15. You are interested in separating 4-methylbenzoic acid from 1,4-dimethoxybenzene using a procedure similar to the extraction procedure we used in lab. You plan to use sodium bicarbonate instead of sodium hydroxide. a) Show the reaction between salicylic acid and sodium bicarbonate. Label the acid, base, conjugate acid, conjugate base. b) Give the pKa values of the acid and conjugate acid. c) Which base will work better, sodium hydroxide or sodium bicarbonate

Answers

Answer 1

Solution :

a). The separation of 4-methylbenzoic acid from 1,4-dimethoxybenzene will work but it will result in lower recovery.

In the reaction of acid-base to form a sodium 4 - methoxy benzoate, that is soluble in the water, 4-methoxy benzoic acid reacts with the sodium bicarbonate to give sodium 4-methoxybenzoate as well as carbonic acid.

b). The pKa for the 4-methoxybenzoic acid is [tex]4.46[/tex], and that of carbonic acid is [tex]6.37[/tex]

c). The Keq for the reaction is [tex]10(6.37 - 4.46) = 101.91[/tex]

Therefore, the equilibrium lies to the right  and also the reaction favors the products and the separation works.

But the recovery will be low when compared to the extraction with Sodium hydroxide as the strong base will drive the equilibrium further to the right position, thus neutralizing all the acids virtually. And the weak base will partially neutralize the acid.


Related Questions

Oxygen and hydrogen are compressed into two cubical boxes of the same
size at a temperature of 28 K. What do these gases have in common
according to the kinetic theory?

Answers

Explanation:

Following are the kinetic theory of gases postulates:

1) Space-volume to molecules ratio is negligible.

2)There is no force of attraction between the molecules at normal temperature and pressure. The force of attraction between the molecules build when the temperature decreases and the pressure increases.

3) There is large space between the molecules resulting in continuous motion.

4) The free movement of molecules results in collision which is perfectly elastic.

5) The molecules have kinetic energy due to random movement. But the average kinetic energy of these molecules differs with temperature.

6) Molecules exert pressure on the walls of the container.

what is the difference between red phosphorus and white phosphorus?​

Answers

Answer:

White phosphorusRed PhosphorusIt is insoluble in water but soluble in carbon disulphide.It is insoluble in both water and carbon disulphide.It undergoes spontaneous combustion in air.It is relatively

Explanation:

I hope it will help you

4. A sample of ammonia, NH3, contains 3.3 x 1021 hydrogen atoms. How many NH; molecules are in this sample?​

Answers

Answer:

1.1 × 10²¹ NH₃ molecules

Explanation:

From the given information:

We were being told that the number of the hydrogen (H) atoms present in the sample of NH3 = 3.3 × 10²¹ hydrogen.

However, it signifies that each molecule of ammonia harbors 3hydrogen (H) atoms.

Hence,  the number of  molecules of NH₃ present;

[tex]\mathsf{=\dfrac{3.3\times 10^{21}}{3} \ molecules \ of \ {NH_3}}[/tex]

= 1.1 × 10²¹ NH₃ molecules

A(n) _____, used as part of the stationary phase, has an affinity for the solvent and the chemical components of the mixture. adsorbent eluent Rf factor chromatogram

Answers

The Adsorbent is used as part of the stationary phase and has an affinity for the solvent and the chemical components of the mixture.

The adsorbent has a high affinity for solvent and the chemical components of the mixture.

Chromatography is a method of separation in which the mixture of substances is introduced into a mobile phase (solvent). The separation occurs as the solvent interacts with an adsorbent(stationary phase).

The extent of separation of the components of the mixture depends on the extent of interaction between the mobile and the stationary phase . This interaction also determines the retention factor (Rf) of the separation.

For a definition of chromatography, see

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Net ionic reaction of H2SO4 with Ba(OH)2

Answers

Answer:

This is an acid-base reaction (neutralization): Ba(OH) 2 is a base, H 2SO 4 is an acid. This is a precipitation reaction: BaSO 4 is the formed precipitate.

Why is it difficult to classify dissolving as simply a physical or a chemical change? (1 point)
O Some substances keep the same molecular structure when they break down, and others do not.
O Some substances release energy when they dissolve, and some absorb energy.
O Some substances taste the same after they dissolve, and others do not.
O Some substances keep the same color when they dissolve, and others do not.

