An acetic acid buffer containing 0.50 M acetic acid (CH3COOH) and 0.50 M sodium acetate (CH3COONa) has a pH of 4.74. What will the pH be after 0.0020 mol of HCl has been added to 100.0 mL of the buffer

Answers

Answer 1

Answer:

pH = 4.71

Explanation:

We can find the pH of a buffer (Mixture of weak acid: CH3COOH, and its conjugate base: CH3COONa) using H-H equation:

pH = pKa + log [CH3COONa] / [CH3COOH]

Where pH is the pH of the buffere = 4.74, pKa the pka of the buffer and [] could be taken as the moles of each reactant.

As initially [CH3COONa] = [CH3COOH], [CH3COONa] / [CH3COOH] = 1:

pH = pKa + log 1

4.74 = pKa

To solve this question we need to find the initial moles of each species, The CH3COONa reacts with HCl to produce CH3COOH. That means the moles of CH3COOH after the reaction are: Initial CH3COOH + Moles HCl

Moles CH3COONa: Initial CH3COONa - Moles HCl.

Moles CH3COOH:

0.100L * (0.50mol / L) = 0.050 moles CH3COOH + 0.0020 moles HCl =

0.052 moles CH3COOH

Moles CH3COONa:

0.100L * (0.50mol / L) = 0.050 moles CH3COONa - 0.0020 moles HCl =

0.048 moles CH3COONa

Using H-H equation:

pH = 4.74 + log [0.048 moles] / [0.052 moles]

pH = 4.71
Answer 2

The pH be after 0.0020 mol of HCl has been added to 100.0 mL of the buffer is 4.71.

What is buffer solution?

Buffer solution is a mixture of weak acid and its conjugate base or vice versa.

We can calculate the pH of buffer solution by using Henderson - Hasselbalch Equation:

pH = pKa + log[CH₃COONa] / [CH₃COOH]

Initially concentration of CH₃COONa is equal to the concentration of CH₃COOH and equal becomes:

4.74 = pKa + log(1)

pKa = 4.74

Given moles of added HCl moles = 0.002 mole

Given molarity of each CH₃COOH & CH₃COONa = 0.50M

Given Volume = 100mL

We can calculate the moles by using the formula:

n = M × V

Moles of CH₃COOH & CH₃COONa = 0.100 × 0.50 = 0.050 moles

Moles of CH₃COOH = 0.050moles CH₃COOH + 0.0020moles HCl =

0.052moles CH₃COOH

Moles of CH₃COONa = 0.050moles CH3COONa - 0.0020moles HCl =

0.048moles CH₃COONa

Now, resultant pH will be:

pH = 4.74 + log [0.048 moles] / [0.052 moles]

pH = 4.71

Hence, pH of resultant solution is 4.71.

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Related Questions

Write the balanced reaction for the methanol cannon demo that includes their Lewis structures . The reaction is the combustion of methanol (CH3OH). Include the states (s, l, g) in your balanced equation as well.

Answers

Answer:

The reaction is the combustion of methanol (CH3OH).

Write the balanced chemical equation.

Draw Lewis structures for each structure.

Explanation:

The balanced chemical equation for the combustion of methane is shown below:

[tex]2CH_3OH(g)+3O_2(g)->2CO_2(g)+ 4 H_2O(g)[/tex]

Lewis structures of the given molecules are shown below:

Can someone please please help

Answers

Answer:

oxidizer

Explanation:

an example of an oxidizers are oxygen and hydrogen peroxide

A chemist measures the amount of iodine solid produced during an experiment. He finds that of iodine solid is produced. Calculate the number of moles of iodine solid produced. Round your answer to significant digits.

Answers

The question is incomplete, the complete question is:

A chemist measures the amount of iodine solid produced during an experiment. He finds that 8.31 g of iodine solid is produced. Calculate the number of moles of iodine solid produced. Round your answer to the correct number of significant digits.

