From the dropdowns, identify whether the compound contains ionic bonds, covalent bonds, or both. a) CBr4 [ Select ] b) copper(II) sulfate [ Select ] c) N2O3 [ Select ] d) phosphorous trichloride

Answers

Answer 1

Answer:

a) Covalent bonds

b) Covalent and ionic bonds

c) Covalent bonds

d) Covalent bonds

Explanation:

Metals and non-metals form ionic bonds (electrons are transferred), whereas nonmetals and nonmetals form covalent bonds.

Identify whether the compound contains ionic bonds, covalent bonds, or both.

a) CBr₄. C and Br are nonmetals. Thus, they form covalent bonds.

b) copper(II) sulfate. Sulfate contains S and O (nonmetals), which are bonded through covalent bonds. Sulfate is bonded to copper (metal) through an ionic bond.

c) N₂O₃. N and O are nonmetals. Thus, they form covalent bonds.

d) phosphorous trichloride. P and Cl are nonmetals. Thus, they form covalent bonds.


Related Questions

Where do reactions in a solid
generally take place?
A. All throughout the solid
B. At the center of the solid.
C. Only on opposite sides of the solid
due to repelling forces.
D. On the surface of the solid.

Answers

Answer:

A

Explanation:

because solid stick together like magnetic and can feel every vibration

Answer:D

Explanation: on the surface of a solid

How many hydrogen atoms are in 3.90 mol of ammonium sulfide?

Answers

Answer:

First, the number of ammonium sulfide molecules should be calculated:

N = NA × n,

where NA - the Avogadro number, n - number of moles.

N (ammonium sulfide) = 6.022 × 1023 × 8.5 mol = 51.187 × 1023.

The moelcular formula of ammonium sulfide is (NH4)2S. It means that each molecule contains 8 hydrogen atoms.

As a result, 8.5 mol of (NH4)2S contain:

51.187 × 1023 × 8 = 41 × 1024 hydrogen atoms.

Answer: 41 × 1024 hydrogen atoms

A sample of 10.6 g of KNO3 was dissolved in 251.0 g of water at 25 oC in a calorimeter. The final temperature of the solution was 21.5 oC. What is the molar heat of solution of KNO3

Answers

Answer:

36.55kJ/mol

Explanation:

The heat of solution is the change in heat when the KNO3 dissolves in water:

KNO3(aq) → K+(aq) + NO3-(aq)

As the temperature decreases, the reaction is endothermic and the molar heat of solution is positive.

To solve the molar heat we need to find the moles of KNO3 dissolved and the change in heat as follows:

Moles KNO3 -Molar mass: 101.1032g/mol-

10.6g * (1mol/101.1032g) = 0.1048 moles KNO3

Change in heat:

q = m*S*ΔT

Where q is heat in J,

m is the mass of the solution: 10.6g + 251.0g = 261.6g

S is specififc heat of solution: 4.184J/g°C -Assuming is the same than pure water-

And ΔT is change in temperature: 25°C - 21.5°C = 3.5°C

q = 261.6g*4.184J/g°C*3.5°C

q = 3830.87J

Molar heat of solution:

3830.87J/0.1048 moles KNO3 =

36554J/mol =

36.55kJ/mol

Diethyl ether (C2H5 )2O vaporizes at room temperature. If the vapor exerts a pressure of 233 mm Hg in a flask at 25 °C, what is the density of the vapor?​

Answers

Answer: The density of the given vapor is 0.939 g/L.

Explanation:

Given: Pressure = 233 mm Hg (1 mm Hg = 0.00131579 atm) = 0.31 atm

Temperature = [tex]25^{o}C[/tex] = (25 + 273) K = 298 K

According to the ideal gas equation,

[tex]PV = \frac{m}{M}RT[/tex]

where,

P = pressure

V = volume

m = mass

M = molar mass

R = gas constant = 0.0821 L atm/mol K

T = temperature

This formula can be re-written as follows.

[tex]PM = \frac{m}{V}RT[/tex]    (where, [tex]Density = \frac{mass (m)}{Volume (V)}[/tex] )

Hence, formula used to calculate density of diethy ether (molar mass = 74.12 g/mol) vapor is as follows.

[tex]d = \frac{PM}{RT}[/tex]

Substitute values into the above formula as follows.

[tex]d = \frac{PM}{RT}\\= \frac{0.31 atm \times 74.12 g/mol}{0.0821 L atm/mol K \times 298 K}\\= \frac{22.9772}{24.4658}\\= 0.939 g/L[/tex]

Thus, we can conclude that the density of the given vapor is 0.939 g/L.

