One way to measure ionization energies is ultraviolet photoelectron spectroscopy (UPS, or just PES), a technique based on the photoelectric effect. In PES, monochromatic light is directed onto a sample, causing electrons to be emitted. The kinetic energy of the emitted electrons is measured. The difference between the energy of the photons and the kinetic energy of the electrons corresponds to the energy needed to remove the electrons (that is, the ionization energy). Suppose that a PES experiment is performed in which mercury vapor is irradiated with ultraviolet light of wavelength 58.4 nm.
(a) What is the energy of a photon of this light in eV?
(b) Write an equation that shows the process corresponding to the first ionization energy of Hg.
(c) The kinetic energy of the emitted electrons is measured to be 10.75 eV. What is the first ionization energy of Hg in kJ/mol?

Answers

Answer 1

Answer:

Explanation:

From the given information:

The energy of photons can be determined by using the formula:

[tex]E = \dfrac{hc}{\lambda}[/tex]

where;

planck's constant (h) = [tex]6.63 \times 10^ {-34}[/tex]

speed oflight (c) = [tex]3.0 \times 10^8 \ m/s[/tex]

wavelength λ = 58.4 nm

[tex]E = \dfrac{6.63 \times 10^{-34} \ J.s \times 3.0 \times 10^8 \ m/s}{58.4 \times 10^{-9 } \ m}[/tex]

[tex]E =0.34 \times 10^{-17} \ J[/tex]

[tex]E = 3.40 \times 10^{-18 } \ J[/tex]

To convert the energy of photon to (eV), we have:

[tex]1 eV = 1.602 \times 10^{-19} \ J[/tex]

Hence

[tex]3.40 \times 10^{-18 } \ J = \dfrac{1 eV}{1.602 \times 10^{-19 } \ J }\times 3.40 \times 10^{-18 } \ J[/tex]

[tex]E = 2.12 \times 10 \ eV[/tex]

E = 21.2 eV

b)

The equation that illustrates the process relating to the first ionization is:

[tex]Hg_{(g)} \to Hg^+ _{(g)} + e^-[/tex]

c)

The 1st ionization energy (I.E) of Hg can be calculated as follows:

Recall that:

I.E  = Initial energy - Kinetic Energy

I₁ (eV) = 21.2 eV - 10.75 eV

I₁ (eV) = 10.45 eV

Since ;

[tex]1 eV = 1.602 \times 10^{-19} \ J[/tex]

[tex]10.45 \ eV = \dfrac{1.602 \times 10^{-19 } \ J }{ 1 \ eV}\times 10.45 \ eV[/tex]

Hence; the 1st ionization energy of Hg atom = [tex]1.67 \times 10^{-18} \ J[/tex]

[tex]1.67 \times 10^{-21} \ kJ[/tex]

Finally;

[tex]I_1 \ of \ the \ Hg (kJ/mol) = \dfrac{1.67 \times 10^{-21 \ kJ} \times 6.02 \times 10^{23} \ Hg \ atom }{1 \ Kg \ atom }[/tex]

[tex]\mathbf{= 1.005 \times 10^3 \ kJ/mol}[/tex]


Related Questions

Write the balanced equation for the equilibrium reaction for the dissociation ofsilver chloride in water, and write the K expression for this reaction. Then create an ICE chart. Since we know the equilibrium concentration of the silver ion, we can solve for Ksp.Does it agree with the literature value

Answers

Answer:

See explanation

Explanation:

Hello there!

In this case, since the the concentrations are not given, and not even the Ksp, we can solve this problem by setting up the chemical equation, the equilibrium constant expression and the ICE table only:

[tex]AgCl(s)\rightleftharpoons Ag^+(aq)+Cl^-(aq)[/tex]

Next, the equilibrium expression according to the produced aqueous species as the solid silver chloride is not involved in there:

[tex]Ksp=[Ag^+][Cl^-][/tex]

And therefore, the ICE table, in which x stands for the molar solubility of the silver chloride:

       [tex]\ \ \ \ \ \ \ \ \ \ \ \ \ \ AgCl(s)\rightleftharpoons Ag^+(aq)+Cl^-(aq)[/tex]

I          -                   0             0

C        -                   +x           +x

E        -                    x             x

Which leads to the following modified equilibrium expression:

[tex]Ksp=x^2[/tex]

Unfortunately, values were not given, and they cannot be arbitrarily assigned or assumed.

