propose a synthetic route for the synthesis of a named alkanal starting with ethyl formate and grignard reagent. ​

Answers

Answer 1

Answer:

See explanation and image attached

Explanation:

A Grignard reagent is an alkyl magnesium halide. If it reacts with ethyl formate, an intermediate is formed as shown.

This intermediate can undergo water hydrolysis to form a diol, ethanol and MgBrOH.

Oxidation of the diol obtained now yields the corresponding alkanal which in this case is ethanal.

The scheme of the reaction is shown in the image attached to this answer.

Propose A Synthetic Route For The Synthesis Of A Named Alkanal Starting With Ethyl Formate And Grignard

Related Questions

Reaction of 2,3-dimethyl-1-butene with HBr leads to an alkyl bromide, C6H13Br. On treatment of this alkyl bromide with KOH in methanol, elimination of HBr occurs and a hydrocarbon that is isomeric with the starting alkene is formed. What is the structure of this hydrocarbon, and how do you think it is formed from the alkyl bromide

Answers

Answer:

See explanation and image attached

Explanation:

The image attached shows the entire scheme of reactions mentioned in the question.

The first reaction is an addition reaction which yields a tertiary alkyl halide as shown in accordance with Markovnikov rule.

The second reaction is a dehydrohalogenation in which the base abstracts a proton from the alkyl halide followed by loss of a bromide ion to yield the corresponding alkene.

This alkene is an isomer of the starting material.

A worker gets paid 11.33 $/hour. The worker works on average 39.7 hours/week for 48 weeks per year. How much does the worker make in 1.7 years? ​

Answers

Answer:

36704 $

Explanation:

First we calculate how much the worker gets paid in one week:

11.33 $/hour * 39.7 hour/week = 449.80 $/week

Then we calculate how many weeks does the worker work in 1.7 years:

48 week/year * 1.7 years = 81.6 weeks

Finally we calculate how much does the worker make in 1.7 years:

449.80 $/week * 81.6 weeks = 36704 $

The student adds 0.0010 mol of NaOH(s) to solution Y, and adds 0.0010 mol of NaOH(s) to solution Z. Assume that the volume of each solution does not change when the NaOH(s) is added. The pH of solution Y changes much more than the pH of solution Z changes. Explain this observation.

Answers

Answer:

The answer is in the explanation.

Explanation:

A buffer is defined as the aqueous mixture of a weak acid and its conjugate base or vice versa. Buffers are able to avoid the pH change of a solution when strong acid or bases are added (As NaOH).

Based on the experiment, it is possible that the solution Z was a buffer and Y another kind of solution. For this reson, pH of the solution Y changes much more than the pH of solution Z changes despite the amount of NaOH added is the same in both solutions.

Describe the buffer capacity of the acetic acid buffer solution in relation to the addition of both concentrated and dilute acids and bases. Reference the results in Data Tables 1,2,3, and 4 in your answer.

Answers

Answer:

The more concentrated acetic acid buffer has a better buffer capacity because requires more moles of acid or base to change the pH than a more diluted acetic acid buffer.

Explanation:

Buffer capacity is defined as the moles of an acid or base that are needed to change the pH of a buffer in 1 unit.

A more concentrated solution of acetic buffer contains more moles of the acid per liter of solution. A solution that contains more moles of the acetic ion or the acetic acid requires more moles of base or acid to change the pH, that means:

The more concentrated acetic acid buffer has a better buffer capacity because requires more moles of acid or base to change the pH than a more diluted acetic acid buffer.

In this lab, you will be making solutions of potassium permanganate (KMnO4), which has a formula weight of 158.04 g/mole. Remember to show your calculations and include tne Correct unnits in your answers
a) How many grams of KMnO4 would you need to make 1 L of a 2M solution?
b) How many grams of KMnO4 would you need to make 350 mL of a 0.75 M solution?
c) How many grams of KMnO4 would you need to make 80 mL of a 0.01 M solution?

