Write any two drawbacks of the octet theory.​

Answer: The ion that contribute to water hardness are:

--> a. Ca2+

--> b. (HCO)3^- and

--> c. Mg2+

While K+ DOES NOT contribute to water hardness.

Explanation:

WATER in chemistry is known as a universal solvent. This is so because it is polar in nature and dissolves most inorganic solutes and some polar organic solutes to form aqueous solutions. It is composed of elements such as hydrogen and oxygen in the combined ratio of 2:1.

Water is said to be HARD if it does not lather readily with soap. There are two types of water hardness:

--> Permanent hardness: This is mainly due to the presence of CALCIUM and MAGNESIUM ions in the form of soluble tetraoxosulphate(VI) and chlorides. These ions are removed by adding washing soda or caustic soda.

--> Temporary hardness: This is due to the presence of calcium HYDROGENTRIOXOCARBONATES. It can be removed by boiling and using slaked lime.

Therefore from the above given ions, Ca2+,(HCO)3^- and Mg2+ contributes to water hardness.

Answer:

For the neutralization reaction between pyridine and propanoic acid, draw curved arrows to indicate the direction of electron flow.

Draw curved arrows to show the movement of electrons in this step of the mechanism.

Explanation:

According to Bronsted acid-base theory, an acid is a substance which is a proton donor.

Base is the proton acceptor.

In the given example, acid is propanoic acid and it loses the proton.

Pyridine is the base and it accepts the proton from propanoic acid.

The entire reaction is shown below:

Answer:

Reactions involving the replacement of one atom or group of atoms. - Substitution reaction

Reactions involving removal of two atoms or groups from a molecule - Elimination reaction

Products show increased bond order between two adjacent atoms - Elimination reaction

Reactant requires presence of a π bond - Addition reaction

Product is the structural isomer of the reactant - Rearrangement reaction

Explanation:

When an atom or a group of atoms is replaced by another in a reaction, then such is a substitution reaction. A typical example is the halogenation of alkanes.

A reaction involving the removal of two atoms or groups from a molecule resulting in increased bond order of products is called an elimination reaction. A typical example of such is dehydrohalogenation of alkyl halides.

Any reaction that involves a pi bond is an addition reaction because a molecule is added across the pi bond. A typical example is hydrogenation of alkenes.

Rearrangement reactions yield isomers of a molecule. Rearrangement may involve alkyl or hydride shifts in molecules.

Reactions involving the replacement of one atom or group of atoms is substitution reaction, reactions involving removal of two atoms or groups from a molecule and products show increased bond order between two adjacent atoms is elimination reaction, reactant requires presence of a π bond in addition reaction and product is the structural isomer of the reactant is rearrangement reaction.

Chemical reactions are those reactions in which reactants undergoes through a variety of changes for the formation of new product.

Hence, classification of above points are done according to their characteristics.

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Answer:

33.8 g Solution

Explanation:

A chemistry student needs 15.0 g of methanol for an experiment. The concentration of ethanol in the solution is 44.4% w/w, that is, there are 44.4 g of methanol every 100 g of solution. The mass of solution that would contain 15.0 g of methanol is:

15.0 g Methanol × 100 g Solution/44.4 g Methanol = 33.8 g Solution

Since 33.8 g are required and 320. g are available, there is enough solution for the requirements.

Answer:

hi I used your code you got it

Answer: The molecule [tex]CH_{3}-CH_{3}[/tex] is expected to have a dipole moment of zero.

Explanation:

The product of magnitude of the charge calculated in electrostatic units is called dipole moment.

Formula for dipole moment is as follows.

Dipole moment = Charge (in esu) [tex]\times[/tex] distance (in cm)

Non-polar molecules have zero dipole moment.

For example, [tex]CH_{3}-CH_{3}[/tex] is a non-polar molecule so its dipole moment is zero.

[tex]H_{2}C=O[/tex] is a polar molecule so it will have dipole moment.

[tex]CH_{2}Cl_{2}[/tex] is a polar molecule so it will have dipole moment.

[tex]NH_{3}[/tex] has nitrogen atom as more electronegative than hydrogen atom. So, net dipole moment will be in the direction of nitrogen atom.

