Answer:
The answer is "Tertiary carbon".
Explanation:
Accent to the results, the carbon-bromine bond is weak, whenever, the bromine is connected to tertiary carbon so, bonding energy is separation for methyl-carbon, which is connected to the bromine = 70 kcal/mol and for the primary energy to the secondary energy is= 68 kcal/mol, and for tertiary CO2 = 65 kcal/mol.
The stronger the energy dissociating connection and the weaker, its power dissociation connection and its weaker bond becomes connecting with a tertiary carbon, that's why "Tertiary carbon" is the correct answer.
An atom of 122In has a mass of 121.910280 amu. Calculate the binding energy in MeV per NUCLEON. Use the masses: mass of 1H atom
The given question is incomplete, the complete question is:
An atom of 122In has a mass of 121.910280 amu. Calculate the binding energy in MeV per atom. Use the masses: mass of 1H atom = 1.007825 amu mass of a neutron = 1.008665 amu 1 amu = 931.5 MeV
Answer:
The correct answer is 1029.95 MeV.
Explanation:
Based on the given information,
The mass of proton is 1.007825, the mass of neutron is 1.008665.
The atomic number of Indium is 49, therefore, the number of neutrons will be, 122-49 = 73.
Now the calculated mass will be,
= 49 * 1.007825 + 73 * 1.008665
= 49.383425 + 73.632545
= 123.01597
The mass defect is calculated by subtracting the actual mas from calculated mass,
Mass defect = Actual mass - Calculated mass
= 121.910280 - 123.01597
= -1.10569 amu
Now the binding energy will be,
Binding energy = 1.10569 * 931.5 MeV
= 1029.95 MeV
How to do q solution, qrxn, moles of Mg , and delta Hrxn?
Answer:
14, 508J/K
ΔHrxn =q/n
where q = heat absorbed and n = moles
Explanation:
m = mass of substance (g) = 0.1184g
1 mole of Mg - 24g
n moles - 0.1184g
n = 0.0049 moles.
Also, q = m × c × ΔT
Heat Capacity, C of MgCl2 = 71.09 J/(mol K)
∴ specific heat c of MgCL2 = 71.09/0.0049 (from the formula c = C/n)
= 14, 508 J/K/kg
ΔT= (final - initial) temp = 38.3 - 27.2
= 11.1 °C.
mass of MgCl2 = 95.211 × 0.1184 = 11.27
⇒ q = 11.27g × 11.1 °C × 14, 508 j/K/kg
= 1,7117.7472 J °C-1 g-1
∴ ΔHrxn = q/n
=1,7117.7472 ÷ 0.1184
= 14, 508J/K
4. A 0.100 M solution of NaOH is used to titrate an HCl solution of unknown concentration. To neutralize the solution, an average volume of
the titrant was 38.2 mL. The starting volume of the HCI solution was 20 ml. What's the concentration of the HCI?
O A.0.284 M
B. 3.34 M
C. 0.191 M
D. 0.788 M
Answer:
C. 0.191 M
Explanation:
Our goal for this question, is to calculate the concentration of the HCl solution. For this, in the experiment, a solution of NaOH was used to find the moles of HCl. Therefore, our first step is to know the reaction between HCl and NaOH:
[tex]HCl~+~NaOH~->~NaCl~+~H_2O[/tex]
The "titrant" in this case is the NaOH solution. If we know the concentration of NaOH (0.100M) and the volume of NaOH (38.2 mL=0.0382 L), we can calculate the moles using the molarity equation:
[tex]M=\frac{mol}{L}[/tex]
[tex]0.100~M=\frac{mol}{0.0382~L}[/tex]
[tex]mol=0.100~M*0.0382~L=0.0382~mol~of~NaOH[/tex]
Now, in the reaction, we have a 1:1 molar ratio between HCl and NaOH (1 mol of HCl is consumed for each mole of NaOH added). Therefore we will have the same amount of moles of HCl in the solution:
[tex]0.0382~mol~of~NaOH\frac{1~mol~HCl}{1~mol~NaOH}=0.0382~mol~HCl[/tex]
If we want to calculate the molarity of the HCl solution we have to divide by the litters of HCl used in the experiment (20 mL= 0.02 L):
[tex]\frac{0.0382~mol~HCl}{0.02~L}~=~0.191~M[/tex]
The concentration of the HCl solution is 0.191 M
I hope it helps!
