Answer:
Explanation:
maleic acid ⇒ fumaric acid
ΔHreaction = ΔHproduct - ΔHreactant
ΔHproduct = -1336.0 kJ mol⁻¹
ΔHreactant = - 1359.2 kJ mol⁻¹.
ΔHreaction = -1336.0 kJ mol⁻¹ - ( - 1359.2 kJ mol⁻¹.)
= 1359.2 kJ mol⁻¹ -1336.0 kJ mol⁻¹
= 23.2 kJ mol⁻¹ .
Enthalpy of isomerization from maleic to fumaric acid is 23.2 kJ per mol.
Which does not result in deviations from linearity in a Beer's law plot of absorbance versus concentration?a. light losses at the cell interface b. all are sources of nonlinearity c. stray radiation d. equilibrium between different forms of the analyte e. a wide bandwidth relative to the width of the absorption band
Answer:
a
Explanation:
Beer-Lambert Law shows the relationship between the factors affecting the absorbance of a sample in relation to the concentration. These factors are:
the concentration c, path length (l), and the molar absorptivity (ε).
As a result, more radiation is assimilated as the concentration rises, and the absorbance rises as well. However, the longer the path length, the increase in the number of molecules and the higher the absorbance.
Thus, the straight-line equation for Beer-Lambert's law is:
A = εcl
From the above explanation, the option that doesn't relate to the deviations from linearity of Beer's law plot is in Option (a).
How many atom in protons
Answer:
Its atomic number is 14 and its atomic mass is 28. The most common isotope of uranium has 92 protons and 146 neutrons. Its atomic number is 92 and its atomic mass is 238 (92 + 146).
You will observe a weak acid-strong base titration in this experiment. Select all statements that are true about weak acid-strong base titrations.
A. Weak acid-strong base titrations always start at a higher pH than strong acid-strong base titrations, no matter the initial concentration.
B. The pH is less than 7 at the equivalence point.
C. The pH is greater than 7 at the equivalence point.
D. Half way to the equivalence point, a buffer region is observed.
Answer:
The pH is greater than 7 at the equivalence point.
Explanation:
Equivalence point is the point where the acid reacts with the base as stipulated in the equation of the reaction.
When a weak acid and a strong base are titrated, the pH of the solution at equivalence point is actually found to be around about pH ~ 9.
Hence, for a weak acid and strong base titration, The pH is greater than 7 at the equivalence point.
A titration between a weak acid and a strong base yields a solution whose pH is greater than 7 at the equivalence point.
What are weak acids?Weak acids are acids which only ionize partially in aqueous solutions.
When weak acids are dissolved in water, they produce only few hydrogen ions.
A strong base on the other hand ionizes completely to produce hydroxide ions in aqueous solutions.
The titration of a weak acid and a strong base gives a solution whose pH is greater than 7 at equivalence point.
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2. 27.8 mL of an unknown were added to a 50.0-mL flask that weighs 464.7 g. The total mass of the flask and the liquid is 552.4 g. Calculate the density of the liquid in Lbs/ in3.
Answer:
[tex]d=4.24x10^{-4}\frac{lb}{in^3}[/tex]
Explanation:
Hello there!
In this case, according to the given information, it turns out firstly necessary for us to set the equation for the calculation of density and mass divided by volume:
[tex]d=\frac{m}{V}[/tex]
Thus, we can find the mass of the unknown by subtracting the total mass of the liquid to the mass of the flask and the liquid:
[tex]m=552.4g-464.7g=87.7g[/tex]
So that we are now able to calculate the density in g/mL first:
[tex]d=\frac{87.7g}{27.8mL}=3.15g/mL[/tex]
Now, we proceed to the conversion to lb/in³ by using the following setup:
[tex]d=3.15\frac{g}{mL}*\frac{1lb}{453.6g}*\frac{1in^3}{16.3871mL}\\\\d=4.24x10^{-4}\frac{lb}{in^3}[/tex]
Regards!
why beta carbon hydrogen is easily replaceable but not alpha carbon hydrogen
Answer:
Four common types of reactions involving carbonyl reactions: 1) nucleophilic addition; 2) nucleophilic acyl substitution; 3) alpha substitution; 4) carbonyl condensations. The first two were previously discussed and the second two involve the properties of the carbon directly adjacent to the carbonyls, α carbons.
