Answer:
the house found in a very cold are Igloos or the ice house
Calculate the molarity of a solution consisting of 65.5 g of K2S0 4 in 5.00 L of solution.
Answer:
Molarity is 0.075 M.
Explanation:
Moles:
[tex]{ \tt{ = \frac{65.5}{RFM} }}[/tex]
RFM of potassium sulphate :
[tex]{ \tt{ = (39 \times 2) + 32 + (16 \times 4)}} \\ = 174 \: g[/tex]
substitute:
[tex]{ \tt{moles = \frac{65.5}{174} = 0.376 \: moles}}[/tex]
In volume of 5.00 l:
[tex]{ \tt{5.00 \: l = 0.376 \: moles}} \\ { \tt{1 \: l = ( \frac{0.376}{5.00} ) \: moles}} \\ { \tt{molarity = 0.075 \: mol \: l {}^{ - 1} }}[/tex]
A reaction rate increases by a factor of 500. in the presence of a catalyst at 37oC. The activation energy of the original pathway is 106 kJ/mol. What is the activation energy of the new pathway, all other factor being equal
Answer:
[tex]E_2=999984KJ/mole[/tex]
Explanation:
From the question we are told that:
Factor [tex]dK=500[/tex]
Temperature [tex]T=37 C=310k[/tex]
Activation energy [tex]E=10^6kJ/mol[/tex]
Generally the Arhenius equation is mathematically given by
[tex]ln \frac{K_2}{K_1}=\frac{ E_1-E_2}{RT}[/tex]
Where
[tex]\frac{K_2}{K_1}=500[/tex]
[tex]ln 500=\frac{ 10^6-10^3-E_2}{8.314*310}[/tex]
[tex]E_2=999984KJ/mole[/tex]
The activation energy of the new reaction is 105.99 kJ/mol.
Using the Arrhenius equation;
ln(k2/k1) = -Ea2/RT2 + Ea1/RT1
Now, from the information in the question;
k2/k1 = 500
Ea = ?
R = 8.314 JKmol-1
T2 = 37oC + 273 = 310 K
T1 = 37oC + 273 = 310 K
Substituting values;
ln (500) =- Ea2 + Ea1
6.2 = -Ea2 + 106 × 10^3 J
Ea = 106 × 10^3 J - 6.2
Ea = 105.99 × 10^3 J or 105.99 kJ/mol
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For an atoms electrons, how many energy sublevels are present in the principal energy level n = 4?
A. 4
B. 9
C. 10
D. 16
E. 32
Answer:
by the own's formula energy sublevels are 2 the power of n or principal quantum number this means 2 the power of 4 equal to 32
Assuming a mixture of equal volumes of o xylene and cyclohexane,which of these will distill off first?
Starting from (R)-3-methylhex-1-yne as the substrate at the center of your page, draw a reaction map showing the regiochemical and stereochemical outcome or outcomes for each of the following series of reagents. Name each of your products, including stereochemical designations for any chirality centers that are generated.
a. HgSO4, H2SO4, H2O
b. 1. 9-BBN; 2. H2O2, NaOH
c. Br2, CCl4
d. HBr
Solution :
A substrate is defined as the chemical species that are being observed in the chemical reaction where the substrate reacts with a reagent and forms a product. It can also be referred to the surface where some other chemical reactions are performed.
Stereochemistry is defined as the study of relative spatial arrangement of the atoms which forms the structure of the molecules and their respective manipulations.
In the context, the products including the stereochemical designations for any chirality centers starting from the (R)-3-methylhex-1-yne as the substrate are attached below.
Consider the chemical reaction: N2 3H2 yields 2NH3. If the concentration of the reactant H2 was increased from 1.0 x 10-2 M to 2.5 x 10-1 M, calculate the reaction quotient (Q) and determine which way the chemical system would shift by comparing the value of Q to K.
In this equilibrium, the chemical system will shift to the right in order to produce more NH₃.
The equilibrium constant of a reaction is defined as:
"The ratio between equilibrium concentrations of products powered to their reaction quotient and equilibrium concentration of reactants powered to thier reaction quotient".
