What is the first step in the curved arrow mechanism for the chlorination of benzene in the presence of FeCl3

Answers

Answer 1

Answer:

See explanation

Explanation:

The chlorination of benzene occurs in the presence of a Lewis acid. A Lewis acid is a compound that can accept a lone pair of electrons.

The first step in the chlorination of benzene is the formation of the ion Cl^+ which attacks the benzene ring.

This ion is formed when the Cl2 molecule undergoes heterolytic fission assisted by FeCl3 to yield FeCl4^- and Cl^+.

The Cl^+ electrophile now attacks the benzene ring to yield chlorobenzene.


Related Questions

Ammonium phosphate is an important ingredient in many solid fertilizers. It can be made by reacting aqueous phosphoric acid with liquid ammonia. Calculate the moles of phosphoric acid needed to produce 1.80 mol of ammonium phosphate. Be sure your answer has a unit symbol, if necessary, and round it to the correct number of significant digits.

Answers

Answer:

Explanation:

The reaction is

H3Po4+3NH3\to→ (NH4)3PO4

Given,7.10g NH3=7.10g/molar mass of NH3

=7.10g/(17.031g/mol)

=0.416mol

From the reaction

3 mol ammonia reacted and produced 1 mole of ammoniam phosphate

So,One mole ammonia reacted and produced 1/ 3 mole ammonium phosphate.

And Also,0.416 mole ammonium reacted and produced (1/3)0.416=0.138 mole ammonium phosphate.

Hence 0.138mole=0.138mole*149.08 g/mole

               =20.573gm ammonium phosphate produced.

Hence 20.573g of ammonium phosphate is produced by the reaction of 7.10 g of ammonia.

Suppose, in an experiment to determine the amount of sodium hypochlorite in bleach, you titrated a 23.92 mL sample of 0.0100 M K I O 3 with a solution of N a 2 S 2 O 3 of unknown concentration. The endpoint was observed to occur at 13.80 mL . How many moles of K I O 3 were titrated

Answers

Answer:

2.39x10⁻⁴ moles

Explanation:

As the problem asks us the number of moles of KIO₃ that were titrated, all that is required of us is to calculate how many moles of KIO₃ are there in 23.92 mL of a 0.0100 M solution (All moles in the samples are titrated).

We can do so by using the definition of molarity:

Molarity = moles / liters

converting 23.92 mL ⇒ 23.92 / 1000 = 0.02392 L

moles = 0.0100 M * 0.02392 Lmoles = 2.39x10⁻⁴ moles

The volume of a single tantalum atom is 1.20×10-23 cm3. What is the volume of a tantalum atom in microliters?

Answers

Answer:

1.20x10⁻²⁰μL

Explanation:

1cm³ is equal to 1milliliter. As we must know, 1milliliter = 1000 microliters, 1000μL. To convert the 1.20x10⁻²³mL we need to use the conversion factor: 1mL = 1000μL.

The volume of tantalum in μL is:

1.20x10⁻²³mL * (1000μL /1L) = 1.20x10⁻²⁰μL

Determine the molarity of the sodium ions when 78.0 g Na2S is dissolved in water for a final volume of 1.0 L.

Answers

Answer:

[Na⁺] = 1.99 M

Explanation:

Na₂S is a ionic salt that can be dissociated.

Dissociation equation is:

Na₂S  →  2Na⁺  +  S⁻²

1 mol of sodium sulfide can give 2 moles of sodium cation.

We convert moles of salt: 78 g . 1mol / 78.06 g = 0.999 moles

As ratio is 1:2, after dissociation we have (0.999 . 2) = 1.998 moles of Na⁺

Molarity is a type of concentration.

It indicates moles of solute in 1 L of solution and in this case, we have 1 L as final voulme.

Moles of Na⁺ are 1.998 moles. Then molarity (mol/L) is:

M =1.99 mol/L  

Increasing the temperature of a chemical reaction usually increases greatly the rate of the reaction. The most iportant reason for this is that increasing the temperature increases: _______.
A) the collision frequency
B) the probability factor
C) the fraction of collisions with energy greater than Bact
D) the energy of activation.
E) the amount of heat released in the reaction

Answers

Answer:

the fraction of collisions with energy greater than Eact

Explanation:

The activation energy of a reaction stands as a sort of energy barrier between reactants and products. It is only reactants that possesses energy greater than the activation energy that can be converted from reactants to products.