Thus, we can conclude that the molecule [tex]CH_{3}-CH_{3}[/tex] is expected to have a dipole moment of zero.

Answer:

The most stable conformation of the following compound has

A. An axial methyl group and an axial ethyl group.

B. An axial methyl group and an equatorial ethyl group.

C. An axial tert-butyl group.

D. An equatorial methyl group and an equatorial ethyl group.

E. An equatorial methyl group and an axial ethyl group.

Explanation:

The most stable conformation in the cyclohexane ring is the one in which both the substituents are in the equatorial position.

Among the given options,

option D  An equatorial methyl group and an equatorial ethyl group.

When the substituents in the cyclohexane ring are in equatorial positions then, the steric repulsions will be reduced.

Answer is option D.

Answer:

For (a): The moles of Ar is 16.94 moles

For (b): The moles of [tex]Cl_2[/tex] is 16.94 moles

For (c): The total number of moles in a tank is 23.47 moles

For (d): The mole fraction of Ar is 0.722

For (e): The mole fraction of [tex]Cl_2[/tex] is 0.278

For (f): The partial pressure of Ar is 2.888 atm

For (g): The partial pressure of [tex]Cl_2[/tex] is 1.112 atm

Explanation:

The number of moles is defined as the ratio of the mass of a substance to its molar mass.  The equation used is:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex] ......(1)

Given mass of Ar = 675.5 g

Molar mass of Ar = 39.95 g/mol

Plugging values in equation 1:

[tex]\text{Moles of Ar}=\frac{675.5g}{39.95g/mol}=16.91 mol[/tex]

Given mass of [tex]Cl_2[/tex] = 465.0 g

Molar mass of [tex]Cl_2[/tex] = 70.9 g/mol

Plugging values in equation 1:

[tex]\text{Moles of }Cl_2=\frac{465.0g}{70.9g/mol}=6.56 mol[/tex]

Total moles of gas in the tank = [16.91 + 6.56] mol = 23.47 mol

Mole fraction is defined as the moles of a component present in the total moles of a solution. It is given by the equation:

[tex]\chi_A=\frac{n_A}{n_A+n_B}[/tex]        .....(2)

where n is the number of moles

Moles of Ar = 16.94 moles

Total moles of gas in the tank = 23.47 mol

Putting values in equation 2, we get:

[tex]\chi_{Ar}=\frac{16.94}{23.47}\\\\\chi_{Ar}=0.722[/tex]

Total mole fraction of the system is always 1

Mole fraction of [tex]Cl_2[/tex] = [1 - 0.722] = 0.278

Raoult's law is the law used to calculate the partial pressure of the individual gases present in the mixture.

The equation for Raoult's law follows:

[tex]p_A=\chi_A\times p_T[/tex]                  .....(3)

where [tex]p_A[/tex] is the partial pressure of component A in the mixture and [tex]p_T[/tex] is the total partial pressure of the mixture

We are given:

[tex]\chi_{Ar}=0.722\\p_T=4.00atm[/tex]

Putting values in equation 3, we get:

[tex]p_{Ar}=0.722\times 4.00atm\\\\p_{Ar}=2.888atm[/tex]

We are given:

[tex]\chi_{Cl_2}=0.278\\p_T=4.00atm[/tex]

Putting values in equation 3, we get:

[tex]p_{Cl_2}=0.278\times 4.00atm\\\\p_{Cl_2}=1.112atm[/tex]

The question is incomplete, the complete question is;

Groups of the periodic table correspond to elements with a. the same color b. the same atomic number c. similar chemical properties d. similar numbers of neutrons

Answer:

similar chemical properties

Explanation:

In the periodic classification of elements, elements are divided into groups and periods. Elements in the same group of the periodic table have the same number of outermost electrons and share very similar chemical properties.

Elements in the same period have the same number of shells and the same maximum energy level of the outermost electron. Chemical properties carry markedly across a period.

Answer:

Mg will be the limiting reagent.

Explanation:

The balanced reaction is:

Mg + 2 HCl → MgCl₂ + H₂

By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

Being the molar mass of each compound:

By reaction stoichiometry, the following mass quantities of each compound participate in the reaction:

0.0350 g of Mg is reacted with 10.00 mL (equal to 0.01 L) of 6 M HCl.

