Draw bond-line formulas of all dichloro derivatives that might be formed when 1-chloro-2,2,3,3,-tetramethylpentane is allowed to react with Cl 2 under UV irradiation. For each structure, indicate, with an asterisk, any stereocenters that might be present. Predcit the percentage of each product using the relative reactivities 3 0 = 5.3, 2 0 = 3.6, 1 0 = 1
Answers
Answer:
Explanation:
This is a halogenation reaction i.e substitution or replacement of a single or more than a single hydrogen atom in the organic alkane compound with the halogen(here it is chlorine).
The chlorination of 1-chloro-2,2,3,3-tetramethylpentane under UV light resulted in the formation of five (5) dichloro derivatives which are shown in the image attached below.
Also, the compounds containing a stereocenter (i.e a location within the compound composing of various substituents in which the interchangeability of these substituents has the tendency of resulting into a stereoisomer) are indicated with an asterisk in the image below.
From the image below:
compound 1 ⇒ 1,1-dichloro-2,2,3,3-tetramethylpentane = 2° C
∴
The given relative reactivity rate for 2° = 3.6x
For compound 2 ⇒ 1,4-dichloro-2,2,3,3-tetramethylpentane = 2° = 3.6x
For compound 3 ⇒ 1,5-dichloro-2,2,3,3-tetramethylpentane = 1° = 1x
For compound 4 ⇒ 1-chloro-2-chloromethyl-2,3,3-trimethylpentane
= 1° = 1x
For compound 5 ⇒ 1-chloro-3-chloromethyl-2,2,3-trimethylpentane
= 1° = 1x
As such, we have:
2(3.6x) + 3(1x) = 100
7.2x + 3x = 100
10.2x = 100
x = 100/10.2
x = 9.803°
∴
For compound (1) = 3.6(9.803) = 35.3%
For compound (2) = 3.6(9.803) = 35.3%
For compound (3) = 1(9.803) = 9.803°%
For compound (4) = 1(9.803) = 9.803°%
For compound (5) = 1(9.803) = 9.803°%
Related Questions
Give your familiarity for following terms
1. roasting 2. smelting 4. zone refining 5. polling
Answers
Answer:
The roasting process is a delicate combination of art and science . Roasters are familiar with how the beans look and the smells Well, familiarity with the machine makes things much easier to predict, but the best way is to do many different tests .Well, familiarity with the machine makes things much easier to predict, but the best way is to do many different tests.Smelting is a process of applying heat to ore in order to extract a base metal. It is a form of extractive metallurgy. It is used to extract many metals from their ores, including silver, iron, copper, and other base metals.In zone refining, solutes are segregated at one end of the ingot in order to purify the remainder, or to concentrate the impurities. For example, in the preparation of a transistor or diode semiconductor, an ingot of germanium is first purified by zone refining. In zone refining, solutes are segregated at one end of the ingot in order to purify the remainder, or to concentrate the impurities. ... For example, in the preparation of a transistor or diode semiconductor, an ingot of germanium is first purified by zone refining.Polling is the process where the computer or controlling device waits for an external device to check for its readiness or state, often with low-level hardware. For example, when a printer is connected via a parallel port, the computer waits until the printer has received the next character.Explanation:
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Which diagram correctly depicts the trend in electronegativity?
a.
b.
c.
d.
Answers
Explanation: Reference this electronegativity graph!
The electronegativity increases across the period and decreases down the group. Thus, option B is correct.
Electronegativity can be defined as the tendency of an atom to gain or attract an electron. The electronegativity has been dependent on the size of the atom, as well as the atomic number and valence electrons.
The atom with the requirement of a less number of atoms to complete its octet can easily gain the electron and thereby have high electronegativity. The atomic size also plays a role in the electronegativity of the atom.
The atom with a bigger size has the lesser force of attraction from the nucleus and thus has difficulty attracting the electron, however, the smaller size atom can easily attract the electron with the attraction force from the nucleus.
Thus, the elements with smaller sizes and a high number of valence electrons are more electronegative. In the periodic table, on moving from left to right the valence electrons increase, thus the electronegativity increases.
