If there is initially 0.420 atm of H2O2(g), the equilibrium partial pressures in atm of H2(g), O2(g), and H2O2(g) are 0.314 atm and if the volume is doubled, the total pressure of the system will be reduced to half of the original pressure due to the gas law.
a) Using the given equilibrium constant, we can set up an ICE (Initial, Change, Equilibrium) table to calculate the equilibrium partial pressures:
⇒ 2H2O2(g) ⇌ 2H2(g) + O2(g)
Initial: 0.420 atm 0 atm 0 atm
Change: -x +2x +x
Equilibrium: 0.420-x 2x x
Substituting the values into the equilibrium constant expression:
⇒ Kc = [H2]^2[O2]/[H2O2]^2 = 7.109
⇒ 7.109 = (2x)^2/(0.420-x)^2
Solving for x, we get x = 0.106 atm
Therefore, at equilibrium, the partial pressures of H2, O2, and H2O2 are:
⇒ PH2 = 2x = 0.212 atm
⇒ PO2 = x = 0.106 atm
⇒ PH2O2 = 0.420 - x = 0.314 atm
b) According to Le Chatelier's principle, the equilibrium will shift in the direction that opposes the change. When the volume is doubled, the system will try to reduce the pressure by shifting towards the side with fewer moles of gas. Since the reaction involves the formation of two moles of gas from two moles of reactants, the forward reaction will be favored to reduce the pressure. As a result, the partial pressure of H2O2(g) will increase to establish a new equilibrium.
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Choose the paramagnetic species from below.
Ar
O
Ti4+
All of the above are paramagnetic.
None of the above are paramagnetic.
The correct answer is option (c) Ti4+.
The species which are attracted to a magnetic field are known as paramagnetic species. If we talk about the given options, then we can see that there are only 3 species that are given. Out of these three, only Ti4+ is paramagnetic. How can we determine whether a species is paramagnetic or not? The species which contain unpaired electrons are paramagnetic in nature. If there are all paired electrons, then the species are diamagnetic. If we talk about Ti4+, then it contains 2 unpaired electrons, which makes it paramagnetic. This is the reason why the correct answer is Ti4+.In Ar, all the electrons are paired, which makes it diamagnetic. In O, there are 2 unpaired electrons, which makes it paramagnetic. How can we determine whether a species is paramagnetic or not? The species which contain unpaired electrons are paramagnetic in nature. If there are all paired electrons, then the species are diamagnetic.
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Complete the sentence to explain why ethanol is soluble in water but propane is not Drag the terms on the left to the appropriate blanks on the right to complete the sentence. Reset Help Ethanol has a that can form but the hydrogen bonds polar –OH group ionic bonds nonpolar-CH, group with alkane propane does not covalent bonds water other ethanol molecules Submit Request Answer Part B Complete the sentences to explain winy 1-propanol is soluble in water but 1-hexanol is not. Drag the terms on the left to the appropriate blanks on the right to complete the sentences. Reset Help one to three longer shorter Alcohols with carbon atoms are completely soluble in water. In alcohols with carbon chains, the effect is diminished, making them slightly soluble to insoluble one to four the-CH, group the-OH group one to five Submit Request Answer
Answer:
In general terms, because (1) the carbon-oxygen and hydrogen-oxygen bonds in ethanol are much more polar than any of the bonds in propane; (2) the oxygen atom in ethanol can form hydrogen bonds with the hydrogen atoms in water, but there is not such possibility with propane; and (3) propane contains more carbon atoms per molecule than ethanol.
Explanation:
In general terms, because (1) the carbon-oxygen and hydrogen-oxygen bonds in ethanol are much more polar than any of the bonds in propane; (2) the oxygen atom in ethanol can form hydrogen bonds with the hydrogen atoms in water, but there is not such possibility with propane; and (3) propane contains more carbon atoms per molecule than ethanol.
Does electronegativity increase as atomic radius increases?
Actually, when atomic radius grows, electronegativity often decreases.
The capacity of an atom to draw electrons into a chemical connection is known as electronegativity. The separation between the nucleus and the farthest electrons grows with increasing atomic radius. As a result, the nucleus's attraction to the electrons is reduced, making it more challenging for the atom to draw electrons to itself. The electronegativity values of bigger atoms are therefore often lower than those of smaller ones. Despite this general tendency, there are certain outliers since electronegativity also depends on other elements including nuclear charge and electron configuration. For instance, the rising nuclear charge in halogens causes the electronegativity to rise as the atomic radius falls.
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g the half life of 2n-71 is 2.4 minutes. if we started with 50g at the beginning, how many grams would be left after 12 minutes?
After 12 minutes, the amount of 2N-71 remaining would be 25 grams. This is because the half-life of 2N-71 is 2.4 minutes, meaning that after 2.4 minutes, half of the initial amount (50 grams) will remain. After 12 minutes, half of the remaining 25 grams will have decayed, leaving 25 grams.