Answers

Answer:

It is difficult because of C

Explanation:

The correct answer is:Some substances keep the same molecular structure when they break down, and others do not.

Some substances change their form when they dissolve and some do not. Dissolution can sometimes be regarded as a sort of reaction between a chemical substance and water.

Usually, we can consider dissolution of a substance in water as a sort of chemical reaction for some substances. For instance, an ionic substance interacts with water to form ions. similarly, some salts become hydrolysed in water and give acidic/basic solutions as  result of that.

However, some substances do not interact with water upon dissolution. They rather remain as molecular entities because they are not composed of ions.

We can see that some substances keep the same molecular structure when they break down, and others do not keep the same molecular structure  when they dissolve hence it is difficult to classify dissolving as a physical or a chemical change.

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Which option is a physical property of matter?

A. acidity

B. reactivity

C. boiling point

D. flammability

Answers

Answer:

boiling point is the physial property of matter

The option that is showing the physical property of the matter is boiling point, the correct option is C.

What is physical property?

A physical property is any measurable property whose value describes the state of a physical system.

Changes in a system's physical properties can be used to describe its transitions between momentary states. Physical properties are also known as observables. They do not have modal properties.

Physical properties include color, phase, odor, and boiling point. Since reactivity with oxygen is dependent on the chemical nature of the object, it is not a physical property.

A compound's physical property is one that can be observed and measured. The chemical composition of a compound is unaffected by a physical property.

Thus, the correct option is C.

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If the Ksp of NaCl is experimentally determined to be 43.9, then what is the concentration of Na (in M) when it begins to crystallize out of solution

Answers

Answer:

6.63 M

Explanation:

NaCl(s) ---> Na^+(aq) + Cl^-(aq)

Given that [Na^+] = [Cl^-] = s

Where s= concentration of the both ions

Ksp = s^2

s= √Ksp

s= √43.9

s= 6.63 M

The concentration of Na (in M) obtained when it begins to crystallize out of solution is 6.63 M

What is solubility of product?

The solubility of product (Ksp) is defined as the concentration of products raised to their coefficient coefficients. This is illustrated below:

mX <=> nY + eZ

Ksp = [Y]^n × [Z]^e

Dissociation equation

NaCl(aq) → Na⁺(aq) + Cl¯(aq)

Let the concentration of Na⁺ be yLet the concentration of Cl¯ be y

How to determine the concentration of Na⁺ Solubility of product (Ksp) = 43.9Concentration of Cl¯ = yConcentration of Na⁺ = y =?

Ksp = [Na⁺] × [Cl¯]

43.9 =  y × y

43.9 = y²

Take the square root of both side

y = √43.9

y = 6.63 M

Thus, the concentration of Na⁺ is 6.63 M

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Write the complete ground-state electron configuration of I⁻.

Answers

Explanation:

here's the answer to your question

Iodine's neutral atom has the following electronic configuration: 1 s² 2 s² 2 p⁶ 3 s² 3 p⁶ 4 s² 3 d¹⁰ 4 p⁶ 5 s² 4 d¹⁰ 5 p⁵. The complete ground-state electron configuration of I⁻ is  [Kr]5s² 4d¹⁰ 5p⁶.

What is electronic configuration?

Electronic configuration is defined as each electron moves individually within an orbital while being surrounded by an average field produced by all other orbitals. The electron configuration is used to describe an atom's ground state orbitals, but it may also be used to depict an atom that has ionized into a cation or anion by making up for any lost or gained electrons in the orbitals after it.

The ground state electronic configuration is defined as the configuration of lower energy electrons surrounding an atom's nucleus. Ground state is defined as the least energetic state feasible for a physical system.  It is important because permits us to determine the location of the excited electrons' departure and return when they release a photon.

Thus, iodine's neutral atom has the following electronic configuration: 1 s² 2 s² 2 p⁶ 3 s² 3 p⁶ 4 s² 3 d¹⁰ 4 p⁶ 5 s² 4 d¹⁰ 5 p⁵. The complete ground-state electron configuration of I⁻ is  [Kr]5s² 4d¹⁰ 5p⁶.

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At 445oC, Kc for the following reaction is 0.020. 2 HI(g) <--> H2 (g) + I2 (g) A mixture of H2, I2, and HI in a vessel at 445oC has the following concentrations: [HI] = 1.5 M, [H2] = 2.50 M and [I2] = 0.05 M. Which one of the following statements concerning the reaction quotient, Qc, is TRUE for the above system?
a. Qc = Kc; the system is at equilibrium.
b. Qc is less than Kc; more H2 and I2 will be produced.
c. Qc is less than Kc; more HI will be produced.
d. Qc is greater than Kc; more HI will be produced.