Molarity being the number of moles of solute that are dissolved in a certain volume, expressed as:

[tex]Molarity=\frac{number of moles of solute}{volume}[/tex]

in units [tex]\frac{moles}{liter}[/tex]

then, the number of moles of HCl that react is:

[tex]6 M=\frac{number of moles of HCl}{0.01 L}[/tex]

number of moles of HCl= 6 M*0.01 L

number of moles of HCl= 0.06 moles

Then you can apply the following rule of three: if by stoichiometry 2 moles of HCl react with 24.3 grams of Mg, 0.06 moles of HCl react with how much mass of Mg?

[tex]mass of Mg=\frac{0.06 moles of HCl* 24.3 grams of Mg}{2 moles of HCl}[/tex]

mass of Mg= 0.729 grams

But 0.729 grams of Mg are not available, 0.0350 grams are available. Since you have less mass than you need to react with 0.06 moles of HCl, Mg will be the limiting reagent.

The limiting reactant in the reaction is Magnesium (Mg)

From the question,

We are to determine the limiting reactant in the reaction.

The given balanced chemical equation for the reaction is

Mg(s) + 2HCl(aq) → MgCl₂(aq) + H₂(g)

This means

1 mole of Mg is required to react completely with 2 moles of HCl

Now, we will determine the number of moles of each reactant present

Mass = 0.0350 g

Using the formula

[tex]Number\ of\ moles = \frac{Mass}{Atomic\ mass}[/tex]

Atomic mass of Mg = 24.305 g/mol

∴ Number of moles of Mg present = [tex]\frac{0.0350}{24.305}[/tex]

Number of moles of Mg present = 0.00144 mole

Concentration = 6M

Volume = 10.00 mL = 0.01 L

Using the formula

Number of moles = Concentration × Volume

∴ Number of moles HCl present = 6 × 0.01

Number of moles HCl present = 0.06 mole

Since,

1 mole of Mg is required to react completely with 2 moles of HCl

Then

0.00144 mole of Mg is required to react completely with 2×0.00144 mole of HCl

2×0.00144 = 0.00288

∴ The number of moles of HCl required to react completely with the Mg is 0.00288 mole

Since the number of moles of HCl present is more than 0.00288 mole, then HCl is the excess reactant and Mg is the limiting reactant.

Hence, the limiting reactant in the reaction is Magnesium (Mg)

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Answer:

aasjajiakjka

Explanation:

Answer: The molarity of NaCl solution is 0.0489 M

Explanation:

Molarity is defined as the amount of solute expressed in the number of moles present per liter of solution. The units of molarity are mol/L. The formula used to calculate molarity:

[tex]\text{Molarity of solution}=\frac{\text{Given mass of solute}\times 1000}{\text{Molar mass of solute}\times \text{Volume of solution (mL)}}[/tex] .....(1)

We are given:

Given mass of NaCl = 0.8 g

Molar mass of NaCl = 58.44 g/mol

Volume of the solution = 280 mL

Putting values in equation 1, we get:

[tex]\text{Molarity of solution}=\frac{0.8\times 1000}{58.44\times 280}\\\\\text{Molarity of solution}=0.0489M[/tex]

Hence, the molarity of NaCl solution is 0.0489 M

Answer:

Explanation:

[H+] = 0.1x0.03x2 + 0.2x0.03 = 0.012 mol

[OH-] = 0.001x0.05x2 = 0.0001 mol

=> [H+] dư = 0.012 - 0.0001 =0.0119 mol

pH = -log[H+] = 1.92

Answer:

See explanation.

Explanation:

Hello there!

In this case, since this problem  is about gas laws, more specifically about the Gay-Lussac's one since the volume is said to be constant, we can use the following equation for its solution for the final pressure, P2:

[tex]\frac{P_2}{T_2} = \frac{P_1}{T_1}[/tex]

[tex]P_2= \frac{P_1T_2}{T_1}\\\\P_2 =\frac{12.0atm*450K}{300K}\\\\P_2= 18.0atm[/tex]

Thus, we fill in the table as follows:

                           Initial        Final

Pressure           12.0 atm     18.0 atm

Volume                4.0 L         4.0 L

Temperature      300K         450K

Regards!