Name two natural sources of esters.​

Answers

Answer:

"Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries."

Explanation:

g 0.500 L of a solution with a concentration of 0.25 M is needed. To prepare this solution, a stock solution with a concentration of 1.25 M is prepared. What volume of the stock solution is needed to create the desired solution

Answers

Answer:

0.1 L

Explanation:

From the question given above, the following data were obtained:

Concentration of stock solution (C₁) = 1.25 M

Volume of diluted solution (V₂) = 0.5 L

Concentration of diluted solution (C₂) = 0.25 M

Volume of stock solution needed solution (V₁) =?

The volume of the stock solution needed can be obtained as follow:

C₁V₁ = C₂V₂

1.25 × V₁ = 0.25 × 0.5

1.25 × V₁ = 0.125

Divide both side by 1.25

V₁ = 0.125 / 1.25

V₁ = 0.1 L

Therefore, the volume of the stock solution needed is 0.1 L

22 Agas that is collected by upward delivery is likely to be A heavier than air B insoluble in water C lighter than air D Soluble in water

Answers

Answer:

joib

Explanation:

Which 2 resonance forms destablize the carbocation intermediate if bezonitrile undergoes chlronation at the ortho or para positions

Answers

The question is incomplete, the complete question is shown in the image attached

Answer:

A and B

Explanation:

The electrophilic substitution of arenes yields a cation intermediate. The positive charge of the cation is delocalized over the entire ring.

The -CN group directs incoming electrophiles to the ortho/para position. The resonance structures for the chlorination of benzonitrile are shown in the question.

Recall that -CN is an electron withdrawing group. The resonance forms that destablize the carbocation intermediate are those in which the -CN group is directly attached to the carbon atom bearing the positive charge as in structures A and B.

Calculate the mass of water produced when 1.57g of butane reacts with excess oxygen

Answers

Explanation:

So, first you will want to write the balanced chemical equation for this reaction.

Butane = [tex]C_4H_{10}[/tex]

[tex]2C_4H_{10}+13O_2=>10H_2O+8CO_2[/tex]

^ This ends up being your balanced chemical equation. Now, you can do the math!

[tex]1.57gC_4H_{10}*\frac{1molC_4H_{10}}{58.12gC_4H_{10}}*\frac{10molH_2O}{2molC_4H_{10}}*\frac{18gH_2O}{1molH_2O}[/tex]

After plugging this into a calculator, your final mass of water should be:

2.43gH2O

Rank the following substances/solutions in order of lowest boiling point to highest boiling point where 1 has the lowest boiling point and 5 has the highest boiling point. pure water; 1.0 m NaCl; 0.5 m KBr, 0.75 m CaCl2; 1.5 m glucose (C6H12O6)

Answers

Answer:

1) pure water

2) 0.75 m CaCl2

3) 1.0 m NaCl

4) 0.5 m KBr

5) 1.5 m glucose (C6H12O6)

Explanation:

Boiling point elevation is a colligative property. Coligative properties are properties that depend on the amount of solute present in the system. The boiling point of solvents increase due to the presence of solutes.

The boiling point elevation depends on the number of particles the solute forms in solution and the molality of the solute. The more the number of particles formed by the solute and the greater the molality of the solute, the greater the magnitude of boiling point elevation.

The order of decreasing hoping point elevation is;

1) 0.75 m CaCl2

2) 1.0 m NaCl

3) 0.5 m KBr

4) 1.5 m glucose (C6H12O6)

Classify each cation as a weak acid or pH neutral (neither acidic nor basic).

a. Na+
b. Ni2+
c. NH4+

Answers

Answer:

a. Na+ is pH neutral

b. Ni2+ = weak acid

c. NH4+ = Weak acid

Explanation:

To know the nature of the cation we need to find the nature of its conjugate base.

If the conjugate base of the ion is a strong base, the ion is neutral.

If the conjugate base is a weak base, the ion is a weak acid:

a. Conjugate base Na+ = NaOH

Sodium hydroxide is a strong base:

Na+ is pH neutral

b. Conjugate base Ni²⁺: Ni(OH)2 is a weak base because is not completely soluble in water. That means:

Ni2+ = weak acid

c. Conjugate base NH4+: NH4OH. Weak base:

NH4+ = Weak acid

What volume (mL) of the sweetened tea described in Example 1 contains the same amount of sugar (mol) as 10 mL of the soft drink in this example

Answers

The question is incomplete, the complete question is:

What volume (mL) of the sweetened tea described in Example 3.14 contains the same amount of sugar (mol) as 10 mL of the soft drink in this example. The example is attached below.

