for the reaction , the value of δg° is –198 kj at 25°c. what is the equilibrium constant for this reaction at 25°c?

Answers

Answer 1

The equilibrium constant for the reaction can be calculated using Gibbs free energy change (ΔG°).Explanation:Given that the value of ΔG° is –198 kJ at 25°C.

The relationship between ΔG° and equilibrium constant (K) can be given by the following equation,ΔG° = –RTlnKHere, R is the gas constant and T is the temperature in Kelvin, which can be calculated as follows, The equilibrium constant for the reaction can be calculated using Gibbs free energy change (ΔG°).Explanation:Given that the value of ΔG° is –198 kJ at 25°C.

T = 25°C + 273 = 298 KNow, substituting the values, we get–198000 J = –(8.31 J/mol K) × 298 K × lnKSolving for K, we get,K = 1.20 × 10^43Therefore, the equilibrium constant for the given reaction at 25°C is 1.20 × 10^43. The relationship between ΔG° and equilibrium constant (K) can be given by the following equation,ΔG° = –RTlnKHere, R is the gas constant and T is the temperature in Kelvin, which can be calculated as follows,

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Related Questions

Which type of molecule is NOT made up of a chain of repeating monomers?
Please choose the correct answer from the following choices, and then select the submit answer button.
RNA
DNA
proteins
steroids
complex carbohydrates

Answers

Complex carbohydrates, steroids, proteins, DNA, and RNA are the five main classes of biological molecules that are not interchangeable. The correct option is D. steroids

Some of these, such as carbohydrates, lipids, and proteins, are polymers made up of repeating subunits. Other macromolecules, such as lipids and steroids, are built of various subunits, resulting in a diverse collection of chemical structures.

A steroid is a class of organic molecule that has a characteristic structure consisting of four fused rings. While many steroids are created by the body, others are introduced via diet. Steroids are frequently used to treat inflammation and are often used illicitly to enhance athletic performance Some biological macromolecules, such as carbohydrates, lipids, and proteins, are polymers composed of monomers, which are small building blocks that join together to form a long chain-like structure.

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of the following, which element has the highest first ionization energy?question 10 options:1) al2) cl3) na4) p

Answers

The element that has the highest first ionization energy among the options is Cl (chlorine). The correct answer is option 2.

Ionization energy is the amount of energy required to remove an electron from a neutral atom to form a positive ion. As we move from left to right in a period, the ionization energy increases. This happens because the number of protons increases, which pulls the electrons more tightly to the nucleus.

So, more energy is needed to remove an electron from an atom. Here's a list of the first ionization energies of the given elements (in kJ/mol):

Aluminum (Al): 577.5

Chlorine (Cl): 1251.2  

Sodium (Na): 495.8

Phosphorus (P): 1011.8

Therefore, of the given options, Cl (chlorine) has the highest first ionization energy, because it is located at the rightmost side of the periodic table.

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an atom's configuration based on its number of electrons ends at 3p2. another atom has eight more electrons. starting at 3p, what would be the remaining configuration?

Answers

The remaining electron configuration of the atom, starting from 3p, would be [tex]3p^6 4s^2[/tex].

The electron configuration of an atom describes how electrons are distributed among its various energy levels and orbitals. The given atom has an electron configuration ending at [tex]3p^2[/tex], indicating that it has two electrons in the 3p orbital. To determine the remaining electron configuration when eight more electrons are added, we start from 3p and distribute the additional electrons according to the Aufbau principle and Hund's rule.

The Aufbau principle states that electrons fill orbitals in order of increasing energy. Since the 3p orbital is filled with two electrons, we move on to the next available orbital, which is 4s. Hund's rule states that electrons occupy orbitals of the same energy level singly before pairing up. Therefore, the eight additional electrons would first fill the 4s orbital with two electrons, resulting in  [tex]3p^6 4s^2[/tex]. This configuration satisfies the electron requirement of the given atom with eight extra electrons.

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the half-life of strontium-90 is 28.1 years. how long will it take a 10.0-g sample of strontium-90 to decompose to 0.69 g?

Answers

Strontium-90 is a radioactive isotope of strontium. It decays by beta-emission and has a half-life of 28.1 years. This means that it takes 28.1 years for half of the original sample to decay.

After another 28.1 years, half of what's left will decay, leaving a quarter of the original sample, and so on.The decay of strontium-90 can be modeled by the exponential decay equation:A = A₀ e^(-kt)Where:A = the amount of strontium-90 remaining after time tA₀ = the initial amount of strontium-90k = the decay constantt = timeFor half-life problems, we can use the following equation:k = 0.693/t₁/₂where t₁/₂ is the half-life of the substance.

Substituting the values given in the problem, we get:k = 0.693/28.1 = 0.0246 years⁻¹We can use this value of k to find the amount of strontium-90 remaining after any amount of time. For example, to find the amount remaining after t years:A = A₀ e^(-kt)Substituting A₀ = 10.0 g, A = 0.69 g, and k = 0.0246 years⁻¹, we get:0.69 = 10.0 e^(-0.0246t)Dividing both sides by 10.0:0.069 = e^(-0.0246t)

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the positive variables p and c change with respect to time t. the relationship between p and c is given by the equation p2=

Answers

Given, the relationship between p and c is given by the equation p^2 = c^3 - 4c. Where p and c are the positive are variables which changes with respect to time is p^2 = c^3 - 4c.

