Answer:
See explanation.
Explanation:
Hello,
In this case, we can realize that water has a very simple atomic structure which consists of two hydrogen atoms bonded to one oxygen atom. The nature of the atomic structure of water causes its molecules to have unique electrochemical properties. The hydrogen side of the water molecule has a slight positive charge whereas at the other side of the molecule a negative charge exists. This molecular polarity causes water to be a powerful solvent and is responsible for its strong surface tension.
Moreover, water is involved in several both inorganic and organic chemical reactions leading to hydration, for example, the conversion of alkenes to alcohols, the hydrolysis of acyl halides, anhydrides, esters and amides to carboxylic acids and the hydration of a raft of inorganic salts that exist as hydrates only, such as copper (II) sulfate pentahydrate and so.
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Does the amount of methanol increase, decrease, or remain the same when an equilibrium mixture of reactants and products is subjected to the following changes?
a. the catalyst is removed
b. the temp is increased
c. the volume is decreased
d. helium is added
e. CO is added
Answer:
a. Methanol remains the same
b. Methanol decreases
c. Methanol increases
d. Methanol remains the same
e. Methanol increases
Explanation:
Methanol is produced by the reaction of carbon monoxide and hydrogen in the presence of a catalyst as follows; 2H2+CO→CH3OH.
a) The presence or absence of a catalyst makes no difference on the equilibrium position of the system hence the methanol remains constant.
b) The amount of methanol decreases because the equilibrium position shifts towards the left and more reactants are formed since the reaction is exothermic.
c) If the volume is decreased, there will be more methanol in the system because the equilibrium position will shift towards the right hand side.
d) Addition of helium gas has no effect on the equilibrium position since it does not participate in the reaction system.
e) if more CO is added the amount of methanol increases since the equilibrium position will shift towards the right hand side.
The gas with an initial volume of 24.0 L at a pressure of 565 torr is compressed until the volume is 16.0 L. What is the final pressure of the gas, assuming the temperature and amount of gas does not change
Answer:
848 torr
Explanation:
The only variables are the pressure and the volume, so we can use Boyle's Law.
p₁V₁ = p₂V₂
Data:
p₁ = 565 torr; V₁ = 24.0 L
p₂ = ?; V₂ = 16.0 L
Calculations:
[tex]\begin{array}{rcl}p_{1}V_{1} & = & p_{2}V_{2}\\\text{565 torr} \times \text{24.0 L} & = & p_{2} \times \text{16.0 L}\\\text{13 560 torr} & = & 16.0p_{2}\\p_{2} & = & \dfrac{\text{13 560 torr}}{16.0}\\\\& = &\textbf{848 torr}\\\end{array}\\\text{The final pressure of the gas is $\large \boxed{\textbf{848 torr}}$}[/tex]
what is ammonium nitrate
Answer:
Ammonium nitrate is a chemical compound with the chemical formula NH₄NO₃. It is a white crystalline solid consisting of ions of ammonium and nitrate.
A strand of messenger RNA coding the synthesis of a protein with 146 amino acids must have a string of___________ bases along its backbone. a. 146 b. 292 c. 438 d. 20 e. 3
Answer:
Since the relationship between amino acid and codon bases would be the values of 3 nitrogenous bases per 1 amino acid.
knowing this relationship what you would do is simply multiply 146 x 3 to find the number of codon bases which would be C. 438.
A strand of messenger RNA coding the synthesis of a protein with 146 amino acids must have a string of 438 bases along its backbone and the correct option is option C.
What is messenger RNA?mRNA or messenger RNA is a single stranded RNA molecule. It is complementary to the DNA and carries genetic information present in the DNA. It is translated to form proteins. The genetic codes (triplet) present on mRNA get translated to amino acids, giving rise to the functional product of a gene.
So mRNA really is a form of nucleic acid, which helps the human genome which is coded in DNA to be read by the cellular machinery. mRNA is actually the translated form of DNA that the machinery can recognize and use to assemble amino acids into proteins.