The initial amount of 2n-71 is 50 g, and the half-life of 2n-71 is 2.4 minutes. We need to determine how many grams of 2n-71 would be left after 12 minutes. During radioactive decay, the amount of a radioactive substance decreases exponentially over time. The formula for determining the amount remaining of a radioactive substance after time t is:A = A₀(1/2)^(t/h)Where, A₀ = the initial amount of the substance,A = the amount of the substance after time t,h = the half-life of the substance, and t = time elapsedPlugging the given values in the formula, we get:A = 50(1/2)^(12/2.4)A = 50(1/2)^5A = 50(1/32)A = 1.5625Therefore, the amount of 2n-71 left after 12 minutes is 1.5625 g.
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Chemistry Assertion and Reasoning
B) Assertion and Reasoning Direction: in the following questions, a statement followed by a statement of reason (R).
Mark the correct choice as:
(A) Both Assertion (a) And Reason (R) Are true and Reason (R) Is thd correct explanation of assertion (A)
(B) Both Assertion (A) And reason ( R) Are true but Reason (R) Is not correct explanation of assertion (A)
(C) Assertion (A) is true but reason ( R) is false
(D) Assertion (A) is false but reason (R) is true
Assertion: Calcium And Argon are isobars
Reason: Calcium And Argon Have Same Mass Numbers
Assertion: the number of valence electrons in oxygen atoms is 6
Reason: the valency of Oxygen atom is 6
Assertion: most of the Alpha Particles in Rutherfords experiment passed straight through gold foil
Reason: The Centre Of The Atom Is Positively Charged
Answer ASAP PLEASE!
1. Calcium and Argon are isobars , the correct answer is (A). 2. number of valence electrons in oxygen atoms is 6, the correct answer is (B) 3. most of the alpha particles deflected, the correct answer is (D).
Describe Protons?Protons are subatomic particles that are found in the nucleus of an atom. They have a positive electrical charge, which is equal and opposite to the negative charge of electrons, the other subatomic particle found in atoms. The number of protons in the nucleus of an atom determines what element the atom is.
The mass of a proton is approximately 1 atomic mass unit (amu), which is about 1.673 x 10⁻²⁷ kg. This is slightly less than the mass of a neutron, which is another subatomic particle found in the nucleus of an atom.
1. The correct answer is (A) Both Assertion (A) and Reason (R) are true, and Reason (R) is the correct explanation of Assertion (A).
The statement in Assertion is true that Calcium and Argon are isobars because they have the same mass number (40). Isobars are atoms of different elements that have the same mass number but different atomic numbers.
The statement in Reason is also true and provides the explanation for Assertion because the mass number of an atom is equal to the sum of the number of protons and neutrons in its nucleus. Calcium has 20 protons and 20 neutrons, giving it a mass number of 40. Argon has 18 protons and 22 neutrons, also giving it a mass number of 40. Therefore, they have the same number of nucleons and are isobars.
Therefore, option (A) is the correct answer.
2. The correct answer is (B) Both Assertion (A) and Reason (R) are true but Reason (R) is not the correct explanation of Assertion (A).
The statement in Assertion is true that the number of valence electrons in oxygen atoms is 6. Valence electrons are the electrons in the outermost shell of an atom that participate in chemical reactions.
The statement in Reason is also true, but it does not provide the correct explanation for Assertion. Valency refers to the combining capacity of an atom, and it is determined by the number of valence electrons. The valency of oxygen is 2, not 6. Oxygen has 6 valence electrons, but it forms two covalent bonds to complete its octet in most compounds, giving it a valency of 2.
Therefore, option (B) is the correct answer.
3. The correct answer is (D) Assertion (A) is false but reason (R) is true.
The statement in Assertion is false because most of the alpha particles in Rutherford's experiment were deflected at various angles, and only a few passed straight through the gold foil. This observation led Rutherford to propose the nuclear model of the atom.
The statement in Reason is true. The center of the atom, or nucleus, is positively charged because it contains protons, which have a positive charge. Electrons, which have a negative charge, orbit the nucleus in a cloud-like distribution.
Therefore, option (D) is the correct answer.
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In an experiment of the photoelectric effect, an incident beam of visible light shined on a piece of metal and produced electrons with zero kinetic energy (Case 1)1. Select ALL radiations that would produce electrons with some kinetic energy (Case I). bv tl hv Case 1: A photon has just enough energy to overcome the binding energy Case II: The excess energy of photon is transferred to the kinetic energy of the ejected electron. Infrared o x-ray Ultraviolet Gamma ray Radio
The correct options for the radiations that would produce electrons with some kinetic energy in an experiment of the photoelectric effect are given below: Infrared, Ultraviolet, X-ray, Gamma ray, and Photoelectric effect.