Answers

Answer:

A. Mass of KMnO₄ = 316.08 g

B. Mass of KMnO₄ = 41.49 g

C. Mass of KMnO₄ = 0.13 g.

Explanation:

A. Determination of the mass of KMnO₄

We'll begin by determining the number of mole of KMnO₄ in the solution. This can be obtained as follow:

Volume = 1 L

Molarity = 2 M

Mole of KMnO₄ =?

Mole = Molarity × Volume

Mole of KMnO₄ = 2 × 1

Mole of KMnO₄ = 2 moles

Finally, we shall determine the mass of KMnO₄. This can be obtained as follow:

Mole of KMnO₄ = 2 moles

Molar mass of KMnO₄ = 158.04 g/mole

Mass of KMnO₄ =?

Mass = mole × molar mass

Mass of KMnO₄ = 2 × 158.04

Mass of KMnO₄ = 316.08 g

B. Determination of the mass of KMnO₄

We'll begin by determining the number of mole of KMnO₄ in the solution. This can be obtained as follow:

Volume = 350 mL = 350/1000 = 0.35 L

Molarity = 0.75 M

Mole of KMnO₄ =?

Mole = Molarity × Volume

Mole of KMnO₄ = 0.75 × 0.35

Mole of KMnO₄ = 0.2625 mole

Finally, we shall determine the mass of KMnO₄. This can be obtained as follow:

Mole of KMnO₄ = 0.2625 mole

Molar mass of KMnO₄ = 158.04 g/mole

Mass of KMnO₄ =?

Mass = mole × molar mass

Mass of KMnO₄ = 0.2625 × 158.04

Mass of KMnO₄ = 41.49 g

C. Determination of the mass of KMnO₄

We'll begin by determining the number of mole of KMnO₄ in the solution. This can be obtained as follow:

Volume = 80 mL = 80/1000 = 0.08 L

Molarity = 0.01 M

Mole of KMnO₄ =?

Mole = Molarity × Volume

Mole of KMnO₄ = 0.01 × 0.08

Mole of KMnO₄ = 0.0008 mole

Finally, we shall determine the mass of KMnO₄. This can be obtained as follow:

Mole of KMnO₄ = 0.0008 mole

Molar mass of KMnO₄ = 158.04 g/mole

Mass of KMnO₄ =?

Mass = mole × molar mass

Mass of KMnO₄ = 0.0008 × 158.04

Mass of KMnO₄ = 0.13 g

Which of the following explains the high boiling
point of water?
a Surface tension
b Polarity
C Capillary action
d Hydrogen bonding

Answers

Answer:

The correct answer is - d. hydrogen bonding.

Explanation:

Water has strong hydrogen bonds between its molecules that require a very high amount of energy in order to break. Water molecules are joined together or bound with a strong intermolecular force called hydrogen bonds.

These bonds require more kinetic energy which means more temperature or heat in order to break the bonds and turn into steam and this is the reason it has a high boiling point.

Which of the following natural hazards occur for a long period of time?
tornado
earthquake
drought
thunderstorm

Answers

Answer:

drought

Explanation:

droughts are long periods without water

Waves are generated when energy passes through causing them to move matter through ____ ?

Answers

Answer:

sending heat waves and vibrations

Why is specific activity used as a measurement of enzyme purity, but the turnover number cannot be used for this purpose?

Answers

Answer:

See explanation

Explanation:

Specific activity of an enzyme is defined as a measure of the rate of reaction between enzyme and substrate.

In the study of enzyme kinetics, specific activity is particularly regarded to be the amount of substrate converted by the enzyme per milligram of protein per unit of time. It is thus a reliable measure of enzyme activity per milligram of total protein.

On the other hand, the turnover number is defined as a measure of the number of conversions achieved by a substrate molecule in one second at a particular active site depending on the specific enzyme concentration.

Since specific activityof the enzyme is the ratio of the enzyme activity to enzyme concentration, then specific activity can be used as a measurement of enzyme purity.

The most intense line in the emission spectrum for sodium appears at a wavelength of 589 nm. What color would you expect to observe when a solution that contains sodium ions is heated strongly in the flame of a Bunsen burner

Answers

Answer:

The most intense line in the emission spectrum for sodium appears at a wavelength of 589 nm.