Answer: 75 mL of sweetened tea will contain the same amount of sugar as in 10 mL of soft drink

Explanation:

We first calculate the number of moles of soft drink in a volume of 10 mL

The formula used to calculate molarity:

[tex]\text{Molarity of solution}=\frac{\text{Moles of solute}\times 1000}{\text{Volume of solution (mL)}}[/tex] .....(1)

Taking the concentration of soft drink from the example be = 0.375 M

Volume of solution = 10 mL

Putting values in equation 1, we get:

[tex]0.375=\frac{\text{Moles of sugar in soft drink}\times 1000}{10}\\\\\text{Moles of sugar in soft drink}=\frac{0.375\times 10}{1000}=0.00375mol[/tex]

Calculating volume of sweetened tea:

Moles of sugar = 0.00375 mol

Molarity of sweetened tea = 0.05 M

Putting values in equation 1, we get:

[tex]0.05=\frac{0.00375\times 1000}{\text{Volume of sweetened tea}}\\\\\text{Volume of sweetened tea}=\frac{0.00375\times 1000}{0.05}=75mL[/tex]

Hence, 75 mL of sweetened tea will contain the same amount of sugar as in 10 mL of soft drink

Certain ketones such as fructose can be oxidized by Benedict's reagent under basic conditions to form what type of compound

Answers

Answer:

Certain ketones such as fructose can be oxidized by Benedict's reagent under basic conditions to form what type of compound

Explanation:

Benedict's solution is a mixture of copper sulfate, anhydrous sodium carbonate, and sodium citrate.

In presence of mild reducing agents, Cu(II) ion in Benedict's solution becomes the Cu(I) ion.

Fructose has an alpha-hydroxy ketone group.

It undergoes tautomerism and forms alpha-hydroxy aldehyde which gives a positive test with Benedict's reagent.

During this test, aldehydes will be converted into carboxylic acids.

The reaction of fructose with Benedict's reagent is shown below:

In a single displacement reaction Zinc can displace ALL but…
Iron
Nickel
Calcium
Lead

Answers

Answer:

Calcium

Explanation:

Zinc cannot displace Ca because calcium is above it in the reactivity series

Many chemistry problems result in equations of the form
1.77 X100.298-z)
When this equation is solved, the two values of the unknown are ________ and ________

Answers

Answer:

When this equation is solved, the two values of the unknown are 0.0643 and -0.082

Explanation:

Given

[tex]1.77 * 10^{-2} = \frac{x^2}{0.298 - x}[/tex] --- the actual equation

Required

The values of x

We have:

[tex]1.77 * 10^{-2} = \frac{x^2}{0.298 - x}[/tex]

Cross Multiply

[tex]1.77 * 10^{-2} * (0.298 - x)= x^2[/tex]

Multiply both sides by 100

[tex]1.77 * (0.298 - x)= 100x^2[/tex]

Open bracket

[tex]0.52746 - 1.77x= 100x^2[/tex]

Rewrite as:

[tex]100x^2 + 1.77x - 0.52746 =0[/tex]

Using quadratic formula:

[tex]x = \frac{-b \± \sqrt{b^2 - 4ac}}{2a}[/tex]

Where:

[tex]a = 100; b = 1.77; c = -0.52746[/tex]

So, we have:

[tex]x = \frac{-1.77 \± \sqrt{1.77^2 - 4*100*- 0.52746 }}{2*100}[/tex]

[tex]x = \frac{-1.77 \± \sqrt{214.1169}}{2*100}[/tex]

[tex]x = \frac{-1.77 \± 14.63}{200}[/tex]

Split

[tex]x = \frac{-1.77 + 14.63}{200}\ or\ x = \frac{-1.77 - 14.63}{200}[/tex]

[tex]x = \frac{12.86}{200}\ or\ x = \frac{-16.40}{200}[/tex]

[tex]x = 0.0643\ or\ x = -0.082[/tex]

How many molecules of C 2H 5Br will be present if you had 4.52 g of this compound?

Answers

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Under certain conditions, the substance mercury(II) oxide can be broken down to form mercury and oxygen. If 32.2 grams of mercury(II) oxide react to form 29.8 grams of mercury, how many grams of oxygen must simultaneously be formed

Answers

Explanation:

This is a decomposition reaction. Firstly, you will want to write the chemical equation out and balance it.

