What would be the voltage (Ecell) of a voltaic cell comprised of Cd(s)/Cd2+(aq) and Zr(s)/Zr4+(aq) if the concentrations of the ions in solution were [Cd2+] = 0.5 M and [Zr4+] = 0.5 M at 298K?

Answer:

(a) when a reaction system reaches a state of equilibrium, the concentration of the products is equal to the concentration of the reactants

Determining whether the statements about equilibrium is True or False

A) The concentration of the products is equal to the concentration of the reactants at equilibrium : TRUE

B) When a system is at equilibrium, Keq = 1 : TRUE

C) The rates of the forward reaction and the reverse reaction are equal at equilibrium :  TRUE

D) Adding a catalyst to a reaction system will shift the position of equilibrium to the right : FALSE

In a chemical reaction at equilibrium the value of Keq will be equal to 1 because the concentration of the products is equal to the concentration of the reactants in the chemica reaction. Also at equilibrium the rate of forward reaction is same as the rate of reverse reaction.

A catalyst can only affect the rate of reaction and not the amount of product ( yield of reaction).

Hence we can conclude that the answers to your questions are as listed above.

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Answer:

1.8x10¹⁷ molecules of CO are in each breath we take

Explanation:

Parts per million, ppm, is an unit of concentration in chemistry used for very diluted solutions.

A 9ppm of X in a solution means in 1 million of molecules (1x10⁶) you have only 9 molecules of X.

In a breath we have 2x10²² molecules and 9 ppm are CO. Thus, CO molecules in each breath are:

2x10²² molecules × (9 molecules CO / 1x10⁶ molecules) =

[tex]1.8\times 10^{17}[/tex] molecules of CO are in each breath we take

A 9ppm of X in a solution represent in 1 million of molecules[tex](1\times10^6)[/tex]you have only 9 molecules of X.

Now CO molecules in each breath is

[tex]= 2\times 10^{22}\ vmolecules \times (9\ molecules\ CO \div 1\times 10^6 molecules) \\\\= 1.8\times 10^{17}[/tex]

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Answer:

83914.52 grams

Explanation:

Given that,

Weight of a man is 185 lb

We need to find his weight in grams

For this, we must know the relation between lb and grams.

We know that,

1 lb = 453.592 grams

To find the mass of man in grams, the step is :

185 lb = (453.592 × 185) grams

= 83914.52 grams

So, the mass of a man is 83914.52 grams.

Answer:

e. The reaction is product favored and would be considered a voltaic (galvanic) cell

Explanation:

An electrochemical cell produces electrical energy from electrochemical reactions.

A voltaic cell is a type of electrochemical cell that produces electrical energy by spontaneous electrochemical reactions. In a voltaic cell, the cell potential is always positive unlike in an electrolytic cell.

Hence, given the fact that the cell potential is positive, it is a product favoured voltaic cell.

Answer:

The rate would have doubled

Explanation:

Answer:

There are fifteen molecular orbitals in benzene filled with electrons.

Explanation:

Benzene is an aromatic compound. Let us consider the number of bonding molecular orbitals that should be present in the molecule;

There are 6 C-C σ bonds, these will occupy six bonding molecular orbitals filled with electrons.

There are 6 C-H σ bonds, these will occupy another six molecular orbitals filled with electrons

The are 3 C=C π bonds., these will occupy three bonding molecular pi orbitals.

All these bring the total number of bonding molecular orbitals filled with electrons to fifteen bonding molecular orbitals.

Answer: The number of moles of a solute per kilogram of solvent

Explanation:

Answer:

[tex]Speed = 3.30 \frac{km}{hr}[/tex]

Explanation:

Given

Distance = 1 mile

Time = 8.92 minutes

Required

Calculate Speed in km/hr

Speed is calculated as thus;

[tex]Speed = \frac{Distance}{Time}[/tex]

Substitute 1 mile for distance and 8.92 minutes for time

[tex]Speed = \frac{1\ mile}{8.92\ minutes}[/tex]

Convert Miles to Kilometres

If

[tex]1\ mile = 1609\ m[/tex];

Then

[tex]1\ mile = \frac{1609\ km}{1000}[/tex]

[tex]1\ mile = 1.609\ km[/tex] --- (1)

Convert minutes to hour

[tex]1\ minutes = 0.0167\ hour[/tex]

Multiply both sides by 8.92

[tex]8.92 * 1\ minutes = 0.0167\ hour * 8.92[/tex]

[tex]8.92 \ minutes = 0.148964\ hour[/tex] ---- (2)

