mol}{(0.08313L/mol)^2}\\\\p=615.2atm[/tex]

And the ideal gas pressure:

[tex]p=\frac{0.08206\frac{atm*L}{mol*K}*502.7K}{0.08313L/mol}\\\\p=496.2atm[/tex]

Finally, the percent difference:

[tex]\%diff=\frac{|496.2atm-615.2atm|}{496.2atm} *100\%\\\\\%diff=24.0\%[/tex]

Regards!

At 445oC, Kc for the following reaction is 0.020. 2 HI(g) <--> H2 (g) + I2 (g) A mixture of H2, I2, and HI in a vessel at 445oC has the following concentrations: [HI] = 1.5 M, [H2] = 2.50 M and [I2] = 0.05 M. Which one of the following statements concerning the reaction quotient, Qc, is TRUE for the above system?
a. Qc = Kc; the system is at equilibrium.
b. Qc is less than Kc; more H2 and I2 will be produced.
c. Qc is less than Kc; more HI will be produced.
d. Qc is greater than Kc; more HI will be produced.

Answers

Explanation:

The given balanced chemical equation is:

[tex]2 HI(g) <--> H_2 (g) + I_2 (g)[/tex]

The value of Kc at 445oC is 0.020.

[HI]=1.5M

[H2]=2.50M

[I2]=0.05M

The value of Qc(reaction quotient ) is calculated as shown below:

Qc has the same expression as the equilibrium constant.

[tex]Qc=\frac{[H_2][I_2]}{[HI]^2} \\Qc=(2.50Mx0.05M)/(1.5M)^2\\Qc=0.055[/tex]

Qc>Kc,

Hence, the backward reaction is favored and the formation of Hi is favored.

Among the given options, the correct answer is option d. Qc is greater than Kc; more HI will be produced.

For which of the following reactions is the enthalpy change equal to the second ionization energy of nitrogen?

Answers

Answer:

"[tex]N^+(g) \rightarrow N^{2+}(g) + e^-[/tex]" is the appropriate answer.

Explanation:

Whenever one electron or particle must be removed from some kind of gas atom or molecule, it requires that the very first amount of energy necessary.Two electrons must be removed from such a mono-positive exhaust gases structure or position of ion before they may become a dipositive gaseous ion.

Thus the above is the correct answer.

The shape of a molecule is determined by:
A. All of these
B. The number of electron clouds around the atom.
C. The number of bonds.
D. Mutual repulsion between electrons.

Answers

By the electron pairs around the central atom. So it’s A

tính chất hóa học của propylen

Answers

Answer:

Propilen là một chất khí không màu với mùi giống như dầu mỏ. Propilen nhẹ hơn nước và tan rất ít trong nước 0.61 g/ . Không hòa tan trong các dung môi phân cực như nước, chỉ tan trong dung môi không phân cực hay ít phân cực.. Propilen không có tính dẫn điện.

Which are the following exothermic or endothermic

Absorbs Energy

-Hrxn

+Hrxn

Feels Hot

Heat flows from surrounds to Reaction

Not Energetically Favorable

Energetically Favorable

Releases Energy

Feels Cold

Heat flows from the reaction to the surrounds

Answers

Answer:

Explanation:

Your mom

Match each land resource to its use.
clay - used to make steel
iron ore - used to make batteries
salt - used to make pottery and tiles
aggregate - used in construction
graphite - used as a flavoring in food
i will give 10 points and brainliest!!!

Answers

Answer:

Explanation:

We are to match each land resource to what they are being used for.

Clay             →→→  used to make pottery and tiles

iron ore       →→→  used to make steel

Salt              →→→   used as a flavoring in food

aggregate   →→→   used in construction

graphite       →→→ used to make batteries

Clay is a kind of soil particle that forms as a result of weathering processes. Examples include; pottery clays, glacial clays, and deep-sea clays e.t.c. The presence of one or more clay minerals, as well as variable quantities of organic and detrital components, characterizes all of them. Clay is usually sticky and moist when wet, but hard when dry. They are used in the making of tiles and potteries.

Iron ore:  The iron ore deposits are found in the Earth's crust's sedimentary rocks. They're made up of iron and oxygen that mix during the chemical process in marine and freshwater. iron ores are used to produce almost every iron and steel product that we use today.

Aggregate: are utilized in construction activities. It is a material used to mix cement, gypsum, bitumen, or lime to produce concrete in the construction industry.

