(S)-CH3CH(N3)CH2CH2CH3 can be synthesized by an SN2 reaction. Draw the structures of the alkyl chloride and nucleophile that will give this compound in highest yield.

Answer:

pKa = 4.89.

Explanation:

We can solve this problem by using the Henderson-Hasselbach equation, which states:

pH = pKa + log [tex]\frac{[A^-]}{[HA]}[/tex]

In this case [A⁻] is the concentration of sodium benzoate and [HA] is the concentration of benzoic acid.

We input the given data:

4.63 = pKa + log [tex]\frac{0.16}{0.29}[/tex]

And solve for pKa:

pKa = 4.89

Answer:

d

Explanation:

Answer:

Calcium

Explanation:

Zinc cannot displace Ca because calcium is above it in the reactivity series

Answer:

The number of moles of H₃PO₄ that reacted is 0.000343 moles

Note: Some data is missing. Data from the attachment is used for the calculationsinnthe explanation below.

Explanation:

The reaction is a neutralization reaction between NaOH and H₃PO₄. The equation of the reaction is given as follows:

3 NaOH + H₃PO₄ ---> Na₃PO₄ + 3 H₂O

The molarity of the NaOH solution is 0.238 mol/L.

Average volume of NaOH used during the titration to arrive to endpoint = (4.6 + 3.9 + 4.5) mL / 3 = 4.33 mL

Molarity is defined ratio of the number of moles of solute to the volume of solution. Mathematically, molarity = number of moles/volume in Litres

Number of moles of NaOH reacted = 0.238 mol/L × (4.33mL × 1 L/1000 mL)

Number of moles of NaOH = 0.00103 moles

From the equation of the reaction, 3 moles of NaOH reacts with 1 mole of H₃PO₄

0.00103 moles of NaOH will react with 0.00103 x 1/3 moles of H₃PO₄ = 0.000343 moles of H₃PO₄.

Therefore, number of moles of H₃PO₄ that reacted is 0.000343 moles

Answer:

21.63 %

Explanation:

The molar mass of Mn₃[Mn(CO)₄]₃ is 665.64 g/mol.

Let's assume we have 1 mol of Mn₃[Mn(CO)₄]₃, if that were the case then we would have 665.64 grams.

There are 12 C moles per Mn₃[Mn(CO)₄]₃, with that in mind we calculate the weight of 12 C moles:

Finally we calculate the mass percent of carbon:

Answer:

Please find the complete solution in attached file.

Explanation:

Periodic law is the the properties of the elements that repeat in a regular way as the atomic numbers increase.

Periodic chart organized collection of all chemical elements arranged roughly according to increasing atomic weight. The periodic recurrence of several features in the elements was originally identified by Dmitry I. Mendeleyev in 1869.

1. This is a vertical arrangement of elements in the periodic table   group

2. This is a horizontal arrangement of elements in the periodic table   period

3. The properties of the elements repeat in a regular way as the atomic numbers increase periodic law

4. Element 19 begins this arrangement in the periodic table period

5. The chemical properties of elements 12, 20, and 38 demonstrate this principle.  periodic law

Therefore, periodic law is the the properties of the elements that repeat in a regular way as the atomic numbers increase.

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Answer:

I don't know what to do

Explanation:

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Answer:

a. Single DNA strand used to produce mRNA ⇒ Transcription

b. Requires tRNA ⇒ Translation

c. Ribosome ⇒ Translation

d. DNA polymerase ⇒ Replication

e. Both DNA strands are duplicate  ⇒ Replication

f. Described as semi-conservative  ⇒ Replication

g. Amino acids added to peptide chain ⇒ Translation

Explanation:

Replication: the double-strand DNA is separated into two strands. Each strand is used as a template by DNA polymerase to produce the other strand. The leading strand is read by DNA polymerase in a continuous form (3' - 5') and the lagging strand is read in a discontinuous form (5'-3'). In this way, both strands are duplicated. The process is semi-conservative because the DNA molecule produced conserves 1 original strand and the other strand is the new synthesized one. The corresponding options are: d, e, f.

Transcription: is a process in which the genetic code of DNA is copied into a molecule called messenger RNA (mRNA). The double-strand DNA is opened and one strand is read. The enzyme involved is RNA polymerase, which binds the DNA (in a sequence called promoter) and uses the nucleotide code of DNA as a template to produce a molecule of RNA (the mRNA). Therefore, the correct option for this process is a.

