Given concentration of NaCl=15%
Means ,
In every 100g of Solution 15g of NaCl is present .
Now
Given mass=250gSo ,
[tex]\\ \Large\sf\longmapsto 250\times 15\%[/tex]
[tex]\\ \Large\sf\longmapsto 250\times \dfrac{15}{100}[/tex]
[tex]\\ \Large\sf\longmapsto 37.5g[/tex]
37.5g of NaCl present in 250g of solution.
Answer:
Given concentration of NaCl=15%
Means ,
In every 100g of Solution 15g of NaCl is present .
Now
Given mass=250g
So ,
➡250 × 15%
➡250×15/100
➡37.5g
37.5g of NaCl present in 250g of solution.
You should set out support, like a cork ring or clamp, before removing the glassware from a glassware kit to place the glassware in and to stop it from _________. Thoroughly check that the glasswar is________ and that it does not have any _______before using it.
Answer:
(A) Slipping and breaking
(B) Clean and dry
(C) Cracks
Explanation:
This describes the process of unpacking a glassware for use.
You should set out support like a cork ring or clamp (these are simple machines that'll hold the glassware in place) before removing the glassware from a glassware kit; to place the glassware in and to stop it from slipping and breaking.
Thoroughly check that the glassware is clean and dry and that it does not have any cracks, before using it.
Elements that have the same number of electron rings are ?
Answer:
are in the same orbital
Explanation:
Answer:
are in the same orbit
Explanation:
For the following list of acids, rank the acids in strength from weakest acid to strongest acid.
a. FCH2OH
b. F2CHOH
c. CH3OH
d. F3COH
Answer:
CH3OH < FCH2OH < F2CHOH < F3COH
Explanation:
Let us recall that, for a carboxylic acid, the dissociation of the acid yields;
RCOOH ⇄RCOO^- + H^+
The ease of dissociation and release of the hydrogen ion depends on the nature of the group designated R.
When R is is a highly electronegative element, the -I inductive effect causes the hydrogen to become less tightly held by the C-Cl bond.
As the number of electron withdrawing substituents increaseses, the acid ionizes much more and becomes stronger.CH3OH < FCH2OH < F2CHOH < F3COH
Hence, the order of decreasing acid strength is;
What enzyme below is an exoenzyme?
A. Casease
B. Citrase
C. Catalase
D. Oxidase
Write a balanced half-reaction for the oxidation of liquid water to aqueous hydrogen peroxide in basic aqueous solution. Be sure to add physical state symbols where appropriate.
Answer:
O2(g) + 2H2O(l) --------> 2H2O2(aq) + 2e
Explanation:
An oxidation reaction reaction refers to a reaction in which electrons are lost. In this case, we are about to see the full balanced half-reaction for the oxidation of liquid water to aqueous hydrogen peroxide in basic aqueous solution.
The full equation is;
O2(g) + 2H2O(l) --------> 2H2O2(aq) + 2e
So, two electrons were lost in the process.
What direction would equilibrium moves towards based on the following if we increased the volume of the container.
[tex]2A_{(g)} + 5B_{(g)} + 12C_{(g)}[/tex] ↔ [tex]14AC_{(g)} + 5B_{(s)}[/tex]
Answer choices:
a) reactants
b) no change
c) products
d) decrease in volume
Please help!
To answer this question, we will first find out the number of gaseous moles on each side of the equilibrium
on the left:
we have 2 moles of A, 5 moles of B and 12 moles of C
which gives us a grand total of 19 gaseous moles
on the right:
here, we have 14 moles of AC gas, we will not count the number of moles of B because it's a solid
giving us 14 gaseous moles on the right
Where does the reaction shift?