Graphite: Graphite is a mineral that occurs in both igneous and metamorphic rocks. It is generally generated on the earth's surface when carbon is exposed to high temperatures and pressures. It is mainly used in the production of batteries and electrodes,

1. Explain the test for unsaturation.
2. Write down the balanced chemical equations for the complete and incomplete
combustion of octene
3. Explain how propanol, an alcohol, is formed from propene..
4. How is margarine formed?

Answers

Answer:

1)In organic chemistry, the bromine test is a qualitative test for the presence of unsaturation (carbon-to-carbon double or triple bonds), phenols and anilines. ... The more unsaturated an unknown is, the more bromine it reacts with, and the less coloured the solution will appear.

2)The equation for incomplete combustion of propane is: 2 C3H8 + 9 O2 → 4 CO2 + 2 CO + 8 H2O + Heat. If not enough oxygen is present for complete combustion, incomplete combustion occurs. The result of incomplete combustion is, once again, water vapour, carbon dioxide and heat. But it also produces carbon monoxide.

Explanation:

3)Propene, also known as propylene, is an unsaturated organic compound with the chemical formula {\displaystyle {\ce {CH3CH=CH2}}}. It has one double bond, and is the second simplest member of the alkene class of hydrocarbons. It is a colorless gas with a faint petroleum-like odor. 

Formula: C3H6

IUPAC ID: Propene

4)Margarines are chemically created during hydrogenation which, until January 1, 2006, relied upon trans fats to solidify their vegetable oils. Food companies have been exploring options for replacing trans fat in partially hydrogenated margarine.

What is the mass of carbon in 69.00 mg of co2

Answers

Answer:

18.82 mg

Explanation:

From the given information:

The molar mass of CO2  is calculated as follow

= (12 + (16 ×2))

= 44

The mass of carbon is determined by dividing the mass no of carbon from co2 by the molar mass of CO2,  followed by multiplying it by 69.00 mg

= [tex](\dfrac{12}{44}\times 69 )[/tex]

=(0.2727 × 69 )

= 18.82 mg

Oxygen and hydrogen are compressed into two cubical boxes of the same
size at a temperature of 28 K. What do these gases have in common
according to the kinetic theory?

Answers

Explanation:

Following are the kinetic theory of gases postulates:

1) Space-volume to molecules ratio is negligible.

2)There is no force of attraction between the molecules at normal temperature and pressure. The force of attraction between the molecules build when the temperature decreases and the pressure increases.

3) There is large space between the molecules resulting in continuous motion.

4) The free movement of molecules results in collision which is perfectly elastic.

5) The molecules have kinetic energy due to random movement. But the average kinetic energy of these molecules differs with temperature.

6) Molecules exert pressure on the walls of the container.

Enough of a monoprotic weak acid is dissolved in water to produce a 0.0118 M solution. The pH of the resulting solution is 2.32 . Calculate the Ka for the acid.

Answers

Answer:

1.94 × 10⁻³

Explanation:

Step 1: Calculate the concentration of H⁺ ions

We will use the definition of pH.

pH = -log [H⁺]

[H⁺] = antilog -pH = antilog -2.32 = 4.79 × 10⁻³ M

Step 2: Calculate the acid dissociation constant (Ka) of the acid

For a monoprotic weak acid, whose concentration (Ca) is 0.0118 M, we can use the following expression.

Ka = [H⁺]²/Ca

Ka = (4.79 × 10⁻³)²/0.0118 = 1.94 × 10⁻³

Why does nitrogen not show allotropy?​

Answers

Answer:

Nitrogen does not show allotropy because of its small size and high electronegativity. The single N-N bond is weaker than P-P bond because of high inter electronic repulsions among non-bonding electrons due to the small bond distance. Hence it does not show allotropy.

Answer:

The nitrogen atom has short inter-bond distance, hence highly electronegative in terms of magnitude. This creates no relation in energy varieties hence no allotropes formed.

Nitrogen atom is also very small.

Isotopes are: A. are only theoretical. B. only formed in laboratories. C. found in nature. D. found in the nuclear reactions in stars but not on Earth.

Answers

Answer:

B. only formed in laboratories

Explanation:

i know

Isotopes are only formed in Laboratories. hence, Option (B) is correct.

What are Isotopes ?

Each of two or more forms of the same element that contain equal numbers of protons but different numbers of neutrons in their nuclei, and hence differ in relative atomic mass but not in chemical properties; in particular, a radioactive form of an element is known as Isotope.

Isotopes are two or more types of atoms that have the same atomic number and position in the periodic table, and that differ in nucleon numbers due to different numbers of neutrons in their nuclei.