On moving down the group, the element size increase, thus the electronegativity decreases down the group.
The electronegativity increases across the period and decreases down the group. Thus, option B is correct.
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Calculate the number of ATOMS in 1.0 mole of O2. blank x 1024
Answers
Answer:
6.023*10^23........ .......
Draw 2,3-dichloro octane
Answers
Answer:
Hi friend
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Which of the following statements correctly explains why bromination reactions are more selective than chlorination reactions.
a. bromine radical is less stable than chlorine radical, so it is more reactive and less choosy
b. bromine radical is more stable than chlorine radical, so it is more reactive and less choosy
c. bromine radical is more stable than chlorine radical, so it is less reactive and more choosy
d. bromine radical is less stable than chlorine radical, so it is less reactive and more choosy
e. relative radical stability is 3' radicals > 2" radicals> 1 radicals when bromine radicals snatch hydrogens from alkanes, but when chlorine radicals snatch hydrogens the resulting alkyl radical stability is 3 radicals < 2 radicals< 1' radicals
Answers
Answer: A bromine radical is more stable than chlorine radical, so it is less reactive and more choosy.
Explanation:
A chlorine atom being more electronegative in nature is able to attract a hydrogen atom more readily towards itself as compared to a bromine atom.
Since bromine is less electronegative in nature so bromine will be more selective as a hydrogen abstracting agent. As a result, bromine radical is more stable in nature than chlorine radical.
Thus, we can conclude that bromine radical is more stable than chlorine radical, so it is less reactive and more choosy.
Consider an acid-base titration in which the base is dispensed from a burette into a flask containing an acid. If any drops of the base adhere to the inner walls of the flask, but do not actually mix with the solution, the calculated acid concentration would be
Answers
Answer:
Higher than the actual value
Explanation:
Titration is a volumetric process in which a known volume of solution is dispensed from a burette to react with a known volume of solution in a conical flask.
When acid-base titration is carried out in such a way that the base is in the burette and the acid is in the conical flask and drops of the base adhere to the inner walls of the flask, but do not actually mix with the solution, the calculated acid concentration would be higher than the actual value.
This is because;
From CA= CBVBnA/VAnB
When VB(volume of base) that reacted is lower than the actual volume recorded, then the calculated volume of CA(concentration of acid) is much higher than the actual value since drops of the base adhere to the inner walls of the flask.
The angular momentum quantum number (l) value of 0 indicates the ________ subshell.
Answers
Answer:
indicates the number of subshells
What is oxygen's half-equation?
Answers
answer; 1/ 20_2[2-] +2e - ->0.
What is the formula of the compound Pentasilicon trioxide ?
Answers
Answer: the molecular formula of trioxide is ClOClO3 or Cl2O4
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A sealed vessel initially contains 100 g of chlorine gas and 90 g of hydrogen gas. The two gases undergo reaction to form HCl. Which of the following statements is true?
a. 100 g HCl is produced
b. 190 g HCl is produced
c. less than 90 g HCl is produced
d. between 100 and 190 g of HCl is produced
Answers
Answer:
d.
Explanation:
H2 + Cl2 = 2HCL
From the equation 2g hydrogen combine with 71g of chlorine.
So 35.5 g Cl2 combines with 1g of H2
There are 100g of Cl2 so this will, by proportion, react with 100/35.5 g hydrogen.
This is 2.8 g hydrogen so the mass of HCl formed = 102.8 g.
The true statement is that d. between 100 and 190 g of HCl is produced.
How do find the mass of HCL?To find mass of HCL:
H2 + Cl2 = 2HCL
From the equation, 2g of hydrogen combines with 71g of chlorine.
So 35.5 g Cl2 combines with 1g of H2
There are 100g of Cl2 so this will, by proportion, react with 100/35.5 g of hydrogen.
This is 2.8 g hydrogen so the mass of HCl formed = 102.8 g.
Hydrogen chloride may be formed by the direct combination of chlorine (Cl2) gas and hydrogen (H2) gas.