more gaseous moles means more space taken, because gas likes to fill all the space it can
if we have more volume, more gas can move around without colliding (reacting) with each other
Hence more volume favors the side with more gaseous moles
here, the left has more gaseous moles. So we can say that the reaction will shift towards the left, or the reactants side
Answer:
Explanation:
given reversible chemical reaction:
2A(g) + 5B(g) + 12C(g) ↔ 14AC(g) + 5B(s)
chemicals in solid form do not take up a lot of volume so change in container volume has no effect
look at chemicals in gas form only:
the total no. of moles of reactants in gas form = 2 + 5 + 12 = 19
the total no. of moles of products in gas form = 14
so an increase in volume of the container will favor the reaction direction with higher volume n high volume means higher no. of moles
the ans is the equilibrium will move towards a) reactants
The decomposition of ethyl amine, C2H5NH2, occurs according to the reaction: C2H5NH2(g)⟶C2H4(g)+NH3(g) At 85∘C, the rate constant for the reaction is 2.5 x 10-1 s-1. What is the half-life (in sec) of this reaction?
Answer:
2.772 seconds
Explanation:
Given that;
t1/2 = 0.693/k
Where;
t1/2 = half life of the reaction
k= rate constant
Note that decomposition is a first order reaction since the rate of reaction depends on the concentration of one reactant
t1/2 = 0.693/2.5 x 10-1 s-1
t1/2= 2.772 seconds
Use the Ka values for weak acids to identify the best components for preparing buffer solutions with the given pH values.
Name Formula Ka
Phosphoric acid H3PO4 7.5 x 10^-3
Acetic acid CH3COOH 1.8 x 10^-5
Formic acid HCOOH 1.8 x 10^-4
pH 1.9 =_________
pH 5.0 = ________
pH 3.9= ________
Answer:
pH= 1.9 then [tex]H_{3} PO_{4}[/tex]
pH = 5.0 , [tex]CH_{3} COOH[/tex]
pH = 3.9 , HCOOH
As we know range left [tex]pH= pKa+/- 1[/tex]
A sample of oxygen occupies 1.00 L. If the temperature remains constant, and the pressure on the oxygen is decreased to one third the original pressure, what is the new volume
Answer:
3.00 L
Explanation:
P₁V₁ = P₂V₂
V₁ = 1.00 L
P₁ = (x) atm
P₂ = [tex]\frac{1}{3}[/tex] · (P₁) = [tex]\frac{x}{3}[/tex]
V₂ = unknown
(x atm)(1.00 L) = ( [tex]\frac{x}{3}[/tex] atm)(V₂)
divide both sides by ( [tex]\frac{x}{3}[/tex] atm)
( 1.00x )( [tex]\frac{3}{x}[/tex] ) = V₂
x cancels out
(1.00)(3) = V₂
V₂ = 3.00 L
The homework question reads:
"A sample of gas in a cylinder of volume 3.42 L at 298 K
and 2.57 atm expands to 7.39 L by two different pathways.
Path A is an isothermal, reversible expansion. Path B has two
steps. In the fi rst step, the gas is cooled at constant volume to
1.19 atm. In the second step, the gas is heated and allowed to
expand against a constant external pressure of 1.19 atm until
the final volume is 7.39 L. Calculate the work for each path.
Answer:
Explanation:
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Answer : The work done for path A and path B is -685.3 J and -478.1 J respectively.
Explanation :
To calculate the work done for path A :
First we have to calculate the moles of the gas.
where,
= initial pressure of gas = 2.57 atm
= initial volume of gas = 3.42 L
n = moles of gas = ?
R = gas constant = 0.0821 atm.L/mol.K
T = temperature of gas = 298 K
Now put all the given values in the above formula, we get:
According to the question, this is the case of isothermal reversible expansion of gas.
As per first law of thermodynamic,
where,
= internal energy
q = heat
w = work done
As we know that, the term internal energy is the depend on the temperature and the process is isothermal that means at constant temperature.
So, at constant temperature the internal energy is equal to zero.