Answer:

Aldehydes and Ketones

Both aldehydes and ketones contain a carbonyl group, a functional group with a carbon-oxygen double bond. The names for aldehyde and ketone compounds are derived using similar nomenclature rules as for alkanes and alcohols, and include the class-identifying suffixes -al and -one, respectively:



In an aldehyde, the carbonyl group is bonded to at least one hydrogen atom. In a ketone, the carbonyl group is bonded to two carbon atoms:





As text, an aldehyde group is represented as –CHO; a ketone is represented as –C(O)– or –CO–.

In both aldehydes and ketones, the geometry around the carbon atom in the carbonyl group is trigonal planar; the carbon atom exhibits sp2 hybridization. Two of the sp2 orbitals on the carbon atom in the carbonyl group are used to form σ bonds to the other carbon or hydrogen atoms in a molecule. The remaining sp2 hybrid orbital forms a σ bond to the oxygen atom. The unhybridized p orbital on the carbon atom in the carbonyl group overlaps a p orbital on the oxygen atom to form the π bond in the double bond.

Like the C=OC=O bond in carbon dioxide, the C=OC=O bond of a carbonyl group is polar (recall that oxygen is significantly more electronegative than carbon, and the shared electrons are pulled toward the oxygen atom and away from the carbon atom). Many of the reactions of aldehydes and ketones start with the reaction between a Lewis base and the carbon atom at the positive end of the polar C=OC=O bond to yield an unstable intermediate that subsequently undergoes one or more structural rearrangements to form the final product (Figure 1).

Figure 1. The carbonyl group is polar, and the geometry of the bonds around the central carbon is trigonal planar.

The importance of molecular structure in the reactivity of organic compounds is illustrated by the reactions that produce aldehydes and ketones. We can prepare a carbonyl group by oxidation of an alcohol—for organic molecules, oxidation of a carbon atom is said to occur when a carbon-hydrogen bond is replaced by a carbon-oxygen bond. The reverse reaction—replacing a carbon-oxygen bond by a carbon-hydrogen bond—is a reduction of that carbon atom. Recall that oxygen is generally assigned a –2 oxidation number unless it is elemental or attached to a fluorine. Hydrogen is generally assigned an oxidation number of +1 unless it is attached to a metal. Since carbon does not have a specific rule, its oxidation number is determined algebraically by factoring the atoms it is attached to and the overall charge of the molecule or ion. In general, a carbon atom attached to an oxygen atom will have a more positive oxidation number and a carbon atom attached to a hydrogen atom will have a more negative oxidation number. This should fit nicely with your understanding of the polarity of C–O and C–H bonds. The other reagents and possible products of these reactions are beyond the scope of this chapter, so we will focus only on the changes to the carbon atoms:

Answer:

i think C  is the answer

Explanation:

The change in average annual temperatures on earth will be due to "photosynthesis by plants and algae".

Photosynthesis can be defined as a process in which plants, as well as other organisms, as well as other organisms, utilize to transform sunlight into chemical energy which can then be released to power the organism's activities using cellular respiration.

Plants seem to be mostly photosynthetic eukaryotes belonging to the plantae kingdom.

Therefore, photosynthesis cannot change in average annual temperature on Earth.

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Answer:

d

Explanation:

cuaase that it sirhal

The chemical formula PbCl₂(s) represented by:

A) a substance

The chemical formula PbCl₂(s) represents a substance. A substance is a single, pure chemical entity with a definite composition. It can be an element, a compound, or an alloy.

A solution is a homogeneous mixture of two or more substances. A homogeneous mixture is a mixture in which the components are evenly distributed throughout the mixture.

A heterogeneous mixture is a mixture in which the components are not evenly distributed throughout the mixture.

A reaction is a process in which one or more substances are transformed into one or more new substances.

Therefore, the chemical formula PbCl₂(s) represents a substance, and the answer is (A).

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Answer: The millimoles of potassium iodide the chemist has added to the flask is 522 millimoles.