The reaction quotient, Q, has the same algebraic expressions but use the actual concentrations of reactants.
To solve this question we need this additional information:
For this reaction, K = 6.0x10⁻² and the initial concentrations of the reactants are:
[N₂] = 4.0M; [NH₃] = 1.0x10⁻⁴M and [H₂] = 1.0x10⁻²M
Thus, for the reaction:
N₂ + 3H₂ ⇄ 2NH₃
The equilibrium constant, K, of this reaction, is defined as:
[tex]K = \frac{[NH_3]^2}{[H_2]^3[N_2]}[/tex]
Where [] are concentrations in equilibrium.
And Q, is:
[tex]Q = \frac{[NH_3]^2}{[H_2]^3[N_2]}[/tex]
Where actual concentrations are:
[NH₃] = 1.0x10⁻⁴M
[N₂] = 4.0M
[H₂] = 2.5x10⁻¹M
Replacing:
Q = 1.6x10⁻⁷
As Q < K,
The chemical system will shift to the right in order to produce more NH₃
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What is the molarity of a solution that contains 0.75 mol Naci in 3.0 L of solution? Select one: O a. 4.0 M O b. 2.3 M O d. 3.8 M O d. 0.25 M Clear my choice
Answer:
[tex]\boxed {\boxed {\sf D. \ 0.25 \ M}}[/tex]
Explanation:
Molarity is a measure of concentration in moles per liter.
[tex]molarity= \frac{moles \ of \ solute}{ liters \ of \ solution}[/tex]
The solution contains 0.75 moles of sodium chloride and has a volume of 3.0 liters.
moles of solute = 0.75 mol NaCl liters of solution = 3.0 LSubstitute these values into the formula.
[tex]molarity= \frac{ 0.75 \ mol \ NaCl}{3.0 \ L}[/tex]
[tex]molarity= 0.25 \ mol \ NaCl/L[/tex]
Molarity has the molar (M) as its unit. 1 molar is equal to 1 mole per liter.
[tex]molarity= 0.25 \ M \[/tex]
The molarity of the solution is 0.25 Molar and Choice D is correct.
calculate the volume of 20.5g of oxygen occupied at standard temperature and pressure.what the volume
Answer :
volume of a gas = weight * 22.4 l / gram molecular weight
volume of o2 = ?
weight given = 20.5 g
gram molecular weight of oxygen = 32 (because of 2 oxygen atoms )
volume of oxygen = 20.5 * 22.4 / 32
volume of oxygen = 14.35 liters
Explanation:
hope this helps you
if wrong just correct me
How many grams of magnesium chloride can be produced from 2.30 moles of chlorine gas reacting w excess magnesium Mg(s)+Cl2(g)->MgCl2(s)
The mass of magnesium chloride produced from 2.30 moles of chlorine gas is 218.99 grams.
How to calculate moles in stoichiometry?Stoichiometry refers to the study and calculation of quantitative (measurable) relationships of the reactants and products in chemical reactions.
According to this question, magnesium reacts with chlorine gas to form magnesium chloride as follows:
Mg + Cl₂ → MgCl₂
Based on the above chemical equation, 1 mole of chlorine gas forms 1 mole of magnesium chloride.
This means that 2.30 moles of chlorine gas will 2.30 moles of magnesium chloride.
Next, we convert moles of magnesium chloride to mass as follows:
molar mass of magnesium chloride = 95.211g/mol
mass of magnesium chloride = 95.211 × 2.30 = 218.99 grams.
Therefore, 218.99 grams of magnesium chloride will be formed.
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2.5
Nakula investigated the effect of heat on amylase. Amylase is an enzyme
that makes starch molecules break down into sugar molecules.
P
• Nakula put some amylase solution into two boiling tubes,
P and Q
• He boiled the solution in tube P. He did not heat tube Q.
• He waited until the solution in tube P had cooled down to
room temperature.
• He added equal volumes of starch solution to tube P and
boiled amylase amylase
• After 10 minutes, he tested both tubes for sugar.
and starch and starch
• Nakula found that there was sugar in tube Q. but not in tube P.
The structure of amylase deteriorates due to high temperature of the solution.
