The carbonyl carbon in a ketone is attacked primarily by the peroxy oxygen bonded to hydrogen as opposed to the peroxy oxygen bonded to carbon because:

Answers

Answer 1

Answer:

This is because peroxy oxygen bonded to hydrogen can easily undergo nucleophilic protonation with the carbonyl carbon to form an alcohol

Explanation:

A ketone is a functional group that contains a carbonyl group (carbon-oxygen double bond ( R1R2-C=O).

The carbonyl carbon doubly bonded to the oxygen is electron deficient as a result of difference in electronegativity between carbon and oxygen, hence is susceptible to nucleophilic attacks

R1R2 - C = O

where R1 and R2 are organic substituents.

The peroxy oxygen that is bonded to hydrogen (H -O-O-R) is the electron-rich centre and easily attacks electron-deficient centres like the carbonyl carbon in ketones to form an alcohol.

The bond between the hydrogen attached to the peroxy oxygen is broken and the resultant hydrogen ion undergoes protonation with the oxygen of the carbonyl group to form an alcohol

R1R2 - C = O + H - O-O - R =>

R1R2- CH - OH + R - O-O-R1


Related Questions

Please help :)
A chocolate chip cookie recipe calls for 0.050 moles of baking soda (NaHCO3). How many grams should the chef mass out?

Answers

Answer: 4.2 g

Explanation:

Note that the number of moles is equal to the actual given mass of the substance over its molar mass.

n = m/M, where n is the moles, m is the given mass, M is the molar mass.

In manipulating this formula, you get that the given mass is equal to the number of moles multiplied by the molar mass of substance.

m = n x M.

(Na = 23, H = 1, C = 12, O = 16)

Molar mass = 23 + 1 + 12 + (16x3)

= 84

1) m = 0.050 x 84
2) m = 4.2 g

Hope this helps, brainliest would be appreciated :)

According to the mole concept, 4.2 g of baking soda should be weighed out.

What is mole concept?

Mole is defined as the unit of amount of substance . It is the quantity measure of amount of substance of how many elementary particles are present in a given substance.

It is defined as exactly 6.022×10²³ elementary entities. The elementary entity can be a molecule, atom ion depending on the type of substance. Amount of elementary entities in a mole is called as Avogadro's number.

It is widely used in chemistry as a suitable way for expressing amounts of reactants and products.For the practical purposes, mass of one mole of compound in grams is approximately equal to mass of one molecule of compound measured in Daltons. Molar mass has units of gram per mole . In case of molecules, where molar mass  in grams present in one mole  of atoms is its atomic mass.

Baking soda has molar mass of 84 g /mole, thus mass is calculated using number of moles formula which is mass= molar mass×number of moles, which is mass=84×0.050=4.2 g.

Thus,4.2 g of baking soda should be weighed out by chef.

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Al wonders if adding salt to water will affect how long it takes the water to
freeze. Al thinks that salt water will freeze more quickly than fresh water.
He decides to check his hypothesis by conducting an experiment. Al takes
two ice trays and fills one with distilled water and the other with distilled
water that has two tablespoons of salt added. He makes sure he puts
exactly the same amount of water in each ice tray. Al takes the trays and
puts them side by side in the freezer. Al checks the ice trays every 10
minutes to see if the water in each tray has begun to freeze. Al finds that
after 20 minutes the water in the ice tray without the salt has started to
form ice, while the ice tray with the salt water is still completely liquid.
Ku

Answers

The hypothesis is that salt water freezes faster than fresh water.

The dependent variable is time taken for ice to appear.

The independent variable is presence or absence of salt

The constants are the amount of water in each tray, freezing conditions and length of time of exposure to freezing condition.

The control group is the tray to which salt was not added

The experimental group is the tray to which salt was added

The presence of solutes in a solution causes the freezing point depression.

A solution is made up of a solute and a solvent. In the presence of a solute, the freezing point of a pure solvent is decreased. This is because freezing point is a colligative property.

Colligative properties depend on the amount of solute present.

Hence, the pure water freezes faster (ice begin to appear earlier) than the salt water.

The hypothesis put forward in this experiment was found to be invalid by the experiment.

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Molar mass of C^6H^12O^6

Answers

Answer:

The molar mass of C6 H12 O6 is 180.15588 g/mol.

Explanation:

what is mean by measurement​

Answers

Answer:

Measurement is defined as the act of measuring or the size of something. An example of measurement means the use of a ruler to determine the length of a piece of paper. ... Extent, quality, or size as determined by measuring; dimension. A waist measurement of 32 inches.

Explanation:

The comparison o unknown quantity with known standard quantity is called measurement.

an atom with six protons and eight neutrons is a(n)___

a. isotope of nitrogen
b. standard carbon atom
c. isotope of carbon
d. isotope of oxygen

Answers

Answer:

standard carbon atom

Explanation:

Answer:

Explanation:

This is an isotope of carbon, more specifically, carbon-14. Carbon 14 has 6 protons, making the element carbon, and eight neutrons since 14-6 = 8.