What color would you expect to observe when a solution that contains sodium ions is heated strongly in the flame of a Bunsen burner?

Explanation:

Put a clean wire loop in a solid sample of the compound containing sodium ions, then keep it on the blue flame of the Bunsen burner.

The color of sodium ions in the Bunsen burner shows charactrestic yellow color.

what flora eat? pliz tell me someone​

Answers

Answer:

flora eat food

Explanation:

because that what every living thing eats to grow.

Answer:

sugar??

Explanation:

plants photosynthesise to make their own food (mainly glucose) to be transported around the plant

A 3.06 gram sample of an unknown hydrocarbon with empirical formula CH2O was found to contain 0.0170 moles of the substance. What are the molecular mass and molecular formula, respectively, of the compound

Answers

Answer:

180 amu

C₆H₁₂O₆

Explanation:

Step 1: Determine the molecular mass of the compound

The sample has a mass (m) of 3.06 g and it contains (n) 0.0170 moles. The molar mass M is:

M = m/n = 3.06/0.0170 mol = 180 g/mol

Then, the molecular mass is 180 amu.

Step 2: Determine the molar mass of the empirical formula.

M(CH₂O) = 1 × M(C) + 2 × M(H) + 1 × M(O)

M(CH₂O) = 1 × 12 g/mol + 2 × 1 g/mol + 1 × 16 g/mol = 30 g/mol

Step 3: Determine the molecular formula

First, we will determine "n" according to the following expression.

n = molar mass molecular formula / molar mass empirical formula

n = 180 g/mol / 30 g/mol = 6

The molecular formula is:

n × CH₂O = 6 × CH₂O = C₆H₁₂O₆

It took 2.30 minutes using a current of 3.00 A to plate out all the copper from 0.300 L of a solution containing Cu2 . What was the original concentration of Cu2

Answers

Answer:

7.16 × 10⁻³ M

Explanation:

Let's consider the reduction reaction of copper during the electroplating.

Cu²⁺(aq) + 2 e⁻ ⇒ Cu(s)

We can calculate the moles of Cu²⁺ present in the solution using the following relations.

1 A = 1 C/s.1 min = 60 s.1 mole of electrons has a charge of 96486 C (Faraday's constant).1 mole of Cu²⁺ is reduced when 2 moles of electrons are gained.

The moles of Cu²⁺ reduced are:

[tex]2.30 min \times \frac{60s}{1min} \times \frac{3.00C}{s} \times \frac{1mole^{-} }{96486C} \times \frac{1molCu^{2+} }{2mole^{-} } = 2.15 \times 10^{-3} molCu^{2+}[/tex]

[tex]2.15 \times 10^{-3} moles[/tex] of Cu²⁺ are in 0.300 L of solution.

[Cu²⁺] = 2.15 × 10⁻³ mol/0.300 L = 7.16 × 10⁻³ M

A sample of a gas at 15°C and 2.50 atm pressure has a volume of 4.5 L. The pressure is lowered to 0.85 atm and the volume decreases to 2.5 L. What is the final temperature of the gas in K.

Answers

Given:

[tex]P_{1} = \text{2.50 atm}[/tex]

[tex]T_{1} = 15^{\circ}\text{C + 273 = 288 K}[/tex]

[tex]V_{1} = \text{4.5 L}[/tex]

[tex]P_{2} = \text{0.85 atm}[/tex]

[tex]V_{2} = \text{2.5 L}[/tex]

Unknown:

[tex]T_{2}[/tex]

Solution:

[tex]\dfrac{P_{1}V_{1}}{T_{1}} = \dfrac{P_{2}V_{2}}{T_{2}}[/tex]

[tex]T_{2} = T_{1} \times \dfrac{P_{2}}{P_{1}} \times \dfrac{V_{2}}{V_{1}}[/tex]

[tex]T_{2} = \text{288 K} \times \dfrac{\text{0.85 atm}}{\text{2.50 atm}} \times \dfrac{\text{2.5 L}}{\text{4.5 L}}[/tex]