Write the equation for the reaction described: A solid metal oxide, , and hydrogen are the products of the reaction between metal and steam. (Use the lowest possible coefficients. Use the pull-down boxes to specify states such as (aq) or (s). If a box is not needed, leave it blank.)
Answer:
Pb + 2H2O --> PbO2 + 2H2
Explanation:
Products:
Solid metal; PbO2
Hydrogen; H
Reactants:
Metal; Pb
Steam; H2O
Reactants --> Products
Pb + H2O --> PbO2 + H2
Upon balancing we have;
Pb + 2H2O --> PbO2 + 2H2
11. The mass (in grams) of FeSO4.7H2O required for preparation of 125 mL of 0.90 M
solution is:
(a) 16 g
(b) 25 g
(c) 13 g
(d) 31 g
(e) 43 g
Answer:
what does little birdie say in the birth of their differences lak lak lak nu pasand aayi baby sleep are no longer children all strong industry all strong baby to show the meaning of rice is here to get up from sleep meaning of lips is Hasan let the mother is saying the baby to sleep in a new
Taking into account the definition of molarity and the molar mass of the compound, the correct answer is option (d): the mass of FeSO₄.7H₂O required for preparation of 125 mL of 0.90 M solution is 31 g.
In first place, you have to know tha molarity is a measure of the concentration of that substance that indicates the number of moles of solute present in the solution.
The molarity of a solution is calculated by dividing the moles of the solute by the volume of the solution.
[tex]molarity=\frac{number of moles of solute}{volume of solution}[/tex]
Molarity is expressed in units [tex]\frac{moles}{liter}[/tex].
In this case, you know:
molarity= 0.90 Mnumber of moles of solute= ?volume= 125 mL= 0.125 L (being 1000 mL=1 L)So, by definition of molarity, the number of moles is calculated as:
[tex]0.90 M=\frac{number of moles of solute}{0.125 L}[/tex]
Solving:
number of moles of solute= 0.90 M× 0.125 L
number of moles of solute= 0.1125 moles
On the other side, molar mass is the mass of one mole of a substance, which can be an element or a compound. In this case, the molar mass of FeSO₄.7H₂O is 277.85 [tex]\frac{g}{mole}[/tex].
Then you can apply the following rule of three: if by definition of molar mass, 1 mole of the compound contains 277.85 g, 0.1125 mole contains how much mass?
[tex]mass=\frac{0.1125 moles*277.85 g}{1 mole}[/tex]
Solving:
mass ≅ 31 g
Finally, the correct answer is option (d): the mass of FeSO₄.7H₂O required for preparation of 125 mL of 0.90 M solution is 31 g.
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Combustion reactions are a notable source of carbon dioxide in the environment. Using the following balanced equation, how many grams of carbon dioxide are formed when 100.00 g of propane is burned? Express your answer to the correct number of significant figures. Be sure to show all steps completed to arrive at the answer. Equation: C3H8 + 5O2 ->>>>>>> 3CO2 + 4H2O
Answer:
Explanation:
Number of moles of propane:
=Mass in grams ÷ Relative molecular Mass
= 100/((12*3) + (1*8))
= 100 ÷ 44
= 2.2727
Mole ratio propane:carbon (IV) oxide = 1:3(from the equation)
Number of moles of CO2 = 3*2.2727 = 6.8181
Mass in grams = Relative molecular Mass * Number of moles
= 44 * 6.8181
= 299.9964 grams
A number of moles of propane:
Mass in grams ÷ Relative molecular Mass
= 100/((12*3) + (1*8))
= 100 ÷ 44
= 2.2727
Mole ratio propane:carbon (IV) oxide = 1:3(from the equation)
Number of moles of CO2 = 3*2.2727 = 6.8181
Mass in grams = Relative molecular Mass * Number of moles
=44 * 6.8181
= 299.9964 grams
What is carbon dioxide useful for?Carbon dioxide is used as a refrigerant, in fireplace extinguishers, for inflating lifestyles rafts and life jackets, blasting coal, foaming rubber and plastics, selling the increased vegetation in greenhouses, and immobilizing animals earlier than slaughter, and in carbonated liquids.
