Why the catalytic and optical properties of nanomaterial are different from bulk material

Answers

Answer 1

Answer:

The material properties of nanostructures are different from the bulk due to the high surface area over volume ratio and possible appearance of quantum effects at the nanoscale. ... Yu; they found that the structural distortions on the quantum dots depend both on the kind of dopant and on the size of the dots.

Explanation:

hope it helps


Related Questions

The first law of thermodynamics defines chemical energy. defines entropy. is a statement of conservation of energy. provides a criterion for the spontaneity of a reaction.

Answers

Answer: The first law of thermodynamics is a statement of conservation of energy.

Explanation:

According to the first law of thermodynamics, heat provided to a system is actually the sum of internal energy and work done by the system or on the system.

Mathematically, [tex]\Delta Q = \Delta U + \Delta W[/tex]

The first law of thermodynamics also means that energy can neither be created nor it can be destroyed. Hence, energy is conserved.

Thus, we can conclude that the first law of thermodynamics is a statement of conservation of energy.

The chemical formula is different from the empirical formula in

Answers

Answer:be careful and relax

Explanation:

Answer:

Hahaha be careful and relax

1. Calculate the number of moles of aluminum, sulfur, and oxygen atoms in 8.00 moles of aluminum sulfate, Al2(SO4)3. 2. Calculate the number of moles of magnesium, chlorine, and oxygen atoms in 6.10 moles of magnesium perchlorate, (Mg(CIO4)2.3. A sample of propane, C3H8, contains 13.8 moles of carbon atoms. How many total moles of atoms does the sample contain?4. A rare gold coin (24 karat, or 100% gold) has a mass of 25.54 g. How many atoms of gold are present in this coin?

Answers

Answer:

1) 16.0 moles Al

24.0 moles S

96.0 moles O

2)In 6.10 moles magnesium perchlorate, (Mg(CIO4)2 we have:

6.10 moles Mg

12.2 moles Cl

48.8 moles O

3)4.6 moles of propane (total) contains 13.8 moles of carbon and 36.8 moles of hydrogen atoms

4)The gold coin contains 7.8 *10^22 atoms

Explanation:

Step 1: Data given

Number of moles of aluminum sulfate, Al2(SO4)3 = 8.00 moles

Step 2: Calculate the number of moles

In 1 mol of aluminum sulfate, Al2(SO4)3 we have:

2 moles of Al

3 moles of S

12 moles of O

This means that in 8.00 moles of aluminum sulfate, Al2(SO4)3 we have:

2*8.00 = 16.0 moles Al

3*8.00 = 24.0 moles S

12*8 = 96.0 moles O

2. Calculate the number of moles of magnesium, chlorine, and oxygen atoms in 6.10 moles of magnesium perchlorate, (Mg(CIO4)2

1 mol of magnesium perchlorate, (Mg(CIO4)2 has:

1 Mol of Mg

2 moles of Cl

8 moles of O

In 6.10 moles magnesium perchlorate, (Mg(CIO4)2 we have:

1 * 6.10 moles = 6.10 moles Mg

2*6.10 = 12.2 moles Cl

8*6.10 = 48.8 moles O

3. A sample of propane, C3H8, contains 13.8 moles of carbon atoms. How many total moles of atoms does the sample contain?

In 1 mol of propane, C3H8 we have:

3 moles of C and 8 moles of H

This means if we have 13.8 moles of carbon, we have 13.8/3 = 4.6 moles of propane, C3H8 and 4.6 *8 = 36.8 moles of H

So 4.6 moles of propane contains 13.8 moles of carbon and 36.8 moles of hydrogen atoms

4. A rare gold coin (24 karat, or 100% gold) has a mass of 25.54 g. How many atoms of gold are present in this coin?

Calculate moles of gold:

Moles = mass of gold / molar mass gold

Moles = 25.54 grams / 196.97 g/mol

Moles = 0.1297 moles

Calculate atoms:

Number of atoms = moles * number of Avogadro

0.1297 * 6.022 *10^23 = 7.8 *10^22 atoms

The gold coin contains 7.8 *10^22 atoms

Please help me ASAP I’ll mark Brainly

Answers

Answer:

cell

chloroplast and cell wall

nucleus

life processes

cell membrane

shape and size

vacuole

Hope it helps

Many home barbeques are fueled with propane gas (C3H8)(C3H8). Part A What mass of carbon dioxide is produced upon the complete combustion of 27.9 LL of propane (the approximate contents of one 5-gallon tank)

Answers

Answer:

41264 g of CO₂

Explanation:

Combustion reaction is:

C₃H₈ + 5O₂ →  3CO₂  +  4H₂O

1 mol of propane react to 5 moles of oxygen in order to proudce 3 moles of carbon dioxide and 4 moles of water.

In a combustion reaction, our reactant reacts to oxygen and the products are always CO₂ and water.

We have the volume of propane but we need moles of it, so we need to apply density.

Density = mass / volume so mass = density . volume.

Density of propane is: 493 g/L

Mass of propane is 493 g/L . 27.9L = 13754.7 g

We convert mass to moles: 13754.7 g . 1 mol/ 44g = 312.6 moles

According to reaction, 1 mol of propane can produce 3 moles of CO₂

Our 312.6 moles will produce 312.6 . 3 = 937.8 moles

We convert moles to mass: 937.8 mol . 44 g/mol = 41264 g

Calculate the average atomic mass for X

Answers

Answer:

39.0229 amu

Explanation:

Hello there!

In this case, according to given information, the idea here is to multiply the percent abundance by the mass number of each isotope and then add them all together as shown below:

[tex]=0.0967*38+0.7868*39+0.1134*40+0.0031*41\\\\=3.6746+30.6852+4.536+0.1271\\\\=39.0229amu[/tex]

Regards!

Perform the following operation and express the answer in scientific notation.
7.296×10² ÷ 9.6×10^-9

Answers

Answer:

7.6×10¹⁰

Explanation:

7.296×10²÷9.6×10⁻⁹

To solve such problem,

We group the whole number ans solved seperately and also group the indices and solve the seperately

Step1 : 7.296/9.6 = 0.76

Step 2: applying the law of indices,

10²÷10⁻⁹ = 10⁽²⁺⁹⁾ = 10¹¹

Therefore,

7.296×10²÷9.6×10⁻⁹ = 0.76×10¹¹ = 7.6×10¹⁰

The data shows the number of years that 30 employees worked for an insurance company before retirement. is the population mean for the number of years worked, and % of the employees worked for the company for at least 10 years. (Round off your answers to the nearest integer.)

Answers

Answer:

14

73%

Explanation:

The mean Number of years worked :

. (sum of service years) / employees in the

(8+13+15+3+13+28+4+12+4+26+29+3+10+3+17+13+15+15+23+13+12+1+14+14+17+16+7+27+18+24) /

(417 / 30)

= 13.9 years

= 14 years

The percentage of employees who have worked for atleast 10 years :

Number of employees with service years ≥ 10 years = 22 employees

Total number of employees

Percentage (%) = (22 / 30= * 100% = 0.7333 * 100% = 73.33% = 73%

Question 16(Multiple Choice Worth 5 points)

(04.01 LC) Which statement is true about the total mass of the reactants during a chemical change?

O It is destroyed during chemical reaction.
O It is less than the total mass of the products. O It is equal to the total mass of the products.
O It is greater than the total mass of the products.​

Answers

Answer:

It is equal to the total mass of the products.

Explanation:

Hope this helps :)

8.7 Two products are formed in the following reaction in a 50:50 mixture. Would the resulting solution be optically active

Answers

Answer:

Yes. The solution would be optically active.