When the temperature of the system is increased, more particles acquire energy greater than the activation energy. Hence, the fraction of collisions with energy greater than the activation energy increases so the rate of reaction increases likewise.

An aqueous solution contains 0.29 M of benzoic acid (HA) and 0.16 M of sodium benzoate (A-). If the pH of this solution was measured to be 4.63, calculate the pKa of benzoic acid g

Answers

Answer:

pKa = 4.89.

Explanation:

We can solve this problem by using the Henderson-Hasselbach equation, which states:

pH = pKa + log [tex]\frac{[A^-]}{[HA]}[/tex]

In this case [A⁻] is the concentration of sodium benzoate and [HA] is the concentration of benzoic acid.

We input the given data:

4.63 = pKa + log [tex]\frac{0.16}{0.29}[/tex]

And solve for pKa:

pKa = 4.89

Calculate the moles of H3PO4 that reacted (8). Consult the coefficients in the balance chemical reaction to obtain the mole ratio. Show your calculation here.

Answers

Answer:

The number of moles of H₃PO₄ that reacted is 0.000343 moles

Note: Some data is missing. Data from the attachment is used for the calculationsinnthe explanation below.

Explanation:

The reaction is a neutralization reaction between NaOH and H₃PO₄. The equation of the reaction is given as follows:

3 NaOH + H₃PO₄ ---> Na₃PO₄ + 3 H₂O

The molarity of the NaOH solution is 0.238 mol/L.

Average volume of NaOH used during the titration to arrive to endpoint = (4.6 + 3.9 + 4.5) mL / 3 = 4.33 mL

Molarity is defined ratio of the number of moles of solute to the volume of solution. Mathematically, molarity = number of moles/volume in Litres

Number of moles of NaOH reacted = 0.238 mol/L × (4.33mL × 1 L/1000 mL)

Number of moles of NaOH = 0.00103 moles

From the equation of the reaction, 3 moles of NaOH reacts with 1 mole of H₃PO₄

0.00103 moles of NaOH will react with 0.00103 x 1/3 moles of H₃PO₄ = 0.000343 moles of H₃PO₄.

Therefore, number of moles of H₃PO₄ that reacted is 0.000343 moles

15. You are interested in separating 4-methylbenzoic acid from 1,4-dimethoxybenzene using a procedure similar to the extraction procedure we used in lab. You plan to use sodium bicarbonate instead of sodium hydroxide. a) Show the reaction between salicylic acid and sodium bicarbonate. Label the acid, base, conjugate acid, conjugate base. b) Give the pKa values of the acid and conjugate acid. c) Which base will work better, sodium hydroxide or sodium bicarbonate

Answers

Solution :

a). The separation of 4-methylbenzoic acid from 1,4-dimethoxybenzene will work but it will result in lower recovery.

In the reaction of acid-base to form a sodium 4 - methoxy benzoate, that is soluble in the water, 4-methoxy benzoic acid reacts with the sodium bicarbonate to give sodium 4-methoxybenzoate as well as carbonic acid.

b). The pKa for the 4-methoxybenzoic acid is [tex]4.46[/tex], and that of carbonic acid is [tex]6.37[/tex]

c). The Keq for the reaction is [tex]10(6.37 - 4.46) = 101.91[/tex]

Therefore, the equilibrium lies to the right  and also the reaction favors the products and the separation works.

But the recovery will be low when compared to the extraction with Sodium hydroxide as the strong base will drive the equilibrium further to the right position, thus neutralizing all the acids virtually. And the weak base will partially neutralize the acid.

Under certain conditions, the substance mercury(II) oxide can be broken down to form mercury and oxygen. If 32.2 grams of mercury(II) oxide react to form 29.8 grams of mercury, how many grams of oxygen must simultaneously be formed

Answers

Explanation:

This is a decomposition reaction. Firstly, you will want to write the chemical equation out and balance it.

[tex]2Hg_2O->4Hg+O_2[/tex] (The -> is supposed to be an arrow, sorry!)

