H2S(g) 2H2O(l)3H2(g) SO2(g) Using standard absolute entropies at 298K, calculate the entropy change for the system when 1.60 moles of H2S(g) react at standard conditions.

Answers

Answer 1

Answer: [tex]\Delta S[/tex] = 473.92J/K.mol

Explanation: In physics, Entropy is defined as a degree of disorder in a system. Entropy change is given by the sum of all the products multiplied by their respective coeficients minus the sum of all the reagents multiplied by their respective coeficients:

[tex]\Delta S = m\Sigma product - n\Sigma reagent[/tex]

The balanced reaction:

[tex]H_{2}S_{(g)}+2H_{2}O_{(l)}=>3H_{2}_{(g)}+SO_{2}_{(g)}[/tex]

gives the proportion reagents react to form products, so, if 1.6 moles of [tex]H_{2}S_{(g)}[/tex]:

3.2 moles of water is used;

4.8 moles of hydrogen gas is formed;

1.6 moles of sulfur dioxide is also formed;

Calculating entropy change:

[tex]\Delta S = (4.8*131+1.6*248.8)-(1.6*205.6+3.2*70)[/tex]

[tex]\Delta S=628.8+398.08-328.96-224[/tex]

[tex]\Delta S[/tex] = 473.92J/K.mol

Entropy change for the given chemical reaction is [tex]\Delta S[/tex] = 473.92J/K.mol


Related Questions

g A chemist combines 59.9 mL of 0.282 M potassium bromide with 15.4 mL of 0.512 M silver nitrate. (a) How many grams of silver bromide will precipitate

Answers

Answer:

[tex]m_{AgBr}=1.48gAgBr[/tex]

Explanation:

Hello,

In this case, the undergoing chemical reaction is:

[tex]KBr(aq)+AgNO_3(aq)\rightarrow AgBr(s)+KNO_3(aq)[/tex]

Thus, since the potassium bromide and silver nitrate are in a 1:1 mole ratio, the first step is to identify the limiting reactant, by considering the reacting volumes of reactants in order to compute the available moles of potassium bromide and the moles of potassium bromide consumed by the 15.4 mL of 0.512-M solution of silver nitrate:

[tex]n_{KBr}=0.0599L*0.282\frac{molKBr}{L} =0.0169molKBr\\\\n_{KBr}^{consumed}=0.0154L*0.512\frac{molAgNO_3}{L} *\frac{1molKBr}{1molAgNO_3}=0.00788molKBr[/tex]

In such a way, since less moles are consumed than available, we infer that silver nitrate is the limiting reactant, for which the resulting grams of silver bromide (molar mass 187.8 g/mol) result:

[tex]m_{AgBr}=0.00788molAgNO_3*\frac{1molAgBr}{1molAgNO_3} *\frac{187.8gAgBr}{1molAgBr} \\\\m_{AgBr}=1.48gAgBr[/tex]

Best regards.

There are 2.4g of calcium hydroxide reacted with nitric acid. Calculate the number of moles of calcium hydroxide used. Write your answer using proper significant digits and units. Show all your work.

Answers

Answer:

0.032 moles

Explanation:

no of moles =

[tex] \frac{mass \: in \: grams}{relative \: molecular \: mass} [/tex]

=

[tex] \frac{2.4}{40 + 32 + 2} [/tex]

= 0.032

Calcium hydroxide reacted with nitric acid the total number of moles will be 0.032 moles.

What is a mole?

A mole is Avogadro's number of particles, which is exactly 6.02214076×1023.

The mole is widely used in chemistry as a convenient way to express amounts of reactants and products of chemical reactions. For example, the chemical equation 2H2 + O2 → 2H2O can be interpreted to mean that for each 2 mol dihydrogen (H2) and 1 mol dioxygen (O2) that react 2 mol of water (H2O) form.

Number of moles = Mass of substance / Mass of one mole Number of moles

mass of substance = 2.4g

molar mass of calcium hydroxide is  (1 ×40.078g/mol Ca) +(2 × 15.999g/mol O) + (2 × 1.008g/mol H) = 74.092 g/mol Ca (OH)2

substituting the value,

number of moles = 2.4 / 74.029

                          = 0.032 moles

Therefore, moles of calcium hydroxide will be 0.032 moles

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Heterocyclic aromatic compounds undergo electrophilic aromatic substitution in a similar fashion to that undergone by benzene with the formation of a resonance-stabilized intermediate. Draw all of the resonance contributors expected when the above compound undergoes bromination

Answers

Answer:

See explanation

Explanation:

When we talk about electrophilic substitution, we are talking about a substitution reaction in which the attacking agent is an electrophile. The electrophile attacks an electron rich area of a compound during the reaction.