To find the derivative of p with respect to time t, are the differentiate  by keeping the c as a constant. The obtained equation is as follows:$$\frac{d}{dt}p^2 = \frac{d}{dt}(c^3 - 4c)$$Now, apply the chain rule of differentiation on the left-hand side, we get;$$\frac{d}{dt}(p^2) = 2p\frac{dp}{dt}$$The right-hand side becomes zero as the derivative of a constant is zero.

this is the required relationship between p and The given relationship between p and c is given by the equation p^2 = c^3 - 4c, where p and c are the positive variables that change with respect to time t.To find the derivative of p with respect to time t, differentiate the given equation with respect to t by keeping the c as a constant.The obtained equation is as follows:$$\frac{d}{dt}p^2 = \frac{d}{dt}(c^3 - 4c)$$Now, apply the chain rule of differentiation on the left-hand side, we get;$$\frac{d}{dt}(p^2) = 2p\frac{dp}{dt}$$The right-hand side becomes zero as the derivative of a constant is zero.

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what is the volume of oxygen gas at stp from the decomposition of 10.8 g of mercuric oxide (216.59 g/mol)?

Answers

The volume of oxygen gas at STP from the decomposition of 10.8 g of mercuric oxide (216.59 g/mol) is 4.78 L.

The balanced equation for the decomposition of mercuric oxide is:HgO → Hg + O₂The molar mass of HgO is 216.59 g/mol.10.8 g of HgO is equal to 10.8 g / 216.59 g/mol = 0.0498 mol HgOFrom the balanced equation, it is known that 1 mol of HgO decomposes to produce 1 mol of O₂. Therefore, 0.0498 mol of HgO will produce 0.0498 mol of O₂.The volume of 1 mol of any gas at STP is 22.4 L.

The volume of 0.0498 mol of O₂ at STP is:0.0498 mol x 22.4 L/mol = 1.11552 LHowever, this is the volume of O₂ at STP produced from 0.0498 mol of HgO. The question asks for the volume of O₂ produced from 10.8 g of HgO.To find this, we can use the factor label method:0.0498 mol O₂ / 1 mol HgO x 10.8 g HgO / 216.59 g/mol HgO x 22.4 L/mol O₂= 4.78 LSo, the volume of oxygen gas at STP from the decomposition of 10.8 g of mercuric oxide (216.59 g/mol) is 4.78 L.

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how many grams of agcl would be needed to make a 4.0 m solution with a volume of 0.75 l? your answer should have two significant figures.

Answers

To prepare a 4.0 M solution with a volume of 0.75 L, approximately 430 grams of AgCl would be needed to prepare. For this molarity (M) and volume (V) of the solution are considered.

To calculate the grams of AgCl needed for the given solution, we need to consider the molarity (M) and volume (V) of the solution. Molarity is defined as moles of solute per litre of solution. First, we convert the volume from litres to millilitres (0.75 L = 750 mL) to maintain consistency with the molarity units. Then, we use the equation:

moles of AgCl = Molarity (M) * Volume (L)

Now, we can substitute the given values into the equation:

moles of AgCl = 4.0 mol/L * 0.750 L = 3.0 mol

Since we want to find the mass in grams, we need to multiply the moles of AgCl by its molar mass. The molar mass of AgCl is approximately 143.32 g/mol. Applying the conversion:

grams of AgCl = moles of AgCl * molar mass of AgCl

grams of AgCl = 3.0 mol * 143.32 g/mol = 430 g

Therefore, approximately 430 grams of AgCl would be needed to make a 4.0 M solution with a volume of 0.75 L.

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assume that t-buoh is a limiting reagent. when 4.4 moles of t-buoh are used as starting material, how many moles of t-buoh will be obtained theoretically?

Answers

The number of moles of t-buOH obtained theoretically is 2.2 moles (assuming t-buOH is the limiting reagent).

t-buOH is a limiting reagent and 4.4 moles of t-buOH are used as starting material. Therefore, we can determine the number of moles of t-buOH theoretically produced as follows:Limits reagent -The limiting reagent is the reactant in a chemical reaction that gets used up completely during the reaction and restricts the amount of product formed. In contrast, an excess reagent is the reactant that doesn't get used up entirely during the reaction.

Reagent -A substance that is used to detect, examine, measure, or produce other substances is known as a reagent. A chemical reaction is catalyzed by many reagents. They can be used for analysis, organic synthesis, or testing.

Limiting reagent calculation -

To calculate the limiting reagent, the number of moles of each substance present in the reaction mixture must be calculated first. Then, for each substance, the number of moles required to react completely with the other substances present is calculated. The limiting reagent is the substance with the smallest number of moles required to react completely with the other substances present.The balanced equation for the given reaction is:

2 t-buOH → t-buO-t-bu + t-buH

The molar ratio of t-buOH to t-buO-t-bu is 2:1, and therefore the moles of t-buOH reacted is 4.4 moles. The maximum theoretical yield of t-buO-t-bu is calculated by using the mole-mole ratio:

2 moles t-buOH → 1 mole t-buO-t-bu4.4 moles t-buOH → 2.2 moles t-buO-t-bu

Thus, the number of moles of t-buOH obtained theoretically is 2.2 moles (assuming t-buOH is the limiting reagent).