Explanation:

Diastereomer are defined as the image that is non mirror and non -identical. It is made up of two stereoisomers. They are formed when the two stereoisomers or more than two stereoisomers of the compound have the same configuration at the equivalent stereocenters.

In the given context, as the product given is a diastereomeric mixture, the product would have an optical activity in total.

So the answer is Yes.

Identify the intermolecular attractions for dimethyl ether and for ethyl alcohol. Which molecule is expected to be more soluble in water? Explain.

Answers

Answer:

See explanation

Explanation:

All molecules possess the London dispersion forces. However London dispersion forces is the only kind of intermolecular interaction that exists in nonpolar substances.

So, the only kind of intermolecular interaction that exists in dimethyl ether is London dispersion forces.

As for ethyl alcohol, the molecule is polar due to the presence of polar O-H bond. In addition to London dispersion forces, dipole-dipole interactions and specifically hydrogen bonding also occurs between the molecules.

Because ethyl alcohol is polar, it is more soluble in water than dimethyl ether.

Methyl orange can change color by transitioning from one chromophore to another. When added to a clear solution and the solution turns red, it is determined to be a(n) __________ in its __________ stable form.

Answers

Answer:

acidic titration in its stable form

Explanation:

Methyl orange can change its color in titration solution. The yellow color is towards alkaline solution and red color is towards acidic solution. The Ph value of solution will change during this chemical process.

what is the mass of insoluble calcium phosphate produced from .555 grams of calcium chloride​

Answers

Answer:

0.518 g

Explanation:

Step 1: Write the balanced equation

3 CaCl₂ + 2 H₃PO₄ ⇒ Ca₃(PO₄)₂ + 6 HCl

Step 2: Calculate the moles corresponding to 0.555 g of CaCl₂

The molar mass of CaCl₂ is 110.98 g/mol.

0.555 g × 1 mol/110.98 g = 5.00 × 10⁻³ mol

Step 3: Calculate the moles of Ca₃(PO₄)₂ produced

5.00 × 10⁻³ mol CaCl₂ × 1 mol Ca₃(PO₄)₂/3 mol CaCl₂ = 1.67 × 10⁻³ mol Ca₃(PO₄)₂

Step 4: Calculate the mass corresponding to 1.67 × 10⁻³ moles of Ca₃(PO₄)₂

The molar mass of Ca₃(PO₄)₂ is 310.18 g/mol.

1.67 × 10⁻³ mol × 310.18 g/mol = 0.518 g

Give the following reaction: ammonium nitrate—> dinitrogen monoxide + water.
a.) Write a complete balanced chemical equation.
b.) Calculate the number of molecules of water produced by 11.2g of ammonium nitrate

Answers

Answer:

a) NH₄NO₃ ⇒ N₂O + 2 H₂O

b) 1.69 × 10²³ molecules

Explanation:

Step 1: Write the balanced equation

NH₄NO₃ ⇒ N₂O + 2 H₂O

Step 2: Convert 11.2 g of NH₄NO₃ to moles

The molar mass of NH₄NO₃ is 80.04 g/mol.

11.2 g × 1 mol/80.04 g = 0.140 mol

Step 3: Calculate the moles of H₂O produced

0.140 mol NH₄NO₃ × 2 mol H₂O/1 mol NH₄NO₃ = 0.280 mol H₂O

Step 4: Calculate the number of molecules in 0.280 moles of water

We will use Avogadro's number.

0.280 mol × 6.02 × 10²³ molecules/1 mol = 1.69 × 10²³ molecules

17. The density of a population would influence which limiting factor?
O niche
O growth rate
O weather
O space

Answers

Answer:

The answer is growth rate

Explanation:

it will help you

an emerald can be described as...

Answers

Answer:

green gemstone

Explanation:

hope this helps someone

A
(c) 2 C(s) + MnO2(s)
Mn(s) + 2 CO(g)
O combination reaction
O decomposition reaction
O combustion reaction
O single-displacement reaction

Answers

Answer: The reaction, [tex]2C(s) + MnO_{2}(s) \rightarrow Mn(s) + 2CO(g)[/tex] is a single-displacement reaction.