This experiment shows that the structure of amylase deteriorates due to high temperature which prevents this amylase from performing its function properly.
At high temperatures the amylase will break starch down very slowly or not at all due to denaturation of the enzyme's active site due to which it can't perform its function properly so we can conclude that high temperature denatures amylase enzyme.
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Nakula's conclusion was- "My results show that boiling destroys amylase"
Amylase is an enzyme that breaks down starch molecules into sugar molecules. He boiled the solution in tube P, and when he checked tube P for sugar, there wasn't any. He didn't boil the solution in tube Q and he found sugar in it.
Amylase had broken down starch molecules to sugar molecules in tube Q. Tube P's solution had been boiled, and this showed that when he boiled it, it destroyed the amylase, that is why the starch molecules hadn't been broken down into sugar molecules.
Which one of the following is not matches the organelle with its function
Answer:
rip there isnt a photo
Explanation:
i do know a lot about cells tho lol
Consider the following reaction:
Cr(NO3)3 (aq) + 2NaF (aq) --> 3NaNO3 (aq) + CrF3 (s)
If 21.0 grams of NaF are needed to precipitate all of the Cr+3 ions present in 0.125L of a solution of Cr(NO3)3, what is the molarity of the Cr(NO3)3 solution?
Your answer should be to 2 decimal places.
Answer:
2.01
Explanation:
First, let's convert grams to moles
(Na) 22.99 + (F) 18.998 = 41.988
Every mole of NaF is 41.988 grams
21/41.988 = 0.500143 moles of NaF
For every Cr+3, we will need 2 NaF, so Cr+3 will be half of NaF
0.500143/2 = 0.250071
molarity = moles/liters
0.250071/0.125 = 2.0057 M
Sally has constructed a concentration cell to measure Ksp for MCln. She constructs the cell by adding 2 mL of 0.05 M M(NO3)n to one compartment of the microwell plate. She then makes a solution of MCln by adding KCl to M(NO3)n. She adds 7.903 mL of the resulting mixture to a second compartment of the microwell plate. Sally knows n = +2. She has already calculated [Mn+] in the prepared MCln solution using the Nernst equation. [Mn+] = 8.279 M
Required:
How many moles of [Cl-] must be dissolved in that compartment?
Answer:
0.1309 mol
Explanation:
From the given information:
The metal ion, two ions of [tex]M^{+}[/tex] reacted with Cl⁻ to form [tex]MCl_n[/tex] i.e. the compound formed is [tex]MCl_2[/tex].
The concentration of the metal ion formed [tex][M^+][/tex] = 8.279 M
The concentration of the chlorine ion formed [tex][Cl^-][/tex] = 2 × 8.279 M
= 16.558 M
∴
We know that:
[tex]\mathsf{Molarity = \dfrac{no \ of \ moles }{volume (mL)}}[/tex]
The number of moles of [tex][Cl^-][/tex] = [tex]16.558 \ mol.L^{-1} \times 7.903 \ mL \times \dfrac{1 \ L}{1000 \ mL}[/tex]
= 0.1309 mol
which of the following is indicated by the ph value of a solution?
a- it's hydrogen ion concentration
b- its ammonium ion concentration
c- ability to undergo chemical reaction
d- its ratio of solute amount to solvent volume
Answer:
c- ability to undergo chemical reaction
what type of bonding does Sodium Sulphate comes under?and explain in detail please
Answer:
The bond between sodium sulfate is an ionic bond since it's a bond between a metal and non metals however the bond between sulfur and oxygen is a covalent bond since the two are non metals and the other reason that makes this an ionic bond is that there is both losing and gaining of electrons..
I hope this helps
Van der Waals forces hold molecules together by: A. moving electrons from one molecule to another. B. attracting a lone pair of electrons to the positive charge of a hydrogen. C. inducing temporary dipoles that attract each other. D. sharing electrons between atoms.
Van der Waals forces hold molecules together by inducing temporary dipoles that attract each other. That is option C
Van Der Waals forces are example of those intermolecular forces which are weaker than ionic and covalent bonds that exists between molecules.