We see that there's only 1mol of Oxygen made in the products, we can do some simple math to solve for the amount of grams of Oxygen produced according to the amount of the reactant (Hg2O).

[tex]32.2gHg_2O*\frac{1molHg_2O}{417.18gHg_2O}*\frac{1molO_2}{2molHg_2O}*\frac{32gO_2}{1molO_2}[/tex]

I want to break this down, just in case:

The 417.18gHg2O is the molecular mass of the molecule (so I doubled Hg and added 16 to it to get this number).

As we can see in the chemical equation, 1mol Hg2O produces 2mol O because Oxygen is a diatomic molecule (so there will always be two of it when it's by itself).

And finally, in 1mol O2 there are 32g of O2.

** When you do math like this, always make sure that all of your units cancel out except for the units you're looking for. For example, here we're looking for the grams of Oxygen, so after everything else cancels out, we should only have grams O2.

So, 1.23gO2 should be your answer.

Indicate type of chemical reactions for 2Mgl2+MN(SO3)2=2MgSO3+Mnl4

Answers

Answer:

double decomposition reaction

The density of aluminum is 2.7 g/cm3.
Part A
What is its density in kilograms per cubic meter?
Express your answer in kilograms per cubic meter to two significant figures.


Answers

Answer:

2700 kg/m³

Explanation:

First let's convert 2.7 g/cm³ to kg/cm³, keeping in mind that 1 kilogram equals 1000 grams:

2.7 g/cm³ * [tex]\frac{1kg}{1000g}[/tex] = 0.0027 kg/cm³

Finally we need to convert 0.0027 kg/cm³ to kg/m³, keeping in mind that 1 meter equals 100 centimeters, as follows:

0.0027 kg/cm³ * [tex](\frac{100cm}{1m} )^3[/tex] = 2700 kg/m³

The answer is 2700 kg/m³.

what mass of phenol must be dissolved in 25.0 g of naphthalene to produce a solution that is 0.22 m in phenol

Answers

Answer: A mass of 0.518 g of phenol must be dissolved in 25.0 g of naphthalene to produce a solution that is 0.22 m in phenol.

Explanation:

Given: Mass of naphthalene = 25.0 g

Molality = 0.22 m

This means that 0.22 moles of solute is present per kg of solvent.

As 25.0 g  of naphthalene is there that will be 25.0 g per 1000 g (1 kg) is equal to 0.025 kg.

Hence, moles of phenol are calculated as follows.

[tex]Molality = \frac{moles}{mass (in kg)}\\0.22 m = \frac{moles}{0.025 kg}\\moles = 0.0055 mol[/tex]

Also, molar mass of phenol is 94.11 g/mol. This means that 1 mole of phenol contains 94.11 g.

Therefore, mass contained by 0.0055 moles of phenol is as follows.

[tex]0.0055 mol \times 94.11 g/mol \\= 0.518 g[/tex]

Thus, we can conclude that a mass of 0.518 g of phenol must be dissolved in 25.0 g of naphthalene to produce a solution that is 0.22 m in phenol.

g 0.500 L of a solution with a concentration of 0.25 M is needed. To prepare this solution, a stock solution with a concentration of 1.25 M is prepared. What volume of the stock solution is needed to create the desired solution

Answers

Answer:

0.1 L

Explanation:

From the question given above, the following data were obtained:

Concentration of stock solution (C₁) = 1.25 M

Volume of diluted solution (V₂) = 0.5 L

Concentration of diluted solution (C₂) = 0.25 M

Volume of stock solution needed solution (V₁) =?

The volume of the stock solution needed can be obtained as follow:

C₁V₁ = C₂V₂

1.25 × V₁ = 0.25 × 0.5

1.25 × V₁ = 0.125

Divide both side by 1.25

V₁ = 0.125 / 1.25

V₁ = 0.1 L

Therefore, the volume of the stock solution needed is 0.1 L

What is the name of this molecule?