What is the photoelectric effect?The photoelectric effect is the emission of electrons when an external electromagnetic radiation falls on a metal surface. When the radiation falls on the surface of a metal, it produces the electrons with kinetic energy due to the transfer of excess energy of the photon to the ejected electron. The emission of electrons occurs when the external radiation falls on the metal surface, and the energy of the photon is greater than or equal to the work function of the metal.
When the energy of the photon is equal to the work function of the metal, the electrons are ejected with zero kinetic energy. However, when the energy of the photon is greater than the work function of the metal, the excess energy is transferred to the kinetic energy of the ejected electron, and it moves out with some kinetic energy. Thus, the radiations that would produce electrons with some kinetic energy in the photoelectric effect are infrared, ultraviolet, x-ray, and gamma rays.
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g the free energy associated with the proton gradient that develops across the inner mitochondrial membrane as a result of the electron transport chain is 23.3 kj per mole of protons. if fadh2 is the only electron donor to the electron transport chain, how many moles of fadh2 would be required to produce a proton gradient in which exactly one mole of protons have been pumped across the membrane, assuming we start with no gradient? the standard reduction potential of fadh2 is 0.10 v, and that of o2 is 0.81 v. select the closest value from the options below. a) 3 mol fadh2 d) 0.17 mol fadh2 b) 1 mol fadh2 e) 5.8 mol fadh2 c) 0.5 mol fadh2
The number of moles of FADH₂ required to produce a proton gradient is 0.17 mol. This can be calculated through the free energy and potential difference. Thus, the correct option is D.
There are 6.022 × 10²³ protons per mole of H⁺. Therefore, one mole of H⁺ contains 1 mole of protons.
The change in potential between FADH₂ and O₂ is: ΔE°' = E°'(O₂) - E°'(FADH₂)
ΔE°' = 0.81 - 0.10
ΔE°' = 0.71 V
ΔG for electron transfer from FADH₂ to O₂ is: ΔG°' = -nFΔE°'
where, n = number of electrons, F = Faraday's constant (96,500 J/V), and ΔE°' is the change in potential between the two half-cells.
We know that n = 2 (since FADH₂ transfers two electrons to O₂).
ΔG°' = -2 × (96,500) × (0.71)
ΔG°' = -137,860 J/mol
ΔG° = -nFΔΨ
where, n = number of protons, F = Faraday's constant (96,500 J/V), and ΔΨ is the change in potential across the membrane. We know that n = 1 (since we want to pump one mole of H⁺ across the membrane).
ΔΨ = ΔG°/(nF)
ΔΨ = (-137,860)/(1 × 96,500)
ΔΨ = -1.43 V
ΔG = ΔG° + RTlnQ
where, R = gas constant (8.31 J/molK), T = temperature in Kelvin (298 K), and Q = reaction quotient.
Since the reaction is at standard conditions, Q = 1 (since all the reactants and products are in their standard states).
ΔG = ΔG°
ΔG = -137,860 J/mol
ΔG = -137.86 kJ/mol
23.3 kJ/mol = n × (1.43 V)
n = 0.17
Therefore, 0.17 mol of FADH₂ is required.
Therefore, the correct option is D.
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Suppose that an ethene molecule gains an additional electron to give the 2 C H-4 ion. Will the bond order of the carbon–carbon bond increase or decrease? Explain.
When an ethene molecule receives an extra electron to form the 2 C H-4 ion, the bond order of the carbon–carbon bond will decrease.
What is bond order?
Bond order is a formal way to quantify the number of covalent bonds that exist between two atoms in chemistry. Bond order is defined as the difference in the number of electron pairs in bonding and antibonding molecular orbitals, as stated by Linus Pauling in his introduction.
Ethene is a hydrocarbon that has two carbon atoms joined by a double bond. In ethene, the carbon-carbon bond order is 2. A bond order is the number of chemical bonds connecting a pair of atoms. Double bonds have a bond order of 2, whereas single bonds have a bond order of 1. Bond order has a significant impact on the stability and strength of the bond.
As a result, a change in bond order can have a significant impact on a molecule's physical and chemical properties.The bond order in the 2 C H-4 ion is calculated using the molecular formula: 2 C + H + 1 e-. Carbon has six electrons in its outermost shell, while hydrogen has one.
To achieve stability, carbon requires four more electrons, and hydrogen requires one more electron. The electron received is utilized to form a new carbon-hydrogen bond. As a result, there will be three single carbon-carbon bonds, and the bond order will decrease from two to 1.5. The bond strength between the two carbon atoms is also reduced. Therefore, the carbon-carbon bond will decrease in bond order when an ethene molecule gains an extra electron to form the 2 C H-4 ion.