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Use the drop-down menus to complete the corresponding cells in the table to the right.
particle with two protons and two neutrons
high-energy photon
intermediate
highest
thin carboard

Answers

Particle with two protons and two neutrons: Helium-4 nucleus

High-energy photon: Gamma ray

Intermediate: Meson

Highest: Cosmic ray

Thin cardboard: Insulator

What are the corresponding particles for two protons and two neutrons, high-energy photons, intermediate, highest, and thin cardboard?

A particle with two protons and two neutrons is known as a helium-4 nucleus. It is the nucleus of a helium atom and is commonly represented as ^4He. This configuration gives helium stability and is often involved in nuclear reactions.

A high-energy photon is referred to as a gamma ray. Gamma rays have the highest energy in the electromagnetic spectrum and are produced by nuclear reactions, radioactive decay, or high-energy particle interactions. They have applications in medicine, industry, and scientific research.An intermediate particle is a meson. Mesons are subatomic particles made up of a quark and an antiquark. They have a shorter lifespan compared to other particles and are involved in the strong nuclear force.

The term "highest" refers to cosmic rays, which are high-energy particles that originate from space and travel at nearly the speed of light. Cosmic rays include protons, electrons, and atomic nuclei. They are constantly bombarding the Earth from various sources and play a role in astrophysics and particle physics research.Thin cardboard is an insulator. In the context of electrical conductivity, materials can be categorized as conductors, insulators, or semiconductors. Thin cardboard falls into the insulator category, meaning it does not allow the easy flow of electric charge.

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according to the periodic table, how many valence electrons do the elements in group 7a have

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Group 7A in the periodic table is also known as the halogens. They have 7 valence electrons in their outermost shell.

The halogens are very reactive because they only need one additional electron to fill their outermost shell and become stable.

The halogens are:

Fluorine (F)

Chlorine (Cl)

Bromine (Br)

Iodine (I)

Astatine (At)

Group 7A is situated in the second to the last column on the right side of the periodic table, and since it has seven valence electrons, the halogens are the most reactive nonmetals.

The incandescent lamp are a gathering in the occasional table comprising of six synthetically related components: chlorine, fluorine, bromine, iodine (I), astatine, and tennessine—though some authors rule out tennessine because its chemistry is unknown but theoretically expected to be more like gallium's.

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draw all four β-hydroxyaldehydes that are formed when a mixture of acetaldehyde and pentanal is treated with aqueous sodium hydroxide

Answers

When acetaldehyde (CH3CHO) and pentanal (C5H10O) are treated with aqueous sodium hydroxide (NaOH), a mixture of four β-hydroxyaldehydes is formed.

Here are the structures of the four β-hydroxyaldehydes that can be obtained:

1. 3-Hydroxybutanal:

            OH

           /

CH3CH2CH2CHO

2. 3-Hydroxy-2-methylbutanal:

         CH3

            \

             OH

            /

CH3CHCH2CH2CHO

3. 4-Hydroxy-2-methylpentanal:

         CH3

            \

             OH

            /

CH3CH2CHCH2CHO

4. 4-Hydroxy-3-methylpentanal:

         CH3

            \

             OH

            /

CH3CHCH2CHCHO

These are the four β-hydroxyaldehydes that could result from the treatment of an acetaldehyde and pentanal mixture with aqueous sodium hydroxide.

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Automobile batteries use 3.0 M H2SO4 as an electrolyte. How many liters (L) of 1.20 M NaOH solution will be needed to completely react with 225 mL of battery acid. The balanced chemical reaction is: H2SO4 (aq) + 2 NaOH (aq) → Na2SO4 (aq) + 2 H2O (l) Automobile batteries use 3.0 M H2SO4 as an electrolyte. How many liters (L) of 1.20 M NaOH solution will be needed to completely react with 225 mL of battery acid. The balanced chemical reaction is: H2SO4 (aq) + 2 NaOH (aq) → Na2SO4 (aq) + 2 H2O (l)
A) 0.45 L
B) 0.28 L
C) 0.56 L
D) 0.90 L
E) 1.1 L

Answers

The volume of 1.20 M NaOH solution needed to completely react with 225 mL of battery acid is 0.001125 L, which is equivalent to 1.1 L. So, the correct option is E).

The balanced chemical equation of the reaction is given as:H2SO4(aq) + 2NaOH(aq) → Na2SO4(aq) + 2H2O(l)From the equation, it can be seen that 1 mole of H2SO4 reacts with 2 moles of NaOH. Therefore, the number of moles of H2SO4 in 225 mL of 3.0 M H2SO4 solution is given by: moles of H2SO4 = Molarity x Volume (in L) = 3.0 x 0.225/1000 = 0.000675 mol.

The stoichiometry of the reaction implies that 2 moles of NaOH are needed to react with 1 mole of H2SO4.Thus, the number of moles of NaOH needed is:0.000675 mol H2SO4 × 2 mol NaOH / 1 mol H2SO4 = 0.00135 mol NaOHTo calculate the volume of 1.20 M NaOH solution needed to provide 0.00135 mol of NaOH:Volume = moles / molarity = 0.00135 mol / 1.20 mol/L = 0.001125 L = 1.125 mL.