[tex]\boxed{T_{2} = \text{54.4 K}}[/tex]

[tex]\\[/tex]

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b. The following reaction takes place in a basic solution. (7 points)
MnO4–(aq) + NO2–(aq) MnO2(s) + NO3–(aq)
The half-reactions (balanced only for atoms) are the following:
MnO4– + 2H2O MnO2 + 4OH–
NO2– + 2OH– NO3– + H2O
Use the following steps to finish balancing the equation.
i. Balance each half-reaction for charge. (2 points)
ii. Multiply each half-reaction by the correct number in order to balance charges for the two half-reactions. (2 points)
iii. Add the equations and simplify to get a balanced equation. (2 points)
iv. How can you tell from this equation that the reaction occurred in a basic solution? (1 point)

Answers

Answer: The final equation has hydroxide ions which indicate that the reaction has occurred in a basic medium.

Explanation:

Redox reaction is defined as the reaction in which oxidation and reduction take place simultaneously.

The oxidation reaction is defined as the reaction in which a chemical species loses electrons in a chemical reaction. It occurs when the oxidation number of a species increases.

A reduction reaction is defined as the reaction in which a chemical species gains electrons in a chemical reaction. It occurs when the oxidation number of a species decreases.

The given redox reaction follows:

[tex]MnO_4^-(aq)+NO_2^-(aq)\rightarrow MnO_2(s)+NO_3^-(aq)[/tex]

To balance the given redox reaction in basic medium, there are few steps to be followed:

Writing the given oxidation and reduction half-reactions for the given equation with the correct number of electrons

Oxidation half-reaction: [tex]NO_2^-+2OH^-\rightarrow NO_3^-+H_2O+2e^-[/tex]

Reduction half-reaction: [tex]MnO_4^-+2H_2O+3e^-\rightarrow MnO_2+4OH^-[/tex]

Multiply each half-reaction by the correct number in order to balance charges for the two half-reactions

Oxidation half-reaction: [tex]NO_2^-+2OH^-\rightarrow NO_3^-+H_2O+2e^-[/tex]         ( × 3)

Reduction half-reaction: [tex]MnO_4^-+2H_2O+3e^-\rightarrow MnO_2+4OH^-[/tex]             ( × 2)

The half-reactions now become:

Oxidation half-reaction: [tex]3NO_2^-+6OH^-\rightarrow 3NO_3^-+3H_2O+6e^-[/tex]

Reduction half-reaction: [tex]2MnO_4^-+4H_2O+3e^-\rightarrow 2MnO_2+8OH^-[/tex]

Add the equations and simplify to get a balanced equation

Overall redox reaction: [tex]3NO_2^-+2MnO_4^-+H_2O\rightarrow 3NO_3^-+2MnO_2+2OH^-[/tex]

As we can see that in the overall redox reaction, hydroxide ions are released in the solution. Thus, making it a basic solution

Kristy finds the mass of an object to be 20 grams and the volume to be 10 mL. What is the density of the object? (don't send me links, just give a straight answer)

Answers

the answer is 2g/ml i believe as you have to do the mass divided by the volume

For the balanced chemical reaction
>
C4H2OH + 602 > 4CO2 + 5H20
if you want to make 100 molecules of CO2, how many molecules of O2 will you need? Answer with a number only.
ITS

Answers

Answer:

150

Explanation:

C₄H₂OH + 6O2 → 4CO2 + 5H₂O

We can find the equivalent number of O₂ molecules for 100 molecules of CO₂ using a conversion factor containing the stoichiometric coefficients of the balanced reaction, as follows:

100 molecules CO₂ * [tex]\frac{6moleculesO_2}{4moleculesCO_2}[/tex] = 150 molecules O₂

150 molecules of O₂ would produce 100 molecules of CO₂.

Which is most likely the first step in a basic food chain?

1. The snake obtain energy by eating the mouse

2. Plants make energy-rich food using sunlight

3. The hawk obtains energy by eating the snake

4. The sun emits energy.

Answers

Answer:

4

Explanation:

(a) Describe the process by which Nitrogen is obtained from air on a large scale​

Answers

Nitrogen is produced commercially almost exclusively from air, most commonly by the fractional distillation of liquid air. In this process, air is first cooled to a temperature below that of the boiling points of its major components, a temperature somewhat less than - 328°F (-200°C).