Regards!

Which is the function of the organ shown below

Answers

Answer:

c the pancreas produce enzyme that breakdown carbohydrate protein and fat

If 1.00 g of KCl is completely dissolved in 24.5 g of water, what is the percent composition (by mass) of the solution that is formed?

Answers

Answer:

3.92%

Explanation:

The solution that is formed is of KCl in water. This means that the percent composition by mass is given by the formula:

Mass of KCl / Mass of Solution * 100%

We now calculate the mass of solution:

Mass of Solution = Mass of KCl + Mass of Water = 1.00 g + 24.5 gMass of Solution = 25.5 g

Finally we calculate the percent composition:

1.00 g / 25.5 g * 100% = 3.92%

Which of the following is a characteristic shared by all living things?
A. They have tissues and organs,
B. They take in oxygen.
C. They make more individuals of the same kind.
D. They move.​

Answers

Answer; it’s either d or a. If it was be I would pick A. Not sure

Consider the following data on some weak acids and weak bases
acid
Ka
name formula
acetic acid
HCH3CO2
1.8 x10−5
hydrocyanic acid
HCN
4.9 x 10−10
base
Kb
name formula
pyridine
C5H5N
1.7 x 10−9
ammonia
NH3
1.8 x 10−5
Use this data to rank the following solutions in order of increasing pH. In other words, select a '1' next to the solution that will have the lowest pH, a '2' next to the solution that will have the next lowest pH, and so on.
a. 0.1M NaCH3CO2
b. 0.1M NH4Br
c. 0.1M NaBr
d. 0.1M KCN

Answers

Answer:

b < c < a < d

Explanation:

The weak acid with the lowest pKa will be the most acidic. In the other way, the conjugate base which the acid is weak will be strong.

The weak base with the lowest pKb will be the most basic. And the conjugate base of the weak base will be a strong acid.

Ka Acetic acid = 1.8x10-5

Ka HCN = 1.9x10-10

Kb pyridine = 1.7x10-9

Kb NH3 = 1.8x10-5

NH4Br is the conjugate base of a weak base. That means is a strong acid.

NH4Br has the lowest pH

NaBr is the conjugate base of a strong acid, HBr. That means NaBr is neutral

The most basic between the conjugate base of the acetic acid, NaCH3CO2 and KCN is KCN because the acetic acid is the stronger acid regard to HCN.

The rank is:

NH4Br < NaBr < NaCH3CO2 < KCN

b < c < a < d

The Swedish chemist Karl Wilhellm was the first to produce chlorine in the lab
2NaCl + 2H2SO4 + MnO2 -----> Na2SO4 + MnSO4 + H2O + Cl2
If Dr. Wilhellm started with 50.0 g of each reactant, which reactant is the limiting reactant?

Answers

Answer:

Explanation:

Remark

Interesting que8stion. You have to figure out how many mols are present in each reactant. Since all periodic tables are different, I'm going to use rounded numbers. If it is too close, I will go further.

NaCl

Na = 23

Cl = 35.5

1 mol = 58.5 grams

given = 50.0 grams

Mols for the reaction = 50/58.5 = 0.855

H2SO4

H2       =    2*1        2

S          =   1 * 32   32

O4       =   4*16     64

1 mol  =               98   grams

mols  present = 50/98 = 0.510

MnO2

Mn     = 1 * 55    = 55

O2   =   2*16      = 32

1 mol =                  87 grams

mols available    = 50/87 = 0.5747

Discussion

Na Cl and H2SO4 both require 2 moles for every mol of Cl2 produces.

H2SO4  has 0.51 mols available for a reaction

NaCl has  0.855 moles available for a reaction

MnO2 has 0.575 moles available for a reaction.