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How to calculate the actual volume (ml) of water removed from the burette with water
density 1 g/ml:
i. 5mL of water removed
Answers
Answer:
Explanation:
The density of pure water is 1 gram per 1 milliliter or one cubic cm. By knowing the density of water we can use it in dilution equations or to calculate the specific gravity of other solutions.
It can also help us determine what other substances are made of using the water displacement experiment. This is done by observing how much water is displaced when an object is submerged in the water. As long as you know the density of the water, the mass of the object being submerged and the volume of increase you can calculate the density of the object.
This was done by the great Archimedes in discovering what composed the kings crown.
What is the volume of a flask containing 0.199mol of Cl2at a temperature of 313K and a pressure of 1.19atm
Answers
Answer:
43.0 L
Explanation:
Step 1: Given and required data
Moles of chlorine gas (n): 0.199 molTemperature (T): 313 KPressure (P): 1.19 atmIdeal gas constant (R): 0.0821 atm.L/mol.KStep 2: Calculate the volume of the flask (V)
We will use the ideal gas equation.
P × V = n × R × T
V = n × R × T / P
V = 1.99 mol × (0.0821 atm.L/mol.K) × 313 K / 1.19 atm = 43.0 L
The answer is 4.30 L
How many liters of hydrogen can be produced at a pressure of 2 atm and a temperature of 298 K
Answers
Answer:
1.17 L of H₂
Explanation:
We'll begin by calculating the number of mole in 2.3 g of Mg. This can be obtained as follow:
Mass of Mg = 2.3 g
Molar mass of Mg = 24 g/mol
Mole of Mg =?
Mole = mass /molar mass
Mole of Mg = 2.3 / 24
Mole of Mg = 0.096 mole
Next, we shall determine the number of mole of H₂ produced by the reaction of 2.3 g (i.e 0.096 mole) of Mg. This can be obtained as follow:
Mg + 2HCl —> MgCl₂ + H₂
From the balanced equation above,
1 mole of Mg reacted to 1 mole of H₂.
Therefore, 0.096 mole of Mg will also react to produce 0.096 mole of H₂.
Finally, we shall determine volume of H₂ produced from the reaction. This can be obtained as follow:
Number of mole (n) of H₂ = 0.096 mole
Pressure (P) = 2 atm
Temperature (T) = 298 K
Gas constant (R) = 0.0821 atm.L/Kmol
Volume (V) of H₂ =?
PV = nRT
2 × V = 0.096 × 0.0821 × 298
Divide both side by 2
V = (0.096 × 0.0821 × 298) /2
V = 1.17 L
Therefore, 1.17 L of H₂ were obtained from the reaction.
A product of homolytic fission can never be
a - charged
b - nucleophile
c- both
d-none of these
Answers
Answer:
both
Explanation:
A homolytic fission is said to have occurred when the breakage of a bond between two atoms leaves each of the bonding atoms with equal number of electrons. Homolytic fission often results in the creation of radicals.
Since homolytic fission yields two species with equal number of electrons(usually odd number of electrons), the products of such process can not be charged. They can not be nucleophiles because nucleophiles need to possess two electrons which can be shared with another chemical specie.
A chemist measures the energy change
ΔH during the following reaction:
2NH3(g)→N2(g)+3H2(g)
ΔH=160kJUse the information to answer the following questions.This reaction is:__________.
a. endothermic
b. exothermic
Suppose 70.9 g of NH3 react. Will any heat be released or absorbed?
a. Yes, absorbed
b. Yes, released
c. No.
If you said heat will be released or absorbed in the second part of this question, calculate how much heat will be released or absorbed. Round your answer to 3 significant digits.
Answers
Answer:
For (1): The correct option is (a)
For (2): The correct option is (a) and 333.6 kJ of heat will be absorbed when 70.9 g of ammonia reacts.
Explanation:
There are 2 types of reactions that are classified based on enthalpy change:
Endothermic reactions: These are the reactions where heat is absorbed by the reaction. The change in enthalpy of the reaction, [tex]\Delta H_{rxn}[/tex] is positive for these reactions.
Exothermic reactions: These are the reactions where heat is released by the reaction. The change in enthalpy of the reaction, [tex]\Delta H_{rxn}[/tex] is negative for these reactions.