Explanation:

A chemical reaction in which one element of a compound is replaced by another element participating in the reaction.

For example, [tex]2C(s) + MnO_{2}(s) \rightarrow Mn(s) + 2CO(g)[/tex]

Here, the element manganese is replaced by carbon atom. As only one element gets replaced so, it is a single-displacement reaction.

Thus, we can conclude that [tex]2C(s) + MnO_{2}(s) \rightarrow Mn(s) + 2CO(g)[/tex] is a single-displacement reaction.

One main difference between the heating of gases on the one hand and solids or liquids on the other is that ___________________. One main difference between the heating of gases on the one hand and solids or liquids on the other is that ___________________. heating of gases depends not only on the temperature difference, but also on the process as well as the amount of gas present. heating of gases depends on temperature difference as well as the amount of gas present. specific heat is not defined for gases. heat cannot be exchanged with gases.

Answers

Answer:

heating of gases depends not only on the temperature difference, but also on the process as well as the amount of gas present.

Explanation:

The work done when a gas is heated does not only depends on the initial and final states of the gas but also on the process used to achieve the change of state of the gas.

Several processes can be applied in changing the state of a gas such as; adiabatic process, isobaric process, isochoric process and isothermal process.

Hence, the heating of a gas, depends not only on the temperature difference, as well as the amount of gas present according to the ideal gas laws but also on the process used to achieve the change of state.

What mass of steam initially at 120oC is needed to warm 200g of water in a glass container from 20.0 oC to 50.0 oC

Answers

Complete question:

What mass of steam initially at 120 ⁰C is needed to warm 200g of water in a 100 g glass container from 20.0 oC to 50.0 ⁰C

Answer:

the initial mass of the steam is 10.82 g

Explanation:

Given;

mass of water, m₁ = 200 g

mass of the glass, m₂ = 100 g

temperature of the steam = 120 ⁰C

initial temperature of the water, 20⁰ C

final temperature of the water, = 50⁰ C

let the mass of the steam = m

specific heat capacity of water c = 1 cal/g ⁰ C

specific heat capacity of glass c₂ = 0.2 cal/g ⁰ C

laten heat of vaporization of steam L = 540 cal/g

Apply principle of conservation energy;

Heat given off by the steam = Heat absorbed by water + heat absorbed by glass

[tex]mc\Delta T_1 + mL + mc\Delta T_2 = m_1c\Delta T_3 + m_2c_2\Delta T_3\\\\mc\Delta T_1 + mL + mc\Delta T_2 = [m_1c + m_2c_2]\Delta T_3[/tex]

m(1) (120 - 100)  +  m(540)  + m(1) (100 - 50) = [200(1)  +  100(0.2)] (50 - 20)

20m + 540m + 50m = 6600

610 m = 6600

m = 6600 / 610

m = 10.82 g

Therefore, the initial mass of the steam is 10.82 g

define saturated and unsaturated fats​

Answers

Answer:

unsaturated fats, which are liquid at room temperature,are different from saturated fat because they contain one or more double bonds and fewer hydrogen atoms on their carbon chain.

The position of the equilibrium for a system where K = 6.4 × 10 9 can be described as being favoring ________________

Answers

Answer:

to the right (products side)

Explanation:

The equilibrium constant K describes the ratio between the concentration of products and reactants at equilibrium. For a general reaction:

a A + b B → c C + d D

The equilibrium constant expression is:

[tex]K = \frac{[C]^{c} [D]^{d} }{[A]^{a} [B]^{b} }[/tex]

A low value of K indicates that the concentration of products (C and D) is low in relation with the concentration of reactants (A and B).

Conversely, a high value of K indicated that the concentration of products is high compared with the concentration of reactants.

