Answer:
The pH of the solution is 12.78.
Explanation:
The pOH (or potential OH) is a measure of the basicity or alkalinity of a solution. The pOH is defined as the negative logarithm of the activity of the hydroxide ions. That is, the concentration of OH- ions:
pOH= - log [OH-]
On the other side, Molarity or Molar Concentration is the number of moles of solute that are dissolved in a certain volume. Molarity is calculated as:
[tex]Molarity= \frac{number of moles}{volume}[/tex]
Molarity is expressed in units: [tex]\frac{moles}{liter}[/tex]
In this case, the solution is prepared by mixing 100 ml (equal to 0.1 L, where 1000 mL = 1 L) of Ca(OH)₂ 0.020 M with 50 ml (equal to 0.05 L) of 0.100 M NaOH. Then, Ca(OH)₂ and NaOH are strong bases, so they dissociate completely. In the case of the first hydroxide, for each mole of Ca(OH)₂,
form two moles of OH-. In the case of sodium hydroxide, for each mole of hydroxide, one mole of OH- is formed. So, taking into account the definition of molarity, the number of moles of OH- that each hydroxide contributes to the solution is calculated as:
From Ca(OH)₂: 0.1 L* 0.02 M*2 = 0.004 moles
From NaOH: 0.05 L* 0.1 M= 0.005 moles
So, the amount of total moles of OH- is the sum that each hydroxide contributes to the solution: 0.004 moles + 0.005 moles= 0.009 moles
On the other hand, volumes are additive. Then: 0.1 L + 0.05 L= 0.15 L
Replacing in the definition of molarity the number of moles and the volume:
[tex][OH-]=\frac{0.009 moles}{0.15 L}[/tex]
Solving:
[OH-]= 0.06 [tex]\frac{moles}{liter}[/tex]
Replacing in the definition of pOH:
pOH= - log 0.06
pOH= 1.22
The following relationship can be established between pH and pOH:
pH + pOH= 14
Being pOH= 1.22 and replacing:
pH + 1.22= 14
pH= 14 - 1.22
pH= 12.78
The pH of the solution is 12.78.
DATA SHEET p 45. TRIAL 1 TRIAL 2 1. Mass of the ground pretzel 1.00 gram 1.03 g 2. Initial volume of the AgNO3 solution 0.00 mL 9.10 mL 3. Final volume of the AgNO3 solution 9.10 mL 17.25 mL 4. Volume of AgNO3 solution used 9.10 mL 8.15 mL Line 3 – Line 2 5. Volume of AgNO3 solution in liters _____ L _____ L 6. Molarity of AgNO3 solution 0.01 M 0.01 M (given) 7. Number of moles of AgNO3 ______ mol _____ mol (Line 5 × Line 6) 8. Number of mol of NaCl present in pretzel ______ mol _____ mol (Line 7) number of mol NaCl = number of mol AgNO3 9. Mass of NaCl present in the titrated sample ______ gram _____ gram (Line 8) × 58.5 g/mol
Answer:
1. 1.00 gm
2. 50 ml
3. 38.93 ml
4. 11.07 ml
5. 0.01107 L
6. 0.010 moles / L
7. 0.0001107 moles
8. 0.0001107 moles
9. 0.00647042 grams
Explanation:
Silver nitrate can react with various compounds to form different products. The weight of products may be different from the original solution introduced due to combustion reaction, as heat energy is released during the chemical process.
An endothermic reaction will start when the required
energy is received from the environment or solution.
AH
activation
thermal
kinetic
Answer:
A: ΔH
Explanation:
Endothermic reactions are this that occur as a result of absorption of heat energy from the surroundings by the reactants to form new products.
Thus, we can say it is one with an increase in enthalpy (ΔH) of the system.
Thus, option A is correct.
When butane reacts with Br2 in the presence of Cl2, both brominated and chlorinated products are obtained. Under such conditions, the usual selectivity of bromination is not observed. In other words, the ratio of 2-bromobutane to 1-bromobutane is very similar to the ratio of 2-chlorobutane to 1-chlorobutane. Can you offer and explanation as to why we do not observe the normal selectivity expected for bromination
Answer:
Bromine radical formation is carried out in the presence of Br₂ and Cl₂ causing the normal selectivity not to be observed ( this causes the difference in activation energy to be reduced )
Explanation:
Why the normal selectivity expected for bromination is not observed
On the basis of selectivity and applying the Arrhenius equation the greater the difference between the activation energies the more the selectivity.
as seen in the formation of primary and secondary radicals in the Bromine radical formation. this difference is caused mainly by the propagation step ( exothermic ) . But the main reason why the the usual selectivity of bromination is not observed is because it Bromine radical formation is carried out in the presence of Br₂ and Cl₂ ( this causes the difference in activation energy to be reduced )
Which statement is true with respect to standard reduction potentials?
