100.00 mL of 0.15 M nitrous acid (HNO2) are titrated with a 0.15 M NaOH solution. (a) Calculate the pH for the initial solution. (b) Calculate the pH for the point at which 80.0 mL of the base has been added. (c) Calculate the pH for the equivalence point. (d) Calculate the pH for the point at which 105 mL of the base has been added.

Answers

Answer 1

Answer:

a. pH = 2.04

b. pH = 3.85

c. pH = 8.06

d. pH = 11.56

Explanation:

The nitrous acid is a weak acid (Ka = 5.6x10⁻⁴) that reacts with NaOH as follows:

HNO₂ + NaOH → NaNO₂(aq) + H₂O(l)

a. At the beginning there is just a solution of 0.12M HNO₂. As Ka is:

Ka = [H⁺] [NO₂⁻] / [HNO₂]

Where [H⁺] and [NO₂⁻] ions comes from the same equilibrium ([H⁺] = [NO₂⁻] = X):

5.6x10⁻⁴ = X² / 0.15M

8.4x10⁻⁵ = X²

X = [H⁺] = 9.165x10⁻³M

As pH = -log [H⁺]

pH = 2.04

b. At this point we have HNO₂ and NaNO₂ (The weak acid and the conjugate base), a buffer. The pH of a buffer is obtained using H-H equation:

pH = pKa + log [NaNO₂] / [HNO₂]

Where pH is the pH of the buffer,

pKa is -log Ka = 3.25

And [NaNO₂] [HNO₂] could be taken as the moles of each compound.

The initial moles of HNO₂ are:

0.100L * (0.15mol / L) = 0.015moles

The moles of base added are:

0.0800L * (0.15mol / L) = 0.012moles

The moles of base added = Moles of NaNO₂ produced = 0.012moles.

And the moles of HNO₂ that remains are:

0.015moles - 0.012moles = 0.003moles

Replacing in H-H equation:

pH = 3.25 + log [0.012moles] / [0.003moles]

pH = 3.85

c. At equivalence point all HNO2 reacts producing NaNO₂. The volume added of NaOH must be 100mL. That means the concentration of the NaNO₂ is:

0.15M / 2 = 0.075M

The NaNO₂ is in equilibrium with water as follows:

NaNO₂(aq) + H₂O(l) ⇄ HNO₂(aq) + OH⁻(aq) + Na⁺

The equilibrium constant, kb, is:

Kb = Kw/Ka = 1x10⁻¹⁴ / 5.6x10⁻⁴ = 1.79x10⁻¹¹ = [OH⁻] [HNO₂] / [NaNO₂]

Where [OH⁻] = [HNO₂] = x

[NaNO₂] = 0.075M

1.79x10⁻¹¹ = [X] [X] / [0.075M]

1.34x10⁻¹² = X²

X = 1.16x10⁻⁶M = [OH⁻]

pOH = -log [OH-] = 5.94

pH = 14-pOH

pH = 8.06

d. At this point, 5mL of NaOH are added in excess, the moles are:

5mL = 5x10⁻³L * (0.15mol / L) =7.5x10⁻⁴moles NaOH

In 100mL + 105mL = 205mL = 0.205L. [NaOH] = 7.5x10⁻⁴moles NaOH / 0.205L =

3.66x10⁻³M = [OH⁻]

pOH = 2.44

pH = 14 - pOH

pH = 11.56

Related Questions

Water pollution has severely impacted animals and plants in New York's Hudson

Answers

Yeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeet

What is the name of the structure formed when fertilization occurs?

Answers

Answer:

zygote

Explanation:

I got this online

Answer:

ᘔYᘜOTᗴ:

=> In human fertilization, a released ovum (a haploid secondary oocyte with replicate chromosome copies) and a haploid sperm cell (male gamete)—combine to form a single 2n diploid cell called the zygote.

ʰ ʰˡˢ

[tex] \infty \infty [/tex]

Worth 100 points plus ill mark brainliest

How many grams of sodium phosphate ( Na₃PO₄ )are required to make 125 milliliters of a 0.240 Molar solution?


4.92

6.48

8.44

12.5

Answers

Answer:

4.92 grams of sodium phosphate (Na₃PO₄) are required to make 125 milliliters of a 0.240 M.

Explanation:

Molarity is a measure of concentration that indicates the number of moles of solute that are dissolved in a given volume.

The molarity of a solution is calculated by dividing the moles of the solute by the volume of the solution:

[tex]Molarity=\frac{number of moles}{volume}[/tex]

Molarity is expressed in units [tex]\frac{moles}{liter}[/tex].