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What is silica gel commonly used for? A. Absorbing moisture to protect goods from damage. B. As insulation in buildings. C. As a lacquer on wood to make it water-resistant. D. A soft, flexible padding, such as on pen grips or mouse pads.
Answer:
A
Explanation:
Absorbing moisture to protect goods from damage. Hence, option A is correct.
What is silica gel?Silica gel is a desiccant, or drying agent, that manufacturers often place in little packets to keep moisture from damaging certain food and commercial products.
Silica Gel is a good drying agent for preventing corrosion, contamination, spoilage, and mould growth in many commodities and products due to its physical properties.
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The gas with an initial volume of 24.0 L at a pressure of 565 torr is compressed until the volume is 16.0 L. What is the final pressure of the gas, assuming the temperature and amount of gas does not change
Answer:
848 torr
Explanation:
The only variables are the pressure and the volume, so we can use Boyle's Law.
p₁V₁ = p₂V₂
Data:
p₁ = 565 torr; V₁ = 24.0 L
p₂ = ?; V₂ = 16.0 L
Calculations:
[tex]\begin{array}{rcl}p_{1}V_{1} & = & p_{2}V_{2}\\\text{565 torr} \times \text{24.0 L} & = & p_{2} \times \text{16.0 L}\\\text{13 560 torr} & = & 16.0p_{2}\\p_{2} & = & \dfrac{\text{13 560 torr}}{16.0}\\\\& = &\textbf{848 torr}\\\end{array}\\\text{The final pressure of the gas is $\large \boxed{\textbf{848 torr}}$}[/tex]
Atomic mass is calculated by _____. subtracting protons from neutrons averaging the mass of isotopes adding protons and neutrons subtracting neutrons from protons
Answer:
Atomic mass is calculated by adding protons and neutrons.
Explanation:
Atomic mass is the sum of protons and neutrons in an atomic nucleus. For example, the element Oxygen has 8 protons (derived from the atomic number) and 8 neutrons (derived from subtracting the amount of protons from the atomic mass).
We can craft an equation to show the relationship between these variables.
M - N = P, where M = Mass, N = Neutrons, and P = Protons
This equation can be rearranged to show the relationship between the neutrons and protons leading to the atomic mass. Simply add N to both sides of the equation.
M = N + P
This shows that atomic mass is equivalent to the sum of protons and neutrons in an atom's nucleus.
what is non metal?
help meh
The element which can not loose electron easily and having electronagtive character is called non-metal it has following property-1. it can not conduct heat and electricity1. it is netiher ductile not malleable3. it is not lsuturous and also not sonorous
Answer:
Non-metals are the elements which form negative ions by accepting or gaining electrons. Non-metals usually have 4, 5, 6 or 7 electrons in their outermost shell. Non-metals are those which lack all the metallic attributes. They are good insulators of heat and electricity. They are mostly gases and sometimes liquid.
g Which ONE of the following pure substances will exhibit hydrogen bonding? A) methyl fluoride, FCH3 B) dimethyl ether, CH3C–O–CH3 C) formaldehyde, H2C=O D) trimethylamine, N(CH3)3 E) hydrazine, H2N-NH2
Answer:
C) formaldehyde, H2C=O.
Explanation:
Hello,
In this case, given that the hydrogen bondings are known as partial intermolecular interactions between a lone pair on an electron rich donor atom, particularly oxygen, and the antibonding molecular orbital of a bond between hydrogen and a more electronegative atom or group. Thus, among the options, C) formaldehyde, H2C=O, will exhibit hydrogen bonding since the lone pair of electrons of the oxygen at the carbonyl group, are able to interact with hydrogen (in the form of water).
Best regards.