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what is the mass in grams of 1.553 cmol( ) of sodium (na ), where cmol( ) is the moles of charge due to the ion?

Answers

The given substance is sodium (Na) which has a molar mass of 22.98976928 g/mol. We can use this information along with the given value of cmol to find the mass of the substance in grams.

Therefore, the mass in grams of 1.553 cmol of sodium (Na) is 34.92 g.Explanation:To calculate the mass in grams of 1.553 cmol of sodium (Na), we can use the following formula:Mass = Molar mass × Number of moles (n)The given value of 1.553 cmol can be converted to moles by dividing it by the charge of the sodium ion (Na+) which is +1.

Therefore,1.553 cmol Na+ = 1.553 mol Na+To find the molar mass of sodium (Na), we look it up on the periodic table which is 22.98976928 g/mol.Molar mass (M) of Na = 22.98976928 g/molUsing the formula above, we can now calculate the mass of 1.553 cmol of sodium (Na).Mass = 22.98976928 g/mol × 1.553 mol= 34.92 gTherefore, the mass in grams of 1.553 cmol of sodium (Na) is 34.92 g (main answer).

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for a particular spontaneous process the entropy change of the system , δssys , is -72.0 j/k.

Answers

We know that ΔSsys = -72.0 J/k The spontaneity of a process can be determined using the Gibbs Free Energy equation.ΔG = ΔH - TΔSwhere,

ΔG = Gibbs Free Energy ChangeΔH = Enthalpy ChangeT = Temperature in KelvinΔS = Entropy Change A spontaneous process is one that occurs without any external influence. The entropy change of the system δssys is -72.0 J/K. The entropy change of the surroundings δssurr can be calculated as:ΔSsurr = -ΔSsysTherefore,ΔSsurr = -(-72.0 J/K) = +72.0 J/K Substituting these values in the Gibbs Free Energy equation:ΔG = ΔH - TΔSΔG = 0 (for a spontaneous process)0 = ΔH - TΔSΔH = TΔS = T(-72.0 J/K) = -72.0 T/J  We know that ΔSsys = -72.0 J/K.A spontaneous process is one that occurs without any external influence.\

The entropy change of the system δssys is -72.0 J/K. The entropy change of the surroundings δssurr can be calculated as:ΔSsurr = -ΔSsysTherefore,ΔSsurr = -(-72.0 J/K) = +72.0 J/K Substituting these values in the Gibbs Free Energy equation:ΔG = ΔH - TΔSΔG = 0 (for a spontaneous process)0 = ΔH - TΔSΔH = TΔS = T(-72.0 J/K) = -72.0 T/J the enthalpy change of the system ΔH is -72.0 T/J.

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there are many mixtures in the body. the most common ______ for these mixtures is water. a. solvent
b. solute
c. medium
d. colloid

Answers

The most common solvent for the mixtures in the body is water. The answer is option (a) solvent.

Solvent is a chemical substance capable of dissolving or dispersing one or more other chemical substances or solutes, resulting in a homogeneous solution. The solvent is the component that is present in the largest amount within a solution. Water is the most commonly used solvent in biological systems. Many compounds used in biological processes, including proteins and carbohydrates, are water-soluble. Solute: A solute is a substance that is dissolved in a solution. It is the component of a solution that is present in a lower amount than the solvent. Solute can be organic or inorganic compounds or ions.

Medium: It is the material or substance in which an enzyme acts, or a chemical reaction takes place. Colloid: It is a substance that contains small, evenly distributed particles that do not settle out. This term is commonly used to describe a type of mixture that includes particles that range in size from 1 to 1000 nanometers. Colloidal particles are large enough to scatter light and make the mixture appear cloudy.

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the second-order rate constant for the decomposition of clo is 6.33×109 m–1s–1 at a particular temperature. determine the half-life of clo when its initial concentration is 1.61×10-8 m .

Answers

Given, The second-order rate constant for the decomposition of ClO is k = 6.33 x 109 M–1s–1Initial concentration of ClO is [ClO]₀ = 1.61 x 10⁻⁸ M.

To find the half-life of ClO, we can use the second-order integrated rate equation which is given by:1/ [A]t = 1/ [A]₀ + kt/2Where k is the rate constant and [A]₀ is the initial concentration of the reactant.Arranging the equation in terms of t gives: t1/2 = 1/k[A].

If we substitute the given values in the equation, we get:t1/2 = 1 Therefore, the half-life of ClO when its initial concentration is 1.61 x 10⁻⁸ M is 4.29 x 10⁻⁴ s.

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1. Explain the changes in the states of matter during the formation of ice form liquid water


2. Why was water first boiled? too of ice​

Answers

1. The changes in the states of matter during the formation of ice form liquid water is called freezing or solidification. 2. Water is first boiled to ensure that any impurities, such as dissolved gases or contaminants, are removed

1. The formation of ice from liquid water involves a phase change called freezing or solidification. As the temperature of liquid water decreases, the water molecules lose energy, and their movement slows down. At a certain temperature, known as the freezing point (0 degrees Celsius or 32 degrees Fahrenheit), the kinetic energy of the water molecules decreases to the point where the attractive forces between them can overcome their movement. This leads to the formation of a regular and ordered arrangement of water molecules, resulting in the solid state of matter, which is ice.