Since K = 6.4 × 10⁹ is a high value, the concentration of products is higher than the concentration of reactants at equilibrium. Thus, the position of the equilibrium is favored to the right.

Calculate the volume in liters of a 1.60 mol/L sodium nitrate solution that contains of sodium nitrate . Round your answer to significant digits.

Answers

Answer:

1.5L of NaNO3 must be present

Explanation:

That contains 200g of sodium nitrate. Round to 2 significant digits

To solve this question we need to convert the mass of NaNO3 to moles using its molar mass (85g/mol). With the moles and the molar concentration we can find the volume in liters of the solution:

Moles NaNO3:

200g * (1mol / 85g) = 2.353 moles NaNO3

Volume:

2.353 moles NaNO3 * (1L / 1.60moles) =

1.5L of NaNO3 must be present

g A sample of chlorine gas starting at 681 mm Hg is placed under a pressure of 991 mm Hg and reduced to a volume of 513.7 mL. What was the initial volume, in mL, of the chlorine gas container if the process was performed at constant temperature?

Answers

Answer:

747.5 mL

Explanation:

Assuming ideal behaviour, we can solve this problem by using Boyle's law, which states that at constant temperature:

P₁V₁ = P₂V₂

Where in this case:

P₁ = 681 mm HgV₁ = ?P₂ = 991 mm HgV₂ = 513.7 mL

We input the data given by the problem:

681 mm Hg * V₁ = 991 mm Hg * 513.7 mL

And solve for V₁:

V₁ = 747.5 mL

Calculate the moment of inertia of a CH³⁵CL₃ molecule around a rotational axis that contains the C-H bond. The C-Cl bond length is 177pm and the HCCl angle is 107⁰f​

Answers

Answer:

The correct answer is "[tex]4.991\times 10^{-45} \ kg.m^2[/tex]".

Explanation:

According to the question,

[tex]R_{C-Cl} = 177 \ pm[/tex]

or,

         [tex]=1.77\times 10^{-10} \ m[/tex]

[tex]\alpha = 107^{\circ}[/tex]

[tex]m_{Cl}=34.97 \ m.u[/tex]

or,

      [tex]=34.97\times 1.66\times 10^{-27}[/tex]

      [tex]=5.807\times 10^{-26} \ kg[/tex]

The moment of inertia around the rotational axis will be:

⇒  [tex]I=3\times m_{Cl}\times (R_{C-Cl})^2 \ Sin^2 \alpha[/tex]

By putting the values, we get

       [tex]=3\times 5.807\times 10^{-26}\times (1.77\times 10^{-10})^2 \ Sin^2 (107)[/tex]

       [tex]=3\times 5.807\times 10^{-26}\times (1.77\times 10^{-10})^2\times 0.91452[/tex]

       [tex]=4.991\times 10^{-45} \ kg.m^2[/tex]

In a closed system, If a gas is transported to a container with double the volume of the previous container, the gas was held in, what is the gases' new volume?

The volume of the gas is fixed and will not change.
The volume of the gas will be half the original volume.
The volume of the gas will be the original volume squared.
The volume of the gas will be double the original volume.

Answers

Answer:

The volume of the gas is fixed and will not change.

Explanation:

The volume of the gas will not change because there is no change in temperature. Temperature increases the volume of gases enclosed in a container.

Sugar is added to water and initially completely dissolves, but eventually solid sugar collects on the bottom of the container. Sugar and water are ________partially miscible . This produces a dynamic equilibrium. Ethanol (a liquid) is added to water and only a single layer is observed no matter how much ethanol is added. Ethanol and water are__________

Answers

Answer: Sugar is added to water and initially completely dissolves, but eventually solid sugar collects on the bottom of the container. Sugar and water are both partially miscible. This produces a dynamic equilibrium. Ethanol (a liquid) is added to water and only a single layer is observed no matter how much ethanol is added. Ethanol and water are miscible.

