Explanation:
The equation is given as;
2 A + B + 3 C → Products
The order of the reaction refers to the extent at which the rate depends n the concentration of the reactant.
The order of reaction is experimentally obtained. It can also be obtained from the rate law of the reaction.
If the rate law is given as;
rate law = k [A]²[B][C]³
Then the order is second order with respect to A.
The order is second order with respect to A.
Reaction series;Given that;
2A + B + 3C → Products at 470 K
Find:
Order of reaction with respect to A
Computation:
The reaction that takes place refers to how much the rate is influenced by the reactant concentration.
The reaction order is determined empirically. This can also be derived from the reaction's rate law.
Rate law = k[A]²[B][C]³
So, The order is second order with respect to A.
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Give the formula of each coordination compound. Include square brackets around the coordination complex. Do not include the oxidation state on the metal. Use parentheses only around polyatomic ligands.
For ethylenediamine, use (en) in the formula.
a) sodium hexachloroplatinate(IV)
b) dibromobis(ethylenediamine)cobalt(III) bromide
c) pentaamminechlorochromium(III) chloride
Answer:
sodium hexachloroplatinate(IV)- Na2[PtCl6]
dibromobis(ethylenediamine)cobalt(III) bromide- [Co(en)2Br2]Br
pentaamminechlorochromium(III) chloride-[Cr(NH3)5Cl]Cl2
Explanation:
The formulas of the various coordination compounds can be written from their names taking cognisance of the metal oxidation state as shown above. The oxidation state of the metal will determine the number of counter ions present in the coordination compound.
The number ligands are shown by subscripts attached to the ligand symbols. Remember that bidentate ligands such as ethylenediamine bonds to the central metal ion via two donors.
"What is the difference between the revertible and nonrevertible rII mutants that Benzer generated?"
explain how the liquid in a thermometer changes so that it can be used to measure a temprature
Answer:
The liquid that is often used in thermometers is chrome.
It is khwon for raising its volule when the temperature raises and vice-versa. ● the temperature and the volume are proprtional to each other so using Mathematics, scientists have figured out a way to benefit from it to make a thermometer.
If each NADHNADH generates 3 ATPATP molecules and each FADH2FADH2 generates 2 ATPATP molecules, calculate the number of ATPATP molecules generated from one saturated 18 ‑carbon fatty acid.
Answer:
[tex]128~ATP[/tex]
Explanation:
The metabolic pathway by which energy can be obtained from a fatty acid is called "beta-oxidation". In this route, acetyl-Coa is produced by removing 2 carbons from the fatty acid for each acetyl-Coa produced. In other words, for each round, 1 acetyl Coa is produced and for each round 2 carbons are removed from the initial fatty acid. Therefore, the first step is to calculate the number of rounds that will take place for an 18-carbon fatty acid using the following equation:
[tex]Number~of~Rounds=\frac{n}{2}-1[/tex]
Where "n" is the number of carbons, in this case "18", so:
[tex]Number~of~Rounds=\frac{18}{2}-1~=~8[/tex]
We also have to calculate the amount of Acetyl-Coa produced:
[tex]Number~of~Acetyl-Coa=\frac{18}{2}~=~9[/tex]
Now, we have to keep in mind that in each round in the beta-oxidation we will have the production of 1 [tex]FADH_2[/tex] and 1 [tex]NADH[/tex]. So, if we have 8 rounds we will have 8 [tex]FADH_2[/tex] and 8 [tex]NADH[/tex].
Finally, for the total calculation of ATP. We have to remember the yield for each compound:
-) [tex]1~FADH_2~=~2~ATP[/tex]
-) [tex]1~NADH~=~3~ATP[/tex]
-) [tex]Acetyl~CoA~=~10~ATP[/tex]
Now we can do the total calculation:
[tex](8*2)~+~(8*3)~+~(9*10)=130~ATP[/tex]
We have to subtract "2 ATP" molecules that correspond to the activation of the fatty acid, so:
[tex]130-2=128~ATP[/tex]
In total, we will have 128 ATP.