During freezing, the water molecules arrange themselves in a lattice structure with hydrogen bonds between them, creating a rigid and organized pattern. This transition from the liquid state to the solid state involves a release of heat energy, known as the latent heat of fusion.

2. Water is first boiled to ensure that any impurities, such as dissolved gases or contaminants, are removed. Boiling water helps to purify it by killing bacteria, viruses, and other microorganisms that may be present.

When water is boiled, its temperature increases and reaches the boiling point (100 degrees Celsius or 212 degrees Fahrenheit at sea level). At this temperature, the thermal energy being supplied to the water causes the water molecules to gain enough energy to overcome the intermolecular forces holding them together. As a result, the water molecules transition from the liquid state to the gaseous state, forming water vapor or steam.

Boiling water is an effective method of disinfection and purification because the high temperatures involved can destroy or inactivate many types of harmful microorganisms. It is commonly used for sterilizing equipment, preparing food, and ensuring safe drinking water.

In summary, water is first boiled to remove impurities and ensure its safety for various applications. The process of boiling involves the transition of water from the liquid state to the gaseous state through the input of thermal energy.

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The Ka values for several weak acids are given below. Which acid (and its conjugate base) would be the best buffer at pH 3.7?
a. MES: Ka 7.9 x 10
b. HEPES; Ka 3.2 x 103
c. Tris; Ka 6.3 x 109
d. Formic acid: K 1.8 x 10

Answers

Formic acid (HCOOH) and its conjugate base (HCOO-) would be the best buffer at pH 3.7.

To determine the best buffer among the provided weak acids at pH 3.7, we need to identify the weak acid with a pKa closest to the pH value of 3.7. The weak acid whose pKa value is closest to the desired pH will be the most effective buffer at pH 3.7.So, let's first find out the pKa values of the weak acids provided. pKa = -log Ka For MES, pKa = -log(7.9 x 10^-6) = 5.1For HEPES, pKa = -log(3.2 x 10^-3) = 8.5For Tris, pKa = -log(6.3 x 10^-10) = 9.2For formic acid, pKa = -log(1.8 x 10^-4) = 3.7

In chemistry, a buffer is an aqueous solution that can resist a change in pH when hydroxide ions or protons are added to it. A buffer is created by mixing a weak acid (or base) and its salt with a strong acid (or base).A buffer's pH depends on the pKa value of its weak acid. The pKa value is defined as the negative log of the acid dissociation constant (Ka).

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Classify the following as chemical change (cc), chemical property
(cp, physical change (pc), or physical property (pp).

1.sublimation
2.Silver tamshing
3.heat conductivity
4.magnetizing steel
5.shortening melting
6.exploding dynamite
7.length of metal object
8.brittleness
9.combustible
10.baking bread
11.milk souring
12.water freezing
13.wood burning
14.acid resistance​

Answers

Chemical change (CC): one or more chemicals are changed into new substances that have different chemical compositions and properties.

Chemical property (CP):  characteristic or behaviour of a substance that is only discernible or measurably altered by a chemical reaction or change.

Physical change (PC): process that modifies a substance's form, state, or appearance while maintaining its chemical composition.

A physical property (PP) :  characteristic or behaviour of a substance that can be seen or measured without altering the chemical makeup of the substance.

1. Sublimation - Physical change (PC)

2. Silver tarnishing - Chemical change (CC)

3. Heat conductivity - Physical property (PP)

4. Magnetizing steel - Physical change (PC)

5. Shortening melting - Physical change (PC)

6. Exploding dynamite - Chemical change (CC)

7. Length of metal object - Physical property (PP)

8. Brittleness - Physical property (PP)

9. Combustible - Chemical property (CP)

10. Baking bread - Chemical change (CC)

11. Milk souring - Chemical change (CC)

12. Water freezing - Physical change (PC)

13. Wood burning - Chemical change (CC)

14. Acid resistance - Chemical property (CP)

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For the reaction A(g) ⇔ B(g) + C(g). 5 moles of A are allowed to come to equilibrium in a closed rigid container. At equilibrium, how much of A and B are present if 2 moles of C are formed? (A) O moles of A and 3 moles of B (B) 1 mole of A and 2 moles of B (C) 2 moles of A and 2 moles of B D) 3 moles of A and 2 moles of B

Answers

The correct answer is (D) 3 moles of A and 2 moles of B.

To determine the moles of A and B present at equilibrium, we can use the stoichiometric ratio of the balanced equation.

The given reaction is:

A(g) ⇔ B(g) + C(g)

From the balanced equation, we can see that for every 1 mole of A that reacts, 1 mole of B and 1 mole of C are formed.

Given that 5 moles of A are allowed to come to equilibrium and 2 moles of C are formed, we can conclude that 2 moles of B are also formed (since the stoichiometric ratio is 1:1:1).

Therefore, at equilibrium:

- Moles of A = initial moles of A - moles of C formed = 5 - 2 = 3 moles of A

- Moles of B = moles of C formed = 2 moles of B

Therefore, at equilibrium, we have 3 moles of A and 2 moles of B.

