Starting from (R)-3-methylhex-1-yne as the substrate at the center of your page, draw a reaction map showing the regiochemical and stereochemical outcome or outcomes for each of the following series of reagents. Name each of your products, including stereochemical designations for any chirality centers that are generated.

a. HgSO4, H2SO4, H2O
b. 1. 9-BBN; 2. H2O2, NaOH
c. Br2, CCl4
d. HBr

Answers

Answer 1

Solution :

A substrate is defined as the chemical species that are being observed in the chemical reaction where the substrate reacts with a reagent and forms a product. It can also be referred to the surface where some other chemical reactions are performed.

Stereochemistry is defined as the study of relative spatial arrangement of the atoms which forms the structure of the molecules and their respective manipulations.

In the context, the products including the stereochemical designations for any chirality centers starting from the  (R)-3-methylhex-1-yne as the substrate are attached below.  


Related Questions

2. An ion is a charged particle that is formed when
a. An atom gains electrons
b. An atom loses electrons
c. Both A and B
d. None of the above

Answers

The correct answer is option c. Both A and B: An ion is a charged particle that is formed when an atom gains electrons or an atom loses electrons.

First you need to know the definition of ion. An ion is a molecule or atom that has a positive or negative electrical charge.

That is, an ion is an atom whose electric charge is not neutral. This charged particle can be positive or negative.  

Ionization is the chemical or physical process by which ions are produced. In this process, negatively charged ions are produced by gaining electrons and are known as anions.

The positively charged are produced by the loss of electrons and are known as cations.

In summary, an ion is a charged particle that is formed when  an atom gains electrons or an atom loses electrons, and they are known as cations and anions respectively.

The correct answer is both A and B.

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Consider an equilibrium (K1) that is established after 10 mL of compound A and 10 mL of compound B are mixed. Now, imagine the equilibrium (K2) where 1 mL of compound A is added to 100 mL of compound B. How are K1 and K2 related algebraically (read this question VERY carefully, at least one more time)

Answers

The equilibrium constant K₁ = Equilbrium constant K₂.

The equilibrium constant, K, of a reaction, is defined as:

"The ratio between concentration of products powered to their reaction quotient and concentration of reactants powered to thier reaction quotient".

For the reaction:

aA + bB ⇄ cC + dD

The equilibrium constant, K, is:

[tex]K = \frac{[C]^c[D]^d}{[A]^a[B]^b}[/tex]

Now, assuming the reaction of the problem is 1:1:

A + B ⇄ C + D

[tex]K = \frac{[C][D]}{[A][B]}[/tex]

The concentrations of the reactants are directly proportional to the volume added. Thus, we can assume that concentration = Volume. Replacing for K₁ and K₂:

[tex]K_1 = \frac{[C][D]}{[10mL][10mL]} = K_1 = \frac{[C][D]}{100mL^2}[/tex]

In the same way:

[tex]K_2 = \frac{[C][D]}{[1mL][100mL]} = K_2 = \frac{[C][D]}{100mL^2}[/tex]

Thus, we can say:

K₁ = K₂

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In the graphic, 195 represents the _______.

195 Pt
78

A. Atomic Mass
B. Atomic Number
C. Neutron Number​

Answers

Answer:

ITS ANSWER IS

OPTION B. ATOMIC NUMBER

HI HAVE A NICE DAY

When hydrogen gas reacts with oxygen gas, water vapour is formed according to the
reaction 2H2 + O2 2H2O. If 3.00 mol of hydrogen gas react with 3.00 mol
of oxygen gas, which reactant will be the reactant in excess?

Answers

Explanation:

here's the answer to the question

How did Kepler's discoveries contribute to astronomy?
O They supported the heliocentric model.
O They established the laws of planetary motion.
O They explained how the Sun rises and sets.
O They made astronomy accessible to people who spoke Italian.
They made astronomy accessible to people who spoke italian

Answers

Answer:

"They established the laws of planetary motion"

Explanation:

Mr. Kepler was the astronomer who came up with the "Laws of Planetary Motion."

A central atom has two lone pairs on opposite sides and four single bonds. What is the molecule geometry of the result?