Answers

Explanation:

The given balanced chemical equation is:

[tex]2 HI(g) <--> H_2 (g) + I_2 (g)[/tex]

The value of Kc at 445oC is 0.020.

[HI]=1.5M

[H2]=2.50M

[I2]=0.05M

The value of Qc(reaction quotient ) is calculated as shown below:

Qc has the same expression as the equilibrium constant.

[tex]Qc=\frac{[H_2][I_2]}{[HI]^2} \\Qc=(2.50Mx0.05M)/(1.5M)^2\\Qc=0.055[/tex]

Qc>Kc,

Hence, the backward reaction is favored and the formation of Hi is favored.

Among the given options, the correct answer is option d. Qc is greater than Kc; more HI will be produced.

what characterizes a homogeneous mixture?

Answers

Answer:

a mixture that doesn't really show the ingredients or things put into the material or food.

1. Explain the test for unsaturation.
2. Write down the balanced chemical equations for the complete and incomplete
combustion of octene
3. Explain how propanol, an alcohol, is formed from propene..
4. How is margarine formed?

Answers

Answer:

1)In organic chemistry, the bromine test is a qualitative test for the presence of unsaturation (carbon-to-carbon double or triple bonds), phenols and anilines. ... The more unsaturated an unknown is, the more bromine it reacts with, and the less coloured the solution will appear.

2)The equation for incomplete combustion of propane is: 2 C3H8 + 9 O2 → 4 CO2 + 2 CO + 8 H2O + Heat. If not enough oxygen is present for complete combustion, incomplete combustion occurs. The result of incomplete combustion is, once again, water vapour, carbon dioxide and heat. But it also produces carbon monoxide.

Explanation:

3)Propene, also known as propylene, is an unsaturated organic compound with the chemical formula {\displaystyle {\ce {CH3CH=CH2}}}. It has one double bond, and is the second simplest member of the alkene class of hydrocarbons. It is a colorless gas with a faint petroleum-like odor. 

Formula: C3H6

IUPAC ID: Propene

4)Margarines are chemically created during hydrogenation which, until January 1, 2006, relied upon trans fats to solidify their vegetable oils. Food companies have been exploring options for replacing trans fat in partially hydrogenated margarine.

chemistry
Which of the following is a characteristic of solid silver?
O A. High electrical conductivity
O B. Brittleness
C. Low melting point
O D. Good insulator
SUBM

Answers

Answer:

A. High electrical conductivity

Explanation:

solid silver isn't brittle, it has a high melting point, and its not a good insulator.

For which of the following reactions is the enthalpy change equal to the second ionization energy of nitrogen?

Answers

Answer:

"[tex]N^+(g) \rightarrow N^{2+}(g) + e^-[/tex]" is the appropriate answer.

Explanation:

Whenever one electron or particle must be removed from some kind of gas atom or molecule, it requires that the very first amount of energy necessary.Two electrons must be removed from such a mono-positive exhaust gases structure or position of ion before they may become a dipositive gaseous ion.

Thus the above is the correct answer.

tom pays 5 cents per minute to use his cell phone. Write an expression for the cost in cents of using his cell phone for minutes.

Answers

Answer:5m

Explanation:Because in the question it say per minute so it would be 5 times m

The fact that a beam of particles was deflected in the presence of an electric
or magnetic force led J.J. Thomson to conclude that the particles had a(n)
O A. large mass
B. electric charge
O C. negligible mass
O D. neutral charge

Answers

Answer:

electric charge

Explanation:

Charged particles are deflected in an electric or a magnetic field. The particles discovered by J.J. Thomson were charged particles.

When these charged particles are passed through electric and magnetic fields, deflection occurs depending on the nature of the charge.

A positive charge is deflected towards the negative part of an electric field or the south pole of a magnetic field.

A negative charge is selected towards the positive end of an electric field or the north pole of a magnetic field.

What 2 variables are needed to calculate the percent yield?

Answers

Answer:

isn’t it reactants and products?

