Rita determined the experimental van 't Hoff factor, i, for KCl to be 1.9 which is less than the theoretical value of 2. Select the option that best explains the difference between the theoretical and experimental i.a) The difference is due to the ion-pairing effect which effectively reduces the number of solute particles present in the solution.b) The difference is due to the ion-pairing effect which effectively increases the number of solute particles present in the solution correct amount of KCl that will give better agreement between the experimental and theoretical results.c) Rita did not freeze the entire sample.

Answers

Answer 1

Answer:

The difference is due to the ion-pairing effect which effectively reduces the number of solute particles present in the solution.

Explanation:

Colligative properties are those properties that depend on the amount of solute present. Such properties include; boiling point elevation, freezing point depression etc.

Ion pairing causes the Van't Hoff factor to deviate from whole numbers. Ion pairing effect generally reduces the number of solute particles in solution thereby decreasing the experimental value of the Van't Hoff factor (i).

Hence, the reason why Rita determined the Van't Hoff factor as 1.9 and not the theoretical value of 2 is because of on-pairing effect which effectively reduces the number of solute particles present in the solution.

Answer 2

The difference between the theoretical and experimental is A. The difference is due to the ion-pairing effect which effectively reduces the number of solute particles present in the solution.

Colligative properties

It should be noted that colligative properties simply means the properties that depend on the amount of solute present.

The ion pairing causes the Van't Hoff factor to deviate from whole numbers. Therefore, they caused the difference between the theoretical and experimental values.

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Related Questions

When metal X is treated with sodium hydroxide, a white precipitate A is obtained which is soluble in excess NaOH to give a soluble complex B. Compound A is soluble in dilute HCl to form compound C. When the compound A is heated strongly it gives compound D which is used to extract metal. a) Identify X, A, B, C, D supporting your answer(s) with appropriate chemical reactions. b) At which group and period does X fall?​

Answers

Answer:

See explanation

Explanation:

If we look at the question closely, we will notice that the metal in question must be aluminum.

When aluminum is treated with sodium hydroxide, a precipitate, aluminium hydroxide is formed as follows;

Al(s) + 3NaOH(aq) ---> Al(OH)3(s) + 3Na(s)

In excess sodium hydroxide, the precipitate dissolves as follows;

Al(OH)3(s) + NaOH(aq) ----> [NaAlOH4]^-(aq)

The complex formed is sodium aluminum tetrahydroxo aluminate III.

The reaction of aluminum faith dilute hydrochloric acid occurs as follows to yield aluminum chloride;

2Al(s) + 6HCl(aq) ----> 2AlCl3(aq) + 3H2(g)

When aluminum metal is heated strongly, it yields aluminum oxide;

2Al(s) + 3O2(g) ---> Al2O3(s)

Calculate the pressure exerted by 40 g of oxygen enclosed in a 1litre flask at 25°C. (0=16) (3 Marks) ​

Answers

Answer:

I don't know sorry siso

Explanation:

I don't know

How many grams of solid sodium cyanide should be added to 1.00 L of a 0.119 M hydrocyanic acid solution to prepare a buffer with a pH of 8.809

Answers

Answer:

1.62 g

Explanation:

Given that:

Concentration of HCN = 0.119 M

Assuming the ka 4.00 × 10⁻¹⁰

The pKa of  HCN (hydrocyanic acid)  = -log (Ka)

= - log ( 4.00 × 10⁻¹⁰)

= 9.398

pH of buffer = 8.809

Using Henderson Hasselbach equation:

[tex]pH = pKa + log \dfrac{[conjugate\ base ]}{acid}[/tex]

[tex]pH = pKa + log \dfrac{[CN^-]}{[HCN]}[/tex]

[tex]8.809 = 9.398 +log \dfrac{[CN^-]}{[HCN]}[/tex]

[tex]log \dfrac{[CN^-]}{[HCN]}= 8.809 - 9.398[/tex]

[tex]log \dfrac{[CN^-]}{[HCN]}= -0.589[/tex]

[tex]\dfrac{[CN^-]}{[HCN]}= 0.2576[/tex]

[CN^-] = 0.2576[HCN]

[CN^-] = 0.2756 (0.119) L

[CN^-] = 0.033 M

The amount of NaCN (sodium cyanide) is calculated as follows:

[tex]= 1.00 L \times \dfrac{0.033 \ mol \ NacN }{1 \ L } \times \dfrac{49.01 \ g}{1 \ mol \ of \ NacN}[/tex]

= 1.62 g

During a reaction in an aqueous solution, the concentration of bactants
decreases and the amount of products increases. How do these changes in
concentration affect the reaction rate?
A. The reaction rate decreases.
B. The reaction rate varies unpredictably.
C. The reaction rate increases.
D. The reaction rate stays the same.