Translation: is the process in which the mRNA sequence (copied from a DNA molecule) is translated into an amino acid sequence to produce a protein. This process is carried out within the cell ribosome. The mRNA is read in groups of three nucleotides (a codon) that codifies amino acids. The translation between codon and amino acid is assisted by molecules called transference RNA (tRNA). As each codon is decoded, an amino acid is added and the new polypeptide sequence is synthesized. Therefore, the correct options are: b, c, g.

Answer:

A sample of calcium fluoride was decomposed into the constituent elements. Write a balanced chemical equation for the decomposition reaction. If the sample produced 294 mg of calcium, how many g of fluorine was formed

Explanation:

The balanced chemical equation for the decomposition of calcium fluoride is shown below:

[tex]CaF_2(s)->Ca(s)+F_2(g)[/tex]

The sample produced 294 g of calcium then, how many grams of fluorine is formed?

From the balanced chemical equation,

1 mol of CaF2 forms 1mol of calcium and 1 mol of fluorine.

That is:

40g of calcium and 38.0 g of fluorine are formed.

then,

If 294 g of calcium is formed then how many grams of fluorine is formed?

[tex]294g Ca * 38g F2 / 40g Ca\\=279.3 g F_2[/tex]

Hence, 279.3 g of fluorine will be formed.

Answer:

The appropriate answer is "9.225 g".

Explanation:

Given:

Required level,

= 63 ppm

Initial concentration,

= 22 ppm

Now,

The amount of free SO₂ will be:

= [tex]Required \ level -Initial \ concentration[/tex]

= [tex]63-22[/tex]

= [tex]41 \ ppm[/tex]

The amount of free SO₂ to be added will be:

= [tex]41\times 225[/tex]

= [tex]9225 \ mg[/tex]

∵ 1000 mg = 1 g

So,

= [tex]9225\times \frac{1}{1000}[/tex]

= [tex]9.225[/tex]

Thus,

"9.225 g" should be added.

The question is incomplete, the complete question is shown in the image attached

Answer:

A and B

Explanation:

The electrophilic substitution of arenes yields a cation intermediate. The positive charge of the cation is delocalized over the entire ring.

The -CN group directs incoming electrophiles to the ortho/para position. The resonance structures for the chlorination of benzonitrile are shown in the question.

Recall that -CN is an electron withdrawing group. The resonance forms that destablize the carbocation intermediate are those in which the -CN group is directly attached to the carbon atom bearing the positive charge as in structures A and B.

Answer:

108.6 g

Explanation:

First we use the PV=nRT formula to calculate the number of nitrogen moles:

Inputting the data:

Then we convert 2.5 moles of N₂ into moles of NaN₃, using the stoichiometric coefficients of the balanced reaction:

Finally we convert 1.67 moles of NaN₃ into grams, using its molar mass:

Answer:

Explanation:

This is a halogenation reaction i.e substitution or replacement of a single or more than a single hydrogen atom in the organic alkane compound with the halogen(here it is chlorine).

The chlorination of 1-chloro-2,2,3,3-tetramethylpentane under UV light resulted in the formation of five (5) dichloro derivatives which are shown in the image attached below.

Also, the compounds containing a stereocenter (i.e a location within the compound composing of various substituents in which the interchangeability of these substituents has the tendency of resulting into a stereoisomer) are indicated with an asterisk in the image below.

From the image below:

compound 1 ⇒  1,1-dichloro-2,2,3,3-tetramethylpentane = 2° C

∴

The given relative reactivity rate for 2°  = 3.6x

For compound 2 ⇒  1,4-dichloro-2,2,3,3-tetramethylpentane = 2°  = 3.6x

For compound 3 ⇒ 1,5-dichloro-2,2,3,3-tetramethylpentane = 1°  = 1x

For compound 4 ⇒ 1-chloro-2-chloromethyl-2,3,3-trimethylpentane

= 1°  = 1x

For compound 5 ⇒ 1-chloro-3-chloromethyl-2,2,3-trimethylpentane

= 1°  = 1x

As such, we have:

2(3.6x) + 3(1x) = 100

7.2x + 3x = 100

10.2x = 100

x = 100/10.2

x = 9.803°

∴

For compound (1) = 3.6(9.803) = 35.3%

For compound (2) = 3.6(9.803) = 35.3%

For compound (3) = 1(9.803) = 9.803°%

For compound (4) = 1(9.803) = 9.803°%

For compound (5) = 1(9.803) = 9.803°%

Water is in the solid phase at 0.25 atm and 0°C.