[tex]2Hg_2O->4Hg+O_2[/tex] (The -> is supposed to be an arrow, sorry!)

We see that there's only 1mol of Oxygen made in the products, we can do some simple math to solve for the amount of grams of Oxygen produced according to the amount of the reactant (Hg2O).

[tex]32.2gHg_2O*\frac{1molHg_2O}{417.18gHg_2O}*\frac{1molO_2}{2molHg_2O}*\frac{32gO_2}{1molO_2}[/tex]

I want to break this down, just in case:

The 417.18gHg2O is the molecular mass of the molecule (so I doubled Hg and added 16 to it to get this number).

As we can see in the chemical equation, 1mol Hg2O produces 2mol O because Oxygen is a diatomic molecule (so there will always be two of it when it's by itself).

And finally, in 1mol O2 there are 32g of O2.

** When you do math like this, always make sure that all of your units cancel out except for the units you're looking for. For example, here we're looking for the grams of Oxygen, so after everything else cancels out, we should only have grams O2.

So, 1.23gO2 should be your answer.

The volume of a single tantalum atom is 1.20×10-23 cm3. What is the volume of a tantalum atom in microliters?

Answers

Answer:

1.20x10⁻²⁰μL

Explanation:

1cm³ is equal to 1milliliter. As we must know, 1milliliter = 1000 microliters, 1000μL. To convert the 1.20x10⁻²³mL we need to use the conversion factor: 1mL = 1000μL.

The volume of tantalum in μL is:

1.20x10⁻²³mL * (1000μL /1L) = 1.20x10⁻²⁰μL

I don’t want to fail help
I need correct answer if u don’t know I will report

When the researcher compiled information which research method did they most likely utilize?

a) documentary
b) survey
c) participant observation
d) case study

Answers

Answer:

a

Explanation:

documentary is best researcher!.

15. You are interested in separating 4-methylbenzoic acid from 1,4-dimethoxybenzene using a procedure similar to the extraction procedure we used in lab. You plan to use sodium bicarbonate instead of sodium hydroxide. a) Show the reaction between salicylic acid and sodium bicarbonate. Label the acid, base, conjugate acid, conjugate base. b) Give the pKa values of the acid and conjugate acid. c) Which base will work better, sodium hydroxide or sodium bicarbonate

Answers

Solution :

a). The separation of 4-methylbenzoic acid from 1,4-dimethoxybenzene will work but it will result in lower recovery.

In the reaction of acid-base to form a sodium 4 - methoxy benzoate, that is soluble in the water, 4-methoxy benzoic acid reacts with the sodium bicarbonate to give sodium 4-methoxybenzoate as well as carbonic acid.

b). The pKa for the 4-methoxybenzoic acid is [tex]4.46[/tex], and that of carbonic acid is [tex]6.37[/tex]

c). The Keq for the reaction is [tex]10(6.37 - 4.46) = 101.91[/tex]

Therefore, the equilibrium lies to the right  and also the reaction favors the products and the separation works.

But the recovery will be low when compared to the extraction with Sodium hydroxide as the strong base will drive the equilibrium further to the right position, thus neutralizing all the acids virtually. And the weak base will partially neutralize the acid.

compound of aspartame is a dipeptide that is often used as a sugar substitute which functional groups are present

Answers

Answer:

Carboxyl, primary amine, amide, ester, and phenyl.

Explanation:

The functional groups present in the compound of aspartame are carboxyl, primary amine, amide, ester, and phenyl. Aspartame is an artificial non-saccharide sweetener which is 200 times sweeter than sucrose. This aspartame is commonly used as a sugar substitute in many foods and beverages. It has the trade names such as NutraSweet, Equal, and Canderel.

Name the following aldehyde PLEASE PLEASE HELP

Answers

Answer:

Explanation:

Answer is D 2,5-dimethylheptanal

You should accern the lowest possible number close to the parent name

A sample of calcium fluoride was decomposed into the constituent elements. Write a balanced chemical equation for the decomposition reaction. If the sample produced 294 mg of calcium, how many g of fluorine were formed

Answers

Answer:

A sample of calcium fluoride was decomposed into the constituent elements. Write a balanced chemical equation for the decomposition reaction. If the sample produced 294 mg of calcium, how many g of fluorine was formed

Explanation:

The balanced chemical equation for the decomposition of calcium fluoride is shown below:

[tex]CaF_2(s)->Ca(s)+F_2(g)[/tex]

The sample produced 294 g of calcium then, how many grams of fluorine is formed?