By substituting (1) and (2) in [tex]Speed = \frac{1\ mile}{8.92\ minutes}[/tex], we have

[tex]Speed = \frac{1.609\ km}{0.48694\ hour}[/tex]

[tex]Speed = 3.304309 \frac{km}{hr}[/tex]

[tex]Speed = 3.30 \frac{km}{hr}[/tex] -- Approximated

Answer:

[tex]m_{CaCO_3}=0.179gCaCO_3[/tex]

Explanation:

Hello,

In this case, since the undergoing chemical reaction is:

[tex]CaCO_3(s)\rightarrow CaO(s)+CO_2(g)[/tex]

The corresponding moles of carbon dioxide occupying 40.0 mL (0.0400 L) are computed by using the ideal gas equation at 273.15 K and 1.00 atm (STP) as follows:

[tex]PV=nRT\\\\n=\frac{PV}{RT}=\frac{1.00 atm*0.0400L}{0.082\frac{atm*L}{mol*K}*273.15 K})=1.79x10^{-3} mol CO_2[/tex]

Then, since the mole ratio between carbon dioxide and calcium carbonate is 1:1 and the molar mass of the reactant is 100 g/mol, the mass that yields such volume turns out:

[tex]m_{CaCO_3}=1.79x10^{-3}molCO_2*\frac{1molCaCO_3}{1molCO_2} *\frac{100g CaCO_3}{1molCaCO_3}\\ \\m_{CaCO_3}=0.179gCaCO_3[/tex]

Regards.

The mass of CaCO₃ required to produce 40.0 mL of CO₂ at STP is 0.179 g

From the question,

We are to determine the mass of CaCO₃ required to produce 40.0 mL of CO₂ at STP.

First, we will determine the number of mole of CO₂ required to be produced

From the formula

PV = nRT

Where

P is the pressure

V is the volume

n is the number of moles

R is the ideal gas constant

and T is the temperature

Then, we can write that

[tex]n = \frac{PV}{RT}[/tex]

From the question,

V = 40.0 mL = 0.04 L

At STP

P = 1 atm

T = 273.15 K

and

R = 0.08206 L atm mol⁻¹ K⁻¹

Putting the parameters into the formula, we get

[tex]n = \frac{1 \times 0.04}{0.08206 \times 273.15}[/tex]

∴ n = 0.0017845 mole

Now, we will write the balanced chemical equation for the decomposition of CaCO₃

CaCO₃ → CaO + CO₂

This means,

1 mole of CaCO₃ will decompose to produce 1 mole of CO₂

Since 0.0017845 mole of CO₂ is to be produced,

Then,

0.0017845 mole of CaCO₃ would be required

Now, for the mass of CaCO₃ required,

Using the formula

Mass = Number of moles × Molar mass

Molar mass of CaCO₃ = 100.0869 g/mol

∴ Mass of CaCO₃ required = 0.0017845 × 100.0869

Mass of CaCO₃ required = 0.178605 g

Mass of CaCO₃ required ≅ 0.179 g

Hence, the mass of CaCO₃ required to produce 40.0 mL of CO₂ at STP is 0.179 g

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Answer:

461.85 degrees Celsius

Answer:

176.8 g of ammonia, NH3.

Explanation:

We'll begin by writing the balanced equation for the reaction. This is given below:

N2 + 3H2 —> 2NH3

Next, we shall determine the mass of H2 that reacted and the mass of NH3 produced from the balanced equation. This is illustrated below:

Molar mass of H2 = 2x1 = 2 g/mol

Mass of H2 from the balanced equation = 3 x 2 = 6 g

Molar mass of NH3 = 14 + (3x1) = 17 g/mol

Mass of NH3 from the balanced equation = 2 x 17 = 34 g.

From the balanced equation above,

6 g of H2 reacted to produce 34 g of NH3.

Finally, we shall determine the mass of ammonia, NH3 produced by reacting 31.2 g of H2.

This can be obtained as follow:

From the balanced equation above,

6 g of H2 reacted to produce 34 g of NH3.

Therefore, 31.2 g of H2 will react to produce = (31.2 x 34)/6 = 176.8 g of NH3.

Therefore, 176.8 g of ammonia, NH3 were obtained from the reaction.

Answer:

6.93

Explanation:

Step 1: Given data

Step 2: Convert the temperature to the Kelvin scale

We will use the following expression.

K = °C + 273.15

K = 50°C + 273.15

K = 323 K

Step 3: Calculate K

We will use the following expression.