For (1):For the given chemical reaction:
[tex]2NH_3(g)\rightarrow N_2(g)+3H_2(g);Delta H=160kJ[/tex]
As the change in enthalpy or heat of the reaction is positive. Thus, the reaction is an endothermic reaction because heat is absorbed by the reaction.
For (2):When ammonia reacts, some amount of heat will be absorbed by the reaction. Thus, we can say the heat will be absorbed.
The number of moles is calculated by using the equation:
[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex] ......(1)
Given mass of ammonia = 70.9 g
Molar mass of ammonia = 17 g/mol
Using equation 1:
[tex]\text{Moles of ammonia}=\frac{70.9g}{17g/mol}=4.17mol[/tex]
By stoichiometry of the reaction:
If 2 mole of ammonia reacts, the heat absorbed is 160 kJ
So, if 4.17 moles of ammonia reacts, the heat absorbed will be = [tex]\frac{160kJ}{2mol}\times 4.17mol=333.6kJ[/tex]
Hence, 333.6 kJ of heat will be absorbed when 70.9 g of ammonia reacts
define saturated and unsaturated fats
Answers
Saturated fatty acids lack double bonds between the individual carbon atoms, while in unsaturated fatty acids there is at least one double bond in the fatty acid chain. Saturated fats tend to be solid at room temperature and from animal sources, while unsaturated fats are usually liquid and from plant sources.
Answer:
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what is the qualitative analysis of (nh4) 2co3 using NaOH, HCL, BaCL2, and AgNO3
Answers
Answer:
qualatatiev is fs-hj_jakakak
A chemist combines 33 g of methane with 289 g of oxygen to from 189 g of carbon dioxide and 30 g of water. Determine if the results of the following word problem adheres to the Law of Conservation of Mass.
Answers
Answer:
The correct answer is - no not adhere to the law of mass conservation.
Explanation:
According to the law of mass conservation in an isolated system, the mass can not be created or destroyed and in a chemical or physical change, the mass of products should be always equal to the mass of reactants.
On the basis of the law the mass of the chemical reaction-
Mass of products = mass of reactants
33 g of methane + 289g of oxygen = 189g of carbon dioxide + 30g of water
322g ≠ 219 g
which means this reaction does not adhere to the law of conservation.
Suppose a 0.042M aqueous solution of phosphoric acid (H3PO4) is prepared. Calculate the equilibrium molarity of HPO4^−2.
Answers
Answer:
2.89x10⁻⁵M = [HPO₄²⁻]
Explanation:
The equilibrium of H3PO4 in water occurs H2PO4-:
H3PO4(aq) + H2O(l) ⇄ H3O⁺(aq) + H2PO4⁻(aq)
pKa = 2.16. And as pKa = -log Ka; Ka = 10^-2.16
Ka = 6.9183x10⁻³ = [H3O⁺] [H2PO4⁻] / [H3PO4]
As both [H3O⁺] and [H2PO4⁻] comes from the same equilibrium,
[H3O⁺]=[H2PO4⁻] :
[H3O⁺] = X
[H2PO4⁻] = X
[H3PO4] = 0.042 - X
Where X is reaction coordinate
Replacing:
6.9183x10⁻³ = [X] [X] / [0.042 - X]
6.9183x10⁻³ = X² / 0.042 - X
2.905686x10⁻⁴ - 6.9183x10⁻³X - X² = 0
Solving for X:
X = -0.02M. False solution. There is no negative concentration.
X = 0.014M. Right solution
[H2PO4⁻] = 0.014M
In the second equilibrium:
H2PO4⁻(aq) + H2O(l) ⇄ HPO4-(aq) + H3O+(aq)
Based on the same principles of the last equilibrium:
pKa2 = 7.21
Ka2 = 6.166x10⁻⁸ = [HPO4-] [H3O+] / [H2PO4⁻]
[HPO4-] = X
[H3O+] = X
[H2PO4⁻] = 0.014M - X
6.166x10⁻⁸ = X² / [0.014M - X]
8.3623x10⁻¹⁰ - 6.166x10⁻⁸X - X² = 0
Solving for X:
X = -0.0000289485. False solution.