Therefore, Isotopes are only formed in Laboratories. hence, Option (B) is correct.

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Consider the constitutional isomers 2-methylbut-1-ene, 2-methylbut-2-ene, and 3-methylbut-1-ene. When each of these alkenes is subjected to catalytic hydrogenation (H2, Pt), a single product results. Which of the following best describes the structural relationship among these products?

a. the product are cis-trans isomers.
b. the product are identical.
c. the product are constitutional isomers.
d. the product are enantiomers.
e. the product are diastereomers.

Answers

Answer:

Explanation:

I am almost sure that the products are identical.

Write the complete ground-state electron configuration of I⁻.

Answers

Explanation:

here's the answer to your question

Iodine's neutral atom has the following electronic configuration: 1 s² 2 s² 2 p⁶ 3 s² 3 p⁶ 4 s² 3 d¹⁰ 4 p⁶ 5 s² 4 d¹⁰ 5 p⁵. The complete ground-state electron configuration of I⁻ is  [Kr]5s² 4d¹⁰ 5p⁶.

What is electronic configuration?

Electronic configuration is defined as each electron moves individually within an orbital while being surrounded by an average field produced by all other orbitals. The electron configuration is used to describe an atom's ground state orbitals, but it may also be used to depict an atom that has ionized into a cation or anion by making up for any lost or gained electrons in the orbitals after it.

The ground state electronic configuration is defined as the configuration of lower energy electrons surrounding an atom's nucleus. Ground state is defined as the least energetic state feasible for a physical system.  It is important because permits us to determine the location of the excited electrons' departure and return when they release a photon.

Thus, iodine's neutral atom has the following electronic configuration: 1 s² 2 s² 2 p⁶ 3 s² 3 p⁶ 4 s² 3 d¹⁰ 4 p⁶ 5 s² 4 d¹⁰ 5 p⁵. The complete ground-state electron configuration of I⁻ is  [Kr]5s² 4d¹⁰ 5p⁶.

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PLEASE HELP! A machine uses filtration to separate a component from orange juice. Which component does the machine most likely separate from the mixture?

A - Pigment
B - Sugar
C - Pulp
D - Water

Answers

Answer: c

Explanation:   Filtration is technically defined as the process of separating suspended solid matter from a liquid

Pulp is a lignocellulosic fibrous material prepared by chemically or mechanically separating cellulose fibers from wood, fiber crops .

Many commercial juices are filtered to remove fiber or pulp.

The correct answer is C, Pulp.

Orange is an example of a citrus fruit. Every citrus fruit has a pulp. The of pulp a citrus fruit is that stringy content in the endocarp of the fruit .

The pulp of a citrus fruit is where its juice is found.

When you want to prepare orange juice, you need to remove the pulp of the citrus fruit. This is done by filtering out the pulp from the juice.

Filtration is the process of removing larger particles. For a liquid juice, filtration is the process of removing solid particles from the orange juice.

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Which option is a physical property of matter?

A. acidity

B. reactivity

C. boiling point

D. flammability

Answers

Answer:

boiling point is the physial property of matter

The option that is showing the physical property of the matter is boiling point, the correct option is C.

What is physical property?

A physical property is any measurable property whose value describes the state of a physical system.

Changes in a system's physical properties can be used to describe its transitions between momentary states. Physical properties are also known as observables. They do not have modal properties.

Physical properties include color, phase, odor, and boiling point. Since reactivity with oxygen is dependent on the chemical nature of the object, it is not a physical property.

A compound's physical property is one that can be observed and measured. The chemical composition of a compound is unaffected by a physical property.

Thus, the correct option is C.

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A(n) _____, used as part of the stationary phase, has an affinity for the solvent and the chemical components of the mixture. adsorbent eluent Rf factor chromatogram

Answers

The Adsorbent is used as part of the stationary phase and has an affinity for the solvent and the chemical components of the mixture.

The adsorbent has a high affinity for solvent and the chemical components of the mixture.

Chromatography is a method of separation in which the mixture of substances is introduced into a mobile phase (solvent). The separation occurs as the solvent interacts with an adsorbent(stationary phase).

The extent of separation of the components of the mixture depends on the extent of interaction between the mobile and the stationary phase . This interaction also determines the retention factor (Rf) of the separation.

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Using the molarity of vinegar, calculate the mass percent of acetic acid in the original sample. Assume the density of vinegar is 1.00 g/mL. (The formula for acetic acid is C2H4O2).