SRP values that are greater than zero always represent a reduction reaction.
SRP values that are less than zero always represent a reduction reaction.
Half-reactions with SRP values greater than zero are spontaneous.
Half-reactions with SRP values greater than zero are nonspontaneous.
Answer:
C). Half-reactions with SRP values greater than zero are spontaneous.
Explanation:
SRPs or Standard Reduction Potentials are characterized as the ability of a probable distinction among the anode and cathode of a usual/standard cell. It aims to examine the capacity of chemicals to reduce themselves.
The third statement asserts a true claim regarding the SRPs(Standard Reduction Potentials) that the 'half-reactions which take place with the SRP possesses the values higher than zero and they are unconstrained.' The other statements are incorrect as they either show the estimation of SRPs more than 0 or display them as being restricted. Thus, option C is the correct answer.
When 4.41g of phosphoric acid (H3PO4) react with 9.25g of barium hydroxide, water and insoluble barium phosphate form. [T/I-7] a. Write and balance the chemical equation.
Answer:
2 H₃PO₄(aq) + 3 Ba(OH)₂(aq) ⇒ Ba₃(PO₄)₂(s) + 6 H₂O(l)
Explanation:
Let's consider the unbalanced equation that occurs when phosphoric acid reacts with barium hydroxide to form water and barium phosphate. This is a neutralization reaction.
H₃PO₄(aq) + Ba(OH)₂(aq) ⇒ Ba₃(PO₄)₂(s) + H₂O(l)
We will balance it using the trial and error method.
First, we will balance Ba atoms by multiplying Ba(OH)₂ by 3 and P atoms by multiplying H₃PO₄ by 2.
2 H₃PO₄(aq) + 3 Ba(OH)₂(aq) ⇒ Ba₃(PO₄)₂(s) + H₂O(l)
Finally, we will get the balanced equation by multiplying H₂O by 6.
2 H₃PO₄(aq) + 3 Ba(OH)₂(aq) ⇒ Ba₃(PO₄)₂(s) + 6 H₂O(l)
Write the symbol for every chemical element that has atomic number greater than 70 and atomic mass less than 185.2
Answer:
HF...Ta... W....Lu...
0.50 g of hydrogen chloride (HCl) is dissolved in water to make 4.0 L of solution. What is the pH of the resulting hydrochloric acid solution
Explanation:
Given the mass of HCl is ---- 0.50 g
The volume of solution is --- 4.0 L
To determine the pH of the resulting solution, follow the below-shown procedure:
1. Calculate the number of moles of HCl given by using the formula:
[tex]number of moles of a substance=\frac{given mass of the substance}{its molecular mass}[/tex]
2. Calculate the molarity of HCl.
3. Calculate pH of the solution using the formula:
[tex]pH=-log[H^+][/tex]
Since HCl is a strong acid, it undergoes complete ionization when dissolved in water.
[tex]HCl(aq)->H^+(aq)+Cl^-(aq)[/tex]
Thus, [tex][HCl]=[H^+][/tex]
Calculation:
1. Number of moles of HCl given:
[tex]number of moles of a substance=\frac{given mass of the substance}{its molecular mass}\\=0.50g/36.5g/mol\\=0.0137mol[/tex]
2. Concentration of HCl:
[tex]Molarity of HCl=\frac{number of moles of HCl}{its molar mass}\\=\frac{0.0137 mol}{4.0 L} \\= 0.003425 M[/tex]
3. pH of the solution:
[tex]pH=-log[H^+]\\=-log(0.003425)\\=2.47[/tex]
Hence, pH of the given solution is 2.47.