The five membered furan ring is aromatic just as benzene. This aromatic structure is maintained during electrophilic substitution reaction. The attack of the electrophile generates a resonance stabilized intermediate whose canonical structures have been shown in the image attached.

What type of chemist exclusively studies most carbon compounds?
-biochemist
-physical chemist
-organic chemist
-inorganic chemist

Answers

Answer:

Organic chemist? I do not know.

Explanation:

Thanks you.

The type of chemist exclusively studies most carbon compounds are organic chemist. Therefore, option C is correct.

What is an organic chemist ?

The structure, characteristics, and reactivity of compounds containing carbon are studied by organic chemists. Additionally, they create novel organic materials with distinct features and uses.

Analytical capabilities, communication skills, and numeracy skills are three of the most important soft skills for an organic chemist.

Organic chemists often work in research and development in labs at universities, pharmaceutical, industrial, and biotechnology businesses, as well as government agencies, according to the American Chemical Society.

According to one assessment, organic chemistry is the hardest college course. According to certain statistics, almost one out of every two students in organic chemistry leave the course. The hopes of a medical career come tumbling down for those who fit this description. Organic chemistry is undoubtedly challenging.

Thus, option C is correct.

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A sample is found to contain 1.29×10-11 g of salt. Express this quantity in picograms

Answers

Answer:12.9e-12g or in short 12.9pg

Explanation:as p=1e-12

A certain covalent compound is named sulfur hexafluoride. What's the chemical formula for this compound? A. F6S2 B. F6S C. S2F6 D. SF6

Answers

Answer: The sulphur hexafluoride will have a chemical formula of [tex]SF_6[/tex]

Explanation:

A covalent compound is a compound where the sharing of electrons takes place between two elements which are non-metals.

The naming of covalent compound is given by:

1. The less electronegative element is written first.

2. The more electronegative element is written second. Then a suffix is added with it. The suffix added is '-ide'.

3. If atoms of an element is greater than 1, then prefixes are added which are 'mono' for 1 atom, 'di' for 2 atoms, 'tri' for 3 atoms and so on.

Thus sulphur hexafluoride will have a chemical formula of [tex]SF_6[/tex]

Answer:

D. sf6

Explanation:

3. What is the mass of an object with a volume of 4 L and a density of 1.25 g/mL?

Answers

Answer:

5000g

Explanation:

mass= density × volume

Since the unit of density here is g/mL, we need to convert the volume to mL.

1L= 1000mL

4L= 4 ×1000 = 4000 mL

Mass of object

= 1.25 ×4000

= 5000g

Answer:

5,000 grams

Explanation:

The mass of an object can be found by multiplying the volume by the density.

mass= volume * density

The density is 1.25 g/mL and the volume is 4 L.

First, we must convert the volume to mL. The density is given in grams per milliliter, but the volume is given in liters.

There are 1,000 mL per L. The volume is 4 L. Therefore, we can multiply 4 and 1,000.

4 * 1,000 = 4,000

The volume is 4,000 mL.

Now, find the mass of the object.

mass= volume * density

volume = 4,000

density= 1.25

mass= 4,000 * 1.25 = 5,000

Add the appropriate units for mass, in this case, grams, or g.

mass= 5,000 g

The mass of the object is 5,000 grams.

Assuming 100% dissociation, which of the following compounds is listed incorrectly with its van't Hoff factor i? Al2(SO4)3, i = 4 NH4NO3, i = 2 Mg(NO3)2, i = 3 Na2SO4, i = 3 Sucrose, i = 1

Answers

Answer:

- Aluminium sulfate Al2(SO4)3 dissociates in two aluminium ions and three sulfate ions, therefore, van't Hoff factor is 5 (incorrect).

Explanation:

Hello,

In this case, since the van't Hoff factor is related with the species that result from the ionization of a chemical compound, we can see that that

- Aluminium sulfate Al2(SO4)3 dissociates in two aluminium ions and three sulfate ions, therefore, van't Hoff factor is 5 (incorrect).