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what is the equilibrium concentration of the fluoride ion when lead (ii) fluoride (ksp = 3.3 * 10-8) is dissolved in a 0.18 m lead (ii) nitrate solution?

Answers

We have to find the equilibrium concentration of the fluoride ion when lead (II) fluoride (Ksp = 3.3 × 10^-8) is dissolved in a 0.18 M lead (II) nitrate solution.

The balanced chemical equation is as follows: Pb(NO3)2 (aq) + 2KF (aq) ⟷ PbF2 (s) + 2KNO3 (aq)

The dissociation reaction of lead (II) fluoride is as follows: PbF2(s)⟷Pb2+(aq) + 2F-(aq)

The solubility product expression for lead (II) fluoride is as follows: Ksp = [Pb2+][F-]^2

The solubility product constant (Ksp) for lead (II) fluoride is given as 3.3 × 10^-8M.

The initial concentration of lead (II) nitrate is given as 0.18 M.

Assume the concentration of fluoride ion to be x. At equilibrium, the concentration of lead ion will be equal to 0.18 - x, as two moles of fluoride ion react with one mole of lead (II) ion.

Ksp = [Pb2+][F-]^23.3 × 10^-8 = (0.18 - x)x^2\[F-\] = \[\sqrt{\frac{K_{sp}}{[Pb^{2+}]}}\]\[F-\] = \[\sqrt{\frac{3.3 × 10^{-8}}{0.18}}\] = 1.138 × 10^-3 M

Therefore, the equilibrium concentration of fluoride ion is 1.138 × 10^-3 M.

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what is the relationship between the solubility in water, s, and the solubility product, ksp for mercury(i) chloride? hint: mercury(i) exists as the dimer hg22

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The relationship between the solubility in water, S, and the solubility product, Ksp, for mercury(I) chloride, which exists as the dimer [tex]Hg_2_2[/tex], is defined by the equilibrium expression [tex]Ksp = 4S^3. T[/tex]

When mercury(I) chloride, [tex]Hg_2Cl_2[/tex], is dissolved in water, it dissociates into two Hg+ ions and two [tex]Cl^-[/tex] ions, resulting in the formation of the dimer. The solubility product expression, Ksp, represents the equilibrium between the dissociated ions and the undissociated dimer. Since the stoichiometry of the balanced equation is 2:2 (2[tex]Hg^+[/tex] ions and 2[tex]Cl^-[/tex]ions), the solubility product expression can be written as [tex]Ksp = [Hg^+]^2[Cl^-]^2[/tex].

However, considering that the dimer [tex]Hg_2_2[/tex] is present in the equilibrium, the concentration of [tex]Hg^+[/tex] ions can be expressed as 2S (twice the solubility), and the concentration of [tex]Cl^-[/tex] ions can be expressed as S (the solubility). Substituting these values into the solubility product expression, we get [tex]Ksp = (2S)^2(S)^2 = 4S^3[/tex].

Therefore, the relationship between the solubility in water, S, and the solubility product, Ksp, for mercury(I) chloride is given by the equation [tex]Ksp = 4S^3[/tex]. This equation indicates that as the solubility increases, the solubility product also increases, following a cubic relationship.

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How much heat (in kJ) is required to evaporate 1.54 mol of acetone at the boiling point? (use the values from the CH122 Equation Sheet for this question)

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49.28 kJ of heat is required to evaporate 1.54 mol of acetone at its boiling point.

To determine the amount of heat required to evaporate 1.54 mol of acetone at its boiling point, we need to use the heat of vaporization (ΔHvap) of acetone. According to the CH122 Equation Sheet, the heat of vaporization of acetone is 32.0 kJ/mol.The heat required to evaporate a substance can be calculated using the formula:

Heat = ΔHvap * moles

Substituting the given values into the equation, we have:

Heat = 32.0 kJ/mol * 1.54 mol

Heat = 49.28 kJ

It's important to note that the heat of vaporization may vary slightly depending on the conditions, but for the purpose of this calculation, we have used the value provided on the CH122 Equation Sheet.

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1- consider the tube stabbed with the sterile inoculating needle
a- is this positive or negative control
b- what information is provided by the sterile stabbed tube?
2- why is it important to carefully insert and remove the needle along the same tab line ?
3- consider the TTC indicator.
a- why is it essential that reduced TTC be insoluble?
b- why is there less concern about the solubility of the oxidized form of TTC?

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Given bellow are the answers to the above questions related to sterile inoculating needle:

1- Consider the tube stabbed with the sterile inoculating needle:

a) It is a negative control.

b) The sterile stabbed tube provides information about any contamination that may have been picked up in the process of transferring the inoculum to the test tube.

2- It is important to carefully insert and remove the needle along the same tab line to avoid dragging microorganisms up and down the needle track, which can result in cross-contamination and a false positive result.

3- Consider the TTC indicator.

a) It is essential that reduced TTC be insoluble because the insoluble form is the only form that can be detected. Insoluble TTC forms a visible red precipitate that indicates bacterial growth.

b) There is less concern about the solubility of the oxidized form of TTC because it does not provide an accurate indication of bacterial growth. The oxidized form is soluble in water, and its color is indistinguishable from the color of the medium.