Answers

Answer:

my define it will be turst me is c

Draw the predominant product(s) of the following reactions including stereochemistry when it is appropriate. CH3CH2 C C CH3 H2O/H2SO4/HgSO4

Answers

Answer:

Draw the predominant product(s) of the following reactions including stereochemistry when it is appropriate.

CH3CH2 C C CH3 H2O/H2SO4/HgSO4

Explanation:

The given compound is: pent-2-yne.

When it reacts with water, in presence of sulphuric acid and mercuric sulphate then a ketone is formed as shown below:

This reaction is an example of nucleophilic attack of water on carbon carbon triple bond.

The general mechanism of the reaction is hsown below:

Pent-2-yne reacts with water and form 3-pentanone.

The reaction is shown below:

Question 11

1 pts

A solution is formed by dissolving 45 grams of NH4Cl in

100 grams of H20 at 70°C. Which statement correctly

describes this solution?

O NH4Cl is the solute, and the solution is saturated.

O NH4Cl is the solute, and the solution is unsaturated.

o NH4Cl is the solvent, and the solution is unsaturated.

O NH4Cl is the solvent, and the solution is saturated.

< Previous

Answers

Answer:

NH4Cl is the solute, and the solution is unsaturated.

Explanation:

To create a saturated solution of ammonium chloride at 70°C, we need to dissolve 62 g of ammonium chloride in 100 g of water.

The question tells us that 45 grams of NH4Cl was dissolved in 100 grams of H20 at 70°C. This creates an unsaturated solution since the amount of solute present is less than the amount of solute that the NH4Cl solution can normally hold at 70°C.

Hence, NH4Cl is the solute, and the solution is unsaturated.

The rate of the reaction is 1.6*10-2 M/s when the concentration of A is 0.15 M. Calculate the rate constant if the reaction is (a) first order in A and (b) second order in A.

Answers

Answer:

[tex]k_1=0.107s^{-1} \\\\k_2=0.711M^{-1}s^{-1}[/tex]

Explanation:

Hello there!

In this case, according to the given information and the attached picture in which we can see the units of the rate constant, it turns out possible for us to realize the two called rate laws are:

[tex]r=k[A]\\\\r=k[A]^2[/tex]

The former is first-order and the latter second-order; in such a way, we solve for the rate constant in both cases to obtain the following:

[tex]k=\frac{r}{[A]}=\frac{1.6x10^{-2}M/s}{0.15M}=0.107s^{-1} \\\\k=\frac{r}{[A]^2}=\frac{1.6x10^{-2}M/s}{(0.15M)^2}=0.711M^{-1}s^{-1}[/tex]

Regards!

Using Hess’s law, what is the standard enthalpy of formation of manganese (II) oxide, MnO(s)?

Answers

With the help of hess's law:

ΔHf(MnO)=−248.9 kJ−12(272.0) kJ=−384.9 kJ(per mole) Δ H f ( M n O ) = − 248.9 k J − 1 2 ( 272.0 ) k J = − 384.9 k J ( p e r m o l e )

What is Hess's law?

Hess's law of constant heat summation, also known simply as Hess' law, is a relationship in physical chemistry named after Germain Hess, a Swiss-born Russian chemist and physician who published it in 1840.

Moreover, hess's Law of Constant Heat Summation (or just Hess's Law) states that regardless of the multiple stages or steps of a reaction, the total enthalpy change for the reaction is the sum of all changes.

Therefore, hess' law is based on the state function character of enthalpy and the first law of thermodynamics. Energy (enthalpy) of a system (molecule) is a state function.

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examples of isotones

Answers

Answer:

Examples of isotones include carbon-12, nitrogen-13 and oxygen-14. These atoms all have six neutrons and six, seven and eight protons respectively. A mnemonic that can be used to differentiate isotones from isotopes and isobars is as follows: same Z (number of protons) = isotopes.