Answer: The number of moles of solid iodine produced is 0.0327 moles

Explanation:

The number of moles is defined as the ratio of the mass of a substance to its molar mass.  The equation used is:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex] ......(1)

Given mass of solid iodine = 8.31 g

Molar mass of solid iodine = 253.8089 g/mol

Plugging values in equation 1:

[tex]\text{Moles of solid iodine}=\frac{8.31g}{253.8089g/mol}=0.0327mol[/tex]

Hence, the number of moles of solid iodine produced is 0.0327 moles

Which elements are main-group elements?
1. Te
2. K
3. V
4. Re
5. Ag

Answers

Answer:

Te

K

Explanation:

Main group elements are elements designated and located on the s-block and p-block on the periodic table. The core group or prominent elements are the elements that make up those groups. These groupings comprise the most naturally rich and abundant elements. The main group elements are those whose characteristics are more predicted as a function of their periodic table location. From the given options, only Te and K are elements of the main-group.

The angular momentum quantum number (l) value of 0 indicates the ________ subshell.

Answers

Answer:

indicates the number of subshells

1. Show that heat flows spontaneously from high temperature to low temperature in any isolated system (hint: use entropy change that occurs during the process for your proof).
2. Work out the entropy change for the decomposition of mercuric oxide using mathematical and graphical arguments.

Answers

Answer:

1 ) Δs ( entropy change for hot block ) = - Q / th  ( -ve shows heat lost to cold block )

Δs ( entropy change for cold block ) = Q / tc

∴ Total Δs = ΔSc + ΔSh

                 = Q/tc - Q/th

2) ΔSdecomposition = Δh / Temp = ( 181.6 * 10^3 / 773 ) = 234.928 J/k

Explanation:

1) To show that heat flows spontaneously from high temperature to low temperature

example :

Pick two(2) solid metal blocks with varying temperatures ( i.e. one solid block is hot and the other solid block is cold )

Place both blocks for time (t ) in an insulated system to reduce heat loss or gain to or from the environment

Check the temperature of both blocks after time ( t ) it will be observed that both blocks will have same temperature after time t ( first law of thermodynamics )

Δs ( entropy change for hot block ) = - Q / th  ( -ve shows heat lost to cold block )

Δs ( entropy change for cold block ) = Q / tc

∴ Total Δs = ΔSc + ΔSh

                 = Q/tc - Q/th

2) Entropy change for Decomposition of mercuric oxide

2HgO (s) → 2Hg(l) + O₂ (g)

Δs = positive

there is transition from solid to liquid and the melting point of mercury ( the point at which reaction will take place ) = 500⁰C

hence ΔSdecomposition = S⁻ Hg  -  S⁻ HgO =

Δh of reaction = 181.6 KJ

Temp = 500 + 273 = 773 k

hence ΔSdecomposition = Δh / Temp = ( 181.6 * 10^3 / 773 ) = 234.928 J/k

PLEASE HELP QUICKLY
The diagram shows the potential energy changes for a reaction pathway. (10 points)

Part 1: Does the diagram illustrate an endothermic or an exothermic reaction? Give reasons in support of your answer.

Part 2: Describe how you can determine the total change in enthalpy and activation energy from the diagram and if each is positive or negative.

Answers

The activation energy of the reaction is the difference between the highest point on the reaction profile and the energy of the reactants.

What is a potential energy diagram?

A potential energy diagram or a reaction profile shows us the energ change between the reactants and the products.

As we look at the reaction profile, we observe that the products have a greater energy than the reactants hence the reaction is endothermic. The enthalpy chamgeis obtained by subtracting the energy of the products from the energy of the reactants.

The activation energy of the reaction is the difference between the highest point on the reaction profile and the energy of the reactants.

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For each pair of elements, indicate which one you would expect to have the greater electron affinity (E.A.) (i.e. mathematically this means the more negative value of EA):

Answers

The question is incomplete, the complete question is shown in the image attached to this answer

Answer:

1) K

2) F

3) Si

4) Br

Explanation:

If an element has a more negative value of electron affinity, then it has a greater ability to attract an electron.