Van Der Waals forces was postulated by a Dutch physicist known as Van Der Waals. He postulated the existence of weak, short-range forces of attraction, which are independent of normal bonding forces, between non-polar molecules. He came to this conclusion after studying the of real gases at low temperatures and high pressures that:
electrons in a non-polar molecule such as hydrogen are close to one nucleus as to the other, although momentary concentration at one end of the molecule may occur, this momentary concentration of electron cloud on one side create a temporary dipole in the hydrogen molecule, that is, one side of the molecule acquires a partial negative charge while the other side acquires a partial positive charge of equal magnitude, the temporary dipole induces a similar dipole in an adjacent behavior molecule, this results in a temporary dipole-induced dipole attraction between the positive and negative ends of the adjacent molecules.This is how weak Van Der Waals forces are set up. Therefore, option C is CORRECT
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An antacid tablet weighing 1.30g was fully neutralized at 42.00 mL(an excess amount) of 0.250MHCl. 10.00 mL of 0.100 M NaOH was then used to back titrate the excess HCl. How many moles of acid did the antacid neutralize
Answer:
0.0095 moles of acid were neutralized by the antiacid
Explanation:
The antiacid is a base that neutralize the acid in stomach. To find the moles of acid neutralized we need to find the moles of acid added initially. This acid is added in excess, then, the moles of NaOH added reacts to neutralize the moles of acid in excess. The difference between initial moles of HCl and moles of NaOH needed to titrate the excess = Moles of HCl that were neturalized by the antiacid as follows:
Moles HCl added:
42.00mL = 0.04200L * (0.250mol/L) = 0.0105 moles HCl
Moles NaOH to titrate the excess:
10.00mL = 0.01000L * (0.10mol/L) = 0.0010 moles NaOH = Moles HCl in excess.
Moles of acid that were neutralized:
0.0105 moles - 0.0010 moles =
0.0095 moles of acid were neutralized by the antiacidwhat is the IUPAC name of 2NaOH(s)
Answer:
NaoH= sodium hydroxide
Which subshells are found in each of the following shells
electron subshell - M shell
Answer:
3
Explanation:
The electron shells are labelled as K,L,M,N,O,P, and Q or 1,2,3,4,5,6, and 7.
As we go from innermost shell outwards, this number denotes the number of subshell in the shell. Electrons in outer shells have higher average energy and travel farther from the nucleus than those in inner shells.
Hence, M shell contains s,p and d subshells.
Compare the modern (electron cloud) model of the atom with Bohr’s atomic model. Which of these statements describe the two models correctly? Check all of the boxes that apply.
A. Bohr’s model was replaced only because of its age.
B. Bohr’s model electrons cannot exist between orbits, but in the electron cloud model the location of the electrons cannot be predicted.
C. The modern model explains all available data about atoms; Bohr’s model does not.
D. The modern model is more widely accepted because it was proposed by more well known scientists.
Answer:
B. Bohr’s model electrons cannot exist between orbits, but in the electron cloud model, the location of the electrons cannot be predicted.
AND
C. The modern model explains all available data about atoms; Bohr’s model does not.
Explanation:
The answers are right on Edge. :)
Answer:
b and c
Explanation:
my assignment was 100% 2022
1. A
a stiff structure that surrounds and
protects a coll: found in plant, fungus, and some bacteria cells.
2.
is living things consisting of many cells.
3.
a green pigment that traps energy
from the sun.
the process in which plants and
some other organisms use the energy in sunlight to make food.
5. A
found in the nucleus of a cell,
a long nucleic acid molecule containing the genetic instructions
for the development and functioning of all living organisms.
Answer:
1 cell wall
2 yes
3 chloroplast
4 photosynthesis
5 Deoxyribonucleic acid (I believe)
hope this helped a little and pls mark brainiest if it did :)
Explanation:
The cell wall is a rigid layer that is found outside the cell membrane and surrounds the cell, providing structural support and protection.
1. Draw the condensed structural formula of sodium benzoate showing all charges, atoms including any lone pairs in the side chain functional group, and all sigma and pi bonds.
2. Draw the condensed structural formula of benzoic acid showing all atoms including any lone pairs in the side chain functional group, and all sigma and pi bonds. Indicate the acidic hydrogen.