The levels of carbon dioxide in the atmosphere a. began decreasing when the burning of fossil fuels increased. b. are estimated to be higher than at any time in the past 420,000 years. c. are high but not higher than the highest estimated levels in the last 420,000 years. d. peaked around 1950 and have begun slowly decreasing since then.

Answers

The levels of carbon dioxide in the atmosphere are estimated to be higher than at any time in the past 420,000 years. That is option B

Carbon dioxide is a very harmful compound which is easily released into the atmosphere through burning of fossil fuels and other carbon compounds in plenty of air.

The released carbon dioxide rises to the upper atmosphere and blocks the radiation of solar energy back into the space. This precipitates a global temperature increase called the greenhouse effect.

According to Intergovernmental Panel on Climate Change (IPCC) in a current research discovered that CO2 concentration in the earth’s atmosphere is higher than at any point during the last 650,000 years. They where able to study this through the study of higher levels of CO2 concentration which coincide with higher temperatures.

Therefore the correct option is B which states that the levels of carbon dioxde in the atmosphere are estimated to be higher than at any time in the past 420,000 years.

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prove thatp=dgh prove that P is equals to Dgh ​

Answers

Answer:

i hope it will help you

Explanation:

mark me as a brainlest answer

calculate molarity, molality and mole fraction of 28 percent aqueous solution of a solute with molar mass 11.5 g per mole and density is 1.25 g per mole

Answers

Explanation:

Aight, I'mma give tell ya an easy way for this question. look at this Forumla

M=

[tex] \frac{10ad}{m} [/tex]

a explains the percentage of aqueous solution

d is the density

m is the molar mass

right, let's just hop to it

M=10×28×1.25/11.5====> M=30.43

Which state of matter has particles that vibrate and can change place but remain touching in a random arrangement.
A. Liquid
B. None of these
C. Plasma
D. Gas

Answers

The particles in the solid are touching with very little space between them. The particles in a liquid usually are still touching but there are some spaces between them. The gas particles have big distances between them.

...

Liquids Solids and Gases:

NON OF THESE

what is mean by vector​

Answers

Answer:

A quantity having direction as well as magnitude is called vector.

Which coefficient of O2 is needed to balance the equation C3H8 + O2 → 3CO2 + 4H2O?
A.
2
B.
3
C.
5
D.
6

Answers

The answer is C. 5

Hope I helped

I have no idea how to do this and need help

Answers

Answer:

60.55%

Explanation:

nO3=155/48

nO2 used: 3/2nO3=4.84375

percent yield: 4.84375/8=60.55%

muddy water is an example of ______mixtures​

Answers

Answer:

suspensions of heterogeneous mixtures from which some of particles settle with time.

Answer:

Muddy water is an example of homogeneous mixture.

What information does the specific heat capacity give about a substance?
A. How much energy is needed to raise its temperature
B. How much heat is released when it changes phases
C. How much energy is needed to overcome an activation energy
O
0
D. How much heat is stored in its chemical bonds

Answers

Specific heat capacity tells about how  much energy is needed to raise its temperature.

What is specific heat capacity?

Specific heat capacity is defined as the amount of energy required to raise the temperature of one gram of substance by one degree Celsius. It has units of calories or joules per gram per degree Celsius.

It varies with temperature and is different for each state of matter. Water in the liquid form has the highest specific heat capacity among all common substances .Specific heat capacity of a substance is infinite as it undergoes phase transition ,it is highest for gases and can rise if the gas is allowed to expand.

It is given by the formula ,

Q=mcΔT

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In the compound Ni2O3, nickel's oxidation number is_____
oxidation number is -2.
and oxygen's

Answers

Answer:

+3

Explanation:

The name of this compound would be nickel (III) oxide. Oxygen typically has a charge of -2. Given there are 3 oxygen atoms, that would equal a charge of -6. The nickel is the cation and must equal the charge of the anion, so must have a charge of +6. Since there are 2 nickel atoms, the charge on each must be +3.

18. If the pH of a strong acid solution is known to be 3.25, what is the [H+)?
(b) what is the pOH of this solution?

Answers

[H+] is 5.623*10^-4
2.poH is 10.75

process of heat treatment and it's meaning

Answers

Answer:

Heat treatment is the process of heating metal without letting it reach its molten, or melting, stage, and then cooling the metal in a controlled way to select desired mechanical properties. Heat treatment is used to either make metal stronger or more malleable, more resistant to abrasion or more ductile.

Elements in the same period Question 7 options: A) form bonds with the same type of elements. B) have the same number of protons. C) have the same number of valence electrons. D) have the same principal quantum number.

Answers

D is the answer .. I have send u pic also

The compound KOH is ________. insoluble, because all compounds containing K are insoluble insoluble, because all compounds containing OH- are in soluble soluble, because all compounds containing K are soluble soluble, because all compounds containing OH- are soluble insoluble, because KOH is insoluble

Answers

Answer:

soluble because all compounds containing K are soluble

Explanation:

Most metal hydroxides are insoluble. However, alkali metal hydroxides (such as KOH and NaOH) are very soluble.

In the case of KOH, the K cation is attracted to the electronegative oxygen on water. The OH anion is capable of hydrogen bonding to the water. (Notice how OH⁻ is simply the deprotonated form of water.)