In each of the following pairs of elements, one element has a more negative electron affinity for certain reasons.

Between K and Ca, the incoming electron in K goes into a 4s orbital which is lower in energy and more stable. For Ca, the electron goes into a 3d orbital which is more unstable.

Between Ne and F, Ne already has a filled outermost shell hence the incoming electron goes into the higher energy 3s level. In F, the electron goes into the 2p level and completes it. Hence F has a more negative electron affinity.

Let us recall that half filled and completely filled orbitals are exceptionally stable. Hence, the electron affinity of Si is more negative than that of P because in P, the electron goes into an exceptionally stable half filled orbital.

Recall that the more the value of Zeff, the more negative the electron affinity hence electron affinity increases across a period; hence, Br has a more negative value of electron affinity than Se.

what is the qualitative analysis of (nh4) 2co3 using NaOH, HCL, BaCL2, and AgNO3​

Answers

Answer:

qualatatiev is fs-hj_jakakak

The number of moles of aluminum that react with 15.7 grams of oxygen according to the equation 4 Al + 3 0 2 - 2 Al 20 3

Answers

Answer:

Explanation:

1mol of [tex]O_2=2*16{gr\over{mol}}=32{gr\over{mol}}\\\\15.7gr->15.7gr*{1\over{32{gr\over{mol}}}}=0.491mol~of~O_2[/tex]

as 1mol of molecular oxigen reacts with 4 mol of aluminium

1 mol of O2         -----------------------------> 4 mol of Al

0.491 mol of O2  ------------------------------>     x

[tex]x={0.491*4\over{1}}~mol~of~Al=1.9625~mol~of~Al[/tex]

What evidence supports the law of conservation of energy?

Light energy is converted to chemical energy during photosynthesis.
Oxygen is made from the breakdown of carbon dioxide during photosynthesis.
Energy is absorbed by chlorophyll during photosynthesis.
The sun gives off light energy that is absorbed by plants.

Answers

Answer:

light energy is converted to chemical energy during photosynthesis.

Explanation:

Law of conservation of energy says: Energy can neither be created nor destroyed-only converted from one form of energy to another.

Answer:

A. Light energy is converted to chemical energy during photosynthesis.

A chemist combines 33 g of methane with 289 g of oxygen to from 189 g of carbon dioxide and 30 g of water. Determine if the results of the following word problem adheres to the Law of Conservation of Mass.

Answers

Answer:

The correct answer is - no not adhere to the law of mass conservation.

Explanation:

According to the law of mass conservation in an isolated system, the mass can not be created or destroyed and in a chemical or physical change, the mass of products should be always equal to the mass of reactants.

On the basis of the law the mass of the chemical reaction-

Mass of products = mass of reactants

33 g of methane + 289g of oxygen = 189g of carbon dioxide + 30g of water

322g ≠ 219 g

which means this reaction does not adhere to the law of conservation.

A chemist measures the energy change
ΔH during the following reaction:
2NH3(g)→N2(g)+3H2(g)
ΔH=160kJUse the information to answer the following questions.This reaction is:__________.
a. endothermic
b. exothermic
Suppose 70.9 g of NH3 react. Will any heat be released or absorbed?
a. Yes, absorbed
b. Yes, released
c. No.
If you said heat will be released or absorbed in the second part of this question, calculate how much heat will be released or absorbed. Round your answer to 3 significant digits.

Answers

Answer:

For (1): The correct option is (a)

For (2): The correct option is (a) and 333.6 kJ of heat will be absorbed when 70.9 g of ammonia reacts.

Explanation:

There are 2 types of reactions that are classified based on enthalpy change:

Endothermic reactions: These are the reactions where heat is absorbed by the reaction. The change in enthalpy of the reaction, [tex]\Delta H_{rxn}[/tex] is positive for these reactions.