For the following reaction, 3.76 grams of iron are mixed with excess oxygen gas . The reaction yields 4.29 grams of iron(II) oxide . iron ( s ) oxygen ( g ) iron(II) oxide ( s ) What is the theoretical yield of iron(II) oxide
Answer:
4.84g of FeO is the theoretical yield
Explanation:
The Iron, Fe(s), reacts with oxygen, O₂(g), producing Iron (II) oxide, as follows:
2Fe(s) + O₂(g) → 2FeO
Theoretical yield is the yield of a reaction in which you assume the 100% of reactants is converted in products.
To find theoretical yield we need to find moles of Iron, and, knowing 2 moles of Fe produce 2 moles of FeO (Ratio 1:1), we can find theoretical yield of FeO as follows:
Moles Fe (Molar mass: 55.845g/mol)
Using the molar mass of the compound we can convert grams to moles, thus:
3.76g Fe × (1mol / 55.845g) = 0.0673 moles of Fe
Moles and mass of FeO
As there are in reaction 0.0673 moles Fe, assuming a theoretical yield (And as ratio of the reaction is 1:1), you will obtain 0.0673 moles of FeO.
Theoretical yield is given in grams, As molar mass of FeO is 71.844g/mol, theoretical yield of the reaction is:
0.0673 moles FeO × (71.844g / mol) =
4.84g of FeO is the theoretical yieldWhich ONE of these cations has the same number of unpaired electrons as Fe2+ ? A) Ni2+ B) Fe3+ C) Cr2+ D) Mn2+ E) Co2+
Answer:
Explanation:
Fe2+ Has 4 unpaired electrons.
By method of elimination;
Option A: Ni2+ has two unpaired electrons. so this option is wrong.
Option B: There are 5 unpaired electrons in the Fe3+ ion. so this option is wrong.
Option C: There are 4 unpaired electrons in the Cr2+ ion. so this option is correct.
Option D: There are 5 unpaired electrons in the Mn2+ ion. so this option is wrong.
Option E: There are 3 unpaired electrons in the Co2+ ion. so this option is wrong.
A piece of plastic sinks in oil but floats in water. Place these three substances in order from lowest density to greatest density.
Answer:
[tex]\rho _{oil}<\rho _{plastic}<\rho _{water}[/tex]
Explanation:
Hello,
In this case, since water and oil are immiscible due to the oil's nonpolarity and water's polarity, when mixed, the oil remains on the water since it is less dense than water. In such a way, for a plastic sunk in the oil and floating on the water (in middle of them) we can conclude that the plastic have a mid density, therefore, the required organization is:
[tex]\rho _{oil}<\rho _{plastic}<\rho _{water}[/tex]
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Nitric acid is a strong acid, sodium hydroxide is a strong base, and sodium nitrate is a soluble salt. Which of the following is the net ionic equation for the reaction?
HNO_3(aq) + NaOH(aq) ------------->NaNO_3(aq) + H_2O(l)
A) H^+(aq) + OH^-(aq) ---------------->H_2O(l)
B) NO_3^-(aq) + Na^+(aq)-----------> NaNO_3(s)
C) H^+(aq) + NaOH(aq) ------------>Na^+(aq) + H_2O(l)
D) HNO_3(aq) + OH^-(aq)---------> NO_3^-(aq) + H_2O(l)
E) none of the above
Two elements represents by the letter Q and R atomic number 9 and 12 respectively.
1. Write the electronic configuration of R
2. To what group does Q belongs to in the periodic table
3. Write the formula of the compound formed when Q combines with R
Answer:
The two elements with atomic number 9 and 12 are represented by letter Q and R respectively, where Q represents fluorine atom and R represents magnesium atom.
1. Electronic configuration of R that is magnesium (atomic number 12) is:
1s2 2s2 2p6 3s2
2. Q represents fluorine atom, which belongs to group 17 in periodic table that is the most reactive and lightest member of the group.
3. Q and R that is fluorine and magnesium combinely form magnesium fluoride or MgF2.
what js the percent yield of lithium hydroxide from a reaction of 7.40 g of lithium with 10.2 g of water? the actual yield was measured to be12.1 g
Answer:
89%.