Answers

Answer:

5.37% w/w is the mass percent of vinegar assuming a molarity of 0.8935mol/L

Explanation:

Assuming the molarity of vinegar is 0.8935mol/L:

Mass percent is defined as 100 times the ratio between mass of solute (In this case, acetic acid), and the mass of the solution

To solve this question we need to find the mass of acetic acid from the moles using the molar mass and the mass of the solution from the volume in liters using the density:

Mass Acetic acid -Molar mass: 60.052g/mol-

0.8935mol * (60.052g / mol) = 53.656g Acetic Acid

Mass Solution:

1L = 1000mL * (1.00g/mL) = 1000g Solution

Mass Percent:

53.656g Acetic Acid / 1000g Solution * 100 =

5.37% w/w is the mass percent of vinegar assuming a molarity of 0.8935mol/L

The mass percent of acetic acid in the original sample of vinegar of molarity 0.8935mol/L is 5.37% w/w.

How do we calculate the mass percent?

Mass percent of any solute present in any solution will be calculated as the:

Mass % of solute = (mass of solute / mass of solution) × 100

Let the molarity of vinegar = 0.8935mol/L

Means 0.8935 moles of vinegar present in the 1 liter of the solution.

Now we calculate mass from moles as:

n = W/M, where

W = required mass

M = molar mass = 60.052g /mol

W = (0.8935mol)(60.052g/mol) = 53.656g

Mass of solution = 1L = 1000mL×(1.00g/mL) = 1000g Solution

Then the mass % of acetic acid:

Mass % = (53.656g / 1000g) × 100 = 5.37% w/w

Hence the required % mass is 5.37% w/w.

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Net ionic reaction of H2SO4 with Ba(OH)2

Answers

Answer:

This is an acid-base reaction (neutralization): Ba(OH) 2 is a base, H 2SO 4 is an acid. This is a precipitation reaction: BaSO 4 is the formed precipitate.

How many of shapes has the same number as the red oval.

Answers

The number of shapes that has the same number as the red oval is; 5

All the shapes has the same number as the red oval exempt the shape at the bottom right, this is because the text in the bottom right shape has one 8  missing at the end before 622.

Hence the number of shapes that has the same number as the red oval is 5

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What do we need to know to understand the formation of a chemical bond?​

Answers

Answer:

A chemical bond is a lasting attraction between atoms, ions or molecules that enables the formation of chemical compounds. The bond may result from the electrostatic force of attraction between oppositely charged ions as in ionic bonds or through the sharing of electrons as in covalent bonds.

Explanation:

You have to put energy into a molecule to break its chemical bonds. The amount needed is called the bond energy. After all, molecules don't spontaneously break

công thức của định lý pytago

Answers

The sum of the squares of two sides of a right angle is equal to the square of the hypotenuse

HELP ASAS 15 POINTS

When using the process of evaporation to separate a mixture, what is left behind in the evaporating dish?

A. None of these.
B. The liquid evaporates and the solid is left in the dish.
C. The mixture does not separate, and the entire mixture evaporates.
D. The mixture does not separate, and the entire mixture remains in the dish.

Answers

Answer:

liquid will be evaporated while solid remains

If the Ksp of NaCl is experimentally determined to be 43.9, then what is the concentration of Na (in M) when it begins to crystallize out of solution

Answers

Answer:

6.63 M

Explanation:

NaCl(s) ---> Na^+(aq) + Cl^-(aq)

Given that [Na^+] = [Cl^-] = s

Where s= concentration of the both ions

Ksp = s^2

s= √Ksp

s= √43.9

s= 6.63 M

The concentration of Na (in M) obtained when it begins to crystallize out of solution is 6.63 M

What is solubility of product?

The solubility of product (Ksp) is defined as the concentration of products raised to their coefficient coefficients. This is illustrated below:

mX <=> nY + eZ

Ksp = [Y]^n × [Z]^e

Dissociation equation

NaCl(aq) → Na⁺(aq) + Cl¯(aq)

Let the concentration of Na⁺ be yLet the concentration of Cl¯ be y

How to determine the concentration of Na⁺ Solubility of product (Ksp) = 43.9Concentration of Cl¯ = yConcentration of Na⁺ = y =?

Ksp = [Na⁺] × [Cl¯]

43.9 =  y × y

43.9 = y²

Take the square root of both side

y = √43.9

y = 6.63 M

Thus, the concentration of Na⁺ is 6.63 M

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I NEED A ANSWER FOR THIS QUESTION, ASAP​

Answers

It’s not showing up

Which shampoo would be displayed third?

Answers

Answer:

Biolage is the answer

Explanation:

Because it's price is third most

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