Alpha-substitution reactions results in the replacement of an H attached to the alpha carbon with an electrophile.
The nucleophile in these reactions are new and called enols and enolates.
Explanation:
The carbon in the carbonyl is the reference point and the alpha carbon is adjacent to the carbonyl carbon.
Hydrogen atoms attached the these carbons denoted with Greek letters will have the same designation, so an alpha hydrogen is attached to an alpha carbon.
Aldehyde hydrogens not given Greek leters.
α hydrogens display unusual acidity, due to the resonance stabilization of the carbanion conjugate base, called an enolate.
Tautomers are readily interconverted constitutional isomers, usually distinguished by a different location for an atom or a group, which is different than resonance.
The tautomerization in this chapter focuses on the carbonyl group with alpha hydrogen, which undergo keto-enol tautomerism.
Keto refers to the tautomer containing the carbonyl while enol implies a double bond and a hydroxyl group present in the tautomer.
The keto-enol tautomerization equilibrium is dependent on stabilization factors of both the keto tautomer and the enol tautomer, though the keto form is typically favored for simple carbonyl compounds.
The 1,3 arrangement of two carbonyl groups can work synergistically to stabilize the enol tautomer, increasing the amount present at equilibrium.
The positioning of the carbonyl groups in the 1,3 arrangement allows for the formation of a stabilizing intramolecular hydrogen bond between the hydroxyl group of the enol and the carbonyl oxygen as well as the alkene group of the enol tautomer is also conjugated with the carbonyl double bond which provides additional stabilization.
Aromaticity can also stabilize the enol tautomer over the keto tautomer.
Under neutral conditions, the tautomerization is slow, but both acid and base catalysts can be utilized to speed the reaction up.
Biological enol forming reactions use isomerase enzymes to catalyze the shifting of a carbonyl group in sugar molecules, often converting between a ketose and an aldose in a process called carbonyl isomerization.
Identify each of the following half-reactions as either an oxidation half-reaction or a reduction half-reaction.
half-reaction identification
Cu+(aq)--->Cu2+(aq) + e- _________
I2(s) + 2e--->2I-(aq) _________
Answer:
Cu+(aq)--->Cu2+(aq) + e- : oxidation
reason: there is loss of electrons.
I2(s) + 2e--->2I-(aq) : reduction
reason: There is reduction of electrons.
What will be the equilibrium temperature when a 245 g block of lead at 300oC is placed in 150-g aluminum container containing 820 g of water at 12.0oC?
Answer:
The correct approach is "12.25°C".
Explanation:
Given:
Mass of lead,
mc = 245 g
Initial temperature,
tc = 300°C
Mass of Aluminum,
ma = 150 g
Initial temperature,
ta = 12.0°C
Mass of water,
mw = 820 g
Initial temperature,
tw = 12.0°C
Now,
The heat received in equivalent to heat given by copper.
The quantity of heat = [tex]m\times s\times t \ J[/tex]
then,
⇒ [tex]245\times .013\times (300-T) = 150\times .9\times (T-12.0) + 820\times 4.2\times (T-12.0)[/tex]
⇒ [tex]3.185(300-T) = 135(T-12.0) + 3444(T-12.0)[/tex]
⇒ [tex]955.5-3.185T=135T-1620+3444T-41328[/tex]
⇒ [tex]43903.5 = 3582.185 T[/tex]
⇒ [tex]T = 12.25^{\circ} C[/tex]
g A high altitude balloon is filled with 1.41 x 104 L of hydrogen gas (H2) at a temperature of 21oC and a pressure of 745 torr. What is the volume of the balloon at a height of 20 km, where the temperature is -48oC and the pressure is 63.1 torr
Answer:
1.27 × 10⁵ L
Explanation:
Step 1: Given data
Initial pressure (P₁): 745 TorrInitial volume (V₁): 1.41 × 10⁴ LInital temperature (T₁): 21 °CFinal pressure (P₂): 63.1 TorrFinal volume (V₂): ?Final temperature (T₂): -48 °CStep 2: Convert the temperatures to the Kelvin scale
We will use the following expression.
