Answer:
[tex]Q\approx6.4~kJ[/tex]
Explanation:
Quantity of heat required by 10 gram of ice initially warm it from -5°C to 0°C:
[tex]Q_1=m.C_s.\Delta T[/tex]
here;
mass, m = 10 g
specific heat capacity of ice, [tex]C_s=2.09~J.g^{-1}.^{\circ}C^{-1}[/tex]
change in temperature, [tex]\Delta T=(5-0)=5^{o}C[/tex]
[tex]Q_1=10\times2.09\times 5[/tex]
[tex]Q_1=104.5~J[/tex]
Amount of heat required to melt the ice at 0°C:
[tex]Q_2=m.\Delta H_{fus}[/tex]
where, [tex]\Delta H_{fus}=6020~J/mol[/tex]
we know that no. of moles is = (wt. in gram) [tex]\div[/tex] (molecular mass)
[tex]Q_2=\frac{10}{18} \times 6020[/tex]
[tex]Q_2=3344.44~J[/tex]
Now, the heat required to bring the water to 70°C from 0°C:
[tex]Q_3=m.C_L.\Delta T[/tex]
specific heat of water, [tex]C_L=4.18~J/g/^oC[/tex]
change in temperature, [tex]\Delta T=(70-0)=70^oC[/tex]
[tex]Q_3=10\times 4.18\times 70[/tex]
[tex]Q_3=2926~J[/tex]
Therefore the total heat required to warm 10.0 grams of ice at -5.0°C to a temperature of 70.0°C:
[tex]Q=Q_1+Q_2+Q_3[/tex]
[tex]Q=104.5+3344.44+2926[/tex]
[tex]Q=6374.94~J[/tex]
[tex]Q\approx6.4~kJ[/tex]
The idea that the behavior of the states of matter is determined by the kinetic energy and movement of their particles is called _____…
A. Sublimation Theory
B. Kinetic Movement Theory
C. Kinetic Molecular Theory
D. Van der Waals Theory
Answer:
C . Kinetic Molecular Theory
0. When measuring tert-butyl alcohol for this experiment, a student first weighs an empty graduated cylinder, then pours 15 mL of the alcohol into the graduated cylinder and weighs the cylinder again. He records the amount of alcohol used as the difference in these two masses. What is wrong with this method
Answer:
Both have solutions in the graduated cylinder.
Explanation:
Recording the amount of alcohol used as the difference between two masses is the wrong method used for measuring tert-butyl alcohol for the experiment. For measuring tert-butyl alcohol for this experiment, the student has to measure the two masses when both the graduated cylinders has solution of tert-butyl alcohol not when one of it is empty (having no tert-butyl alcohol ).
The wrong aspect is that the liquid didn't need to be weighed. Instead the volume should have been recorded with the aid of the graduated cylinder.
What is a Graduated cylinder?This is a cylinder with marked readings and is used to measure the volume of liquids in the laboratory.
The graduated cylinder will accurately measure the amount of alcohol used due to it being volatile and the mass fluctuating during the measurement.
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A mixture of methane and carbon dioxide gases contains methane at a partial pressure of 431 mm Hg and carbon dioxide at a
partial pressure of 504 mm Hg. What is the mole fraction of each gas in the mixture?
XCHA
Xc02
Answer:
XCH₄ = 0.461
XCO₂ = 0.539
Explanation:
Step 1: Given data
Partial pressure of methane (pCH₄): 431 mmHgPartial pressure of carbon dioxide (pCO₂): 504 mmHgStep 2: Calculate the total pressure in the container
We will sum both partial pressures.
P = pCH₄ + pCO₂
P = 431 mmHg + 504 mmHg = 935 mmHg
Step 3: Calculate the mole fraction of each gas
We will use the following expression.
