Answer:
[Ag⁺] = 5.0x10⁻¹⁴M
Explanation:
The product solubility constant, Ksp, of the insoluble salts PbI₂ and AgI is defined as follows:
Ksp(PbI₂) = [Pb²⁺] [I⁻]² = 1.4x10⁻⁸
Ksp(AgI) = [Ag⁺] [I⁻] = 8.3x10⁻¹⁷
The PbI₂ just begin to precipitate when the product [Pb²⁺] [I⁻]² = 1.4x10⁻⁸
As the initial [Pb²⁺] = 0.0050M:
[Pb²⁺] [I⁻]² = 1.4x10⁻⁸
[0.0050] [I⁻]² = 1.4x10⁻⁸
[I⁻]² = 1.4x10⁻⁸ / 0.0050
[I⁻]² = 2.8x10⁻⁶
[I⁻] = 1.67x10⁻³So, as the [I⁻] concentration is also in the expression of Ksp of AgI and you know concentration in solution of I⁻ = 1.67x10⁻³M:
[Ag⁺] [I⁻] = 8.3x10⁻¹⁷
[Ag⁺] [1.67x10⁻³] = 8.3x10⁻¹⁷
[Ag⁺] = 5.0x10⁻¹⁴MIn which of the following compounds does the carbonyl stretch in the IR spectrum occur at the lowest wavenumber?
a. Cyclohexanone
b. Ethyl Acetate
c. λ- butyrolactone
d. Pentanamide
e. Propanoyl Chloride
Answer:
a. Cyclohexanone
Explanation:
The principle of IR technique is based on the vibration of the bonds by using the energy that is in this region of the electromagnetic spectrum. For each bond, there is a specific energy that generates a specific vibration. In this case, you want to study the vibration that is given in the carbonyl group C=O. Which is located around 1700 cm-1.
Now, we must remember that the lower the wavenumber we will have less energy. So, what we should look for in these molecules, is a carbonyl group in which less energy is needed to vibrate since we look for the molecule with a smaller wavenumber.
If we look at the structure of all the molecules we will find that in the last three we have heteroatoms (atoms different to carbon I hydrogen) on the right side of the carbonyl group. These atoms allow the production of resonance structures which makes the molecule more stable. If the molecule is more stable we will need more energy to make it vibrate and therefore greater wavenumbers.
The molecule that fulfills this condition is the cyclohexanone.
See figure 1
I hope it helps!
Consider these metal ion/metal standard reduction potentials Cd2+(aq)|Cd(s) Zn2+(aq)|Zn(s) Ni2+(aq)|Ni(s) Cu2+(aq)|Cu(s) Ag+(aq)|Ag(s) -0.40 V -0.76 V ‑0.25 V +0.34 V +0.80 V Based on the data above, which species is the best reducing agent?
Answer:
The best reducing agent is Zn(s)
Explanation:
A reducing agent must to be able to reduce another compound, by oxidizing itself. Consequently, the oxidation potential must be high. The oxidation potential of a compound is the reduction potential of the same compound with the opposite charge. Given the reduction potentials, the best reducing agent will be the compound with the most negative reduction potential. Among the following reduction potentials:
Cd₂⁺(aq)|Cd(s) ⇒ -0.40 V
Zn²⁺(aq)|Zn(s) ⇒ -0.76 V
Ni²⁺(aq)|Ni(s) ⇒‑0.25 V
Cu²⁺(aq)|Cu(s) ⇒ +0.34 V
Ag⁺(aq)|Ag(s) ⇒ +0.80 V
The most negative is Zn²⁺(aq)|Zn(s) ⇒ -0.76 V
From this, the most reducing agent is Zn. Zn(s) is oxidized to Zn²⁺ ions with the highest oxidation potential (0.76 V).
When titrating a strong acid with a strong base, after the equivalence point is reached, the pH will be determined exclusively by: Select the correct answer below:
A) hydronium concentration
B) hydroxide concentration
C) conjugate base concentration
D) conjugate acid concentration
Answer:
B) hydroxide concentration
Explanation:
Hello,
In this case, since we are talking about strong both base and acid, since the base is the titrant and the acid the analyte, once the equivalence point has been reached, some additional base could be added before the experimenter realizes about it, therefore, since the titrant is a strong base, it completely dissociates in hydroxide ions and metallic ions which allows us to compute the pOH of the solution by known the hydroxide ions concentration.
After that, due to the fact that the pH is related with the pOH as shown below:
pH=14-pOH
We can directly compute the pH.
Best regards.
Calculate the molarity of a solution containing 29g of glucose (C 6 H 12 O 6 ) dissolved in 24.0g of water. Assume the density of water is 1.00g/mL.
Answer:
whats the ph ofpoh=9.78
Explanation:
How does the spontaneity of the process below depend on temperature? PCl5(g)+H2O(g)→POCl3(g)+2HCl(g) ΔH=−126 kJ mol−1, ΔS=146 J K−1mol−
The given question is incomplete, the complete question is:
How does the spontaneity of the process below depend on temperature? PCI5(9)+H2O(g)POCI3(g) +2HCI(g) -126 kJ mol1, AS = 146 J K-'mol1 ΔΗ Select the correct answer below: nonspontaneous at all temperatures spontaneous at all temperatures spontaneous at high temperatures and nonspontaneous at low temperatures spontaneous at low temperatures and nonspontaneous at high temperatures
Answer:
The correct answer is spontaneous at all the temperatures.