Each strand has 3 bases, so 146 × 3 = 438 bases
Therefore, A strand of messenger RNA coding the synthesis of a protein with 146 amino acids must have a string of 438 bases along its backbone and the correct option is option C.
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A 135 g sample of H20 at 85°C is cooled. The water loses a total of 15 kJ of energy in the cooling
process. What is the final temperature of the water? The specific heat of water is 4.184 J/g.°C.
A. 112°C
B. 58°C
C. 70°C
D. 84°C
E. 27°C
Answer:
B. 58°C
Explanation:
Hello,
In this case, the relationship among heat, mass, specific heat and temperature for water is mathematically by:
[tex]Q=mCp\Delta T=mCp(T_2-T_1)[/tex]
In such a way, solving for the final temperature [tex]T_2[/tex] we obtain:
[tex]T_2=T_1+\frac{Q}{mCp}[/tex]
Therefore, we final temperature is computed as follows, considering that the involved heat is negative as it is lost for water:
[tex]T_2=85\°C+\frac{-15kJ*\frac{1000J}{1kJ} }{135g*4.184\frac{J}{g\°C} }\\\\T_2=58\°C[/tex]
Thereby, answer is B. 58°C .
Regards.
Calculate the equilibrium constant K c for the following overall reaction: AgCl(s) + 2CN –(aq) Ag(CN) 2 –(aq) + Cl –(aq) For AgCl, K sp = 1.6 × 10 –10; for Ag(CN) 2 –, K f = 1.0 × 10 21.
Answer:
1.6x10¹¹ = Kc
Explanation:
For the reaction:
AgCl(s) + 2CN⁻(aq) ⇄ Ag(CN)₂⁻(aq) + Cl⁻(aq)
Kc is defined as:
Kc = [Ag(CN)₂⁻] [Cl⁻] / [CN⁻]²
Ksp of AgCl is:
AgCl(s) ⇄ Ag⁺(aq) + Cl⁻(aq)
Where Ksp is:
Ksp = [Ag⁺] [Cl⁻] = 1.6x10⁻¹⁰
In the same way, Kf of Ag(CN)₂⁻ is:
Ag⁺(aq) + 2CN⁻ ⇄ Ag(CN)₂⁻
Kf = [Ag(CN)₂⁻] / [CN⁻]² [Ag⁺] = 1.0x10²¹
The multiplication of Kf with Ksp gives:
[Ag⁺] [Cl⁻] * [Ag(CN)₂⁻] / [CN⁻]² [Ag⁺] = Ksp*Kf
[Ag(CN)₂⁻] [Cl⁻] / [CN⁻]² = Ksp*Kf
Obtaining the same expression of the first reaction
That means Ksp*Kf = Kc
1.6x10⁻¹⁰*1.0x10²¹ = Kc
1.6x10¹¹ = KcBeginning with Na, record the number of energy levels, number of protons, and atomic radius for each element in period 3.
Answer:
Sodium, magnesium, aluminium, silicon, phosphorus, sulfur, chlorine, and argon are the elements of third period.
Explanation:
There are three energy levels in sodium atom. It has 11 electrons revolving around the nucleus. the atomic radius of sodium atom is 227 ppm. Magnesium, aluminium, silicon, phosphorus, sulfur, chlorine, and argon has also three energy levels like sodium because all these elements belongs to third period. There are 12 electrons present in magnesium, 13 in aluminium, 14 in silicon, 15 in phosphorus, 16 in sulfur, 17 in chlorine, and 18 electrons in argon. The atomic radius of magnesium atom is 173 ppm. The atomic radius of aluminium atom is 143 ppm. The atomic radius of silicon atom is 111 ppm. The atomic radius of phosphorus atom is 98 ppm. The atomic radius of sulfur atom is 87 ppm. The atomic radius of chlorine atom is 79 ppm and the atomic radius of argon atom is 71 ppm.
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Refining aluminum takes place in steel vats lined with graphite. What function does the graphite lining serve?