A. octahedral

B. tetrahedral

C. square planar

D. linear

Answers

The correct answer is C. square planar

According to the Valence Shell Electron Pair Repulsion Theory(VSEPR), The shape of a molecule depends on the number of electron pairs in the molecule.

VSEPR theory was first coined by Gillespie  and Nyhlom in 1957 as an improvement over the Sidgwick - Powell theory.

According to this theory, the shape of a molecule is determined by the number of electron pairs that surround the valence shell of the central atom in the molecule.  The electron pairs are positioned as far apart in space as possible to minimize repulsion of electron pairs.

However, the presence of lone pairs distorts the shape anticipated for the molecule on the basis of VSEPR.

For a molecule having six electron pairs, an octahedral geometry is expected(electron domain geometry). However, the presence of two lone pairs which are positioned at opposite side of the four single bonds leads to an observed square planar molecular geometry.

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Answer:

square planar

Explanation:

what is the bond energy required to break one mole of carbon-carbon bonds​

Answers

Answer:

100 kcal of bond energy

a. You have a stock solution of 14.8 M NH3. How many milliliters of this solution should you dilute to make 1000.0 mL of 0.250 M NH3?
b. If you take a 10.0 mL portion of the stock solution and dilute it to a total volume of 0.500 L, what will be the concentration of the final solution?

Answers

Answer:A) V = 16.892 ml

Explanation:

M1 * V1 = M2 * V2

14.8 M * V1 =0.250 M * 1000 ml

V1 = 16.892 ml

a. The volume of 16.89 milliliters of the stock solution of 14.8 M  should be diluted to make 1000.0 mL of 0.250 M.

b. The concentration of the final solution is 0.296 M.

What is the dilution law?

The concentration or the volume of the concentrated or dilute solution can be calculated by using the equation:

M₁V₁ = M₂V₂

where M₁ and V₁ are the concentration and volume of the concentrated solution respectively and M₂ and V₂ are the concentration and volume of the dilute solution.

A stock solution is a solution that has a high concentration and that will be diluted to a low concentration by the addition of water in it.

Given, a stock solution of concentration, M₁ = 14.8 M

The concentration of the diluted solution, M₂ = 0.250 M

The volume of diluted solution, V₂  = 1000ml

Substitute the value of the molarity and volume in equation (1):

(14.8)× (V₁) = (1000) × (0.250)

V₁ = 16.89 ml

Similarly, for part (b): M₁ = 14.8 M, V₁ = 10 ml and V₂  = 0.5L = 500 ml

(14.8)× (10) = (500) × (M₂)

M₂ = 0.296 M

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Two common methods to generate an aldehyde is by oxidation of an alcohol and through ozonolysis.

a. True
b. False

Answers

Answer:

a. True.

Explanation:

Only primary and secondary alcohols can oxidise to give an aldehyde. But a weak oxidizing agent must be used to prevent formation of a carboxylic acid or ketone.

weak oxidizing agents: Chromyl chloride, silver/oxygen/500°C

take an example of ethanol:

[tex]{ \bf{CH _{3} CH_{2}OH \: \: \frac{Ag/O_{2} }{500 \degree C} > \: \:CH _{3} CHO}}[/tex]

[tex]{ \sf{CH _{3} CHO \: \: is \: ethanal}} [/tex]

By ozonolysis:

Here, reactants are Ozone gas, Carbon tetrachloride at a temperature (<20°C), ethanoic acid, zinc and water.

take an example of propanol:

if it undergoes ozonolysis, it gives ethanal and methanal.

Answer:

A. True

Explanation:

Only primary and secondary alcohols can oxidise to give an aldehyde. But a weak oxidizing agent must be used to prevent formation of a carboxylic acid or ketone.

weak oxidizing agents: Chromyl chloride, silver/oxygen/500°C

take an example of ethanol:

By ozonolysis:

Here, reactants are Ozone gas, Carbon tetrachloride at a temperature (<20°C), ethanoic acid, zinc and water.

take an example of propanol:

if it undergoes ozonolysis, it gives ethanal and methanal.