Explanation:
Gibbs Free energy is an essential relation that determines the spontaneity of any reaction, that is, ΔG = ΔH - TΔS
When ΔG is less than zero, that is, negative, the reaction is considered to be in spontaneous state. Based on the given information, ΔH = -126 kJ/mol
= -126000 J/mol, it is negative
ΔS = 146 J/K/mol, it is positive
Now, ΔG = ΔH-TΔS
= (-ve) - T (+ve), Thus, when ΔH, is -ve, ΔS is +ve, -TΔS is -ve, the ΔG will be -ve. Therefore, reaction will be spontaneous at all the temperatures.
What is the energy of a photon of electromagnetic radiation with a wavelength of 963.5 nm? (c = 3.00 × 108 m/s, h = 6.63 × 10–34 J · s
Answer:
[tex]E=2.06\times 10^{-19}\ J[/tex]
Explanation:
Given that,
The wavelength of electromagnetic radiation is 963.5 nm.
We need to find the energy of a photon with this wavelength.
The formula used to find the energy of a photon is given by :
[tex]E=\dfrac{hc}{\lambda}\\\\E=\dfrac{6.63\times 10^{-34}\times 3\times 10^8}{963.5\times 10^{-9}}\\\\E=2.06\times 10^{-19}\ J[/tex]
So, the energy of a photon is [tex]2.06\times 10^{-19}\ J[/tex].
A piece of solid Fe metal is put into an aqueous solution of Cu(NO3)2. Write the net ionic equation for any single-replacement redox reaction that may be predicted. Assume that the oxidation state of in the resulted solution is 2 . (Use the lowest possible coefficients for the reaction. Use the pull-down boxes to specify states such as (aq) or (s). If a box is not needed, leave it blank. If no reaction occurs, leave all boxes blank and click on Submit.)
Answer:
Fe(s) + Cu^2+(aq) ---> Fe^2+(aq) + Cu(s)
Explanation:
The ionic equation shows the actual reaction that took place. It excludes the spectator ions. Spectator ions are ions that do not really participate in the reaction even though they are present in the system.
For the reaction between iron and copper II nitrate, the molecular reaction equation is;
Fe(s) + Cu(NO3)2(aq)----> Fe(NO3)2(aq) +Cu(s)
Ionically;
Fe(s) + Cu^2+(aq) ---> Fe^2+(aq) + Cu(s)
How has the work of chemists affected the environment over the years?
Answer:
Chemistry is one of the causes for global warming, and in some cases it can even cause certain illnesses.
Answer:
Chemists have both hurt the environment and helped the environment by their actions.
Explanation:
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What is the ph of 0.36M HNO3 ?
Answer:
0.44
Explanation:
We know that the pH of any acid solution is given by the negative logarithm of its hydrogen ion concentration. Hence, if I can obtain the hydrogen ion concentration of any acid, I can obtain its pH.
For the acid, HNO3, [H^+] = [NO3^-]= 0.36 M
pH= -log [H^+]
pH= - log[0.36]
pH= 0.44
243
Am
95
1. The atomic symbol of americium-243 is shown. Which of the following is correct?
• A. The atomic mass is 243 amu, and the atomic number is 95.
B. The atomic mass is 338 amu, and the atomic number is 95.
• C. The atomic mass is 95 amu, and the atomic number is 243.
D. The atomic mass is 243 amu, and the atomic number is 338.
Answer:
A. The atomic mass is 243 amu, and the atomic number is 95.
A 1.0 L buffer solution is 0.250 M HC2H3O2 and 0.050 M LiC2H3O2. Which of the following actions will destroy the buffer?
A. adding 0.050 moles of NaOH
B. adding 0.050 moles of LiC2H3O2
C. adding 0.050 moles of HC2H3O2
D. adding 0.050 moles of HCl
E. None of the above will destroy the buffer.
Answer:
D
Explanation:
Addition of 0.05 M HCl, will react with all of the C2H3O2- from LiAc which will give 0.05 M more HAc. So there will be no Acetate ion left to make the solution buffer. Hence, the correct option for the this question is d, which is adding 0.050 moles of HCl.
The action that destroys the buffer is option c. adding 0.050 moles of HCl.
What is acid buffer?It is a solution of a weak acid and salt.
Here, The buffer will destroy at the time when either HC2H3O2 or NaC2H3O2 should not be present in the solution.
The addition of equal moles of HCl finishly reacts with equal moles of NaC2H3O2. Due to this, there will be only acid in the solution.