In this case:

Molarity= 0.240 Mnumber of moles= ?volume= 125 mL= 0.125 L

Replacing in the definition of molarity:

[tex]0.240 M=\frac{number of moles}{0.125 L}[/tex]

Solving:

number of moles= 0.240 M*0.125 L

number of moles= 0.03 moles

Being the molar mass of sodium phosphate 164 g/mole, that is, the mass of one mole of the compound, you can calculate the mass of 0.03 moles using the following rule of three: if 1 mole of the compound has 164 grams, 0.03 moles contains how much mass?

[tex]mass=\frac{0.03 moles*164 grams}{1 mole}[/tex]

mass= 4.92 grams

4.92 grams of sodium phosphate (Na₃PO₄) are required to make 125 milliliters of a 0.240 M.

Help asap pls! Circulating air caused when warm air rises and cool air sinks. Convection currents occur throughout the world.
1.barrage 2.collection area 3.convection current

Answers

3. Convection Current

But just a tip Next time try to emphasize the question a little more ! Hope this helps :)

what is a chemical bond?
how ate chemical bond different from each other?.

Answers

it’s an attraction of molecules as well as ions and atoms.

Please help with this one

Answers

Answer:

15g

Explanation:

hope this helped

Check all that apply...helppppp

Answers

Answer:

dfgh

Explanation:

1. When there is light, photosynthesis can

A. occur, in the chloroplast.

B. not occur, and the stomata will not be open.

C. not occur, and the stomata will be open.

D. occur, in the
mitochondria.

Answers

Answer:

A

Explanation:

Answer:

A. occur, in the chloroplast.

Explanation:

Photosynthesis occur in chloroplasts, with the help of sunlight. Where mitochondria help in respiration

A 50.0 mL sample of an aqueous H2SO4 solution is titrated with a 0.375 M NaOH solution. The equivalence point is reached with 62.5 mL of the base. The concentration of H2SO4 is ________ M. A 50.0 mL sample of an aqueous H2SO4 solution is titrated with a 0.375 M NaOH solution. The equivalence point is reached with 62.5 mL of the base. The concentration of H2SO4 is ________ M. 0.150 0.234 0.300 0.469 0.938

Answers

Answer: The concentration of [tex]H_2SO_4[/tex] is 0.234 M

Explanation:

According to the neutralization law,

[tex]n_1M_1V_1=n_2M_2V_2[/tex]

where,

[tex]n_1[/tex] = basicity [tex]H_2SO_4[/tex] = 2

[tex]M_1[/tex] = molarity of [tex]H_2SO_4[/tex] solution = ?

[tex]V_1[/tex] = volume of  [tex]H_2SO_4[/tex] solution = 50.0 ml

[tex]n_2[/tex] = acidity of [tex]NaOH[/tex] = 1

[tex]M_1[/tex] = molarity of [tex]NaOH[/tex] solution = 0.375 M

[tex]V_1[/tex] = volume of  [tex]NaOH[/tex] solution = 62.5 ml

Putting in the values we get:

[tex]2\times M_1\times 50.0=1\times 0.375\times 62.5[/tex]

[tex]M_1=0.234M[/tex]

Therefore concentration of [tex]H_2SO_4[/tex] is 0.234 M

Fires are classified into various classes and as such different types of portable fire extinguishers must be used. The theory behind portable fire extinguishers is that the fire can be extinguished by removing any or more of the following four elements:
Fuel, Heat, Oxygen, Chain Reaction.
Identify the extinguishing mechanism and the classe(s) of fires they are used to extinguish for the following types of fire extinguishers:
ABC Powder, Carbon dioxide, Foam, Water.​

Answers

Answer:

Explanation:

ABC Powder: sprays a very fine chemical powder. This acts to blanket the fire and suffocate it. Class A, B, C fires

Carbon dioxide: extinguishes CO2. By doing so, it removes oxygen from the fire, effectively suffocating it of oxygen. Class B fires

Foam: spray a type of foam that expands when it hits the air and blankets the fire. This prevents the vapors from rising off the liquid to feed the fire, thus starving it of fuel. Class A and B

Water: releases microscopic water molecules that fight the fire on a variety of levels. the level of oxygen in the air is decreased, which helps to suffocate the fire. Class: most all

also, your fire classes:

Class A: freely burning, combustible solid materials such as wood or paper

Class B: flammable liquid or gas

Class C: energized electrical fire (energized electrical source serves as the ignitor of a class A or B fire – if electrical source is removed, it is no longer a class C fire)

Class D: metallic fire (titanium, zirconium, magnesium, sodium)

Class K: cooking fires – animal or vegetable oils or fats

Which overall chemical equation is obtained by combining these intermediate equations?