3. Draw the condensed structural formula of tetrahydrofuran (THF) showing all heteroatoms plus their lone pairs and all sigma and pi bonds.
The structures are shown in the image attached.
A structural formula is the representation of the molecule in which all atoms and bonds in the molecule are shown.
Since the question requires that all the lone pairs, formal charges and sigma and pi bonds should be shown, then the simple condensed structural formula becomes insufficient in this case.
I have attached images of the structural formula of sodium benzoate (image 1), benzoic acid (image 2) and tetrahydrofuran (image 3).
All the formal charges, lone pairs as well as sigma and pi bonds are fully shown.
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the nutrition label on rice lists the amounts of protein, carbohydrates and fats in one serving. these substances are important for human nutrition
Answer:
Carbohydrates, proteins, and fats are biological macromolecules that are made up of chemical elements which are inherent to chemistry.
Chemistry explain how these macromolecules are bonded together at the molecular level and give an explanation for their behavior.
Explanation:
Another method for creating a buffer, in situ, is to add an appropriate amount of a strong base, e.g., NaOH, to a weak acid OR add an appropriate amount of a strong acid, e.g., HNO3, to a weak base. As an example, mixing 1.0 mol of acetic acid with 0.5 mol of NaOH will result in a buffer solution with 0.5 mol of acetic acid and 0.5 mol of acetate. The acetate is created by the reaction of acetic acid and the strong base, hydroxide. Given this information, which of the following, when mixed with the appropriate amount of HCl, would create a buffer solution?
a. HNO3
b. HClO2
c. LiCl
d. NH3
Answer:
As an example, mixing 1.0 mol of acetic acid with 0.5 mol of NaOH will result in a buffer solution with 0.5 mol of acetic acid and 0.5 mol of acetate. The acetate is created by the reaction of acetic acid and the strong base, hydroxide.
When HClO2 is mixed with the appropriate amount of HCl it would create a buffer solution. That is option B.
Methods used to form buffer solutionA buffer solution is the solution that resists a change in pH of a solution when acid or base is added because it is made up of weak acid and the conjugate base or weak base and the conjugate acid.
The methods that can be used to form a buffer solution include:
Adding a strong base to a weak acid: For example, mixing 1.0 mol of acetic acid with 0.5 mol of NaOH will result in a buffer solution with 0.5 mol of acetic acid and 0.5 mol of acetate.Adding a weak acid to a conjugate base: For example HCl is a strong acid which will react with a conjugate base such as HClO2.Although HCl is a strong acid, it can be converted to a weak acid through dilution with water. It is in this context that it can be used to form a buffer solution.
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For the following acids of varying concentrations, which are titrated with 0.50 M NaOH, rank the acids in order of least to most volume of base needed to completely neutralize the acid.
a. 0.2M H2C6H5O7
b. 0.2M H2C2O4
Answer:
0.2M H2C6H5O7 < 0.2M H2C2O4
Explanation:
A weak acid/base ionizes to a very small extent in water. Hence, if we say that a substance is a weak acid/base, its percentage of ionization in solution is very little.
More volume of a very weak acid is required to neutralize a strong base. Since NaOH is a strong base, the weaker acid among the duo will require more volume for neutralization.
Since H2C6H5O7 is a weaker acid than H2C2O4, equal concentration of the both acids will require less volume of H2C2O4 than H2C6H5O7 to neutralize 0.50 M NaOH.
H₂C₆H₅O₇ is a weaker acid than H₂C₂O₄, and will require the least volume of 0.50 M NaOH to be neutralized.
H₂C₆H₅O₇ < H₂C₂O₄
The strength of an acid is related to the value of its dissociation constant, Ka or its pKa (negative logarithm of Ka)
Strong acids have high Ka values or low pKa value, whereas weak acids have low Ka values and high pKa values.
Between two acids, the acid with a higher Ka or lower pKa values is the stronger acid.
Acids are classified as either strong or weak depending on how well it ionizes in solution to produce hydrogen ions.
Strong acids ionizes completely to produce hydrogen ions.
Weak acid ionizes partially to a varying degrees in water to produce hydrogen ions.
