There are two stereoisomers of 1-tert-butyl-4-chloro-cyclohexane. One of these isomers reacts with sodium ethoxide in an E2 reaction that is 500 times faster than the reaction of the other isomer. Identify the isomer that reacts faster, and explain the difference in rate for these two isomers.

Answers

Answer 1

Answer:

Explanation:

Answer:

cis-isomer reacts faster

Explanation:

The missing diagrams in the question are attached in the first image below and the isomers that react faster are shown in the second image attached.

The cis-isomer quickly follows E2 reaction due to the fact that it is locked in a chair conformation whereby chlorine dominates an axial position, as displayed in drawing C as well as the leaving group Cl which is antiperiplanar to a beta proton.

Due to the bulkiness of tert-butyl, the trans-isomer is Basically trapped in a chair configuration, with chlorine occupying an equatorial position as displayed in drawing A below, thus leaving the group isn't antiperiplanar to a beta proton.

Tert butyl favors an equatorial position due to its bulkiness. This makes the Cl to assume an axial position in an isomer

The difference:

From the second image attached below, in the first diagram(1):

Suppose H is antiperiplanar, C-H bond electrons reach antibonding orbitals of C-Cl, assisting in the breakdown of the C-Cl bond and therefore speeding up the process.

From the second diagram(2) in the second image:

Unless Cl is in the axial position would it have β-hydrogen in the antiperiplanar position. Because tert-butyl prefers equatorial location, the Cl occupies equatorial position in the trans isomer.

As a result, the reaction is slower and there is no β-hydrogen antiperiplanar to Cl.

There Are Two Stereoisomers Of 1-tert-butyl-4-chloro-cyclohexane. One Of These Isomers Reacts With Sodium
There Are Two Stereoisomers Of 1-tert-butyl-4-chloro-cyclohexane. One Of These Isomers Reacts With Sodium

Related Questions

What is its density in kilograms per cubic meter?

Answers

Copper has a density of 8950 kg/m3 = 8.95 kg/dm3 = 8.95 g/cm3. Water has a density of 1000 kg/m3 = 1000 g/L = 1 kg/dm3 = 1 kg/L = 1 g/cm3 = 1 g/mL.

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Question 6 of 10
What is the relationship between temperature and kinetic energy?
O A. When all molecular motion stops, the temperature stops changing.
OB. As molecules move more quickly, the temperature increases.
C. As molecules slow down, the temperature starts to increase.
D. When all molecular motion stops, the temperature starts to
decrease

Answers

The answer is B. Molecules move more quickly as temperature increases.

When Allmond molecular motion stops, that is considered absolute zero. That does not mean that it cannot get colder, disapproving A.

C is just wrong.

D says when molecular motion stops the temperature STARTS to decrease, it was decreasing before it got there.

Draw the structure of the neutral organic product formed in the reaction. Do not draw counterions or byproducts.

Answers

Answer: Hello the reaction related to your question is missing attached below is the reaction

answer : attached below

Explanation:

The structure of the neutral organic product formed in the reaction is attached below.

The neutral organic product formed is ESTER

The reaction in the question is Anhydride on reaction with alcohol

Gizmo Warm-up Just like students sharing markers, atoms sometimes share or swap electrons. By doing this, atoms form bonds. The Ionic Bonds Gizmo allows you to explore how ionic bonds form. To begin, check that Sodium (Na) and Chlorine (Cl) are selected from the menus at right. Click Play ( ) to see electrons orbiting the nucleus of each atom. (Note: These atom models are simplified and not meant to be realistic.) 1. Each atom consists of a central nucleus and several shells that contain electrons. The outermost electrons are called valence electrons. How many valence electrons does each atom have

Answers

Answer: Sodium element has 1 valence electron and chlorine element has 7 valence electrons.

Explanation:

Valence electrons are defined as the electrons that are present in the outermost shell.