I hope it helps!
If we represent the equilibrium as:...N2O4(g) 2 NO2(g) We can conclude that: 1. This reaction is: A. Exothermic B. Endothermic C. Neutral D. More information is needed to answer this question. 2. When the temperature is increased the equilibrium constant, K: A. Increases B. Decreases C. Remains the same D. More information is needed to answer this question. 3. When the temperature is increased the equilibrium concentration of NO2: A. Increases B. Decreases C. Remains the same D. More information is needed to answer this question.
Answer:
1. This reaction is: B. Endothermic.
2. When the temperature is increased the equilibrium constant, K: A. Increases.
3. When the temperature is increased the equilibrium concentration of NO2: A. Increases.
Explanation:
Hello,
In this case, considering the images, we can state that the red color at high temperature is due to the presence of nitrogen dioxide (product) and the lower coloring is due to the presence of dinitrogen tetroxide (reactant) at low temperature.
With the aforementioned, we can conclude that the chemical reaction:
[tex]N_2O_4(g) \rightleftharpoons 2 NO_2(g)[/tex]
Is endothermic since high temperatures favor the formation of the product and the low temperatures favor the consumption of the the reactant. thereby:
1. This reaction is: B. Endothermic.
2. When the temperature is increased the equilibrium constant, K: A. Increases. In this particular case, since the dinitrogen tetroxide has 1 molecule and nitrogen dioxide two molecules in the chemical reaction, the entropy change should be positive, therefore, by increasing the T, the Gibbs free energy of reaction becomes more negative:
[tex]G=H-TS[/tex]
As Gibbs free energy becomes more negative, the equilibrium constant becomes bigger given their relationship:
[tex]K=exp(-\frac{\Delta G}{RT} )[/tex]
3. When the temperature is increased the equilibrium concentration of NO2: A. Increases.
Regards.
Calculate the pH of a solution that is 0.210 M in nitrous acid (HNO2) and 0.290 M in potassium nitrite (KNO2). The acid dissociation constant of nitrous acid is 4.50 × 10-4.
Answer:
pH = 3.49
Explanation:
We have a buffer system formed by a weak acid (HNO₂) and its conjugate base (NO₂⁻ coming from KNO₂). We can calculate the pH of a buffer ssytem using the Henderson-Hasselbach equation.
pH = pKa + log [base] / [acid]
pH = -log Ka + log [NO₂⁻] / [HNO₂]
pH = -log 4.50 × 10⁻⁴ + log 0.290 M / 0.210 M
pH = 3.49
The pH of the solution containing 0.210 M nitrous acid (HNO₂) and 0.290 M potassium nitrite (KNO₂) is 3.49
We'll begin by calculating the the pKa of acid. This can be obtained as follow:
Acid dissociation constant (Ka) = 4.50×10¯⁴
pKa =?pKa = –Log Ka
pKa = –Log 4.50×10¯⁴
pKa = 3.35Finally, we shall determine the pH of the solution.pKa = 3.35
Concentration of HNO₂, [HNO₂] = 0.210 M
Concentration of KNO₂, [KNO₂] = 0.290 M
pH =?The pH of the solution can obtain by using the Henderson-Hasselbach equation as illustrated below:
pH = pKa + log [base] / [acid]pH = pKa+ log [NO₂⁻] / [HNO₂]
pH = 3.35 + log (0.290 / 0.210)
pH = 3.49Thus, the pH of the solution is 3.49
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Which describes the molecule below
Answer:
Option D. A lipid with three unsaturated fatty acid.
Explanation:
The molecule in the diagram above contains three fatty acid.
A careful observation of the molecule reveals that each of the three fatty acids contains a double bond.
The presence of a double bond in a compound shows that the compound is unsaturated.
Thus, we can say that the molecule is a lipid with three unsaturated fatty acid.