Given those numbers 0.510 mols of H2SO4 will only produce 0.255 mols of chlorine and the rest will be reduced in a similar manner. H2SO4 is the limiting reagent (reactant).

In other words only 0.510 moles of NaCl will be used and 0.855 - 0.510 moles will be left over on the reactants side.

only 0.575 moles of MnO2 will be used and 0.065 moles will be left over.

The oddity in the result shows up because the balance numbers in the equation give a ratio of 2 to 1 for H2SO4 and NaCl The 2 belongs to the reactants and the 1 for the chlorine.

Which of the following regions has an economy based on processing food and consumer goods?

A. Western Europe
B. Eastern Europe
C. northern Europe
D. southern Europe


No links plz

Answers

Answer:

B. Eastern Europe

Explanation:

The economy of Eastern Europe depends on producing foods. For example, Poland and Belarus are two countries in Eastern Europe, and they both produce chocolates. Producing foods isn't the only detrimental part of the region's economic data. The other half depends on consumer goods. For example, Estonia and Latvia are good countries in packaging food. The answer to the question is B.

t-Butyl alcohol was produced by the liquid-phase hydration (using water, W) of isobutene (I) over an Amberlyst-15 catalyst.

a. True
b. False

Answers

Answer:

True

Explanation:

This is because, The hydroboration oxidation of an alkene which is isobutene in the presence of a catalyst will result to alcohol as the product . Therefore, the OH group will attach or link itself to the carbon which is less obstructed. Thus this reaction is in accordance to Anti-Markownikoff's rule.

So isobutene on hydroboration oxidation will produce ter isobutyl alcohol.

Determine the number of electrons in an Cl ion with a charge of -3

Answers

Answer:

There are 20 electrons.

Explanation:

Chlorine has 17 electrons in its atom to begin with (you can tell from the proton number in the periodic table).

A charge of -3 means that the chlorine atom gained 3 electrons, and now needs to lose 3 electrons to return to its atom configuration.

Cuo
+ H2 → → Cu + + H20
colorless
water
black
powder
reddish
solid
gas
vapor

Answers

Explanation:

because there is 2 hydrogen atoms in the reactions side of the equation (you can tell because the H has a 2 in the subscript) you have to have 2 hydrogen atoms in the reactants side to help balance out the equation. and since the copper and oxygen atoms are already balanced there is no coefficient needed.

Potassium nitrate, KNO3 , has a molar mass of 101.1 g/mol. In a constant-pressure calorimeter, 13.3 g of KNO3 is dissolved in 213 g of water at 23.00 °C . KNO3(s)−→−−H2OK+(aq)+NO−3(aq) The temperature of the resulting solution decreases to 19.60 °X . Assume that the resulting solution has the same specific heat as water, 4.184 J/(g·°C) , and that there is negligible heat loss to the surroundings. How much heat was released by the solution

Answers

Answer:

[tex]Q_{sln}=-3219.25 J[/tex]

Explanation:

Hello there!

In this case, for this calorimetry problem, it is possible for us to infer that the heat of the reaction of dissolution of KNO3 is absorbed by the solution composed by the former and water so that we can write:

[tex]Q_{rxn}=-Q_{sln}[/tex]

Thus, given the mass, specific heat and temperature of the solution, we plug in the data to obtain the heat absorbed, by the reaction:

[tex]Q_{rxn}=-m_{sln}C_{sln}\Delta T _{sln}\\\\Q_{rxn}=-(13.3+213)g(4.184\frac{J}{yg\°C} )(19.60-23.00)\°C\\\\Q_{rxn}=3219.25J[/tex]

Also, we can say the the heat released by the solution was -3219.25 J.

Best regards!

What happens to the entropy when a solution is made?
A. The entropy increases.
B. The entropy decreases.
C. The entropy goes to zero.
D. The entropy is unaffected.

Answers

Answer:

The entropy increases

Explanation:

Just took the quiz

What is true of an earthquake that causes major damage to buildings in an area?

It has a high magnitude.
It has a high frequency.
It has a low frequency.
It has a low magnitude.