Explanation:
We'll begin by writing the balanced equation for the reaction. This is given below:
2Li + 2H2O —> 2LiOH + H2
Next, we shall determine the masses of Li and H2O that reacted and the mass of LiOH produced from the balanced equation.
This is illustrated below:
Molar mass of Li = 7 g/mol
Mass of Li from the balanced equation = 2 x 7 = 14 g
Molar mass of H2O = (2x1) + 16 = 18 g/mol
Mass of H2O from the balanced equation = 2 x 18 = 36 g
Molar mass of LiOH = 7 + 16 + 1 = 24 g/mol
Mass of LiOH from the balanced equation = 2 x 24 = 48 g
Summary:
From the balanced equation above,
14 g of Li reacted with 36 g of H2O to produce 48 g of LiOH.
Next, we shall determine the limiting reactant. This can be obtained as follow:
From the balanced equation above,
14 g of Li reacted with 36 g of H2O.
Therefore, 7.4 g of Li will react with = (7.4 x 36)/14 = 19.03 g of H2O.
From the calculation made above, we can see that it will take a higher amount i.e 19.03 g than what was given i.e 10.2 g of H2O to react completely with 7.4 g of Li.
Therefore, H2O is the limiting reactant and Li is the excess reactant.
Next, we shall determine the theoretical yield of LiOH.
In this case we shall use the limiting reactant.
The limiting reactant is H2O and the theoretical yield of LiOH can be obtained as follow:
From the balanced equation above,
36 g of H2O reacted to produce 48 g of LiOH.
Therefore, 10.2 g of H2O will react to produce = (10.2 x 48)/36 = 13.6 g of LiOH.
Therefore, the theoretical yield of LiOH is 13.6 g
Finally, we shall determine the percentage yield of LiOH. This can be obtained as follow:
Actual yield = 12.1 g
Theoretical yield = 13.6 g
Percentage yield =..?
Percentage yield = Actual yield /Theoretical yield x 100
Percentage yield = 12.1/ 13.6 x 100
Percentage yield = 89%
Therefore, the percentage yield LiOH is 89%.
Which of the following sets of quantum numbers (n, l, ml, ms) refers to a 3d orbital? Question 5 options: 2 0 0 – g 5 4 1 – 4 2 –2 + 4 3 1 – 3 2 1 –
3 2 1 is the set of quantum numbers.
What are Quantum Numbers?The set of numbers used to describe the position and energy of the electron in an atom is called quantum numbers. There are four quantum numbers, namely, principal, azimuthal, magnetic, and spin quantum numbers.
What is the rule of quantum numbers?The rules for quantum numbers are: (n) can be any positive, nonzero integral value. (l) can be zero or any positive integer but not larger than (n-1). l = 0, 1, 2, 3, 4, …. (n-1) (ml) values follow the equation.
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g When considering the effects of temperature on spontaneity, if both ΔH and ΔS are positive, _______. Select the correct answer below: the process is spontaneous at all temperatures
Explanation:
The spontaneity of a system is deduced by the sign of the gibbs free energy value. If it is negative, it means the process / reaction is spontaneous however a positive value indicates the such process is not spontaneous.
Gibbs free energy, enthalpy and entropy are related by the following equation;
ΔG = ΔH - TΔS
A positive value of enthalpy, H and entropy, S means that G would always be a negative value at all temperatures.
An equilibrium mixture of N2, H2, and NH3 at 700 K contains 0.036 M N2 and 0.15 M H2. At this temperature, Kc for the reaction N2(g) + 3 H2(g)<=> 2NH3(g) is 0.29.
What is the concentration of NH3?
Answer:
5.94×10¯³
Explanation:
The following data were obtained from the question:
Concentration of N2, [N2] = 0.036 M
Concentration of H2, [H2] = 0.15 M
Equilibrium constant (Kc) = 0.29 M
Concentration of NH3, [NH3] =.…?
The equation for the reaction is given below:
N2(g) + 3H2(g) <=> 2NH3(g)
Thus, we can determine the concentration of NH3 by using the equilibrium expression for the reaction.
This is illustrated below:
The equilibrium constant for a reaction is simply defined as the ratio of the concentration of the product raised to their coefficient to the concentration of the reactant raised to their coefficient.