The element nitrogen exists as a gas  and is  obtained from air on a large scale​ by fractional distillation of air.

What is an element?

An element is defined as a substance which cannot be broken down further into any other substance. Each element is made up of its own type of atom. Due to this reason all elements are different from one another.

Elements can be classified as metals and non-metals. Metals are shiny and conduct electricity and are all solids at room temperature except mercury. Non-metals do not conduct electricity and are mostly gases at room temperature except carbon and sulfur.

The number of protons in the nucleus is the defining property of an element and is related to the atomic number.All atoms with same atomic number are atoms of same element.

Learn more about element,here:

https://brainly.com/question/14347616

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QUESTION 3 (a) Ammonium sulphate, (NH),50, is a soluble salt and it is used in agriculture as fertiliser. 5 g of ammonium sulphate is dissolved in 1 litre of water to produce ammonium sulphate solution. (Relative atomie mass: H = 1, N = 14,0 = 16, )
Calculate

(1) the number of inoles of dissolved ammonium sulphate

(ii) the number of molecules present in the ammonium sulphate solution.

(iii) the number of positive ions present in the ammonium sulphate solution

(iv) the number of negative ions present in the ammonium sulphate solution

(v) the total number of ions present in the ammonium sulphate solution​

Answers

Answer:

The equation: (NH₄)₂SO₄ = 2NH4(+) + SO4(-2)

The number of moles = 5 g / 132.14 g/mol = 0.038 mol

The number of molecules = 0.038 X 6.022x10^23 = 2.29x10^23

the number of positive ions present in the ammonium sulphate solution:

2 positive ions for every 1 molecule of (NH₄)₂SO₄

so 2 x 2.29x10^23 = 4.58x10^23

the number of negative ions present in the ammonium sulphate solution

1 negative ion for every 1 molecule of (NH₄)₂SO₄

so 1 x 2.29x10^23 = 2.29x10^23

the total number of ions present in the ammonium sulphate solution​

4.58x10^23 + 2.29x10^23 = 6.87x10^23

Describe the three freezing points. Is there a relationship between the amount of solute in the solution and the freezing temperature

Answers

Answer:

The three freezing points will all be slightly different. It is given that a water solution has a freezing point of zero degrees Celsius, so water would have a freezing temperature below that. Salt will lower the freezing point, the more that is added.

Explanation:

In what form is energy that is NOT used for life processes released from living things?

1. Thermal energy
2. Chemical energy
3. Light energy
4. Sound energy

Answers

Answer:

Correct answer would be Option 2, Chemical Energy

Hope this helps!

How much energy is produced when 13.1 g of tin reacts with 2.715 g of N2 ?
I.
3 Sn + 2 N2-----------Sn3N4 + 632 KJ
Hint change grams to moles first.
1 mole Sn= 119g
1 mole N2= 28 g

Answers

Answer:

23.2 kJ of energy are released by the reaction.

Explanation:

Hello there!

In this case, according to the given information, it turns out firstly necessary for us to calculate the moles of both tin and nitrogen and the produced moles of Sn3N4 product by each reactant as shown below:

[tex]13.1gSn*\frac{1molSn}{119gSn} *\frac{1molSn_3N_4}{3molSn} =0.0367molSn_3N_4\\\\2.715gN_2*\frac{1molN_2}{28gN_2} *\frac{1molSn_3N_4}{2molN_2} =0.0485molSn_3N_4[/tex]

Thus, since 13.1 grams of tin produce the fewest moles of Sn3N4 product, we infer tin is the limiting reactant, and the correct produced energy, due to this reaction is:

[tex]E=632\frac{kJ}{mol\ rxn}*\frac{1mol\ rxn}{1molSn_3N_4}*0.0367mol Sn_3N_4\\\\E=23.2kJ[/tex]

Regards!