X =
2.89x10⁻⁵M = [HPO₄²⁻]Draw the skeletal structure for: (E)-hept-5-en-2-one
Answers
Answer:
Draw the skeletal structure for: (E)-hept-5-en-2-one
Explanation:
The root word hept indicates that the given compound has seven carons in its longest chain.
-en- primary suffix indicates that the compound has one double bond in it.
2-one indicates that the compound has -C=O bond in the second carbon.
The prefix (E) indicates that the highest priority groups are on the opposite direction of the double bond.
The structure of the given molecule is:
Classify each of the following as a strong acid or a weak acid and indicate how each should be written in aqueous solution. Classify ... In solution this acid should be written as: weak 1. hydrocyanic acid H3O CN- _______ 2. hydrobromic acid
Answers
Answer:
HCN, weak acid
H⁺, Br⁻, strong acid
Explanation:
Hydrocyanic acid is a weak acid, according to the following equation.
HCN(aq) ⇄ H⁺(aq) + CN⁻(aq)
Thus, it should be written in the undissociated form (HCN).
Hydrobromic acid is a strong acid, according to the following equation.
HBr(aq) ⇒ H⁺(aq) + Br⁻(aq)
Thus, it should be written in the ionic form (H⁺, Br⁻).
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Which of the following lists describes characteristics of an acid? (3 points)
Bitter taste, high pH, and caustic
Sour taste, low pH, and dissolves metals
Sour taste, high pH, and dissolves metals
Slippery, low pH, and caustic
Answers
Acids have sour taste, low pH and dissolves metals.
The list that describes the characteristics of an acid is that it has sour taste, low pH, and dissolves metals.
Characteristics of an acidAn acid is a chemical substance that has the ability to donate hydrogen ions when involved in a chemical reaction.
The following are the characteristics or features of an acid:
They have a sour taste when tasted.When measured using a pH scale it is less than 7(low pH).They react with active metals to yield hydrogen gas.Therefore, the list that describes the characteristics of an acid is that it has sour taste, low pH, and dissolves metals.
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g Consider two different liquids at atmospheric pressure: hexane and water. Hexane has a higher vapor pressure than water. As a result, the temperature at which hexane will boil will be [ Select ] water and its vapor pressure when it is boiling will be [ Select ] water when water is boiling.
Answers
Answer:
Lower than
Higher than
Explanation:
The vapour pressure and boiling point of liquids are inversely related. Thus, the higher the vapour pressure of a liquid, the lower it's boiling point. Lower vapour pressure implies that the liquid is easily converted into vapour phase.
If hexane has a higher vapour pressure than water then its boiling point is lower than that of water and its vapor pressure when it is boiling will be higher than water when water is boiling.
Silver has two naturally occurring isotopes with the following isotopic masses: 10747Ag 10947Ag 106.90509 108.9047 The average atomic mass of silver is 107.8682 amu. The fractional abundance of the lighter of the two isotopes is ________.
Answers
Answer: The fractional abundance of lighter isotope is 0.518
Explanation:
Average atomic weight is the sum of the masses of the individual isotopes each multiplied by its fractional abundance. The equation used is:[tex]\text{Average atomic weight}=\sum_{i=1}^{n}\text{(Atomic mass of isotope)}_i\times \text{(Fractional abundance)}_i[/tex] ......(1)
Let the fractional abundance of Ag-107 isotope be 'x'
For Ag-107 isotope:Atomic mass = 106.90509 amu
Fractional abundance = x
For Ag-109 isotope:Atomic mass = 108.9047 amu
Fractional abundance = (1 - x)
Average atomic mass of silver = 107.8682 amu
Plugging values in equation 1:
[tex]107.8682=(106.90509 \times x) + (108.9047 \times (1-x))\\\\107.8682=106.90509x+108.9047-108.9047x\\\\1.99961x=1.0365\\\\x=0.518[/tex]
Fractional abundance of Ag-107 isotope (lighter) = x = 0.518
Hence, the fractional abundance of lighter isotope is 0.518
Qual número atômico do ferro?