The equilibrium constant for the above equation is given below:
Kc = [NH3]² / [N2] [H2]³
Inputting the value of Kc, [N2], and [H2] the value of [NH3]can be obtained as follow:
Kc = [NH3]² / [N2] [H2]³
0.29 = [NH3]²/ 0.036 × 0.15³
Cross multiply
[NH3]² = 0.29 × 0.036 × 0.15³
[NH3]² = 3.5235×10¯⁵
Take the square root of both side
[NH3] = √(3.5235×10¯⁵)
[NH3] = 5.94×10¯³
Therefore, the concentration of NH3, [NH3] is 5.94×10¯³ M.
When 1604 J of heat energy is added to 48.9 g of hexane, C6H14, the temperature increases by 14.5 ∘C. Calculate the molar heat capacity of C6H14.
Answer:
THE MOLAR HEAT CAPACITY OF HEXANE IS 290.027 J/ C
Explanation:
1604 J of heat is added to 48.9 g of hexane
To calculate the molar heat capacity of hexane, it is important to note that the molar heat capacity of a substance is the measure of the amount of heat needed to raise 1 mole of a substance by 1 K.
Since 1604 J of heat = 48.9 g of hexane
Molar mass of hexane = 86 g/mol = 1 mole
then;
1604 J = 48.9 g
x = 86 g
x = 1604 * 86 / 48.9
x = 4205.4 J
Hence, 4205.4 J of heat will be added to 1 mole or 86 g of hexane to raise the temperature by 14.5 C.
In other words,
heat = molar heat capacity * temperature change
molar heat capacity = heat/ temperature change
Molar heat capacity = 4205.4 J / 14.5 C
Molar heat capacity = 290.027 J/C
The molar heat capacity of hexane is 290.027 J/ C
A compound is found to contain 11.21 % hydrogen and 88.79 % oxygen by mass. What is the empirical formula for this compound?
Answer:
H₂O
Explanation:
The empirical formular of the compound is obtained using the following steps;
Step 1: Divide the percentage composition by the atomic mass
Hydrogen = 11.21 / 1 = 11.21
Oxygen = 88.79 / 16 = 5.55
Step 2: Divide by the lowest number
Hydrogen = 11.21 / 5.55 = 2.02 ≈ 2
Oxygen = 5.55 / 5.55 = 1
This means the ratio of the elements is 2 : 1
The empirical formular (simplest formular of a compound) of the compound is;
H₂O
Answer:Empirical formula ======== H₂O
Explanation:The empirical formula of a compound shows the whole number ratio for each atom in a compound.
To find empirical formula. we follow the below steps
The total mass of the compound here is 100 grams, that is (11.21% of hydrogen + 88.79% of oxygen) we can then assume 11.21 grams of hydrogen and 88.79grams of oxygen
Hydrogen Oxygen
1.composition by mass 11.21 88.79
molecular weight 1.007g/mol 15.990g/mol
2.Divide composition by mass 11.21/1.007 88.79/15.99
by each molecular weight to get 11.13 5.553
no of moles
3 Divide by the least number of moles
to get atomic ratio 11.13/5.553 5.553/5.553
2.004 1.00
4.Convert to whole numbers 2 1
Empirical formula ======== H₂O
13. Arrange each group of units from smallest to
largest
a)km, mm, cm, m
b) mg, kg, g
C) L, mL
d) s, ms, min, h
Answer:
A. mm,cm,m,Km
B. mg, g, Kg
C. mL,L
D. ms, s, min, h
Explanation:
You are a paleontology professor working at a dig site looking for fossils. You come across a deposit that is emitting radiation. Upon further testing you find that the sample is changing from carbon (atomic number 6) into nitrogen (atomic number 7) as radiation is emitted. What type of radiation is it?
Answer:
β particles
Explanation:
The most common radioactive isotope of carbon is C-13.
The unbalanced nuclear equation is
[tex]\rm _{6}^{13}C \longrightarrow \, ? + \, _{7}^{13N}[/tex]
Let's write the question mark as a nuclear symbol.