A. It is the cathode.
B. It is the anode.
C. It soaks up the waste oxygen released from bauxite (Al2O3)
D. It serves as a grounding layer to prevent electrical surges.
Answer: It's the anode broski (B)
Explanation: I'm taking the Chem summer course too broski, this was the correct answer. Cheers broski
The intermolecular forces present in CH 3NH 2 include which of the following? I. dipole-dipole II. ion-dipole III. dispersion IV. hydrogen bonding
Answer:
I. dipole-dipole
III. dispersion
IV. hydrogen bonding
Explanation:
Intermolecular forces are weak attraction force joining nonpolar and polar molecules together.
London Dispersion Forces are weak attraction force joining non-polar and polar molecules together. e.g O₂, H₂,N₂,Cl₂ and noble gases. The attractions here can be attributed to the fact that a non -polar molecule sometimes becomes polar because the constant motion of its electrons may lead to an uneven charge distribution at an instant.
Dispersion forces are the weakest of all electrical forces that act between atoms and molecules. The force is responsible for liquefaction or solidification of non-polar substances such as noble gas an halogen at low temperatures.
Dipole-Dipole Attractions are forces of attraction existing between polar molecules ( unsymmetrical molecules) i.e molecules that have permanent dipoles such as HCl, CH3NH2 . Such molecules line up such that the positive pole of one molecule attracts the negative pole of another.
Dipole - Dipole attractions are more stronger than the London dispersion forces but weaker than the attraction between full charges carried by ions in ionic crystal lattice.
Hydrogen Bonding is a dipole-dipole intermolecular attraction which occurs when hydrogen is covalently bonded to highly electronegative elements such as nitrogen, oxygen or fluorine. The highly electronegative elements have very strong affinity for electrons. Hence, they attracts the shared pair of electrons in the covalent bonds towards themselves, leaving a partial positive charge on the hydrogen atom and a partial negative charge on the electronegative atom ( nitrogen in the case of CH3NH2 ) . This attractive force is know as hydrogen bonding.
Answer:
The intermolecular forces present in CH_3NH_2 includes
II. (ion-dipole) and IV. (hydrogen bonding)Explanation:
The intermolecular forces present in CH_3NH_2 includes II. (ion-dipole) and IV. (hydrogen bonding)
It is a polar molecule due to NH polar bond and it can form Hydrogen bond also due to NH bond.
Interaction will be dipole- dipole and Hydrogen dispersion forces can always be taken into account.
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A student determines the value of the equilibrium constant to be 1.5297 x 107 for the following reaction: HBr(g) + 1/2 Cl2(g) --> HCl(g) +1/2 Br2(g) Based on this value of Keq, calculate the Gibbs free energy change for the reaction of 2.37 moles of HBr(g) at standard conditions at 298 K.
Answer:
[tex]\Delta G=-97.14kJ[/tex]
Explanation:
Hello,
In this case, the relationship between the equilibrium constant and the Gibbs free energy of reaction is:
[tex]\Delta G=-RTln(K)[/tex]
Hence, we compute it as required:
[tex]\Delta G=-8.314\frac{J}{mol\times K}*298K*ln(1.5297x10^7)\\\\\Delta G=-40.99kJ/mol[/tex]
And for 2.37 moles of hydrogen bromide, we obtain:
[tex]\Delta G=-40.99kJ/mol*2.37mol\\\\\Delta G=-97.14kJ[/tex]
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11mg of cyanide per kilogram of body weight is lethal for 50% of domestic chickens. How many grams per kilogram of body weight is a lethal dose for 50% of domestic chickens?
Answer:
[tex]0.033g[/tex]
Explanation:
Hello,
In this case, since 11 mg per kilogram of body weight has the given lethality, the mg that turn out lethal for a chicken weighting 3 kg is computed by using a rule of three:
[tex]11mg\longrightarrow 1kg\\\\x\ \ \ \ \ \ \longrightarrow 3kg[/tex]
Thus, we obtain:
[tex]x=\frac{3kg*11mg}{1kg}\\ \\x=33mg[/tex]
That in grams is:
[tex]=33mg*\frac{1g}{1000mg} \\\\=0.033g[/tex]
Regards.