Xi = pi / P
XCH₄ = pCH₄/P = 431 mmHg/935 mmHg = 0.461
XCO₂ = pCO₂/P = 504 mmHg/935 mmHg = 0.539
A metal (C = 0.2158 cal/g· °C) is removed from a hot (350. °F) oven in which it had achieved thermal equilibrium. The metal is placed into 200. mL acetic acid. The temperature of the acid increases to 90.3 °C from 24.3 °C. What is the mass of the metal? (dacetic acid = 1.04 g/cm3; Cs, acetic acid = 2.055 J/g·°C) Group of answer choices 120. g 362 g 1452 g 347 g 281 g
Answer:
362g
Explanation:
heat lost by metal= heat gained by acetic acid
tfs are the same so you cando delta T
convert Cal/gc to J/gc
thectgod ig follow
why does D2O
have a higher boiling point than H2O
Answer:
deuterium is heavier isotope of hydrogen need
high weight of atom will lead to higher boiling point
Deduce the formula of calcium Phosphide.
Answer:
[tex]{ \sf{Ca _{3} P_{2} }}[/tex]
How are radioactive isotopes used to diagnose thyroid problems?
Answers
A.
Production of radioactive iodine by the thyroid is measured.
B.
Uptake of radioactive iodine by the thyroid gland is measured.
C.
Destruction of damaged cells by radioisotopes is measured.
D.
Absorption of gamma rays from ingested radioisotopes is measured.
Question
Answer:
A
Explanation:
uptakw of raduoactive iofine by the thyroid gland js measurd
what is the complete ionic equation between the reaction of sodium carbonate and calcium hydroxide to form a precipitate
Answer:
CaCl2(aq) + Na2CO3(aq) → CaCO3(s) + 2NaCl(aq)
Reference:
H.W. Hanna and A. Dittmar; Laboratory Manual for General Chemistry, 4th ed.; Morton Publishing Company, Denver, Colorado
Calculate the percent error in the atomic weight if the mass of a Zn electrode increased by 0.3681g and 6.514x10-3 moles of Zn was produced. You may assume the molar mass of elemental zinc is 65.38 g/mol.
a. -13.5%
b. 13.52%
c. -13.52%
d. 13.5%
Answer:
13.5%
Explanation:
To answer this you need to understand that percentage error can never be negative as we use absolute value in the equation
To get molar/atomic mass = mass/moles
=0.3681g/(6.514×10^-3)moles
=56.509g/moles
percentage error = (65.38-56.509)/65.38 ×100
=13.56% (this is what I'm getting without rounding off your question wasn't specific on how many d.p to use)
Which of the following is a reduction half-reaction?
Solution : An oxidation reduction (redox) reaction is a type of chemical reaction that involves a transfer of electrons between tow species an oxidaion reductin reaction is any chemical reaction in which the oxidation number of a molecule atom or ion changes by gaining or losing an electron
Select all that are true for both a voltaic cell and an electrolytic cell. Group of answer choices There must be a complete circuit to allow electrons to flow. The redox reaction is spontaneous. Oxidation happens at the anode. Reduction happens at the cathode. The redox reaction is non-spontaneous. g
Answer:
There must be a complete circuit to allow electrons to flow. Oxidation happens at the anode. Reduction happens at the cathode.
Explanation:
Select all that are true for both a voltaic cell and an electrolytic cell.
There must be a complete circuit to allow electrons to flow. YES. This is true for both cells.
The redox reaction is spontaneous. NO. This is only true for the voltaic cell.
Oxidation happens at the anode. YES. This is true for both cells.
Reduction happens at the cathode. YES. This is true for both cells.
The redox reaction is non-spontaneous. NO. This is only true for the electrolytic cell.
The statements that have been true for both voltaic and electrolytic cells are:
Option A: There must be a complete circuit to allow electrons to flow.
Option C: Oxidation happens at the anode.
Option D: Reduction happens at the cathode.
The electrolytic cells are the one that converts electrical energy into chemical energy. Voltaic cells convert chemical energy into electrical energy.