13. What does the Law of Conservation of Mass state?

Answers

The law of conservation of mass states that mass can neither be created or destroyed in a chemical reaction.

Disadvantages of modern periodic table?

Answers

Answer:

It has its elements with mass numbers phrased in many decimal places, it requires one to round off to get the actual value.

The atomic numbers of some elements such as Protonium were just guessed.

Arrange the following molecules in order of decreasing polarity of their bonds.

a. PBr3
b. SF2
c. H2O
d. NCl3

Answers

Answer:

SF2 > H2O > PBr3 > NCl3

Explanation:

Compare the electronegativity values for the atoms and classify the nature of the bonding based on the electronegativity difference.

P has an electronegativity of 2.1, while Br has an electronegativity of 2.96. The difference is 0.86, indicating that these atoms will form covalent bonds.

S has an electronegativity of 2.58 while F has an electronegativity of 4.0. The difference is 1.42, indicating that these atoms will form polar covalent bonds.

O has an electronegativity of 3.5 while H has an electronegativity of 2.1. The difference is 1.4, indicating that these atoms will form polar covalent bonds.

N has an electronegativity of 3.04, whereas Cl has an electronegativity of 3.5. This difference of 0.46 indicates that these atoms will form covalent bonds.

We know that the greater the electronegativity, the higher the polarity. In decreasing order of polarity, we have:

SF2 > H2O > PBr3 > NCl3

The average molecular speed in a sample of Ar gas at a certain temperature is 213 m/s. The average molecular speed in a sample of Ne gas is ______ m/s at the same temperature.

Answers

Answer:

300m/s is the average molecular speed of Ne

Explanation:

Based on Graham's law, the ratio of speed of two gases under constant temperature is equal to the square root of the inverse of their molar masses. The equation is:

v1 / v2 = √m2 / √m1

Where v is the speed of the gas and m the molar mass of the gas

Assuming gas 1 is Argon and gas 2 is Neon:

v1 = 213m/s

v2 = ?

m2 = 20.18g/mol

m1 = 39.948g/mol

213m/s / v2 = √20.18g/mol / √39.948g/mol

v2 = 213m/s / 0.71074

v2 = 300m/s is the average molecular speed of Ne

help!! An atomic number of 4, an atomic mass of 8 and a charge of +1.

Answers

Answer:

berylium

Explanation:

atomic number 4 atomic mass 8 and charge +1

A liquid solvent is added to a flask containing an insoluble solid. The total volume of the solid and liquid together is 80.0 mL. The liquid solvent has a mass of 21.0 g and a density of 0.865 g/mL. Determine the mass of the solid given its density is 2.00 g/mL.

Answers

Answer:

111.44 g

Explanation:

We'll begin by calculating the volume of the solvent. This can be obtained as follow:

Mass of solvent = 21 g

Density of solvent = 0.865 g/mL.

Volume of solvent =?

Density = mass /volume

0.865 = 21 /volume of solvent

Cross multiply

0.865 × volume of solvent = 21

Divide both side by 0.865

Volume of solvent = 21 / 0.865

Volume of solvent = 24.28 mL

Next, we shall determine the volume of the solid. This can be obtained as follow:

Volume of solvent + solid = 80.0 mL.

Volume of solvent = 24.28 mL

Volume of solid =?

Volume of solid = (Volume of solvent + solid) – (Volume of solvent)

Volume of solid = 80 – 24.28

Volume of solid = 55.72 mL

Finally, we shall determine the mass of the solid. This can be obtained as follow:

Density of solid = 2.00 g/mL.

Volume of solid = 55.72 mL

Mass of solid =.?

Density = mass / volume

2 = mass of solid / 55.72

Cross multiply

Mass of solid = 2 × 55.72

Mass of solid = 111.44 g

Therefore, the mass of the solid is 111.44 g

Which two properties are explained by the pool-of-shared-electrons model for metals?

A. low vapor pressure, high melting point

B. malleability, conductivity

C. high melting point, conductivity

D. low vapor pressure, malleability

Answers

I believe it is C but if not that A

Answer:

Actually the answer is B Malleability, conductivity

Explanation:

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