Exothermic reactions: These are the reactions where heat is released by the reaction. The change in enthalpy of the reaction, [tex]\Delta H_{rxn}[/tex] is negative for these reactions.

For (1):

For the given chemical reaction:

[tex]2NH_3(g)\rightarrow N_2(g)+3H_2(g);Delta H=160kJ[/tex]

As the change in enthalpy or heat of the reaction is positive. Thus, the reaction is an endothermic reaction because heat is absorbed by the reaction.

For (2):

When ammonia reacts, some amount of heat will be absorbed by the reaction. Thus, we can say the heat will be absorbed.

The number of moles is calculated by using the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex] ......(1)

Given mass of ammonia = 70.9 g

Molar mass of ammonia = 17 g/mol

Using equation 1:

[tex]\text{Moles of ammonia}=\frac{70.9g}{17g/mol}=4.17mol[/tex]

By stoichiometry of the reaction:

If 2 mole of ammonia reacts, the heat absorbed is 160 kJ

So, if 4.17 moles of ammonia reacts, the heat absorbed will be = [tex]\frac{160kJ}{2mol}\times 4.17mol=333.6kJ[/tex]

Hence, 333.6 kJ of heat will be absorbed when 70.9 g of ammonia reacts

PLEASE HELP!!!!

Which of the following lists describes characteristics of an acid? (3 points)
Bitter taste, high pH, and caustic
Sour taste, low pH, and dissolves metals
Sour taste, high pH, and dissolves metals
Slippery, low pH, and caustic

Answers

Acids have sour taste, low pH and dissolves metals.

The list that describes the characteristics of an acid is that it has sour taste, low pH, and dissolves metals.

Characteristics of an acid

An acid is a chemical substance that has the ability to donate hydrogen ions when involved in a chemical reaction.

The following are the characteristics or features of an acid:

They have a sour taste when tasted.

When measured using a pH scale it is less than 7(low pH).

They react with active metals to yield hydrogen gas.

Therefore, the list that describes the characteristics of an acid is that it has sour taste, low pH, and dissolves metals.

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When taking a measurement with a pH meter, keep the instrument in the _______storage solution or water until it is needed. Rinse the pH meter with
_______deionized water or acetone and gently pat dry. Place the meter in the sample solution, and record the measurement when the pH _______stabilizes or reaches the maximum value

Answers

Answer:

storage solution , deionized water, stabilizes

Explanation:

A pH meter is a scientific device or instrument that is used to measure the pH of a given aqueous solution thereby determining the nature of the solution whether it is acidic or basic or neutral.

While using the pH meter or taking the measurement using the pH meter --

it should be kept in a storage solution for effective working.Before using the device, it is rinsed with a deionized water and pat dry.Record the measurements when the pH meter stabilizes.

Explain what happens when water reacts with sodium metal. Support your answer with the relevant

equation.​

Answers

Sodium metal reacts rapidly with water to form a solution of sodium hydroxide (NaOH) and hydrogen gas (H2). This reaction is exothermic.

Equation:

2Na + 2H²0 --------}- 2NaOH + H²

How to calculate the actual volume (ml) of water removed from the burette with water
density 1 g/ml:
i. 5mL of water removed

Answers

Answer:

Explanation:

The density of pure water is 1 gram per 1 milliliter or one cubic cm. By knowing the density of water we can use it in dilution equations or to calculate the specific gravity of other solutions.

It can also help us determine what other substances are made of using the water displacement experiment. This is done by observing how much water is displaced when an object is submerged in the water. As long as you know the density of the water, the mass of the object being submerged and the volume of increase you can calculate the density of the object.

This was done by the great Archimedes in discovering what composed the kings crown.

Identify a process that is NOT reversible. Identify a process that is NOT reversible. melting of snow baking of bread deposition of carbon dioxide freezing water melting of aluminum

Answers

Answer:

Identify a process that is NOT reversible.

Melting of snow

baking of bread

deposition of carbon dioxide

freezing water

melting of aluminum

Explanation:

A physical change is the one in which there is a change only in its physical state, color, the appearance of the substance. But the chemical composition of the substance remains unchanged.