The expression used for work done will be,
where,
w = work done on the system = ?
n = number of moles of gas = 0.359 mole
R = gas constant = 8.314 J/mole K
T = temperature of gas = 298 K
= initial volume of gas = 3.42 L
= final volume of gas = 7.39 L
Now put all the given values in the above formula, we get :
Thus, the work done of path A is, -685.3 J
To calculate the work done for path B :
The formula used for isothermally irreversible expansion is :
where,
w = work done
= external pressure = 1.19 atm
= initial volume of gas = 3.42 L
= final volume of gas = 7.39 L
Now put all the given values in the above formula, we get :
Thus, the work done of path B is, -478.1 J
A uniform plastic block floats in water with 50.0 % of its volume above the surface of the water. The block is placed in a second liquid and floats with 23.0 % of its volume above the surface of the liquid.
What is the density of the second liquid?
Express your answer with the appropriate units.
Answer:
density of second liquid = 650 kg/m³
Explanation:
Given that:
The volume of the plastic block submerged inside the water = 0.5 V
The force on the plastic block = [tex]\rho_1V_1g[/tex]
[tex]= 0.5p_1 V_g[/tex]
when the block is floating, the weight supporting the force (buoyancy force) is:
W [tex]= 0.5p_1 V_g[/tex]
[tex]\rho Vg = 0.5p_1 V_g[/tex]
[tex]\rho = 0.5 \rho _1[/tex]
where;
water density [tex]\rho _1[/tex] = 1000
[tex]\rho = 0.5 (1000)[/tex]
[tex]\rho = 500 kg/m^3[/tex]
In the second liquid, the volume of plastic block in the water = (100-23)%
= 77% = 0.7 V
The force on the plastic block is:
[tex]= 0.77p_2 V_g[/tex]
when the block is floating, the weight supporting the force (buoyancy force) is:
[tex]W = 0.77p_2 V_g[/tex]
[tex]\rho Vg = 0.77 \rho_2 V_g \\ \\ \rho = 0.77 \rho_2 \\ \\ 500 = 0.77 \rho_2 \\ \\ \rho_2 = 500/0.77[/tex]
[tex]\mathbf{ \rho_2 \simeq 650 \ kg/m^3}[/tex]
Classify each of the following chemical reaction as a synthesis, decomposition, single-displacement, or double-displacement reaction. Drag the appropriate items to their respective bins.
CH3Br → CH3(g) + Br(g)
Zn(s) + CoCl2(aq) → ZnCl2(aq)
First Reaction is a Decomposition reaction as a single reactant hets decompoesed to form two products.Second reaction is a Synthesis reaction as two Reactant reacts together to form one product.
What is Decomposition Reaction ?Decomposition reactions are processes in which chemical species break up into simpler parts.
Usually, decomposition reactions require energy input.
Hence, First Reaction is a Decomposition reaction as a single reactant hets decompoesed to form two products.Second reaction is a Synthesis reaction as two Reactant reacts together to form one product.
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42 Organic compound may have names ending in -ane, -ene, -ol or -oic acid. How many of these endings indicate the compounds contain double bonds in their molecules? * (1 Point)
Answer: Organic compounds ending with the name (-ene) indicate that the compounds contain double bonds in their molecules.
Explanation:
Organic compounds are those molecules that contains carbon atoms (as their main element), hydrogen and oxygen which are usually present. The presence of numerous organic compounds is due to the following properties of carbon:
--> the exceptional ability of carbon atoms to catenate, that is, to combine with one another to form straight chains, branched chains or ring compounds containing many carbon atoms.
--> The ease with which carbon combines with hydrogen, oxygen, Nitrogen and halogens
--> The ability of carbon atoms to form single, DOUBLE or triple bonds.
The organic compound that has the name ending with -ene are known as the alkenes. The members of the alkene series are formed from the alkanes by the removal of two hydrogen atoms and the introduction of a DOUBLE BOND in the carbon chain. They are named after the corresponding alkanes by changing the -ane ending to -ene.
Note: the systematic name of a compound is formed from the root hydrocarbon by adding a suffix and prefixes to denote the substitution of the hydrogen atoms.
1. Most of the chemicals included in your General Chemistry Lab kit can be discarded down a drain. Describe a situation in which you would need to neutralize a chemical before discarding down a drain.