Identify the oxidation half-reaction for this reaction:
Fe(s) + 2HCl(aq) → FeCl2(aq) + H2(g)
A. Fe2+ + 2e → Fe(s)
O B. H2(g) → 2H+ + 2e
O C. Fe(s) → Fe2+ + 2e
O D. 2H+ + 2e → H2(9)
Answer:
Fe(s)->Fe2+2e-
Explanation:
A.p.e.x
The oxidation half-reaction for the given reaction is Fe(s) → Fe²⁺ + 2e⁻ Hence, Option (C) is correct
What is Oxidation reaction ?Oxidation reaction is a chemical reaction which can be described as follows ;
Addition of oxygen Removal of hydrogen Loss of ElectronAddition of electronegative atomRemoval of Electropositive elementIn the given reaction ;
Fe(s) + 2HCl(aq) → FeCl₂(aq) + H₂(g)
Fe at RHS got converted to Fe²⁺ state at LHS which shows the gain of electron by Fe with in the reaction.
Therefore,
The oxidation half-reaction for the given reaction is Fe(s) → Fe²⁺ + 2e⁻ Hence, Option (C) is correct
Learn More about redox reaction here ;
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5. A beam of photons with a minimum energy of 222 kJ/mol can eject electrons from a potassium surface. Estimate the range of wavelengths of light that can be used to cause this phenomenon. Show your calculations with units of measure (dimensional analysis) and briefly explain your reasoning.
Answer: The range of wavelengths of light that can be used to cause given phenomenon is [tex]8.953 \times 10^{21} m[/tex].
Explanation:
Given: 222 kJ/mol (1 kJ = 1000 J) = 222000 J
Formula used is as follows.
[tex]E = \frac{hc}{\lambda}[/tex]
where,
E = energy
h = Planck's constant = [tex]6.625 \times 10^{-25} Js[/tex]
c = speed of light = [tex]3 \times 10^{8} m/s[/tex]
Substitute the values into above formula as follows.
[tex]E = \frac{hc}{\lambda}\\222000 J = \frac{6.625 \times 10^{-34}Js \times 3 \times 10^{8} m/s}{\lambda}\\\lambda = 8.953 \times 10^{21} m[/tex]
Thus, we can conclude that the range of wavelengths of light that can be used to cause given phenomenon is [tex]8.953 \times 10^{21} m[/tex].
Calculate percent yield when you start with 0.78 grams of camphor and end with 0.23 grams of iso/borneol. The molecular weight of camphor is 152.23 g/mol, and the molecular weight of iso/borneol is 154.25 g/mol.
Answer:
29.1%
Explanation:
First we convert 0.78 g of camphor to moles, using its molar mass:
0.78 g ÷ 152.23 g/mol = 0.00512 mol camphorThen we convert 0.23 g of isoborneol to moles, using its molar mass:
0.23 g ÷ 154.25 g/mol = 0.00149 mol isoborneolFinally we calculate the percent yield:
0.00149 mol / 0.00512 mol * 100% = 29.1%A molecule of acetone and a molecule of propyl aldehyde are both made from 3 carbon atoms, 6 hydrogen atoms, and 1 oxygen atom. The molecules differ in their arrangement of atoms. How do formulas for the two compounds compare? Both compounds have the same molecular formula, but have unique structural formulas. Both compounds have unique molecular formulas and structural formulas. Both compounds have the same structural formula, but have unique molecular formulas.
Explanation:
The structures of both acetone and propanal are shown below:
In the formula of propanal there is -CHO functional group at the end.
In acetone -CO- group is present in the middle that is on the second carbon.
The molecular formula is C3H6O.
Both have same molecular formula but different structural formulas.
An electrolysis reaction is
A)
exothermic.
B)
hydrophobic.
C)
spontaneous.
D)
non-spontaneous.
Answer:
the electrolysis reaction is a non- spontaneous reaction
Explanation:
Since electrons flow from it, the anode in an electrolytic cell is positive, while the cathode is negative when electrons flow into it. The device functions like a galvanic cell in that direction. In an electrolytic cell, an external voltage is applied and that is what causes a non spontaneous reaction
Classify the following as either solutions or colloids. If a colloid, name the type of colloid and identify both the dispersed and the dispersing phases.
a. glucose in water
b. smoke in air
c. carbon dioxide in air
d. milk
Answer:
a. glucose in water( solution)
b. smoke in air (colloids)
c. carbon dioxide in air (solution)
d. milk( colloids)
Explanation:
A solution is said to be formed when a solute dissolves in a solvent to form a homogeneous mixture. The solute particles are less than 10^-9m in size. Familiar solutions are those where the solute are dissolved in a liquid solvent. When the liquid water, the solution is known as an aqueous solution. A typical example is (glucose in water). In some other cases, the apparent solution of a solute in a solvent is accompanied by a chemical reaction and this is often known as a chemical reaction. A typical example is (carbon dioxide in air).