An ionic compound is formed when the complete transfer of electrons takes place from one element (usually metals) to another element (usually non-metals).

To know this, we need to write the electronic configuration of each element.

Sodium is the 11th element of the periodic table and has an electronic configuration of [tex]1s^22s^22p^63s^1[/tex]

It has 1 valence electron

Chlorine is the 17th element of the periodic table and has an electronic configuration of [tex]1s^22s^22p^63s^23p^5[/tex]

It has 7 valence electrons

Hence, sodium element has 1 valence electron and chlorine element has 7 valence electrons.

A community has a nearby forest that has some insect-damaged trees that are dying. They decide to cut the dying trees and sell the wood for
firewood.
How does science knowledge support this solution?
A. Cutting down the trees allows more animals to live in the forest.
B. Using the trees for firewood eliminates pollution caused by heating homes.
C. Selling the diseased trees as firewood allows the community to make money.
D. Removing the diseased trees allows the remaining trees to get more water and sunlight.

Answers

The answer is D (because I did the process of elimination)

A is incorrect because cutting down trees is mostly bad for the environment and give animals less homes

B is my incorrect because nothing in the question points out pollution made by nearby homes

C is incorrect because money doesn’t have anything to do with the environmental crisis in this particular situation

A can contains 375mL of soda. Using the appropriate number of significant figures, how much soda is left in the can after 308mL is poured into a glass

Answers

Answer:

[tex]V_l=67mL[/tex]

Explanation:

From the question we are told that:

Initial Volume [tex]V_1=375mL[/tex]

Final Volume [tex]V_2=308mL[/tex]

Generally the equation for Left-Over is mathematically given by

 [tex]V_l=V_1-V_2[/tex]

 [tex]V_l=375-308[/tex]

 [tex]V_l=67mL[/tex]

Fill in the blank to complete the statement

Answers

Answer:

I dont get it what words are we using bc I see words on the side just it doesn't make any sense

The concentration of a solute in a solution is greater than the maximum concentration that is predicted from the solute's solubility

Answers

This solution is called a supersaturated solution.

Lee y analiza a detalle el Anexo #1 de este plan de trabajo el cual habla sobre las fuentes alternativas de energía. Posteriormente con la información elabora un cartel o un cuadro sinóptico en tu cuaderno donde organices la información para darla a conocer a los miembros de tu comunidad.

Answers

Answer: el texto no es tan claro

pasagot plizzz kung sino makasagot ng tamang sagot ibebrainliest ko​

Answers

Answer:

1. B

2.B

3.B

4.C

5.C

Explanation:

I hope this help you

Identify the alkene obtained on dehydration of each of the following alcohols:

a. 3-Ethyl-3-pentanol
b. 1-Propanol
c. 2-Propanol
d. 2,3,3-Trimethyl-2-butanol

Answers

Answer:

Explanation:

The information below explains how dehydration of alcohol occurs to produce alkene.

Under the influence of a catalyst, alcohol dehydrates to produce an alkene and water. To produce alkene and water, the reaction eliminates the OH group from alcohol containing the carbon atom and the hydrogen atom from a neighboring carbon atom via the same molecule.

The –OH group in alcohol contribute two(2) electrons to H+ out from the acid reagent, resulting in the formation of an alkyloxonium ion. This ion serves as an excellent leaving group, allowing a carbocation to form. The nucleophile which acts as the deprotonated acid subsequently attacks and creates a double bond with the hydrogen next to the carbocation.

Guys I don't know science, if you are intelligent tell me what is science ​

Answers

Explanation:

Science is the pursuit and application of knowledge and understanding of the natural and social world following a systematic methodology based on evidence

Wat are representative elements

Answers

In chemistry and atomic physics, the main group is the group of elements whose lightest members are represented by helium, lithium, beryllium, boron, carbon, nitrogen, oxygen, and fluorine as arranged in the periodic table of the elements

Answer:

the representative elements are elements where the the s and p orbitals are filling. The transition elements are elements where the d orbitals (groups 3-11 on the periodic table) are filling, and the inner transition metals are the elements where the f orbitals are filling.