∆G° = -R × T × ln K

-5.20 × 10³ J = -(8.314 J/mol.K) × 323 K × ln K

K = 6.93

Answer:

Electrons "surround"

Explanation:

Protons and neutrons "make up" the nucleus so they are contained "within" the nucleus meaning that electrons would "surround" the nucleus as they orbit around the nucleus

Answer:

Electrons

Explanation:

Protons and nuetrons are present inside the nucleus of an atom while the electron revolve around the nucleus in different energy levels.

Answer:

Mass = 11.688g

Explanation:

Volume = 2.00L

Molar concentration = 0.100M

Mass = ?

These quantities are relatted by the following equation;

Conc = Number of moles / volume

Number of moles = Conc * Volume = 2 * 0.100 = 0.2 mol

Number of moles = Mass / Molar mass

Mass = Number of moles * Molar mass

Mass = 0.2mol * 58.44g/mol

Mass = 11.688g

Answer:

B.

Explanation:

A chemical reaction that has the general formula of nA → (A)n is best classified as a polymerization reaction.

Answer:

B. Polymerization

Explanation:

I'm just smart

Answer:

The correct answer is 206 ml.

Explanation:

Based on the given information, the molarity or M₁ of MgF₂ solution is 0.0887 M, the molarity or M₂ of the final solution given is 0.0224 M. The initial volume of V₁ of the solution is 69.6 ml, for finding the final volume of V₂ of the solution, the formula to be used is,  

M₁V₁ = M₂V₂

Now putting the values in the formula we get,  

0.0887 × 69.6 = 0.0224 M × V₂

V₂ = 0.0887 × 69.6 / 0.0224

V₂ = 275.6 ml

Therefore, the volume in ml added to the initial volume of 69.6 ml to make the molarity of the solution 0.0224 will be,  

= 275.6 ml - 69.6 ml = 206 ml

Answer:

14.297 g

Explanation:

From the question;

1 mo of the compound requires 1320.0 kJ

From the molar mass;

1 ml of the compound weighs 30.55g

How many grams requires 617.30kJ?

1 ml = 1320

x mol = 617.30

x = 617.30 / 1320

x = 0.468 mol

But 1 mol = 30.55

0.468 mol = x

x = 14.297 g

Answer:

Explanation:

A tertiary alcohol is a compound (an alcohol) in which the carbon atom that has the hydroxyl group (-OH) is also bonded (saturated) to three different carbon atoms.

Based on the question, the only tertiary alcohol that can result from C₆H₁₄O that have a 4-carbon chain is

2-hydroxy-2,3-dimethylbutane

     H  OH   H    H

      |     |       |      |

H - C - C -   C  - C - H

      |     |       |      |

     H  CH₃  CH₃ H

From the above, we can see that the carbon atom having the hydroxyl group is also bonded to three other carbon atoms. And since we aren't considering stereochemistry, this is the only tertiary alcohol we can have with a 4-carbon chain

Answer:

Half-life at 629K = 252.4min

Explanation:

Using Arrhenius equation:

[tex]ln\frac{K_1}{K_2} = \frac{Ea}{R} (\frac{1}{T_2} -\frac{1}{T_1})[/tex]

And as Half-life in a first order reaction is:

[tex]t_{1/2}=\frac{ln2}{K}[/tex]

We can convert the half-life of 58.0min to know K₁ adn replacing in Arrhenius equation find half-life at 629K:

[tex]58.0min=\frac{ln2}{K}[/tex]

K = 0.01195min⁻¹ = K₁

[tex]ln\frac{0.01195min^{-1}}{K_2} = \frac{218kJ/mol}{8.314x10^{-3}kJ/molK} (\frac{1}{629K} -\frac{1}{652K})[/tex]

[tex]ln\frac{0.01195min^{-1}}{K_2} =1.47[/tex]

[tex]\frac{0.01195min^{-1}}{K_2} =4.35[/tex]

K₂ = 2.75x10⁻³ min⁻¹

And, replacing again in Half-life expression:

[tex]t_{1/2}=\frac{ln2}{2.75x10^{-3}min^{-1}}[/tex]

The half-life of the first-order reaction of ethylene oxide decomposition at 629 K is 251.1 min when the half-life at 652 K is 58.0 min and the activation energy is 218 kJ/mol.   