It is a temporary change and can be reversed easily.

For example:

melting, freezing, deposition etc.

Baking is a permanent change and the chemical composition of the substance changes.

Hence, among the given options, baking of bread is not a reversible change.

Out of the following all are physical changes except baking of bread and physical changes are reversible so the process  which is not reversible is baking of bread.

What are physical changes?

Physical changes are defined as changes which affect only the form of a substance but not it's chemical composition. They are used to separate mixtures in to chemical components but cannot be used to separate compounds to simpler compounds.

Physical changes are always reversible using physical means and involve a change in the physical properties.Examples of physical changes include melting,boiling , change in texture, size,color,volume and density.Magnetism, crystallization, formation of alloys are all reversible and hence physical changes.

They involve only rearrangement of atoms and are often characterized to be changes which are reversible.

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define saturated and unsaturated fats​

Answers

Saturated fatty acids lack double bonds between the individual carbon atoms, while in unsaturated fatty acids there is at least one double bond in the fatty acid chain. Saturated fats tend to be solid at room temperature and from animal sources, while unsaturated fats are usually liquid and from plant sources.

Answer:

hope it is helpful to you

What is the best tool for making a decorative zucchini or celery twist

Answers

Answer:

don't knoe sorry

Explanation:

Your answer is a peeler.

The length of a covalent bond depends upon the size of the atoms and the bond order.

a. True
b. False

Answers

Answer:

True

Explanation:

The length of covalent bond depends upon the size of atoms and the bond order.

Consider the balanced chemical equation below.

3 A ⟶ C + 4 D

How many moles of C would be produced if 7 moles of A were used?

Answers

Answer:

2.33 mol C

Explanation:

Step 1: Write the balanced generic chemical equation

3 A ⟶ C + 4 D

Step 2: Establish the appropriate molar ratio

According to the balanced equation, the molar ratio of A to C is 3:1.

Step 3: Calculate the number of moles of C produced from 7 moles of A

We will use the previously established molar ratio.

7 mol A × 1 mol C/3 mol A = 2.33 mol C

A product of homolytic fission can never be

a - charged

b - nucleophile

c- both

d-none of these

Answers

Answer:

both

Explanation:

A homolytic fission is said to have occurred when the breakage of a bond between two atoms leaves each of the bonding atoms with equal number of electrons. Homolytic fission often results in the creation of radicals.

Since homolytic fission yields two species with equal number of electrons(usually odd number of electrons), the products of such process can not be charged. They can not be nucleophiles because nucleophiles need to possess two electrons which can be shared with another chemical specie.

How many carbon atoms are there in 15 lbs of sugar, C12H22O11?

Answers

Answer:

A molecule of sucrose (C12H22O11) has 12 carbon atoms, 22 hydrogen atoms and 11 oxygen atoms.

Explanation:

if this does not help let me know :)

There are   1.4376  × 10²⁶ carbon atoms in 15 lbs of sugar (C12H22O11).

From the given information,

Using the standard conversion method;

1 lbs = 453.592 gram

15 lbs = (453.592 gram × 15 lbs/1 lbs)

= 6803.88 grams

Now, we will need to determine the molar mass of the sugar compound C12H22O11.

Molar mass of C12H22O11 =  (12 × 12) +(1 × 22) + (16 × 11)

Molar mass of C12H22O11 = 144 + 22 + 176

Molar mass of C12H22O11 = 342 g/mol

Using the relation:

[tex]\mathbf{Number \ of \ moles = \dfrac{mass}{molar \ mass}}[/tex]

Number of moles = [tex]\dfrac{6803.88 }{ 342}[/tex]

Number of moles of C12H22O11   = 19.894 moles

Since we've known the number of moles present in C12H22O11, the next thing to do is determine the number of molecules of sugar by using Avogadro's constant:

i.e.