Answer: Chemicals like acids and bases are harmful and must be neutralized before draining.
Explanation:
A strong acid or strong base is required to be diluted or neutralized before it is discarded in the drain as if is discarded without diluting and neutralization it can spill and splash from sink or drain and can harm people in chemistry lab, moreover the fumes of the discarded chemical on spilling can cause respiratory tract burning and can even cause fire hazard so it must be converted into less harmful form and then must be drained.
Please explain how to do it as well!
Write a complete, balanced equation for the following reactions:
a) The combustion of C₆H₁₂O (teachers note: You figure out products).
b) Aqueous ferric iron (III) sulfate plus barium hydroxide (teachers note: You figure out the products).
Answer:
a) C₆H₁₂O + 8.5 O₂ ⇒ 6 CO₂ + 6 H₂O
b) Fe₂(SO₄)₃ + 3 Ba(OH)₂ ⇒ 3 BaSO₄ + 2 Fe(OH)₃
Explanation:
a) A combustion is a reaction of a compound with oxygen to produce carbon dioxide and water. The corresponding equation is:
C₆H₁₂O + O₂ ⇒ CO₂ + H₂O
We will start balancing C atoms by multiplying CO₂ by 6 and H atoms by multiplying H₂O by 6.
C₆H₁₂O + O₂ ⇒ 6 CO₂ + 6 H₂O
Then, we get the balanced equation by multiplying O₂ by 8.5.
C₆H₁₂O + 8.5 O₂ ⇒ 6 CO₂ + 6 H₂O
b) This is a double displacement reaction of the general structure:
Salt 1 + Base 1 = Salt 2 + Base 2
The corresponding equation is:
Fe₂(SO₄)₃ + Ba(OH)₂ ⇒ BaSO₄ + Fe(OH)₃
First, we will balance Fe atoms by multiplying Fe(OH)₃ by 2 and S atoms by multiplying BaSO₄ by 3.
Fe₂(SO₄)₃ + Ba(OH)₂ ⇒ 3 BaSO₄ + 2 Fe(OH)₃
Then, we will get the balanced equation by multiplying Ba(OH)₂ by 3.
Fe₂(SO₄)₃ + 3 Ba(OH)₂ ⇒ 3 BaSO₄ + 2 Fe(OH)₃
Answer:
a.[tex]\bold{C_{6}H_{12}O_{6}\rightarrow 6CO_{2}+6H_{2}O}[/tex]
△H=−72 kcal
The energy required for production of 1.6 g of glucose is [molecular mass of glucose is 180 gm]
b.
[tex]\bold{Fe_{2}(SO_{4})_{3}+3Ba(OH)_{2}\rightarrow 3BaSO_{4}+2Fe(OH)_{3}}[/tex]
The iron(III) ions and chloride ions remain aqueous and are spectator ions in a reaction that produces solid barium sulfate.
A system receives 425 J of heat from and delivers 425 J of work to its surroundings. What is the change in internal energy of the system (in J)?
Answer:
0 J
Explanation:
Applying,
ΔE = q+w................ Equation 1
Where ΔE = change in internal energy of the system, q = Heat of the system, w = work of the system.
Note: q is positive, while w is negative
From the question,
Given: q = 425 J, w = -425 J
Substitute these values into equation 1
ΔE = 425-425
ΔE = 0 J
Hence the change in internal energy of the system is 0 J
The compound IF5 contains Question 16 options: polar covalent bonds with partial negative charges on the F atoms. ionic bonds. polar covalent bonds with partial negative charges on the I atoms. nonpolar covalent bonds.
Answer:
See explanation
Explanation:
The molecule IF5 possesses five I-F polar bonds. However, the presence of polar bonds does not automatically imply that the molecule will be polar.
The geometry of the molecule is very important in determining the polarity of a compound. Since IF5 has a lone pair of electrons, the molecule is bent and as such there is a permanent dipole moment created in the molecule thereby making IF5 polar in nature.