- Ammonium nitrate NH4NO3 dissociates in one ammonium ions and one nitrate ion, therefore, van't Hoff factor is 2 (correct).

- Sodium sulfate Na2SO4 dissociates in two sodium ions and one sulfate, therefore, van't Hoff factor is 3 (correct).

- Sucrose is not ionized, therefore, van't Hoff factor is 1 (correct).

Best regards.

Account for the change when NO2Cl is added using the reaction quotient Qc. Match the words in the left column to the appropriate blanks in the sentences on the right.
1. decreases
2. loss
3. Increases
4. greater
A. Disturbing the equilibrium by adding NO2Cl______Qc to a value_____than Kc.
B. To reach a new state of equilibrium, Qc therefore______which means that the denominator of the expression for Qc______.
C. To accomplish this, the concentration of reagents______, and the concentration of products_______.

Answers

Answer:

A. Disturbing the equilibrium by adding NO2Cl decreases Qc to a value less than Kc.

B. To reach a new state of equilibrium, Qc therefore increases which means that the denominator of the expression for Qc decreases.

C. To accomplish this, the concentration of reagents decreases, and the concentration of products increases.

Explanation:

Hello,

In this case, for the equilibrium reaction:

[tex]NO_2Cl(g)+NO(g)\rightleftharpoons NOCl(g)+NO_2(g)[/tex]

Whose equilibrium expression is:

[tex]Kc=\frac{[NO_2][NOCl]}{[NO_2Cl][NO]}[/tex]

The proper matching is:

A. Disturbing the equilibrium by adding NO2Cl decreases Qc to a value less than Kc, since the denominator becomes greater, therefore, Qc decreases.

B. To reach a new state of equilibrium, Qc therefore increases which means that the denominator of the expression for Qc decreases, since the lower the denominator, the higher Qc as it has the concentration of reactants.

C. To accomplish this, the concentration of reagents decreases, and the concentration of products increases, since the reactants must be consumed in order to reestablish equilibrium by shifting the reaction towards the products.

Best regards.

Chemistry
What is a chemical reaction

Answers

Answer:

A process that involves rearrangement

Explanation:

A chemical reaction is the process that involves rearrangement of the molecular or ironic structure of a substance, as a distinct from a change in physical form or a nuclear reaction.

Answer:

Explanation:

Chemistry

The chemical reaction H2(g) + ½ O2(g) → H2O(l) describes the formation of water from its elements.

The reaction between iron and sulfur to form iron(II) sulfide is another chemical reaction, represented by the chemical equation:

8 Fe + S8 → 8 FeS

The change in entropy for the surroundings in a situation where heat flows from a hotter system to a cooler surrounding is: ________

a. Greater than zero
b. Less than zero
c. Equal to zero
d. Impossible to predict

Answers

Answer:

A

Explanation:

The change in entropy for the surroundings in a situation where heat flows from a hotter system to a cooler surrounding is Greater than Zero.

Here the randomness of the molecules increase as the temperature of the surrounding increases.( it absorbs heat from the system).

Answer:

Option a (Greater than zero) is the correct answer.

Explanation:

The entropy transition can sometimes be due to something like the reconfiguration of atom or molecule through one sequence to the next. In the substances, there would be a corresponding increase throughout entropy mostly during response unless the compounds are still very much abnormal compared with the reaction mixture.

Some other three choices don't apply to either the situations in question. And the correct approach will be Options A.

Please tell the answer​

Answers

Answer:

see the photo

Explanation:

it was the answer

In a reversible reaction, the endothermic reaction absorbs ____________ the exothermic reaction releases. A. less energy than B. None of these, endothermic reactions release energy C. the same amount of energy as D. more energy than

Answers

Answer: C. the same amount of energy as

Explanation:

A reversible reaction is a chemical reaction where the reactants form products that, in turn, react together to give the reactants back.

Reversible reactions will reach an equilibrium point where the concentrations of the reactants and products will no longer change.

[tex]A+B\rightleftharpoons C+D[/tex]

Thus if forward reaction is exothermic i.e. the heat is released , the backward reaction will be endothermic i.e. the heat is absorbed and in same amount.

The amount of energy released will be equal and opposite in sign to the energy absorbed in that reaction.