Answers

Explanation:

here is your answer

hope this will help you

Name the following aldehyde PLEASE PLEASE HELP

Answers

Answer:

Explanation:

Answer is D 2,5-dimethylheptanal

You should accern the lowest possible number close to the parent name

which selection is an example of an electrolyte
a. potassium iodide in water
b. sucrose in water
c. pentane in octane
d. methanol in water

Answers

Answer:

i believe its A, potassium iodide in water

Explanation:

A. Potassium iodide in water

I don’t want to fail help
I need correct answer if u don’t know I will report

When the researcher compiled information which research method did they most likely utilize?

a) documentary
b) survey
c) participant observation
d) case study

Answers

Answer:

a

Explanation:

documentary is best researcher!.

Wine goes bad soon after opening because the ethanol dissolved in it reacts with oxygen gas to form water and aqueous acetic acid , the main ingredient in vinegar. Calculate the moles of acetic acid produced by the reaction of of ethanol. Be sure your answer has a unit symbol, if necessary, and round it to significant digits.

Answers

Answer:

The answer is "It takes 1,70 mol of ethanol".

Explanation:

To make acetic acid, we must first write the balanced reaction that occurs of ethanol with oxygen

The response is balanced:

[tex]CH_3CH_2OH+O_2\to CH_3COOH+H_2O[/tex]

1 mol of ethanol creates 1 mol of According the equilibrium Ethanol moles, therefore, required 1.70 mol of water = 1.70 mol

Calculate the mass of water produced when 1.57g of butane reacts with excess oxygen

Answers

Explanation:

So, first you will want to write the balanced chemical equation for this reaction.

Butane = [tex]C_4H_{10}[/tex]

[tex]2C_4H_{10}+13O_2=>10H_2O+8CO_2[/tex]

^ This ends up being your balanced chemical equation. Now, you can do the math!

[tex]1.57gC_4H_{10}*\frac{1molC_4H_{10}}{58.12gC_4H_{10}}*\frac{10molH_2O}{2molC_4H_{10}}*\frac{18gH_2O}{1molH_2O}[/tex]

After plugging this into a calculator, your final mass of water should be:

2.43gH2O

Certain ketones such as fructose can be oxidized by Benedict's reagent under basic conditions to form what type of compound

Answers

Answer:

Certain ketones such as fructose can be oxidized by Benedict's reagent under basic conditions to form what type of compound

Explanation:

Benedict's solution is a mixture of copper sulfate, anhydrous sodium carbonate, and sodium citrate.

In presence of mild reducing agents, Cu(II) ion in Benedict's solution becomes the Cu(I) ion.

Fructose has an alpha-hydroxy ketone group.

It undergoes tautomerism and forms alpha-hydroxy aldehyde which gives a positive test with Benedict's reagent.

During this test, aldehydes will be converted into carboxylic acids.

The reaction of fructose with Benedict's reagent is shown below:

The table shows the nature of reactants and products formed in a certain type of chemical reaction.
Nature of Reactants and Products

Reactants

Metal + lonic compound

Products

Metal + lonic compound

Which of the following is true about the type of chemical reaction?

it is a single replacement reaction, and the anions in the two inic compounds are different.

It is a single replacement reaction, and the cations in the two ionic compounds are different.

It is a double replacement reaction, and the anions in the two ionic compounds are different.

It is a double replacement reaction, and the cations in the two ionic compounds are different.

Answers

Answer: It is true about the type of reaction that it is a single replacement reaction, and the cations in the two ionic compounds are different.

Explanation:

When one element in a compound is replaced by another element in a chemical reaction then it is called a single replacement reaction.

For example, [tex]K + NaCl \rightarrow KCl + Na[/tex]

Here, potassium metal is replacing the sodium metal in the sodium chloride compound.

As metals become cation by losing an electron in a chemical reaction.

Thus, we can conclude that it is true about the type of reaction that it is a single replacement reaction, and the cations in the two ionic compounds are different.

Answer: Its A

Explanation:

a single replacement reactions, and the ANIONS in the two ionic compounds are different

22 Agas that is collected by upward delivery is likely to be A heavier than air B insoluble in water C lighter than air D Soluble in water

Answers

Answer:

joib

Explanation:

Which 2 resonance forms destablize the carbocation intermediate if bezonitrile undergoes chlronation at the ortho or para positions

Answers

The question is incomplete, the complete question is shown in the image attached

Answer:

A and B

Explanation:

The electrophilic substitution of arenes yields a cation intermediate. The positive charge of the cation is delocalized over the entire ring.