Consider the acid H3PO4. This acid will react with water by the following equation. H3PO4+H2O↽−−⇀H2PO−4+H3O+ What will be true of the resulting conjugate base H2PO−4? Select the correct answer below: H2PO−4 can act as an acid.
Answer:
H+/PO-4^-2
Explanation:
hydrogen has dissolved completely
In the given reaction conjugate base is H₂PO₄⁻, it also behave as a weak acid.
What is acid - conjugate base pair?
An acid and conjugate base pairs are those pairs in which they are differentiated by the one atom of hydrogen atom.
Given chemical reaction is:
H₃PO₄ + H₂O → H₂PO₄⁻ + H₃O⁺
In the above reaction H₃PO₄ is an acid as it gives H⁺ ion to the solution and formed H₂PO₄⁻, which is a conjugate base of H₃PO₄ acid. H₂PO₄⁻ will also behave as an acid because it have H⁺ ion to gives in the solution but nature of this acid is weak as they not readily dissociates.
Hence, H₂PO₄⁻ is a conjugate base.
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Which of the following happens to a molecule of an object when the object is heated? (1 point)
Answer:
They get more energy, so they vibrate!
Explanation:
g All of the molecules below have polar bonds but only one of the molecules is a polar molecule. Which one is a polar molecule? A) C2F2 B) C2Cl4 C) CO2 D) NF3 E) CF4
Answer: [tex]NF_3[/tex]
Explanation:
Geometrical symmetry of the molecule and the polarity of the bonds determine the polarity of the molecule.
The molecule that has zero dipole moment that means it is a geometrically symmetric molecule and the molecule which has some net dipole moment means it is a geometrically asymmetric molecule.
As the molecule is symmetric, the dipole moment will be zero as dipole moments cancel each other and the molecule will be non-polar.
As the molecule is asymmetric, the dipole moment will not be zero and the molecule will be polar.
Example: [tex]NF_3[/tex]
Thus, we can say that [tex]NF_3[/tex] is a polar molecule.
How are Math, Physics, Chemistry, and Biology all related?
Answer:
- you have to do maths in all 3
- atoms make up everything even parts of a cel and theyre studied in chem and physics
- chemistry is used in biology by finding out what different substances are eg cytoplasm in a cell
If 1 mol of a pure triglyceride is hydrolyzed to give 2 mol of RCOOH, 1 mol of R'COOH, and 1 mol of glycerol, which of the following compounds might be the triglyceride?
CHOC(O)R
A. CHOC(O)R
CHOC(O)R
CH,OC(O)R
B. CHOC(O)R
CH2OC(O)R
CHOC(O)R
C. CHOC(O)R
CHOC(O)R
CHOC(O)R
D. CHOC(O)R
CHOC(O)R
Answer:
The correct option is C.
Note the full question and structure of the moleculesis found in the attachment below.
Explanation:
Triglycerides or triacylglycerols are non-polar, hydrophobic lipid molecules composed of three fatty acids linked by ester bonds to a molecule of glycerol.
The fatty acids linked to the glycerol molecule are denoted by R and may be of the same kind or different. when the R group is the same, the R is attached in all the three positions for ester bonding in the glycerol molecule but when they are different are denoted by R, R' and R'' respectively.
During the hydrolysis of triglycerides, the three fatty acids molecules are obtained as well as a glycerol molecule.
From the question, when 1 mole of the triglyceride is hydrolysed, 2 moles of RCOOH, 1 mole of R'COOH and 1 mole of glycerol is obtained. The triglyceride must then be composed of two fatty acids which are the same denoted by R, and a different fatty acid molecule denoted by R'.
The correct option therefore, is C
Typical "hard" water contains about 2.0 x 10–3 mol of Ca2+ per liter. Calculate the maximum concentration of fluoride ion that could be present in hard water. Assume fluoride is the only anion present that will precipitate calcium ion.