Explanation:

=)

When optically active (R)-2-methylcyclohexanone is treated with either aqueous base or acid, racemization occurs. Explain.

Answers

Answer:

See explanation

Explanation:

Racemization is said to occur when a 1:1 ratio of (+) and (-) enantiomers of a compound are produced in a reaction.

The reaction of optically active (R)-2-methylcyclohexanone with either aqueous base or acid leads to the formation of a planar enol species for reaction with acid and a planar enolate species for reaction with base.

Both reactions involves the formation of achiral species which reverts back to the chiral product with equal chances of the formation of both enantiomers of the product during the process. This leads to racemization of the product in both cases.

Racemization of the optically active (R)-2-methylcyclohexanone results from the production and subsequent interconversion of intermediates during the reaction with an aqueous base or acid. This is due to the inversion of stereochemistry at the chiral centre.

Racemization can happen when an optically active molecule is exposed to an aqueous base or acid because the compound's enantiomers are interconverted. The carbon-carbon bond next to the carbonyl group in (R)-2-methylcyclohexanone breaks as a result of the chemical reaction with the aqueous base or acid. The creation of the negatively charged intermediate known as the enolate ion occurs when a base, such as hydroxide ions, is present and attacking the carbonyl carbon. The carbonyl group can then be reformated by this enolate ion after it has undergone a nucleophilic attack on a proton.

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What is the molar solubility of MgF2 in a 0.36 M Mg(NO3)2 solution? For MgF2, Ksp = 8.4 × 10^–8

Answers

Answer:

2.4 × 10⁻⁴ M

Explanation:

Step 1: Calculate the concentration of Mg²⁺ coming from Mg(NO₃)₂

Mg(NO₃)₂ is a strong electrolyte and the molar ratio of Mg(NO₃)₂ to Mg²⁺ is 1:1. The initial molar concentration of Mg²⁺ is 1/1 × 0.36 M = 0.36 M.

Step 2: Make an ICE chart for the solution of MgF₂

        MgF₂(s) ⇄ Mg²⁺(aq) + 2 F⁻(aq)

I                           0.36             0

C                           +S             +2S

E                         0.36+S         2S

The solubility product constant is:

Ksp = [Mg²⁺] × [F⁻]² = (0.36+S) × (2S)²

Since S <<< 0.36, 0.36+S ≈ 0.36.

Ksp = 0.36 × 4S² = 8.4 × 10⁻⁸

S = 2.4 × 10⁻⁴ M

Which of the following mixtures is best separated by the use of a separating funnel?
methane and water
ethyl ethanoate and water
ethanol and water
ethanoic acid and water

Answers

Answer:

ethyl ethanoate and water

Explanation:

At the point when one fluid doesn't blend in with another yet glides on top of it, an isolating pipe can be utilized to isolate the two fluids. Oil glides on water. This combination can be isolated utilizing an isolating channel as demonstrated on the following page.  

Ethyl liquor and water are two miscible fluids.   Refining is a cycle that can be utilized to isolate an unadulterated fluid from a combination of fluids. An isolating channel can be utilized to isolate the parts of the combination of immiscible fluids.

The answer is ethyl ethanoate and water. Hope this helps you!

What law allows calories to be determined by heat (energy) transfer from one substance to another, but it is never destroyed?

Answers

Answer:

matter i think

Explanation:

matter i am pretty sure

The law that allows calories to be determined by heat (energy) transfer from one substance to another, but it is never destroyed is first law of thermodynamics.

What is first law of thermodynamics?

Energy cannot be generated or destroyed, only changed in form, according to the basic law of thermodynamics.

Energy transfer occurs when mass crosses the control boundary, external work is performed, or heat is transferred across the boundary in any system. These cause the stored energy in the control volume to shift.