According to the following reaction, how many grams of ammonia will be formed upon the complete reaction of 31.2 grams of hydrogen gas with excess nitrogen gas ? nitrogen(g) + hydrogen(g) ammonia(g)
Answer:
176.8 g of ammonia, NH3.
Explanation:
We'll begin by writing the balanced equation for the reaction. This is given below:
N2 + 3H2 —> 2NH3
Next, we shall determine the mass of H2 that reacted and the mass of NH3 produced from the balanced equation. This is illustrated below:
Molar mass of H2 = 2x1 = 2 g/mol
Mass of H2 from the balanced equation = 3 x 2 = 6 g
Molar mass of NH3 = 14 + (3x1) = 17 g/mol
Mass of NH3 from the balanced equation = 2 x 17 = 34 g.
From the balanced equation above,
6 g of H2 reacted to produce 34 g of NH3.
Finally, we shall determine the mass of ammonia, NH3 produced by reacting 31.2 g of H2.
This can be obtained as follow:
From the balanced equation above,
6 g of H2 reacted to produce 34 g of NH3.
Therefore, 31.2 g of H2 will react to produce = (31.2 x 34)/6 = 176.8 g of NH3.
Therefore, 176.8 g of ammonia, NH3 were obtained from the reaction.
Solid sodium iodide is slowly added to a solution that is 0.0050 M Pb 2+ and 0.0050 M Ag +. [K sp (PbI 2) = 1.4 × 10 –8; K sp (AgI) = 8.3 × 10 –17] Calculate the Ag + concentration when PbI 2 just begins to precipitate.
Answer:
[Ag⁺] = 5.0x10⁻¹⁴M
Explanation:
The product solubility constant, Ksp, of the insoluble salts PbI₂ and AgI is defined as follows:
Ksp(PbI₂) = [Pb²⁺] [I⁻]² = 1.4x10⁻⁸
Ksp(AgI) = [Ag⁺] [I⁻] = 8.3x10⁻¹⁷
The PbI₂ just begin to precipitate when the product [Pb²⁺] [I⁻]² = 1.4x10⁻⁸
As the initial [Pb²⁺] = 0.0050M:
[Pb²⁺] [I⁻]² = 1.4x10⁻⁸
[0.0050] [I⁻]² = 1.4x10⁻⁸
[I⁻]² = 1.4x10⁻⁸ / 0.0050
[I⁻]² = 2.8x10⁻⁶
[I⁻] = 1.67x10⁻³So, as the [I⁻] concentration is also in the expression of Ksp of AgI and you know concentration in solution of I⁻ = 1.67x10⁻³M:
[Ag⁺] [I⁻] = 8.3x10⁻¹⁷
[Ag⁺] [1.67x10⁻³] = 8.3x10⁻¹⁷
[Ag⁺] = 5.0x10⁻¹⁴MWhat is the edge length of a face-centered cubic unit cell that is made of of atoms, each with a radius of 154 pm
Answer:
The edge length of a face-centered cubic unit cell is 435.6 pm.
Explanation:
In a face-centered cubic unit cell, each of the eight corners is occupied by one atom and each of the six faces is occupied by a single atom.
Hence, the number of atoms in an FCC unit cell is:
[tex] 8*\frac{1}{8} + 6*\frac{1}{2} = 4 atoms [/tex]
In a face-centered cubic unit cell, to find the edge length we need to use Pythagorean Theorem:
[tex] a^{2} + a^{2} = (4R)^{2} [/tex] (1)
Where:
a: is the edge length
R: is the radius of each atom = 154 pm
By solving equation (1) for "a" we have:
[tex] a = 2R\sqrt{2} = 2*154 pm*\sqrt{2} = 435.6 pm [/tex]
Therefore, the edge length of a face-centered cubic unit cell is 435.6 pm.
I hope it helps you!