K = °C + 273.15
K = 21 °C + 273.15 = 294 K
K = -48 °C + 273.15 = 225 K
Step 3: Calculate the final volume of the balloon
We will use the combined gas law.
P₁ × V₁ / T₁ = P₂ × V₂ / T₂
V₂ = P₁ × V₁ × T₂/ T₁ × P₂
V₂ = 745 Torr × 1.41 × 10⁴ L × 225 K/ 294 K × 63.1 Torr
V₂ = 1.27 × 10⁵ L
CAN HF USED TO CLEAVE ETHERS EXPLAIN
Answer:
no
Explanation:
Fluoride is not nucleophilic (having the tendency to donate electrons) enough to allow for the use of HF to cleave ethers in protic media(protic solvents are polar liquid compounds that have dissociable hydrogen atoms). The rate of reaction is comparably low, so that heating of the reaction mixture is required.
Draw the structure of the neutral product formed in the reaction of dimethyl malonate and methyl vinyl ketone.
Answer:
Explanation:
The reaction between dimethyl malonate which is an active methylene group with an (∝, β-unsaturated carbonyl compound) i.e methyl vinyl ketone is known as a Micheal Addition reaction. The reaction mechanism starts with the base attack on the β-carbon to remove the acidic ∝-hydrogens and form a carbanion. The carbanion formed(enolate ion) attacks the methyl vinyl ketone(i.e. a nucleophilic attack at the β-carbon) to give a Micheal addition product, this is followed by the protonation to give the neutral product.
Consider the following equation for the combustion of acetone (C3H6O), the main ingredient in nail polish remover.
C3H6O(l) + 4O2(g) → 3CO2(g) + 3H2O(g) ΔHrxn = −1790kJ
If a bottle of nail polish remover contains 143 g of acetone, how much heat would be released by its complete combustion? Express your answer to three significant figures.
Molar mass of Acetone
C3H6O3(12)+6+1658g/molNow
1 mol releases -1790KJ heat .Moles of Acetone:-
143/58=2.5molAmount of heat:-
2.5(-1790)=-4475kJ9. How can you separate sugar from a sugar solution contained in a glass without taste? Explain
Answer:
See explanation
Explanation:
Sugar is a polar crystalline substance. The sugar crystal is capable of dissolving in water since it is polar.
When sugar dissolves in water, a sugar solution is formed. If I want to separate the sugar from the water in the solution, I have to boil the solution to a very high temperature.
When I do that, the water in the sugar solution is driven off and the pure sugar crystal is left behind.
How many atoms are in .45 moles of P4010
Answer:
5×6.02×1023
Explanation:
there are 5×6.02×1023 molecules of p4010 in 5mole. there are four P atoms in a single molecule of p4010
C. A sample may contain any or all of the following ions Hg2 2, Ba 2, and Al 3. 1) No precipitate forms when an aqueous solution of NaCl was added to the sample solution. 2) No precipitate forms when an aqueous solution of Na2SO4 was added to the sample. 3) A precipitate forms when the sample solution was made basic with NaOH. Which ion or ions were present. Write the net ionic equation(s) for the the reaction (s).
Answer:
Al^3+
Explanation:
Solubility rules tell us what substances are soluble in water. Since NaCl was added and no precipitate was observed, the mercury II ion is absent.
Addition of Na2SO4 does not form a precipitate meaning that Ba^2+ is absent.
If a precipitate is formed when NaOH is added, the the ionic reaction is as follows;
Al^3+(aq) + 3 OH^-(aq) ------> Al(OH)3(s)
Si enfriamos mercurio de 100C. Calcular la cantidad de calor que se debe restar sabiendo que la masa de mercurio es de 1800gr
Answer:
I do not speak Spanish.