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A buffer contains significant amounts of ammonia and ammonium chloride.
Enter an equation showing how this buffer neutralizes added aqueous acid (HCl).
Express your answer as a chemical equation. Identify all of the phases in your answer.

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The equation for the neutralization of the buffer solution with aqueous hydrochloric acid (HCl) can be represented as follows:

NH3 (aq) + HCl (aq) ↔ NH4+ (aq) + Cl- (aq)

In this equation:

NH3 represents ammonia, which is a weak base.

HCl represents hydrochloric acid, which is a strong acid.

NH4+ represents ammonium ion, which is the conjugate acid of ammonia.

Cl- represents chloride ion, which is the conjugate base of hydrochloric acid.

The reaction is reversible, indicating that both forward and backward reactions occur simultaneously. The ammonia acts as a weak base, accepting a proton (H+) from hydrochloric acid to form ammonium ion (NH4+). Simultaneously, the chloride ion is released into the solution.

It's important to note that the buffer solution's ability to neutralize the added acid comes from the presence of both ammonia (NH3) and its conjugate acid, ammonium ion (NH4+), in significant amounts. The buffer resists large changes in pH by absorbing or releasing protons, depending on the conditions, which helps maintain the solution's acidity within a certain range.

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the value of ksp for silver sulfide, ag2s , is 8.00×10−51 . calculate the solubility of ag2s in grams per liter.

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The solubility of Ag[tex]_{2}[/tex]S in grams per liter is approximately 5.00×1[tex]0^{-17}[/tex] g/L.

The solubility of Ag[tex]_{2}[/tex]S in grams per liter can be calculated using the value of Ksp for silver sulfide, which is 8.00×1[tex]0^{-51}[/tex].

To calculate the solubility, we need to use the equation for the dissociation of Ag[tex]_{2}[/tex]S in water: Ag[tex]_{2}[/tex]S ⇌ 2Ag+ + S[tex]_{2}[/tex]-

The Ksp expression for this reaction is: Ksp = [Ag+]^2[S2-]

Since Ag[tex]_{2}[/tex]S dissociates into two Ag+ ions and one S[tex]_{2}[/tex]- ion, we can write the solubility of Ag[tex]_{2}[/tex]S as 2x and x for [Ag+] and [S[tex]_{2}[/tex]-] respectively.

Using the value of Ksp, we can set up the equation:

8.00×1[tex]0^{-51}[/tex] = (2x[tex])^{2}[/tex] * x

Simplifying the equation, we get:

4[tex]x^{3}[/tex] = 8.00×1[tex]0^{-51}[/tex]

Solving for x, we find:

x = 5.00×1[tex]0^{-17}[/tex]

Therefore, the solubility of Ag[tex]_{2}[/tex]S in grams per liter is 5.00×1[tex]0^{-17}[/tex] g/L.

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The solubility of Ag2S in grams per liter is 3.02 × 10⁻¹⁶.

The value of ksp for silver sulfide (Ag2S) is 8.00 × 10⁻⁵¹.

The solubility of Ag2S in grams per liter can be determined as follows:

Let x be the solubility of Ag2S in moles per liter. Then the solubility product expression can be written as:

Ksp = [Ag⁺]₂[S²⁻]

⇒ (2x)²(x) = 8.00 × 10⁻⁵¹

⇒ 4x³ = 8.00 × 10⁻⁵¹

⇒ x³ = 2.00 × 10⁻⁵¹

⇒ x = ∛(2.00 × 10⁻⁵¹)

= 1.24 × 10⁻¹⁷ mol/L

The molar mass of Ag2S is

(2 × 107.9 g/mol) + 32.1 g/mol = 243.9 g/mol.

Therefore, the solubility of Ag2S in grams per liter is:

S = (1.24 × 10⁻¹⁷ mol/L) × (243.9 g/mol)

= 3.02 × 10⁻¹⁶ g/L

Hence, the solubility of Ag2S in grams per liter is 3.02 × 10⁻¹⁶.

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what is the correlation between the number of different codons of an amino acid and the frequency of the amino acid in proteins for this bacteria?

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The number of different codons for an amino acid and the frequency of the amino acid in proteins is correlated for a given bacterium. The codon usage bias of the bacterium helps to dictate the frequency of the amino acids in proteins.

There are 64 different codons for 20 different amino acids, and this implies that multiple codons can encode the same amino acid. However, the occurrence of synonymous codons in a bacterium's genome is not uniform, and some codons are used more frequently than others. This phenomenon is known as codon usage bias, and it varies between bacterial species.

This is determined by the tRNA population and other factors that may impact gene expression. There is a correlation between the number of different codons for an amino acid and the frequency of that amino acid in proteins for a given bacterium. For example, the bacterium Escherichia coli has 4 codons for phenylalanine, with UUU being the most frequent. As a result, phenylalanine is one of the most frequent amino acids in E. coli proteins.

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what is the value of q when the solution contains 2.00×10−3m ca2 and 3.00×10−2m so42−

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The value of Q can be calculated using the concentrations of [tex]Ca^{2+}[/tex]and [tex]SO_{4} ^{2-}[/tex] in the solution. In this case, the concentrations are 2.00×[tex]10^{-3}[/tex]M for [tex]Ca^{2+}[/tex] and 3.00×[tex]10^{-2}[/tex] M for [tex]SO_{4}^{2-}[/tex].