Determine whether each phrase describes carboxylic acids or esters.a. Do not form hydrogen bonds amongst themselves and have higher vapor pressureb. Form hydrogen bonds amongst themselves and have lower vapor pressurec. Notable for their pleasant fragrancesd. Their reactions with base are kn. own as saponificationse. Usually have a sour odorf. Their reactions with base are known as neutralizations
Explanation:
a. Esters
b. Carboxylic acids
c. Esters (ethyl hexanoate smells like pineapple)
d. Carboxylic acids (produces a carboxylic salt)
For the given phrases the following description is better.
a. Esters
b. Carboxylic acids
c. Esters (ethyl hexanoate smells like pineapple)
d. Carboxylic acids (produces a carboxylic salt)
Esters and carboxylic acids:An ester is a synthetic compound got from a corrosive in which somewhere around one - OH hydroxyl bunch is supplanted by an - O-alkyl (alkoxy) bunch, as in the replacement response of a carboxylic acid and a liquor.
Carboxylic acid is any of a class of natural mixtures in which a carbon (C) particle is clung to an oxygen (O) molecule by a twofold bond and to a hydroxyl bunch (―OH) by a solitary bond.
Find more information about esters here:
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Why are cells important to an organisms survival
Answer:
Cells are the basic structures of all living organisms. Cells provide structure for the body, take in nutrients from food and carry out important functions. ... These organelles carry out tasks such as making proteins?, processing chemicals and generating energy for the cell
Answer: I absolutely love this question! Biology is so interesting, so I always love to answer the curiosity of others regarding biology, such as that!
Cells are simply the basic structures of all organisms, that are living, of course! Cells provide structure for the body, and they also take in nutrients that your body needs from food and they carry out important functions. These organelles carry out tasks such as making proteins, processing chemicals, and generating energy for the cell. Isn’t that cool?
Hope this helped! <3
How many cups are in five gallons?
Answer:
In 5 US liquid gallons, there are 80 cups.
Explanation:
To get from gallons to cups, just multiply the amount of gallons you have by 16.
f the Ksp for HgBr2 is 2.8×10−14, and the mercury ion concentration in solution is 0.085 M, what does the bromide concentration need to be for a precipitate to occur?
Answer:
0.057 M
Explanation:
Step 1: Given data
Solubility product constant (Ksp) for HgBr₂: 2.8 × 10⁻⁴
Concentration of mercury (II) ion: 0.085 M
Step 2: Write the reaction for the solution of HgBr₂
HgBr₂(s) ⇄ Hg²⁺(aq) + 2 Br⁻
Step 3: Calculate the bromide concentration needed for a precipitate to occur
The Ksp is:
Ksp = 2.8 × 10⁻⁴ = [Hg²⁺] × [Br⁻]²
[Br⁻] = √(2.8 × 10⁻⁴/0.085) = 0.057 M
A 0.753 g sample of a monoprotic acid is dissolved in water and titrated with 0.250 M NaOH. What is the molar mass of the acid if 21.5 mL of the NaOH solution is required to neutralize the sample?
Answer:
[tex]MM_{acid}=140.1g/mol[/tex]
Explanation:
Hello,
In this case, since the acid is monoprotic, we can notice a 1:1 molar ratio between, therefore, for the titration at the equivalence point, we have:
[tex]n_{acid}=n_{base} \\\\V_{acid}M_{acid}=V_{base}M_{base}\\\\n_{acid}=V_{base}M_{base}[/tex]
Thus, solving for the moles of the acid, we obtain:
[tex]n_{acid}=0.0215L*0.250\frac{mol}{L}=5.375x10^{-3}mol[/tex]
Then, by using the mass of the acid, we compute its molar mass:
[tex]MM_{acid}=\frac{0.753g}{5.375x10^{-5}mol} \\\\MM_{acid}=140.1g/mol[/tex]
Regards.
Draw the structure for the organic radical species produced by reaction of the compound with a chlorine atom. Assume reaction occurs at the weakest C-H bond.
Answer:
See explanation
Explanation:
The reaction of chlorine with the pictured compound will occur via free radical mechanism. The stability of the free radical formed will depend on its structure.
The order of stability of free radicals is methyl < primary < secondary < tertiary. Hence a tertiary carbon free radical is the most stable.