Answer:

C.) the same amount of energy as

Explanation:

I got it correct on founders edtell

volume of percentage =
formula??​

Answers

Answer:

Volume percent is defined as: v/v % = [(volume of solute)/(volume of solution)] x 100%

Explanation:

Cite examples of how copper deposits occur. Choose one or more: A. as an agglomeration metal B. as a native metal C. in carbonate ore minerals D. in sulfide ore minerals

Answers

Answer:

A. as an agglomeration metal

B. as a native metal

D. in sulfide ore minerals

Explanation:

Copper is a metal with symbol Cu and atomic number 29. It has a pinkish-orange color and is malleable, ductile and has a high thermal and electrical conductivity. This is why it is often used in electrical appliances.

Copper exists as an agglomeration metal, as a native metal or in sulfide ore minerals such as Cu2S.

The examples of copper deposits are  agglomeration metal, as a native metal or in sulfide ore minerals. Option A, B, and D are correct.

 

Copper is a metal with high thermal and electrical conductivity. hence, it is often used in electrical appliances.

Copper found as an agglomeration metal, as a native metal or in sulfide ore minerals such as [tex]\bold { Cu_2S.}[/tex]

Therefore, the examples of copper deposits are  agglomeration metal, as a native metal or in sulfide ore minerals. Option A, B, and D are correct.

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Lead ions are toxic when absorbed into the body and can interfere with the neurological development of children. Based on what you learned in this lab activity, what substance might be added to an IV solution to remove Pb2 ions from the blood of a contaminated person

Answers

Answer:

The interpretation of the particular subject is covered in the subsection below in detail.

Explanation:

Large quantities of heavy substances like Lead ions become extremely poisonous when provided by a human. The administration of the medications recognized as "chelators" will eliminate these harmful chemicals from an infected individual's blood.However, here law enforcers calcium sodium polyacrylate seems to be the safest chelator in radiation sickness. It could be administered intravenously and attaches throughout the blood system with either the lead ions and afterward, removes the metal-chelator complicated from urine.

(a) Identify the name of the method used below for the separation.
(b) Give one more application of this method of separation.
(c) What is the name for the line at position B ?
(d) what conclusions can you draw about the colours present in sweets C and D ?

Answers

Answer:

(a) Chromatography

(b) DNA fingerprinting

(c) Origin

(d) Sweet C consists of more colours than sweet D.

  ii. The speed of colours in sweet C are proportional to one another, while that of colours in D is not.

Explanation:

Chromatography is one of the physical method of separating mixtures. This process composed of the ability of the constituents in a mixture to separate by virtue of rate of movement through a medium, thus separates into constituents.

It can be used to determine the soluble constituents of a given mixture. And for purification purpose.

A hypothetical metal crystallizes with the face-centered cubic unit cell. The radius of the metal atom is 198 picometers and its molar mass is 195.08 g/mol. Calculate the density of the metal in g/cm3.

Answers

Answer:

7.38 g/cm³ is the density of the metal

Explanation:

In a Face-centered cubic unit cell you have 4 atoms. Also, the edge length is √8×r (r is radius of the atom).

To solve this problem, we need first to calculate the volume of the unit cell and then, with molar mass calculate the mass of 4 atoms. As density is the ratio between mass and volume we can obtain this value.

Volume of the unit cell

Volume = a³

a = √8×r

(r = 198x10⁻¹²m)

a = 5.6x10⁻¹⁰ m

Volume = 1.756x10⁻²⁸ m³

1m = 100cm → 1m³ = (100cm)³:

1.756x10⁻²⁸ m³× ((100cm)³ / 1m³) =

1.756x10⁻²² cm³ → Volume of the unit cell in cm³Mass of the unit cell:

There are 4 atoms of gold:

4 atoms × (1mol / 6.022x10²³ atoms) = 6.64x10⁻²⁴ moles of gold

As 1 mole weighs 195.08g:

6.64x10⁻²⁴ moles of gold × (195.08g / mol) =

1.296x10⁻²¹g is the mass of the unit cellDensity of the metal:

1.296x10⁻²¹g / 1.756x10⁻²² cm³ =

7.38 g/cm³ is the density of the metal

The density of the metal is 7.40 g/cm³

In cubic crystal system, face-centered cubic FFC is the name given to sort of atom arrangement observed in which structure is made up of atoms organized in a cube with a portion of an atom in each corner and six extra atoms in the center of each cube face.