Carbon, nitrogen, and oxygen.


Spell out the full name of the compound.
Submit
Help plz

Answers

Explanation:

A=Butan-2-one

B=Pentan-3-one

Which of the following reasons explains why if salt water is heated, the water turns into steam while the salt remains?

Water and salt have an equal boiling point.
Water has a lower boiling point than salt.
Salt has a lower boiling point than water.
Salt and water have an equal melting point.

Answers

If the salt water is heated, the water turns into steam and the salt remains because the water has a lower boiling point than the salt.

The  following points can be considered:

The boiling point is defined as the temperature at which the substance turns into the gaseous state from the liquid state.The boiling point of water is [tex]100^{o} C[/tex].The salt is a substance comprising two entities separated by the opposite charges with ionic interactions.The boiling point of a salt is higher than the boiling point of the water.

The process involved when salt water is heated:

The salt water mixture when heated, the water turns into steam at [tex]100^{o} C[/tex]But the salt remains until it reaches its boiling temperature. If the salt is soluble in water and is then heated, then there occurs an elevation in the boiling point of the substance, due to the presence of the salt.

Therefore, the answer is water has a lower boiling point than salt.

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A student collecting CaCO3 produced by the reaction of Na2CO3(aq) and CaCl2(aq) obtains a percent yield of 81%. Choose all of the following observations that could explain the low yield.

a. The combined reactants were not stirred before filtering the precipitate.
b. The student did not completely dry the precipitate before weighing it.
c. The precipitate was not washed prior to drying.
d. A rubber policeman was not used to scrape precipitate from the beaker.
e. The filter paper was not wetted with water prior to filtering the precipitate.

Answers

Answer:

a, d and e. are true.

Explanation:

The reaction that occurs is:

Na2CO3(aq) + CaCl2(aq) → CaCO3(s) + 2NaCl

In ideal conditions, the percent yield of the reaction must be 100%. All explanations about why the student could not collect all precipitate are right:

a. The combined reactants were not stirred before filtering the precipitate. Not stirring could not promote all the reaction. TRUE.

b. The student did not completely dry the precipitate before weighing it. If the student don't dry the precipitate, the mass of precipitate must be higher producing a percent yield > 100%. FALSE.

c. The precipitate was not washed prior to drying. Produce more mass. FALSE.

d. A rubber policeman was not used to scrape precipitate from the beaker. If the student doesn't collect all the precipitate the percent yield could be < 100%.. TRUE.

e. The filter paper was not wetted with water prior to filtering the precipitate. TRUE. If you don't wet the filter paper you can lose a part of precipitate from the walls of this one.

The acid dissociation constant, Ka, of HNO3 is 4.0 x104. What does the ka
value indicate about this compound?
A. HNO3 is neither an acid nor a base,
B. HNO3 is a strong acid.
C. HNO3 is a weak acid
D. HNO3 is a strong base.

Answers

Answer:

i thing its b

Explanation:

The acid dissociation constant (Ka) is a measure of the strength of an acid in solution. In HNO₃ (nitric acid), the given Ka value is 4.0 x 10⁴. It represents the equilibrium constant for the dissociation reaction of an acid in water. Therefore, option B is correct.

The dissociation constant often denoted as Kd, is a measure of the strength of the interaction between a ligand and a receptor or between a substrate and an enzyme.

A high Ka value indicates a strong acid, while a low Ka value indicates a weak acid. In this case, the Ka value of 4.0 x 10⁴ for HNO₃ is relatively high.

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The half life for the radioactive decay of potassium-40 to argon-40 is 1.26×109 years. Suppose nuclear chemical analysis shows that there is 0.359 mmol of argon-40 for every 1.000mmol of potassium-40 in a sample of rock. Calculate the age of the rock.