From the balanced chemical equation,

1 mol of CaF2 forms 1mol of calcium and 1 mol of fluorine.

That is:

40g of calcium and 38.0 g of fluorine are formed.

then,

If 294 g of calcium is formed then how many grams of fluorine is formed?

[tex]294g Ca * 38g F2 / 40g Ca\\=279.3 g F_2[/tex]

Hence, 279.3 g of fluorine will be formed.

Ammonium phosphate is an important ingredient in many solid fertilizers. It can be made by reacting aqueous phosphoric acid with liquid ammonia. Calculate the moles of phosphoric acid needed to produce 1.80 mol of ammonium phosphate. Be sure your answer has a unit symbol, if necessary, and round it to the correct number of significant digits.

Answers

Answer:

Explanation:

The reaction is

H3Po4+3NH3\to→ (NH4)3PO4

Given,7.10g NH3=7.10g/molar mass of NH3

=7.10g/(17.031g/mol)

=0.416mol

From the reaction

3 mol ammonia reacted and produced 1 mole of ammoniam phosphate

So,One mole ammonia reacted and produced 1/ 3 mole ammonium phosphate.

And Also,0.416 mole ammonium reacted and produced (1/3)0.416=0.138 mole ammonium phosphate.

Hence 0.138mole=0.138mole*149.08 g/mole

               =20.573gm ammonium phosphate produced.

Hence 20.573g of ammonium phosphate is produced by the reaction of 7.10 g of ammonia.

A gas bottle contains 0.650 mol of gas at 730. mmHg pressure. If the final pressure is 1.15 atm, how many moles of gas were added to the bottle

Answers

Answer: There are 0.779 moles of gas were added to the bottle.

Explanation:

Given: [tex]n_{1}[/tex] = 0.650 mol,     [tex]P_{1}[/tex] = 730 mm Hg (1 mm Hg = 0.00131579 atm) = 0.96 atm

[tex]n_{2}[/tex] = ?,           [tex]P_{2}[/tex] = 1.15 atm

Formula used is as follows.

[tex]\frac{P_{1}}{n_{1}} = \frac{P_{2}}{n_{2}}[/tex]

Substitute the values into above formula as follows.

[tex]\frac{P_{1}}{n_{1}} = \frac{P_{2}}{n_{2}}\\\frac{0.96 atm}{0.650 mol} = \frac{1.15 atm}{n_{2}}\\n_{2} = 0.779 mol[/tex]

Thus, we can conclude that there are 0.779 moles of gas were added to the bottle.

Given the amount of camphor (200mg) we are using in this experiment, please determine how many mg of sodium borohydride to use in this reaction. We would like you to use 5.2 molar equivalents of this reagent. This means 5.2 times the mmol of camphor we are using. As an example: for 110.0 mg of camphor,142 mg of NaBH4 would be used (see if you can confirm this result). For complete credit, your work needs to be clearly drawn out!

Answers

Answer:

Explanation:

From the given information:

Camphor may be reduced as readily in the presence of sodium borohydride(NaHB4). The resulting compound which is stereoselective requires 1 mole of sodium borohydride (NaHB4) to reduce 1 mole of camphor in this reaction. The reaction is shown below.

Through the reduction process of camphor, the reducing agent can reach the carbonyl face with a one-carbon linkage. The product stereoisomer is known as borneol.

If the molecular weight of camphor = 152.24 g/mol

and it mass = 200 mg

The its no of moles = 200 mg/ 152.24 g/mol

= 1.3137 mmol

Now the amount of the required mmol for NaBH4 to be consumed in the reaction = 5.2 × 1.3137 mmol

= 6.831 mmol

since the molar mass of NaBH4 = 37.83 g/mol

Then, using the same formula:

No of moles = mass/molar mass

mass = No of moles × molar mass

mass = 6.831 mmol × 37.83 g/mol

mass of NaBH4 used = 258.42 mg  

The element antimony has two stable isotopes, antimony-121 with a mass of 120.90 amu and antimony-123 with a mass of 122.90 amu. From the atomic weight of Sb = 121.76 one can conclude that: ________
antimony-123 has the highest percent natural abundance
most antimony atoms have a mass of 121.76 amu
antimony-121 has the highest percent natural abundance
both isotopes have the same percent natural abundance

Answers

Answer:

antimony-121 has the highest percent natural abundance

Explanation:

percent natural abundance;

121.76 = 120.90 x + 122.90 (1 - x)

121.76 = 120.90 x + 122.90 - 122.90x

121.76 = -2x + 122.90

121.76 - 122.90 = -2x

x= 121.76 - 122.90/ -2

x= 0.57

Where x and 1 - x refers to the relative abundance of each of the isotopes

Percent natural abundance of antimony-121 = 57 %

Percent natural abundance of antimony-123 = (1 - 0.57) = 43%

Let us remember that isotopy refers to a phenomenon in which atoms of the same element have the same atomic number but different mass numbers. This results from differences in the number of neutrons in atoms of the same element.