Each set of quantum numbers to the correct sub shell description
It is found that, when a dilute gas expands quasistatically from 0.40 to 5.0 L, it does 210 J of work. Assuming that the gas temperature remains constant at 300 K, how many moles of gas are present
Answer:
[tex]n=0.033mole[/tex]
Explanation:
From the question we are told that:
Initial volume [tex]V_1=0.40L[/tex]
Final Volume[tex]V_2=5.0L[/tex]
Work [tex]W=210J[/tex]
Temperature [tex]T=300k[/tex]
Generally the equation for Ideal gas is mathematically given by
[tex]W=nRTIn\frac{V_2}{V_1}[/tex]
[tex]n=\frac{W}{RTIn\frac{V_2}{V_1}}[/tex]
[tex]n=\frac{210}{8.32*300In\frac{5.0}{0.4}}[/tex]
[tex]n=0.033mole[/tex]
Write a net ionic equation for the overall reaction that occurs when aqueous solutions of carbonic acid and sodium hydroxide are combined. Assume excess base.
Answer:
[tex]H_2CO_3(aq)+2OH^-(aq)\rightarrow (CO_3)^{2-}(aq)+2H_2O(l)[/tex]
Explanation:
Hello there!
In this case, according to the given information, it turns out possible for us to set up this net ionic equation, by firstly setting up the complete molecular equation as follows:
[tex]H_2CO_3(aq)+2NaOH(aq)\rightarrow Na_2CO_3(aq)+2H_2O(l)[/tex]
Thus, since carbonic acid is weak it merely ionizes whereas sodium hydroxides ionizes for the 100 % as it is strong; thus, we can write the complete ionic equation:
[tex]H_2CO_3(aq)+2Na^+(aq)+2OH^-(aq)\rightarrow 2Na^+(aq)+(CO_3)^{2-}(aq)+2H_2O(l)[/tex]
Whereas sodium ions act as the spectator ones to be cancelled out for us to obtain:
[tex]H_2CO_3(aq)+2OH^-(aq)\rightarrow (CO_3)^{2-}(aq)+2H_2O(l)[/tex]
Regards!
For each of the following compounds, indicate the pH at which 50% of the compound will be in a form that possesses a charge and at which pH more than 99% of the compound will be in a form that possesses a charge.
ClCH2COOH (pKa = 2.86)
CH3CH2NH+3 (pKa = 10.7)
Express your answer using two decimal places
a. Determine a pH at which 50% of ClCH2COOH will be in a form that possesses a charge.
b. Determine a pH at which pH more than 99% of ClCH2COOH will be in a form that possesses a charge.
c. Determine a pH at which 50% of CH3CH2NH+3 will be in a form that possesses a charge.
d. Determine a pH at which pH more than 99% of CH3CH2NH+3 will be in a form that possesses a charge.
Answer:
a. 2..86 b. 4.86 c. 10.7 d. 8.7
Explanation:
a. Determine a pH at which 50% of ClCH2COOH will be in a form that possesses a charge.
Using the Henderson-Hasselbalch equation,
pH = pKa + log[A⁻]/[HA]
where [A⁻] = concentration of conjugate base (or charged form) and [HA] = concentration of acid.
At 50% concentration, [A⁻] = [HA] ⇒ [A⁻]/[HA] = 1
So, pH = pKa + log[A⁻]/[HA]
pH = pKa + log1
pH = pKa = 2.86
b. Determine a pH at which pH more than 99% of ClCH2COOH will be in a form that possesses a charge.
Let x be the concentration of the acid. Since 99% of it should possess a charge, the basic concentration is 0.99x while the acidic concentration is remaining 1 % (1 - 0.99)x = 0.01x
Using the Henderson-Hasselbalch equation,
pH = pKa + log[A⁻]/[HA] where [A⁻] = concentration of conjugate base (or charged form) = 0.99x and [HA] = concentration of acid = 0.01x.
pH = pKa + log0.99x/0.01x
pH = pKa + log0.99/0.01
pH = 2.86 + log99
pH = 2.86 + 1.996
pH = 4.856
pH ≅ 4.86
c. Determine a pH at which 50% of CH3CH2NH+3 will be in a form that possesses a charge.