Write balanced equations for the reaction of each of the following carboxylic acids with NaOH. Part A formic acid Express your answer as a chemical equation. A chemical reaction does not occur for this question. Request Answer Part B 3-chloropropanoic acid Express your answer as a chemical equation. nothing A chemical reaction does not occur for this question.

Answers

Answer:

Part A

HCOOH(aq) + NaOH(aq) → HCOONa(aq) + H2O(l)

Part B

ClCH2CH2CO2H(aq) + NaOH(aq) ------> ClCH2CH2CO2Na(aq) + H2O(l)

Explanation:

The reaction between an alkanoic acid and a base is a neutralization reaction. The reaction occurs as follows;

RCOOH + NaOH ----> RCOONa + H2O

We have to note the fact that the net ionic reaction still remains;

H^+(aq) + OH^-(aq) ---> H2O(l)

In both cases, the reaction can occur and they actually do occur as written.

Consider the reaction: A(aq) + 2B (aq) === C (aq). Initially 1.00 mol A and 1.80 mol B
were placed in a 5.00-liter container. The mole of B at equilibrium was determined to
be 1.00 mol. Calculate K value.
0.060
5.1
25
17
Ugh

Answers

Answer:

17

Explanation:

Step 1: Calculate the needed concentrations

[A]i = 1.00 mol/5.00 L = 0.200 M

[B]i = 1.80 mol/5.00 L = 0.360 M

[B]e = 1.00 mol/5.00 L = 0.200 M

Step 2: Make an ICE chart

        A(aq) + 2 B(aq) ⇄ C(aq)

I       0.200    0.360        0

C        -x           -2x         +x

E     0.200-x  0.360-2x   x

Then,

[B]e = 0.360-2x = 0.200

x = 0.0800

The concentrations at equilibrium are:

[A]e = 0.200-0.0800 = 0.120 M

[B]e = 0.200 M

[C]e = 0.0800 M

Step 3: Calculate the concentration equilibrium constant (K)

K = [C] / [A] × [B]²

K = 0.0800 / 0.120 × 0.200² = 16.6 ≈ 17

Determine the number of moles of aluminum in 2.154 x 10-1 kg of Al. Group of answer choices 5816 mol 7.984 mol 6.02 X 1023 mol 4.801 mol 8.783

Answers

Answer:

Avogadro's number is 1 mol  = 6.02 * 10^23 elements

It means that 1 mol of atoms is 6.02 * 10^23 atoms

1 mol of atoms = 6.02 * 10^23 atoms

From there, if you divide both sides by 1 mol of atoms, you get

1 = 6.02 * 10^23 atoms / 1 mol of atoms.

That means, that to pass from a number of moles of atoms to number of atoms you have to multipby by the conversion factor

         6.02*10^23  atoms Al/ 1 mol Al

That is the second option of the list.

Explanation:

Forcus on the yellow highlighted texts, your help is appreciated.
[tex]{ \sf{ \red{no \: pranks}}}[/tex]

Answers

Answer:

Transition temperature is the temperature at which a substance changes from one state to another.

Allotropy is the existence of an element in many forms.

Each 5-ml teaspoon of Extra Strength Maalox Plus contains 450 mg of magnesium hydroxide and 500 mg of aluminum hydroxide. How many moles of hydronium ions H3O are neutralized by 1 teaspoon of antacid product?

Answers

Answer:

0.0347 moles of hydronium ions

Explanation:

The equation of the neutralization reaction between hydroxide and hydronium ions is given below:

H₃O+ (aq) + OH- (aq) ----> 2 H₂O (l)

From the equation above, 1 mole of hydroxide ions will neutralize one mole hydronium ions.