In neutralization reactions between acids and bases, stronger acids will require the most volume of base or alkali in order to be neutralized.
H₂C₂O₄ has a Ka value of 5.9 x 10⁻² and a pKa value of 1.23
H₂C₆H₅O₇ has a Ka value of 8.4 x 10⁻⁴ and a pKa value of 3.08
Hence H₂C₂O₄ is a stronger acid than H₂C₆H₅O₇
For equal molar concentrations of the two acids, H₂C₂O₄ will produce more hydrogen ions than H₂C₆H₅O₇, and thus, will require more volume base (0.50 M NaOH) to be neutralized.
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Which redox reaction would most likely occur if silver and copper metal were added to a solution that contained silver and copper ions?
A. Cu + Agt Cu2+ + 2Ag
B. Cu2+ + 2Ag* → Cu + 2Ag
C. Cu2+ + 2Ag → Cu + 2Ag+
D. Cu + 2Ag Cu²+ + 2Ag+
give the wrong answer and I'm reporting
Answer:
B
Explanation:
b/c copper is readuction agent
The most likely redox reaction that would occur if silver and copper metal were added to a solution that contained silver and copper ions is [tex]\rm Cu^{2+} + 2Ag \rightarrow Cu + 2Ag^+[/tex]. The correct answer is option C.
Redox reaction is a reaction in which reduction and oxidation takes place simultaneously.
In this reaction:
[tex]\rm Cu^{2+} + 2Ag \rightarrow Cu + 2Ag^+[/tex]
Copper metal has a higher reduction potential than silver metal, which means that it will be oxidized to [tex]\rm Cu^{2+}[/tex] ions before silver metal is oxidized to [tex]\rm Ag^+[/tex] ions.
The [tex]\rm Cu^{2+}[/tex] ions in the solution will then react with the silver metal to form [tex]\rm Ag^+[/tex] ions and Copper metal. This reaction is an example of a displacement reaction, where a more reactive metal removes a less reactive metal from its compound.
Therefore, option C. [tex]\rm Cu^{2+} + 2Ag \rightarrow Cu + 2Ag^+[/tex] is the correct answer.
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When comparing Be2 and H2:
I. Be2 is more stable because it contains both bonding and antibonding valence electrons.
II. H2 has a higher bond order than Be2.
III. H2 is more stable because it only contains 1s electrons.
IV. H2 is more stable because it is diamagnetic, whereas Be2 is paramagnetic
a. II,III,IV
b.II,III
c.III only
d.I,II
e.III,IV.
Answer:
The answer is "Option b".
Explanation:
H2 does have bond energy of 1, while Be2 has a covalent bond of zero. Be2 has eight electrons, each of which dwells in a distinct orbital. As just a result, four of them are linked molecular orbitals and two are antibonding molecular orbitals, respectively. As just a result, this molecule is unstable. This chemical orbital, with a bond order of 1, has just two electrons. As a result, it is a very solid substance. H2's bond length is higher than Be2's. Since it only has one electron, H2 is more stable than that of other compounds.
11 Explain how you would obtain solid lead carbonate from a mixture of lead carbonate and sodium chloride
Explanation:
Add water, Na2CO3 dissolves, filter, PbCO3 stays in the paper and dissolved Na2CO3 goes through as the solution. Dry the PbCO3 and you have the dry solid.
OR
Add water to dissolve then filter to obtain PbCo3 as you're residue and Na2Co3 as the filtrate. Dry the insoluble PbCo3 between filter papers and you obtain solid PbCo3
Calculate the pH of each solution.
A. 0.18 M CH3NH2
B. 0.18 M CH3NH3Cl
C. a mixture of 0.18 M CH3NH2 and 0.18 M CH3NH3Cl
Answer:
See Explanations
Explanation:
pH =-log[H₃O⁺] = -log[H⁺]
pOH = -log[OH⁻]
For weak acids [H⁺] = SqrRt(Ka·[Acid])
For weak bases [OH⁻] = SqrRt(Kb·[Base])
pH + pOH = 14
__________________________________________
A. Given 0.18M CH₃NH₂; Kb = (4.4 x 10⁻⁴)* => pH = 11.95
CH₃NH₂ + H₂O => CH₃NH₃OH ⇄ CH₃NH₃⁺ + OH⁻;
[OH⁻] = SqrRt(Kb·[weak base]) = SqrRt(4.4 x 10⁻⁴ x 0.18)M = 8.97 x 10⁻³M
=> pOH = -log[OH⁻] = -log(8.93x10⁻³) = -(-2.05) = 2.05
=> pH = 14 - pOH = 14 - 2.05 = 11.95.