Answers

The correct option is :

=》It has a high magnitude.

the damage caused by an earthquake is proportional to its magnitude, as much the magnitude is, that much damage will be caused by it.

The term used to indicate and earthquake that causes major damage to buildings in an area is called a high magnitude earthquake. Hence, option a is correct.

What is high magnitude earthquake?

The most typical way to gauge an earthquake's size is by its magnitude. No matter where you are or how violent the shaking is, it is the same number since it represents the size of the earthquake's source.

The USGS no longer uses the outmoded Richter scale to determine the magnitude of major, teleseismic earthquakes. Several magnitude scales measure various aspects of the earthquake, but the Richter scale measures the biggest wobble (amplitude) on the recording.

Currently, the USGS uses the Moment Magnitude scale to report earthquake magnitudes, however many different magnitudes can be calculated for comparison and research. Therefore, option a is correct.

Find more on earthquakes:

https://brainly.com/question/29500066

#SPJ3

2 Which of the gases in air are elements? Explain how you can tell.​

Answers

Answer:

I'll explain.

Explanation:

The molecules of two different elements, nitrogen and oxygen, make up about 99 percent of the air. The rest includes small amounts of argon and carbon dioxide. Oxygen is the life-giving element in the air. You can tell because they're on the periodic table which is a table for elements.

Explanation:

nitrogen and oxygen are the gases in the air which are elements you can simply say it by looking the periodic table

is scandium a transition metal?​

Answers

Answer:no

Explanation:

Answer:

Scandium is a transition metal

Explanation:

A 25.0 mL NaOH solution of unknown concentration was titrated with a 0.189 M HCl solution. 19.6 mL HCl was required to reach the equivalence point. In a separate titration, a 10.0 mL H3PO4 solution was titrated with the same NaOH solution. This time, 34.9 mL NaOH was required to reach the equivalence point. What is the concentration of the H3PO4 solution

Answers

Answer:

0.172 M

Explanation:

The reaction for the first titration is:

HCl + NaOH → NaCl + H₂O

First we calculate how many HCl moles reacted, using the given concentration and volume:

19.6 mL * 0.189 M = 3.704 mmol HCl

As one HCl mol reacts with one NaOH mol, there are 3.704 NaOH mmoles in 25.0 mL of solution. With that in mind we determine the NaOH solution concentration:

3.704 mmol / 25.0 mL = 0.148 M

As for the second titration:

H₃PO₄ + 3NaOH → Na₃PO₄ + 3H₂O

We determine how many NaOH moles reacted:

34.9 mL * 0.148 M = 5.165 mmol NaOH

Then we convert NaOH moles into H₃PO₄ moles, using the stoichiometric coefficients:

5.165 mmol NaOH * [tex]\frac{1mmolH_3PO_4}{3mmolNaOH}[/tex] = 1.722 mmol H₃PO₄

Finally we determine the H₃PO₄ solution concentration:

1.722 mmol / 10.0 mL = 0.172 M

Please help me on 6 and 8 thanks

Answers

Answer:

6.) 3, 12, 1, and 4   8.) 4, 1, and 3

Explanation:

By multiplying subscripts inside and outside of the parentheses you can count the number of atoms that are present. I recently answered a question for you and I did the math wrong I am going to go back and comment so you know which one and I will correct my errors. Sorry for the inconvenience!

the number of atoms in number 6:

N: 3

H: 12

P: 1

O: 4

the number of atoms for number 8:

Ca: 4

C: 1

O: 3

hope I clarified my mistake and helped you! :)

Which of the following is an advantage of asexual reproduction compared to sexual reproduction?

Both will produce genetically identical offspring from the parent.

Sexual reproduction will increase genetic variability within a species.

Asexual reproduction requires less energy and will produce more offspring over time.

Sexual reproduction has minimal changes of mutations compared to asexual reproduction.