The moles of hydroxide ions present in 1 teaspoon or 5 mL of antacid product is calculated as follows:

Number of moles = mass / molar mass

Molar mass of Magnesium hydroxide, Mg(OH)₂ = 58 g/mol

Molar mass of aluminium hydroxide, Al(OH)₃ = 78 g/mol

Mass of magnesium hydroxide = 450 g = 0.45 g

Mass of aluminium hydroxide = 500 mg = 0.5 g

Moles of magnesium hydroxide = (0.45/58) moles

Moles of aluminium hydroxide = (0.5/78) moles

Equation of the ionization of magnesium hydroxide and aluminium hydroxide is given below:

Mg(OH)₂ (aq) ----> Mg²+ (aq) + 2 OH- (aq)

Al(OH)₃ (aq) ---> Al³+ (aq) + 3 OH- (aq)

Number of moles of hydroxide ions present in (0.45/58) moles of magnesium hydroxide = 2 × (0.45/58) moles = 0.0155 moles

Number of moles of hydroxide ions present in (0.5/78) moles of aluminium hydroxide = 3 × (0.5/78) moles = 0.0192 moles

Total moles of hydroxide ions = 0.0155 + 0.0192 = 0.0347 moles hydroxide ions

Therefore, 0.0347 moles of hydroxide ions will neutralize 0.0347 moles of hydronium ions.

6) Hydrogen gas can be generated from the reaction between aluminum metal and hydrochloric acid:
2 Al(s) + 6 HCl(aq) + 2 AICI3, (aq) + 3 H2(g)
a. Suppose that 3.00 grams of Al are mixed with excess acid. If the hydrogen gas produced is directly collected
into a 850 mL glass flask at 24.0 °C, what is the pressure inside the flask (in atm)?
b. This hydrogen gas is then completely transferred from the flask to a balloon. To what volume (in L) will the
balloon inflate under STP conditions?
c. Suppose the balloon is released and rises up to an altitude where the temperature is 11.2 °C and the pressure is
438 mm Hg. What is the new volume of the balloon (in L)?

Answers

Stoichiometry refers to the relationship between the moles of reactants and products.

This question must be solved using both stoichiometry and the gas laws

The reaction equation is;

2 Al(s) + 6 HCl(aq) --------> 2 AICI3, (aq) + 3 H2(g)

Using stoichiometry

Number of moles of Al = 3g/27g/mol = 0.11 moles

According to the reaction equation;

2 moles of Al yields 3 moles of H2

0.11 moles of Al yields 0.11 * 3/2 = 0.165 moles

Using the gas laws

From the ideal gas equation;

PV=nRT

P = ?

n= 0.165 moles

V = 0.85 L

T = 297 K

R = 0.082 atmLK-1mol-1

P= nRT/V

P = 0.165 * 0.082 * 297/0.85

P= 4.73 atm

Under STP conditions;

P1 = 4.73 atm

T1 = 297 K

V1 = 0.85 L

P2 = 1 atm

T2 =273 K

V2 =?

From the general gas equation;

P1V1/T1 = P2V2/T2

P1V1T2 = P2V2T1

V2 = P1V1T2/P2T1

V2 =  4.73 * 0.85 * 273/1 * 297

V2 = 3.69 L

P1 = 760 mmHg

T1 = 273 K

V1 = 3.69

P2 = 438 mm Hg

T2 = 284.2 K

V2 =?

P1V1/T1 = P2V2/T2

P1V1T2 = P2V2T1

V2 = P1V1T2/P2T1

V2 = 760 * 3.69 * 284.2/438 *273

V2 = 797010.48/119574

V2= 6.67 L

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The elementary reaction 2H2O(g)↽−−⇀2H2(g)+O2(g) proceeds at a certain temperature until the partial pressures of H2O, H2, and O2 reach 0.0900 bar , 0.00100 bar , and 0.00350 bar respectively. What is the value of the equilibrium constant at this temperature?

Answers

Answer:

3.89 ×10^-5

Explanation:

Since they are gaseous reactants, we obtain the equilibrium constant from the given partial pressures;

p(H2O) = 0.0900 bar

p(H2) = 0.00100 bar

p(O2) = 0.00350 bar

The equation of the reaction is;2H2O(g)⇄2H2(g)+O2(g)

Kp= p(H2) . p(O2)/p(H2O)

Kp= 0.00100 × 0.00350/0.0900

Kp= 3.89 ×10^-5

Draw a formula for Thr-Gly-Ala (T-G-A) in its predominant ionic form at pH 7.3. You may assume for the purposes of this question that the pKa values of the acidic groups of amino acid residues in the peptide are the same as in the amino acid itself.