Looking at the compound, the radical will form at the position shown in the image attached since it will lead to a secondary free radical which is more stable.
The structure that should be drawn is shown below.
The reaction of chlorine:It should be within the pictured compound that will arise via a free radical mechanism. The stability should be based on the structure. The stability of the order of free radicals should be methyl < primary < secondary < tertiary. Thus, a tertiary carbon free radical should be most stable.
Here look at the compound, the radical should form at the position that should be shown in the image that resulted in the secondary free radical i.e. more stable.
Draw the structure of beeswax.beeswax is made from the esterfication of a saturated 16-carbon fatty acid and a 30 carbon straight chain primary alcohol.
Answer:
Triacontyl palmitate
Explanation:
In this case, we have a reaction between an acid and an alcohol. When we put together these kind of compounds an ester is produced. This reaction is called "esterification".
In our case, the alcohol is a structure with 30 carbon in which the "OH" group is bonded on carbon 1. The name of this compound is "n-triacontanol". The acid is a structure in which we have 16 carbon in which the "COOH" group is placed on carbon 1. The name of this compound is "palmitic acid". The ester produced by the acid and the alcohol is "Triacontyl palmitate".
See figure 1.
I hope it helps!
For the reaction 3H 2(g) + N 2(g) 2NH 3(g), K c = 9.0 at 350°C. What is the value of ΔG at this temperature when 1.0 mol NH 3, 5.0 mol N 2, and 5.0 mol H 2 are mixed in a 2.5 L reactor?
Answer:
ΔG = - 31.7kJ/mol
Explanation:
It is possible to find ΔG of a reaction at certain temperature knowing Kc following the equation:
ΔG = ΔG° + RT ln Q
ΔG° = -RT lnKc
ΔG = -RT lnKc + RT ln Q (1)
Where R is gas constant (8.314J/molK), T absolute temperature (350°C + 273.15 = 623.15K) and Q reaction quotient
For the reaction,
3H₂(g) + N₂(g) ⇄ 2NH₃(g)
Q = [NH₃]² / [H₂]³[N₂]
Where the concentrations of each chemical are:
[NH₃] = 1.0mol / 2.5L = 0.4M
[H₂] = 5.0mol / 2.5L = 2M
[N₂] = 2.5mol / 2.5L = 1M}
Q = [0.4M]² / [2M]³[1M]
Q = 0.02
And replacing in (1):
ΔG = -RT lnKc + RT ln Q
ΔG = -8.314J/molK*623.15K ln 9 + 8.314J/molK*623.15K ln 0.02
ΔG = - 31651J/mol
ΔG = - 31.7kJ/molWhich option draws the correct conclusion from the following case study?
A patient with sickle-cell anemia and a fever goes to the emergency room and is given Tylenol to reduce
the fever. The patient has seizures and dies after taking the Tylenol. The physician writes up this case as
an interesting outcome for a patient with sickle-cell anemia.
The case study's validity is obvious because it describes a real-life situation.
The case study was influenced by bias, and led to incorrect conclusions being drawn
The case study was not intended to produce a generalized conclusion about treatment
Upon reading this case study, physicians should stop treating sickle cell patients with fevers using Tylenol
Answer:
I believe the answer The case study was influenced by bias, and led to incorrect conclusions being drawn. plz correct me if I am wrong
Explanation:
Answer: options B
Explanation:
Draw a picture of what you imagine solid sodium chloride looks like at the atomic level. (Do NOT draw Lewis structures.) Make sure to include a key. Then describe what you've drawn and any assumptions you are making.
Answer:
Kindly check the explanation section.
Explanation:
PS: kindly check the attachment below for the required diagram that is the diagram showing solid sodium chloride looks like at the atomic level.
The chemical compound known as sodium chloride, NaCl has Molar mass: 58.44 g/mol, Melting point: 801 °C and
Boiling point: 1,465 °C. The structure of the solid sodium chloride is FACE CENTRED CUBIC STRUCTURE. Also, solid sodium chloride has a coordination number of 6: 6.