Colloids are also known as false solutions. Here, the individual solute particles are larger than the particles of the true solution, but not large enough to be seen by the naked eye. When a light beam is placed beside a beaker containing a colloid, the light rays of the beam can be clearly seen. This shows that it exhibits the Tyndall effect while a solution dosent exhibit such.
In a colloid, the liquid solvent is more appropriately know as the DISPERSION medium while the solid solute particles constitute the DISPERSED substance. This can either be solid, liquid or gas.
For example:
--> smoke in air : Dispersion medium is gas while the dispersed substance is solid.
--> milk: Dispersion medium is liquid while the dispersed substance is liquid.
Determine whether the reaction will be spontaneous at high temperatures only, at low temperatures only, at all temperatures, or no temperatures. (HINT: Use your chemical sense and your real-world knowledge to predict the signs of delta Hrxn & delta Srxn)
4Fe(s) + 3O2(g) ----> 2Fe2O3(s) [rust]
Circle one:High T, Low T, All T, No T
Answer:
The rusting of iron is spontaneous at low temperatures.
Explanation:
The given chemical reaction is:
4Fe(s) + 3O2(g) ----> 2Fe2O3(s) [rust]
The rusting of iron is a chemical reaction in which iron reacts with oxygen in presence of moisture and forms iron oxide.
This reaction takes place in a faster rate when there is low temperatures in the atmosphere.
When temperature is low, the moisture in the atmosphere is more and hence, rate of rusting is more.
explain in brief how some bacteria cause tooth cavities
Answer:
because some bacteria change the ph of the teeth and leads to tooth cavitiew
For a gas sample containing equimolar amounts of carbon monoxideand heliumat 300 K, heliumhas _____________average speed and _____________ average kinetic energy compared tocarbon monoxidegas.a.a lower; the same b. the same; the same c. a higher; the same d. a higher; higher
Answer:
Option C (a higher; the same) is the appropriate response.
Explanation:
Given:
Temperature,
T = 300 K (both [tex]N_2[/tex] and [tex]H_2[/tex])
As we know,
Average speed of a molecule,
⇒ [tex]\bar v=\sqrt{\frac{8RT}{\pi M} }[/tex]
Thus, the average speed of [tex]N_2[/tex] will be lower as its molar mass is greater than [tex]H_2[/tex].
Now,
⇒ [tex]Average \ kinetic \ energy = \frac{3}{2} \ KT[/tex] (not depend on molar mass)
Hence, it will be the same.
The other three alternatives aren't connected to the scenario given. So the above is the correct answer.
it takes 513 kj to remove a mole of electrons from the atoms at the surface of a piece of metal. how much energy does it take to remove a single electron from n atom at the surface of the metal
Answer:
The right solution is "[tex]8.5\times 10^{-19} \ joule[/tex]".
Explanation:
As we know,
1 mole electron = [tex]6.023\times 10^{23} \ no. \ of \ electrons[/tex]
Total energy = [tex]513 \ KJ[/tex]
= [tex]513\times 1000 \ joule[/tex]
For single electron,
The amount of energy will be:
= [tex]\frac{513\times 1000}{(6.023\times 10^{23})}[/tex]
= [tex]8.5\times 10^{-19} \ joule[/tex]
A sample of oxygen gas has a volume of 89.6 L at STP. How many moles of oxygen gas are present ?
Answer:
89,6/22,4 =4(mol)
Explanation:
There are approximately 1.089 moles of oxygen gas present in the sample at STP.