From the given options, the best-suited option for both electrolytic and voltaic cells are:
For any of the cells to perform the current flow, the circuit must be complete. Option A stating that there must be a complete circuit to allow electrons to flow is correct.The redox reaction has been a spontaneous reaction and results in the chemical conversion to form energy. Since the chemical energy has been converted into electrical energy, statement B has been true for only Voltic cells. Thus option B is incorrect.Oxidation is the reaction to the loss of electrons. In both cells, oxidation happens at the anode. Thus, option C is correct.Since oxidation takes place at anode, cathode acts as the reduction end in both the cells. Thus option D is correct.The redox reaction has been non-spontaneous only in the electrolytic cell. Thus option E is incorrect.The statements that have been true for both voltaic and electrolytic cells are, Option A, C, and D.
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Which of the following chemical equations depicts a balanced ionic equation?
A. 2OH−+Ca2+−>Ca(OH)2
B. OH−+Ca2+−>Ca(OH)2
C. 2OH−+Ca2+−>2Ca(OH)2
D. OH−+2Ca2+−>Ca(OH)2
Answer:
[tex]{ \sf{A. \: 2OH {}^{ - } _{(aq)} +Ca {}^{2 + } _{(aq)} −>Ca(OH) _{2(s)} }}[/tex]
The chemical equations depict a balanced ionic equation is 2OH−+Ca2+−>Ca(OH)2. option A is correct.
What is the ionic equation?
An ionic equation is a chemical equation in which the electrolytes in an aqueous solution are expressed as dissociated ions. The ions in aqueous solutions are stabilized by ion-dipole interactions with water molecules
Strong acids, strong bases, and soluble ionic compounds (usual salts) exist as dissociated ions in an aqueous solution, and Weak acids and bases and insoluble salts are usually written using their molecular formulas because only a small amount of them dissociates into ions.
Ag+(aq) + NO3-(aq) + Na+(aq) + Cl-(aq) → AgCl(s) + Na+(aq) + NO3-(aq) is an ionic equation example.
Therefore, the balanced ionic reaction will be 2OH−+Ca2+−>Ca(OH)2. option A is correct.
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Given the equation: 2C6H10(l) 17 O2(g) ---> 12 CO2(g) 10 H2O(g) MM( g/mol): 82 32 44 18 If 115 g of C6H10 reacts with 199 g of O2 and 49 g of H2O are formed, what is the percent yield of the reaction
Answer:
74%
Explanation:
Step 1: Write the balanced equation
2 C₆H₁₀(l) + 17 O₂(g) ⇒ 12 CO₂(g) + 10 H₂O(g)
Step 2: Determine the limiting reactant
The theoretical mass ratio (TMR) of C₆H₁₀ to O₂ is 164:544 = 0.301:1.
The experimental mass ratio (EMR) of C₆H₁₀ to O₂ is 115:199 = 0.578:1.
Since EMR > TMR, the limiting reactant is O₂.
Step 3: Calculate the theoretical yield of H₂O
The theoretical mass ratio of O₂ to H₂O 544:180.
199 g O₂ × 180 g H₂O/544 g O₂ = 65.8 g H₂O
Step 4: Calculate the percent yield of H₂O
%yield = (experimental yield/theoretical yield) × 100%
%yield = (49 g/65.8 g) × 100% = 74%
Answer:
Percentage yield of H₂O = 74.24%
Explanation:
The balanced equation for the reaction is given below:
2C₆H₁₀ + 17O₂ —> 12CO₂ + 10H₂O
Next, we shall determine the masses of C₆H₁₀ and O₂ that reacted and the mass of H₂O produced from the balanced equation. This is can be obtained as follow:
Molar mass of C₆H₁₀ = 82 g/mol
Mass of C₆H₁₀ from the balanced equation = 2 × 82 = 164 g
Molar mass of O₂ = 32 g/mol
Mass of O₂ from the balanced equation = 17 × 32 = 544 g
Molar mass of H₂O = 18 g/mol
Mass of H₂O from the balanced equation = 10 × 18 = 180 g
SUMMARY:
From the balanced equation above,
164 g of C₆H₁₀ reacted with 544 g of O₂ to produce 180 g of H₂O.