Explanation:

Given: Volume of KI = 370.0 mL (1 mL = 0.001 L) = 0.37 L

Molarity of KI solution = 1.41 mol/L

Now, moles of KI (potassium iodide) is calculated as follows.

[tex]Moles = Volume \times Molarity \\= 0.37 L \times 1.41 M\\= 0.5217 mol[/tex]

Convert moles into millimoles as follows.

1 mol = 1000 millimoles

0.5217 mol = [tex]0.5217 mol \times \frac{1000 millimoles}{1 mol} = 521.7 millimoles[/tex]

This can be rounded off to the value 522 millimoles.

Thus, we can conclude that the millimoles of potassium iodide the chemist has added to the flask is 522 millimoles.

Answer: The mass of [tex](NH_4)_2SO_4[/tex] produced is 9910.5 g

Explanation:

Molarity is calculated by using the equation:

[tex]\text{Molarity}=\frac{\text{Moles}}{\text{Volume}}[/tex] ......(1)  

Molarity of [tex]H_2SO_4[/tex] = 3.0 M

Volume of solution = 25.0 L

Putting values in equation 1, we get:

[tex]\text{Moles of }H_2SO_4=(3.0mol/L\times 25.0L)=75mol[/tex]

The ideal gas equation is given as:

[tex]PV=nRT[/tex] .......(2)

where,

P = pressure of the gas = 0.68 atm

V = volume of gas = [tex]3.1\times 10^3L[/tex]

n = number of moles of gas = ? moles

R = Gas constant = 0.0821 L.atm/mol.K

T = temperature of the gas = 298 K

Putting values in equation 2, we get:

[tex]0.68atm\times 3.1\times 10^3L=n\times 0.0821L.atm/mol.K\times 298K\\\\n=\frac{0.68\times 3.1\times 10^3}{0.0821\times 298}=86.16mol[/tex]

For the given chemical equation:

[tex]NH_3(g)+H_2SO_4(aq)\rightarrow (NH_4)_2SO_4(aq)[/tex]

By stoichiometry of the reaction:

If 1 mole of [tex]H_2SO_4[/tex] reacts with 1 mole of [tex]NH_3[/tex]

So, 75 moles of [tex]H_2SO_4[/tex] will react with = [tex]\frac{1}{1}\times 75=75mol[/tex] of [tex]NH_3[/tex]

As the given amount of [tex]NH_3[/tex] is more than the required amount. Thus, it is present in excess and is considered as an excess reagent

Thus, [tex]H_2SO_4[/tex] is considered a limiting reagent because it limits the formation of the product.

By the stoichiometry of the reaction:

If 1 mole of [tex]H_2SO_4[/tex] produces 1 mole of [tex](NH_4)_2SO_4[/tex]

So, 75 moles of [tex]H_2SO_4[/tex] will produce = [tex]\frac{1}{1}\times 75=75mol[/tex] of [tex](NH_4)_2SO_4[/tex]

The number of moles is defined as the ratio of the mass of a substance to its molar mass. The equation used is:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]

We know, molar mass of [tex](NH_4)_2SO_4[/tex] = 132.14 g/mol

Putting values in above equation, we get:

[tex]\text{Mass of }(NH_4)_2SO_4=(75mol\times 132.14g/mol)=9910.5g[/tex]

Hence, the mass of [tex](NH_4)_2SO_4[/tex] produced is 9910.5 g

Answer: The correct option is C (One of the fatty acid salts was unsaturated, and it completely isomerized under the reaction conditions).

Explanation:

Fats and oils belongs to a general group of compounds known as lipids. Fatty acids are weak acid and are divided into two:

--> Saturated fatty acids: These have NO double bonds in their hydrocarbon chain, and

--> Unsaturated fatty acids: These have one or more double bonds in their hydrocarbon chain.

SAPONIFICATION is defined as the process by which fats and oil is hydrolyzed with caustic alkali to yield propane-1,2,3-triol and the corresponding sodium salt of the component fatty acids. During this process, One hydroxide ion is required to hydrolyze one ester linkage of a triacylglycerol molecule. Because there are three ester linkages in a triacylglycerol, three equivalents of sodium hydroxide will be needed to completely saponify the triacylglycerol. This explains the reason why saponification of the triacylglycerol iresulted in four different fatty acid salts.