Answers

Answer:

gggggggggg

Explanation:

gggggggg

The tripeptide formed from threonine, glycine and alanine is neutral at the pH of 7.3. The carboxylic end is negative charged by donating its proton to form the NH₃⁺ group.

What is peptide?

Peptides are protein units formed from two or more amino acids bonded through peptide bonds. There are essential and non-essential amino acids. Essential amino acids have to be uptake from food and non-essential amino acids are synthesized inside the body.

Threonine is an essential amino acid with a CH₃CHOH side group. Glycine has the simplest side group hydrogen and alanine has  CH₃ side chain. Both glycine and alanine are non-essential amino acids.

Each amino acids are represented with a three letter code or one letter symbol. Thus threonine is T,  G for glycine and A for alanine. At a pH of 7.3 the peptide formed from these amino-acids contains a negatively charged carboxylic end.

A positively charged amino end made by protonation from the acid group make the overall charge zero. The structure of the peptide is given in the uploaded image.

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The mass of a container is determined to be 1.2 g. A sample of a compound is transferred to this container, and the mass of the compound plus the container is determined to be 3.06 g. The mass of the compound should be reported as:__.

Answers

Answer:

Sorry I don't know what you

According to law of conservation of mass as mass is neither created nor destroyed mass of compound should be reported as 1.86 g that is by subtracting mass of compound from mass of compound and container.

What is law of conservation of mass?

According to law of conservation of mass, it is evident that mass is neither created nor destroyed rather it is restored at the end of a chemical reaction .

Law of conservation of mass and energy are related as mass and energy are directly proportional which is indicated by the equation E=mc².Concept of conservation of mass is widely used in field of chemistry, fluid dynamics.

Law needs to be modified in accordance with laws of quantum mechanics under the principle of mass and energy equivalence.This law was proposed by Antoine Lavoisier in the year 1789.

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A nuclease enzyme breaks the covalent bond originally connecting the phosphate to the 5' carbon in a nucleic acid. After allowing this enzyme to completely digest the nucleic acid down to monomers, you perform tests to determine where the phosphate is attached to each monomer. Where do you expect to find this phosphate

Answers

Answer:

The phosphate will remain attached to the 5' carbon of the deoxy or the ribose sugar in the nucleic acid monomers.

Explanation:

The structure of nucleic acid polymers is built up from monomers of nucleotides.

A nucleotide consists of a sugar backbone which is either a ribose or deoxyribose sugar, a nitogenous base which is either a purine or pyrimidine, and a phosphate group. The nitrogenous base is attached to the carbon number 1 or C-1 of the sugar backbone by a covalent bond. The phosphate group on the other hand is covalently attached to the carbon number 5 or 5' carbon of the sugar backbone.

When polymers of nucleic acids are formed, the phosphate at the 5' carbon of the sugar backbone is covalently linked in a phosphodiester bond to the 3' carbon of the sugar backbone in another nucleotide molecule, thus extending the strands of the nucleic acid molecule.

Nucleases are enzymes that break down the phosphodiseter bonds in nucleic acids resulting in nucleotide monomers. After complete digestion ofmthe nucleic acid polymer by nucleases, the phosphate will remain attached to the 5' carbon of the deoxy or the ribose sugar in the nucleic acid monomers.

The functional groups in an organic compound can frequently be deduced from its infrared absorption spectrum.

a. True
b. False

Answers

Answer:

a. True

Explanation:

The main information that gives an infrared absorption spectrum is the type of functional groups that are present in an organic compound. The infrared (IR) spectroscopy is based on the fact that functional groups absorb light in the IR region of the electromagnetic spectrum (approximately at 2,500-16,000 nm) and induces a vibrational excitation of the covalently bonded atoms in the group. The vibration of the atoms can be of different types, such as stretching, bending, etc. Each functional group (such as the carbonyl group) in an organic compound absorbs at a specific IR frequency so they can be distinguished from an IR spectrum.

How many grams of H₂SO₄ are contained in 2.00 L of 6.0 M H₂SO₄?

Please explain and show work.