Explanation:
Which of the following are examples of physical properties of ethanol? Select all that apply.
The boiling point is 78.37°C
It is a clear, colorless liquid
It is flammable
It is a liquid at room temperature
2.50 L of 0.700 M phosphoric acid reacts with 5.25 moles of sodium hydroxide. How many moles of hydrogen ions will completely neutralize the moles of hydroxide ions present in this amount of sodium hydroxide? a) 0.583 b) 1.75 c) 3.00 d) 15.75 e) 5.25
Answer:
5.25 moles of protons. Option e
Explanation:
Reaction between phosphoric acid and sodium hydroxide is neutralization.
We can also say, we have an acid base equilibrium right here:
H₃PO₄ + 3NaOH → Na₃PO₄ + 3H₂O
Initially we have 5.25 moles of base.
We have data from the acid, to state its moles:
M = mol/L, so mol = M . L
mol = 1.75 moles of acid
If we think in the acid we know:
H₃PO₄ → 3H⁺ + PO₄⁻³
We know that 1 mol of acid can give 3 moles of protons (hydrogen ions)
If we have 1.75 moles of acid, we may have
(1.75 . 3) /1 = 5.25 moles of protons
These moles will be neutralized by the 5.25 moles of base
H₃O⁺ + OH⁻ ⇄ 2H₂O Kw
In a titration of a weak acid and a strong base, we have a basic pH
Balance the following chemical equation.
CCl4 -> ___ C+ ___ Cl2
Answer:
Explanation:
CCl4 => C + 2Cl2
Which statement is true with respect to standard reduction potentials?
SRP values that are greater than zero always represent a reduction reaction.
SRP values that are less than zero always represent a reduction reaction.
Half-reactions with SRP values greater than zero are spontaneous.
Half-reactions with SRP values greater than zero are nonspontaneous.
Answer:
C). Half-reactions with SRP values greater than zero are spontaneous.
Explanation:
SRPs or Standard Reduction Potentials are characterized as the ability of a probable distinction among the anode and cathode of a usual/standard cell. It aims to examine the capacity of chemicals to reduce themselves.
The third statement asserts a true claim regarding the SRPs(Standard Reduction Potentials) that the 'half-reactions which take place with the SRP possesses the values higher than zero and they are unconstrained.' The other statements are incorrect as they either show the estimation of SRPs more than 0 or display them as being restricted. Thus, option C is the correct answer.
0.50 g of hydrogen chloride (HCl) is dissolved in water to make 4.0 L of solution. What is the pH of the resulting hydrochloric acid solution
Explanation:
Given the mass of HCl is ---- 0.50 g
The volume of solution is --- 4.0 L
To determine the pH of the resulting solution, follow the below-shown procedure:
1. Calculate the number of moles of HCl given by using the formula:
[tex]number of moles of a substance=\frac{given mass of the substance}{its molecular mass}[/tex]
2. Calculate the molarity of HCl.
3. Calculate pH of the solution using the formula:
[tex]pH=-log[H^+][/tex]
Since HCl is a strong acid, it undergoes complete ionization when dissolved in water.
[tex]HCl(aq)->H^+(aq)+Cl^-(aq)[/tex]
Thus, [tex][HCl]=[H^+][/tex]
Calculation:
1. Number of moles of HCl given:
[tex]number of moles of a substance=\frac{given mass of the substance}{its molecular mass}\\=0.50g/36.5g/mol\\=0.0137mol[/tex]
2. Concentration of HCl:
[tex]Molarity of HCl=\frac{number of moles of HCl}{its molar mass}\\=\frac{0.0137 mol}{4.0 L} \\= 0.003425 M[/tex]
3. pH of the solution:
[tex]pH=-log[H^+]\\=-log(0.003425)\\=2.47[/tex]
Hence, pH of the given solution is 2.47.