The activation energy of a reaction is related to its rate constant as follows:  

[tex] k = Ae^{-\frac{E_{a}}{RT}} [/tex]   (1)

Where:

We can find the rate constant of the first-order reaction at 652 K with the half-life as follows:

[tex]k_{652} = \frac{ln(2)}{t_{1/2}_{(652)}}[/tex]   (2)

Where [tex]t_{1/2}_{(652)}[/tex] is the half-life at 652 K= 58.0 min

Hence, the rate constant at 652 K is:                            

[tex] k_{652} = \frac{ln(2)}{58.0 min} = 0.012 min^{-1} [/tex]

Now, from equation (1) we can find the pre-exponential factor (A):

[tex]A = \frac{k_{652}}{e^{(-\frac{E_{a}}{RT_{1}})}} = \frac{0.012 \:min{-1}}{e^{(-\frac{218\cdot 10^{3} \:J/mol}{8.314 \:J/(K*mol)*652 \:K})}} = 3.51 \cdot 10^{15} min^{-1}[/tex]  

With the pre-exponential factor we can calculate the rate constant at 629 K (eq 1):

[tex]k_{629} = 3.51 \cdot 10^{15} min^{-1}*e^{(-\frac{218 \cdot 10^{3} J/mol}{8.314 J/(K*mol)*629 K})} = 2.76 \cdot 10^{-3} min^{-1}[/tex]

Finally, the half-life at 629 K is (eq 2):

[tex] t_{1/2}_{629} = \frac{ln(2)}{2.76\cdot 10^{-3} min^{-1}} = 251.1 min [/tex]

Therefore, the half-life at 629 K is 251.1 min.

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Answer:

a. NCl3

Explanation:

All the elements stated are non metals. Generally the bond between non metals is a covalent bond. However depending on how the electrons are shared, this bond can either be polar or non polar.

A non polar covalent bond is formed when the electrons are shared equally between the atoms.

A way to determine if a bond is non polar or polar covalent is by comparing the electronegativity values.

If the electronegativity difference is less than 0.5, it is regarded as a non polar covalent bond.

Going back to the question;

Between N and Cl; the electronegativity difference is 3.0 - 3.0 = 0

Between Cl and O; the electronegativity difference is 3.5 - 3.0 = 0.5

Between Cl and P; the electronegativity difference is 3.5 - 2.1 = 1.4

From these we can tell that the correct option is option A.

Answer:

OPTION C is correct

3.86 x 10-19 J

Explanation:

Energy of the line can be calculated using below formula

E= h ν.................(1)

Where E= energy

h= plank constant= 6.626 10-34 J s

c=speed of light=3 x 108 m/s

But we know that Velocity V= = c / λ

Then substitute into equation (1) we have

E = h c / λ.............(2)

We can calculate our( hc ) in nm for unit consistency

h c =( 6.626 ×10^-34)x(3×108)

h c = (1.986 x 10-16 )

hc = 1.986 x 10-16 J nm then since our (hc) and λ are in the same unit , were good to go then substitute into equation(2)

E = h c / λ = (1.986 x 10-16) / 515

E = 3.86 x 10-19 J

Therefore, the Energy is 3.86 x 10-19 J

Answer:

The number of electrons transferred in the reaction

Explanation:

Answer:

A

Explanation:

Answer:

6.5 mg/L.

Explanation:

Step one: write out and Balance the chemical reaction in the Question above:

NiCl2 + 2AgNO3 =====> 2AgCl + Ni(NO3)2.

Step two: Calculate or determine the number of moles of AgCl.

So, we are given that the mass of AgCl = 3.6 mg = 3.6 × 10^-3 g. Therefore, the number of moles of AgCl can be calculated as below:

Number of moles AgCl = mass/molar mass = 3.6 × 10^-3 g / 143.32. = 2.5118 × 10^-5 moles.

Step three: Calculate or determine the number of moles of NiCl2.

Thus, the number of moles of NiCl2 = 2.5118 × 10^-5/ 2 = 1.2559 × 10^-5 moles.

Step four: detemine the mass of NiCl2.

Therefore, the mass of NiCl2 = number of moles × molar mass = 1.2559 × 10^-5 moles × 129.6 = 1.6 × 10^-3 g.

Step five: finally, determine the concentration of NiCl2.

1000/ 250 × 1.6 × 10^-3 g. = 6.5 mg/L.

Answer:

a. Ca₃(PO₄)₂.

b. 0.010 moles of Ca₃(PO₄)₂ can we expect to be produced

c. 3.1g of Ca₃(PO₄)₂

d. Percent yield = 93.5%

Explanation:

a. Based on the reaction:

3Ca(NO₃)₂(aq) + 2Na₃PO₄(aq) → Ca₃(PO₄)₂(s) + 6NaNO₃(aq)

3 moles of calcium nitrate reacts with 2 moles of sodium phosphate producieng 1 mole of calcium phosphate.