In the diagram below, the positive sign shows the sodium ion while the thick full stop sign represent the chlorine ion.
The NaCl has been the ionic structure with an equal number of sodium and chlorine ions bonded.
In the structure, there has been each Na ion bonded with the Cl ions. There has been the transfer of electrons between the structure in order to attain a stable configuration.
The expected structure of the NaCl would be the image attached below.
The image has been the cubic structure of NaCl. With the presence of Na ions at the vertex of the structure, there has been the presence of the Cl ion with every Na ion for the electron transfer.
For more information about the structure of NaCl, refer to the link:
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candium forms the ion Sc3+. How many bromite ions could bond with Sc3+, and what would be the chemical formula?
a.3 bromite ions, Sc(Broa)2
b.2 bromite ions, Sc(BrO4)3
c.3 bromite ions, Sc(Broz)
d.2 bromite ions, Sc (BrO2)2
Answer: 3 bromite ions and [tex]Sc(BrO_2)_3[/tex]
Explanation:
For formation of a neutral ionic compound, the charges on cation and anion must be balanced. The cation is formed by loss of electrons by metals and anions are formed by gain of electrons by non metals.
Here scandium is having an oxidation state of +3 called as [tex]Sc^{3+}[/tex] cation and bromite is an anion with oxidation state of -1 called as [tex]BrO_2^-[/tex]. Thus 1 Scandium ion combines with three bromite ions and their oxidation states are exchanged and written in simplest whole number ratios to give neutral [tex]Sc(BrO_2)_3[/tex]
Answer:
3 bromite ions and
Explanation:
"Aqueous solutions of lead nitrate and ammonium chloride are mixed" together. Which statement is correct
Answer:
PbCl₂ will precipitate from solution.
Explanation:
Statements are:
Insufficient information is given.
Both NH4NO3 and PbCl2 precipitate from solution.
No precipitate forms.
PbCl2 will precipitate from solution.
NH4NO3 will precipitate from solution.
The reaction of ammonium chloride (NH₄Cl) with lead nitrate (Pb(NO₃)₂) is:
Pb(NO₃)₂ + 2NH₄Cl → PbCl₂ + 2 NH₄NO₃
Talking of rules of solubility, all nitrates are soluble in water, that means NH₄NO₃ is soluble and no precipitate is formed.
In the same way, all chlorides are soluble except silver chloride and lead chloride. That means:
PbCl₂ (Lead chloride) will precipitate from solution.0.22 L of HNO3 is titrated to equivalence using 0.18 L of 0.2 MNaOH. What is the concentration of the HNO3?
Answer:
0.16 M
Explanation:
Data provided as per the question is below:-
Volume of [tex]HNO_3[/tex] = 0.22 L
The Volume of NaOH = 0.18 L
Morality of NaOH = 0.2
According to the given situation, the calculation of the concentration of the [tex]HNO_3[/tex] is shown below:-
For equivalence,
Number of the equivalent of [tex]HNO_3[/tex] = Number of equivalents of NaOH
[tex]= \frac{0.18\times0.2}{0.22}[/tex]
[tex]= \frac{0.036}{0.22}[/tex]
= 0.16363 M
or
= 0.16 M
What class of organic product results when 1-heptyne is treated with a mixture of mercuric acetate in aqueous sulfuric acid, and then HOCH2CH2OH with catalytic sulfuric acid
Answer:
2-methyl-2-pentyl-1,3-dioxolane
Explanation:
In this case, we have two reactions:
First reaction:
1-heptyne + mercuric acetate -------> Compound A
Second reaction:
Compound A + HOCH2CH2OH -------> Compound C
First reaction
In the first reaction, we have as a main functional group a triple bond. We have to remember that mercuric acetate in sulfuric acid will produce a ketone. The carbonyl group (C=O) would be placed in the most substituted carbon of the triplet bond (in this case, carbon 2). With this in mind, we will have as a product: heptan-2-one. (See figure 1).