Answers

Answer:

1176 grams

Explanation:

nH2SO4 =2*6=12 mol

mH2SO4=12*98=1176 grams

Answer:

solution given:

molarity of H₂SO₄=6 M

volume=2L

no of mole =6M*2=12mole

we have

mass =mole* actual mass=12*98=1176g

the mass is 1176g.

The freezing point of a substance is -20°C. Its boiling point is 120°C.
a. At 80°C the substance is in the state
b. At -50°C the substance is in the state.
C. At 140°C the substance is in the state.

Answers

Answer:

a. liquid

b. solid

c. gas, (should be at it's boiling point)

Explanation: If the normal melting point of a substance is below room temperature, the substance is a liquid at room temperature. Benzene melts at 6°C and boils at 80°C; it is a liquid at room temperature. If both the normal melting point and the normal boiling point are above room temperature, the substance is a solid.

if you need an explanation to each lmk

Which of the following best describes physical science?
0...
OA.
the study of motion
OB.
the study of matter and energy
O C.
the study of Earth's structure and processes
OD.
the study of reactions
O E.
the study of living things
Reset
Ne

Answers

B. The study of matter and energy.

Because physical science is everything that doesn't include organic things.

The  study of matter and energy among the following  best describes physical science.

What is matter?

Matter in chemistry, is defined as any kind of substance that has mass and occupies space that means it possess volume .Matter is composed up of atoms which may or not be of same type.

Atoms are further made up of sub atomic particles which are the protons ,neutrons and the electrons .The matter can exist in various states  of substances such as solids, liquids and gases depending on the conditions of  the temperature and  the pressure.

The states of matter are inter convertible into each other by changing the parameters of temperature and pressure.Matter is always conserved by law of conservation of matter.The law was proposed by Antoine Lavoisier.

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At what velocity (m/s) must a 20.0g object be moving in order to possess a kinetic energy of 1.00J

Answers

Answer:

10 ms-1

Explanation:

Kinetic energy = 1/2 × m × v^2

1 = 1/2× 20 ×10^ -3 × v^2

v ^ 2 = 100

v = 10 ms-1

note : convert grams in to kg before substitution as above

The velocity will be "10 m/s".

Given:

Kinetic energy,

K.E = 1.00 J

Mass,

m = 20.0 g

We know the formula,

→ [tex]K.E = \frac{1}{2} mv^2[/tex]

By putting the values, we get

       [tex]1 = \frac{1}{2}\times 20\times 10^{-3}\times (v)^2[/tex]

     [tex]v^2 = 100[/tex]

       [tex]v = \sqrt{100}[/tex]

       [tex]v = 10 \ m/s[/tex]

Thus the above response is correct.

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Determine which choice is an example of an endothermic process.
O A. Lighting a match
B. Respiration
C. Running a gas engine
D. Baking bread

Answers

Answer:

D. Baking bread

Explanation:

In this process, energy is absorbed and in an endothermic process energy is absorbed too.

Baking bread is an example of an endothermic process, therefore option (d) is correct .

What do you mean by endothermic process ?

Endothermic reactions are chemical processes in which the reactants absorb heat from the environment to produce products.

An endothermic reaction is  accompanied by an absorption of heat.

Endothermic  reactions cause a cooling effect by lowering the temperature of the surrounding environment.

A decrease in temperature can be observed with the progression of the reaction. The reaction is non-spontaneous in endothermic reactions .

Baking bread is an example of an endothermic process, hence  option (d) is correct .

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In practice, the second law of thermodynamics means that:

a. Systems move from ordered behavior to more random behavior.
b. Systems move from random behavior to more ordered behavior.
c. Systems move between ordered and random behavior patterns based on temperature.
d. Systems are constantly striving to reach equilibrium.

Answers

Answer:

Systems move from ordered behavior to more random behavior.

Explanation:

Entropy refers to the degree of disorderliness in a system. The second law of thermodynamics can be restated in terms of entropy as follows; “any spontaneous process in any isolated system always results in an increase in the entropy of that system.''(science direct)

According to this law, systems tend towards a more disorderly behaviour (increase in entropy) hence the answer given above.

ort
Which is a primary alcohol?
0 3-pentanol
2-propanol
1-ethanol
4-octanol
urvey
Lig A Moving to another question will save this response.