Using the Henderson-Hasselbalch equation,
pH = pKa + log[A⁻]/[HA]
where [A⁻] = concentration of conjugate base and [HA] = concentration of acid.
At 50% concentration, [A⁻] = [HA] ⇒ [A⁻]/[HA] = 1
So, pH = pKa + log[A⁻]/[HA]
pH = pKa + log1
pH = pKa = 10.7
d. Determine a pH at which pH more than 99% of CH3CH2NH+3 will be in a form that possesses a charge.
Let x be the concentration of the acid. Since 99% of it should possess a charge, the basic concentration is 0.01x while the acidic concentration is remaining 99 % (1 - 0.01)x = 0.99x (which possesses the charge).
Using the Henderson-Hasselbalch equation,
pH = pKa + log[A⁻]/[HA] where [A⁻] = concentration of conjugate base = 0.01x and [HA] = concentration of acid = 0.99x.
pH = pKa + log0.01x/0.99x
pH = pKa + log1/99
pH = 10.7 - log99
pH = 10.7 - 1.996
pH = 8.704
pH ≅ 8.7
Calculate the mass of sodium phosphate in aqueous solution to fully react with 37 g of chromium nitrate(III) an aqueous solution?(report answer in grams and only three Sigg figs do not put the unit)
Answer:
41 g
Explanation:
The equation of the reaction is;
Cr(NO3)3(aq)+Na3PO4(aq)=3NaNO3(s)+CrPO4(aq)
Number of moles of chromium nitrate = 37g/ 146.97 g/mol = 0.25 moles
1 mole of sodium phosphate reacts with 1 mole of chromium nitrate
x moles of sodium phosphate react as with 0.25 moles of chromium nitrate
x= 1 × 0.25/1
x= 0.25 moles
Mass of sodium phosphate = 0.25 moles × 163.94 g/mol
Mass of sodium phosphate = 41 g
What is "X" in the following reaction?
To determine the concentration of an EDTA solution, 4.11 g of Zn metal was used. The volume of EDTA solution needed to reach the endpoint was 28.26 mL. What was the concentration (in molarity) of the EDTA solution?
Answer:
2.23M
Explanation:
Molarity of a solution is calculated thus
Molarity = number of moles (n) ÷ volume (V)
According to this question, 4.11g of Zn metal was used in order to reach a volume of EDTA solution of 28.26 mL.
28.26mL = 28.26/1000
= 0.02826L
Using mole = mass/molar mass to calculate no. of moles of Zn
Mole = 4.11/65.4
mole = 0.0628mol
Molarity = 0.0628 ÷ 0.02826
Molarity = 2.23M
The concentration of the EDTA solution used is 2.23M
any two functions of crystals
Answer:
1. Participating in calcium homeostatis storage of calcium.
2. High capacity calcium (Ca) regulation and protection against herbivory
[tex]\large \boxed{\sf 2 \: functions \: of \: crystals \: are :- } [/tex]
_________________
⟹
[tex] \sf \: \underline{ Calcium \: oxalate \: (CaOx) \: crystals} \: are \: distributed \: \\\sf among \: all \: taxonomic \: levels \\ \sf\: of \: photosynthetic \: organisms \: from \\ \sf \: small \: algae \: to \: angiosperms \: and \: giant \: gymnosperms .[/tex]
__________________
⟹
[tex]\sf Bone \: is \: mostly \: made \: of \: \underline{mineral \: crystals} \: \\ \sf and \: the \: protein \: collagen. \: The \: mineral \: crystals \: bone \\ \sf\: provide \: strength \: and \: rigidity \: for \: the \: matrix \: upon \: \\ \sf \: and \: within \: which \: they \: are \: deposited.[/tex]
Classify the processes as endothermic or exothermic.