Answers

Answer:

2.42x10⁹ years is the age of the rock

Explanation:

The decay of an isotope follows the equation:

Ln[A] = -kt + Ln[A]₀

Where [A] is amount of isotope after time t, k is decay constant and [A]₀ is the initial amount of the isotope

To find decay constant from half-life:

k = ln2 / half-life

k = ln2 / 1.26x10⁹years

k = 5.501x10⁻¹⁰ years⁻¹

As in the reaction, K-40 produce Ar-40:

[A] = 0.359mmol

[A]₀ = 0.359mmol + 1.000mmol = 1.359mmol

Replacing:

Ln[0.359mmol] = -5.501x10⁻¹⁰ years⁻¹t + Ln[1.359mmol]

-1.3312 = -5.501x10⁻¹⁰ years⁻¹t

t = 2.42x10⁹ years is the age of the rock

Describe why corrosion is a natural process

Answers

Answer :

Answer :because it happens due to moisture and oxygen

A steel with a critical fracture toughness of 150 MPa.m1/2 has a yield strength of 1500 MPa. If fracture were to take place at the yield stress, answer the following questions.
Surface crack size at yielding leading to failure is:_____________.
a. 0.497 cm
b. 0.994 cm
c. 0.32 cm

Answers

Answer:

c.

Explanation:

From the given information:

Critical fracture toughness [tex]K_{IC}[/tex] = 150 MPa.[tex]m ^{1/2}[/tex]

yield strength [tex]\sigma[/tex] = 1500 MPa

surface crack size [tex]a_c[/tex] = ???

The formula for the fracture toughness is can be expressed as:

[tex]K_{IC}= \sigma \sqrt{\pi a_c}[/tex]

replacing our values to solve for the surface crack size, we have:

[tex]150= 1500 \sqrt{\pi a_c}[/tex]

[tex]\dfrac{150}{ 1500} = \sqrt{\pi a_c}[/tex]

[tex]\dfrac{0.1}{1.77} = \sqrt{ a_c}[/tex]

[tex]a_c[/tex] = 0.0564²

[tex]a_c[/tex] = 0.0032 m

[tex]a_c[/tex] = 0.32 cm

0.159 mol 2.25 M = A L of HCI

Answers

Answer:

hmmm?what?

Explanation:

ayusin mo flece:>

Answer will be
0.159 mol
2.25 M
= A L of HCI
.0707

Hope this helps.

A student measures her computer keyboard with a meter stick and finds that it has a width of 47.35 cm. Which statement about this measurement is true?

PLZZZZ HELP

A.) All the numbers are certain
B.) The 4 is uncertain
C.) The 5 is somewhat uncertain
D.) The 5 is certain ​

Answers

the 5 is somewhat uncertain (c)

What is nitrogen???? explain!!! ​

Answers

Answer:

It is a colourless, odourless, tasteless gas that is the most plentiful element in Earth's atmosphere and is a constituent of all living matter.

Explanation:

Have a nice day :D

Answer:

Nitrogen is a gas

Explanation:

Hukkam aap bio image dekhona please and bataona ki kese lage

Nuclear reactions take place inside the nucleus of the atom. Which of the following does NOT represent an everyday example of a nuclear reaction?

Conversion of carbon dioxide and water in photosynthesis

Hydrogen atoms fused together in the Sun

Loss of protons and electrons in plutonium-240 decay

Energy produced by the Sun that is transferred to Earth

Answers

Answer:

Loss of protons and electrons in plutonium 240 decay is not an example of an everyday reaction

Draw the product formed when diene and dienophile react in a Diels–Alder reaction.

Answers

Answer:

Explanation:

Diels-Alder reactions are cyclo-additional reactions between conjugated dienes and a dienophile (a substituted alkene compound for example acrylic acid) to produce a ring structure of cyclohexene compounds.

From the image attached below, we will see the reaction between 2,3-dimethylbuta-1,3-diene which is a conjugated diene with acrylic acid to produce a Diel-Alder adduct as the product.  From the reaction, a single new π-bond and two σ-bonds are produced.

The products in a decomposition reaction _____. are compounds can be elements or compounds are elements include an element and a compound

Answers

Answer:

compounds are elements include an element and a compound

Explanation:

elements in the decomposition reaction is the substance that cannot be separated into simpler substances. Compounds, technically act as a reactant in the decomposition reaction, but since the reaction breakdown one substance into two or more, sometimes it exists in the product

Match each term with the best description.

a. The electrode where oxidation occurs
b. A device that produces electricity
c. The connection between two half-cells
d. The electrode where reduction occurs
e. A device that consumes electricity
f. A device that utilizes redox reactions to either consume or produce electricity

1. Anode
2. Cathode
3. Electrolytic cell
4. Electrochemical
5. Galvanic cell
6. Salt bridge

Answers

Answer:

Match each term with the best description.

a. The electrode where oxidation occurs: Anode

b. A device that produces electricity: Galvanic cell

c. The connection between two half-cells: salt bridge

d. The electrode where reduction occurs: Cathode

e. A device that consumes electricity: Electrolytic cell

f. A device that utilizes redox reactions to either consume or produce electricity: Electrochemical cell.