Answers

Answer:

1 ethanol is right answer

Explanation:

CH3- CH2-OH

Nitric acid can be formed in two steps from the atmospheric gases nitrogen and oxygen, plus hydrogen prepared by reforming natural gas. In the first step, nitrogen and hydrogen react to form ammonia: N2 (g) + 3H2 (g) â 2NH3 (g) =ÎHâ92.kJ In the second step, ammonia and oxygen react to form nitric acid and water:

NH3 (g) + 2O2 (g) â HNO3 (g) + H2O (g) =ÎHâ330.kJ

Required:
Calculate the net change in enthalpy for the formation of one mole of nitric acid from nitrogen, hydrogen and oxygen from these reactions.

Answers

Answer:

-376 kJ

Explanation:

The first step equation:

[tex]\mathsf{N_{2(g)} + 3H_2{(g)} \to 2NH_3{(g)} \ \ \ \Delta H = -92\ kJ}[/tex]    ---- (1)

The second step equation:

[tex]\mathsf{NH_{3(g)} + 2O_2{(g)} \to HNO_3{(g)} +H_2O_{(g)} \ \ \ \Delta H = -330\ kJ}[/tex]      ---- (2)

To determine the enthalpy of formation for 1 mole of HNO₃ (nitric acid), we have the following.

From the above equations; let multiply equation (1) by 1 and equation (2) by 2.

[tex]\mathsf{N_{2(g)} + 3H_2{(g)} \to 2NH_3{(g)} \ \ \ \Delta H = -92\ kJ}[/tex]     ---- (3)

[tex]\mathsf{2NH_{3(g)} + 4O_2{(g)} \to 2HNO_3{(g)} +2H_2O_{(g)} \ \ \ \Delta H = 2(-330)\ kJ}[/tex]      ----- (4)

adding the above two equations, we have:

[tex]\mathsf{N_{2(g)} + 3H_2{(g)}+ 2NH_{3(g)} + 4O_{2(g)} \to 2HNO_{3(g)} + 2NH_3{(g)} +2H_2O_{(g)} \ \ \ \Delta H = (-660 \ kJ -92\ kJ)}[/tex][tex]\mathsf{N_{2(g)} + 3H_2{(g)} + 4O_{2(g)} \to 2HNO_{3(g)} +2H_2O_{(g)} \ \ \ \Delta H = (-752 \ kJ)}[/tex]

Now, from the recent equation, we have:

2 moles of nitric acid = -752 kJ

1 mole of nitric acid will be: = (1 mole × (-752 kJ)) ÷ 2 moles

1 mole of nitric acid will be: = -376 kJ

If the balance were not tared prior to weighing out the KHP.... how would you expect this to affect the molarity of NaOH calculated? What type of error is this?

Answers

Answer:

Following are the response to the given question:

Explanation:

In the given scenario, When the balance has never been tainted before the KHP is weighted, which can affect the molar concentration of NaOH because its molarity is directly proportional to the weight including its substance. In this question it is the mistake is systemic because it may be corrected by modifying balancing parameters.

The sample concentration was measured at 50mg/ml. The loading concentration needs to be 10mg/ml. The final volume needs to be 25ul. What is the volume of sample needed and the amount of buffer needed to reach 25ul

Answers

Answer:

a)  [tex]V_1=5ul[/tex]

b)  [tex]v=20ul[/tex]

Explanation:

From the question we are told that:

initial Concentration [tex]C_1=50mg/ml[/tex]

Final Concentration [tex]C_2=10mg/ml[/tex]

Final volume needs [tex]V_2 =25ul[/tex]

Generally the equation for Volume is mathematically given by

[tex]C_1V_1=C_2V_2[/tex]

[tex]V_1=\frac{C_1V_1}{C_2}[/tex]

[tex]V_1=\frac{10*25}{50}[/tex]

[tex]V_1=5ul[/tex]

Therefore

The volume of buffer needed is

[tex]v=V_2-V_1\\\\v=25-5[/tex]

[tex]v=20ul[/tex]

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