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Using your knowledge of periodic properties and trends, how would these elements BEST be classified and why?O A Elements W and Z are metals, Elements X and Y are nonmetals, but Element X is in Group 18 (noble gas).O B. Elements W and Z are nonmetals, but Element w Is In Group 17 (halogen). Elements X and Y are metals.C. Elements W and Z are nonmetals, Elements X and Y are metals, but Element Y is in Group 1 (alkall metal)© D. Elements W and Z are metals, Elements X and Y are nonmetals, but Element Y is in Group 18 (noble gas).
The correct response is D. Elements W and Z are metals, Elements X and Y are nonmetals, but Element Y is in Group 18 (noble gas).
What is element?A substance is considered to be an element if it cannot be chemically reduced to a simpler form. Every atom in an element has the same amount of protons in its atomic nucleus, and as such, the element is made up of identical atoms.
In general, elements in the same group of the periodic table exhibit comparable chemical and physical properties due to their similar electron configurations.
Option D proposes that Elements W and Z are metals, which frequently lose electrons to create positive ions and have poor electronegativity. In contrast, Elements X and Y are nonmetals, which tend to have strong electronegativity and tend to gain electrons to create negative ions. This grouping makes sense as metals and nonmetals have extremely different properties, and elements that are close each other in the periodic table tend to have different properties.
Noble gases are known for their unreactivity and non-reactive character due to their stable electron configurations, so this classification makes sense as well.
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examine the ungraded ball‑and‑stick model to determine the three‑dimensional structure of the molecule. on the corresponding 2d structure, draw one wedge bond and one dash bond over two existing bonds to indicate the same arrangement of atoms in space. the narrow part of each wedge‑and‑dash bond should be towards the same central carbon atom.
In geometry, a three dimensional form may be described as a solid figure or an item or shape that has three dimensions— length, breadth, and height.
What is dimensional structure?Two-dimensional structures are often composed of thin structured slabs of metals and dielectrics on a substrate and enable confinement along two dimensions in the plane transverse to the direction of propagation.
Proteins require a three-dimensional structure because they function as enzymes and cell building components. Proteins have a crucial role as structural elements in cells. Proteins have a set form to offer structure for cells, similar to how bricks have a definite shape to provide structure for our buildings.
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The answers are:
(S)-1-chloro-2,3-dimethylbutaneS configuration, which stands for counterclockwise priority sequence, is provided.Wedge for the methyl group and slash for the H group are placed at the second carbon.What is dimensional structure?Two-dimensional structures, which allow confinement along two dimensions in the plane perpendicular to the path of propagation, are frequently made of thin structured slabs of metals and dielectrics on a substrate.
The carbon on the left is assigned top priority because it is joined to a chlorine atom, which has a much higher molar mass than C and H.
2nd priority is given to the isopropyl group .
3rd priority is given to methyl group
4th priority is given to H.
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Question 15 (1 point) Give the net ionic equation for the reaction (if any) that occurs when aqueous solutions of Na2CO3 and HCl are mixed. O A) 2 H+ (aq) + CO32" (aq) + H2CO3(s) O B) 2 Na* (aq) + CO32" (aq) + 2 H+ (aq) + 2 CI"(aq) + H2CO3(s) + 2 NaCl(aq) O C) 2 H*(aq) + CO32-(aq) → H2O(l) + CO2(e) O D) 2 Na+(aq) + CO32"(aq) + 2 H+ (aq) + 2 CI-(aq) + H2CO3(s) + 2 Nat(aq) + 2 Cl(aq) 20 21
The net ionic equation for the reaction that occurs when aqueous solutions of Na₂CO₃ and HCl are mixed is:
2 H⁺(aq) + CO₃²⁻(aq) → H₂O(l) + CO₂(g). Thus, option C is correct.
A net ionic equation is a chemical equation that depicts only the species that are involved in a reaction in an aqueous solution.
The spectator ions, Na⁺ and Cl⁻, do not participate in the reaction and are present on both sides of the equation.
The H₂CO₃ formed in the reaction quickly decomposes into H₂O and CO₂.
Therefore, the net ionic equation only includes the species that actually participate in the reaction.
2 H+(aq) + CO32-(aq) → H2O(l) + CO2(g).
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A 0.598 g sample of a green metal carbonate, containing unknown metal M, was heated to give the metal oxide and 0.222 g of CO2 (g) according to the reaction below. MCO3(s) + MO(s) + CO2(g) What is the metal M? Prove your answer with appropriate calculations for the number of moles of metal carbonate MCO3, the molar mass of MCO3, and finally the molar mass of the metal M.
The green metal carbonate is decomposed according to the given equation: MCO₃(s) → MO(s) + CO₂(g)
What is molar mass of MCO₃?
The number of moles of CO₂(g) produced can be used to determine the number of moles of the green metal carbonate (MCO₃) that decomposed.0.222 g of CO₂ (g) represents 1 mol of CO₂ (g), since its molar mass is 44 g/mol.
Therefore,1 mol of MCO₃ will produce 1 mol of CO₂ (g) in the reaction. So, 0.222 g of CO₂ (g) corresponds to 1 mol of MCO₃.