Explanation:

When a substance (solute) dissolves partially in a solvent then it is known as partially miscible in the solvent. In such cases, a small amount of solute remains at the bottom of solution.

If a solute dissolves completely in solvent like water such that only one layer is seen in the solution then it means that the solute is miscible in solvent.

Thus, we can conclude that sugar is added to water and initially completely dissolves, but eventually solid sugar collects on the bottom of the container. Sugar and water are both partially miscible. This produces a dynamic equilibrium. Ethanol (a liquid) is added to water and only a single layer is observed no matter how much ethanol is added. Ethanol and water are miscible.

14 protons,14 electrons and 14 neutrons

Answers

The answer is silicon.

the answer is silicon!!

Based on the equations below, which metal is the least active? Pb(NO3)2(aq) + Ni (s) --> Ni(NO3)2 (aq)+ Pb(s) Pb(NO3)2(aq) + Ag(s) --> No reaction Cu(

Answers

Answer:

Ni

Explanation:

An active metal is a highly reactive metal. Active metals are found high up in the activity series.

Active metals react with other metals that are lower than them in the activity thereby displacing the lower metals from a solution of their salts. This is what may have happened in the other two reactions.

Ni is the most active metal listed in the question since it can react a compounds with Pb(NO3)2(aq) to liberate Pb metal.

Match the description with the type of precipitation being described.
1. Its formation requires very strong updrafts
2. Its formation requires falling through a layer of above freezing air
3. Precipitation from cumuliform clouds is typically of this nature
4. Precipitation from stratus clouds is typically of this nature
Options:
a. Hail
b. Drizzle
c. Shower
d. Freezing Rain

Answers

Answer:

1. Its formation requires very strong updrafts = a. Hail

2. Its formation requires falling through a layer of above-freezing air = d. Freezing Rain

3. Precipitation from cumuliform clouds is typically of this nature = c. Shower

4. Precipitation from stratus clouds is typically of this nature = Drizzle

Explanation:

Hail formation requires very strong updrafts, these updrafts are the upward moving air created in a thunderstorm. This period of noticeable thunderstorms creates hails.

Freezing rain requires the presence of warm air, it requires falling through a layer of above-freezing air to the colder air below to produce an ice coating on anything it drops on.

Showers are produced by cumuliform clouds which look like cotton balls. Since cumuliform clouds precipitate too, these clouds can have fluctuating rain in a day in the form of showers.

Drizzle which raises low visibility is considered a type of liquid precipitation since it also falls from a cloud. Drizzle which is obviously smaller in diameter when compared to that of raindrops, however, is common with stratus clouds.

I need help solving this!


For the reaction C + 2H2 → CH4, how many moles of hydrogen are needed to make 146.6 grams of methane, CH4 ?

Round your answer to the nearest tenth. If you answer is a whole number like 4, report the answer as 4.0

Use the following molar masses. If you do not use these masses, the computer will mark your answer incorrect.:

Element

Molar Mass

Hydrogen

1

Carbon

12

Answers

Answer: Moles of hydrogen required are 4.57 moles to make 146.6 grams of methane, [tex]CH_{4}[/tex].

Explanation:

Given: Mass of methane = 146.6 g

As moles is the mass of a substance divided by its molar mass. So, moles of methane (molar mass = 16.04 g/mol) are calculated as follows.

[tex]Moles = \frac{mass}{molar mass}\\= \frac{146.6 g}{16.04 g/mol}\\= 9.14 mol[/tex]

The given reaction equation is as follows.

[tex]C + 2H_{2} \rightarrow CH_{4}[/tex]

This shows that 2 moles of hydrogen gives 1 mole of methane. Hence, moles of hydrogen required to form 9.14 moles of methane is as follows.

[tex]Moles of H_{2} = \frac{9.14}{2}\\= 4.57 mol[/tex]

Thus, we can conclude that moles of hydrogen required are 4.57 moles to make 146.6 grams of methane, [tex]CH_{4}[/tex].

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