Explanation:

Answer: reactants and products

Explanation:

Which are the following exothermic or endothermic

Absorbs Energy

-Hrxn

+Hrxn

Feels Hot

Heat flows from surrounds to Reaction

Not Energetically Favorable

Energetically Favorable

Releases Energy

Feels Cold

Heat flows from the reaction to the surrounds

Answers

Answer:

Explanation:

Your mom

How many oxygen atoms are there in 0.25 mole of CO2?

Answers

Answer:

It is known that 1 mol of a molecule contains 6.023×1023 6.023 × 10 23 number of molecules. So, 0.25 moles of CO2 C O 2.

The correct option for the given question about Mole Concept is Na / 2 atom of oxygen.

What is mole?In chemistry, a mole is a unit. A mole of a substance is the mass of the substance containing precisely 12 gram of the same number of atoms as 12C.The mole is the SI unit used to measure a substance's quantity. It has the symbol mol.

How to solve this question?

In 1 mole number of molecules of CO₂ = Na (Avagadro Number)

In 0.25 mole number of molecules of CO₂ = 0.25 × Na molecules

In 1 molecule number of oxygen atom = 2 atom

In 0.25 × Na molecules number of oxygen atom = 2 × 0.25 × Na atom

In 0.25 × Na molecules number of oxygen atom = 0.5 × Na atom

So in 0.25 mole of CO₂ number of oxygen atom = Na / 2 atom

Thus we can conclude that in 0.25 mole of CO₂ number of oxygen atom will be Na / 2, where Na is Avagadro Number.

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Hãy cho biết giá trị và ý nghĩa của số lượng tử n, l, m, ms khi mô tả trạng thái của electron trong nguyên tử?

Answers

Yes beautiful language

Urea, CH4N2O (s), is manufactured from NH3 (g) and CO2 (g). H2O (l) is another product of this reaction. An experiment is started with 2.6 grams of NH3 (g) added into a reaction vessel with CO2 (g).
Write the balanced equation for this reaction, being sure to include physical states. Based on the balanced equation above, calculate the following:
a. the theoretical yield of urea in grams that can be made from the NH3
b. the actual amount of urea made if the percent yield for this reaction is 34%.

Answers

Answer:

a. 4.41 g of Urea

b. 1.5 g of Urea

Explanation:

To start the problem, we define the reaction:

2NH₃ (g) +  CO₂ (g) → CH₄N₂O (s)  +  H₂O(l)

We only have mass of ammonia, so we assume the carbon dioxide is in excess and ammonia is the limiting reactant:

2.6 g . 1mol / 17g = 0.153 moles of ammonia

Ratio is 2:1. 2 moles of ammonia can produce 1 mol of urea

0.153 moles ammonia may produce, the half of moles

0153 /2 = 0.076 moles of urea

To state the theoretical yield we convert moles to mass:

0.076 mol . 58 g/mol = 4.41 g

That's the 100 % yield reaction

If the percent yield, was 34%:

4.41 g . 0.34 = 1.50 g of urea were produced.

Formula is (Yield produced / Theoretical yield) . 100 → Percent yield

Isotopes are: A. are only theoretical. B. only formed in laboratories. C. found in nature. D. found in the nuclear reactions in stars but not on Earth.

Answers

Answer:

B. only formed in laboratories

Explanation:

i know

Isotopes are only formed in Laboratories. hence, Option (B) is correct.

What are Isotopes ?

Each of two or more forms of the same element that contain equal numbers of protons but different numbers of neutrons in their nuclei, and hence differ in relative atomic mass but not in chemical properties; in particular, a radioactive form of an element is known as Isotope.

Isotopes are two or more types of atoms that have the same atomic number and position in the periodic table, and that differ in nucleon numbers due to different numbers of neutrons in their nuclei.

Therefore, Isotopes are only formed in Laboratories. hence, Option (B) is correct.

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According to the ideal gas law, a 9.998 mol sample of argon gas in a 0.8311 L container at 502.7 K should exert a pressure of 496.2
atm. What is the percent difference between the pressure calculated using the van der Waals' equation and the ideal pressure? For Ar
gas, a = 1.345 L’atm/mol? and b = 3.219x10-2 L/mol.
Pideal – Puan der Waals |
Percent difference
x 100

Answers

Answer:

[tex]\%diff=24.0\%[/tex]

Explanation:

Hello there!