[tex]\rm _{6}^{13}C} \longrightarrow \, _{Z}^{A}X+ \, _{7}^{13}N[/tex]
The main point to remember in balancing nuclear equations is that the sums of the superscripts and the subscripts must be the same on each side of the equation.
Then
13 = A + 13, so A = 13 - 13 = 0, and
6 = Z + 7, so Z = 6 - 7 = -1
Then, your nuclear equation becomes
[tex]\rm _{6}^{13}C \longrightarrow \, _{-1}^{0}M + \, _{7}^{13}N[/tex]
The particle with "zero" mass and a charge of -1 is an electron, so the balanced nuclear equation is
[tex]\rm _{6}^{13}C \longrightarrow \, _{-1}^{0}e + \, _{7}^{13}N[/tex]
The radiation consists of β particles (electrons)
Answer:
I think think that the one above me is beta radiation
Explanation:
Draw a structure for an alcohol that exhibits a molecular ion at M+ = 88 and that produces fragments at m/z = 73, m/z = 70 and m/z = 59.
Answer:
3-pentanol
Explanation:
In this case, we have alcohol as the main functional group (OH) with a molecular ion at 88. If the molecular ion is 88 the molar mass is also 88 g/mol therefore the formula for the unknown molecule is [tex]C_5H_1_2O[/tex].
Additionally, if the mass spectrum shows the molecular ion peak we can not have tertiary alcohols (tertiary alcohols often do not show M+ at all). So, the structures only can be primary and secondary structures.
With this in mind, our options are:
-) 1-pentanol
-) 2-pentanol
-) 3-pentanol
Now we can analyze each structure:
-) 1-pentanol
The structure must explain all the fragments produced (73, 70, and 59). In this primary alcohol, we will have an alpha cleavage (the red bond would be broken). If this has to happen, we will have fragments at 31 and 57. These fragments dont fit with the reported ones, therefore this is not a possible structure (See figure 1).
-) 2-pentanol
On this structure, we will have also an alpha cleavage (red bond). In this rupture we will have fragments at 45 and 43, these m/z values dont fit with the reported ones, therefore this is not a possible structure (See figure 1).
-) 3-pentanol
In this structure, we have the "OH" bonded to carbon three. So, we can analyze each fragment:
-) m/z 59
This fragment, can be explained as an alpha cleavage. But, in this case we have two ruptures that can produce the same ion. The carbons on both sides of the C-OH bond.
-) m/z 71
This fragment, can be explained as a loss of water (M-18) in which we have the production of a carbocation in the carbon where we previously have the C-OH bond.
-) m/z 73
This fragment, can be explained as a beta cleavage. But, in this case, also we have two ruptures that can produce the same ion. The methyl groups on each end molecule.
See figure 2
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A solution of HCOOH has 0.16M HCOOH at equilibrium. The Ka for HCOOH is 1.8×10−4. What is the pH of this solution at equilibrium? Express the pH numerically.
Answer:
[tex]pH=2.28[/tex]
Explanation:
Hello,
In this case, for the acid dissociation of formic acid (HCOOH) we have:
[tex]HCOOH(aq)\rightarrow H^+(aq)+HCOO^-(aq)[/tex]
Whose equilibrium expression is:
[tex]Ka=\frac{[H^+][HCOO^-]}{[HCOOH]}[/tex]
That in terms of the reaction extent is:
[tex]1.8x10^{-4}=\frac{x*x}{0.16-x}[/tex]
Thus, solving for [tex]x[/tex] which is also equal to the concentration of hydrogen ions we obtain:
[tex]x=0.00528M[/tex]
[tex][H^+]=0.00528M[/tex]
Then, as the pH is computed as:
[tex]pH=-log([H^+])[/tex]
The pH turns out:
[tex]pH=-log(0.00528M)\\\\pH=2.28[/tex]
Regards.