At STP (Standard Temperature and Pressure), the conditions are defined as follows:
Temperature (T) = 0 degrees Celsius = 273.15 Kelvin
Pressure (P) = 1 atmosphere (atm) = 101.325 kPa = 1013.25 hPa
Now, to find the number of moles of oxygen gas (O2) present in the sample, we can use the ideal gas law:
PV = nRT
Where:
P = pressure (in atm)
V = volume (in liters)
n = number of moles
R = ideal gas constant = 0.0821 L.atm/(mol.K)
T = temperature (in Kelvin)
Given:
V = 89.6 L (volume at STP)
T = 273.15 K (STP temperature)
Let's plug in the values and solve for n (number of moles):
n = PV / RT
n = (1 atm) × (89.6 L) / (0.0821 L.atm/(mol.K) × 273.15 K)
n = 1.089 moles
So, there are approximately 1.089 moles of oxygen gas present in the sample at STP.
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Identify the highest energy molecular process that occurs when a molecule absorbs a microwave photon.
The question is incomplete, the complete question is;
Identify the highest energy molecular process that occurs when a molecule absorbs a microwave photon
a) electronic excitation
b) bond breakage
c) molecular vibration
d) molecular rotation
Answer:
molecular rotation
Explanation:
Microwaves are part of the electromagnetic spectrum. They are lower energy, lower frequency radiation.
When molecules absorb infrared radiation, they transition between the rotational states of the molecule.
Hence, the highest energy molecular process that occurs when a molecule absorbs a microwave photon is molecular rotation.
_________one moleculetwo moleculesone moletwo moles of H2(g) reacts with _________one moleculetwo moleculesone moletwo moles of F2(g) to form _________one moleculetwo moleculesone moletwo moles of HF(g).
Answer:
The reaction between hydrogen and fluorine.
Explanation:
The balanced chemical equation of the reaction is:
[tex]H_2(g)+F_2(g)->2HF(g)[/tex]
From the balanced chemical equation, it is clear that:
1 mole of [tex]H_2[/tex] gas reacts with one mole of [tex]F_2(g)[/tex] and forms 2 moles of HF(g).
What is the major product in this reaction
Answer:
I think option A is right answer
dentify the correct formula for the following ionic compounds. - sodium chloride - magnesium chloride - calcium oxide - lithium phosphide - aluminum sulfide - calcium nitride A. SCl B. LiP 3 C. AlS D. Li 3P E. CaN F. CaO G. Ca 3N 2 H. MgCl 2 I. NaCl J. CaO 2 K. CaN 2 L. LiP M. MnCl 2 N. Al 2S 3 O. AlS 3
Explanation:
The chemical formula of an ionic compound can be written by using the symbols of the respective cations and anions.
The overall charge on the molecule should be zero.
Hence, the total charge of cations=total charge of anions.
The symbols of the given molecules are shown below:
sodium chloride ---- NaCl
magnesium chloride ---[tex]MgCl_2[/tex]
calcium oxide ---- CaO
lithium phosphide----[tex]Li_3P[/tex]
aluminum sulfide ----- [tex]Al_2S_3[/tex]
calcium nitride---- [tex]Ca_3N_2[/tex]
Poly(ethylene terephthalate) (PET), which has glass transition (Tg) and crystalline melting (Tm) temperature of 69 and 267 °C, respectively, can exist in a number of different states depending upon temperature and thermal history. Thus, it is possible to prepare materials that are semicrystalline with amorphous regions that are either glassy or rubbery and amorphous materials that are glassy, rubbery or melts. Consider a sample of PET cooled rapidly from 300 °C (state A) to room temperature. The resulting material is rigid and perfectly transparent (state B). The sample is then heated to 100 °C and maintained at this temperature, during which time is gradually becomes translucent (state C). It is then cooled to room temperature, where it is again observed to be translucent (state D).
Answer:
Following are the solution to the given points:
Explanation:
For point A:
The sample cooking (PET) is between 300°C and room temperature.Now in nature, the substance is exceedingly stiff.Samples of PET up to 100°C were heated and stayed on equal footing.Now it has cooled off the same sample below 100° C and we may see how it is again TRASNEPARENT in nature.For point B:
In point 3, the mixture was added to 100°C, which implies that the granular material flows and deforms, enabling it to become elongated. This is termed solid-state crystalline such that grains are flexible, but this material contaminates numerous little crystalline that has spheres when we cool down in point 4 polymers. It forms therefore an unstructured solid, which then in point 4 is higher in particles and less pliable in orderly atoms.
For point C:
In point 2, the specimen gets forced at room temperature to organize a huge molecule in an ordinary and crystal fashion and therefore is transparent due to highly crystalline atoms in point 2 of the PET sample.