Next, we shall determine the limiting reactant. This can be obtained as follow:
From the balanced equation above,
164 g of C₆H₁₀ reacted with 544 g of O₂.
Therefore, 115 g of C₆H₁₀ will react to produce = (115 × 544)/164 = 381 g of O₂.
From the calculations made above, we can see that a higher mass (i.e 381 g) of O₂ than what was given (i.e 199 g) is needed to react with 115 g of C₆H₁₀.
Therefore, O₂ is the limiting reactant and C₆H₁₀ is the excess reactant.
Next, we shall determine the theoretical yield of H₂O. This can be obtained by using the limiting reactant as shown below:
From the balanced equation above,
544 g of O₂ reacted to produce 180 g of H₂O.
Therefore, 199 g of O₂ will react to produce = (199 × 180)/544 = 66 g of H₂O.
Thus, the theoretical yield of H₂O is 66 g.
Finally, we shall determine the percentage yield. This can be obtained as follow:
Actual yield of H₂O = 49 g
Theoretical yield of H₂O = 66 g
Percentage yield of H₂O =?
Percentage yield = Actual yield /Theoretical yield × 100
Percentage yield of H₂O = 49/66 × 100
Percentage yield of H₂O = 74.24%
Which chemical can remove color of red/Pink phenol and make it clear like water transparent?
How many grams of Al were reacted with excess HCl if 3.86 L of hydrogen gas were collected at STP in the following reaction?
2 Al (s) + 6 HCl (aq) → 2 AlCl₃ (aq) + 3 H₂ (g)
The amount, in grams, of Al that reacted with excess HCl if 3.86 L of hydrogen gas were collected at STP in the reaction would be 3.099 grams.
Stoichiometric problemFrom the equation of the reaction, the mole ratio of Al that reacts with that of hydrogen gas that forms is 2:3.
At STP, 1 mole of any gas is equivalent to 22.4 Liters of the gas.
But only 3.86 L of hydrogen was formed in the reaction.
The equivalent mole of 3.86 L hydrogen at STP would be:
3.86 x 1/22.4 = 0.1723 moles
From the mole ratio, the equivalent mole of Al that will produce 0.1723 moles of hydrogen gas would be:
0.1723 x 2/3 = 0.1149 moles
Recall that: mass = mole x molar mass
Mass of 0.1149 moles Al = 0.1149 x 26.98
= 3.099 grams
Thus, the amount of Al that reacted with excess HCl is 3.099 grams.
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An alkane can show structural isomerism if it has at least ______ carbon atom
1)1
2)2
3)3
4)4
Spam = report and kick u
Answer:
2) 3 carbons
Explanation:
The alkane with one carbon is methane but it has no isomer.
The alkanes starting with propane only have isomers
Explanation:
An alkane can show structural isomerism if it has at least __4__ carbon atom
Arrange the following in order of increasing melting point: NaCl, H2O, CH4, C6H4(OH)2.
a. NaCl < H2O < CH4 < C6H4(OH)2
b. CH4 < H2O < NaCl < C6H4(OH)2
c. CH4 < H2O < C6H4(OH)2 < NaCl
d. CH4 < C6H4(OH)2 < H2O < NaCl
e. CH4 < NaCl < C6H4(OH)2 < H2O
Explanation:
one thing to know is that higher surface area = higher boiling point.
NaCl has the smallest surface area, so it's the first one.
H2O has less surface area than methane, so it's second.
Methane has more surface area than H20, so it's third.
The big molecule has the most surface area, so it's last
Temperature measures the average kinetic energy of particles of the substances. Melting point is directly proportional to surface area. Therefore, the correct option is option C.