Answers
Answer:
The answer is Iron.
Explanation:
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Nickel + oxygen = nickel oxide. What is the balanced redox reaction?
Answers
Answer:
This is an oxidation-reduction (redox) reaction:
2 Ni0 - 4 e- → 2 NiII
(oxidation)
2 O0 + 4 e- → 2 O-II
(reduction)
Ni is a reducing agent, O2 is an oxidizing agent.
An ionic compound contains an unknown ion X and has the formula X3N2. Ion X contains 10 electrons. Write down the chemical symbol of X?
Answers
Answer:
Mg3N2
Explanation:
it would be magnesium as it would loss to electron so it would have 10 electron. you can see in the picture above .
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What is the cell potential of an electrochemical cell that has the half-reactions shown below?
Ag⁺ + e⁻ → Ag
Fe → Fe³⁺ + 3e⁻
Answers
Answer:
E°(Ag⁺/Fe°) = 0.836 volt
Explanation:
3Ag⁺ + 3e⁻ => Ag°; E° = +0.800 volt
Fe° => Fe⁺³ + 3e⁻ ; E° = -0.036 volt
_________________________________
Fe°(s) + 3Ag⁺(aq) => Fe⁺³(aq) + 3Ag°(s) ...
E°(Ag⁺/Fe°) = E°(Ag⁺) - E°(Fe°) = 0.800v - ( -0.036v) = 0.836 volt
1. Arrange the following groups in order of decreasing priority that would allow you to determine E/Z, or R/S. Provide a string of letters (e.g. abcd) as an answer with the highest priority listed first, lowest priority last:
a) -CH3 b) -CH2OH c) -CH2NH2 d) -CH2BR
2. Arrange the following groups in order of decreasing priority that would allow you to determine E/Z, or R/S. Provide a string of letters (e.g. abcd) as an answer with the highest priority listed first, lowest priority last:
a) -F b) -CH2OH c) -CHO d) -CH3
Answers
2. acbd
Good luck
Regards
BLACKSHARK
1) The order of decreasing priority would allow determining E/Z or R/S is "dbca".
2) The order of decreasing priority would allow determining E/Z or R/S is "acbd".
What is absolute configuration?Absolute configuration can be described as to the spatial arrangement of atoms within a chiral molecular entity. Absolute configuration in organic molecules, where carbon is bonded to four different substituents.
The absolute configuration has used a set of rules to describe the relative positions around the chiral center atom. The most common labeling method is the descriptors R or S where R and S refer to Rectus and Sinister.
The group with the highest atomic number will get the highest priority and the group with the lowest atomic number substituents will get the lowest priority. Therefore, the order of priority is -CH₂Br > -CH₂OH > -CH₂NH₂ > -CH₃.
Therefore, the order of priority for the second part is -F > -CHO > -CH₂OH > -CH₃.
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Identify a process that is NOT reversible. Identify a process that is NOT reversible. melting of snow baking of bread deposition of carbon dioxide freezing water melting of aluminum
Answers
Answer:
Identify a process that is NOT reversible.
Melting of snow
baking of bread
deposition of carbon dioxide
freezing water
melting of aluminum
Explanation:
A physical change is the one in which there is a change only in its physical state, color, the appearance of the substance. But the chemical composition of the substance remains unchanged.
It is a temporary change and can be reversed easily.
For example:
melting, freezing, deposition etc.
Baking is a permanent change and the chemical composition of the substance changes.
Hence, among the given options, baking of bread is not a reversible change.
Out of the following all are physical changes except baking of bread and physical changes are reversible so the process which is not reversible is baking of bread.
What are physical changes?Physical changes are defined as changes which affect only the form of a substance but not it's chemical composition. They are used to separate mixtures in to chemical components but cannot be used to separate compounds to simpler compounds.
Physical changes are always reversible using physical means and involve a change in the physical properties.Examples of physical changes include melting,boiling , change in texture, size,color,volume and density.Magnetism, crystallization, formation of alloys are all reversible and hence physical changes.
They involve only rearrangement of atoms and are often characterized to be changes which are reversible.
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