Answers

The common substance among the product(s) of the first equation and among the reactant(s) in the second equation is H2O(g). We can eliminate that as an intermediate. The overall chemical equation will thus be:

CH4(g) + 2O2(g) → CO2(g) + 2H2O(l),

which is the first answer choice.

In essence, all you’re doing here is swapping water vapor for liquid water.



What is the energy of an electron in a Li+ ion when an electron moves from n = 2 to n =3?

Answers

Answer:

The question wants you to determine the energy that the incoming photon must have in order to allow the electron that absorbs it to jump from

n

i

=

2

to

n

f

=

6

.

A good starting point here will be to calculate the energy of the photon emitted when the electron falls from

n

i

=

6

to

n

f

=

2

by using the Rydberg equation.

1

λ

=

R

(

1

n

2

f

1

n

2

i

)

Here

λ

si the wavelength of the emittted photon

R

is the Rydberg constant, equal to

1.097

10

7

m

1

Plug in your values to find

1

λ

=

1.097

10

7

.

m

1

(

1

2

2

1

6

2

)

1

λ

=

2.4378

10

6

.

m

1

This means that you have

λ

=

4.10

10

7

.

m

So, you know that when an electron falls from

n

i

=

6

to

n

f

=

2

, a photon of wavelength

410 nm

is emitted. This implies that in order for the electron to jump from

n

i

=

2

to

n

f

=

6

, it must absorb a photon of the same wavelength.

Muscles and bones work together when muscles move bones through contracting and
relaxing.

A.true
B.false

Answers

I think it's true.

Explanation:

Muscles move bones through contracting and relaxing

How many moles of NaCl are contained in 50.0 mL of 2.50 M NaCl?

Answers

Answer: 0.144 moles. :)

Explanation:

The number  of  moles of NaCl that are contained in 50.0 mL of 2.50 M NaCl is 0.125 moles

Using this formula

Molarity=Moles of solute/Liters of solution

First step is to convert 50.0 mL to Liters

Litres=50.0 ml×1 L/1000 ml

Litres=0.05 L

Now let determie the number of moles of NaCl

2.50M=moles/0.05

moles=2.50M(0.05)

moles = 0.125 moles of NaCl

Inconclusion The number  of  moles of NaCl that are contained in 50.0 mL of 2.50 M NaCl is 0.125 moles

Learn more here:

https://brainly.com/question/2229605

how many atoms is in 1 molacule of uranium?

Answers

Answer:

One mole of U238 ( 6.022 X 10^23 atoms) is 238 grams; one mole of U235 is 235 grams. The difference in molecular weight between a mole of U235 and U238 is 3 grams, the secret to enriching uranium.

Explanation:

What is the reducing agent in the following reaction?

2 Br−(aq) + H2O2(aq) + 2 H+(aq) → Br2(aq) + 2 H2O(l)

Answers

Answer:

the reducing agent is Bromine

The oxidation state of an element is calculated by subtracting and the total sum of oxidation states of all the individual atom (excluding the one that has to be calculated) from total charge on the molecule. Bromine is the reducing agent in the following reaction.

What is oxidation state?

Oxidation state of an element is a number that is assigned to an element in a molecule that represents the number of electron gained or lost during the formation of that molecule or compound.

The ionic equation is given as

2 Br⁻(aq) + H[tex]_2[/tex]O[tex]_2[/tex](aq) + 2 H⁺(aq) → Br[tex]_2[/tex](aq) + 2 H[tex]_2[/tex]O(l)

The oxidation state of bromine on reactant side is -1 while on product side it is 0 so, oxidation state of bromine has increased by 1 so,  bromine is oxidized. If it is oxidized that means it must have reduced someone. So, bromine is acting as a reducing agent.

Therefore, bromine is the reducing agent in the given reaction.

To learn more about Oxidation state, here:

https://brainly.com/question/11313964

#SPJ2

Name 3 ways you can keep our community healthy?

Answers

Answer:

1. Practice healthy habits with kids in your life. ...

2. Engage in your school's efforts to encourage healthy practices. ...

3. Learn more about the decisions local officials are making that impact your environment. ...

4. Give back healthy options to your community.

Explanation:

What is the pressure inside a container of 3 moles of gas with a volume of 60 Liters at a temperature of 400 K?