What is temperature?Temperature is used to measure degree or intensity of heat of a particular substance. Temperature is measured by an instrument called thermometer.
Temperature can be measured in degree Celsius °c, Kelvin k or in Fahrenheit. Temperature is a physical quantity. Heat always flow from higher temperature source to lower temperature source.
We can convert these units of temperature into one another. The relationship between degree Celsius and Fahrenheit can be expressed as:
°C={5(°F-32)}÷9
Melting point is directly proportional to surface area. NaCl has the smallest surface area. Water has less surface area than methane. Methane has more surface area than H[tex]_2[/tex]O.
Therefore, the correct option is option C.
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Help ASAP 15 Points
A student is conducting their science experiment on the effect of caffeine on dogs. He has 3 groups of test subjects. The 1st group of dogs receives plain water. The 2nd group of dogs receives 10 mg of caffeine each, and the 3rd group receives 50 mg of caffeine each. He will measure their activity levels by recording how long each dog runs without stopping, after giving them the pills. What could be evaluated in this experiment to ensure reliability?
A. The different amounts of caffeine given could lead to different activity levels which would throw off the result of the experiment.
B. The group that receives water will be an outlier and throw off the best fit line.
C. The test subjects are dogs and not people, so their data is unreliable.
D. If the dogs are different breeds, their activity levels could be different because of their breed and not the caffeine. Reset Selection
Answer:
The independent variable of an experiment is the one that is intentionally changed or manipulated to see the results of changing said variable.
We are told that in each different group, the amount of caffeine that is given to the dog's changes - in the control group, they get no caffeine, in the 2nd group, they get 10 mg of caffeine each, and in the 3rd group, they get 50 mg of caffeine each.
Therefore, since the amount of caffeine that is given to the dogs is the only variable that is being manipulated, this is the independent variable.
Answer: The independent variable of an experiment is the one that is intentionally changed or manipulated to see the results of changing said variable.
The independent variable of an experiment is the one that is intentionally changed or manipulated to see the results of changing said variable.
We are told that in each different group, the amount of caffeine that is given to the dog's changes - in the control group, they get no caffeine, in the 2nd group, they get 10 mg of caffeine each, and in the 3rd group, they get 50 mg of caffeine each.
Therefore, since the amount of caffeine that is given to the dogs is the only variable that is being manipulated, this is the independent variable.
We are told that in each different group, the amount of caffeine that is given to the dog's changes - in the control group, they get no caffeine, in the 2nd group, they get 10 mg of caffeine each, and in the 3rd group, they get 50 mg of caffeine each.
Therefore, since the amount of caffeine that is given to the dogs is the only variable that is being manipulated, this is the independent variable.
Explanation:
How many nitrate ions are present in the following aqueous solution?
5.08 L of a solution containing 2.68 x 1021 formula units of lithium nitrate per liter.
When you have the number, determine its log (base 10) and enter that value with 3 decimal places
Answer:
22.1
Explanation:
Step 1: Calculate the number of formula units of lithium nitrate
A 5.08 L solution contains 2.68 × 10²¹ formula units per liter.
5.08 L × 2.68 × 10²¹ formula units/1 L = 1.36 × 10²² formula units
Step 2: Calculate the number of nitrate ions
Lithium nitrate dissociates completely in water according to the following equation.
LiNO₃(aq) ⇒ Li⁺(aq) + NO₃⁻(aq)
The molar ratio of LiNO₃ to NO₃⁻ is 1:1. The number of nitrate ions is 1/1 × 1.36 × 10²² = 1.36 × 10²².
Then,
log (1.36 × 10²²) = 22.1
The number of nitrate ions are present in the following aqueous solution is 13.6x10²¹, and log(base 10) value of this is 22.2.
What are strong electrolytes?
Those salts which are completely dissociate into their ions in the solution form will known as strong electrolyte.