It is expressed by using the formula:

[tex]\mathbf{\rho = \dfrac{Z \times M}{N_A\times a^}}[/tex]

where;

[tex]\rho[/tex] = density of the metalZ = atoms coordination no = 4 (for FCC)Molar mass (M) = 195.8 g/molAvogadro's constant (NA) = 6.022 × 10²³ /mola = edge length

For face-centered cubic FFC;

The edge length  [tex]\mathbf{a =2 \sqrt{2}\times r }[/tex]

[tex]\mathbf{a =2 \sqrt{2}\times 198 \ pm }[/tex]

[tex]\mathbf{a =560.0285 \ pm }[/tex]

a = 5.60 × 10⁻⁸ cm

Replacing it into the previous equation, we have:

[tex]\mathbf{\rho = \dfrac{4 \times 195.8}{6.022 \times 10^{23} \times( 5.60 \times 10^{-8} )^3}}[/tex]

[tex]\mathbf{\rho = 7.40\ g/cm^3 }[/tex]

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A 10.00-mL aliquot of vinegar requires 16.95 mL of the 0.4874 M standardized NaOH solution to reach the end point of the titration. Demonstrate how to calculate the molarity of the vinegar solution (HC2H3O2). Show complete work below. Answer: 0.8261 M.

Answers

Answer:

0.8261 M.

Explanation:

We'll begin by writing the balanced equation for the reaction. This is given below:

HC2H3O2 + NaOH —> NaC2H3O2 + H2O

From the balanced equation above, we obtained the following:

Mole ratio of the acid, HC2H3O2 (nA) = 1

Mole ratio of the base, NaOH (nB) = 1

Data obtained from the question include the following:

Volume of acid, HC2H3O2 (Va) = 10 mL

Molarity of acid, HC2H3O2 (Ma) =..?

Volume of base, NaOH (Vb) = 16.95 mL Molarity of base, NaOH (Mb) = 0.4874 M

Finally, we shall determine the molarity of the acid solution, as follow:

MaVa/MbVb = nA/nB

Ma x 10 / 0.4874 x 16.95 = 1

Cross multiply

Ma x 10 = 0.4874 x 16.95

Divide both side by 10

Ma = (0.4874 x 16.95) /10

Ma = 0.8261 M.

Therefore, the molarity of the vinegar solution (HC2H3O2) is 0.8261 M.

Using the following diagram, determine which of the statements below is true: The activation energy for the forward reaction is −60 J. The overall energy change for the forward reaction is −20 J. The activation energy for the reverse reaction is −80 J. The overall energy change for the reverse reaction is −40 J.

Answers

Answer:its saturated   or  unsaturaded

Explanation:

Which of the following happens to a molecule of an object when the object is heated? (1 point)

Answers

Answer:

They get more energy, so they vibrate!

Explanation:

Determine the oxidation state for each of the elements below. The oxidation state of ... silver ... in ... silver oxide Ag2O ... is ... ___ . The oxidation state of sulfur in sulfur dioxide SO2 is ___ . The oxidation state of iron in iron(

Answers

Answer:

The oxidation state of silver in [tex]\rm Ag_2O[/tex] is [tex]+1[/tex].

The oxidation state of sulfur in [tex]\rm SO_2[/tex] is [tex]+4[/tex].

Explanation:

The oxidation states of atoms in a compound should add up to zero.

Ag₂O

There are two silver [tex]\rm Ag[/tex] atoms and one oxygen [tex]\rm O[/tex] atom in one formula unit of [tex]\rm Ag_2O[/tex]. Therefore:

[tex]\begin{aligned}&\rm 2 \times \text{Oxidation state of $\rm Ag$}+ \rm 1 \times \text{Oxidation state of $\rm O$} = 0\end{aligned}[/tex].

The oxidation state of oxygen in most compounds (with the exception of peroxides and fluorides) is [tex]-2[/tex]. Silver oxide [tex]\rm Ag_2O[/tex] isn't an exception. Therefore:

[tex]\begin{aligned}&\rm 2 \times \text{Oxidation state of $\rm Ag$}+ \rm 1 \times \text{Oxidation state of $\rm O$} = 0\\ &\rm 2 \times \text{Oxidation state of $\rm Ag$}+ \rm 1 \times (-2) = 0\end{aligned}[/tex].

Solve this equation for the (average) oxidation state of [tex]\rm Ag[/tex]:

[tex]\text{Oxidation state of $\rm Ag$} = 1[/tex].