Answer:

1.46 × 10⁻⁸ g

Explanation:

Step 1: Given data

Molecules of CO₂: 2.00 × 10¹⁴ molecules

Step 2: Convert molecules to moles

We need a conversion factor: Avogadro's number. There are 6.02 × 10²³ molecules in 1 mole of molecules.

2.00 × 10¹⁴ molecules × 1 mol/6.02 × 10²³ = 3.32 × 10⁻¹⁰ mol

Step 3: Convert moles to mass

We need a conversion factor: the molar mass. The molar mass of CO₂is 44.01 g/mol.

3.32 × 10⁻¹⁰ mol × 44.01 g/mol = 1.46 × 10⁻⁸ g

Answer:

bleh

Explanation:

Answer:

Magnesium reacts with dilute hydrochloric acid in a conical flask which is ... One student can add the magnesium ribbon to the acid and stopper the flask, ... 50 cm3 of 1M hydrochloric acid is a six-fold excess of acid.

Answer: Pair 1 has Mg and Sr, Pair 2 has Kr and Ne, Pair 3 has As and P.

Explanation:

A periodic table is a group of elements presented in a tabular form where elements are arranged in a series of 7 rows and 18 columns.

The vertical columns are known as groups and horizontal rows are known as periods.

The elements having similar chemical properties are arranged in one group.

Magnesium (Mg) is the 12th element of periodic table placed at Group 2 and Period 3

Strontium (Sr) is the 38th element of periodic table placed at Group 2 and Period 5

Krypton (Kr) is the 36th element of periodic table placed at Group 18 and Period 4

Neon (Ne) is the 10th element of periodic table placed at Group 18 and Period 2

Arsenic (As) is the 33rd element of periodic table placed at Group 15 and Period 4

Phosphorus (P) is the 15th element of periodic table placed at Group 15 and Period 3

As magnesium and strontium are present in the same group, they will have similar chemical properties. Similarly, krypton and neon will form the second pair. Likewise, arsenic and phosphorus will form a pair.

Hence, Pair 1 has Mg and Sr, Pair 2 has Kr and Ne, Pair 3 has As and P.

Answer:

C) isoleucine

Explanation:

Isoleucine is among nine necessary amino acids in humans (found in dietary proteins). It has a variety of physiological activities, including aiding tissue repair, nitrogenous waste detoxification, immunological stimulation, and hormonal production promotion. When attached at a binding site, they are capable of providing a side chain thereby increasing the hydrophobicity at the binding site.

The answer ( 13 and 8 )

x²=5²+12²

x²=25+144

x²=169

x=13

x²=5²+6²

x²=25+36

x²=61

x=7.8

x=8

Answer: Pressure of the gas is 0.129375 atm when the volume of the vessel increased by a factor of 16.00.

Explanation:

The formula for ideal gas equation is as follows.

[tex]PV = Nk_{b}T[/tex]

where,

[tex]k_{b}[/tex] = Boltzmann constant

N = number of moles

That can also be written as:

[tex]\frac{PV}{T} = constant[/tex]

As pressure and volume are inversely proportional to each other. So, if one of the state variable is increased then the other one will decrease or vice-versa.

So, if volume of the vessel increased by a factor of 16.00 then it means pressure is decreased by a factor of 16.00

Therefore, final volume is as follows.

[tex]65.8 L \times 16.00\\= 1052.8 L[/tex]

Now, final pressure is as follows.

[tex]\frac{2.07}{16.00}\\= 0.129375 atm[/tex]

Initially the product of pressure and volume is as follows.

[tex]PV = 2.07 \times 65.8\\= 136.206[/tex]

Hence, if volume of the vessel increased by a factor of 16.00 and pressure is decreased by a factor of 16.00 then its product is as follows.

[tex]PV = 0.129375 \times 1052.8\\= 136.206[/tex]

Here, product of pressure and volume remains the same.

Thus, we can conclude that pressure of the gas is 0.129375 atm when the volume of the vessel increased by a factor of 16.00.