Answer:
[tex][F^-]_{max}=4x10{-3}\frac{molF^-}{L}[/tex]
Explanation:
Hello,
In this case, for the described situation, we infer that calcium reacts with fluoride ions to yield insoluble calcium fluoride as shown below:
[tex]Ca^{+2}(aq)+2F^-(aq)\rightleftharpoons CaF_2(s)[/tex]
Which is typically an equilibrium reaction, since calcium fluoride is able to come back to the ions. In such a way, since the maximum amount is computed via stoichiometry, we can see a 1:2 mole ratio between the ions, therefore, the required maximum amount of fluoride ions in the "hard" water (assuming no other ions) turns out:
[tex][F^-]_{max}=2.0x10^{-3}\frac{molCa^{2+}}{L}*\frac{2molF^-}{1molCa^{2+}} \\[/tex]
[tex][F^-]_{max}=4x10{-3}\frac{molF^-}{L}[/tex]
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Calculate the amount of heat needed to melt of ice () and bring it to a temperature of . Round your answer to significant digits. Also, be sure your answer contains a unit symbol.
Answer:
your answer is given below
Explanation:
Take it stepwise, and you are going to have to look up the various heat values.
You have 36.5grams of ice, presumably at 0C. You will need to add heat to take the ice at 0 C to water at 0 C. (Latent heat of melting) Then you add in a different heat value to take the water at 0 C to water at 82.3 C. (Specific heat of water)
Add the two heat amounts together.
According to specific heat capacity, to calculate the amount of heat needed to melt ice given mass of ices is multiplied by specific heat of ice and the temperature change which it undergoes.
What is specific heat capacity?Specific heat capacity is defined as the amount of energy required to raise the temperature of one gram of substance by one degree Celsius. It has units of calories or joules per gram per degree Celsius.
It varies with temperature and is different for each state of matter. Water in the liquid form has the highest specific heat capacity among all common substances .Specific heat capacity of a substance is infinite as it undergoes phase transition ,it is highest for gases and can rise if the gas is allowed to expand.
It is given by the formula ,
Q=mcΔT
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Which of the following goes through the largest volumetric change? Question 4 options: A) Water when it's heated from 1oC to 99oC B) Water when it freezes into ice C) Ice when it melts into water D) Water when it boils into steam
Answer:
Water when it freezes into ice
Explanation:
Most liquids expand when heated and contract when cooled, water behaves in an anomalous fashion. Water rather expands when cooled and contracts when heated.
Water usually contracts on cooling from any temperature until 4°C, after 4°C, the water begins to expand rapidly. Hence water has its least volume at 4°C and increases rapidly afterwards.
Thus the largest volume change for water occurs during freezing since it expands when cooled.
2NH3 → N2 + 3H2 If 2.22 moles of ammonia (NH3) decomposes according to the reaction shown, how many moles of hydrogen (H2) are formed? A) 2.22 moles of H2 B) 1.11 moles of H2 C) 3.33 moles of H2 D) 6.66 moles of H2
Answer:
C
Explanation:
According to the mole ratio, using 2NH3 will give you 3H2. Which means in order to find the moles of H2 you would only need to divide 2 and multiply 3 to get the amount of moles of H2 produced.
Answer:
I think it's C
Explanation:
Please, tell me if I'm incorrect.
If the heat of combustion for a specific compound is −1320.0 kJ/mol and its molar mass is 30.55 g/mol, how many grams of this compound must you burn to release 617.30 kJ of heat?
Answer:
14.297 g
Explanation:
From the question;
1 mo of the compound requires 1320.0 kJ
From the molar mass;
1 ml of the compound weighs 30.55g
How many grams requires 617.30kJ?
1 ml = 1320
x mol = 617.30
x = 617.30 / 1320
x = 0.468 mol
But 1 mol = 30.55
0.468 mol = x
x = 14.297 g
what is the lewis structure for OP(N3)3
Explanation:
this is the ans
hope this helps
Nitric oxide (NO) can be formed from nitrogen, hydrogen and oxygen in two steps. In the first step, nitrogen and hydrogen react to form ammonia: (g) (g) (g) In the second step, ammonia and oxygen react to form nitric oxide and water: (g) (g) (g) (g) Calculate the net change in enthalpy for the formation of one mole of nitric oxide from nitrogen, hydrogen and oxygen from these reactions. Round your answer to the nearest .