As you can see, Ca₃(PO₄)₂ is a solid product -(s)-, that means when the reaction occurs the precipitate produced is the solid,

b. As 3 moles of calcium nitrate produce 1 mole of calcium phosphate and there are 0.030 moles of calcium nitrate

0.030 moles Ca(NO₃)₂ × (1 mol Ca₃(PO₄)₂ / 3 moles Ca(NO₃)₂) =

c. As molar mass of Ca₃(PO₄)₂ is 310.18g/mol, the mass of 0.010 moles (The expected mass) is;

0.010 moles Ca₃(PO₄)₂ × (310.18g / mol) =

d. The percent yield is defined as 100 times the ratio between the obtained yield (That is 2.9g of precipitate, Ca₃(PO₄)₂) and the expected yield, 3.1g of Ca₃(PO₄)₂:

[tex]\frac{2.9g}{3.1g} *100[/tex]

(a) The product in solid state would be the precipitate. Hence, the precipitate would be Ca3(PO4)2

(b) From the balanced equation of the reaction: 3 moles of Ca(NO3)2 is required for 1 mole of Ca3(PO4)2

If there are just 0.030 moles of Ca(NO3)2, then"

3 moles = 1

0.030 moles =    1 x 0.030/3

                         = 0.01 moles of Ca3(PO4)2

In other words, 0.01 moles of the precipitate would be expected to be produced from 0.030 moles of calcium nitrate.

(c) 0.01 moles solid (Ca3(PO4)2) is expected. Mass of Ca3(PO4)2 expected:

      mass   = mole x molar mass

molar mass of Ca3(PO4)2 = 310.18 g/mol

mass of Ca3(PO4)2 expected to be produced = 0.01 x 310.18

                                                                       = 3.1018 g

Hence, 3.1018g of solid is expected to be produced.

(d) Percentage yield = actual yield/theoretical yield x 100

                          = 2.9/3.1018 x 100

                               = 93.5%

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Answer:

3.0x10⁻²M

Explanation:

Silver sulfate, Ag₂SO₄, has a product constant solubility equilbrium of:

Ag₂SO₄(s) ⇄ 2Ag⁺ + SO₄²⁻

When an excess of silver sulfate is added, some Ag₂SO₄ will react producing Ag⁺ and SO₄²⁻ until reach the equilbrium determined for the formula:

ksp = 1.4x10⁻⁵ = [Ag⁺]² [SO₄²⁻]

Assuming the Ag₂SO₄ that react until reach equilibrium is X, we can replace in Ksp expression:

1.4x10⁻⁵ = [Ag⁺]² [SO₄²⁻]

1.4x10⁻⁵ = [2X]² [X]

1.4x10⁻⁵ = 4X³

3.5x10⁻⁶ = X³

0.015 = X

As [Ag⁺] is 2X:

[Ag⁺] = 0.030 = 3.0x10⁻²M

The answer is:

Answer:

H2SO4 with concentrated HCl

Answer: NaCl would give the higher pressure

Explanation:

Osmotic pressure depends only on the number of ions.

NaCl dissociates as Na+ and Cl- ; CsBr  dissociates as Cs+ and Br-

But the concentration of the solutions are different.  

Concentration (morality ) of NaCl = Moles /Litre = (1 g /58.44g/mol)/0.01L

Total number of ions in NaCl solution = 2 x (1 g /58.44g/mol)/0.01L ( 1 mol NaCl gives 2 moles ions, 1 mol Na+ and 1 mol Cl-)  

= 1.71×2RT

Similarly total number of ions in CsBr solution = 2 x (1 g /212.80 g/mol)/0.01L

= 0.47×2RT

Therefore osmotic pressure is higher in NaCl solution.

Answer: [tex]NF_3[/tex]

Explanation:

Geometrical symmetry of the molecule and the polarity of the bonds determine the polarity of the molecule.

The molecule that has zero dipole moment that means it is a geometrically symmetric molecule and the molecule which has some net dipole moment means it is a geometrically asymmetric molecule.

As the molecule is symmetric, the dipole moment will be zero as dipole moments cancel each other and the molecule will be non-polar.

As the molecule is asymmetric, the dipole moment will not be zero and the molecule will be polar.

Example: [tex]NF_3[/tex]

Thus, we can say that [tex]NF_3[/tex] is a polar molecule.