A pressure of 50 kPa and a temperature of 50 °C correspond to the “water” region—here, water exists only as a liquid. At 25 kPa and 200 °C, water exists only in the gaseous state.

Under standard atmospheric conditions, water exists as a liquid. But if we lower the temperature below 0 degrees Celsius, or 32 degrees Fahrenheit, water changes its phase into a solid called ice.

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Answer:

[Na⁺] = 1.99 M

Explanation:

Na₂S is a ionic salt that can be dissociated.

Dissociation equation is:

Na₂S  →  2Na⁺  +  S⁻²

1 mol of sodium sulfide can give 2 moles of sodium cation.

We convert moles of salt: 78 g . 1mol / 78.06 g = 0.999 moles

As ratio is 1:2, after dissociation we have (0.999 . 2) = 1.998 moles of Na⁺

Molarity is a type of concentration.

It indicates moles of solute in 1 L of solution and in this case, we have 1 L as final voulme.

Moles of Na⁺ are 1.998 moles. Then molarity (mol/L) is:

M =1.99 mol/L  

Answer:

high melting point

Explanation:

The filament of a bulb is often heated to very high temperatures as the bulb is in operation.

Many times, electric bulbs may have to be on for a whole day and they may reach temperatures that are outrageously high in the process.

The material of the filament must have a very high melting point so that it doesn't melt while the bulb is still in operation.

Answer:

Actually the answer is High Vapor pressure

Explanation:

Answer:

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Answer:

antimony-121 has the highest percent natural abundance

Explanation:

percent natural abundance;

121.76 = 120.90 x + 122.90 (1 - x)

121.76 = 120.90 x + 122.90 - 122.90x

121.76 = -2x + 122.90

121.76 - 122.90 = -2x

x= 121.76 - 122.90/ -2

x= 0.57

Where x and 1 - x refers to the relative abundance of each of the isotopes

Percent natural abundance of antimony-121 = 57 %

Percent natural abundance of antimony-123 = (1 - 0.57) = 43%

Let us remember that isotopy refers to a phenomenon in which atoms of the same element have the same atomic number but different mass numbers. This results from differences in the number of neutrons in atoms of the same element.

We can clearly see that antimony-121 has the highest percent natural abundance.

Answer:

Option A (0.043 g) is the correct answer.

Explanation:

Given:

= 43 mg

As we know,

[tex]1 \ mg = \frac{1}{1000} \ g[/tex]

then,

⇒ [tex]43 \ mg = \frac{43}{1000} \ g[/tex]

              [tex]= 0.043 \ g[/tex]

Thus, the above is the correct alternative.

Answer:

5.0molO

Explanation:

To find the moles of oxygen in 2.5 moles of caffeine, we will first research caffeine's molecular formula: C8H10N4O2. From the molecular formula, we can see there are 2 oxygen atoms in every 1 molecule of C8H10N4O2.We can therefore multiply by the following mole ratio to get the moles of oxygen.

2.5molC8H10N4O2×2molO/1molC8H10N4O2 = 5.0molO.

Answer: The density of the given vapor is 0.939 g/L.

Explanation:

Given: Pressure = 233 mm Hg (1 mm Hg = 0.00131579 atm) = 0.31 atm

Temperature = [tex]25^{o}C[/tex] = (25 + 273) K = 298 K

According to the ideal gas equation,

[tex]PV = \frac{m}{M}RT[/tex]

where,

P = pressure

V = volume

m = mass

M = molar mass

R = gas constant = 0.0821 L atm/mol K

T = temperature

This formula can be re-written as follows.

[tex]PM = \frac{m}{V}RT[/tex]    (where, [tex]Density = \frac{mass (m)}{Volume (V)}[/tex] )

Hence, formula used to calculate density of diethy ether (molar mass = 74.12 g/mol) vapor is as follows.