Since
moles of HC2H3O2 = 1*0.250 = 0.250
moles of NaC2H3O2 = 1*0.050 = 0.050.
moles of HCl is added = 0.050
Now
The reaction between HCl and NaC2H3O2
[tex]HCl + NaC_2H_3O_2 \rightarrow HC_2H_3O_2 + NaCl[/tex]
Now
BCA table is
NaC2H3O2 HCl HC2H3O2
Before 0.050 0.050 0.250
Change -0.050 -0.050 +0.050
After 0 0 0.300
Now, the solution contains the acid (HC2H3O2 ) only.
Therefore addition of 0.050 moles of HCl will destroy the buffer.
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When methane is burned with oxygen, the products are carbon dioxide and water. If you produce 9 grams of water and 11 grams of carbon dioxide from 16 grams of oxygen, how many
The given question is incomplete.
The complete question is:
When methane is burned with oxygen, the products are carbon dioxide and water. If you produce 9 grams of water and 11 grams of carbon dioxide from 16 grams of oxygen, how many grams of methane were needed for the reaction?
Answer: 4 grams of methane were needed for the reaction
Explanation:
According to the law of conservation of mass, mass can neither be created nor be destroyed. Thus the mass of products has to be equal to the mass of reactants. The number of atoms of each element has to be same on reactant and product side. Thus chemical equations are balanced.
{tex]CH_4+2O_2\rightarrow CO_2+H_2O[/tex]
Given: mass of oxygen = 16 g
Mass of carbon dioxide = 11 g
Mass of water = 9 g
Mass of products = Mass of carbon dioxide + mass of water = 11 g +9 g = 20 g
Mass or reactant = mass of methane + mass of oxygen = mass of methane + 16 g
As mass of reactants = mass of products
mass of methane + 16 g= 20 g
mass of methane = 4 g
Thus 4 grams of methane were needed for the reaction
Calculate the amount of heat that must be absorbed by 10.0 g of ice at –20°C to convert it to liquid water at 60.0°C. Given: specific heat (ice) = 2.1 J/g·°C; specific heat (water) = 4.18 J/g·°C; ΔH fus = 6.0 kJ/mol.
Answer:
The amount of heat to absorb is 6,261 J
Explanation:
Calorimetry is in charge of measuring the amount of heat generated or lost in certain physical or chemical processes.
The total energy required is the sum of the energy to heat the ice from -20 ° C to ice of 0 ° C, melting the ice of 0 ° C in 0 ° C water and finally heating the water to 60 ° C.
So:
Heat required to raise the temperature of ice from -20 °C to 0 °CBeing the sensible heat of a body the amount of heat received or transferred by a body when it undergoes a temperature variation (Δt) without there being a change of physical state (solid, liquid or gaseous), the expression is used:
Q = c * m * ΔT
Where Q is the heat exchanged by a body of mass m, made up of a specific heat substance c and where ΔT is the temperature variation (ΔT=Tfinal - Tinitial).
In this case, m= 10 g, specific heat of the ice= 2.1 [tex]\frac{J}{g*C}[/tex] and ΔT=0 C - (-20 C)= 20 C
Replacing: Q= 10 g*2.1 [tex]\frac{J}{g*C}[/tex] *20 C and solving: Q=420 J
Heat required to convert 0 °C ice to 0 °C waterThe heat Q necessary to melt a substance depends on its mass m and on the called latent heat of fusion of each substance:
Q= m* ΔHfusion
In this case, being 1 mol of water= 18 grams: Q= 10 g*[tex]6.0 \frac{kJ}{mol} *\frac{1 mol of water}{18 g}[/tex]= 3.333 kJ= 3,333 J (being kJ=1,000 J)
Heat required to raise the temperature of water from 0 °C to 60 °CIn this case the expression used in the first step is used, but being: m= 10 g, specific heat of the water= 4.18 [tex]\frac{J}{g*C}[/tex] and ΔT=60 C - (0 C)= 60 C
Replacing: Q= 10 g*4.18 [tex]\frac{J}{g*C}[/tex] *60 C and solving: Q=2,508 J
Finally, Qtotal= 420 J + 3,333 J + 2,508 J
Qtotal= 6,261 J
The amount of heat to absorb is 6,261 J
The amount of heat to absorb is 6,261 J.
Calculation for heat:Heat required to raise the temperature of ice from -20 °C to 0 °C.
The formula for specific heat is used to calculate the amount of heat
Q = c * m * ΔT
Where,
Q =heat exchanged by a body,
m= mass of the body
c= specific heat
ΔT= change in temperature
Given:
m= 10 g,
specific heat of the ice= 2.1
ΔT=0 C - (-20 C)= 20 C
On substituting the values:
Q= 10 g*2.1 *20 C
Q=420 J
Heat required to convert 0 °C ice to 0 °C water.
The heat Q necessary to melt a substance depends on its mass m and on the called latent heat of fusion of each substance:
Q= m* ΔHfusion
Heat required to raise the temperature of water from 0 °C to 60 °C
m= 10 g,
Specific heat of the water= 4.18
ΔT=60 C - (0 C)= 60 C
On substituting:
Q= 10 g*4.18 *60 C
Q=2,508 J
Thus, Qtotal= 420 J + 3,333 J + 2,508 J
Qtotal= 6,261 J
The amount of heat to absorb is 6,261 J
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