The compound KOH is soluble insoluble, because all compounds containing K are insoluble insoluble, because all compounds containing OH- are in soluble soluble, because all compounds containing K are soluble soluble, because all compounds containing OH- are soluble insoluble, because KOH is insoluble

What are alkalis?

Alkalis are bases which are soluble in water. The basic alkalis are as follows:

KOHNaOHCa(OH)2

Mg(OH)2 is insoluble in water.

In conclusion, KOH is a soluble base

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HELLPP ASAP, FIRST PERSON WITH THE CORRECT ANSWER WILL RECEIVE BRAINLIEST

How are the number of valence electrons and the types of ions related?

Answers

Answer:

"The number of electrons in an atom's outermost valence shell governs its bonding behaviour."

Explanation:

Credits to:

https://socratic.org/questions/how-do-valence-electrons-affect-chemical-bonding

Make sure to put in your own words

Hopefully this helps

Answer:

The number of electrons in an atom's outermost valence shell governs its bonding behaviour. ... They need to lose only one or two valence electrons to form positive ions with an s²p⁶ configuration. NONMETALS. Nonmetals tend to attract additional valence electrons to form either ionic or covalent bonds.

How does a balanced chemical equation represent the conservation of
matter in a chemical reaction?
1. There are more atoms in the reactants than in the products.
2. The type of matter in the products is different from the type of matter in
the reactants.
3. The number of atoms of each element in the reactants equals the number
of atoms of each element in the products.
4. There are fewer atoms in the reactants than in the products

Answers

Answer:

The correct answer would be 3. The number of atoms of each element in the reactants equals the number of atoms of each element in the products.

Explanation:

The law of conservation of matter states that energy cannot be created or destroyed, only transfered. Thus, option 3 is correct.

Josefina and Raul were comparing how sound moves through various mediums and how charge moves through conducting wires. They performed experiments to find out if the factors that determine the speed of sound are the same as those that determine the flow in a circuit. What did they find? Describe two things that they found. For each, explain how the speed of sound and flow of current are affected

Answers

They found that difference occurs in the speed of both sound and charges occur due to the difference in the type of medium.

Sound and charges needs specific medium for faster movement i.e. sound moves faster in solid as compared to liquid and gas whereas charges moves faster and easily in gold due to lower resistance which is followed by copper. Sound can move from solid, liquid and gases whereas charges move only in solid metal in which free electrons are present. The speed of sound and flow of current are affected due to difference in the arrangement of atoms in solid, liquid and gas.

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Which type of bonds can carbon atoms form with other carbon atoms? (1 point)
O double, triple, and quadruple bonds
O single and double bonds
O double and triple bonds
O single, double, and triple bonds

Answers

Answer:

single, double, and triple bonds

Cuales son los tipos de yemas

Answers

Tipos de yemas son terminal, cuando está ubicada en la punta de una ramilla;
axilar, cuando está ubicada en la axila de una hoja (también denominadas laterales);
adventicia, cuando ocurre en los demás lugares, por ejemplo en el tronco o en las raíces.

career in chemistry list ten

Answers

Answer:

Analytical Chemist

Forensics

Toxicologist

Biochemist

Chemical Engineer

Laboratory Technician

Pharmacologist

Chemical Technician

Materials Scientist

Environmental Chemist

Research scientist
Chemical engineer
Toxicologist
Analytical chemist
Chemistry teacher
Forensic scientist
Hazardous waste chemist
Water chemist
Geochemist
Pharmacologist

How does the chemistry of the ocean change in response to high levels of CO2 in the atmosphere?

Answers

Ocean acidification is occurring because excess carbon dioxide (CO2) in the atmosphere is being absorbed at the surface of the ocean at an increasing rate. This excess CO2 results in more hydrogen ions, which increases the acidity of the ocean.

what is electrolysis ​

Answers

Answer:

Electrolysis is commercially important as a stage in the separation of elements from naturally occurring sources such as ores using an electrolytic cell

please solve this question

Answers

Answer:

b) it gets accumulated in the respiratory system which then halts or slows down the supply of oxygen to the brain hence leading to death

best way to separate a solid from a liquid what separation technique is needed​

Answers

Filtration is a method for separating an insoluble solid from a liquid.

Answer:

Filtiration technique

Explanation:

An atom has mass number 23 and atomic number 11.
a) How many electrons are revolving around the nucleus?
b) How many electron shells are there in the atom?

Answers

A): The closest orbital to the nucleus, called the 1s orbital, can hold up to two electrons. This orbital is equivalent to the innermost electron shell of the Bohr model of the atom. It is called the 1s orbital because it is spherical around the nucleus. The 1s orbital is always filled before any other orbital.

Given:
- Mass number of atom = 23
- Atomic number of atom = 11

As, the number of electrons in an atom is equal to an atomic number of the element.

So, number of electrons = 11

Secondly , number of protons are equal to number of electrons.

So, number of protons = 11

And number of neutrons = mass number - atomic number = 23−11 = 12

So, number of neutrons = 12

Thus , the atom contains 11 protons, 11 electrons, 12 neutrons.
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