In this case, according to the given information, it turns out firstly necessary for us to set up the van der Waals' equation as shown below:

[tex]p=\frac{RT}{v-b}-\frac{a}{v^2}[/tex]

Thus, we secondly calculate the molar volume as:

[tex]v=\frac{0.8311L}{9.998mol} =0.083L/mol[/tex]

Then, we plug in the entire variables in the vdW equation to get such pressure:

[tex]p=\frac{0.08206\frac{atm*L}{mol*K}*502.7K}{0.08313L/mol-0.03219L/mol}-\frac{1.345L*atm/mol}{(0.08313L/mol)^2}\\\\p=615.2atm[/tex]

And the ideal gas pressure:

[tex]p=\frac{0.08206\frac{atm*L}{mol*K}*502.7K}{0.08313L/mol}\\\\p=496.2atm[/tex]

Finally, the percent difference:

[tex]\%diff=\frac{|496.2atm-615.2atm|}{496.2atm} *100\%\\\\\%diff=24.0\%[/tex]

Regards!

The shape of a molecule is determined by:
A. All of these
B. The number of electron clouds around the atom.
C. The number of bonds.
D. Mutual repulsion between electrons.

Answers

By the electron pairs around the central atom. So it’s A

I NEED A ANSWER FOR THIS QUESTION, ASAP​

Answers

It’s not showing up

PLEASE HELP! A machine uses filtration to separate a component from orange juice. Which component does the machine most likely separate from the mixture?

A - Pigment
B - Sugar
C - Pulp
D - Water

Answers

Answer: c

Explanation:   Filtration is technically defined as the process of separating suspended solid matter from a liquid

Pulp is a lignocellulosic fibrous material prepared by chemically or mechanically separating cellulose fibers from wood, fiber crops .

Many commercial juices are filtered to remove fiber or pulp.

The correct answer is C, Pulp.

Orange is an example of a citrus fruit. Every citrus fruit has a pulp. The of pulp a citrus fruit is that stringy content in the endocarp of the fruit .

The pulp of a citrus fruit is where its juice is found.

When you want to prepare orange juice, you need to remove the pulp of the citrus fruit. This is done by filtering out the pulp from the juice.

Filtration is the process of removing larger particles. For a liquid juice, filtration is the process of removing solid particles from the orange juice.

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Atoms that have a positive or negative electrical charge are called ________.​

Answers

Explanation:

They are called or known as cations

The density of an aqueous solution containing 25.0 percent of ethanol (C2H5OH) by mass is 0.950 g/mL. (a) Calculate the molality of this solution. m (b) Calculate its molarity. M (c) What volume of the solution would contain 0.275 mole of ethanol

Answers

Answer:

a. 7.24m

b. 5.15M

c. 53.4mL of the solution would contain this amount of ethanol.

Explanation:

Molality, m, is defined as the moles of solute (ethanol, in this case) per kg of solvent.

Molarity, M, are the moles of solute per kg of solvent

To solve this question we need to find the moles of solute in 100g of solution and the volume using its density as follows:

a. Moles ethanol -Molar mass: 46.07g/mol-:

25g ethanol * (1mol/46.07g) = 0.54265 moles ethanol

kg solvent:

100g solution - 25g solute = 75g solvent * (1kg / 1000g) = 0.075kg

Molality:

0.54265 moles ethanol / 0.075kg = 7.24m

b. Liters solution:

100g solution * (1mL / 0.950g) = 105.3mL * (1L / 1000mL) = 0.1053L

Molarity:

0.54265 moles ethanol / 0.1053L = 5.15M

c. 0.275 moles ethanol * (1L / 5.15moles Ethanol) = 0.0534L =

53.4mL of the solution would contain this amount of ethanol

HELP ASAS 15 POINTS

When using the process of evaporation to separate a mixture, what is left behind in the evaporating dish?

A. None of these.
B. The liquid evaporates and the solid is left in the dish.
C. The mixture does not separate, and the entire mixture evaporates.
D. The mixture does not separate, and the entire mixture remains in the dish.

Answers

Answer:

liquid will be evaporated while solid remains

What do we need to know to understand the formation of a chemical bond?​

Answers

Answer:

A chemical bond is a lasting attraction between atoms, ions or molecules that enables the formation of chemical compounds. The bond may result from the electrostatic force of attraction between oppositely charged ions as in ionic bonds or through the sharing of electrons as in covalent bonds.

Explanation:

You have to put energy into a molecule to break its chemical bonds. The amount needed is called the bond energy. After all, molecules don't spontaneously break

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