Answer: [tex]\Delta H = -272.25kJ[/tex] for 1 mole of NO.
Explanation: Hess' Law of Constant Summation or Hess' Law states that the total enthalpy change of a reaction with multiple stages is the sum of the enthalpies of all the changes.
For this question:
1) [tex]N_{2}_{(g)} + 3H_{2}_{(g)}[/tex] => [tex]2NH_{3}_{(g)}[/tex] [tex]\Delta H=-92kJ[/tex]
2) [tex]4NH_{3}_{(g)}+5O_{2}_{(g)}[/tex] => [tex]4NO_{(g)}+6H_{2}O_{(g)}[/tex] [tex]\Delta H=-905kJ[/tex]
Amonia ([tex]NH_{3}_{(g)}[/tex]) appeares as product in the first equation and as reagent in the 2 reaction, so when adding both, there is no need to inverse reactions. However, in the 2nd, there are 4 moles of that molecule, so to cancel it, you have to multiply by 2 the first chemical equation and enthalpy:
[tex]2N_{2}_{(g)} + 6H_{2}_{(g)}[/tex] => [tex]4NH_{3}_{(g)}[/tex] [tex]\Delta H=-184kJ[/tex]
Now, adding them:
[tex]2N_{2}_{(g)} + 6H_{2}_{(g)}[/tex] => [tex]4NH_{3}_{(g)}[/tex] [tex]\Delta H=-184kJ[/tex]
[tex]4NH_{3}_{(g)}+5O_{2}_{(g)}[/tex] => [tex]4NO_{(g)}+6H_{2}O_{(g)}[/tex] [tex]\Delta H=-905kJ[/tex]
[tex]2N_{2}_{(g)}+6H_{2}_{(g)}+5O_{2}_{(g)}=>4NO_{(g)}+6H_{2}O_{(g)}[/tex] [tex]\Delta H = -185-905[/tex]
[tex]2N_{2}_{(g)}+6H_{2}_{(g)}+5O_{2}_{(g)}=>4NO_{(g)}+6H_{2}O_{(g)}[/tex] [tex]\Delta H = -1089kJ[/tex]
Note net enthalpy is for the formation of 4 moles of nitric oxide.
For 1 mole:
[tex]\Delta H = \frac{-1089}{4}[/tex]
[tex]\Delta H=-272.25kJ[/tex]
To form 1 mol of nitric oxide from nitrogen, oxygen and hydrogen, net change in enthalpy is [tex]\Delta H=-272.25kJ[/tex].
Which of these species would you expect to have the lowest standard entropy (S°)?
a. CH4(g)
b. H2O(g)
c. NH3(g)
d. HF(g)
Answer:
d. HF(g)
Explanation:
Hello,
In this case, the standard entropy S° could be predicted by looking at the amount of bonds the compound has, thus, the fewer the number bonds, the lower the standard entropy, it means that d. HF(g) has lowest value as it has one bond only whereas methane has four bonds, water two bonds and ammonia three bonds.
Best regards.
Experiment:
Part I: Voltaic Cell
Assume that you are provided with the following materials:
Strips of metallic zinc, metallic copper, metallic iron
1M aqueous solutions of ZnSO4, CuSO4, FeSO4, and aqueous iodine (I2)
Other required materials to create Voltaic cells such as beakers, porous containers, graphite rods, a voltmeter, and a few wires with alligator clips.
In this modified version of the lab, after thoroughly studying the lab hand out and watching the videos, identify 4 different combinations of Voltaic cells that are possible to be created with the above materials.
For each cell created, include the following details.
Which electrode was the anode and which was the Cathode?
The anode and cathode half reactions.
Balanced equation for each cell you propose to construct.
Calculated Eocell
Short hand notation (line notation) for each cell (be sure to include the inactive electrode if needed)
Answer:
Here are four possible voltaic cells.