Hence, the number of moles of MCO₃ is:
moles of MCO₃= mass/Molar
mass= 0.598 g/Molar mass of MCO₃
The molar mass of MCO₃ can be calculated using the following:
mass percent of MCO₃ = [(mass of M)/(molar mass of M)] × 100%molar mass of MCO₃ = mass of MCO₃/moles of MCO₃
By substituting the value of moles of MCO₃ and the mass of MCO₃ into the equation above, the molar mass of MCO₃ can be calculated.
molar mass of MCO₃= (mass of MCO₃) / (moles of MCO₃)
Finally, to determine the molar mass of metal M, subtract the molar mass of CO3 from the molar mass of MCO₃.
MCO₃ = 12.011 + 3(15.999) + M(55.845)
= 181.76 + 55.845MM
= 55.845 - 60.01MM
= -4.165
The molar mass of the metal M is 4.165 g/mol.
To summarize, the metal M is sodium (Na) and its molar mass is 4.165 g/mol.
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what is the function of the electron transport chain in cellular respiration ?
The electron transport chain (ETC) is an essential part of cellular respiration, which is a series of molecules that transfer electrons from one molecule to another used by cells to convert nutrients into energy.
This starts with the oxidation of molecules such as glucose, which releases electrons that are then transferred to a series of electron carriers in the ETC. The electron carriers are molecules that hold the electrons and can transfer them to other molecules which is known as redox reactions. As the electrons move through the ETC, they release energy which is used to form a proton gradient that is then used to drive the synthesis of ATP, the energy currency of the cell. The ETC is an essential part of cellular respiration as it is the process responsible for generating the energy necessary for cells to function.
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three metals, a, b and c, of equal mass, have heat capacities of 0.3 j/goc, 0.4 j/goc, and 0.5 j/goc, respectively. which of these metals will have the largest increase in temperature if the same amount of heat is added to the each of their systems?
The metal that will respond to the added temperature by increasing is metal A because it has the lowest heat capacity.
How to determine increase in temperature?The metal with the smallest heat capacity will have the largest increase in temperature if the same amount of heat is added to each of their systems. This is because metals with smaller heat capacities require less heat energy to increase their temperature compared to those with larger heat capacities.
Therefore, metal A with the heat capacity of 0.3 J/g°C will have the largest increase in temperature if the same amount of heat is added to each of their systems, followed by metal B with 0.4 J/g°C and metal C with 0.5 J/g°C.
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What is the purpose of the one balloon larger in size than the other balloons? o to represent unoccupied space in a molecule to represent any pair of electrons - bonding or lone pair to represent the space lone pairs occupy in a molecule Submit Request Answer
The balloon that is one size larger than the others serves to symbolise the area in a molecule inhabited by lone pairs of electrons, signifying unshared electron pairs in a particular region.
The Lewis structure is a chemical model that depicts how atoms and valence electrons are arranged in a molecule. The atoms are represented by symbols, and the valence electrons, which are the electrons at the highest energy level, are shown as dots or lines. In organic chemistry, the bigger balloon often designates a region of a molecule where electrons are not shared with any other atoms or groups. The structure and reactivity of the molecule are impacted by this region, which is referred to as a lone pair. The wider balloon makes it easier to see where these unshared electron pairs are located and how they affect the molecule's overall structure and behaviour.
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the atmospheric pressure on venus is about 90 atm or 90 times more than the pressure on earth. carbon dioxide makes up 96.5% of this atmosphere. what is the partial pressure of carbon dioxide on venus?
The partial pressure of carbon dioxide on Venus is approximately 86.85 atmospheres.
If the atmospheric pressure on Venus is approximately 90 times greater than the pressure on Earth, and carbon dioxide makes up 96.5% of the Venusian atmosphere, we can calculate the partial pressure of carbon dioxide on Venus.
Let's assume the pressure on Earth is 1 atmosphere (atm). Then, the atmospheric pressure on Venus would be 90 atm.
To find the partial pressure of carbon dioxide on Venus, we multiply the total atmospheric pressure by the fraction of carbon dioxide in the atmosphere:
Partial pressure of carbon dioxide on Venus = Total atmospheric pressure on Venus * Fraction of carbon dioxide in the atmosphere
Partial pressure of carbon dioxide on Venus = 90 atm * (96.5 / 100)
Partial pressure of carbon dioxide on Venus = 90 atm * 0.965
Partial pressure of carbon dioxide on Venus ≈ 86.85 atm
Therefore, the partial pressure of carbon dioxide on Venus is approximately 86.85 atmospheres.
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(science) explain the difffrence between a food chain and a food web
Answer: A food chain shows what eats what. A food web is made up of all the food chains in the ecosystems.
Explanation: Hope that helps!
Answer:
Explanation:
A food chain outlines who eats whom.