Identify the oxidation half-reaction for this reaction:
Fe(s) + 2HCl(aq) → FeCl2(aq) + H2(g)
A. Fe2+ + 2e → Fe(s)
O B. H2(g) → 2H+ + 2e
O C. Fe(s) → Fe2+ + 2e
O D. 2H+ + 2e → H2(9)
Answer:
Fe(s)->Fe2+2e-
Explanation:
A.p.e.x
The oxidation half-reaction for the given reaction is Fe(s) → Fe²⁺ + 2e⁻ Hence, Option (C) is correct
What is Oxidation reaction ?Oxidation reaction is a chemical reaction which can be described as follows ;
Addition of oxygen Removal of hydrogen Loss of ElectronAddition of electronegative atomRemoval of Electropositive elementIn the given reaction ;
Fe(s) + 2HCl(aq) → FeCl₂(aq) + H₂(g)
Fe at RHS got converted to Fe²⁺ state at LHS which shows the gain of electron by Fe with in the reaction.
Therefore,
The oxidation half-reaction for the given reaction is Fe(s) → Fe²⁺ + 2e⁻ Hence, Option (C) is correct
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A molecule of acetone and a molecule of propyl aldehyde are both made from 3 carbon atoms, 6 hydrogen atoms, and 1 oxygen atom. The molecules differ in their arrangement of atoms. How do formulas for the two compounds compare? Both compounds have the same molecular formula, but have unique structural formulas. Both compounds have unique molecular formulas and structural formulas. Both compounds have the same structural formula, but have unique molecular formulas.
Explanation:
The structures of both acetone and propanal are shown below:
In the formula of propanal there is -CHO functional group at the end.
In acetone -CO- group is present in the middle that is on the second carbon.
The molecular formula is C3H6O.
Both have same molecular formula but different structural formulas.
For a gas sample containing equimolar amounts of carbon monoxideand heliumat 300 K, heliumhas _____________average speed and _____________ average kinetic energy compared tocarbon monoxidegas.a.a lower; the same b. the same; the same c. a higher; the same d. a higher; higher
Answer:
Option C (a higher; the same) is the appropriate response.
Explanation:
Given:
Temperature,
T = 300 K (both [tex]N_2[/tex] and [tex]H_2[/tex])
As we know,
Average speed of a molecule,
⇒ [tex]\bar v=\sqrt{\frac{8RT}{\pi M} }[/tex]
Thus, the average speed of [tex]N_2[/tex] will be lower as its molar mass is greater than [tex]H_2[/tex].
Now,
⇒ [tex]Average \ kinetic \ energy = \frac{3}{2} \ KT[/tex] (not depend on molar mass)
Hence, it will be the same.
The other three alternatives aren't connected to the scenario given. So the above is the correct answer.
A sample of oxygen gas has a volume of 89.6 L at STP. How many moles of oxygen gas are present ?
Answer:
89,6/22,4 =4(mol)
Explanation:
There are approximately 1.089 moles of oxygen gas present in the sample at STP.
At STP (Standard Temperature and Pressure), the conditions are defined as follows:
Temperature (T) = 0 degrees Celsius = 273.15 Kelvin
Pressure (P) = 1 atmosphere (atm) = 101.325 kPa = 1013.25 hPa
Now, to find the number of moles of oxygen gas (O2) present in the sample, we can use the ideal gas law:
PV = nRT
Where:
P = pressure (in atm)
V = volume (in liters)
n = number of moles
R = ideal gas constant = 0.0821 L.atm/(mol.K)
T = temperature (in Kelvin)
Given:
V = 89.6 L (volume at STP)
T = 273.15 K (STP temperature)
Let's plug in the values and solve for n (number of moles):
n = PV / RT
n = (1 atm) × (89.6 L) / (0.0821 L.atm/(mol.K) × 273.15 K)
n = 1.089 moles
So, there are approximately 1.089 moles of oxygen gas present in the sample at STP.
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Identify the highest energy molecular process that occurs when a molecule absorbs a microwave photon.
The question is incomplete, the complete question is;
Identify the highest energy molecular process that occurs when a molecule absorbs a microwave photon
a) electronic excitation
b) bond breakage
c) molecular vibration
d) molecular rotation
Answer:
molecular rotation
Explanation:
Microwaves are part of the electromagnetic spectrum. They are lower energy, lower frequency radiation.