Lithium nitrate is a strong electrolyte and it shows complete dissociation as:
LiNO₃ → Li⁺ + NO₃⁻
Given that,
1 liter of solution containing = 2.68 x 10²¹ formula unit
5.08 L of solution containing = 5.08 x 2.68 x 10²¹ = 13.6x10²¹ formula unit
So, number of nitrate ion in given solution = 13.6x10²¹ formula unit
Log(13.6x10²¹) = 22.1
Hence, required values are 13.6x10²¹ and 22.1.
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Why benzene is called aromatic compound according to Huckel’s rule?
Answer:
It obeys rule
Explanation:
Benzene is an aromatic hydrocarbon because it obeys Hückel's rule.
Answer:
Benzene is an aromatic compound because it is planar, cyclic, conjugated and has (4n +2) π electrons, where n= 1.
Explanation:
Hückel's rule states that a molecule is aromatic if it is planar, cyclic, conjugated and has (4n +2) π electrons.
Breaking it down into 4 requirements, we have:
planarcyclicconjugated(4n +2) π electronsLet's look at each of the 4 parts!
What is planar?
Planar refers to the molecule being flat. When an atom is sp² hybridized, it is in a trigonal planar geometry. Let's look at the benzene molecule. Each carbon is attached to 3 other atoms, namely 2 carbons and 1 hydrogen. This means that each carbon is sp² hybridized, making the molecule planar.
Cyclic
This refers to the molecule having a closed ring shape. Benzene fulfils this criteria.
Conjugation
This refers to a system of connected p orbitals, which allows π electrons to delocalize. Each carbon atom in benzene has one 2p orbital, making benzene a conjugated molecule. For molecules that are not cations or anions, conjugated molecules are those that have alternating single and double bonds.
(4n +2) π electrons
n is an integer (e.g. 0, 1, 2, 3) thus for the molecule to be aromatic, it can have 2, 6 or 10 π electrons (non exhaustive). This separates an aromatic compound from an antiaromatic compound, which has 4n π electrons instead.
Benzene has 6 π electrons, so n has a value of 1 in this case.
Thus, benzene is an aromatic compound because it is planar, cyclic, conjugated and has (4n +2) π electrons.
_______
Counting the number of π electrons
Let's look at π bonds!
A double bond is made up of 1 σ bond and 1 π bond, and each π bond is made up of 2 π electrons. We do not count the number of single bonds since single bonds are made up of 1 σ bond only.
There are 3 double bonds in the Kekulé structure of benzene. Thus, the number of π electrons in benzene is 3(2)= 6.
Attached diagrams
Kekulé structure of benzenesp² hybridized carbon6 p orbitals in benzene ringGive 3 examples of chemical change and physical change in daily life
Explanation:
Physical change
★ Boiling of water
❤︎ freezing of water
❣︎ washing of clothes
♫︎ mixing black and brown stones
Chemical change
➪ making of dough
㋛︎ burning of wood
❥︎ cooking of the raw food
❁ burning of paper
ꨄ︎ rusting of iron
★★★➪➪➪➪ it was help to you
What happens to the electropositive character of elements on moving from left to right along a period in a periodic table?
Answer:
On moving from left to right in a period the electropositive character decreases as the tendency to lose electrons decreases.
Explanation:
Prepare a flow sheet for the preparation of triphenylmethanol. Using your knowledge of the physical properties of the solvents, reactants, and products, show how the products can be purified. Indicate which layer should contain the product in the liquid/liquid extraction steps.
Answer:
See explanation and Image attached
Explanation:
The preparation of triphenylmethanol occurs as shown in the image attached to this answer.
The first step is the nucleophillic reaction of the phenyl magnesium bromide with the carbonyl group.
Reaction of the second molecule of phenyl magnesium bromide with the product yields triphenyl methoxide ion. Reaction with acid yields the triphenylmethanol product which is extracted into the organic phase.
The triphenylmethanol product can be purified by recrystallization.