A food web is all of the food chains in an ecosystem.
The phenomenon in which electrons that are closer to the nucleus slightly repel those that are farther out, is known as: select the correct answer below: - shielding - deflecting - building up - converging
The phenomenon in which electrons that are closer to the nucleus slightly repel those that are farther out is known as Shielding.
Electrons in an atom are negatively charged particles, and they are attracted to the positively charged nucleus. However, the outer electrons of an atom are also repelled by the inner electrons that are closer to the nucleus. This repulsion is due to the negative charges of the electrons, and it partially cancels out the attraction of the nucleus for the outer electrons.
Shielding is the phenomenon in which electrons that are closer to the nucleus slightly repel those that are farther out. This makes it possible for electrons in higher energy levels to be farther from the nucleus, so they are less strongly attracted and easier to remove.
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Use the linear regression line from your calibration curve to calculate the concentration of caffeine, in ppm, in your diluted sample. Correct this value for dilution and report the actual concentration of caffeine, in ppm, in the original (i.e. undiluted sample) in your lab report. 0.0235 g Caffeine diluted to 250.0 mL to make standard stock solution undiluted = 5.812 AU diluted 1:10 = 0.573 AU Std Volume AU 1 0.189 2.5 0.481 5 1.35 7.5 2.301 10 3.214 Atarget range Aunknown Cailuted unkown Cunknown
The concentration of caffeine in the diluted sample can be multiplied by 10 to obtain the concentration of caffeine in the original undiluted sample. Concentration of caffeine in original sample= 1.94 × 10= 19.4 ppmTherefore, the actual concentration of caffeine in the original sample (i.e., undiluted sample) is 19.4 ppm.
EXPLANTION: Linear regression line of the calibration curve. From the graph of the calibration curve, the linear regression equation can be determined. The linear regression equation represents a straight line and gives the relationship between the concentration of the analyte and the corresponding response. The equation for the calibration curve is given byY = mx + bwhere Y is the response, m is the slope of the line, x is the concentration, and b is the y-intercept. The slope of the linear regression line can be determined using the formula:m = ∆Y/∆Xwhere ∆Y is the change in the response and ∆X is the change in the concentration. Here,∆Y = (3.214 - 0.189) = 3.025 AU∆X = (10 - 1) = 9 ppmHence,m = ∆Y/∆X= 3.025/9= 0.3361 AU/ppmTherefore, the equation for the calibration curve isY = 0.3361x + bHere, b is the y-intercept of the line, which can be determined by substituting the values of Y and x for any point on the line.Using the point (1, 0.189)Y = mx + b0.189 = 0.3361(1) + bTherefore,b = 0.189 - 0.3361= -0.1471 AUThe linear regression equation isY = 0.3361x - 0.1471 ppmConcentration of caffeine in diluted sampleFrom the calibration curve, the response of the diluted sample is found to be 0.573 AU. Substituting this value in the linear regression equationY = 0.3361x - 0.14710.573 = 0.3361x - 0.1471Solving for x,x = (0.573 + 0.1471)/0.3361= 1.94 ppmTherefore, the concentration of caffeine in the diluted sample is 1.94 ppm.Correcting for dilutionThe diluted sample was prepared by diluting the standard stock solution by a factor of 10. Hence, the concentration of caffeine in the diluted sample can be multiplied by 10 to obtain the concentration of caffeine in the original undiluted sample. Concentration of caffeine in original sample= 1.94 × 10= 19.4 ppmTherefore, the actual concentration of caffeine in the original sample (i.e., undiluted sample) is 19.4 ppm.
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choose the pair of words or phrases that best completes the sentence below. isoelectronic species have radii that vary with even though they have the same number of . select the correct answer below: the number of electrons; protons atomic number; electrons atomic number; neutrons the number of electrons; neutrons
The pair of words or phrases that best completes the sentence "Isoelectronic species have radii that vary with ___even though they have the same number of ___." is "atomic number; electrons."
Explanation:
Isoelectronic species refers to atoms, molecules or ions having the same number of electrons but a different number of protons. They have identical electron configurations but different nuclear charges. As a result, they may have different ionic radii.
The ionization energy and electron affinity of isoelectronic species are identical, but the size of the atoms varies with the nuclear charge or atomic number. Atomic radius depends on the number of electrons and the nuclear charge. This is because the nuclear charge exerts an attractive force on the electrons in the outer shell that holds them in place.
The greater the nuclear charge, the smaller the atom.The pair of words or phrases that best completes the sentence is "atomic number; electrons." The number of electrons in the outermost shell of an atom determines its size. As we progress from left to right on a period, the number of electrons in the outer shell stays the same, but the nuclear charge increases.
This results in a decrease in size from left to right .Arranging isoelectronic species in a table shows that the radius of an ion is inversely proportional to the nuclear charge or atomic number.
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in which case the reaction in the gas mixture will proceed nonspontaneously in the forward direction?