In point 4, however, we notice how amorphous, firm but not crystalline develops. It's why light tends to disperse over many cereal limits, since many microscopic crystallines, therefore dispersion, PET in point 4 is translucent.
cual es la masa atomica del hidrogeno
El hidrógeno es el elemento químico de número atómico 1, representado por el símbolo H. Con una masa atómica de 1.00784 u es el más ligero de la tabla periódica de los elementos. Por lo general, se presenta en su forma molecular, formando el gas diatómico H₂ en condiciones normales.
How many electrons are shown in the following electron
configuration: 1s22s22p63s 23p64s23d104p65s24d105p66s2 ?
Express your answer numerically as an integer.
Answer:
1s22s22p6
Explanation:
Neon is an element in the periodic table and has an atomic number of 10, which means it has 10 protons in its nucleus and thus since the number of protons and electrons is the same then it has 10 electrons.
Therefore, it has 2 electrons in the first energy shell and 8 electrons in the second energy shell. To elaborate further, the first shell has a single s-sub shell that contains a single s-orbital that can hold two electrons. The second energy shell has a single s-sub-shell whose s-orbital will occupy 2 electrons, and also has a p-orbital which can hold 6 electrons, making the second shell to have 8 electrons.
The reversible reaction: 2SO2(g) O2(g) darrow-tn.gif 2SO3(g) has come to equilibrium in a vessel of specific volume at a given temperature. Before the reaction began, the concentrations of the reactants were 0.060 mol/L of SO2 and 0.050 mol/L of O2. After equilibrium is reached, the concentration of SO3 is 0.040 mol/L. What is the equilibrium concentration of O2
Answer:
[tex][O_2]_{eq}=0.030M[/tex]
Explanation:
Hello there!
In this case, according to the given information, it turns out possible for us to solve this problem by firstly writing out the mathematical expression for the concentration of oxygen at equilibrium, given the initial one and the change due to the reaction extent:
[tex][O_2]_{eq}=0.050M-x[/tex]
Whereas [tex]x[/tex] can be found considering the equilibrium of SO3:
[tex][SO_3]_{eq}=2x=0.040M[/tex]
Which means:
[tex]x=\frac{0.040M}{2} =0.020M[/tex]
Thus, the equilibrium concentration of oxygen gas turns out:
[tex][O_2]_{eq}=0.050M-0.020M=0.030M[/tex]
Regards!
A gas at 74°C is heated to 120°C so there is pressure reaches 1.79 ATM. What is its initial pressure?
Explanation:
here's the answer to your question
2, classify the following molecules as polar or non polar.
A,CH4 B,CHcl C,Co2 D,H2O2 E,BCl3 F,H2S
A. CH4= NON POLAR
B. CH3cl= POLAR
C. CO2= NON POLAR
D. H2O2= POLAR
E. BCl3= NON POLAR
F. H2S= SLIGHTLY POLAR
Use the following key to classify each of the elements below in its elemental form:
A. Discrete atoms .. C. Metallic lattice
B. Molecules ... D. Extended, three-dimensional network
1. Magnesium
2. Nitrogen ...
3. Lithium
4. Potassium ...
Answer:
Magnesium - Metallic lattice
Nitrogen - Molecules
Lithium - Metallic lattice
Potassium - Metallic lattice
Explanation:
Metals exist in metallic lattices. In this lattice, metal ions are held together with a sea of electrons by strong electrostatic forces.
All metals possess this metallic lattice, hence; potassium, lithium and magnesium all consist of metal lattices.
Nitrogen is a nonmetal and consists of molecules of N2.
Two substances (A and B) are placed at each end of a glass tube. The vapors of the substances form a solid that is closer to substance
A's end than to substance B's end.
Which conclusion will be made?
O Substance A has a greater molecular mass than substance B.
Substance B has a greater molecular mass than substance A.
The molecular masses of both substances are the same.
Answer:
Substance A has a greater molecular mass than substance B
Explanation:
The greater the mass of a substance, the slower it will travel. If the solid formed closer to substance A, it means that substance A, travelled less and that it was slower, meaning it had a greater molecular mass.
Please mark it as brainliest if it helped you
Answer:
thank you... I would say is the answer: Subtance A has a greater molecular mass than substance B.
Explanation:
thanks for posting all the comments all the time!
have a great week... stay warm from a snow storm