We can clearly see that antimony-121 has the highest percent natural abundance.

According to Newton's law of universal gravitation, how do the masses of two
objects relate to the gravitational force between them?
A. As either mass increases, the gravitational force between them
increases.
B. As either mass increases, the gravitational force between them
decreases.
C. Gravitational force increases only when both masses increase.
D. Gravitational force increases only when both masses decrease.

Answers

Answer:

As either mass increases, the gravitational force between them

increases.

Explanation:

According to Newton's law of universal gravitation;

F α m1m2/r^2

That is, the force between two masses in a gravitational field is directly proportional to the product of the two masses and inversely proportional to their distance apart.

Hence, as either of the masses increase, the force of gravitation between the two masses increases. Hence the answer.

Wine goes bad soon after opening because the ethanol dissolved in it reacts with oxygen gas to form water and aqueous acetic acid , the main ingredient in vinegar. Calculate the moles of acetic acid produced by the reaction of of ethanol. Be sure your answer has a unit symbol, if necessary, and round it to significant digits.

Answers

Answer:

The answer is "It takes 1,70 mol of ethanol".

Explanation:

To make acetic acid, we must first write the balanced reaction that occurs of ethanol with oxygen

The response is balanced:

[tex]CH_3CH_2OH+O_2\to CH_3COOH+H_2O[/tex]

1 mol of ethanol creates 1 mol of According the equilibrium Ethanol moles, therefore, required 1.70 mol of water = 1.70 mol

atomaticity of chlorine 1) 2, 2)1, 3) 32 , 4) 4.​

Answers

Answer:

ATOMICITY OF CHLORINE IS 2

Explanation:

Atomicity is defined as the total number of atoms present in a molecule.

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Help a friend edit his college application Which is the best definition of directional selection?a process by which two species can no longer reproducea process by which one of the extreme variations of a trait is favoreda process by which individuals with either extreme of a trait are favoreda process by which average individuals in a population are favored Summarize the article in one sentence (your own words). What is the main idea? Newspaper Coverage of the Invasion at NormandyWar News Summarized June 6th 1944 | New York Times The invasion of western Europe began this morning. General Eisenhower, in his first communique from Supreme Headquarters, Allied Expeditionary Force, issued at 3:30 am, said that Allied naval forces supported by strong air forces began landing Allied armies this morning on the northern coast of France. The assault was made by British, American, and Canadian troops who, under command of Gen. Sir Bernard L. Montgomery, landed in Normandy. London gave no further details but earlier Berlin had broadcast that parachute troops had landed on the Normandy Peninsula near Cherbourg and that invasion forces were pouring from landing craft under cover of warships near Havre. Dunkerque and Calais were being heavily bombed, the Germans said. Later announcements from Berlin said that there was fighting between Caen and Trouville and that shock troops had swung into action to halt the invasion. General Eisenhower, in an order of the day to each member of the great crusade told his men the enemy would fight savagely: We will accept nothing less than full victory! Good luck. In a broadcast to the Peoples of Western Europe, he said the day would come when he would need their full help.A special word to France added that Frenchmen would rule the country. Almost simultaneously it was announced that General de Gaulle had arrived in London. The liberation of Rome in no way slowed the Allied pursuit of the tired and disorganized German armies in Italy yesterday. Armored and motorized units sped across the Tiber River to attack upon the retreating enemies' heels. Five hundred heavy bombers joined with lighter aircraft to smash rail and road routes leading to northern Italy and to add to the foes demoralization. The Eighth Army, despite heavy opposition, especially northeast of Valmontone, captured a number of strategic towns. General Clark said that parts of the two German armies had been smashed. He doubted the ability of the Germans Fourteenth to put up effective opposition, and felt the Allied victory would come soon. President Roosevelt warned the people of the United States in a radio talk last night not to overemphasize the military significance of the liberation of Rome. Germany has not yet been driven to surrender, he said. Victory still lies some distance ahead it will be tough and costly You want to be able to identify the services running on a set of servers on your network. Which tool would best give you the information you need? What is a variegated leaf