SO₂

Similarly, because there are one sulfur [tex]\rm S[/tex] atom and two oxygen [tex]\rm O[/tex] atoms in each [tex]\rm SO_2[/tex] molecules:

[tex]\begin{aligned}&\rm 1\times \text{Oxidation state of $\rm S$}+ \rm 2 \times \text{Oxidation state of $\rm O$} = 0\end{aligned}[/tex].

The oxidation state of [tex]\rm O[/tex] in [tex]\rm SO_2[/tex] is also [tex]-2[/tex], not an exception, either.

Therefore:

[tex]\begin{aligned}&\rm 1 \times \text{Oxidation state of $\rm S$}+ \rm 2 \times \text{Oxidation state of $\rm O$} = 0\\ &\rm 1 \times \text{Oxidation state of $\rm S$}+ \rm 2 \times (-2) = 0\end{aligned}[/tex].

Solve this equation for the oxidation state of [tex]\rm S[/tex] here:

[tex]\text{Oxidation state of $\rm S$} = 4[/tex].

An unknown gas diffuses 5 times slower than that of H2.The moleculer mass of unknown gas is??

Answers

Answer:

50.

Explanation:

We can write Graham's Law of Diffusion as:

(Rate 1)^2 = Molecular Mass 2

--------------    -------------------------

(Rate 2)^2    Molecular Mass 1

So using the Given Information:

1^2  / (1/5)^2 = Molecular Mass of unknown gas / 2, so:

25 = M/2

M = 50.

Match the words below to the appropriate blanks in the sentences. Make certain each sentence is complete before submitting your answerβ-1,4- and α-1,6-glycosidicβ-1,4-glycosidicgalactosean unbranchedglucosea branchedfructoseα-1,6-glycosidicAmylose is ......... polymer of ....... units joined by ........ bonds. Amylopectin is ....... polymer of .......units joined by ........ bonds.

Answers

The words given are not clear, so the clear question is as follows:

Match the words below to the appropriate blanks in the sentences. Make certain each sentence is complete before submitting your answer:

A. β-1,4- and α-1,6-glycosidic

B. α-1,4-glycosidic

C. α-1,4-galactose

D. an unbranched glucose

E. a branched fructose

F. α-1,6-glycosidic

Amylose is ......... polymer of ....... units joined by ........ bonds.

Amylopectin is ....... polymer of .......units joined by ........ bonds.

Answer:

D. an unbranched glucose

C. α-1,4-galactose

B. α-1,4-glycosidic

E. a branched fructose

A. β-1,4- and α-1,6-glycosidic

F. α-1,6-glycosidic

Explanation:

Amylose and amylopectin are two types of polysaccharides that can be found in starch granules.

Amylose is linear or unbranched glucose polymer of α-1,4-galactose units that are joined by α-1,4-glycosidic.

Amylopectin is a branched fructose polymer of β-1,4- and α-1,6-glycosidic units joined by α-1,6-glycosidic bonds.

Hence, the correct answers in the sequential order are:

Amylose:

D. an unbranched glucose

C. α-1,4-galactose

B. α-1,4-glycosidic

Amylopectin:

E. a branched fructose

A. β-1,4- and α-1,6-glycosidic

F. α-1,6-glycosidic

Please help, Which molecule is shown below

Answers

Answer:

Option B. 3–methylheptane.

Explanation:

To obtain the name of the compound given in the question above, we must

1. Determine the functional group of the compound.

2. Locate the longest continuous carbon chain. This gives the parent name of the compound.

3. Identify the substituent groups attached.

4. Locate the position of the substituent group attached by giving it the lowest possible count.

5. Combine the above to obtain the name.

Now let us name the compound given in the question above.

1. The compound is an alkane since it contains only single bond.

2. The longest continuous carbon chain is 7. Hence the parent name I the compound is heptane.

3. The substituent group attached is

—CH3 i.e methyl.

4. The substituent group attached is at carbon 3.

5. Therefore, the name of the compound is:

3–methylheptane.

How many moles of NaF must be dissolved in 1.00 liter of a saturated solution of PbF 2 at 25°C to reduce the [Pb 2+] to 1.0 × 10 –6 M? The K sp for PbF 2 at 25 °C is 4.0 × 10 –8.