Explanation:

a.The electrode where oxidation occurs is called the anode.

Oxidation is losing of electrons.

b. Galvanic cell produces electricity by using redox chemical reaction.

It is also called a voltaic cell or electrochemical cell.

c. The connection between two cells is called a salt bridge.

It will not allow the solutions to diffuse with each other.

It maintains electrical neutrality.

d. The electrode where reduction occurs: Cathode

Reduction means the gaining of electrons.

e. Electrolytic cell is the one that consumes electricity and then produces a chemical change.

f. A device that utilizes redox reactions to either consume or produce electricity: Electrochemical cell.

How is the atomic mass of an element calculated?

Answers

Answer:

Mass number (A) is the number of nucleons (proton and neutron) present in a atom.

Explanation:

electrons don't cout since they are thousandth's of the mass of protons or neutrons

what is the scientific name of lion

Answers

Answer:

the scientific name of lion is

Panthera leo

Panthera leo will be ur answer

PLZZZ HELPPPPPPPPPPPPPPPP

Answers

The answer is B. 9.43.

10.003-0.57= 9.433

Because there is a 3 in the third decimal place and not a number above 5, the 0.03 isn’t rounded up and will remain a 3. This means that when the number is rounded it rounds so 9.43.

Calculate the energy in kj/mol of photon in red light of wavelength 656nm​

Answers

Answer:

you don't know the answer?ha me too

A 0.15 M solution of BaCl2 contains: Group of answer choices 0.30 M Ba2 ions and 0.30 M Cl- ions. 0.15 M Ba2 ions and 0.15 M Cl- ions. 0.30 M Ba2 ions and 0.15 M Cl- ions. 0.15 M Ba2 ions and 0.30 M Cl- ions. none of the above

Answers

Answer:

0.15 M Ba⁺² ions and 0.30 M Cl⁻ ions

Explanation:

The dissociaton of barium chloride is as follows:

BaCl₂ → Ba²⁺ + 2Cl⁻

By observing the stoichiometric coefficients, we can tell that the number of moles of Ba²⁺ is the same as the number of moles of BaCl₂, while the number of moles of Cl⁻ is the double of that.

A chemist requires a large amount of 1-bromo-4-phenyl-2-butene as starting material for a synthesis and decides to carry out the following NBS allylic bromination reaction in the presence of UV light. Draw the structures of all of the observed products.
NBS
(C6H5)CH2CH = CHCH3 → ?
CCI4
Draw one additional resonance structure for the species below:
CH3CH=CHCH=CHCH=CHCH2

Answers

Answer:

CH 2 CH 3 CHCH = C6H5 + 5 Hydrogen Atoms

I hope I helped you.

Deepest apologies if I was wrong!

Bye!

~ Myaka O.

Fabric A is used to rub a wooden rod. A second piece of Fabric A is used to rub an ebonite rod. It is observed that the wooden rod and the ebonite rod attract one another. What can you say about the position of Fabric A in the electrostatic series in relation to wood and ebonite?

Answers

Answer:

What I think is : The protons are present at the centre of the atom with rotating electrons around it so when it is rubbed by fur the electrons get passed from the ebonite rod to the fur leaving the rod negatively charged

Hope this helps you ❤️

Mark me as brainliest ❤️

Fabric A is likely to be a material that has a moderate tendency to gain electrons when in contact with other materials and is lower in the electrostatic series than ebonite but higher than wood.

What is electrostatic series?

The electrostatic series is a list of materials ranked in order of their tendency to gain or lose electrons when in contact with another material.

Materials higher in the series tend to lose electrons more readily and become positively charged, while materials lower in the series tend to gain electrons more readily and become negatively charged.

Ebonite is a synthetic polymer that is known to become negatively charged when rubbed, and it is typically placed near the top of the electrostatic series.

Wood, on the other hand, is a poor conductor of electricity and does not readily become charged when rubbed. Based on these facts, we can infer that Fabric A is lower in the electrostatic series than ebonite, but higher than wood.

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