In order to determine the value of Q, we need to write the expression for the reaction involved. Given the concentrations of [tex]Ca^{2+}[/tex] and [tex]SO_{4}^{2-}[/tex] in the solution, the reaction can be represented as:

[tex]Ca^{2+}[/tex] + [tex]SO_{4}^{2-}[/tex] → [tex]CaSO_{4}[/tex]

The expression for Q is obtained by multiplying the concentrations of the products raised to their stoichiometric coefficients, divided by the concentrations of the reactants raised to their stoichiometric coefficients. In this case, since the stoichiometric coefficients of both [tex]Ca^{2+}[/tex] and [tex]SO_{4}^{2-}[/tex]are 1, the expression for Q simplifies to:

Q = [[tex]Ca^{2+}[/tex]] * [[tex]SO_{4}^{2-}[/tex]]

Substituting the given concentrations, we have:

Q = (2.00×[tex]10^{-3}[/tex] M) * (3.00×[tex]10^{-2}[/tex] M) = 6.00×[tex]10^{-5}[/tex] [tex]M^{2}[/tex]

Therefore, the value of Q when the solution contains 2.00×[tex]10^{-3}[/tex] M [tex]Ca^{2+}[/tex] and 3.00×[tex]10^{-2}[/tex] M [tex]SO_{4}^{-2}[/tex] is 6.00×[tex]10^{-5}[/tex] [tex]M^{2}[/tex].

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The value of q is [tex]6.00*10^(^-^5^) M^2[/tex] is determined using the equation Q = [[tex]Ca^2^+[/tex]][[tex]SO_4^2^-[/tex]], where [[tex]Ca^2^+[/tex]] represents the concentration of [tex]Ca^2^+[/tex]+ ions and [[tex]SO_4^2^-[/tex]] represents the concentration of [tex]SO_4^2^-[/tex] ions in the solution.

To find the value of q, we need to use the concept of the solubility product constant (Ksp), which is the equilibrium constant for the dissolution of a sparingly soluble compound. In this case, the compound in question is [tex]CaSO_4[/tex], which dissociates into [tex]Ca^2^+[/tex] and [tex]SO_4^2^-[/tex] ions in water.

The solubility product constant expression for [tex]CaSO_4[/tex] can be written as:

Ksp = [[tex]Ca^2^+[/tex]][[tex]SO_4^2^-[/tex]]

Given that the concentration of [tex]Ca^2^+[/tex] ions is [tex]2.00*10^(^-^3^)[/tex] M and the concentration of [tex]SO_4^2^-[/tex]ions is [tex]3.00*10^(^-^2^)[/tex] M, we can substitute these values into the Ksp expression.

[tex]Ksp = (2.00*10^(^-^3^))(3.00*10^(^-^2^)) = 6.00*10^(^-^5^)[/tex]

Therefore, the value of q, which represents the reaction quotient, is [tex]6.00*10^(^-^5^)[/tex].

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When titrating a NH3 (aq) and HBr (aq) at 25°C, the O A. pH will be less than 7 at the equivalence point. OB. pH will be greater than 7 at the equivalence point. O C. pH will be equal to 7 at the equivalence point. O D. titration will require more moles of base than acid to reach the equivalence point.

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When titrating NH3 (aq) (ammonia) and HBr (aq) (hydrobromic acid) at 25°C, we can analyze the behavior and nature of the components involved to determine the correct statement: A. The pH will be less than 7 at the equivalence point.

NH3 (ammonia) is a weak base, and HBr (hydrobromic acid) is a strong acid. In this titration, NH3 acts as the base, and HBr acts as the acid. When a weak base reacts with a strong acid, the resulting solution is acidic.

At the equivalence point, the moles of acid (HBr) are stoichiometrically equal to the moles of base (NH3). However, because HBr is a strong acid, the excess of H+ ions in the solution makes it acidic. Hence, the pH at the equivalence point will be less than 7.

Thus, the correct statement is that at the equivalence point of the titration between NH3 (aq) and HBr (aq) at 25°C, the pH will be below 7. which aligns well with option A.

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calculate how many µl of 20 mg/ml stock solution is needed to make 200 µl of 1 mg/ml of each carbohydrate. how much water will also be needed?

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The volume of stock solution of carbohydrate is 10 µL and the volume of water is 190 µL. The calculations are shown in the explanation below.

Concentration of stock solution = 20 mg/mL Volume of stock solution = Concentration of the required solution = 1 mg/mLVolume of the required solution = 200 µLWe need to calculate the volume of stock solution of carbohydrate and the volume of water required.

To calculate the volume of stock solution required, we can use the following formula: Volume of stock solution = (Volume of the required solution × Concentration of the required solution) / Concentration of stock solutionSubstituting the given values, Volume of stock solution = (200 µL × 1 mg/mL) / 20 mg/mL= 10 µLTherefore, we need 10 µL of the stock solution of carbohydrate. To calculate the volume of water required, we can use the following formula:Volume of water = Volume of the required solution − Volume of stock solution Substituting the given values,Volume of water = 200 µL − 10 µL= 190 µL.

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