In the experiment students will create solutions with different ratios of ethanol and water. What is the mole fraction of ethanol when 10.00 mL of pure ethanol is combined with 2.00 mL of water
Answer:
[tex]x_{et}=0.6068[/tex]
Explanation:
Hello,
In this case, since the mole fraction of a compound, in this case ethanol, in a binary mixture, in this constituted by both water and ethanol, is mathematically defined as follows:
[tex]x_{et}=\frac{n_{et}}{n_{et}+n_{w}}[/tex]
Whereas [tex]n[/tex] accounts for the moles in the solution for each species, we must first compute the moles of both ethanol (density: 0.789 g/mL and molar mass: 46.07 g/mol) and water (density: 1g/mL and molar mass: 18.02 g/mol)
[tex]n_{et}=10.00mL\ et*\frac{0.789g\ et}{mL\ et} *\frac{1mol\ et}{46.07g\ et}=0.1713mol\ et\\ \\n_w=2.00mL\ w*\frac{1g\ w}{mL\ w} *\frac{1mol\ w}{18.02g\ w}=0.1110mol\ w[/tex]
Therefore, the mole fraction turns out:
[tex]x_{et}=\frac{0.1713mol}{0.1713mol+0.1110mol}\\\\x_{et}=0.6068[/tex]
Best regards.
The two common properties of all solids are fixed _____ and _____.
Answer:
shape
volume
Hope this helps! （づ￣3￣）づ╭❤～
Explanation:
Classify each of the following fatty acids as saturated, monounsaturated, or polyunsaturated. Drag the appropriate items to their respective bins.
1. myristic acid
2. oleic acid
3. linoleic acid
4. palmitic acid
A. Saturated acids
B. Monounsaturated acids
C. Polyunsaturated acids
Answer:
A. Saturated acids - 1. myristic acid, 4. palmitic acid
B. Monounsaturated acids - 2. oleic acid
C. Polyunsaturated acids - 3. linoleic acid
Explanation:
Saturated fatty acids are the fats combined together with a single bond and no double or triple bond while unsaturated fatty acids are the fats having a double or triple bond between them.
Monosaturated acids have only one double or triple bond while polyunsaturated acids have more than one double or triple bond.
So, an appropriate match of given acids are:
A. Saturated acids - Myristic acid (CH3(CH2)12COOH) and Palmitic acid (CH3(CH2)14COOH) dont have any double or triple bonds.
B. Monounsaturated acids - Oleic acid (CH3(CH2)7CH=CH(CH 2)7COOH) have only one double bond.
C. Polyunsaturated acids - Linoleic acid (HOC–7CH=CH–CH 2–CH=CH–3H) has two double bonds.
Hence, the correct answer is:
A. Saturated acids - 1. myristic acid, 4. palmitic acid
B. Monounsaturated acids - 2. oleic acid
C. Polyunsaturated acids - 3. linoleic acid
Calculate the number of hydrogen atoms in a 110.0 sample of tetraborane(B4H10) . Be sure your answer has a unit symbol if necessary, and round it to 4 significant digits.
Answer:
[tex]1.242 \times 10^{25}\text{ atoms H}[/tex]
Explanation:
You must convert the mass of B₄H₁₀ to moles of B₄H₁₀, then to molecules of B₄H₁₀, and finally to atoms of H.
1. Moles of B₄H₁₀
[tex]\text{Moles of B$_{4}$H}_{10} = \text{110.0 g B$_{4}$H}_{10} \times \dfrac{\text{1 mol B$_{4}$H}_{10}}{\text{53.32 g B$_{4}$H}_{10}} = \text{2.063 mol B$_{4}$H}_{10}[/tex]
2. Molecules of B₄H₁₀
[tex]\text{No. of molecules} = \text{2.063 mol B$_{4}$H}_{10} \times \dfrac{6.022 \times 10^{23}\text{ molecules B$_{4}$H}_{10}}{\text{1 mol B$_{4}$H}_{10}}\\\\=1.242 \times 10^{24}\text{ molecules B$_{4}$H}_{10}[/tex]
3. Atoms of H
[tex]\text{Atoms of H} = 1.242 \times 10^{24}\text{ molecules B$_{4}$H}_{10} \times \dfrac{\text{10 atoms H}}{\text{1 molecule B$_{4}$H}_{10}}\\\\= \mathbf{1.242 \times 10^{25}}\textbf{ atoms H}[/tex]