Second reaction
In this reaction, we have as reagents:
-) Heptan-2-one
-) Ethylene-glycol [tex]HOCH_2CH_2OH[/tex]
-) Sulfuric acid [tex]H_2SO_4[/tex]
When we put ethylene-glycol with a ketone or an aldehyde we will form a cyclic acetal. In this case, this structure would be formed on carbon 2 forming 2-methyl-2-pentyl-1,3-dioxolane. (See figure 2).
I hope it helps!
o prepare vegetables for finishing by grilling, sautéing, pan frying, deep frying, or stewing, you should _______ them to cook them to partial doneness
Answer:
To prepare vegetables for finishing by grilling, sautéing, pan frying, deep frying, or stewing, you should parboil them to cook them to partial doneness.
4. Given that the enthalpy of reaction for a system at 298 K is -292 kJ/mol and the entropy for that system is 224 J/mol K, what's the free energy for the system?
A.-87,793 kJ
B.-358 kJ
C.-225 kJ
D. -66,751 kJ
Answer:
[tex]\Delta G=-359\frac{kJ}{mol}[/tex]
Explanation:
Hello,
In this case, we must remember that the Gibbs free energy is defined in terms of the enthalpy, temperature and entropy as shown below:
[tex]\Delta G=\Delta H -T\Delta S\\[/tex]
In such a way, for the given data, we obtain it, considering the conversion from J to kJ for the entropy in order to conserve the proper units:
[tex]\Delta G=-292\frac{kJ}{mol} -(298)(224\frac{J}{mol}*\frac{1kJ}{1000J} )\\\\\Delta G=-359\frac{kJ}{mol}[/tex]
Best regards.
Answer:
B- 358 kj
Explanation: I took the test
Which state of matter does this image represent? Image of water Solid Liquid Gas Plasma
Answer:Liquid
Explanation:
Assume you dissolve 0.235 g of the weak benzoic acid, C6H5CO2H in enough water to make 100.0 mL of the solution and then titrate the solution with 0.108 M NaOH. Benzoic acid is a monoprotic acid.
1. What is the pH of the original benzoic acid solution before the titration is started?
2. What is the pH when 7.00 mL of the base is added? (Hint: This is in the buffer region.)
3. What is the pH at the equivalence point?
Answer:
1. pH = 2.98
2. pH = 4.02
3. pH = 8.12
Explanation:
1. Initial molarity of benzoic acid (Molar mass: 122.12g/mol; Ka = 6.14x10⁻⁵) is:
0.235 ₓ (1mol / 122.12g) = 1.92x10⁻³ moles / 0.100L = 0.01924M
The equilibrium of benzoic acid with water is:
C6H5CO2H(aq) + H2O(l) → C6H5O-(aq) + H3O+(aq)
And Ka is defined as the ratio between equilibrium concentrations of products over reactants, thus:
Ka = 6.14x10⁻⁵ = [C6H5O⁻] [H3O⁺] / [C6H5CO2H]
The benzoic acid will react with water until reach equilibrium. And equilibrium concentrations will be:
[C6H5CO2H] = 0.01924 - X
[C6H5O⁻] = X
[H3O⁺] = X
Replacing in Ka:
6.14x10⁻⁵ = [X] [X] / [0.01924 - X]
1.1815x10⁻⁶ - 6.14x10⁻⁵X = X²
1.1815x10⁻⁶ - 6.14x10⁻⁵X - X² = 0
Solving for X:
X = -0.0010→ False solution. There is no negative concentrations
X = 0.0010567M → Right solution.
pH = - log [H3O⁺] and as [H3O⁺] = X:
pH = - log [0.0010567M]
pH = 2.982.