number of moles of sugar = [tex]19.894 moles \times \dfrac{6.023 \times 10^{23}}{mol}[/tex]

= 1.198 × 10²⁵ molecules of C12H22O11

Now to determine the number of carbon atoms in 15 lbs, we have:

= number of carbon atoms × amount of molecules

= 12 × 1.198 × 10²⁵ carbon atoms

= 1.4376  × 10²⁶ carbon atoms

Therefore, we can conclude that there are  1.4376  × 10²⁶ carbon atoms present in 15 lbs of sugar, C12H22O11

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For the molecular compound dioxygen difluoride , what would you multiply "grams of O2F2 " by to get the units "molecules of O2F2 "

Answers

Answer:

Molecules of O₂F₂ = mass of O₂F₂ × (1 mole O₂F₂ / 70 g O₂F₂) × (6.02 × 10²³ molecules / one mole of O₂F₂)

Explanation:

The Avogadros constant gives the the number of specified entities in one mole of a substance. One mole of any substance contains 6.02 × 10²³ particles. Therefore, one mole of O₂F₂ contains 6.02 × 10²³ molecules.

Also, the molar mass of a substance is the mass in grams of one mole of that substance. It is obtained by summing the relative atomic masses of all the atoms of the elements in the substance. For O₂F₂, the molar mass = (2 × 16 + 2 × 19) g/mol = 70 g/mol

Converting to molecules of O₂F₂;

To convert from grams of a substance to molecules of that substance, multiply by the ratio of one mole and mass of one mole, and then by the number of molecules per mole.

Molecules of A = mass of A × (1 mole / mass of one mole) × (6.02 × 10²³ molecules / 1 mole)

Therefore,Molecules of O₂F₂ = mass of O₂F₂ × (1 mole O₂F₂ / 70 g O₂F₂) × (6.02 × 10²³ molecules /one mole of O₂F₂)

What is the formula of the compound Pentasilicon trioxide ?

Answers

Answer: the molecular formula of  trioxide is ClOClO3 or Cl2O4

hope its helps you.

keep smiling be happy stay safe

. The nucleophile in the reaction is _______ b. The Lewis acid catalyst in the reaction is ______ c. This reaction proceeds___________(faster or slower) than benzene. d. Draw the structure of product D

Answers

Answer:

a. eletrophile

b. able to impose regioselectivity and stereo selectivity.

c. faster

Explanation:

Necleophile reaction is chemical reaction in which electron rich chemical specie replaces functional group with another electron deficient molecule. Lewis acid catalyst is organic chemical reaction which lewis acid act as electron pair acceptor. Nucleophile reaction proceeds about 25 times more faster than benzene.

Which diagram correctly depicts the trend in electronegativity?

a.
b.
c.
d. ​

Answers

Answer: B

Explanation: Reference this electronegativity graph!

The electronegativity increases across the period and decreases down the group. Thus, option B is correct.

Electronegativity can be defined as the tendency of an atom to gain or attract an electron. The electronegativity has been dependent on the size of the atom, as well as the atomic number and valence electrons.

The atom with the requirement of a less number of atoms to complete its octet can easily gain the electron and thereby have high electronegativity. The atomic size also plays a role in the electronegativity of the atom.

The atom with a bigger size has the lesser force of attraction from the nucleus and thus has difficulty attracting the electron, however, the smaller size atom can easily attract the electron with the attraction force from the nucleus.

Thus, the elements with smaller sizes and a high number of valence electrons are more electronegative. In the periodic table, on moving from left to right the valence electrons increase, thus the electronegativity increases.

On moving down the group, the element size increase, thus the electronegativity decreases down the group.

The electronegativity increases across the period and decreases down the group. Thus, option B is correct.

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What is oxygen's half-equation?

Answers

answer; 1/ 20_2[2-] +2e - ->0.

¿soy guapo?
si dices que si te doy una galletita

Answers

Answer:

Hindi ko po ma gets sinasabi nyu pwedeng pakiayus

Chrehtegv ittgger ok so eva
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