Explanation:
1. Standard reduction potentials
E°/V
I₂(s) + 2e⁻ ⟶ 2I⁻(aq); 0.54
Cu²⁺(aq) + 2e⁻ ⟶ Cu(s); 0.34
Fe²⁺(aq) + 2e⁻ ⟶ Fe(s); -0.41
Zn²⁺(aq) + 2e⁻ ⟶ Zn(s); -0.76
2. Possible Voltaic cells
(a) Zn/I₂
E°/V
Anode: Zn(s) ⟶ Zn²⁺(aq) + 2e⁻; 0.76
Cathode: I₂(s) + 2e⁻ ⟶ 2I⁻(aq); 0.54
Cell: Zn(s) + I₂(s) ⟶ Zn²⁺(aq) + 2I⁻(aq); 1.30
Zn(s)|Zn²⁺(aq)∥I⁻(aq)|I₂(s)|C(s, graphite)
Zn is the anode; graphite is the cathode.
(b) Zn/Cu²⁺
E°/V
Anode: Zn(s) ⟶ Zn²⁺(aq) + 2e⁻; 0.76
Cathode: Cu²⁺(aq) + 2e⁻ ⟶ Cu(s); 0.34
Cell: Zn(s) + Cu²⁺(s) ⟶ Zn²⁺(aq) + Cu(s); 1.10
Zn(s)|Zn²⁺(aq)∥Cu²⁺(aq)|Cu(s)
Zn is the anode; Cu is the cathode.
(c) Zn/Fe²⁺
E°/V
Anode: Zn(s) ⟶ Zn²⁺(aq) + 2e⁻; 0.76
Cathode: Fe²⁺(aq) + 2e⁻ ⟶ Fe(s); -0.41
Cell: Zn(s) + Fe²⁺(s) ⟶ Zn²⁺(aq) + Fe(s); 0.35
Zn(s)|Zn²⁺(aq)∥Fe²⁺(aq)|Fe(s)
Zn is the anode; Fe is the cathode.
(d) Fe/I₂
E°/V
Anode: Fe(s) ⟶ Fe²⁺(aq) + 2e⁻; 0.41
Cathode: I₂(s) + 2e⁻ ⟶ 2I⁻(aq); 0.54
Cell: Zn(s) + I₂(s) ⟶ Zn²⁺(aq) + 2I⁻(aq); 0.95
Fe(s)|Fe²⁺(aq)∥I⁻(aq)|I₂(s)|C(s, graphite)
Fe is the anode; graphite is the cathode.
The complex ion Fe(CN)63- is paramagnetic with one unpaired electron. The complex ion Fe(SCN)63- has five unpaired electrons. Where does SCN- lie in the spectrochemical series with respect to CN-?
Answer:
SCN- is a weak field ligand while CN- is a strong field ligand
Explanation:
The spectrochemical series is an arrangement of ligands according to their magnitude of crystal field splitting. Ligands that cause only a small degree of crystal field splitting are called weak field ligands while ligands that cause large crystal field splitting are called strong field ligands.
Strong field ligands often lead to the formation of low spin complexes with the least number of unpaired electrons while high spin complexes are formed by weak field ligands.
CN- is a strong field ligand as it lies towards the right hand side of the spectrochemical series.
SCN- is a weak field ligand hence it forms a high spin complex having the maximum number of unpaired electrons for Fe^3+, hence the answer.
SCN⁻ lies in the lower (weak field) region of the spectrochemical series while CN⁻ lies in the higher (stronger field) region.
CN⁻ is a strong field ligand with a large splitting constant, and it is high up in the spectrochemical series.
Conversely, SCN⁻ is a weak field ligand with a low splitting constant, and it is lower in the spectrochemical series.
Hence, SCN⁻ lies in the lower (weak field) region of the spectrochemical series while CN⁻ lies in the higher (stronger field) region.
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Calculate the pH of a solution formed by mixing 250.0 mL of 0.15 M NH4Cl with 200.0 mL of 0.12 M NH3. The Kb for NH3 is 1.8 × 10-5.
Answer:
The pH of the solution is 9.06.