Hence first law of thermodynamics justify the given statement.

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Look at this picture.
Which process in the water cycle is shown in the picture?
evaporation
transpiration
condensation
precipitation

Answers

Answer:

condensation

Explanation:

the water has condensed from the gaseous form into rain drops

Answer:

precipitation

Explanation:

Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy
AS.
Note: if you have not been given enough information to decide a sign, select the "unknown" option.

Answers

Answer:

Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option observations conclusions reaction ΔΗ is (pick one) The reverse of this reaction is always spontaneous. A As is (pick one) This reaction is spontaneous except below ΔΗ is (pick one) 38. °C but proceeds at a faster rate above (pick one) 91. °C As is ΔΗ iS (pick one) Crystallization of a pure compound is C spontaneous only below 146. °C. AS is (pick one) X

The molecule β-carotene has λ 450 nm, and ɛ = 15,000 m2 mol-1. Calculate the absorption (A) expected for a solution in which 0.1 mg has been dissolved in 10 ml of water (given: the molecular weight of β-carotene, C40H56, as 536) with a path length of 1 cm. Group of answer choices

Answers

Answer: The absorbance for a solution is 0.0028

Explanation:

To calculate the absorption of a solution, the equation by Beer-Lambert law is used:

[tex]A=\varepsilon \times b\times C[/tex]

OR

[tex]A=\varepsilon \times b\times \frac{\text{Given mass of solute}\times 1000}{\text{Molar mass of solute}\times \text{Volume of solution (mL)}}[/tex]

where,

A = absorbance = ?

[tex]\varepsilon[/tex] = molar absorptivity = [/tex]15000m^2mol^{-1}L[/tex]

b = path length = 1 cm = 0.01 m                 (Conversion factor: 1 m = 100 cm)

Given mass of [tex]\beta-[/tex] carotene = 0.1 mg = 0.0001 g     (Conversion factor: 1 g = 1000 mg)

Molar mass of [tex]\beta-[/tex] carotene = 536 g/mol

Volume of solution = 10 mL

Putting values in equation 1:

[tex]A=15000\times 0.01\times \frac{0.0001\times 1000}{536\times 10}\\\\A=0.0028[/tex]

Hence, the absorbance for a solution is 0.0028

For each system listed in the first column of the table below, decide (if possible) whether the change described in the second column will increase in GPS of the system, decrease S, or leave S unchanged. If you don’t have enough information to decide, check the “not enough information“ button in the last column. Note for advanced students: you may assume ideal gas and ideal solution behavior.

Answers

Answer:

For each system listed in first column of the table below, decide (if possible) whether the change described in the second column will increase the entropy S of the system, decrease S , or leave S unchanged. If you don?t have enough information to decide, check the not enough information button in the last column

which has maximum number of molecules among 7 gram of nitrogen, 16 gram of NO2 16 gram of oxygen and 2 gram of hydrogen​

Answers

Answer:

2 g of H₂

Explanation:

We have:

7 g of N₂

16 g of NO₂

16 g of O₂

2 g of H₂

Let's count to verify the moles:

7 g . 1 mol / 28g = 0.25 moles of nitrogen

16 g . 1 mol / 46g = 0.348 moles of nitrogen dioxide

16 g . 1mol /32g = 0.5 moles

2 g . 1 mol / 2g = 1 mol

The biggest number of moles is in the hydrogen.