Answers

Explanation:

sexual reproduction has minimal changes of mutations compared to asexual reproduction

Answer:

sexual reproduction has minimal changes of mutations compared to asexual reproduction

I hope this helps

How many grams are there in 1.8055 x 10^25 molecules of sodium sulfate? Hint: Convert to moles first

Answers

Answer:

4258.82 g of Na₂SO₄

Explanation:

From the question given above, the following data were obtained;

Number of molecules of Na₂SO₄ = 1.8055x10²⁵ molecules.

Number of mole of Na₂SO₄ =?

From Avogadro's hypothesis,

6.02×10²³ molecules = 1 mole

Therefore,

6.02×10²³ molecules = 1 mole of Na₂SO₄

Next, we shall determine the mass of 1 mole of Na₂SO₄. This can be obtained as follow:

1 mole of Na₂SO₄ = (23×2) + 32 + (16×4)

= 46 + 32 + 64

= 142 g

Thus,

6.02×10²³ molecules = 142 g of Na₂SO₄

Finally, we shall determine the mass of Na₂SO₄ that contains 1.8055x10²⁵ molecules. This can be obtained as follow:

6.02×10²³ molecules = 142 g of Na₂SO₄

Therefore,

1.8055x10²⁵ molecules

= (1.8055x10²⁵ × 142) / 6.02×10²³

= 4258.82 g of Na₂SO₄

Thus, 4258.82 g of Na₂SO₄ contains 1.8055x10²⁵ molecules

You are performing an acid-base neutralization reaction in the laboratory to determine the concentration of an unknown base. You are supposed to titrate it with a monoprotic acid, but your lab partner accidentally fills your buret with sulfuric acid, a diprotic acid, with the same concentration as the acid called for in the experiment. How will the volume of diprotic acid compare to the volume of monoprotic acid you would have used

Answers

Answer:

Volume is reduced to half

Explanation:

Acid base titration are commonly used reactions in a lab, and are ofter used to get pH or different kind of solutions.

The neutralization of an acid base reaction is reached, when the solution (having added an indicator previously) changes its original color. chemically speaking, this occurs when the number of moles of the acid and the base are balanced and equal. In other words the following:

n₁ = n₂   (1)

This expression can also be expressed in function of concentration and volume:

M₁V₁ = M₂V₂   (2)

From here, solving for V₁:

V₁ = M₂V₂  / M₁

Now, this expression is true only when we have the same kind of substance that can lose or gain the same number of hydrogens.

Lets suppose that we have as base NaOH (Monoprotic base) and HCl (monoprotic acid), the titration reaction would be:

NaOH + HCl --------> NaCl + H₂O

As both of the species are monoprotic, the number of moles are the same  when they reach the equilibrium, so, expression  (2) can be used, and calculate volume or concentrations.

However, in this case, a partner made a mistake and use a diprotic acid, in this case, H₂SO₄, In this case, things chance because H₂SO₄ is diprotic, meaning that we need to dissociate two hydrogens in equilibrium, therefore, expression (2) would be something like this.

Acid: 1; Base: 2

H₂SO₄ + 2NaOH ------> Na₂SO₄ + H₂O

nH₂SO₄ = n₁ = 1

nNaOH = n₂ = 2

n₁/n₂ = 1/2

2n₁ = n₂   (3)

Writting this, in function of concentration and volume, it would be:

2M₁V₁ = M₂V₂   (4)

From here, if we solve for the volume of the acid (V₁):

V₁ = M₂V₂ / 2M₁

Therefore, according to this expression, we can see that the volume required of the acid would be half the volume required of the monoprotic acid. For example, if we need 50 mL of Chloridic acid to reach the equivalence point with NaOH, then, with H₂SO₄ it will only need 25 mL. This, of course, assuming that concentrations are the same, and volume of the base used, the same.

Hope this helps

1) Heat is the ______ of energy and a unit is ____.
A: Measure; Joule
B: Measure; Kelvin
C: Movement; Kelvin
D: Movement; Joule

2) ______ is the internal energy of particles and when this motion is measured, the unit used is ___.
A: Heat; Joule
B: Thermal Energy; Kelvin
C: Thermal Energy; Joule
D: Heat; Kelvin

Answers

Answer:

Q1) B

Q2) C

Kelvin is the SI unit of temperature.

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