The reaction in the gas mixture will proceed non-spontaneously in the forward direction when the standard free energy change (∆G°) is positive or zero.
What is spontaneous reaction?In chemical reactions, the term spontaneity refers to whether the reaction proceeds on its own or requires an input of energy to occur. When ∆G° is negative, a reaction is said to be spontaneous in the forward direction, meaning it occurs naturally without any external input of energy. When ∆G° is positive or zero, on the other hand, the reaction proceeds nonspontaneously in the forward direction.
In other words, the reaction requires energy input to proceed. The free energy change (∆G) of a reaction is related to its standard free energy change (∆G°) through the equation:
∆G = ∆G° + RT ln(Q)
where, R is the gas constant, T is the temperature in Kelvin, and Q is the reaction quotient.
If Q = 1, the reaction is at equilibrium and ∆G = ∆G°. If Q < 1, the reaction proceeds spontaneously in the forward direction (∆G < 0), and if Q > 1, the reaction proceeds spontaneously in the reverse direction (∆G > 0).
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Please answer really quickly!!
Explain how equilibrium works in terms of energy transfers and temperature. Give an example.
Equilibrium is a state of balance in which the rates of forward and reverse reactions are equal, and energy is exchanged between the reactants and products. The Haber process is an example, where nitrogen and hydrogen gases react to form ammonia with the exchange of heat energy.
How does increasing the temperature affect an equilibrium reaction?Increasing the temperature generally increases the rate of both the forward and reverse reactions, but the effect on the equilibrium constant depends on whether the reaction is exothermic or endothermic. For an exothermic reaction, increasing the temperature will shift the equilibrium towards the reactants, while for an endothermic reaction, increasing the temperature will shift the equilibrium towards the products.
How does changing the concentration of a reactant affect an equilibrium reaction?Changing the concentration of a reactant can shift the equilibrium towards the products or the reactants, depending on whether the reactant is a reactant or a product in the balanced equation. If the concentration of a reactant is increased, the equilibrium will shift towards the products, and if the concentration of a product is increased, the equilibrium will shift towards the reactants, according to Le Chatelier's principle.
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boiling point (bp) elevation is a colligative property. rank the following 0.10 m solutions from lowest to highest bp. i. ammonia ii. methylamine iii. diethylamine iv. t-butylamine
The following 0.10 m solutions can be ranked from lowest to highest boiling point (bp) as:
ammonia < diethylamine < methylamine < t-butylamine.
The elevation in boiling point, ΔTb can be calculated using the expression;
ΔTb = Kb × bm
where ΔTb is the elevation in boiling point, Kb is the boiling point elevation constant, m is the molality of the solution.
For a given solvent, the boiling point elevation is directly proportional to the molality of the solute present, which means that the higher the molality of the solute, the higher the elevation in boiling point. Hence, we can rank the given solutions based on their molality.
The given solutions are all amines and they have the same formula NH₂R. The boiling point elevation constant is inversely proportional to the size of the molecule, which means that the smaller the molecule, the higher the boiling point elevation constant. Hence, the given amines can be ranked based on the size of their alkyl groups.
The order of the given amines based on the size of their alkyl groups is;
t-butylamine > diethylamine > methylamine > ammonia
The order of the given amines based on the boiling point elevation constant is;
ammonia > methylamine > diethylamine > t-butylamine
Ranking the given solutions based on their molality gives;
ammonia < diethylamine < methylamine < t-butylamine
Hence, the order of the given solutions from lowest to highest bp is;
ammonia < diethylamine < methylamine < t-butylamine
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describe the effect of each of the following on the rate of the reaction of magnesium metal with a solution of hydrochloric acid: the molarity of the hydrochloric acid, the temperature of the solution, and the size of the pieces of magnesium.
The molarity will determine the concentration of the acid in the solution, thus increasing the rate of the reaction. The temperature will increase the kinetic energy of the particles. The size of the pieces of magnesium: a larger surface area of magnesium will increase the rate of reaction.
The molarity of the hydrochloric acid:The rate of reaction of magnesium metal with a solution of hydrochloric acid is increased when the molarity of the hydrochloric acid increases. This is because an increase in the molarity of the hydrochloric acid increases the concentration of hydrogen ions in the solution, which increases the frequency of successful collisions between magnesium atoms and hydrogen ions, hence increasing the rate of reaction.
The temperature of the solution:The rate of reaction of magnesium metal with a solution of hydrochloric acid is increased when the temperature of the solution increases. This is because an increase in temperature increases the kinetic energy of magnesium atoms and hydrogen ions, increasing the frequency of successful collisions between them, hence increasing the rate of reaction.
The size of the pieces of magnesium:The rate of reaction of magnesium metal with a solution of hydrochloric acid is increased when the size of the pieces of magnesium decreases. This is because a smaller size of magnesium increases the surface area of magnesium in contact with the solution, increasing the frequency of successful collisions between magnesium atoms and hydrogen ions, hence increasing the rate of reaction.