1 mol of anything contains NA particles

1 mol of oxygen contains 6.02×10²³ molecules, the maximun number

la. A man was traveling by sie is allowed a maximum of 20kg luggage. The man
weighing 3.5kg, 15kg.2kg and 15kg
Find the excess weight of his luggage.
Express the excess weight as a percentage of the maximum weight allowed

Answers

Answer: The excess weight of the luggage is 15.5 kg and its percentage is 77.5%

Explanation:

Given values:

Maximum amount of luggage allowed = 20 kg

Amount of luggage man is carrying = [3.5 + 15 + 2 + 15] kg = 35.5 kg

Excessive weight of the luggage carried = Amount of luggage carrying - Maximum amount of luggage allowed

Excessive weight of the luggage carried = [35.5 - 20] = 15.5 kg

To calculate the percentage of excess weight, we use the equation:

[tex]\% \text{excess weight}=\frac{\text{Excess weight carried}}{\text{Maximum allowed}}\times 100[/tex]

Putting values in above equation, we get:

[tex]\% \text{excess weight}=\frac{15.5kg}{20kg}\times 100\\\\\% \text{excess weight}=77.5%[/tex]

Hence, the excess weight of the luggage is 15.5 kg and its percentage is 77.5%

A 1 liter solution contains 0.402 M hypochlorous acid and 0.302 M potassium hypochlorite. Addition of 0.332 moles of hydrochloric acid will:

Answers

Answer:

Lower the pH by several units.

Exceed the buffer capacity.

Explanation:

The options are:

*Raise the pH slightly

*Lower the pH slightly

*Raise the pH by several units

*Lower the pH by several units

*Not change the pH

*Exceed the buffer capacity

The hydrochloric acid reacts with potassium hypochlorite to produce hypochlorous acid. The amount of HCl added is the HClO produced and the KClO consumed. As the moles of HCl > moles KClO, all the KClO is consumed exceeding the buffer capacity and lowering the pH by several units.

what is most likely to happen during a precipitation reaction

Answers

A substance will react with oxygen to form water and carbon. ... dioxide.

Answer:

it will rain and there the other defined for precipitation snow and sleet and hail

What is the role of a decomposer in a food chain?
A. to move food from producers to consumers
B. to move food from consumers to other consumers
C. to make food for the ecosystem
D. to return matter to the environment

Answers

Answer:D

Explanation:

Decomposers decompose food and return it to the environment through the soil

I believe the correct answer is D

HELP ME PLZ AND THANKS I WILL MARK YOU AS BRAINLIEST!!!

Answers

Answer:

Final pressure = 6 atm

Final volume = 1.1 L

Final temperature = 100 K

Explanation:

We are given;

Initial Pressure; P1 = 2 atm

Initial volume; V1 = 3.3 L

Initial temperature; T1 = 27° C + 273 = 300 K

Final pressure; P2 = 6 atm

We will use Boyles law to get the final volume.

P1V1 = P2V2

V2 = (P1 × V1)/P2

P2 = (2 × 3.3)/6

V2 = 1.1 L

We can use Charles law to find the final temperature.

V1/T1 = V2/T2

T2 = (V2 × T1)/V1

T2 = (1.1 × 300)/3.3

T2 = 100 K

What is the price coke difference between a strong and weak acid?

Answers

Explanation:

Strong acids are those that are completely ionized in body fluids, and weak acids are those that are incompletely ionized in body fluids. Hydrochloric acid (HCl) is considered a strong acid because it is present only in a completely ionized form in the body, whereas carbonic acid (H2 CO3) is a weak acid because it is ionized incompletely, and, at equilibrium, all three reactants are present in body fluids. See the reactions below.

H2 CO3 (acid)↔H+ + HCO3- (base)

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Determine the number of moles of C in each sample
2.0 mol CH4, 0.175 mol C2H6,
4.21 mol C4H10, 24.5 mol C8 H18

Answers

Explanation:

In [tex]CH_4[/tex]:

Given moles = 2.0 moles

1 mole of methane contains 1 mole of carbon and 4 moles of hydrogen

Moles of carbon in [tex]CH_4=(2.0\times 1)=2.0 moles[/tex]

In [tex]C_2H_6[/tex]:

Given moles = 0.175 moles

1 mole of ethane contains 2 moles of carbon and 6 moles of hydrogen

Moles of carbon in [tex]C_2H_6=(0.175\times 2)=0.35 moles[/tex]