a. Ice melting
b. Water condensing on surface
c. Baking a cake
d. The chemical reaction inside an instant cold pack.
e. A car using gasoline
endothermic absorbs heat
exothermic gives heat
a. endothermic
b. exothermic
c. endothermic
d. exothermic
a. Ice melting - endothermic
b. Water condensing on the surface - exothermic
c. Baking a cake - endothermic
d. The chemical reaction inside an instant cold pack - endothermic
e. A car using gasoline - exothermic
What is an exothermic and endothermic reaction?An exothermic reaction can be described as a thermodynamic chemical reaction that emits energy from the system to its surroundings usually in the form of light, heat, or sound.
While an endothermic reaction can be described as an opposite of an exothermic reaction where the energy gains in the form of heat. In exothermic chemical reactions, the bond energy is transformed into thermal energy.
In exothermic reactions, the reaction happens the form of the kinetic energy of molecules when the energy is released. The release of energy is due to the electronic transition of electrons from one energy level to another.
The burning of gasoline, and water condensation is also an exothermic reaction in which energy is released while ice melting and baking cake is an endothermic reaction.
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how many of the electrons in a molecule of ethane are not involved in bondind
Ethane consists of 6C−H bonds and 1C−C bond. Total number of bonds is 7. Each bond is made up of two electrons
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Compute the equilibrium constant for the spontaneous reaction between Cd2 (aq) and Zn(s).
Answer:
Kc = [Zn²⁺] / [Cd²⁺]
Explanation:
Let's consider the spontaneous redox reaction between Cd²⁺ and Zn.
Cd²⁺(aq) + Zn(s) ⇄ Cd(s) + Zn²⁺(aq)
The equilibrium constant, Kc, is the ratio of the equilibrium concentrations of products over the equilibrium concentrations of reactants each raised to the power of their stoichiometric coefficients. It only includes gases and aqueous species.
Kc = [Zn²⁺] / [Cd²⁺]
5.60g of glyceraldehydes was dissolved in 10ml of a solvent and placed in a 50mm cell if the rotation is 1.74 calculate the specific rotation?
Answer:
6.214 degrees-mL/gdm
Explanation:
The specific rotation α' = α/LC where α = observed rotation, L = length of tube and C = concentration of solution.
Given that α = 1.74, L = length of cell = 50 mm = 0.50 dm and C = m/V where m = mass of glyceraldehyde = 5.60 g and V = volume = 10 ml
So, C = m/V = 5.60 g/10 ml = 0.560 g/ml
Since α' = α/LC
substituting the values of the variables into the equation, we have
α' = α/LC
α' = 1.74/(0.50 dm × 0.560 g/ml)
α' = 1.74/(0.28 gdm/l)
α' = 0.006214 °mL/gdm
α' = 6.214 °mL/gdm
α' = 6.214 degrees-mL/gdm
Sometimes in lab we collect the gas formed by a chemical reaction over water . This makes it easy to isolate and measure the amount of gas produced.
Suppose the CO, gas evolved by a certain chemical reaction taking place at 50.0°C is collected over water, using an apparatus something like that in the sketch, and the final volume of gas in the collection tube is measured to be 132. mL. Calculate the mass of CO, that is in the collection tube. Round your answer to 2 significant digits.
Answer:
0.17 g
Explanation:
Since the volume of gas collected is 132 mL, we need to find the number of moles of gas present in 132 mL.
So, number of moles, n = volume of gas, v/molar volume, V
n = v/V where v = 132 mL = 0.132 L and V = 22.4 L
So, substituting the values of the variables into the equation, we have
n = v/V
n = 0.132 L/22.4 L
n = 0.005893 mol
We then need to calculate the molar mass of CO, M = atomic mass of carbon + atomic mass of oxygen = 12 g/mol + 16 g/mol = 28 g/mol
Also, number of moles of gas, n = m/M where m = mass of CO and M = molar mass of CO
m = nM
m = 0.005893 mol × 28 g/mol
m = 0.165004 g
m ≅ 0.17 g to 2 significant digits