[tex]d = \frac{PM}{RT}[/tex]

Substitute values into the above formula as follows.

[tex]d = \frac{PM}{RT}\\= \frac{0.31 atm \times 74.12 g/mol}{0.0821 L atm/mol K \times 298 K}\\= \frac{22.9772}{24.4658}\\= 0.939 g/L[/tex]

Thus, we can conclude that the density of the given vapor is 0.939 g/L.

Answer:

The molar concentration of the H₂SO₄ solution is 0.28 M

Explanation:

Molar concentration = number of moles / volume in litres

Number of moles = molar concentration × volume

From the equation of reaction, molar ratio of acid to base = 1 : 2

Using the formula; Na/Nb = CaVa/CbVb

Where Na is the number of moles of acid; Nb = number of moles of base; Ca = concentration of acid; Va = volume of acid; Cb = concentration of base; Vb = volume of base; Na/Nb = mole ratio of acid to base

Substituting the given values in the equation:

1/2 = Ca × 25.18 / 0.93 × 14.92

Ca = 0.93 × 14.92/ 25.18 × 2

Ca = 0.28M

Therefore, the molar concentration of the H₂SO₄ solution is 0.28 M

Answer: There are 0.779 moles of gas were added to the bottle.

Explanation:

Given: [tex]n_{1}[/tex] = 0.650 mol,     [tex]P_{1}[/tex] = 730 mm Hg (1 mm Hg = 0.00131579 atm) = 0.96 atm

[tex]n_{2}[/tex] = ?,           [tex]P_{2}[/tex] = 1.15 atm

Formula used is as follows.

[tex]\frac{P_{1}}{n_{1}} = \frac{P_{2}}{n_{2}}[/tex]

Substitute the values into above formula as follows.

[tex]\frac{P_{1}}{n_{1}} = \frac{P_{2}}{n_{2}}\\\frac{0.96 atm}{0.650 mol} = \frac{1.15 atm}{n_{2}}\\n_{2} = 0.779 mol[/tex]

Thus, we can conclude that there are 0.779 moles of gas were added to the bottle.

Answer:

methylcyclohexane does not possess a chiral center

Explanation:

A molecule is said to possess a chiral center if one or more of the atoms in the molecule is bonded to four different atoms or groups.

If we look at methylcyclohexane, none of the carbon atoms in the molecule is bonded to four different atoms or groups hence the molecule contains no chiral centers and will not exhibit optical isomerism.

So, methylcyclohexane has a plane of symmetry thus it is an achiral molecule.

Answer:

c

Explanation:

The question is incomplete, the complete question is:

What volume (mL) of the sweetened tea described in Example 3.14 contains the same amount of sugar (mol) as 10 mL of the soft drink in this example. The example is attached below.

Answer: 75 mL of sweetened tea will contain the same amount of sugar as in 10 mL of soft drink

Explanation:

We first calculate the number of moles of soft drink in a volume of 10 mL

The formula used to calculate molarity:

[tex]\text{Molarity of solution}=\frac{\text{Moles of solute}\times 1000}{\text{Volume of solution (mL)}}[/tex] .....(1)

Taking the concentration of soft drink from the example be = 0.375 M

Volume of solution = 10 mL

Putting values in equation 1, we get:

[tex]0.375=\frac{\text{Moles of sugar in soft drink}\times 1000}{10}\\\\\text{Moles of sugar in soft drink}=\frac{0.375\times 10}{1000}=0.00375mol[/tex]

Calculating volume of sweetened tea:

Moles of sugar = 0.00375 mol

Molarity of sweetened tea = 0.05 M

Putting values in equation 1, we get:

[tex]0.05=\frac{0.00375\times 1000}{\text{Volume of sweetened tea}}\\\\\text{Volume of sweetened tea}=\frac{0.00375\times 1000}{0.05}=75mL[/tex]

Hence, 75 mL of sweetened tea will contain the same amount of sugar as in 10 mL of soft drink

Answer:

F. When everyone is together it gets hotter

Explanation:

Answer:

c. it lies near the equator

Answer:

H2CO

Explanation:

Becuase it has 2 sigma bonds plus one pi bond and one sigma bond that consitute the double bond between C and O.

Answer:

B. H2CO

Explanation:

ANSWER IS ABOVE

THE METHANOIC ACID