Answers

Answer:

0.1957 moles of NaF

Explanation:

The Pb²⁺ and F⁻ are in equilibrium with PbF₂ as follows:

PbF₂(s) ⇄ Pb²⁺(aq) + 2F⁻(aq)

Where Ksp expression is:

Ksp = 4.0x10⁻⁸ = [Pb²⁺] [F⁻]²

A saturated solution contains the maximum possible amount of Pb²⁺ and F⁻. That is:

PbF₂(s) ⇄ Pb²⁺(aq) + 2F⁻(aq)

PbF₂(s) ⇄ X + 2X

Where X is amount of ions presents in solution

4.0x10⁻⁸ = [Pb²⁺] [F⁻]²

4.0x10⁻⁸ = [X] [2X]²

4.0x10⁻⁸ = 4X³

4.0x10⁻⁸/4 = X³

1.0x10⁻⁸ = X³

2.15x10⁻³M = X

That means initial concentration of Pb²⁺ is = X = 2.15x10⁻³M and [F⁻] = 2X = 4.30x10⁻³M

Now, using again Ksp, if you want a [Pb²⁺] = 1.0x10⁻⁶M, the [F⁻] you need is:

4.0x10⁻⁸ = [Pb²⁺] [F⁻]²

4.0x10⁻⁸ = [1.0x10⁻⁶M] [F⁻]²

0.04M = [F⁻]²

0.2M = [F⁻]

You need a final concentration of 0.2M of F⁻. As initial concentration was 4.30x10⁻³M and volume of the buffer is 1.00L, the moles of F⁻ = moles of NaF you must add are:

0.2M - 4.30x10⁻³M =

0.1957 moles of NaF

Which of these species would you expect to have the lowest standard entropy (S°)?

a. CH4(g)
b. H2O(g)
c. NH3(g)
d. HF(g)

Answers

Answer:

d. HF(g)

Explanation:

Hello,

In this case, the standard entropy S° could be predicted by looking at the amount of bonds the compound has, thus, the fewer the number bonds, the lower the standard entropy, it means that d. HF(g) has lowest value as it has one bond only whereas methane has four bonds, water two bonds and ammonia three bonds.

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Any process with a negative change in enthalpy and a positive change in entropy will be:_______.
a. spontaneous
b. nonspontaneous
c. spontaneous at high temperatures
d. spontanteous at low temperatures

Answers

Answer:

a. spontaneous

Explanation:

Hello,

In this case, since the Gibbs free energy is a metric that allows us to know whether a chemical reaction is spontaneous (Gibbs free energy less than 0) or nonspontaneous (Gibbs free energy greater than 0) we can mathematically define it as:

[tex]\Delta G=\Delta H-T\Delta S[/tex]

Thus, if the enthalpy is negative and the entropy is negative, the subtraction become always negative, for which the Gibbs free energy is negative as well, therefore, based on the aforementioned, any process with a negative change in enthalpy and a positive change in entropy will be: a. spontaneous.

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The heat of vaporization of water is 40.66 kJ/mol. How much heat is absorbed when 3.11 g of water boils at atmospheric pressure?

Answers

Answer:

The amount of heat that is absorbed when 3.11 g of water boils at atmospheric pressure is 7.026 kJ.

Explanation:

A molar heat of vaporization of 40.66 kJ / mol means that 40.66 kJ of heat needs to be supplied to boil 1 mol of water at its normal boiling point.

To know the amount of heat that is absorbed when 3.11 g of water boils at atmospheric pressure, the number of moles represented by 3.11 g of water is necessary. Being:

H: 1 g/moleO: 16 g/mole

the molar mass of water is:

H₂O= 2* 1 g/mole + 16 g/mole= 18 g/mole

So: if 18 grams of water are contained in 1 mole, 3.11 grams of water in how many moles are present?

[tex]moles of water=\frac{3.11 grams*1 mole}{18 gramos}[/tex]

moles of water= 0.1728

Finally, the following rule of three can be applied: if to boil 1 mole of water at its boiling point it is necessary to supply 40.66 kJ of heat, to boil 0.1728 moles of water, how much heat is necessary to supply?

[tex]heat=\frac{0.1728 moles*40.66 kJ}{1 mole}[/tex]

heat= 7.026 kJ

The amount of heat that is absorbed when 3.11 g of water boils at atmospheric pressure is 7.026 kJ.

Please help, Which type of molecule is shown below?

Answers

Answer:

Carbohydrate

Explanation:

A.pex

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