In [tex]C_4H_{10}[/tex]:

Given moles = 4.21 moles

1 mole of butane contains 4 moles of carbon and 10 moles of hydrogen

Moles of carbon in [tex]C_4H_{10}=(4.21\times 4)=16.84 moles[/tex]

In [tex]C_8H_{18}[/tex]:

Given moles = 24.5 moles

1 mole of octane contains 8 moles of carbon and 18 moles of hydrogen

Moles of carbon in [tex]C_8H_{18}=(24.5\times 8)=196 moles[/tex]

Write the structural formula for a primary, a secondary, and a tertiary constitutionally isomeric alcohol of the molecular formula C5H12O.

Answers

Answer:

The structures of all isomeric alcohols of molecular formula C5H12O along with their IUPAC names are as shown.

Their classification of primary, secondary, and tertiary alcohols are -

1-pentanol -

2-pentanol -

3-pentanol

2-methylbutan-1-ol

2-methylbutan-2-ol

3-methylbutan-2-ol

3-methylbutan-1-ol

2,2-dimethylpropanol

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Among U.S. high school students, what is TRUE about intimate partner violence (IPV)?a.Teenage IPV looks very different from adult IPV.b.IPV affects about one tenth of the population.c.IPV occurs more in rural areas than in urban areas.d.IPV is not a significant problem. reverend parris did not want to expose the fact that the girls lied because___A.nobody would believe it and chaos or further mass hysteria would result B.he would be seen as a liar, tooC.it would make the church officials look like liarsD.his daughter would be seen as a liar, too, and his reputation be ruined Which characteristic distinguishes dwarf planets from planets?orbits the Sunis roundis not a moonhas not cleared its orbit of objects A number y divided by 3 is at least - 19. 1.Siguraduhing _______ang mga datos o impormasyong2.Isaalang- alang ang partikular na _______ o lokasyon ng pinagmulan ng impormasyon3.Upang matiyak na hindi ______ang mga impormasyon, maaaring magsaliksik at kilalaning mabuti ang awtor at ang kanyang mga artikulo A.Gold and silverB.guns and ammunitionC.chocolate and tobaccoD.copper and pearls Find the surface area of each solid figure security awareness training that should be encouraged Cary earned $56 for 7 hours of babysitting. How much would Cary earn for 55 hours of babysitting? Someone who is ________________ has a combination of what we think of as "male" and "female" reproductive systems or a combination of DNA other than XX or XY. Read the compound sentence.Which is the correct way to punctuate the sentence?Dr. Burke wanted to trust her assistant with the secretformula but she was afraid her assistant was a spy:Dr. Burke wanted to trust her assistant with the secretformula; but she was afraid her assistant was a spy. aDr. Burke wanted to trust her assistant, with thesecret formula: but she was afraid her assistant was aSpy.Dr. Burke wanted to trust her assistant with the secretformula but she was afraid her assistant was a spy. a1D Dr. Burke wanted to trust her assistant with the secretformula, but she was afraid hel assistant was a spy. What were some disadvantages of the Roman Paved roads ? What is the slope of the line that is perpendicular to the line that passes through (-3, 6) and (6, 8)? Which of the following is a between the lines question?a.Who wrote this poem?c.Why write about a house?b.What is this poem about?d.When was this poem written?Please select the best answer from the choices providedABCD what makes the pottery of mata ortiz a traditional art form? On Wednesday, a local hamburger shop sold a combined total of 294 hamburgers and cheeseburgers. The number of cheeseburgers sold was two times the number of hamburgers sold. How many hamburgers were sold on Wednesday? Where does the comma go Which is the graph of f(x) = (x + 3)(x - 2)?Ty248o- 4 24HELP IM BEING TIMED A physics class has students. Of these, students are physics majors and students are female. Of the physics majors, are female. Find the probability that a randomly selected student is female or a physics major. which of the following is equivalent to the product below? thank you for helping!