When molecules absorb infrared radiation, they transition between the rotational states of the molecule.
Hence, the highest energy molecular process that occurs when a molecule absorbs a microwave photon is molecular rotation.
What is the major product in this reaction
Answer:
I think option A is right answer
dentify the correct formula for the following ionic compounds. - sodium chloride - magnesium chloride - calcium oxide - lithium phosphide - aluminum sulfide - calcium nitride A. SCl B. LiP 3 C. AlS D. Li 3P E. CaN F. CaO G. Ca 3N 2 H. MgCl 2 I. NaCl J. CaO 2 K. CaN 2 L. LiP M. MnCl 2 N. Al 2S 3 O. AlS 3
Explanation:
The chemical formula of an ionic compound can be written by using the symbols of the respective cations and anions.
The overall charge on the molecule should be zero.
Hence, the total charge of cations=total charge of anions.
The symbols of the given molecules are shown below:
sodium chloride ---- NaCl
magnesium chloride ---[tex]MgCl_2[/tex]
calcium oxide ---- CaO
lithium phosphide----[tex]Li_3P[/tex]
aluminum sulfide ----- [tex]Al_2S_3[/tex]
calcium nitride---- [tex]Ca_3N_2[/tex]
Poly(ethylene terephthalate) (PET), which has glass transition (Tg) and crystalline melting (Tm) temperature of 69 and 267 °C, respectively, can exist in a number of different states depending upon temperature and thermal history. Thus, it is possible to prepare materials that are semicrystalline with amorphous regions that are either glassy or rubbery and amorphous materials that are glassy, rubbery or melts. Consider a sample of PET cooled rapidly from 300 °C (state A) to room temperature. The resulting material is rigid and perfectly transparent (state B). The sample is then heated to 100 °C and maintained at this temperature, during which time is gradually becomes translucent (state C). It is then cooled to room temperature, where it is again observed to be translucent (state D).
Answer:
Following are the solution to the given points:
Explanation:
For point A:
The sample cooking (PET) is between 300°C and room temperature.Now in nature, the substance is exceedingly stiff.Samples of PET up to 100°C were heated and stayed on equal footing.Now it has cooled off the same sample below 100° C and we may see how it is again TRASNEPARENT in nature.For point B:
In point 3, the mixture was added to 100°C, which implies that the granular material flows and deforms, enabling it to become elongated. This is termed solid-state crystalline such that grains are flexible, but this material contaminates numerous little crystalline that has spheres when we cool down in point 4 polymers. It forms therefore an unstructured solid, which then in point 4 is higher in particles and less pliable in orderly atoms.
For point C:
In point 2, the specimen gets forced at room temperature to organize a huge molecule in an ordinary and crystal fashion and therefore is transparent due to highly crystalline atoms in point 2 of the PET sample.
In point 4, however, we notice how amorphous, firm but not crystalline develops. It's why light tends to disperse over many cereal limits, since many microscopic crystallines, therefore dispersion, PET in point 4 is translucent.
cual es la masa atomica del hidrogeno
El hidrógeno es el elemento químico de número atómico 1, representado por el símbolo H. Con una masa atómica de 1.00784 u es el más ligero de la tabla periódica de los elementos. Por lo general, se presenta en su forma molecular, formando el gas diatómico H₂ en condiciones normales.
How many electrons are shown in the following electron
configuration: 1s22s22p63s 23p64s23d104p65s24d105p66s2 ?
Express your answer numerically as an integer.
Answer:
1s22s22p6
Explanation:
Neon is an element in the periodic table and has an atomic number of 10, which means it has 10 protons in its nucleus and thus since the number of protons and electrons is the same then it has 10 electrons.
Therefore, it has 2 electrons in the first energy shell and 8 electrons in the second energy shell. To elaborate further, the first shell has a single s-sub shell that contains a single s-orbital that can hold two electrons. The second energy shell has a single s-sub-shell whose s-orbital will occupy 2 electrons, and also has a p-orbital which can hold 6 electrons, making the second shell to have 8 electrons.