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What is the difference in electrochemical potential between two electrodes of an electrochemical cell called?
The difference in electrochemical potential between two electrodes of an electrochemical cell is called as the cell potential.
What is the cell potential?The potential difference or voltage that exists between two electrodes in an electrochemical cell when no current is flowing through the cell is called the cell potential. Cell potential, also known as electromotive force (emf), is a measure of the driving force that drives a chemical reaction in an electrochemical cell forward.
The potential difference between the anode and cathode of an electrochemical cell is a quantitative measurement of the cell's capacity to generate electrical energy. The cell potential is usually measured in volts (V), and its sign is determined by the direction in which the electrons flow through the cell. When electrons flow spontaneously from the anode to the cathode, the cell potential is positive, whereas if electrons are forced to flow from the cathode to the anode, the cell potential is negative.
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draw the organic product that is expected to form when the following compound is treated with aqueous naoh.
The organic product that is expected to form when the following compound is treated with aqueous NaOH is RCOONa + H₂O .
The given compound is a carboxylic acid. When treated with aqueous NaOH, it will undergo a reaction known as neutralization to form the corresponding salt of the carboxylic acid.The reaction mechanism is as follows;The first step is the dissociation of NaOH into its ions
NaOH → Na⁺ + OH⁻
Secondly, there will be proton transfer between the carboxylic acid and the OH ion of NaOH as follows:
RCOOH + OH⁻ → RCOO⁻ + H₂O
With this, we can draw the organic product expected to form when the given compound is treated with aqueous NaOH as shown below: OR RCOONa + H₂O. The product formed is the salt of the given carboxylic acid.
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Complete the following radioactive decay problem.
234 U → 4^He +
92. 2
The complete radioactive decay equation is as follows:
234/92 → 4/2He + 230/90 Th
What is a radioactive decay?Radioactive decay is a several processes by which unstable nuclei emit subatomic particles and/or ionizing radiation and disintegrate into one or more smaller nuclei.
According to this question, uranium with the mass number 234 and atomic number 92 undergoes a radioactive decay as follows:
234/92 U → 4/2 He + 230/90 Th
Uranium-234 nuclei decay by alpha emission to thorium-230, except for the tiny fraction (parts per billion) of nuclei that undergo spontaneous fission.
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Determine the pH of each of the following solutions., 3.6×10−2 M HI,9.23×10−2 M HClO4, a solution that is 4.0×10−2 M in HClO4 and 4.8×10−2 M in HCl, a solution that is 1.01% HCl by mass (Assume a density of 1.01 g/mL for the solution.)
A 3.6102 M HI solution has a pH of 1.44. A 9.23102 M HClO4 solution has a pH of 0.036. The mass-based solution with 1.01% HCl has a pH of 2.09 in water.
The concentration of hydrogen ions (H+) in a solution determines the pH, which is a measurement of the solution's acidity or basicity. The pH values of various solutions are measured in the examples provided. Strong acids, HI and HClO4, are present in the first two solutions. Due to its lower pH, HI is a stronger acid than HClO4. The third solution, which comprises a combination of HClO4 and HCl and is weaker than the previous two because of its higher pH level, contains HCl. The pH of the final solution, which contains 1.01% HCl by mass, is 2.09, showing that it is a weak acid.
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What volume of air is present in human lungs if 0.19 mol are present at 312K and 1.3 atm?
A. 0.066
B. 2.9L
C. 5.5L
D.3.7L
Answer:
The answer is D - 3.7 L.
) Predict the product for the following reaction. Assume you have an excess of potassium tert-butoxide. (CH3),COK Br
The potassium tert-butoxide is final product of the reaction is (CH3)3COH.
Why potassium tert-butoxide is (CH3)3COH?
The product for the given reaction is (CH3)3COH.
Reaction: (CH3)3CBr + KOtBu →(CH3)3COH + KBr
Potassium tert-butoxide (KOtBu) is a strong base that can deprotonate hydrogen from (CH3)3COH to form (CH3)3CO-.On the other hand,
(CH3)3CBr is a tertiary halide that can undergo an E2 reaction.
E2 is the abbreviation for bimolecular elimination reactions,
which involve the abstraction of a proton from the adjacent carbon and the removal of the halide anion.
The hydrogen that is abstracted by KOtBu can only come from the carbon that is adjacent to the bromine in (CH3)3CBr, according to Saytzeff's rule, because this is the carbon with the least number of hydrogens.
As a result, an alkene intermediate will be formed.
The KBr salt will be the by-product.
The alkene intermediate, however, is not present in the end product because it is a reactive molecule and quickly reacts with any available hydrogen.
The hydrogen is provided by the KOtBu base.
As a result, the final product of the reaction is (CH3)3COH.
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