Determine the rate of reaction based on the data below:
75-
rate of reaction = y
hydrogen produced (cm)
х
y
25
50
75
100
125
time (seconds)
Answer:
75
Explanation:
is the answer for your question
A strawberry nutritional drink used for a liquid diet is flavored with methyl butanoate. Draw the structure of methyl butanoate.
Answer:
See explanation and image attached
Explanation:
Methyl butanoate is an ester. Esters have the general molecular formula, RCOOR where the two Rs may represent the same or different alkyl groups.
Methyl butanoate is has a fruity odor, smelling like apples or pineapples fragrance. It is also called methyl butyrate.
The structure of the compound is shown in the image attached to this answer.
Which processes occur during the second stage of technological design? Check all that apply.
designing a solution
studying relevant information
rebuilding and retesting
reporting a solution
defining criteria of success
identifying a problem
building a prototype
When 1 mole of CO(g) reacts with H2O(l) to form CO2(g) and H2(g) according to the following equation, 2.80 kJ of energy are absorbed. CO(g) + H2O(l)CO2(g) + H2(g) Is this reaction endothermic or exothermic? _________ What is the value of q? kJ
explain chlorination of methane
Answer:
Methane and chlorine
If a mixture of methane and chlorine is exposed to a flame, it explodes - producing carbon and hydrogen chloride. This is not a very useful reaction! The reaction we are going to explore is a more gentle one between methane and chlorine in the presence of ultraviolet light - typically sunlight. This is a good example of a photochemical reaction - a reaction brought about by light.
CH4+Cl2+energy→CH3Cl+HCl(3.4.2)
The organic product is chloromethane. One of the hydrogen atoms in the methane has been replaced by a chlorine atom, so this is a substitution reaction. However, the reaction doesn't stop there, and all the hydrogens in the methane can in turn be replaced by chlorine atoms.
Substitution reactions happen in which hydrogen atoms in the methane are replaced one at a time by chlorine atoms. You end up with a mixture of chloromethane, dichloromethane, trichloromethane and tetrachloromethane.
I hope this help you!:)
Explanation:
why is it difficult to undergo nucleophilic substitution in haloarene?
Answer:
In Haloarenes the C atom to which the X group is attached is SP2 hybridized thus it is become difficult to replace it by the Nucleophile. Since arenes and Vinyl halides are electron rich molecules due to presenceof n bonds, they repel Nucleophile attacking them.
Question:-
Why it is difficult for haloarenes to undergo nucleoplhilic subsituⁿ reaction?
Answer:-
Haloarenes are less reactive towards the nucleoplhilic substitution rxⁿ . This is due to following reasons :-
[tex]\red{\bigstar}\underline{\textsf{ Reason 1 :- Partial double bond character .}}[/tex]
Halogen atom has one lone pair, and due to presence of π - σ - lp , resonance is established in the compound ( see attachment) . Due to resonance there is a partial double bond character in the carbon halogen bond , so it is difficult to break a double bond than a single bond.
[tex]\rule{200}2[/tex]
[tex]\red{\bigstar}\underline{\textsf{ Reason 2 :- $\pi$ cloud .}}[/tex]
When a nucleoplhile comes to attack , it is repelled by the π-cloud of the benzene ring.
[tex]\rule{200}2[/tex]
[tex]\red{\bigstar}\underline{\textsf{ Reason 3 :- Phenyl cation .}}[/tex]
If somehow the halogen atoms leaves the benzene ring ,being more electronegative than carbon , it takes away the electron , thus a positive charge is left on benzene ring and the phenyl cation so formed is very unstable .
[tex]\rule{200}2[/tex]
Complete (predict the products, write correct formulas) and balance the following reaction:
Gaseous hydrochloric acid reacts with solid calcium hydroxide. Include states of matter and use subscripts as needed to receive full credit for a correct answer.
Explanation:
since hydrochloric acid is an acid and calcium hydroxide is a base, we know that this is an acid base reaction. The ions will then dissociatiate and bond with one another.