Explanation:
The reaction of the dissociation of NH₃ in water is:
NH₃(aq) + H₂O(l) ⇄ NH₄⁺(aq) + OH⁻(aq) (1)
[NH₃] - x [NH₄⁺] + x x
The concentration of NH₃ and NH₄⁺ is:
[tex] [NH_{3}] = \frac{n_{NH_{3}}}{V_{T}} = \frac{C_{i}_{(NH_{3})}*Vi_{NH_{3}}}{V_{NH_{3}} + V_{NH_{4}^{+}}} = \frac{0.12 M*0.2 L}{0.2 L + 0.25 L} = 0.053 M [/tex]
[tex] [NH_{4}^{+}] = \frac{C_{i}_{(NH_{4}^{+})*V_{NH_{4}^{+}}}}{V_{NH_{3}} + V_{NH_{4}^{+}}} = \frac{0.15 M*0.25 L}{0.2 L + 0.25 L} = 0.083 M [/tex]
From equation (1) we have:
[tex]Kb = \frac{[NH_{4}^{+}][OH^{-}]}{[NH_{3}]}[/tex]
[tex] 1.8 \cdot 10^{-5} = \frac{(0.083 + x)*x}{0.053 - x} [/tex]
[tex] 1.8 \cdot 10^{-5}(0.053 - x) - (0.083 + x)*x = 0 [/tex]
By solving the above equation for x we have:
x = 1.15x10⁻⁵ = [OH⁻]
The pH of the solution is:
[tex] pOH = -log([OH^{-}]) = -log(1.15 \cdot 10^{-5}) = 4.94 [/tex]
[tex] pH = 14 - pOH = 14 - 4.94 = 9.06 [/tex]
Therefore, the pH of the solution is 9.06.
I hope it helps you!
Testbank Question 47 Consider the molecular orbital model of benzene. In the ground state how many molecular orbitals are filled with electrons?
Answer:
There are fifteen molecular orbitals in benzene filled with electrons.
Explanation:
Benzene is an aromatic compound. Let us consider the number of bonding molecular orbitals that should be present in the molecule;
There are 6 C-C σ bonds, these will occupy six bonding molecular orbitals filled with electrons.
There are 6 C-H σ bonds, these will occupy another six molecular orbitals filled with electrons
The are 3 C=C π bonds., these will occupy three bonding molecular pi orbitals.
All these bring the total number of bonding molecular orbitals filled with electrons to fifteen bonding molecular orbitals.
A compound is found to contain 29.68 % sulfur and 70.32 % fluorine by mass. What is the empirical formula for this compound?
Answer:
[tex]SF_4[/tex]
Explanation:
The first thing would be to calculate the number of moles of each element in the compound.
No of moles of sulfur (S) = mass/molar mass
= 29.68/32.065 = 0.9256
No of moles of fluorine (F) = mass/molar mass
= 70.32/18.998 = 3.7014
Then, let us find the atomic ratio of each of the element in the compound by dividing by the no of moles by the smallest no of mole:
S : F
[tex]\frac{0.9256}{0.9256}[/tex] = 1 : [tex]\frac{3.7014}{0.9256}[/tex] = 4
Therefore, the empirical formula for the compound is [tex]SF_4[/tex]
At standard temperature and pressure conditions, the volume of an ideal gas contained in a jar is 55.3 L. How many molecules are in the jar. This question is to be answered in scientific notation.(eg. 1.5 e5)
Answer:
1.49e24
Explanation:
Standars temperature and pressure are 273.15K and 1atm, respectively.
Using ideal gas law, we can find moles of an ideal gas if we know its pressure, temperature and volume as follows:
PV = nRT
PV / RT = n
Where P is pressure (1atm), V is volume (55.3L), R is gas constant (0.082atmL/molK), T is temperature (273.15K) and n moles of the ideal gas.
Replacing:
PV / RT = n
1atm*55.3L / 0.082atmL/molK*273.15K = n
2.47 moles = n
Now, the question is about the number of molecules in the jar. By definition, 1 mole = 6.022x10²³ molecules.
As we have 2.47 moles:
2.47 mol × (6.022x10²³ molecules / 1 mole) =
1.49x10²⁴ molecules that are in the jar
In scientific notation:
1.49e24