The -CN group directs incoming electrophiles to the ortho/para position. The resonance structures for the chlorination of benzonitrile are shown in the question.

Recall that -CN is an electron withdrawing group. The resonance forms that destablize the carbocation intermediate are those in which the -CN group is directly attached to the carbon atom bearing the positive charge as in structures A and B.

What is the phase of water at 0.25 atm and 0°C?
Water
(liquid)
Pressure (atm)
0.5-
0.25
Ice
(solid)
Water vapor
(gas)
0
000
Temperature (°C)
O A. Gas
O B. Solid and gas
O C. Solid and liquid
D. Solid

Answers

It should be a because the temperature and the atm are to low

Water is in the solid phase at 0.25 atm and 0°C.

In what phase is water at 25?

A pressure of 50 kPa and a temperature of 50 °C correspond to the “water” region—here, water exists only as a liquid. At 25 kPa and 200 °C, water exists only in the gaseous state.

What phase is water in at 0 C?

Under standard atmospheric conditions, water exists as a liquid. But if we lower the temperature below 0 degrees Celsius, or 32 degrees Fahrenheit, water changes its phase into a solid called ice.

Learn more about the solid phase here https://brainly.com/question/13396621

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compound of aspartame is a dipeptide that is often used as a sugar substitute which functional groups are present

Answers

Answer:

Carboxyl, primary amine, amide, ester, and phenyl.

Explanation:

The functional groups present in the compound of aspartame are carboxyl, primary amine, amide, ester, and phenyl. Aspartame is an artificial non-saccharide sweetener which is 200 times sweeter than sucrose. This aspartame is commonly used as a sugar substitute in many foods and beverages. It has the trade names such as NutraSweet, Equal, and Canderel.

The following statements either define or are closely related to the terms periodic law, period, or group. Match the terms to the appropriate statements.1. This is a vertical arrangement of elements in the periodic table. 2. This is a horizontal arrangement of elements in the periodic table. 3. The properties of the elements repeat in a regular way as the atomic numbers increase. 4. Element 19 begins this arrangement in the periodic table 5. The chemical properties of elements 12, 20, and 38 demonstrate this principle.

Answers

Answer:

Please find the complete solution in attached file.

Explanation:

Periodic law is the the properties of the elements that repeat in a regular way as the atomic numbers increase.

What is periodic table?

Periodic chart organized collection of all chemical elements arranged roughly according to increasing atomic weight. The periodic recurrence of several features in the elements was originally identified by Dmitry I. Mendeleyev in 1869.

1. This is a vertical arrangement of elements in the periodic table   group

2. This is a horizontal arrangement of elements in the periodic table   period

3. The properties of the elements repeat in a regular way as the atomic numbers increase periodic law

4. Element 19 begins this arrangement in the periodic table period

5. The chemical properties of elements 12, 20, and 38 demonstrate this principle.  periodic law

Therefore, periodic law is the the properties of the elements that repeat in a regular way as the atomic numbers increase.

To learn more about periodic table, here:

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liquid junction potential arise due to?

Answers

Answer:

liquid junction potentials

when a cell contains a boundary between two electrolytic solutions of different composition or concentration, a liquid junction potential is developed due to the "diffusion of the various components at characteristic rates in the boundary zone."

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How many hydrogen atoms are in 3.90 mol of ammonium sulfide?

Answers

Answer:

First, the number of ammonium sulfide molecules should be calculated:

N = NA × n,

where NA - the Avogadro number, n - number of moles.

N (ammonium sulfide) = 6.022 × 1023 × 8.5 mol = 51.187 × 1023.

The moelcular formula of ammonium sulfide is (NH4)2S. It means that each molecule contains 8 hydrogen atoms.

As a result, 8.5 mol of (NH4)2S contain:

51.187 × 1023 × 8 = 41 × 1024 hydrogen atoms.

Answer: 41 × 1024 hydrogen atoms

How many molecules of C 2H 5Br will be present if you had 4.52 g of this compound?

Answers

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Name two natural sources of esters.​

Answers

Answer:

"Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries."

Explanation:

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