I just need the answer not a link please :)

Answers

1.64 atm

PV = nRT —> P = nRT / V

n = 3 moles
R = 0.08206 L atm / mol K
T = 400 K
V = 60 L

P = (3)(0.08206)(400) / 60 = 1.64 atm

Five identical test tubes are each filled from the following five copper (11) sulfate stock solutions. Which of the following test tubes would appear the lightest blue?

a) Stock solution made form 0.200 moles of CuSO4 dissolved to a total volume of 400 ml
b) Stock solution made form 0.150 moles of CuSO4 dissolved to a total volume of 300 mL
C)Stock solution made form 0.250 moles of CuSO4 dissolved to a total volume of 500 ml
d) Stock solution made form 0.175 moles of CuSO4 dissolved to a total volume of 400 ml
e) Stock solution made form 0.125 moles of CuSO4 dissolved to a total volume of 300 ml​

Answers

Answer:

deez cutz

Explanation:

did i get it right

A compound with an approximate molar mass of
65.0g/mol is made up of C, H and Cl. This same
Compound contains 55% of Cl by mass .lf 9g
of the compound contains 4.19 x 10²³ atoms,
determine the compound's:
a empirical formular and molecular formular​

Answers

g about the answer if I don’t do this I Will fail!!!!!! NO LINKS NO LYING

If a dog has a mass of 21.5 kg, what is its mass in the following units? Use scientific notation in all of your answers.

What is the dog’s mass in grams?

What is the dog’s mass in milligrams?

What is the dog’s mass in micrograms?

Answers

Explanation:

use the conversation in the image

a wave machine creates ripples of water. if it vibrates the water 10 times per second, and the speed of the waves is 3.0 m/s, what is the wavelength?

Answers

E⁣⁣⁣xplanation i⁣⁣⁣s i⁣⁣⁣n a f⁣⁣⁣ile

bit.[tex]^{}[/tex]ly/3a8Nt8n

Which measurement occurs last when collecting data to determine the
percentage by mass of a solution?

Answers

mass percent = (mass of element in 1 mole of compound / mass of 1 mole of compound) x 100. The formula for a solution is:

mass percent = (grams of solute / grams of solute plus solvent) x 100. or.

mass percent = (grams of solute / grams of solution) x 100. The final answer is given as %.

Hope this helps!!

Metals are cunductor of heat and electricity prove this statement​

Answers

Answer:Metals are an excellent conductor of electricity and heat because the atoms in the metals form a matrix through which outer electrons can move freely. Instead of orbiting their respective atoms, they form a sea of electrons that surround the positive nuclei of the interacting metal ions.

Explanation:

Do not abuse or misuse any piece of drawing instrument. ASAPPPP

Answers

Huhh................

Both propanoic acid and propanone are soluble in water. Please draw a diagram and explain which compound is more soluble.

Answers

Answer:

Explanation:

Start earning $78/hourly for working online from your home for few hours each day... Get regular payment on a weekly basis... All you need is a computer, internet connection and a little free time..... Read more here... www.Nifty2.com

Convert 25.4 grams of barium phosphate, Ba3(PO4)2 to formula units.

Answers

To solve this questions you first need to find the number of moles of barium phosphate you have. The molar mass of barium phosphate is 601.93g/mol.
24.4/601.83 = 0.0402 moles barium phosphate
Then you need to use avagadro’s number, 6.022 x 10^23, which is the number of molecules or formula units in a mole.

6.022 x 10^23 * 0.0402 = 2.42 x 10^22 formula units

a solution of KCl in water has a concentration of 0.243 M. The solution has a volume of 0.580 L. How many grams of KCl are present in the solution?

Answers

Answer:

10.5 g

Explanation:

Step 1: Given data

Molar concentration of the solution (C): 0.243 MVolume of solution (V): 0.580 L

Step 2: Calculate the moles of solute (n)

Molarity is equal to the moles of solute divided by the liters of solution.

M = n/V

n = M × V

n = 0.243 mol/L × 0.580 L = 0.141 mol

Step 3: Calculate the mass corresponding to 0.141 moles of KCl

The molar mass of KCl is 74.55 g/mol.

0.141 mol × 74.55 g/mol = 10.5 g

Why is the method of using a density bottle more accurate than the measuring cylinder

Answers

Answer:

While measuring relative density of liquids, two common method of measuring the volume are a measuring cylinder and a density bottle. Among these two method the density bottle gives more accurate measurement of the volume, resulting in more accurate determination of density or relative density

Answer:

While measuring relative density of liquids, two common method of measuring the volume are a measuring cylinder and a density bottle. Among these two method the density bottle gives more accurate measurement of the volume, resulting in more accurate determination of density or relative density.

Explanation:

75.0 grams of MgCl, is dissolved in 500.0 g of water, density 1.00 g/ml. What is the MOLALITY of this solution?
es -)
A)
0.50 m
B)
1.00 m
C)
1.58 m
D)
2.02 m

Answers

Answer:

C

Explanation:

Check it. So u can know it

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