*Kb values for most ammonia derivatives in water can be found online by searching 'Kb-values for weak bases'. Kb-values for methyl amine and methylammonium chloride are both 4.4x10⁻⁴.
___________________________________________________
B. Given 0.18M CH₃NH₃Cl
In water ... CH₃NH₃Cl => CH₃NH₃⁺ + Cl⁻; Kb(CH₃NH₃Cl) = 4.4 x 10⁻⁴
Cl⁻ + H₂O => No Rxn (i.e.; no hydrolysis occurs) ... Cl⁻ does not react with H₂O.
Hydrolysis Reaction of Methylammonium Ion:
CH₃NH₃⁺ + H₂O => CH₃NH₄OH ⇄ CH₃NH₄⁺ + OH⁻
Ka' x Kb = Kw => Ka' = Kw/Kb = 10⁻¹⁴/4.4 x 10⁻⁴ = 2.27 x 10⁻¹¹ Ka' = [CH₃NH₄⁺][OH⁻]/[CH₃NH₄OH] = (x)(x)/(0.18M) = (x²/0.18M) = 2.27 x 10⁻¹¹ => x = [OH⁻] = SqrRt(2.27x10⁻¹¹ x 0.18)M = 2.02 x 10⁻⁶M => pOH = -log(2.02 x 10⁻⁶) = -(-5.69) = 5.69 => pH = 14 - pOH = 14 - 5.69 = 8.31.
*note => the general nature of halide interactions would increase acidity (lower pH) of the halogenated compound.
C. A mixture of 0.18M CH₃NH₂ and 0.18M CH₃NH₃Cl
Mixture of 0.18M CH₃NH₂ + 0.18M CH₃NH₃Cl
In Water ...
=> 0.18M CH₃NH₃OH + 0.18M CH₃NH₃Cl
=> 0.18M CH₃NH₃⁺ + 0.1M OH⁻ + 0.18M CH₃NH₃⁺ + 0.18M Cl⁻
=> 0.36M CH₃NH₃⁺ + 0.18M OH⁻ + 0.18M Cl⁻
-----------------------------------------------------------
Ka'(CH₃NH₃⁺) x Kb(CH₃NH₂) = Kw => Ka'(CH₃NH₃⁺) = Kw/Kb(CH₃NH₂)
=> Ka'(CH₃NH₃⁺) = (10⁻¹⁴/4.4x10⁻⁴) = 2.27x10⁻¹¹
----------------------------------------------------------
From the 0.36M CH₃NH₃⁺
=> CH₃NH₃⁺ + H₂O ⇄ CH₃NH₄⁺ + OH⁻
C(eq) 0.36M ---- x x (<= at equilibrium after mixing)
Ka'(CH₃NH₃⁺) = [CH₃NH₄⁺][OH⁻]/[CH₃NH₃⁺] = x²/(0.36M)
=> x = [OH⁻] = SqrRt(Ka'(CH₃NH₃⁺)·0.36M) = SqrRt(2.27x10⁻¹¹/0.36) = 0.0126M
=> Total [OH⁻] = 0.0126M + 0.18M = 0.1926M from hydrolysis process
=> final solution mix is therefore, 0.1926M in OH⁻ + 0.18M in Cl⁻
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Cl⁻ + H₂O => No Rxn (Cl⁻ does not react with H₂O)The 0.1926M in OH⁻ => [H⁺] = Kw/[OH⁻] = (10⁻¹⁴/0.1926)M = 5.192 x 10⁻¹⁴M in H₃O⁺ ions (= H⁺ ions) ...∴pH = -log[H⁺] = -log(5.192x10⁻¹⁴) = -(-13.29) = 13.29 for solution mix
The acid and base dissociation constant and the 0.18 M of CH₃NH₂ and
CH₃NH₃Cl and the mixture give the following approximate values;
A. The pH value of the 0.18 M CH₃NH₂ is 11.93
B. The pH value of the 0.18 M CH₃NH₃Cl is 5.69
C. The pH value of the mixture is 10.644
Which method can be used to calculate the pH values?A. 0.18 M CH₃NH₂
The solution is presented as follows;
CH₃NH₂ + H₂O → CH₃NH₃⁺ + OH⁻
Let x represent the number of moles of CH₃NH₃⁺ and OH⁻ produced, we
have;
The number of moles of CH₃NH₂ remaining = 0.18 - x
Which gives;
[tex]K_b = \mathbf{\dfrac{[CH_3NH_3^+][OH^-]}{[CH_3NH_2]}}[/tex]