pH of a buffer is determined using H-H equation (For benzoic acid:
pH = pka + log [C6H5O⁻] / [C6H5OH]
pKa = -log Ka = 4.21 and [] could be understood as moles of each chemical
The benzoic acid reacts with NaOH as follows:
C6H5OH + NaOH → C6H5O⁻ + Na⁺ + H₂O
That means NaOH added = Moles C6H5O⁻ And C6H5OH = Initial moles (1.92x10⁻³ moles - Moles NaOH added)
7.00mL of NaOH 0.108M are:
7x10⁻³L ₓ (0.108 mol / L) = 7.56x10⁻⁴ moles NaOH = Moles C₆H₅O⁻
And moles C6H5OH = 1.92x10⁻³ moles - 7.56x10⁻⁴ moles = 1.164x10⁻³ moles C₆H₅OH
Replacing in H-H equation:
pH = 4.21 + log [7.56x10⁻⁴ moles] / [ 1.164x10⁻³ moles]
pH = 4.023. At equivalence point, all C6H5OH reacts producing C6H5O⁻. The moles are 1.164x10⁻³ moles
Volume of NaOH to reach equivalence point:
1.164x10⁻³ moles ₓ (1L / 0.108mol) = 0.011L. As initial volume was 0.100L, In equivalence point volume is 0.111L and concentration of C₆H₅O⁻ is:
1.164x10⁻³ moles / 0.111L = 0.01049M
Equilibrium of C₆H₅O⁻ with water is:
C₆H₅O⁻(aq) + H₂O(l) ⇄ C₆H₅OH(aq) + OH⁻(aq)
Kb = [C₆H₅OH] [OH⁻]/ [C₆H₅O⁻]
Kb = kw / Ka = 1x10⁻¹⁴ / 6.14x10⁻⁵ = 1.63x10⁻¹⁰
Equilibrium concentrations of the species are:
C₆H₅O⁻ = 0.01049M - X
C₆H₅OH = X
OH⁻ = X
Replacing in Kb expression:
1.63x10⁻¹⁰ = X² / 0.01049- X
1.71x10⁻¹² - 1.63x10⁻¹⁰X - X² = 0
Solving for X:
X = -1.3x10⁻⁶ → False solution
X = 1.3076x10⁻⁶ → Right solution
[OH⁻] = 1.3076x10⁻⁶
as pOH = -log [OH⁻]
pOH = 5.88
And pH = 14 - pOH
pH = 8.12Compare and contrast an electrolytic cell with a voltaic cell. Provide one example where both are present in daily life.
Answer:
ELECTROLYTIC CELL
An electrochemical cell in which a non-spontaneous chemical reaction takes place when electric current is passed through the solution,is called an electrolytic cell.
EXAMPLE
Nelsons cell and Downs cell
VOLTAIC CELL OR GALVANIC CELL
The electrochemical cell in which a spontaneous chemical reaction takes place and generates electric current is called galvanic and voltaic cell.
EXAMPLE
Daniel cell
Explanation:
Electrolytic cell by the non-spontaneous reactions covert the chemical energy into electical and volataic cells are those in which spontaneous redox reaction takes place.
What is cell?Cell is a device which converts chemical energy into electrical energy.
Electrolytic Cell: An electrolytic cell is an electrochemical cell in which a non-spontaneous redox chemical reaction occurs when an electric current is conducted through the solution.
Example- Electrolysis of sodium chloride, by which formation of sodium metal and chlorine gas takes place.
Voltaic cell: Voltaic cells are electrochemical cells in which a spontaneous redox chemical reaction occurs and creates electric current. These cells are also known by the name of Galvanic cells.
Example- It is used in the form of batteries which can be portable easily.
Hence, in electrolytic cells non - spontaneous reaction occur and in voltaic cell spontaneous reaction is occured.
To know more about cells, visit the below link:
https://brainly.com/question/1172236
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If the lead concentration in water is 1 ppm, then we should be able to recover 1 mg of lead from _____ L of water.
Answer:
1 L
Explanation:
ppm means parts per million. Generally the relationship between mass and litre is given as;
1 ppm = 1 mg/L
This means that 1 ppm is equivalent to 1 mg of a substance dissolved in 1 L of water.