[tex]K_b[/tex] for CH₃NH₂ = 4.167 × 10⁻⁴
Therefore;
[tex]4.167 \times 10^{-4} = \mathbf{\dfrac{x \times x}{0.18 - x}}[/tex]
4.167 × 10⁻⁴ × (0.18 - x) = x²
4.167 × 10⁻⁴ × (0.18 - x) - x² = 0
Which gives;
x = [OH⁻] = 8.455 × 10⁻³
pH = 14 + log[OH⁻]
Which gives;
pH = 14 + log(8.455 × 10⁻³) ≈ 11.93
B. 0.18 M CH₃NH₃Cl
The solution is presented as follows;
CH₃NH₃⁺ → CH₃NH₂ + H⁺
Let x represent the number of moles of CH₃NH₂ and H⁺ produced,
respectively, we have;
The number of moles of CH₃NH₃⁺ remaining = 0.18 - x
Which gives;
[tex]K_a = \mathbf{\dfrac{[CH_3NH_2][H^+]}{[CH_3NH_3^+]}}[/tex]
Kₐ for CH₃NH₃Cl = 2.27 × 10⁻¹¹
Therefore;
[tex]2.27\times 10^{-11} = \dfrac{x \times x}{0.18 - x}[/tex]
2.27 × 10⁻¹¹ × (0.18 - x) = x²
2.27 × 10⁻¹¹ × (0.18 - x) - x² = 0
Which gives;
x = [H⁺] ≈ 2.02 × 10⁻⁶
pH = -log[H⁺]
Which gives;
pH = -log(2.02 × 10⁻⁶) ≈ 5.69
C. For the mixture of 0.18 M CH₃NH₂ and 0.18 M of CH₃NH₃Cl, we have;
Based on the Henderson-Hasselbalch equation, we have;
[tex]pH = \mathbf{ pKa + log\dfrac{[Conjugate \ base]}{[acid ]}}[/tex]
Which gives;
[tex]pH = -log\left(2.27 \times 10^{-11} \right)+ log\dfrac{0.18}{0.18} \approx \underline{10.644}[/tex]
Learn more about Henderson-Hasselbalch equation here:
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Which statement describes the 3d, 4s, and 4p orbitals of Arsenic (As) based on its electronic configuration and position in the periodic table?
The 3d and 4s orbitals are completely filled, and the 4p orbital is partially filled.
The 3d orbital is completely filled, and the 4s and 4p orbitals are partially filled.
The 3d, 4s, and 4p orbitals are completely filled.
The 3d, 4s, and 4p orbitals are partially filled.
Answer:
The 3d and 4s orbitals are completely filled, and the 4p orbital is partially filled.
Explanation:
The correct answer is: The 3d and 4s orbitals are completely filled, and the 4p orbital is partially filled.
The d orbital contains 10 electrons, the s orbital takes 2 electrons and the p orbital takes six electrons.
The orbital in chemistry is defined as a region in space where there is a high probability of finding an electron. There are s, p, d, f orbitals in chemistry which correspond to sharp, principal, diffuse and fundamental.
The electronic configuration of arsenic is 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p3.
From this electronic configuration, we can see that the 4s and 3d orbitals are half filled while the 4p orbital is half filled.
For more about electronic configuration, see:
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